AU2001250020A1 - A nickel-rhenium catalyst for use in reductive amination processes - Google Patents
A nickel-rhenium catalyst for use in reductive amination processesInfo
- Publication number
- AU2001250020A1 AU2001250020A1 AU2001250020A AU5002001A AU2001250020A1 AU 2001250020 A1 AU2001250020 A1 AU 2001250020A1 AU 2001250020 A AU2001250020 A AU 2001250020A AU 5002001 A AU5002001 A AU 5002001A AU 2001250020 A1 AU2001250020 A1 AU 2001250020A1
- Authority
- AU
- Australia
- Prior art keywords
- nickel
- reductive amination
- rhenium
- rhenium catalyst
- weight percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006268 reductive amination reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- UJRJCSCBZXLGKF-UHFFFAOYSA-N nickel rhenium Chemical compound [Ni].[Re] UJRJCSCBZXLGKF-UHFFFAOYSA-N 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 8
- 229910052759 nickel Inorganic materials 0.000 abstract 4
- 229910052702 rhenium Inorganic materials 0.000 abstract 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8896—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
- C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
A nickel/rhenium catalyst composition for the reductive amination of lower aliphatic alkane derivatives is described. The catalyst includes from about 2 to about 75 weight percent nickel and has a nickel to rhenium weight percent ratio of from about 1:1 to about 200:1. The nickel and rhenium are supported on an alumina-silica support which contains from about 5 to about 65 weight percent silica and has a BET surface area of from about 30 to about 450 m2/g. A process for the reductive amination of lower aliphatic alkane derivatives using such a catalyst composition is also provided.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/519,724 US6534441B1 (en) | 1999-03-06 | 2000-03-03 | Nickel-rhenium catalyst for use in reductive amination processes |
US09/519,724 | 2000-03-03 | ||
PCT/US2001/040221 WO2001066247A2 (en) | 2000-03-03 | 2001-03-02 | A nickel-rhenium catalyst for use in reductive amination processes |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2001250020A1 true AU2001250020A1 (en) | 2001-09-17 |
Family
ID=24069505
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2001250020A Abandoned AU2001250020A1 (en) | 2000-03-03 | 2001-03-02 | A nickel-rhenium catalyst for use in reductive amination processes |
Country Status (8)
Country | Link |
---|---|
US (1) | US6534441B1 (en) |
EP (1) | EP1385625B1 (en) |
JP (1) | JP5290486B2 (en) |
CN (1) | CN1192822C (en) |
AT (1) | ATE342128T1 (en) |
AU (1) | AU2001250020A1 (en) |
DE (1) | DE60123845T2 (en) |
WO (1) | WO2001066247A2 (en) |
Families Citing this family (50)
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FR2819430B1 (en) * | 2001-01-15 | 2003-02-28 | Inst Francais Du Petrole | CATALYST COMPRISING SILICA-ALUMINA AND ITS USE IN HYDROCRACKING OF HYDROCARBON CHARGES |
US20020157535A1 (en) * | 2001-02-28 | 2002-10-31 | Kanazirev Vladislav I. | Process and adsorbent for gas drying |
SE524126C2 (en) | 2001-07-24 | 2004-06-29 | Akzo Nobel Nv | Process for the preparation of diethylenetriamine and higher polyethylene polyamines by transamination of ethylenediamine |
US7196033B2 (en) * | 2001-12-14 | 2007-03-27 | Huntsman Petrochemical Corporation | Advances in amination catalysis |
AU2003301248A1 (en) * | 2002-10-16 | 2004-05-04 | Conocophillips Company | High hydrothermal stability catalyst support |
TWI346574B (en) * | 2003-03-31 | 2011-08-11 | Shell Int Research | A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition |
US20050032640A1 (en) * | 2003-08-07 | 2005-02-10 | He Huang | Method and structure for desulfurizing gasoline or diesel fuel for use in a fuel cell power plant |
US7897538B2 (en) * | 2004-05-21 | 2011-03-01 | Exxonmobil Research And Engineering Company | Process for removing sulfur compounds from hydrocarbon streams and adsorbent used in this process |
WO2006119311A2 (en) * | 2005-05-02 | 2006-11-09 | Symyx Technologies, Inc. | High surface area metal and metal oxide materials and methods of making same |
BRPI0811305B1 (en) | 2007-05-09 | 2020-02-27 | Shell Internationale Research Maatschappij B.V. | EPOXIDATION CATALYST, A PROCESS FOR THE PREPARATION OF THE CATALYST AND A PROCESS FOR THE PRODUCTION OF AN OLEPHINE OXIDE, A 1,2-DIOL, A 1,2-DIOL ETHER, A 1,2-CARBONATE OR AN ALKANOLAMINE |
US8119558B2 (en) * | 2008-03-14 | 2012-02-21 | Süd-Chemie Inc. | Ultra high temperature shift catalyst with low methanation |
CN102066348B (en) * | 2008-05-07 | 2013-09-25 | 国际壳牌研究有限公司 | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
KR20110030472A (en) * | 2008-05-22 | 2011-03-23 | 다우 글로벌 테크놀로지스 엘엘씨 | Metallic platinum on silica support catalyst and process for preparing it |
EP2352585B1 (en) * | 2008-10-06 | 2020-06-17 | Union Carbide Corporation | Low metal loaded, alumina supported, catalyst compositions and amination process |
EP2344445B1 (en) | 2008-10-06 | 2017-05-10 | Union Carbide Chemicals & Plastics Technology LLC | A process to selectively manufacture diethylenetriamine (deta) or other desirable ethylenamines via continuous transamination of ethylenediamine (eda), and other ethyleneamines over a heterogeneous catalyst system |
WO2010042168A2 (en) | 2008-10-06 | 2010-04-15 | Dow Global Technologies Inc. | Methods for making ethanolamine(s) and ethyleneamine(s) from ethylene oxide and ammonia, and related methods |
JP2012504610A (en) * | 2008-10-06 | 2012-02-23 | ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー | Method for producing ethyleneamine |
BRPI0914009A2 (en) * | 2008-10-06 | 2015-07-28 | Union Carbide Chem Plastic | Method to repair a cyclic triamine |
CN102227258B (en) * | 2008-10-06 | 2014-02-19 | 联合碳化化学品及塑料技术公司 | Low metal (nickel and rhenium) catalyst compositions including acidic mixed metal oxide as carrier |
JP5806116B2 (en) * | 2008-10-06 | 2015-11-10 | ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー | Transalkoxylation of nucleophilic compounds |
US20100292076A1 (en) * | 2009-05-18 | 2010-11-18 | Sud-Chemie Inc. | Ultra high temperature shift catalyst with low methanation |
CN101875014B (en) * | 2009-11-17 | 2012-10-03 | 中国科学院大连化学物理研究所 | Catalyst for use in conversion of monoethanolamine and ammonia into ethylenediamine in hydrogen atmosphere |
CN102639231B (en) * | 2009-12-03 | 2014-12-10 | 巴斯夫欧洲公司 | Catalyst and method for producing an amine |
CN102781571B (en) | 2009-12-03 | 2015-06-17 | 巴斯夫欧洲公司 | Catalyst and method for producing an amine |
US8772548B2 (en) | 2009-12-17 | 2014-07-08 | Basf Se | Reaction of glycolaldehyde with an aminating agent |
CN103261174B (en) | 2010-11-10 | 2016-04-20 | 陶氏环球技术有限责任公司 | Nitrogenous compound turns amino and manufactures ring-type and ring-type/acyclic polyamine mixture |
BR112013011669A2 (en) | 2010-11-10 | 2019-09-24 | Dow Global Technologies Llc | method for making a mixture of products containing linear high molecular weight polyamine, method for making a mixture of high molecular weight polyamine congeners and method for making a mixture of high molecular weight acyclic polyamines |
BR112014015064A2 (en) * | 2011-12-22 | 2017-06-13 | Dow Global Technologies Llc | method for preparing composition containing piperazine and aminoethylethanolamine |
WO2013102097A2 (en) | 2011-12-29 | 2013-07-04 | Dow Global Technologies Llc | Cyclic amine compounds, compositions, and polyurethane foams made therefrom |
US9162995B2 (en) | 2011-12-29 | 2015-10-20 | Dow Global Technologies Llc | Formation of higher molecular weight cyclic polyamine compounds from cyclic polyamine compounds |
WO2013102053A1 (en) | 2011-12-29 | 2013-07-04 | Dow Global Technologies Llc | Amine polyether polyols and polyurethane foam compositions made from cyclic amine compounds |
US10399064B2 (en) * | 2012-03-27 | 2019-09-03 | Dow Global Technologies Llc | Rhenium recovery from used reductive amination catalysts |
WO2014150384A1 (en) | 2013-03-15 | 2014-09-25 | Segetis, Inc. | Method of manufacture of octanedioic acid, precursors, and derivatives |
EP3077444B1 (en) | 2013-12-02 | 2018-04-25 | Dow Global Technologies LLC | Preparation of high molecular weight, branched, acyclic polyalkyleneamines and mixtures thereof |
CN103819344B (en) * | 2013-12-18 | 2016-04-27 | 西安近代化学研究所 | A kind of synthetic method of 1,2-propylene diamine |
US20180148535A1 (en) | 2015-06-19 | 2018-05-31 | Dow Global Technologies Llc | Autocatalytic polyol useful for polyurethane foam manufacture |
JP7094894B2 (en) | 2016-06-03 | 2022-07-04 | アイオワ・コーン・プロモーション・ボード | A continuous process for the highly selective conversion of carbohydrates producing aldohexose to ethylene glycol |
US10472310B2 (en) | 2016-06-03 | 2019-11-12 | Iowa Corn Promotion Board | Continuous processes for the highly selective conversion of sugars to propylene glycol or mixtures of propylene glycol and ethylene glycol |
CN109476807B (en) | 2016-06-13 | 2021-08-10 | 陶氏环球技术有限责任公司 | Autocatalytic polyols |
CN106242978B (en) * | 2016-07-28 | 2018-08-31 | 南京工业大学 | Method for preparing antioxidant 6PPD by using micro-reaction device |
CN110072838B (en) | 2016-12-15 | 2022-04-15 | 阿克苏诺贝尔化学品国际有限公司 | Process for preparing ethyleneamines |
US10995058B2 (en) | 2016-12-15 | 2021-05-04 | Nouryon Chemicals International B.V. | Process for manufacturing hydroxyethyl ethylene amines |
GB201904612D0 (en) | 2019-04-02 | 2019-05-15 | Univ Leuven Kath | Reaction of glycoladehyde |
CN111196763B (en) * | 2018-11-16 | 2021-06-01 | 中国科学院大连化学物理研究所 | Catalyst for producing 3-aminopropanol by hydrogenating 3-hydroxypropionitrile and preparation method thereof |
EP3908641A4 (en) | 2019-01-11 | 2022-04-20 | Archer Daniels Midland Company | Processes and catalysts for the selective hydrogenation of compounds having carbonyl carbon atoms |
CN110052276A (en) * | 2019-04-01 | 2019-07-26 | 天津大学 | It prepares bimetallic catalyst and is applied to the method that conversion lignin prepares aromatic compounds or liquid alkane fuel |
CN113993837A (en) * | 2019-06-11 | 2022-01-28 | 巴斯夫欧洲公司 | Gas phase process for conversion of glycolaldehyde with aminating agent |
WO2020249428A1 (en) | 2019-06-11 | 2020-12-17 | Basf Se | Products obtained by the conversion of glycolaldehyde derivatives and aminating agents and their conversion to ethyleneamines and ethanolamines |
WO2020249426A1 (en) | 2019-06-11 | 2020-12-17 | Basf Se | Conversion of glycolaldehyde with an aminating agent |
CN113713853B (en) * | 2021-09-16 | 2024-03-22 | 中触媒新材料股份有限公司 | Method for preparing aliphatic diamine from cyclic imine and catalyst used in method |
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US3492314A (en) | 1965-08-23 | 1970-01-27 | Mitsubishi Petrochemical Co | Process for catalytic hydrogenation of dicarboxylic acid anhydride and catalyst therefor |
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US4123462A (en) | 1976-01-07 | 1978-10-31 | Union Carbide Corporation | Amination process using nickel-rhenium catalysts |
US4255357A (en) | 1980-03-24 | 1981-03-10 | Pennwalt Corporation | Catalytic process for preparing ethyl amines |
SE461095B (en) | 1983-09-09 | 1990-01-08 | Berol Kemi Ab | AMINING PROCEDURE USING A RUTENIUM DOPPED NICKEL AND / OR COVOLT CATALYST |
US4863890A (en) | 1983-09-09 | 1989-09-05 | Berol Kemi Ab | Process for preparing a ruthenium-promoted, halogen-containing nickel and/or cobalt catalyst and a catalyst prepared by the process |
US4665195A (en) | 1983-12-23 | 1987-05-12 | Exxon Research And Engineering Company | Process for preparing di-amino-polyalkenyl ethers |
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US4708945A (en) * | 1985-12-31 | 1987-11-24 | Exxon Research And Engineering Company | Catalysts comprising silica supported on a boehmite-like surface, their preparation and use |
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US5600000A (en) | 1993-12-22 | 1997-02-04 | Union Carbide Chemicals & Plastics Technology Corporation | Reductive amination processes for the selective production of amino-ethylethanolamine |
DE4429547A1 (en) | 1994-08-19 | 1996-02-22 | Basf Ag | Process for the production of amines |
US5817593A (en) | 1995-06-02 | 1998-10-06 | The Dow Chemical Company | Catalyst and process for producing amines |
JPH11514401A (en) * | 1995-10-04 | 1999-12-07 | ザ ダウ ケミカル カンパニー | Amine-terminated polyether and method for producing the same |
US6117814A (en) * | 1998-02-10 | 2000-09-12 | Exxon Research And Engineering Co. | Titania catalysts their preparation and use in fischer-tropsch synthesis |
-
2000
- 2000-03-03 US US09/519,724 patent/US6534441B1/en not_active Expired - Lifetime
-
2001
- 2001-03-02 CN CNB018078249A patent/CN1192822C/en not_active Expired - Lifetime
- 2001-03-02 WO PCT/US2001/040221 patent/WO2001066247A2/en active IP Right Grant
- 2001-03-02 EP EP01923315A patent/EP1385625B1/en not_active Expired - Lifetime
- 2001-03-02 AT AT01923315T patent/ATE342128T1/en active
- 2001-03-02 JP JP2001564891A patent/JP5290486B2/en not_active Expired - Lifetime
- 2001-03-02 AU AU2001250020A patent/AU2001250020A1/en not_active Abandoned
- 2001-03-02 DE DE60123845T patent/DE60123845T2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US6534441B1 (en) | 2003-03-18 |
WO2001066247A3 (en) | 2002-04-11 |
WO2001066247A2 (en) | 2001-09-13 |
JP2003525738A (en) | 2003-09-02 |
DE60123845D1 (en) | 2006-11-23 |
DE60123845T2 (en) | 2007-05-16 |
CN1192822C (en) | 2005-03-16 |
ATE342128T1 (en) | 2006-11-15 |
WO2001066247A8 (en) | 2003-04-10 |
EP1385625B1 (en) | 2006-10-11 |
JP5290486B2 (en) | 2013-09-18 |
EP1385625A2 (en) | 2004-02-04 |
CN1441698A (en) | 2003-09-10 |
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