AU1852900A - (in situ) manufacture of membrane microfilters - Google Patents
(in situ) manufacture of membrane microfilters Download PDFInfo
- Publication number
- AU1852900A AU1852900A AU18529/00A AU1852900A AU1852900A AU 1852900 A AU1852900 A AU 1852900A AU 18529/00 A AU18529/00 A AU 18529/00A AU 1852900 A AU1852900 A AU 1852900A AU 1852900 A AU1852900 A AU 1852900A
- Authority
- AU
- Australia
- Prior art keywords
- membrane
- microfilter
- embossing
- web portion
- tool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000012528 membrane Substances 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 238000011065 in-situ storage Methods 0.000 title description 4
- 238000000034 method Methods 0.000 claims description 49
- 239000011148 porous material Substances 0.000 claims description 31
- 238000004049 embossing Methods 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 24
- 238000007373 indentation Methods 0.000 claims description 9
- 238000003486 chemical etching Methods 0.000 claims description 2
- 238000000608 laser ablation Methods 0.000 claims description 2
- 238000005530 etching Methods 0.000 description 11
- 238000002679 ablation Methods 0.000 description 5
- 230000007547 defect Effects 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000003754 machining Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000004992 fission Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000001668 ameliorated effect Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 238000001393 microlithography Methods 0.000 description 1
- 238000005459 micromachining Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 238000003631 wet chemical etching Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/022—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/0025—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0053—Inorganic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/0055—Inorganic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B26—HAND CUTTING TOOLS; CUTTING; SEVERING
- B26F—PERFORATING; PUNCHING; CUTTING-OUT; STAMPING-OUT; SEVERING BY MEANS OTHER THAN CUTTING
- B26F1/00—Perforating; Punching; Cutting-out; Stamping-out; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/24—Use of template or surface directing agents [SDA]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/34—Use of radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/021—Pore shapes
- B01D2325/0214—Tapered pores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/0283—Pore size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/14—Filters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/755—Membranes, diaphragms
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Forests & Forestry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Filtering Materials (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Description
WO 00/38823 PCT/CA99/01242 IN SITU MANUFACTURE OF MEMBRANE MICROFILTERS This invention relates to the manufacture of membrane microfilters. 5 Membrane microfilters, as opposed to depth filters, function as simple sieves. If a fluid suspension is passed through a membrane microfilter, all objects within that suspension under a certain size (the pore size) are permitted to pass. Everything else is held back and captured on the membrane microfilter's surface. The quality and performance of membrane microfilters are 10 characterized by the pore size distribution, the number of pores in a given area (porosity), and the degree of overlap between pores (doublets and triplets, etc.). The dominant technology for the production of membrane microfilters (that is, with pore sizes in the micron range) is the track-etch technique. In this technique, a thin polymeric film is exposed to a collimated beam of massive, 15 energetic nuclei such as U 235 fission fragments. As the nuclei pass through the film, they break the polymer's backbone bonds, leaving a directed trail of defects. In a second and final step, the film is placed in a warm caustic bath where the defect trails are preferentially etched against the bulk of the material. The result is a set of microscopic pores whose average size can be controlled by 20 the etch parameters (temperature, concentration, time) and whose surface density is controlled by the length of time the film is left in the particle beam. There are several problems associated with the manufacture, quality, and application of conventional track-etched membrane microfilters. The use of the track-etch technique places numerous restrictions on the 25 materials used, their thickness and composition. They cannot be too thick or the fission fragments will not leave a complete defect trail. Nor can they be conductive or the charge build-up will distort the otherwise collimated beam. The technique is rather difficult to apply in practice, requiring as it does a particle beam source, which may represent a considerable investment. The 1 SUBSTITUTE SHEET (RULE 26) WO 00/38823 PCT/CA99/01242 track-etching takes place under restrictive conditions that make it impractical to process anything other than continuous rolls of polymeric film material. The second stage etching process is difficult (though not impossible) to control and any piece produced in this way must be further processed to remove traces of 5 the harsh chemical used to manufacture the part. The point of collision between the individual particles and the polymeric film cannot, in general, be controlled. As a consequence, the distribution of the defect trails over the surface of the polymer film is random. One consequence is that the arrangement of pores is also random. Another is that there is a high 10 probability of pore overlap if the defect trails are too close together. This can compromise the cut-off point of the membrane microfilter and is only ameliorated by reducing overall porosity (which itself becomes a limitation). If the polymer material used is particularly thick or the etching process is not carefully controlled, the pores produced can take on a tapered character so that they are 15 not square to the membrane surface. In addition, if the particle beam is not well collimated, the angle of entry of the particles can vary widely with serious consequences for the quality of the microfilter formed. With all of these compromises and limitations, it is not surprising that track-etch membrane microfilters often fail to follow their theoretical models of performance. 20 The restrictions inherent in the manufacturing of track-etch membrane microfilters will often translate into application problems for the designer or engineer. For example, the track-etch membrane is manufactured in a separate process and must eventually be mated to some support structure in order to be used. Affixing the track-etch membrane to this support will necessitate the use 25 of glues or thermo-welding process. Placing the membrane on the support structure is not trivial, nor is maintaining a taut, uniformly-stressed surface. Finally, the microfilter's composition may be incompatible with the intended use of the completed part. A solution to these problems is found in a three-step manufacturing 2 WO 00/38823 PCT/CA99/01242 process involving the creation of a moulded part, the embossing of that part, and the etching of the embossed region for a controlled breakthrough to create an in situ membrane microfilter on the part. According to the invention, there is provided a method for manufacturing 5 a membrane microfilter, comprising forming a blank having a web portion defining a filter region, embossing one side of the web portion in the filter region with an array of indentations of cross-sections comparable to a desired pore size of the filter, and ablating material from the web portion in the filter region until the indentation forms through pores of the desired pore size. 10 SHORT DESCRIPTION OF THE DRAWINGS Figures 1 a, l b, and I c show stages in the production of a blank for application of the method of the invention; all views in this and subsequent figures are cross-sectioned unless otherwise stated; 15 Figures 2a, 2b and 2c show successive stages in the embossing of the moulded blank; Figure 3 shows an embossing tool; Figure 4 shows deformation occurring when an embossing tool breaks through the blank; 20 Figures 5a and 5b show the result of misalignment of a two-part embossing tool; Figure 6 shows damage to the embossing tool caused by it contacting a hard surface; Figures 7a and 7b illustrate a method of operating the embossing tool; 25 Figures 8a and 8b show etching of the blank from the side opposite the tool; Figures 9a and 9b show how pore characteristics can be controlled during the etching; Figures 10Oa, 10Ob and 10Oc illustrate how different pore size may be formed 3 C1urfl T W f T -'I \ WO 00/38823 PCT/CA99/01242 in the same blank, Figure 10Oc being a plan view. Figure 1 illustrates the formation of a blank to be subsequently provided with an integral microfilter. 5 The precise technique used to create the moulded blank is not important to the invention. The blank may be pressure moulded from a starting blank c between two mould parts (as in Figure 1A), together defining a mould cavity d (see Figure 1 B), or may be injection moulded, cast, or manufactured by any other applicable technique. What is important is that the blank has a defined 10 filter region e in which the process membrane microfilter is required. It is usually advisable that this region be relatively thin compared to the rest of the blank, but it should be understood that the final thickness of the filter is determined by subsequent steps of the process. In practice, a thickness much less than 100 microns may be difficult to produce. 15 In the next step, the filter region c, where the membrane microfilter is required, is embossed (see figure 2), using an embossing tool E having an array of projections g so as to produce an array of indentations in one side of the filter region. The embossing technique is not critical. The embossing may be performed immediately after the blank is moulded while the material is still 20 relatively soft. Alternatively, the embossing may take place as the part is moulded or may be a completely separate step. In any case, the region that requires the microfilter is embossed using a tool having an array of asperities g that can create an array of micro-indentations h in the molded part. The indentations may typically have a diameter up to 10 microns and a separation of 25 at least 10 microns. Embossing tools f whose details include extremely high asperities (see Figure 3) can be easily manufactured by techniques such as microlithography. The drawback to this, or indeed any other embossing tool with such an array of micro-formed features is that the tool must be brought to bear against a hard surface n if the intention is to complete the microfilter formation in 4 *, ",V, 1TTV WO 00/38823 PCT/CA99/01242 this step. If the embossing tool simply breaks through the part to form the microfilter pores, the microfilter itself will be of poor quality, with a deformed surface as seen at k in Figure 4B, with a consequently wide distribution of pore sizes. If the embossing tool is designed to break through into a set of aligned 5 wells m, there is a problem in obtaining precise alignment of the asperities with the wells to avoid tool damage (see Figures 5a and 5b). In either case, the tool will rapidly wear out if it is brought to bear against a hard surface during embossing - its delicate microstructure will be destroyed (see figure 6). Instead, the embossing tool is only used to create an array of precisely formed 10 indentations in the microfilter region e of the blank (see Figure 7). It does not "break through" and so is not brought to bear against any other hard surface, greatly increasing tool life and preserving its microstructure. In the final step in this procedure, the moulded, embossed part e is subjected to an in situ ablation procedure in the region of the embossing (see 15 Figure 8). The ablation procedure may be any one of a range currently available, such as laser ablation, chemical etching, mechanical abrasion, or any other technique that may remove material from a surface in a specified region in a controlled manner. Material may be removed from the side of the region opposite the embossing, or from both sides. 20 As the material is removed from the embossed region, the embossed indentations will reach the opposite surface of the region, forming through pores p. in the microfilter region of the blank so that it forms a membrane microfilter. An additional advantage of this technique is that the pore size may be controlled through the etching without comprising porosity or incurring overlap problems. 25 For example, if the embossing tool has a microstructure consisting of an array of high-asperity cones then the embossed region will consist of an array of deep, conical wells. By removing a specified amount of material during the etching process, a pre-determined cone cross-section is revealed. If the etching is increased, the exposed cross-section is increased and the effective pore size s 5 WO 00/38823 PCT/CA99/01242 rises uniformly (see Figure 9). There is no inherent restriction on the material used in this three-step procedure. So long as the material can be molded, embossed, and etched in a controlled fashion, any substance may be used. A presently preferred material 5 is polypropylene, although polystyrene is also advantageous. Furthermore, since the microfilter can be "post-processed" into the filter region of the moulded, embossed part, it is possible to stock-pile an enormous number of blanks for "just-in-time" microfilter manufacture that would correspond to a consumer's requirements. In de-coupling the microfilter blank manufacture from actual 10 microfilter production, both may be separately optimized. This technique then allows the two to be varied independently without compromising the flexibility in pore dimensions often required by a range of customers. The filter region of the blank can be moulded with a minimum thickness of about 100 microns, this being limited by the technique used to form the region, 15 while the area of this region may be as large as required but is typically of the order of one square centimetre or less. Any of a number of techniques may be used to produce the surface structure of the embossing tool. The fine structure of that embossing surface depends, to some extent, on the technique used to create it. 20 A presently preferred method for the manufacture of the embossing tool is the LIGA process (X-ray Lithographic, Galvanoformung, Abformtechnik (reference: E.W. Becker et al, Microelectronic Engineering 4, 35-56, 1986). In the LIGA process, a fine structure can be produced using an X-ray source in a photoresist material. Subsequent development of this resist creates a relief 25 reproduction of the fine structure, although the resist itself is too fragile to be used directly. Electro-deposition fills the resist's surface with metal and when the resist is removed, the metal part is ready for use. A typical embossing tool might have protuberances 10 microns in diameter, spaced by 20 microns. The protuberances themselves may be 6 WO 00/38823 PCT/CA99/01242 tapered, as in Figures 7a and 7b, or cylindrical as in Figure 5A. The depth of penetration of the hot embossing tool into the filter region depends on the thickness of the latter but is typically in the range of 10 to 100 microns. 5 A wide range of ablation techniques may be used, of which the following are only exemplary of subtractive micro-machining techniques that may be compatible with the invention having regard to the materials employed. a. Wet chemical etching; in which a fluid etchant is introduced which 10 dissolves away the plastic material. This is controlled by time of exposure and temperature. The exposure to the wet chemical is an isotropic process that will etch in all directions and so open out the pores (perhaps creating "craters"). So long as the process is predictable, this feature can be accommodated. 15 b. Cold photo-ablation; in which material is removed by the action of an ultraviolet laser capable of delivering direct bond-breaking energy to the work surface. This is highly directional and does not suffer from the isotropic action mentioned above. 20 c. Hot photo-ablation; in which material is removed by the action of a laser system (or other light source) that heats, melts and vapourizes the work material to remove it. Again, the action is directional, but the heat-damage effects can make this more difficult to control (a problem that does not appear in the cold worked process above). 25 d. Laser machining with reactive gases; in which the laser is combined with a locally-present reactive gas such as chlorine (in the case of a silicon work material) that combines with the ablated material and carries it away. The result is a better definition of the surface features. 7 DTTI'IC rIT'TI ETTP "VrTITqr /TT' IT 1 WO 00/38823 PCT/CA99/01242 e. Focused ion beam milling; in which a mechanical drill bit is replaced by a focused column of energetic ions that are capable of cutting the material. f. Ultrasonic etching in which an ultrasonic tool is set in motion and is 5 coupled to the workpiece by an abrasive slurry. The mechanical motion of the ultrasonic tool drives the abrasive slurry to eat away at the workpiece. g. Water jet machining; in which a high-velocity stream of water (with or without an abrasive) is used to cut the material in question. 10 h. Ultra-high precision mechanical machining; in which computer numerical controlled (CNC) milling machines capable of 0.05 micron steps are used to remove work material using single crystal diamond tools. 15 The quality of the finished filter of the invention should normally be greatly superior to its track-etched counterpart. Pore size can now be controlled to within a narrow tolerance and its statistical distribution is many times narrower than a comparable track-etched membrane. The use of an embossing tool to create the pore distribution over the microfilter's surface means that pore 20 distributing can be precisely controlled. Thus, the porosity can be specified to within narrow tolerances depending on the requirements of the application. There is no danger of pore overlap and thus nothing to compromise the integrity of the filter cut-off. In addition, the embossing tool may be produced with any desired array of 25 cones, which need not all be of the same size (see Figure 10). After the post processing etching, these can yield a variety in the size of pores within the filter in any desired arrangement. A great advantage of the process of the invention is that the membrane microfilter can be included in a moulded part without the drawbacks encountered 8 WO 00/38823 PCT/CA99/01242 in mechanical mounting methods. This reduces part cost, reduces manufacture time, and eliminates the problem of contamination during the mounting procedure. 5 9
Claims (8)
1. A method for manufacturing a membrane microfilter, comprising forming a blank having a web portion defining a filter region, embossing one side of the 5 web portion in the filter region with an array of indentations of cross-sections comparable to a desired pore size of the filter, and ablating material from the web portion in the filter region until the indentation forms through pores of the desired pore size. 10
2. A method according to claim 1 wherein the web is embossed by a tool carrying an array of asperities of cross-section comparable to a desired pore size of the filter.
3. A method according to claim 2, wherein the asperities are tapered. 15
4. A method according to claim 2, wherein the asperities are cylindrical.
5. A method according to claim 2, 3 or 4, wherein the tool has asperities of more than one cross-section, such as to provide pores of more than one size. 20
6. A method according to any one of claims 1-5, wherein the web portion is ablated from its side opposite the side that is embossed.
7. A method according to any one of claims 1-6, wherein the web portion is 25 ablated by chemical etching.
8. A method according to any one of claims 1-6, wherein the web portion is ablated by laser ablation. 10 '"WT TV Vi~
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11381498P | 1998-12-23 | 1998-12-23 | |
US60113814 | 1998-12-23 | ||
PCT/CA1999/001242 WO2000038823A1 (en) | 1998-12-23 | 1999-12-23 | In situ manufacture of membrane microfilters |
Publications (1)
Publication Number | Publication Date |
---|---|
AU1852900A true AU1852900A (en) | 2000-07-31 |
Family
ID=22351670
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU18529/00A Abandoned AU1852900A (en) | 1998-12-23 | 1999-12-23 | (in situ) manufacture of membrane microfilters |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1140332A1 (en) |
JP (1) | JP2002533236A (en) |
AU (1) | AU1852900A (en) |
CA (1) | CA2356684A1 (en) |
WO (1) | WO2000038823A1 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040126538A1 (en) * | 2002-01-18 | 2004-07-01 | Corcoran Craig S. | Sheet having microsized architecture |
WO2003062133A2 (en) | 2002-01-18 | 2003-07-31 | Avery Dennison Corporation | Covered microchamber structures |
DE10239551A1 (en) * | 2002-08-23 | 2004-03-04 | Daimlerchrysler Ag | Filter body for soot filter |
US7597815B2 (en) * | 2003-05-29 | 2009-10-06 | Dressel Pte. Ltd. | Process for producing a porous track membrane |
ES2625345T3 (en) * | 2003-12-19 | 2017-07-19 | The University Of North Carolina At Chapel Hill | Methods for manufacturing microstructures and nanostructures using soft lithography or printing |
WO2006057619A1 (en) * | 2004-11-26 | 2006-06-01 | Agency For Science, Technology And Research | Method and apparatus for forming microstructures |
AP2007004070A0 (en) * | 2004-12-22 | 2007-08-31 | Dressel Pte Ltd | Membrane card and method for the production and use thereof |
NL1028759C2 (en) * | 2005-04-13 | 2006-10-16 | Fluxxion B V | Emulsification with microsieve. |
TWI506070B (en) * | 2009-12-14 | 2015-11-01 | 3M Innovative Properties Co | Microperforated polymeric film and methods of making and using the same |
US9266066B2 (en) * | 2011-12-13 | 2016-02-23 | Pall Corporation | Membrane with localized asymmetries |
EP3169424B1 (en) | 2014-07-18 | 2020-10-28 | Sartorius Stedim Biotech GmbH | Membrane with performance enhancing multi-level macroscopic cavities |
EP3838385A1 (en) | 2019-12-17 | 2021-06-23 | 3M Innovative Properties Company | Ultrasonically surface modified polyethersulfone membranes and method of making thereof |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3929135A (en) * | 1974-12-20 | 1975-12-30 | Procter & Gamble | Absorptive structure having tapered capillaries |
US4652412A (en) * | 1985-06-14 | 1987-03-24 | Polaroid Corporation | Method for forming microporous filter |
FR2623100B1 (en) * | 1987-11-13 | 1991-04-05 | Commissariat Energie Atomique | MICROPOROUS MEMBRANE OBTAINED BY TWO-SIDED IRRADIATION AND METHOD FOR OBTAINING SAME |
US4964992A (en) * | 1989-03-21 | 1990-10-23 | Goldsmith Susan H | Method of making membrane-type filter and product thereof |
JP2542790B2 (en) * | 1993-10-15 | 1996-10-09 | 清二 加川 | Porous film manufacturing equipment |
-
1999
- 1999-12-23 EP EP99962020A patent/EP1140332A1/en not_active Withdrawn
- 1999-12-23 JP JP2000590767A patent/JP2002533236A/en active Pending
- 1999-12-23 WO PCT/CA1999/001242 patent/WO2000038823A1/en not_active Application Discontinuation
- 1999-12-23 CA CA002356684A patent/CA2356684A1/en not_active Abandoned
- 1999-12-23 AU AU18529/00A patent/AU1852900A/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
WO2000038823A1 (en) | 2000-07-06 |
EP1140332A1 (en) | 2001-10-10 |
JP2002533236A (en) | 2002-10-08 |
CA2356684A1 (en) | 2000-07-06 |
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