ATE754T1 - PROCESS FOR THE PREPARATION OF SUBSTANTIALLY MONOMERIC METHYLVERAETHERTED METHYLOLMELAMINE. - Google Patents

PROCESS FOR THE PREPARATION OF SUBSTANTIALLY MONOMERIC METHYLVERAETHERTED METHYLOLMELAMINE.

Info

Publication number
ATE754T1
ATE754T1 AT79102771T AT79102771T ATE754T1 AT E754 T1 ATE754 T1 AT E754T1 AT 79102771 T AT79102771 T AT 79102771T AT 79102771 T AT79102771 T AT 79102771T AT E754 T1 ATE754 T1 AT E754T1
Authority
AT
Austria
Prior art keywords
formaldehyde
melamine
methylolmelamine
mols
methylveraetherted
Prior art date
Application number
AT79102771T
Other languages
German (de)
Inventor
Hans Dr. Hoenel
Karlfried Dr. Keller
Walter Dr. Michel
Manfred Dr. Schoen
Original Assignee
Cassella Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6049278&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE754(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Cassella Aktiengesellschaft filed Critical Cassella Aktiengesellschaft
Application granted granted Critical
Publication of ATE754T1 publication Critical patent/ATE754T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/64—Condensation products of melamine with aldehydes; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C08G12/42—Chemically modified polycondensates by etherifying
    • C08G12/424—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds
    • C08G12/425—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds based on triazines
    • C08G12/427—Melamine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

This invention relates to a process for the manufacture of methanol-etherified methylolmelamines which are largely monomeric containing more than 5 mols of formaldehyde and more than 4 mols of methyl-etherified methylol groups, per mol of melamine, and having a viscosity of less than 20 pascal-seconds at 25 DEG C. and a solids content of at least 95%, comprising (a) methylolating melamine with formaldehyde at a molar melamine:formaldehyde ratio of 1:6.5 to 1:8 for 11/2 to 5 hours at 50 DEG C. to 85 DEG C., with the formaldehyde source being an aqueous solution of formalin containing 30 to 50% by weight of formaldehyde and having a pH of 6.7 to 7.3, and (b) etherifying the resulting suspension of methylolmelamine with 15 to 30 mols of methanol per mol of melamine at temperatures of 30 DEG C. to 60 DEG C. in the presence of a strong acid.
AT79102771T 1978-09-13 1979-08-02 PROCESS FOR THE PREPARATION OF SUBSTANTIALLY MONOMERIC METHYLVERAETHERTED METHYLOLMELAMINE. ATE754T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19782839713 DE2839713A1 (en) 1978-09-13 1978-09-13 METHOD FOR PRODUCING LARGE MONOMER METHYL-ETHERED METHYLOLMELAMINS
EP79102771A EP0008683B1 (en) 1978-09-13 1979-08-02 Process for the preparation of mainly monomeric methylated methylol melamines

Publications (1)

Publication Number Publication Date
ATE754T1 true ATE754T1 (en) 1982-04-15

Family

ID=6049278

Family Applications (1)

Application Number Title Priority Date Filing Date
AT79102771T ATE754T1 (en) 1978-09-13 1979-08-02 PROCESS FOR THE PREPARATION OF SUBSTANTIALLY MONOMERIC METHYLVERAETHERTED METHYLOLMELAMINE.

Country Status (5)

Country Link
US (1) US4223141A (en)
EP (1) EP0008683B1 (en)
AT (1) ATE754T1 (en)
DE (2) DE2839713A1 (en)
ES (1) ES484113A1 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3112808A1 (en) * 1981-03-31 1982-10-14 Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München METHOD FOR PRODUCING MIXTURES OF PARTIAL-ETHERED METHYLOLMELAMINE
IT1138115B (en) * 1981-07-28 1986-09-17 Pomponesco Chim PROCESS FOR THE PRODUCTION OF ESACIS (METOXYMETHYL) MELAMINE
AT378369B (en) * 1983-08-26 1985-07-25 Krems Chemie Gmbh METHOD FOR PRODUCING METHYLOLATED MELAMINES
US5017699A (en) * 1990-07-19 1991-05-21 Suen Tzeng J Process for preparing polyalkoxymethylmelamines
DE19709696A1 (en) * 1997-03-10 1998-09-17 Basf Ag Aqueous wood-based material binders
DE19835114A1 (en) 1998-08-04 2000-02-10 Basf Ag Microcapsules made from low-formaldehyde melamine-formaldehyde resins
DE102005058855A1 (en) * 2005-12-09 2007-06-14 Basf Ag Etherified melamine-formaldehyde condensates with high solids content and low viscosity
CN108623994A (en) * 2018-05-23 2018-10-09 重庆建峰浩康化工有限公司 The fire-retardant melamine resin of butyl etherization is produced with trimethylol melamine
CN108623766A (en) * 2018-05-23 2018-10-09 重庆建峰浩康化工有限公司 The fire-retardant melamine resin of high imino group methyl-etherified and its production method
CN108727548B (en) * 2018-05-23 2021-03-23 重庆建峰浩康化工有限公司 Environment-friendly flame-retardant water-soluble high-imino melamine resin and production method thereof
WO2020041921A1 (en) * 2018-08-27 2020-03-05 江苏国立化工科技有限公司 Process for preparing hexamethoxymethyl melamine resin rubber adhesive
CN109293863A (en) * 2018-09-07 2019-02-01 沈阳化工大学 A kind of one kettle way prepares melamine resin method
CN111808250B (en) * 2020-06-30 2023-06-16 杭州传化精细化工有限公司 Preparation method of low-formaldehyde stiffening agent
CN112011021A (en) * 2020-09-28 2020-12-01 山东阳谷华泰化工股份有限公司 Preparation method of methylated melamine formaldehyde resin
CN113956415A (en) * 2021-11-09 2022-01-21 山东阳谷华泰化工股份有限公司 Preparation method of aqueous imino methylated melamine formaldehyde resin

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB611013A (en) * 1942-02-05 1948-10-25 Chem Ind Basel Manufacture of highly etherified aminotriazine-formaldehyde condensation products
US2645625A (en) * 1951-10-31 1953-07-14 Monsanto Chemicals Methods of concentrating solutions
FR1086826A (en) * 1952-06-28 1955-02-16 Cassella Farbwerke Mainkur Ag Methylol compounds of aminotriazines etherified with methanol, insoluble in water or miscible with little water only, and their preparation
US2998410A (en) * 1956-07-09 1961-08-29 American Cyanamid Co Process for the manufacture of methylol melamines and alkylated methylol melamines
CH432839A (en) * 1962-03-01 1967-03-31 Sueddeutsche Kalkstickstoff Process for the preparation of water-miscible methylol melamine alkyl ether resins
DE2005166C3 (en) * 1970-02-05 1975-05-15 Chemische Fabrik Pfersee Gmbh, 8900 Augsburg Process for the production of water-soluble, etherified methylolmelamines
DE2716006A1 (en) * 1977-04-09 1978-10-19 Cassella Farbwerke Mainkur Ag PROCESS FOR THE PRODUCTION OF MAJORLY MONOMERIC METHYLVER ETHERED METHYLOL MELAMINE

Also Published As

Publication number Publication date
EP0008683A1 (en) 1980-03-19
DE2962287D1 (en) 1982-04-15
EP0008683B1 (en) 1982-03-17
ES484113A1 (en) 1980-05-16
DE2839713A1 (en) 1980-03-27
US4223141A (en) 1980-09-16

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Legal Events

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REN Ceased due to non-payment of the annual fee