ATE368723T1 - PARTICLE-FORMED ACETONETRILE DERIVATIVES AS BLEACH ACTIVATORS IN SOLID DETERGENTS - Google Patents
PARTICLE-FORMED ACETONETRILE DERIVATIVES AS BLEACH ACTIVATORS IN SOLID DETERGENTSInfo
- Publication number
- ATE368723T1 ATE368723T1 AT01938265T AT01938265T ATE368723T1 AT E368723 T1 ATE368723 T1 AT E368723T1 AT 01938265 T AT01938265 T AT 01938265T AT 01938265 T AT01938265 T AT 01938265T AT E368723 T1 ATE368723 T1 AT E368723T1
- Authority
- AT
- Austria
- Prior art keywords
- alkyl
- particle
- acetonetrile
- derivatives
- radical
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0034—Fixed on a solid conventional detergent ingredient
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0078—Multilayered tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/3925—Nitriles; Isocyanates or quarternary ammonium nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention aims to improve the oxidating and bleaching properties of inorganic peroxygen compounds during textile washing in a storage-resistant manner. In order to achieve this, particle-shaped compounds of formula (I) are essentially used, wherein R<1 >represents H, CH3, a C2-24 alkyl or alkenyl radical, a substituted C2-24 alkyl or alkenyl radical comprising at least one substituent from the group Cl, Br, OH, NH2, CN, an alkyl or alkenylaryl radical comprising a C2-24 alkyl group, or a substituted alkyl or alkenylaryl radical comprising a C1-24 alkyl group and at least one further substituent on the aromatic ring; R<2 >and R<3 >are independently chosen from CH2-CN, CH3, CH2-H3, CH2-CH2-CH3, CH(CH3)-CH3, CH2-OH, CH2-CH2-OH, -CH(OH)-CH3, CH2-CH2-CH2OH, CH2-CH(OH)-CH3, CH(OH)-CH2-CH3, (CH2CH2-O)nH, n being equal to 1, 2, 3, 4, 5 or 6; R<4 >and R<5 >independently have one of the designations cited above for R<1>, R<2 >or R<3>; and X represents a charge equalising anion. Textile detergent contains approximately 0.1 wt. % to 10 wt. % of one such bleaching agent.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10038845A DE10038845A1 (en) | 2000-08-04 | 2000-08-04 | Particle-formulated acetonitrile derivatives as bleach activators in solid detergents |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE368723T1 true ATE368723T1 (en) | 2007-08-15 |
Family
ID=7651836
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT01938265T ATE368723T1 (en) | 2000-08-04 | 2001-06-15 | PARTICLE-FORMED ACETONETRILE DERIVATIVES AS BLEACH ACTIVATORS IN SOLID DETERGENTS |
Country Status (7)
Country | Link |
---|---|
US (1) | US20040067862A1 (en) |
EP (1) | EP1305384B1 (en) |
AT (1) | ATE368723T1 (en) |
AU (1) | AU2001263963A1 (en) |
DE (2) | DE10038845A1 (en) |
ES (1) | ES2288513T3 (en) |
WO (1) | WO2002012425A1 (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005531597A (en) | 2002-05-31 | 2005-10-20 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | Deodorization of cationic acetonitrile derivatives |
MXPA05006578A (en) | 2002-12-18 | 2005-08-16 | Procter & Gamble | Organic activator. |
ATE357497T1 (en) * | 2002-12-20 | 2007-04-15 | Henkel Kgaa | DETERGENTS OR CLEANING PRODUCTS CONTAINING BLEACH |
EP1433839B2 (en) † | 2002-12-24 | 2015-04-01 | Dalli-Werke GmbH & Co. KG | Optimised wash and cleaning compositions for an improved bleaching effect at low temperatures |
DE10351325A1 (en) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Detergent or cleaning agent with water-soluble builder system and dirt-releasing cellulose derivative |
ATE350447T1 (en) * | 2003-02-10 | 2007-01-15 | Henkel Kgaa | INCREASING THE WATER ABSORPTION CAPACITY OF TEXTILES |
DE10351321A1 (en) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Enhancing the cleaning performance of detergents through a combination of cellulose derivatives |
JP4519122B2 (en) * | 2003-02-10 | 2010-08-04 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | Bleach-containing laundry or cleaning agent comprising a water-soluble builder system and a soil-dissociating cellulose derivative |
DE502004003950D1 (en) * | 2003-02-10 | 2007-07-12 | Henkel Kgaa | REINFORCEMENT OF THE CLEANING PERFORMANCE OF DETERGENTS BY CELLULOSE DERIVATIVE AND HYGROSCOPIC POLYMER |
JP2006517245A (en) * | 2003-02-10 | 2006-07-20 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | Use of cellulose derivatives as foam control agents |
US20070244028A1 (en) * | 2004-05-17 | 2007-10-18 | Henkel Kgaa | Washing Agent With Bleach Boosting Transition Metal Complex Optionally Generated in Situ |
DE102005026522B4 (en) * | 2005-06-08 | 2007-04-05 | Henkel Kgaa | Reinforcement of cleaning performance of detergents by polymer |
DE102005026544A1 (en) | 2005-06-08 | 2006-12-14 | Henkel Kgaa | Reinforcement of cleaning performance of detergents by polymer |
GB0917951D0 (en) * | 2009-10-14 | 2009-11-25 | Chemlink Specialities Ltd | Composition including one or more hydrolytically unstable components |
RU2533494C1 (en) * | 2013-05-13 | 2014-11-20 | Открытое акционерное общество "НАПОР" ОАО "НАПОР" | Reagent for absorbing hydrogen sulphide and light mercaptan (versions) |
Family Cites Families (33)
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---|---|---|---|---|
US3234258A (en) * | 1963-06-20 | 1966-02-08 | Procter & Gamble | Sulfation of alpha olefins |
US4116885A (en) * | 1977-09-23 | 1978-09-26 | The Procter & Gamble Company | Anionic surfactant-containing detergent compositions having soil-release properties |
DE3413571A1 (en) * | 1984-04-11 | 1985-10-24 | Hoechst Ag, 6230 Frankfurt | USE OF CRYSTALLINE LAYERED SODIUM SILICATES FOR WATER SOFTENING AND METHOD FOR WATER SOFTENING |
DE3417649A1 (en) * | 1984-05-12 | 1985-11-14 | Hoechst Ag, 6230 Frankfurt | METHOD FOR PRODUCING CRYSTALLINE SODIUM SILICATES |
FR2597473B1 (en) * | 1986-01-30 | 1988-08-12 | Roquette Freres | PROCESS FOR THE OXIDATION OF DI-, TRI-, OLIGO- AND POLYSACCHARIDES TO POLYHYDROXYCARBOXYLIC ACIDS, CATALYST IMPLEMENTED AND PRODUCTS THUS OBTAINED. |
DE3723873A1 (en) * | 1987-07-18 | 1989-01-26 | Henkel Kgaa | USE OF HYDROXYALKYLPOLYETHYLENE GLYCOLETHERS IN RINSE AID FOR MACHINE CLEANING |
YU221490A (en) * | 1989-12-02 | 1993-10-20 | Henkel Kg. | PROCEDURE FOR HYDROTHERMAL PRODUCTION OF CRYSTAL SODIUM DISILICATE |
DE4000705A1 (en) * | 1990-01-12 | 1991-07-18 | Hoechst Ag | METHOD FOR PRODUCING CRYSTALLINE SODIUM SILICATES |
GB9012001D0 (en) * | 1990-05-30 | 1990-07-18 | Unilever Plc | Bleaching composition |
US5075041A (en) * | 1990-06-28 | 1991-12-24 | Shell Oil Company | Process for the preparation of secondary alcohol sulfate-containing surfactant compositions |
GB9022724D0 (en) * | 1990-10-19 | 1990-12-05 | Unilever Plc | Detergent compositions |
DE4107230C2 (en) * | 1991-03-07 | 1995-04-06 | Hoechst Ag | Process for the production of sodium silicates |
DE4142711A1 (en) * | 1991-12-21 | 1993-06-24 | Hoechst Ag | METHOD FOR PRODUCING CRYSTALLINE SODIUM DISILICATES |
DE4221381C1 (en) * | 1992-07-02 | 1994-02-10 | Stockhausen Chem Fab Gmbh | Graft copolymers of unsaturated monomers and sugars, process for their preparation and their use |
DE4203923A1 (en) * | 1992-02-11 | 1993-08-12 | Henkel Kgaa | METHOD FOR PRODUCING POLYCARBOXYLATES ON A POLYSACCHARIDE BASE |
DE4300772C2 (en) * | 1993-01-14 | 1997-03-27 | Stockhausen Chem Fab Gmbh | Water-soluble, biodegradable copolymers based on unsaturated mono- and dicarboxylic acids, process for their preparation and their use |
DE4303320C2 (en) * | 1993-02-05 | 1995-12-21 | Degussa | Detergent composition having improved soil carrying power, process for its preparation and use of a suitable polycarboxylate therefor |
DE4405511A1 (en) * | 1994-02-22 | 1995-08-24 | Henkel Kgaa | Detergent with amorphous silicate builder substances |
DE19503061A1 (en) * | 1995-02-01 | 1996-08-08 | Henkel Kgaa | Dimer alcohol bis- and trimer alcohol tris-sulfates and ether sulfates |
US5739327A (en) * | 1995-06-07 | 1998-04-14 | The Clorox Company | N-alkyl ammonium acetonitrile bleach activators |
US5814242A (en) * | 1995-06-07 | 1998-09-29 | The Clorox Company | Mixed peroxygen activator compositions |
US5888419A (en) * | 1995-06-07 | 1999-03-30 | The Clorox Company | Granular N-alkyl ammonium acetontrile compositions |
DE19605688A1 (en) * | 1996-02-16 | 1997-08-21 | Henkel Kgaa | Transition metal complexes as activators for peroxygen compounds |
DE19620411A1 (en) * | 1996-04-01 | 1997-10-02 | Henkel Kgaa | Transition metal amine complexes as activators for peroxygen compounds |
DE19616693A1 (en) * | 1996-04-26 | 1997-11-06 | Henkel Kgaa | Enol esters as bleach activators for detergents and cleaning agents |
DE19649375A1 (en) * | 1996-11-29 | 1998-06-04 | Henkel Kgaa | Acetonitrile derivatives as bleach activators in detergents |
US6211130B1 (en) * | 1997-08-21 | 2001-04-03 | Henkel Kommanditgesellschaft Auf Aktien | Use of quaternary acetonitrile compounds as activators for detergents |
DE19740671A1 (en) * | 1997-09-16 | 1999-03-18 | Clariant Gmbh | Bleach activator granulate containing ammonium nitrile and layered silicate |
DE19819187A1 (en) * | 1998-04-30 | 1999-11-11 | Henkel Kgaa | Solid dishwasher detergent with phosphate and crystalline layered silicates |
KR100630289B1 (en) * | 1998-12-15 | 2006-09-29 | 헨켈 코만디트게젤샤프트 아우프 악티엔 | Acetonitrile derivatives formulated in particulate form as bleach activators in solid detergents |
DE19857596A1 (en) * | 1998-12-15 | 2000-06-21 | Henkel Kgaa | Use of N-cyanomethyl quaternary ammonium salts as bleach activators, useful in dishwashing compositions, stabilized by formulating as particles with silicon-containing carrier |
DE19908051A1 (en) * | 1999-02-25 | 2000-08-31 | Henkel Kgaa | Process for the preparation of compounded acetonitrile derivatives |
DE19914811A1 (en) * | 1999-03-31 | 2000-10-05 | Henkel Kgaa | Detergent compositions containing a bleaching agent include a combination of a cyanomethyl ammonium salt bleach activator and an enzyme |
-
2000
- 2000-08-04 DE DE10038845A patent/DE10038845A1/en not_active Ceased
-
2001
- 2001-06-15 DE DE50112796T patent/DE50112796D1/en not_active Expired - Fee Related
- 2001-06-15 WO PCT/EP2001/006810 patent/WO2002012425A1/en active IP Right Grant
- 2001-06-15 US US10/470,281 patent/US20040067862A1/en not_active Abandoned
- 2001-06-15 AU AU2001263963A patent/AU2001263963A1/en not_active Abandoned
- 2001-06-15 AT AT01938265T patent/ATE368723T1/en not_active IP Right Cessation
- 2001-06-15 EP EP01938265A patent/EP1305384B1/en not_active Expired - Lifetime
- 2001-06-15 ES ES01938265T patent/ES2288513T3/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
WO2002012425A1 (en) | 2002-02-14 |
DE10038845A1 (en) | 2002-02-21 |
EP1305384B1 (en) | 2007-08-01 |
EP1305384A1 (en) | 2003-05-02 |
DE50112796D1 (en) | 2007-09-13 |
ES2288513T3 (en) | 2008-01-16 |
US20040067862A1 (en) | 2004-04-08 |
AU2001263963A1 (en) | 2002-02-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
REN | Ceased due to non-payment of the annual fee |