ATE382595T1 - Neuartige diazaphospholan-liganden für asymmetrische katalysatoren - Google Patents
Neuartige diazaphospholan-liganden für asymmetrische katalysatorenInfo
- Publication number
- ATE382595T1 ATE382595T1 AT05792834T AT05792834T ATE382595T1 AT E382595 T1 ATE382595 T1 AT E382595T1 AT 05792834 T AT05792834 T AT 05792834T AT 05792834 T AT05792834 T AT 05792834T AT E382595 T1 ATE382595 T1 AT E382595T1
- Authority
- AT
- Austria
- Prior art keywords
- diazaphospholane
- ligands
- novel
- optically active
- asymmetric catalysts
- Prior art date
Links
- 239000003446 ligand Substances 0.000 title abstract 2
- RVJBOIPTJJXRCT-UHFFFAOYSA-N diazaphospholidine Chemical compound C1CPNN1 RVJBOIPTJJXRCT-UHFFFAOYSA-N 0.000 title 1
- 239000011982 enantioselective catalyst Substances 0.000 title 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/16—Preparation of optical isomers
- C07C231/18—Preparation of optical isomers by stereospecific synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
- C07F9/6584—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms having one phosphorus atom as ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60515304P | 2004-08-27 | 2004-08-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE382595T1 true ATE382595T1 (de) | 2008-01-15 |
Family
ID=35478863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT05792834T ATE382595T1 (de) | 2004-08-27 | 2005-08-25 | Neuartige diazaphospholan-liganden für asymmetrische katalysatoren |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7189883B2 (de) |
| EP (1) | EP1781590B1 (de) |
| JP (1) | JP5122956B2 (de) |
| CN (1) | CN101072745A (de) |
| AT (1) | ATE382595T1 (de) |
| DE (1) | DE602005004162T2 (de) |
| WO (1) | WO2006026489A1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7071357B2 (en) * | 2001-07-23 | 2006-07-04 | Wisconsin Alumni Research Foundation | Diazaphosphacycles |
| DE102008050414A1 (de) * | 2008-10-04 | 2010-04-08 | Bayer Materialscience Ag | 1,4,2-Diazaphospholidin-Derivate |
| JP5458303B2 (ja) * | 2009-03-12 | 2014-04-02 | 国立大学法人名古屋大学 | 光学活性アリールアミノホスホニウム塩、不斉合成反応用触媒、及び光学活性化合物の製造方法 |
| JP5666596B2 (ja) * | 2009-09-28 | 2015-02-12 | ザ ガバナーズ オブ ザ ユニバーシティ オブ アルバータ | 不均一系ロジウム金属触媒 |
| CN110105204A (zh) * | 2019-06-04 | 2019-08-09 | 荆楚理工学院 | 一种4-(2-卤代异丁酰基)苯乙醇衍生物及其制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5360938A (en) | 1991-08-21 | 1994-11-01 | Union Carbide Chemicals & Plastics Technology Corporation | Asymmetric syntheses |
| US5530150A (en) | 1993-03-12 | 1996-06-25 | Takasago International Corporation | Phosphine compound, complex containing the phosphine compound as ligand, process for producing optically active aldehyde using the phosphine compound or the complex, and 4-[(R)-1'-formylethyl]azetidin-2-one derivatives |
| US6727377B2 (en) | 1998-08-21 | 2004-04-27 | The Penn State Research Foundation | Asymmetric catalysis based on chiral phospholanes and hydroxyl phospholanes |
| JP2002537400A (ja) * | 1999-02-23 | 2002-11-05 | ザ ユニバーシティ オブ ワーウィック | キラルジアザホスホリジンリガンド |
| DE10027505A1 (de) | 2000-06-06 | 2001-12-13 | Studiengesellschaft Kohle Mbh | Chirale Monophosphite als Liganden für die asymmetrische Übergangsmetall-katalysierte Hydrierung |
| US7071357B2 (en) | 2001-07-23 | 2006-07-04 | Wisconsin Alumni Research Foundation | Diazaphosphacycles |
| DE60141724D1 (de) * | 2001-07-23 | 2010-05-12 | Wisconsin Alumni Res Found | Methode zur Herstellung von Diazaphosphacyclen |
| US7169953B2 (en) * | 2001-11-09 | 2007-01-30 | The Penn State Research Foundation | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions |
| AU2002363788A1 (en) | 2001-11-09 | 2003-05-26 | The Penn State Research Foundation | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions |
| US20040072680A1 (en) | 2002-04-26 | 2004-04-15 | The Penn State Research Foundation | Chiral phosphorus cyclic compounds for transition metal-catalyzed asymmetric reactions |
| US7015360B2 (en) | 2003-03-28 | 2006-03-21 | Dow Global Technologies, Inc. | Asymmetric catalysts prepared from optically active bisphosphites bridged by achiral diols |
-
2005
- 2005-08-25 DE DE602005004162T patent/DE602005004162T2/de active Active
- 2005-08-25 US US11/211,918 patent/US7189883B2/en active Active
- 2005-08-25 EP EP05792834A patent/EP1781590B1/de not_active Not-in-force
- 2005-08-25 WO PCT/US2005/030519 patent/WO2006026489A1/en active IP Right Grant
- 2005-08-25 JP JP2007530187A patent/JP5122956B2/ja not_active Expired - Fee Related
- 2005-08-25 AT AT05792834T patent/ATE382595T1/de not_active IP Right Cessation
- 2005-08-25 CN CNA2005800288982A patent/CN101072745A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN101072745A (zh) | 2007-11-14 |
| JP5122956B2 (ja) | 2013-01-16 |
| EP1781590B1 (de) | 2008-01-02 |
| US7189883B2 (en) | 2007-03-13 |
| DE602005004162D1 (de) | 2008-02-14 |
| DE602005004162T2 (de) | 2008-05-08 |
| US20060069281A1 (en) | 2006-03-30 |
| EP1781590A1 (de) | 2007-05-09 |
| WO2006026489A1 (en) | 2006-03-09 |
| JP2008511636A (ja) | 2008-04-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Wang et al. | Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions | |
| ATE495143T1 (de) | Verfahren zur herstellung optisch aktiver carbonylverbindungen | |
| Burks et al. | Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis | |
| Gladiali et al. | BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis | |
| Nishida et al. | Enantioselective synthesis of P-stereogenic alkynylphosphine oxides by Rh-catalyzed [2+ 2+ 2] cycloaddition | |
| MY158433A (en) | Hydroformylation process with a doubly open-ended bisphosphite ligand | |
| Lightburn et al. | Regioselective hydroformylation of allylic alcohols | |
| ATE507233T1 (de) | Bisphosphitliganden für die übergangsmetallkatalysierte hydroformylierung | |
| DE502004011288D1 (de) | Auf basis von phosphoramiditliganden | |
| ATE382595T1 (de) | Neuartige diazaphospholan-liganden für asymmetrische katalysatoren | |
| Ramasamy et al. | The developing concept of bifunctional catalysis with transition metal N‐heterocyclic carbene complexes | |
| JP2008515843A5 (de) | ||
| MX2010008110A (es) | Catalizadores para reacciones de metatesis incluyendo metatesis de olefina enantioselectiva, y metodos relacionados. | |
| JP2017537965A5 (de) | ||
| ATE525130T1 (de) | Aktivierung von hydrierungskatalysatoren mittels kohlenmonoxid und verwendung von katalysatoren zur hydrierung | |
| TW200624171A (en) | Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions | |
| ATE320438T1 (de) | Bisphosphit-ligande für carbonylierungsverfahren | |
| DE60330752D1 (de) | Regenerierung von katalysatoren für die hydrierung von kohlenstoffmonoxid | |
| ATE534464T1 (de) | Fluorphosphithaltige katalysatoren für hydroformylierungsverfahren | |
| MY152291A (en) | Catalyst for oligomerization of ethylene, method for preparation thereof and process for oligomerization using it | |
| WO2008121194A8 (en) | Hydroformylation process | |
| TW201129537A (en) | Controlling the normal: iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure | |
| WO2004094442A3 (en) | Asymmetric catalysts prepared from optically active bisphosphites bridged by achiral diols | |
| ZA200711026B (en) | Hydroformylation process | |
| DE502005002594D1 (de) | Verfahren zur herstellung von c5-aldehyden und propen aus einem 1-buten-und 2-buten-haltigen c4-strom |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |