ATE496865T1 - COMPLEX HYDRIDES FOR HYDROGEN STORAGE - Google Patents

COMPLEX HYDRIDES FOR HYDROGEN STORAGE

Info

Publication number
ATE496865T1
ATE496865T1 AT03778089T AT03778089T ATE496865T1 AT E496865 T1 ATE496865 T1 AT E496865T1 AT 03778089 T AT03778089 T AT 03778089T AT 03778089 T AT03778089 T AT 03778089T AT E496865 T1 ATE496865 T1 AT E496865T1
Authority
AT
Austria
Prior art keywords
hydrogen storage
complex hydrides
hydrogen
temperature
titanium
Prior art date
Application number
AT03778089T
Other languages
German (de)
Inventor
Ragaiy Zidan
Original Assignee
Savannah River Nuclear Solutions Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Savannah River Nuclear Solutions Llc filed Critical Savannah River Nuclear Solutions Llc
Application granted granted Critical
Publication of ATE496865T1 publication Critical patent/ATE496865T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
    • C01B6/10—Monoborane; Diborane; Addition complexes thereof
    • C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
    • C01B6/15—Metal borohydrides; Addition complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A hydrogen storage material and process of forming the material is provided in which complex hydrides are combined under conditions of elevated temperatures and/or elevated temperature and pressure with a titanium metal such as titanium butoxide. The resulting fused product exhibits hydrogen desorption kinetics having a first hydrogen release point which occurs at normal atmospheres and at a temperature between 50° C. and 90° C.
AT03778089T 2002-11-01 2003-11-03 COMPLEX HYDRIDES FOR HYDROGEN STORAGE ATE496865T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42317202P 2002-11-01 2002-11-01
PCT/US2003/034980 WO2004041717A1 (en) 2002-11-01 2003-11-03 Complex hydrides for hydrogen storage

Publications (1)

Publication Number Publication Date
ATE496865T1 true ATE496865T1 (en) 2011-02-15

Family

ID=32312615

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03778089T ATE496865T1 (en) 2002-11-01 2003-11-03 COMPLEX HYDRIDES FOR HYDROGEN STORAGE

Country Status (8)

Country Link
US (1) US7094387B2 (en)
EP (1) EP1558520B1 (en)
JP (1) JP4584716B2 (en)
AT (1) ATE496865T1 (en)
AU (1) AU2003286873A1 (en)
CA (1) CA2503025C (en)
DE (1) DE60335896D1 (en)
WO (1) WO2004041717A1 (en)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10163697A1 (en) * 2001-12-21 2003-07-03 Studiengesellschaft Kohle Mbh Reversible storage of hydrogen with the help of doped alkali metal aluminum hydrides
WO2004041717A1 (en) 2002-11-01 2004-05-21 Westinghouse Savannah River Company, Llc Complex hydrides for hydrogen storage
US7384574B2 (en) * 2003-07-17 2008-06-10 Westinghouse Savannah River Co. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides
US20070014683A1 (en) * 2003-09-30 2007-01-18 General Electric Company Hydrogen storage composition, and associated article and method
US7175826B2 (en) * 2003-12-29 2007-02-13 General Electric Company Compositions and methods for hydrogen storage and recovery
JP4427643B2 (en) * 2004-08-27 2010-03-10 国立大学法人室蘭工業大学 Method for drying and storing activated aluminum fine particles
US8124558B2 (en) * 2004-08-27 2012-02-28 Savannah River Nuclear Solutions, Llc Catalyzed borohydrides for hydrogen storage
US20060194695A1 (en) * 2004-08-27 2006-08-31 Westinghouse Savannah River Co., Llc Destabilized and catalyzed borohydrided for reversible hydrogen storage
US20110180753A1 (en) * 2008-02-22 2011-07-28 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
US8124559B2 (en) * 2004-08-27 2012-02-28 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
US8105974B2 (en) * 2004-08-27 2012-01-31 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
ATE554193T1 (en) * 2004-12-07 2012-05-15 Univ Queensland MAGNESIUM ALLOYS FOR HYDROGEN STORAGE
CA2529427C (en) * 2004-12-17 2011-03-15 University Of New Brunswick Synthesis, recharging and processing of hydrogen storage materials using supercritical fluids
US20070092395A1 (en) * 2005-10-03 2007-04-26 General Electric Company Hydrogen storage material and method for making
US8883371B2 (en) * 2007-10-16 2014-11-11 Motorola Mobility Llc Hydrogen storage materials and hydrogen fuel cells
AU2009214142B2 (en) 2008-02-12 2013-05-02 Ilika Technologies Ltd Doped hydrogen storage material
US7754641B2 (en) * 2008-02-14 2010-07-13 General Electric Company Hydrogen storage material and related processes
US8153020B1 (en) 2008-03-19 2012-04-10 University Of South Florida Hydrogen-storing hydride complexes
KR100984718B1 (en) * 2008-08-11 2010-10-01 한화케미칼 주식회사 More advanced preparation method of organic-transition metal hydride complexes containing aryl group or alkyl group as hydrogen storage materials
US20100233076A1 (en) * 2008-09-18 2010-09-16 Ford Global Technologies, Llc Hydrogen Storage Materials
CA2790561C (en) 2010-02-24 2018-08-28 Hydrexia Pty Ltd Hydrogen release system
RU2466929C1 (en) * 2011-03-24 2012-11-20 Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр - Всероссийский научно-исследовательский институт экспериментальной физики" (ФГУП "РФЯЦ-ВНИИЭФ") Method of titanium hydride processing
DK2791053T3 (en) 2011-12-15 2023-04-17 Usw Commercial Services Ltd PREVIOUSLY UNKNOWN METAL HYDRIDES AND THEIR USE IN HYDROGEN STORAGE APPLICATIONS
RU2507150C1 (en) * 2012-07-03 2014-02-20 Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр-Всероссийский научно-исследовательский институт экспериментальной физики" (ФГУП "РФЯЦ-ВНИИЭФ") Method of obtaining powder-like titanium hydride
KR102307546B1 (en) 2013-06-14 2021-09-30 유에스더블유 커머셜 서비시스 리미티드 Synthesis and hydrogen storage properties of manganese hydrides
FI3154901T3 (en) 2014-06-13 2023-12-19 Usw Commercial Services Ltd Synthesis and hydrogen storage properties of novel metal hydrides
JP2018527459A (en) 2015-07-23 2018-09-20 ハイドレキシア ピーティーワイ リミテッド Mg-based alloys for hydrogen storage
US11192783B1 (en) * 2017-06-08 2021-12-07 National Technology & Engineering Solutions Of Sandia, Llc Ternary borides and borohydrides for hydrogen storage and method of synthesis
US11267702B1 (en) 2017-06-08 2022-03-08 National Technology & Engineering Solutions Of Sandia, Llc Solid state synthesis of metal borohydrides
US11002255B2 (en) 2019-08-20 2021-05-11 Lowry Inheritors Trust Carbon negative clean fuel production system
US11976235B2 (en) 2020-10-27 2024-05-07 Battelle Savannah River Alliance, Llc High temperature thermochemical energy storage materials
CN114735643B (en) * 2022-05-07 2023-10-27 瀚锐氢能科技集团有限公司 Organic liquid hydrogen storage material, performance regulation and control method and application thereof

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3720752A (en) 1967-04-11 1973-03-13 Houten R Van Massive metal hydride structures and methods for their preparation
DE1909732A1 (en) * 1968-06-21 1970-02-19 Grosse Aristid Victor Method and device for the production and storage of hydrogen
US4360569A (en) 1980-03-12 1982-11-23 The United States Of America As Represented By The United States Department Of Energy Porous metal hydride composite and preparation and uses thereof
US4790985A (en) * 1986-10-16 1988-12-13 Ethyl Corporation Synthesis of sodium aluminum hydride
US4948423A (en) 1989-07-21 1990-08-14 Energy Conversion Devices, Inc. Alloy preparation of hydrogen storage materials
US5411928A (en) 1993-05-24 1995-05-02 The United States Of America As Represented By The United States Department Of Energy Composition for absorbing hydrogen
DE4343321A1 (en) 1993-12-18 1995-06-22 Varta Batterie Electric accumulator
US5460745A (en) 1994-02-07 1995-10-24 The United States Of America As Represented By The United States Department Of Energy Hydride compositions
EP0755898B1 (en) * 1995-07-18 2000-05-10 Matsushita Electric Industrial Co., Ltd. Hydrogen storage alloy and electrode therefrom
DE19526434A1 (en) * 1995-07-19 1997-01-23 Studiengesellschaft Kohle Mbh Process for the reversible storage of hydrogen
CN1121920C (en) 1996-09-26 2003-09-24 丰田自动车株式会社 Hydrogen absorbing alloy powder and method of producing hydrogen absorbing alloy powder
US6074453A (en) 1996-10-30 2000-06-13 Iowa State University Research Foundation, Inc. Ultrafine hydrogen storage powders
EP0872903B1 (en) 1997-01-27 2001-10-04 Shin-Etsu Chemical Co., Ltd. Method for making hydrogen storage alloy powder and electrode comprising the alloy powder
SE9702189D0 (en) 1997-06-06 1997-06-06 Hoeganaes Ab Powder composition and process for the preparation thereof
CA2218271A1 (en) * 1997-10-10 1999-04-10 Mcgill University Method of fabrication of complex alkali mental hydrides
CA2220503A1 (en) 1997-11-07 1999-05-07 Leszek Zaluski Hydrogen storage composition
DE19758384C2 (en) * 1997-12-23 2002-08-01 Geesthacht Gkss Forschung Process for the production of nanocrystalline metal hydrides
JP3528599B2 (en) 1998-05-21 2004-05-17 トヨタ自動車株式会社 Hydrogen storage alloy
US6471935B2 (en) * 1998-08-06 2002-10-29 University Of Hawaii Hydrogen storage materials and method of making by dry homogenation
CN1318033A (en) * 1998-08-06 2001-10-17 夏威夷大学 Novel hydrogen storage materials and method of making by dry homogenation
WO2000020329A1 (en) * 1998-10-07 2000-04-13 Mcgill University Reversible hydrogen storage composition
WO2000020328A1 (en) * 1998-10-07 2000-04-13 Mcgill University Lithium-based hydrogen storage compositions
US6268077B1 (en) 1999-03-01 2001-07-31 Motorola, Inc. Portable fuel cell power supply
US6305442B1 (en) 1999-11-06 2001-10-23 Energy Conversion Devices, Inc. Hydrogen-based ecosystem
DE10012794A1 (en) * 2000-03-16 2001-09-20 Studiengesellschaft Kohle Mbh Process for the reversible storage of hydrogen comprises using reversible hydrogen-storage materials containing mixtures of aluminum metal with alkali metals and/or alkali metal hydrides
US6680042B1 (en) 2000-11-07 2004-01-20 Hydro-Quebec Method of rapidly carrying out a hydrogenation of a hydrogen storage material
US6596055B2 (en) 2000-11-22 2003-07-22 Air Products And Chemicals, Inc. Hydrogen storage using carbon-metal hybrid compositions
TWI260344B (en) 2001-01-12 2006-08-21 Safe Hydrogen Llc A method of operating a hydrogen-fueled device
US6773692B2 (en) * 2001-08-02 2004-08-10 Iowa State University Research Foundation, Inc. Method of production of pure hydrogen near room temperature from aluminum-based hydride materials
US6680043B2 (en) * 2001-11-29 2004-01-20 General Motors Corporation Process for enhancing the kinetics of hydrogenation/dehydrogenation of MAIH4 and MBH4 metal hydrides for reversible hydrogen storage
US20030165423A1 (en) * 2002-01-29 2003-09-04 Gross Karl J. Direct synthesis of hydride compounds using a titanium aluminate dopant
US6793909B2 (en) * 2002-01-29 2004-09-21 Sandia National Laboratories Direct synthesis of catalyzed hydride compounds
US7011768B2 (en) * 2002-07-10 2006-03-14 Fuelsell Technologies, Inc. Methods for hydrogen storage using doped alanate compositions
WO2004041717A1 (en) 2002-11-01 2004-05-21 Westinghouse Savannah River Company, Llc Complex hydrides for hydrogen storage

Also Published As

Publication number Publication date
US7094387B2 (en) 2006-08-22
AU2003286873A1 (en) 2004-06-07
EP1558520B1 (en) 2011-01-26
JP4584716B2 (en) 2010-11-24
CA2503025A1 (en) 2004-05-21
US20040105805A1 (en) 2004-06-03
JP2006504616A (en) 2006-02-09
EP1558520A4 (en) 2009-03-18
CA2503025C (en) 2011-01-04
WO2004041717A1 (en) 2004-05-21
EP1558520A1 (en) 2005-08-03
DE60335896D1 (en) 2011-03-10

Similar Documents

Publication Publication Date Title
ATE496865T1 (en) COMPLEX HYDRIDES FOR HYDROGEN STORAGE
WO2005091765A3 (en) Hydrogen storage system materials and methods including hydrides and hydroxides
ES2138364T3 (en) PROCEDURE FOR REVERSIBLE STORAGE OF HYDROGEN.
WO2002038494A3 (en) Method for rapidly carrying out a hydrogenation of a hydrogen storage material
TW200613217A (en) High strength monolithic carbon foam
EP1355849A4 (en) Storage, generation, and use of hydrogen
MY134077A (en) Cross-linking of starch
CN107362750A (en) A kind of composite polycrystal-diamond and its Synthetic block
AU2002364896A8 (en) Process for enhancing the kinetics of hydrogenation/dehydrogenation of ma1h4 and mbh4 metal hydrides for reversible hydrogen storage
DE102005037305B4 (en) Process for the powder metallurgy production of metal foam and parts made of metal foam
MXPA02001722A (en) Metal hydride bands and use thereof for storing hydrogen.
CA2150841A1 (en) Method for the Preparation of Magnesium Hydride
ATE312207T1 (en) PRODUCTION PROCESS FOR POROUS METAL OBJECTS
TW200630493A (en) Magnesium alloys for hydrogen storage
DE50213554D1 (en) Pressurizer with Disconnect Membrane and Method of Making the Same
SG134321A1 (en) Thermoplastic resin pellet, process for preparing thermoplastic resin pellets and expanded thermoplastic resin bead
GB1508764A (en) Alloy useful as hydrogen storage material
AP1488A (en) Method for reduction of nickel from an aqueous solution.
MY122747A (en) Method for activating passivated iron.
PL1778739T3 (en) Preparation of ultrapure polymeric articles
EP0857730A3 (en) Process for the hydrogenation of sugars
PL321047A1 (en) Method of producing pellets of lenticular shape by calendering a melt
CA2461624A1 (en) Process for producing nickel carbonyl, nickel powder and use thereof
WO2001069144A3 (en) Hydrogen compressor
WO2005019491A3 (en) Thermal cvd synthesis of nanostructures

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties