ATE103261T1 - PROCESS FOR GENERATING CHLORINE DIOXIDE. - Google Patents

PROCESS FOR GENERATING CHLORINE DIOXIDE.

Info

Publication number
ATE103261T1
ATE103261T1 AT89850354T AT89850354T ATE103261T1 AT E103261 T1 ATE103261 T1 AT E103261T1 AT 89850354 T AT89850354 T AT 89850354T AT 89850354 T AT89850354 T AT 89850354T AT E103261 T1 ATE103261 T1 AT E103261T1
Authority
AT
Austria
Prior art keywords
reaction vessel
formic acid
chlorine dioxide
content
gaseous
Prior art date
Application number
AT89850354T
Other languages
German (de)
Inventor
Maria Norell
Bjoern Svedin
Original Assignee
Eka Nobel Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eka Nobel Ab filed Critical Eka Nobel Ab
Application granted granted Critical
Publication of ATE103261T1 publication Critical patent/ATE103261T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B11/00—Oxides or oxyacids of halogens; Salts thereof
    • C01B11/02—Oxides of chlorine
    • C01B11/022—Chlorine dioxide (ClO2)
    • C01B11/023—Preparation from chlorites or chlorates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)

Abstract

A process for production of chlorine dioxide by reacting in a reaction vessel an alkali metal chlorate, a mineral acid and methanol as a reducing agent in proportions to generate chlorine dioxide in a reaction medium maintained at a temperature from about 50 DEG C to about 100 DEG C and at an acidity within the interval from about 2 to about 11 N and subjected to a subatmospheric pressure. Thereby water is evaporated and a mixture of chlorine dioxide, water vapour and gaseous by-products is withdrawn from an evaporation region in the reaction vessel. The alkali metal sulphate is precipitated in a crystallization region in the reaction vessel. The content of formic acid in the reaction vessel is increased by addition of formic acid to a content of formic acid exceeding about 0.3 M. The gaseous by-products are condensed to obtain formic acid and the content of formic acid in the reaction vessel is increased by recirculation of the condensate.
AT89850354T 1988-10-25 1989-10-17 PROCESS FOR GENERATING CHLORINE DIOXIDE. ATE103261T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8803817A SE463671B (en) 1988-10-25 1988-10-25 PROCEDURE FOR PREPARATION OF CHLORIDE Dioxide
EP89850354A EP0366636B1 (en) 1988-10-25 1989-10-17 A process for the production of chlorine dioxide

Publications (1)

Publication Number Publication Date
ATE103261T1 true ATE103261T1 (en) 1994-04-15

Family

ID=20373736

Family Applications (1)

Application Number Title Priority Date Filing Date
AT89850354T ATE103261T1 (en) 1988-10-25 1989-10-17 PROCESS FOR GENERATING CHLORINE DIOXIDE.

Country Status (11)

Country Link
US (1) US4978517A (en)
EP (1) EP0366636B1 (en)
JP (1) JPH075283B2 (en)
AT (1) ATE103261T1 (en)
BR (1) BR8905386A (en)
CA (1) CA1333519C (en)
DE (1) DE68914090D1 (en)
FI (1) FI89474C (en)
NZ (1) NZ231088A (en)
PT (1) PT92085B (en)
SE (1) SE463671B (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5348683A (en) * 1990-02-06 1994-09-20 Olin Corporation Chloric acid - alkali metal chlorate mixtures and chlorine dioxide generation
US5242554A (en) * 1990-02-06 1993-09-07 Olin Corporation Electrolytic production of chloric acid and sodium chlorate mixtures for the generation of chlorine dioxide
US5322598A (en) * 1990-02-06 1994-06-21 Olin Corporation Chlorine dioxide generation using inert load of sodium perchlorate
SE9002262D0 (en) * 1990-06-27 1990-06-27 Eka Nobel Ab PROCEDURE FOR THE PREPARATION OF CHLOROXIDE
US5205995A (en) * 1991-04-22 1993-04-27 Sterling Canada Inc. Metathesis of acidic by-product of chlorine dioxide generating apparatus
US5116595A (en) * 1991-04-22 1992-05-26 Tenneco Canada Inc. Metathesis of acidic by-product of chlorine dioxide generating process
CA2148462C (en) * 1992-11-09 1999-08-31 Herbert C. Scribner Metathesis of acidic by-product of chlorine dioxide generating process
US5399332A (en) * 1993-10-20 1995-03-21 Sterling Canada, Inc. Dynamic leaching procedure for metathesis
US5599518A (en) * 1994-12-01 1997-02-04 Olin Corporation Catalytic process for chlorine dioxide generation from chloric acid
US6322768B1 (en) 1998-09-29 2001-11-27 International Paper Company Recovery of chlorine dioxide from gas streams
US6287533B1 (en) 1999-09-20 2001-09-11 Mohammed N. I. Khan Production of chlorine dioxide by chemical reduction of ammonium chlorate in aqueous acidic solution
US6306281B1 (en) 1999-11-30 2001-10-23 Joseph Matthew Kelley Electrolytic process for the generation of stable solutions of chlorine dioxide
US6855294B2 (en) 2000-11-22 2005-02-15 Resonance, Inc. Apparatus and methods for efficient generation of chlorine dioxide
WO2005080262A1 (en) * 2004-02-23 2005-09-01 Akzo Nobel N.V. Process for production of chlorine dioxide
CN100471791C (en) * 2004-02-23 2009-03-25 阿克佐诺贝尔公司 Process for production of chlorine dioxide
JP2005330159A (en) * 2004-05-21 2005-12-02 Mitsubishi Gas Chem Co Inc Method for producing chlorine-free bleaching agent for chemical pulp from sodium chloride
WO2006062455A1 (en) * 2004-12-06 2006-06-15 Akzo Nobel N.V. Chemical process and apparatus
EP2443059B1 (en) * 2009-06-16 2015-08-26 Akzo Nobel N.V. Process for the production of chlorine dioxide
UY32927A (en) 2009-10-12 2011-03-31 Akzo Nobel Chemicals Int Bv PROCESS FOR THE PRODUCTION OF CHLORINE DIOXIDE
FI122623B (en) * 2009-10-30 2012-04-30 Kemira Oyj Process for the preparation of chlorine dioxide

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3864456A (en) * 1964-08-13 1975-02-04 Electric Reduction Co Manufacture of chlorine dioxide, chlorine and anhydrous sodium sulphate
FR1471370A (en) * 1965-03-12 1967-03-03 Hooker Chemical Corp Chlorine dioxide production
US3933988A (en) * 1966-10-24 1976-01-20 Hooker Chemicals & Plastics Corporation Method of simultaneously producing chlorine dioxide and a sulfate salt
US3563702A (en) * 1968-03-05 1971-02-16 Hooker Chemical Corp Production of chlorine dioxide
NL7501253A (en) * 1974-02-15 1975-08-19 Basf Ag METHOD FOR THE WINNING OF MERIC ACID.
US4145401A (en) * 1976-03-19 1979-03-20 Erco Industries Limited High efficiency chlorine dioxide production at low acidity with methanol addition
CA1080433A (en) * 1976-03-19 1980-07-01 Erco Industries Limited High efficiency chlorine dioxide production at low acidity
SE425322B (en) * 1976-05-11 1982-09-20 Kemanobel Ab PROCEDURE FOR THE PREPARATION OF ALKALIMETAL OR EARTHALKALIMETAL CHLORITE
US4465658A (en) * 1983-06-13 1984-08-14 Erco Industries Limited Chlorine dioxide process
US4473540A (en) * 1983-07-07 1984-09-25 Erco Industries Limited High efficiency chlorine dioxide process
DE3522934A1 (en) * 1985-06-27 1987-01-08 Thomson Brandt Gmbh VIDEO RECORDER
SE460046B (en) * 1987-03-27 1989-09-04 Eka Nobel Ab PROCEDURE FOR PREPARATION OF CHLORIDE Dioxide

Also Published As

Publication number Publication date
DE68914090D1 (en) 1994-04-28
CA1333519C (en) 1994-12-20
FI89474B (en) 1993-06-30
BR8905386A (en) 1990-05-22
NZ231088A (en) 1991-08-27
FI895028A0 (en) 1989-10-23
JPH075283B2 (en) 1995-01-25
SE8803817D0 (en) 1988-10-25
SE8803817L (en) 1990-04-26
JPH02157102A (en) 1990-06-15
SE463671B (en) 1991-01-07
PT92085A (en) 1990-04-30
EP0366636A1 (en) 1990-05-02
EP0366636B1 (en) 1994-03-23
FI89474C (en) 1993-10-11
PT92085B (en) 1995-08-09
US4978517A (en) 1990-12-18

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Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
EELA Cancelled due to lapse of time