AT338447B - FOUNDRY MODEL MADE OF PLASTIC - Google Patents
FOUNDRY MODEL MADE OF PLASTICInfo
- Publication number
- AT338447B AT338447B AT152775A AT152775A AT338447B AT 338447 B AT338447 B AT 338447B AT 152775 A AT152775 A AT 152775A AT 152775 A AT152775 A AT 152775A AT 338447 B AT338447 B AT 338447B
- Authority
- AT
- Austria
- Prior art keywords
- plastic
- model made
- models
- coating
- foundry model
- Prior art date
Links
- 239000004033 plastic Substances 0.000 title claims description 7
- 229920003023 plastic Polymers 0.000 title claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000005266 casting Methods 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 239000003110 molding sand Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C7/00—Patterns; Manufacture thereof so far as not provided for in other classes
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Mold Materials And Core Materials (AREA)
Description
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Die Erfindung bezieht sich auf ein Giessereimodell aus Kunststoff, dessen Oberfläche mit einem stromlos (chemisch) abgeschiedenen Nickelüberzug oder einem Nickellegierungsüberzug versehen ist, der anschliessend an die Abscheidung gehärtet wird.
Giessformen werden bekanntlich aus Formsand hergestellt, und die Herstellung beruht auf der Verwendung entsprechender Modelle. Handelt es sich um die Herstellung von Einzelstücken, so genügt das Urmodell. Für die Massenproduktion hingegen ist eine Vielzahl von Modellen erforderlich.
Diese Modelle werden üblicherweise als Abgüsse-unter Zwischenschaltung eines Negativs-vom Urmodell hergestellt. Während früher in der Regel Modelle aus Metall hergestellt wurden, hat sich in neuerer Zeit die Verwendung von Kunststoffen, z. B. von härtbaren Giessharzen, für diesen Zweck eingebürgert. Naturgemäss werden die Oberflächen der Modelle durch den dauernden Kontakt mit dem Formsand, der ja im Wesen aus den sehr harten Quarzkristallen bzw. -teilchen besteht, stark abgescheuert, so dass die Modelle eine im Vergleich zu den Herstellungskosten zu geringe Lebensdauer haben, also unwirtschaftlich sind.
Es handelt sich also darum, die Abriebfestigkeit der Oberflächen und damit die Standzeit solcher Modelle zu erhöhen. Hiefür bietet sich als Lösung die Aufbringung einer entsprechend abriebfesten, gut haftenden Schutzschicht an, da im Falle der Verwendung von z. B. Giessharzen als Modellmaterial die Härte derselben-auch mit Rücksicht auf ihre problemlose Verarbeitung-nicht über ein gewisses Mass hinaus gesteigert werden kann.
Für die Erzeugung einer solchen abriebfesten Schutzschicht ist im Falle von metallischen Gussformen bereits die Auftragung von chemisch abgeschiedenen Nickelüberzügen vorgeschlagen worden (man vgl. z. B. Kapitel 14. 4. 5 auf S. 194 des Buches "Chemische (stromlose) Vernickelung"v. C. Cawrilov, Eugen G. Leuze Verlag).
Durch die deutsche Auslegeschrift 2154895 wird die Möglichkeit der Anwendung bzw. Übertragung dieser Methode auf das Überziehen von Modellen bzw. Gussformen aus Epoxydharzen angeregt.
Die Herstellung haftfester Nickelniederschläge auf Metalloberflächen durch chemische Abscheidung konnte jedoch nicht mit gleichem Erfolg auch auf Kunststoffoberflächen in dem für den in Rede stehenden Zweck erforderlichen Ausmass erzielt werden.
Aufgabe der Erfindung ist die Schaffung hinlänglich haftfester Überzüge bei sorgfältiger Anwendung der im übrigen für die Vorbereitung von Kunststoffoberflächen bekannten Vorbehandlungsmassnahmen, wie chemisches Aufrauhen, Bekeimen und Aktivieren.
Zur Lösung dieses Problems wird erfindungsgemäss vorgeschlagen, dass der Kunststoff ein Metallpulver z. B. von Eisen, Nickel oder Aluminium enthält.
Durch diese Massnahme wird erreicht, dass bei dem der Abscheidung vorangehenden Beizen des Modells zahlreiche Metallteilchen auf der Oberfläche des Modells freigelegt werden, von denen ein Teil aus der Oberfläche herausfällt und jeweils einen kleinen Krater hinterlässt. Die durch den Niederschlag gebildete Überzugsschicht dringt in diese Krater ein, wodurch eine Verankerung der Schicht erzielt wird. Ausserdem erleichtern die wohl freigelegten, aber in der Oberfläche eingebettet gebliebenen Metallteilchen die Aktivierung des Niederschlages. Auf diese Weise wird ein Überzug erreicht, dessen Haftfestigkeit zumindest gleich ist der eines gleichwertigen Überzuges auf einer Metalloberfläche.
Die Härte bzw. Abriebfestigkeit der Überzugsschichten kann weiter gesteigert werden, wenn phosphoroder borhaltige Nickellegierungsschichten abgeschieden werden.
EMI1.1
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
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The invention relates to a foundry model made of plastic, the surface of which is provided with an electroless (chemically) deposited nickel coating or a nickel alloy coating, which is then hardened after the deposition.
It is known that casting molds are made from molding sand, and production is based on the use of appropriate models. If the production of individual pieces is concerned, the master model is sufficient. On the other hand, a variety of models are required for mass production.
These models are usually made as casts - with the interposition of a negative - from the original model. While in the past models were usually made of metal, more recently the use of plastics, e.g. B. of curable casting resins, naturalized for this purpose. Naturally, the surfaces of the models are heavily abraded by constant contact with the molding sand, which essentially consists of very hard quartz crystals or particles, so that the models have a too short lifespan compared to the manufacturing costs and are therefore uneconomical .
The aim is to increase the abrasion resistance of the surfaces and thus the service life of such models. The solution here is to apply a correspondingly abrasion-resistant, well-adhering protective layer, since in the case of using z. B. casting resins as model material, the hardness of the same - also with regard to their problem-free processing - cannot be increased beyond a certain level.
For the production of such an abrasion-resistant protective layer, the application of chemically deposited nickel coatings has already been proposed in the case of metallic casting molds (see, for example, Chapter 14.4.5 on p. 194 of the book "Chemical (electroless) nickel plating" v . C. Cawrilov, Eugen G. Leuze Verlag).
The German Auslegeschrift 2154895 suggests the possibility of using or transferring this method to covering models or casting molds made of epoxy resins.
However, the production of firmly adhering nickel deposits on metal surfaces by chemical deposition could not be achieved with the same success on plastic surfaces to the extent required for the purpose in question.
The object of the invention is to create sufficiently adhesive coatings with careful application of the pretreatment measures otherwise known for the preparation of plastic surfaces, such as chemical roughening, germination and activation.
To solve this problem, the invention proposes that the plastic is a metal powder z. B. of iron, nickel or aluminum.
This measure ensures that during the pickling of the model prior to the deposition, numerous metal particles are exposed on the surface of the model, some of which fall out of the surface and each leave a small crater. The coating layer formed by the precipitate penetrates these craters, whereby an anchoring of the layer is achieved. In addition, the metal particles that have been exposed but remain embedded in the surface facilitate the activation of the precipitate. In this way, a coating is achieved whose adhesive strength is at least equal to that of an equivalent coating on a metal surface.
The hardness or abrasion resistance of the coating layers can be increased further if phosphorus or boron-containing nickel alloy layers are deposited.
EMI1.1
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT152775A AT338447B (en) | 1975-02-27 | 1975-02-27 | FOUNDRY MODEL MADE OF PLASTIC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT152775A AT338447B (en) | 1975-02-27 | 1975-02-27 | FOUNDRY MODEL MADE OF PLASTIC |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ATA152775A ATA152775A (en) | 1976-12-15 |
| AT338447B true AT338447B (en) | 1977-08-25 |
Family
ID=3515489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT152775A AT338447B (en) | 1975-02-27 | 1975-02-27 | FOUNDRY MODEL MADE OF PLASTIC |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT338447B (en) |
-
1975
- 1975-02-27 AT AT152775A patent/AT338447B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ATA152775A (en) | 1976-12-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ELJ | Ceased due to non-payment of the annual fee | ||
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |