AT150283B - Process for the production of gray pig iron from white or mottled pig iron. - Google Patents
Process for the production of gray pig iron from white or mottled pig iron.Info
- Publication number
- AT150283B AT150283B AT150283DA AT150283B AT 150283 B AT150283 B AT 150283B AT 150283D A AT150283D A AT 150283DA AT 150283 B AT150283 B AT 150283B
- Authority
- AT
- Austria
- Prior art keywords
- pig iron
- gray
- white
- production
- mottled
- Prior art date
Links
- 229910000805 Pig iron Inorganic materials 0.000 title claims description 21
- 238000000034 method Methods 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 229910000676 Si alloy Inorganic materials 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 238000010079 rubber tapping Methods 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000005266 casting Methods 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Description
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Verfahren zur Herstellung von grauem Roheisen aus weissem oder meliertem Roheisen.
Bei der Herstellung von Roheisen im Hochofen, das nicht mehr als 0. 6% Si aufweist, erstarrt das Eisen beim Guss in Sand oder offene Kokillen erfahrungsgemäss entweder mit rein weissem, also zementitischem Gefüge oder aber mit einem teils graphitischen, teils zementitischen Mischgefüge.
Es ist nun seit langem bekannt und eisenhüttenmännisches Allgemeingut, weisse Roheisensorten durch sekundäre Erhöhung ihres Si-Gehaltes in die graue, stabile Erstarrungsform überzuführen.
EMI1.1
etwa 1%. Praktisch rein graue Roheisensorten mit wesentlich weniger als 1% Si, insbesondere mit weniger als 0'6% Si und ohne thermische Nachbehandlung (Glühen), sind niemals bekannt geworden. (Vgl. auch die Zusammenstellung bei Osann"Lehrbuch der Eisenhüttenkunde"Band l, Leipzig, W.
Engelmann, 1923, S. 696 und 697.)
Gegenstand der vorliegenden Erfindung bildet nun ein Verfahren, das es ermöglicht, Roheisen mit weniger als 1% Si, ja mit weniger als 0. 6% Si, in praktisch rein grauer graphitisch-perlitischer und/oder ferritischer Struktur herzustellen.
Dies wird dadurch erreicht, dass im Hochofen ein Roheisen hergestellt wird, dessen Si-Gehalt
EMI1.2
in Form von Legierungen, z. B. in Form von Ferrosilizium, zugesetzt wird, der Endgehalt des Si im Roheisen aber 0. 6% nicht übersteigt, also noch weit unterhalb der heute geltenden Grenze für graues Roheisen bleibt.
EMI1.3
erzeugt und in Kokillen oder Sandformen abgestochen. Es ergibt sich stets ein teils weisses, teils graues Mischgefüge. Auf Grund des vorliegenden Verfahrens wird nun ein Roheisen B mit genau den gleichen C-, Mn-, P-, S-usw. Gehalten wie das Roheisen A, jedoch nur mit z. B. 0'2% Si, im Hochofen hergestellt.
Diesem Eisen B wird nun, z. B. in Form von festem Ferrosilizium, eine solche Menge Si zugeführt, dass der Si-Gehalt auf z. B. 0'45% gesteigert wird.
Roheisen A und Roheisen B haben nun also genau die gleiche chemische Zusammensetzung.
Während aber Roheisen A, wie erwähnt, stets teils grau, teils weiss erstarrt, weist das Gefüge von Roheisen B bei vollkommen gleicher Giess-, Kokillen- und/oder Sandtemperatur, überhaupt völlig identischen Giessbedingungen wie beim Roheisen A, ein praktisch rein graues Gefüge auf.
Da für gewisse Arten von hochwertigem Gusseisen ein rein graues Gefüge der Ausgangseisen Vorbedingung ist, in vielen Fällen aber gerade ein niedriger Si-Gehalt gewünscht wird, Forderungen, die bisher praktisch nicht vereinbar waren, so bedeutet das nach dem oben beschriebenen Verfahren erzeugte Roheisen eine wertvolle Bereicherung der Giessereitechnik.
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
<Desc / Clms Page number 1>
Process for the production of gray pig iron from white or mottled pig iron.
During the production of pig iron in a blast furnace, which does not contain more than 0.6% Si, experience has shown that iron solidifies either with a pure white, i.e. cementitic structure or with a partly graphitic, partly cementitic mixed structure when it is cast in sand or open molds.
It has been known for a long time and is common property of the ironworks to convert white pig iron varieties into the gray, stable solidification form by secondary increases in their Si content.
EMI1.1
about 1%. Practically pure gray pig iron types with significantly less than 1% Si, in particular with less than 0.6% Si and without thermal aftertreatment (annealing), have never become known. (See also the compilation in Osann's "Textbook of Metallurgy" Volume 1, Leipzig, W.
Engelmann, 1923, pp. 696 and 697.)
The subject matter of the present invention is a process which makes it possible to produce pig iron with less than 1% Si, even with less than 0.6% Si, in a practically pure gray graphitic-pearlitic and / or ferritic structure.
This is achieved in that a pig iron is produced in the blast furnace whose Si content
EMI1.2
in the form of alloys, e.g. B. in the form of ferrosilicon, is added, but the final content of Si in the pig iron does not exceed 0.6%, so it remains far below the current limit for gray pig iron.
EMI1.3
generated and tapped in molds or sand molds. There is always a partly white, partly gray mixed structure. On the basis of the present method, a pig iron B with exactly the same C, Mn, P, S, etc. Held like pig iron A, but only with z. B. 0'2% Si, produced in a blast furnace.
This iron B is now, for. B. in the form of solid ferrosilicon, such an amount of Si supplied that the Si content on z. B. 0'45% is increased.
Pig iron A and pig iron B now have exactly the same chemical composition.
However, while pig iron A, as mentioned, always solidifies partly gray and partly white, the structure of pig iron B has a practically pure gray structure with completely the same casting, mold and / or sand temperature and completely identical casting conditions as with pig iron A .
Since a purely gray structure of the starting iron is a precondition for certain types of high-quality cast iron, but in many cases a low Si content is desired, requirements that were previously incompatible, the pig iron produced according to the process described above is valuable Enrichment of foundry technology.
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE449594X | 1934-10-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT150283B true AT150283B (en) | 1937-07-26 |
Family
ID=6538293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT150283D AT150283B (en) | 1934-10-12 | 1935-09-04 | Process for the production of gray pig iron from white or mottled pig iron. |
Country Status (2)
| Country | Link |
|---|---|
| AT (1) | AT150283B (en) |
| GB (1) | GB449594A (en) |
-
1935
- 1935-09-04 AT AT150283D patent/AT150283B/en active
- 1935-09-07 GB GB24931/35A patent/GB449594A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB449594A (en) | 1936-06-30 |
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