ATE700T1 - METALLIC DITHIOPHOSPHATES, PROCESS FOR THEIR PRODUCTION AND THEIR USE AS ADDITIVES FOR LUBRICATION OILS. - Google Patents
METALLIC DITHIOPHOSPHATES, PROCESS FOR THEIR PRODUCTION AND THEIR USE AS ADDITIVES FOR LUBRICATION OILS.Info
- Publication number
- ATE700T1 ATE700T1 AT80400268T AT80400268T ATE700T1 AT E700 T1 ATE700 T1 AT E700T1 AT 80400268 T AT80400268 T AT 80400268T AT 80400268 T AT80400268 T AT 80400268T AT E700 T1 ATE700 T1 AT E700T1
- Authority
- AT
- Austria
- Prior art keywords
- additives
- metal
- production
- dithiophosphates
- metallic
- Prior art date
Links
- 239000000654 additive Substances 0.000 title 1
- 238000005461 lubrication Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000003921 oil Substances 0.000 title 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- -1 cycloaliphatic Chemical group 0.000 abstract 2
- 239000010687 lubricating oil Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000005069 Extreme pressure additive Substances 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000007866 anti-wear additive Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
- C10M137/10—Thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/14—Group 7
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/16—Groups 8, 9, or 10
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/252—Diesel engines
- C10N2040/253—Small diesel engines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
Abstract
Metallic dithiophosphates of the formula: <IMAGE> in which R1 is an alkyl, alkenyl, cycloaliphatic, aryl, or heterocyclic radical, R2 and R3 are alkyl radicals, preferably C1-C4 radicals, and m represents the valence of the metal M, M being a metal of Groups IIB, IIIB, IVB, or VIII of the Periodic System of Elements, preferably zinc. They are obtained by the action of P2S5 on a monoester alcohol of the formula: <IMAGE> and then by reaction of a metal oxide, such as zinc oxide, with the dithiophosphoric acid formed. These metallic dithiophosphates are useful as extreme-pressure and anti-wear additives for lubricating oils in amounts of between 0.2 and 10 percent, referred to the weight of lubricating oils.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7906058A FR2450841A1 (en) | 1979-03-09 | 1979-03-09 | NOVEL METAL DITHIOPHOSPHATES AND THEIR APPLICATION AS ADDITIVES FOR LUBRICATING OILS |
| EP80400268A EP0015824B1 (en) | 1979-03-09 | 1980-02-27 | Metal dithiophosphates, process for their preparation and their use as additives for lubricating oils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE700T1 true ATE700T1 (en) | 1982-03-15 |
Family
ID=9222944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT80400268T ATE700T1 (en) | 1979-03-09 | 1980-02-27 | METALLIC DITHIOPHOSPHATES, PROCESS FOR THEIR PRODUCTION AND THEIR USE AS ADDITIVES FOR LUBRICATION OILS. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4288335A (en) |
| EP (1) | EP0015824B1 (en) |
| JP (1) | JPS5949232B2 (en) |
| AT (1) | ATE700T1 (en) |
| BR (1) | BR8001370A (en) |
| CA (1) | CA1132997A (en) |
| DE (1) | DE3060193D1 (en) |
| ES (1) | ES489287A1 (en) |
| FR (1) | FR2450841A1 (en) |
| ZA (1) | ZA801367B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4400283A (en) * | 1981-06-20 | 1983-08-23 | Mobil Oil Corporation | Multifunctional lubricant additives and compositions thereof |
| US4507215A (en) * | 1983-04-25 | 1985-03-26 | Lubrizol Corp | Phosphorus-containing metal salt/olefin compositions and reaction products of same with active sulfur |
| GB8729963D0 (en) * | 1987-12-23 | 1988-02-03 | Exxon Chemical Patents Inc | Dithiophosphates |
| AU3530189A (en) * | 1988-04-11 | 1989-11-03 | Lubrizol Corporation, The | Lubricating oil additives |
| JP3677939B2 (en) * | 1996-07-30 | 2005-08-03 | 日本精工株式会社 | Rolling device having surface-treated rolling member |
| DE19757298A1 (en) | 1997-12-22 | 1999-06-24 | Basf Ag | Process for the preparation of polymer powders |
| KR20010072049A (en) | 1998-07-22 | 2001-07-31 | 미첼 롤리에르 | Coupling system (white filler/diene elastomer) based on polysulphide alkoxysilane, zinc dithiophosphate and guanidine derivative |
| US9090847B2 (en) | 2011-05-20 | 2015-07-28 | Afton Chemical Corporation | Lubricant compositions containing a heteroaromatic compound |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2177983A (en) * | 1935-12-30 | 1939-10-31 | Benjamin R Harris | Phosphate esters |
| US2905683A (en) * | 1952-12-17 | 1959-09-22 | Lubrizol Corp | Ether containing esters of dithiophosphoric acid and salts thereof |
| US2802856A (en) * | 1953-09-08 | 1957-08-13 | Lubrizol Corp | Methods of preparing tri-esters of thiophosphoric acids |
| US2895973A (en) * | 1955-02-09 | 1959-07-21 | Exxon Research Engineering Co | Metal salts of dithiophosphoric acids |
| US2959544A (en) * | 1959-02-24 | 1960-11-08 | Exxon Research Engineering Co | Lubricating oil composition containing fluorinated dithiophosphates |
| FR1310171A (en) | 1960-12-20 | 1963-03-06 | ||
| US3288819A (en) * | 1961-10-30 | 1966-11-29 | Standard Oil Co | Zinc salts of glycerol monoester dithiophosphates |
| US3944495A (en) * | 1974-02-19 | 1976-03-16 | Texaco Inc. | Metal dialkyldithiophosphates |
-
1979
- 1979-03-09 FR FR7906058A patent/FR2450841A1/en active Granted
-
1980
- 1980-02-27 AT AT80400268T patent/ATE700T1/en not_active IP Right Cessation
- 1980-02-27 DE DE8080400268T patent/DE3060193D1/en not_active Expired
- 1980-02-27 EP EP80400268A patent/EP0015824B1/en not_active Expired
- 1980-03-04 US US06/127,049 patent/US4288335A/en not_active Expired - Lifetime
- 1980-03-07 BR BR8001370A patent/BR8001370A/en unknown
- 1980-03-07 ES ES489287A patent/ES489287A1/en not_active Expired
- 1980-03-07 ZA ZA00801367A patent/ZA801367B/en unknown
- 1980-03-07 JP JP55028230A patent/JPS5949232B2/en not_active Expired
- 1980-03-07 CA CA347,274A patent/CA1132997A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2450841B1 (en) | 1982-12-17 |
| CA1132997A (en) | 1982-10-05 |
| BR8001370A (en) | 1980-11-11 |
| JPS5949232B2 (en) | 1984-12-01 |
| ZA801367B (en) | 1980-12-31 |
| US4288335A (en) | 1981-09-08 |
| EP0015824A1 (en) | 1980-09-17 |
| DE3060193D1 (en) | 1982-03-25 |
| ES489287A1 (en) | 1980-08-16 |
| JPS55143998A (en) | 1980-11-10 |
| FR2450841A1 (en) | 1980-10-03 |
| EP0015824B1 (en) | 1982-02-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification | ||
| REN | Ceased due to non-payment of the annual fee |