ATE509040T1 - METHOD FOR PRODUCING MODIFIED BUTENE-1 POLYMER AND BUTENE-1 POLYMER OBTAINED THEREFROM - Google Patents
METHOD FOR PRODUCING MODIFIED BUTENE-1 POLYMER AND BUTENE-1 POLYMER OBTAINED THEREFROMInfo
- Publication number
- ATE509040T1 ATE509040T1 AT03705328T AT03705328T ATE509040T1 AT E509040 T1 ATE509040 T1 AT E509040T1 AT 03705328 T AT03705328 T AT 03705328T AT 03705328 T AT03705328 T AT 03705328T AT E509040 T1 ATE509040 T1 AT E509040T1
- Authority
- AT
- Austria
- Prior art keywords
- based polymer
- buten
- average molecular
- molecular weight
- butene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/08—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having four or more carbon atoms
- C08F255/10—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having four or more carbon atoms on to butene polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
Abstract
The present invention relates to a process for producing a buten-1-based polymer satisfying the following requirements (a), (b) and (c): (a) a crystalline resin having a melting point (Tm -D) of 0 to 100 DEG C, the melting point being defined as a top of a peak observed on a highest-temperature side in a melting endothermic curve obtained by a differential scanning calorimeter (DSC) when a sample is held in a nitrogen atmosphere at -10 DEG C for 5 min and then heated at a temperature rise rate of 10 DEG C/min; (b) a stereoregularity index represented by (mmmm)/(mmrr + rmmr) of 20 or less; and (c) a weight-average molecular weight (Mw) of 10,000 to 1,000,000 and a ratio (Mw/Mn) of weight-average molecular weight to number-average molecular weight of 4.0 or less; a modified buten-1-based polymer produced by modifying the buten-1-based polymer with a radical polymerization initiator and an organic acid; and an adhesive composition containing the modified buten-1-based polymer. The modified buten-1-based polymer of the present invention is capable of imparting a high adhesiveness, a high strength and a good softness to polyolefins, and providing sealants having a high adhesiveness, or polyolefins having an improved compatibility to inorganic fillers, etc., in particular, is useful as resins for hot-melt adhesives.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002043543 | 2002-02-20 | ||
PCT/JP2003/001792 WO2003070786A1 (en) | 2002-02-20 | 2003-02-19 | Process for producing modified butene-1 polymer and modified butene-1 polymer obtained by the process |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE509040T1 true ATE509040T1 (en) | 2011-05-15 |
Family
ID=27750530
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT03705328T ATE509040T1 (en) | 2002-02-20 | 2003-02-19 | METHOD FOR PRODUCING MODIFIED BUTENE-1 POLYMER AND BUTENE-1 POLYMER OBTAINED THEREFROM |
Country Status (5)
Country | Link |
---|---|
US (1) | US7420023B2 (en) |
EP (1) | EP1477498B1 (en) |
JP (1) | JP4260635B2 (en) |
AT (1) | ATE509040T1 (en) |
WO (1) | WO2003070786A1 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4260635B2 (en) | 2002-02-20 | 2009-04-30 | 出光興産株式会社 | Method for producing modified butene-1 polymer and modified butene-1 polymer obtained by the method |
JP3979997B2 (en) * | 2002-02-21 | 2007-09-19 | 出光興産株式会社 | Highly fluid 1-butene polymer and process for producing the same |
JP4902099B2 (en) | 2003-10-09 | 2012-03-21 | 出光興産株式会社 | Polar group-containing higher olefin polymer and process for producing the same |
DE102008041279A1 (en) | 2008-08-15 | 2010-02-18 | Evonik Degussa Gmbh | Silane-modified polyolefins with a high degree of functionalization |
DE102008041277A1 (en) | 2008-08-15 | 2010-02-18 | Evonik Degussa Gmbh | Modified polyolefin comprising 1-butene, and an isotactic poly(1-butene)-triad useful e.g. as or in molding composition and adhesive, in protective composition, sealants, marking composition, coating composition and sealing strips |
DE102008041281A1 (en) | 2008-08-15 | 2010-02-18 | Evonik Degussa Gmbh | Modified polyolefin based on a base polyolefin, which has specific content of propylene and isotactic poly(propylene)-triad and is grafted with silane e.g. vinyltrimethoxy silane, useful as or in molding composition and adhesives |
DE102009027445A1 (en) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modified polyolefins with a particular property profile, process for their preparation and their use |
DE102009027446A1 (en) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modified polyolefins with a particular property profile, process for their preparation and their use |
DE102009027447A1 (en) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modified polyolefins with a particular property profile, process for their preparation and their use |
WO2012052429A1 (en) * | 2010-10-21 | 2012-04-26 | Basell Poliolefine Italia S.R.L. | Pressure sensitive adhesive with butene-1 copolymers |
JP6270558B2 (en) * | 2014-03-13 | 2018-01-31 | 三井化学株式会社 | Coating agent |
JP6970619B2 (en) * | 2016-01-28 | 2021-11-24 | 三井化学株式会社 | Butene-based polymers, resin compositions and moldings |
JP2017197651A (en) * | 2016-04-27 | 2017-11-02 | 出光興産株式会社 | Modified olefin-based polymer and production method thereof |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2917531A1 (en) * | 1978-05-03 | 1979-11-08 | Ato Chimie | POLYMERIC ADHESIVES ON THE BASIS OF MODIFIED MIXED POLYMERISATES OF ETHYLENE AND VINYLESTERS OR ACRYLESTERS AND / OR MODIFIED ATACTICAL POLYOLEFINES AND ADHESIVE COMPOUNDS CONTAINING SUCH SUBSTANCES |
JPS59206415A (en) * | 1983-05-11 | 1984-11-22 | Mitsui Petrochem Ind Ltd | Polymerization of 1-butene |
JPS619477A (en) * | 1984-06-22 | 1986-01-17 | Du Pont Mitsui Polychem Co Ltd | Bondable composition |
JPH06104699B2 (en) | 1985-11-20 | 1994-12-21 | 三井石油化学工業株式会社 | 1-Butene random copolymer and heat-sealability improving agent for thermoplastic resin comprising the same |
JP3540431B2 (en) | 1994-12-20 | 2004-07-07 | 三井化学株式会社 | Method for producing poly 1-butene |
US6221967B1 (en) * | 1999-12-16 | 2001-04-24 | Shell Oil Company | Preformed multi-acid adducts useful for grafting polyolefin polymers |
TWI263645B (en) | 2000-08-22 | 2006-10-11 | Idemitsu Kosan Co | 1-butene based polymer and product formed therefrom |
US6930160B2 (en) | 2000-08-22 | 2005-08-16 | Idemitsu Petrochemical Co. Ltd. | 1-Butene polymer and molded product consisting of the polymer |
DE10296585B4 (en) | 2001-03-29 | 2013-01-10 | Idemitsu Kosan Co., Ltd. | Polyolefin-based resin composition and film |
JP4260635B2 (en) | 2002-02-20 | 2009-04-30 | 出光興産株式会社 | Method for producing modified butene-1 polymer and modified butene-1 polymer obtained by the method |
-
2003
- 2003-02-19 JP JP2003569693A patent/JP4260635B2/en not_active Expired - Fee Related
- 2003-02-19 EP EP03705328A patent/EP1477498B1/en not_active Expired - Lifetime
- 2003-02-19 AT AT03705328T patent/ATE509040T1/en not_active IP Right Cessation
- 2003-02-19 WO PCT/JP2003/001792 patent/WO2003070786A1/en active Application Filing
- 2003-02-19 US US10/504,141 patent/US7420023B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
WO2003070786A1 (en) | 2003-08-28 |
EP1477498A4 (en) | 2006-12-13 |
EP1477498B1 (en) | 2011-05-11 |
EP1477498A1 (en) | 2004-11-17 |
US7420023B2 (en) | 2008-09-02 |
JP4260635B2 (en) | 2009-04-30 |
JPWO2003070786A1 (en) | 2005-06-09 |
US20050245710A1 (en) | 2005-11-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |