ATE243T1 - PROCESS FOR THE MANUFACTURE OF HIGH ALKALINE METAL CONTAINING CLEANING DISPERSING ADDITIVES, ESPECIALLY FOR LUBRICATION OIL AND PRODUCT MADE THEREOF. - Google Patents
PROCESS FOR THE MANUFACTURE OF HIGH ALKALINE METAL CONTAINING CLEANING DISPERSING ADDITIVES, ESPECIALLY FOR LUBRICATION OIL AND PRODUCT MADE THEREOF.Info
- Publication number
- ATE243T1 ATE243T1 AT79400390T AT79400390T ATE243T1 AT E243 T1 ATE243 T1 AT E243T1 AT 79400390 T AT79400390 T AT 79400390T AT 79400390 T AT79400390 T AT 79400390T AT E243 T1 ATE243 T1 AT E243T1
- Authority
- AT
- Austria
- Prior art keywords
- alkaline
- earth metal
- dispersant
- detergent
- manufacture
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000000654 additive Substances 0.000 title 1
- 238000004140 cleaning Methods 0.000 title 1
- 238000005461 lubrication Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 5
- 239000002270 dispersing agent Substances 0.000 abstract 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 4
- -1 alkaline-earth metal alkylbenzene sulfonates Chemical class 0.000 abstract 4
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 3
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 abstract 1
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 239000010687 lubricating oil Substances 0.000 abstract 1
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 239000011369 resultant mixture Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/24—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process of preparing metallic detergent-dispersant compositions is provided by: 1. Reacting sulfur with an alkylphenol, bearing one or more C6-C60 alkyl substituents, in the presence of a dilution oil, an alkaline-earth metal alkylbenzene sulfonate of a molecular weight of more than about 300 and a TBN of less than or equal to about 150, an alkaline-earth metal compound, optionally an alkaline-metal hydroxide, a base component of metallic detergent-dispersant of a TBN greater than or equal to 200 selected from among superalkalinized sulfurized alkaline-earth metal alkylphenates, alkaline-earth metal alkylbenzene sulfonates, and mixtures of superalkalinized sulfurized alkaline earth metal alkylphenates and alkaline-earth metal alkylbenzene sulfonates, and an alkylene glycol, at a temperature of between 100 DEG C. and 190 DEG C.; 2. Carbonating the resultant mixture with carbon dioxide at a temperature of between 100 DEG C. and 200 DEG C., the amount of CO2 being between that which can be completely absorbed and an excess of 30 percent of said amount; 3. Removing the alkylene glycol; and 4. Separating the metallic detergent-dispersant of high alkalinity thus obtained. The detergent-dispersants thus obtained are useful in improving the detergent-dispersant power of lubricating oils.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7818946A FR2429832A1 (en) | 1978-06-26 | 1978-06-26 | IMPROVED PROCESS FOR THE PREPARATION OF HIGH ALKALINITY METAL DETERGENT-DISPERSANT ADDITIVES, PARTICULARLY FOR LUBRICATING OILS |
| EP79400390A EP0007260B1 (en) | 1978-06-26 | 1979-06-14 | Process for the preparation of metalliferous detergent-dispersant additives of high alkali content, especially for lubricating oils, and product obtained |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE243T1 true ATE243T1 (en) | 1981-10-15 |
Family
ID=9209959
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT79400390T ATE243T1 (en) | 1978-06-26 | 1979-06-14 | PROCESS FOR THE MANUFACTURE OF HIGH ALKALINE METAL CONTAINING CLEANING DISPERSING ADDITIVES, ESPECIALLY FOR LUBRICATION OIL AND PRODUCT MADE THEREOF. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4293431A (en) |
| EP (1) | EP0007260B1 (en) |
| JP (1) | JPS6056199B2 (en) |
| AT (1) | ATE243T1 (en) |
| BR (1) | BR7903979A (en) |
| CA (1) | CA1129842A (en) |
| DE (1) | DE2960884D1 (en) |
| ES (1) | ES481864A1 (en) |
| FR (1) | FR2429832A1 (en) |
| MX (1) | MX5560E (en) |
| ZA (1) | ZA793196B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2063250B (en) * | 1979-10-02 | 1984-05-31 | Bdh Chemicals Ltd | Liquid crystal esters |
| FR2529225B1 (en) * | 1982-06-24 | 1986-04-25 | Orogil | NEW HIGH ALKALINITY METAL DETERGENT-DISPERSANT ADDITIVE FOR LUBRICATING OILS |
| FR2529224B1 (en) * | 1982-06-24 | 1986-02-07 | Orogil | NEW SURALKALINIZED DETERGENT-DISPERSANT ADDITIVE FOR LUBRICATING OILS |
| US4744921A (en) * | 1986-10-21 | 1988-05-17 | Chevron Research Company | Methods for preparing, group II metal overbased sulfurized alkylphenols |
| US5024773A (en) * | 1986-10-21 | 1991-06-18 | Chevron Research Company | Methods for preparing, group II metal overbased sulfurized alkylphenols |
| US4971710A (en) * | 1986-10-21 | 1990-11-20 | Chevron Research Company | Methods for preparing, Group II metal overbased sulfurized alkylphenols |
| US4832857A (en) * | 1988-08-18 | 1989-05-23 | Amoco Corporation | Process for the preparation of overbased molybdenum alkaline earth metal and alkali metal dispersions |
| US4973411A (en) * | 1989-09-15 | 1990-11-27 | Texaco Inc. | Process for the preparation of sulfurized overbased phenate detergents |
| US5370803A (en) * | 1993-09-03 | 1994-12-06 | Texaco Inc. | Efficient method of producing lubricant detergent additives |
| US9029304B2 (en) * | 2008-09-30 | 2015-05-12 | Chevron Oronite Company Llc | Lubricating oil additive composition and method of making the same |
| CN113186015B (en) * | 2021-02-02 | 2024-02-06 | 安徽澳润新材料有限公司 | High-base-number magnesium sulfonate detergent and preparation method thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1080531A (en) * | 1952-02-01 | 1954-12-09 | Standard Oil Dev Co | Preparation of compound products containing metal sulphonates and metal salts of aromatic sulphides |
| US3178368A (en) * | 1962-05-15 | 1965-04-13 | California Research Corp | Process for basic sulfurized metal phenates |
| USB194963I5 (en) * | 1962-05-15 | |||
| US3493516A (en) * | 1966-05-04 | 1970-02-03 | Chevron Res | Carboxylate modified phenates |
| US3629109A (en) * | 1968-12-19 | 1971-12-21 | Lubrizol Corp | Basic magnesium salts processes and lubricants and fuels containing the same |
| GB1429243A (en) * | 1973-02-22 | 1976-03-24 | Orobis Ltd | Overbased phenates |
| GB1469289A (en) * | 1974-07-05 | 1977-04-06 | Exxon Research Engineering Co | Detergent additives |
| JPS5272707A (en) * | 1975-12-15 | 1977-06-17 | Karonaito Kagaku Kk | Preparation of additive for perbasic lubricating oil |
-
1978
- 1978-06-26 FR FR7818946A patent/FR2429832A1/en active Granted
-
1979
- 1979-06-14 AT AT79400390T patent/ATE243T1/en not_active IP Right Cessation
- 1979-06-14 DE DE7979400390T patent/DE2960884D1/en not_active Expired
- 1979-06-14 EP EP79400390A patent/EP0007260B1/en not_active Expired
- 1979-06-19 US US06/049,959 patent/US4293431A/en not_active Expired - Lifetime
- 1979-06-21 MX MX798107U patent/MX5560E/en unknown
- 1979-06-22 CA CA330,659A patent/CA1129842A/en not_active Expired
- 1979-06-25 ES ES481864A patent/ES481864A1/en not_active Expired
- 1979-06-25 BR BR7903979A patent/BR7903979A/en not_active IP Right Cessation
- 1979-06-26 ZA ZA793196A patent/ZA793196B/en unknown
- 1979-06-26 JP JP54079792A patent/JPS6056199B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0007260B1 (en) | 1981-09-23 |
| FR2429832A1 (en) | 1980-01-25 |
| FR2429832B1 (en) | 1982-04-02 |
| CA1129842A (en) | 1982-08-17 |
| JPS5540765A (en) | 1980-03-22 |
| EP0007260A1 (en) | 1980-01-23 |
| MX5560E (en) | 1983-10-11 |
| JPS6056199B2 (en) | 1985-12-09 |
| ES481864A1 (en) | 1980-02-16 |
| ZA793196B (en) | 1980-06-25 |
| US4293431A (en) | 1981-10-06 |
| BR7903979A (en) | 1980-03-25 |
| DE2960884D1 (en) | 1981-12-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification | ||
| REN | Ceased due to non-payment of the annual fee |