AR115153A1 - PROCESSES TO PRODUCE BIODERIVED AROMATIC COMPOUNDS AND DERIVED THEREOF - Google Patents

PROCESSES TO PRODUCE BIODERIVED AROMATIC COMPOUNDS AND DERIVED THEREOF

Info

Publication number
AR115153A1
AR115153A1 ARP190101368A ARP190101368A AR115153A1 AR 115153 A1 AR115153 A1 AR 115153A1 AR P190101368 A ARP190101368 A AR P190101368A AR P190101368 A ARP190101368 A AR P190101368A AR 115153 A1 AR115153 A1 AR 115153A1
Authority
AR
Argentina
Prior art keywords
bio
derived
produce
diol
aromatic
Prior art date
Application number
ARP190101368A
Other languages
Spanish (es)
Inventor
Sadesh H Sookraj
Utpal Vakil
Original Assignee
Novomer Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novomer Inc filed Critical Novomer Inc
Publication of AR115153A1 publication Critical patent/AR115153A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Reivindicación 1: Un proceso para obtener un producto de ácido carboxílico aromático bioderivado, caracterizado porque comprende carbonilar un epóxido bioderivado con monóxido de carbono bioderivado para producir una b-lactona bioderivada; reorganizar catalíticamente la b-lactona bioderivada para producir un ácido orgánico insaturado bioderivado; poner en contacto el ácido orgánico insaturado bioderivado con un dieno conjugado bioderivado para producir un ciclohexeno bioderivado intermediario; y transformar el ciclohexeno bioderivado intermediario en el producto de ácido carboxílico aromático bioderivado por deshidroaromatización. Reivindicación 12: Un proceso para producir un copolímero bioderivado a partir de un ácido aromático bioderivado y un diol bioderivado, caracterizado porque comprende mezclar un ácido aromático bioderivado y un diol bioderivado para producir una mezcla de reacción homogénea; esterificar la mezcla de reacción homogénea para producir uno o más ésteres intermediarios; oligomerizar los uno o más ésteres intermediarios para producir uno o más oligómeros; y polimerizar por policondensación los uno o más oligómeros para producir el copolímero bioderivado del ácido aromático bioderivado y el diol bioderivado. Reivindicación 16: Un proceso para obtener un producto copolimérico bioderivado, caracterizado porque comprende los siguientes pasos: producir un ácido carboxílico aromático bioderivado a partir de fuentes de óxido de etileno y monóxido de carbono bioderivado; producir un diol bioderivado a partir de fuentes de óxido de etileno y monóxido de carbono bioderivado; esterificar el ácido carboxílico aromático bioderivado y el diol bioderivado para producir un éster aromático bioderivado intermediario; prepolimerizar el éster aromático bioderivado intermediario para producir un oligómero bioderivado intermediario; polimerizar por policondensación el oligómero bioderivado intermediario para producir el producto copolimérico bioderivado.Claim 1: A process for obtaining a bio-derived aromatic carboxylic acid product, characterized in that it comprises carbonylating a bio-derived epoxide with bio-derived carbon monoxide to produce a bio-derived b-lactone; catalytically rearranging the bio-derived b-lactone to produce a bio-derived unsaturated organic acid; contacting the bio-derived unsaturated organic acid with a bio-derived conjugated diene to produce an intermediate bio-derived cyclohexene; and transforming the intermediate bio-derived cyclohexene into the bio-derived aromatic carboxylic acid product by dehydroaromatization. Claim 12: A process for producing a bio-derived copolymer from a bio-derived aromatic acid and a bio-derived diol, characterized in that it comprises mixing a bio-derived aromatic acid and a bio-derived diol to produce a homogeneous reaction mixture; esterifying the homogeneous reaction mixture to produce one or more intermediate esters; oligomerizing the one or more intermediate esters to produce one or more oligomers; and polycondensation polymerizing the one or more oligomers to produce the bio-derived copolymer of the bio-derived aromatic acid and the bio-derived diol. Claim 16: A process to obtain a bio-derived copolymeric product, characterized in that it comprises the following steps: producing a bio-derived aromatic carboxylic acid from sources of ethylene oxide and bio-derived carbon monoxide; producing a bio-derived diol from sources of ethylene oxide and bio-derived carbon monoxide; esterifying the bio-derived aromatic carboxylic acid and the bio-derived diol to produce an intermediate bio-derived aromatic ester; prepolymerizing the intermediate bio-derived aromatic ester to produce an intermediate bio-derived oligomer; polycondensation polymerizing the intermediate bio-derived oligomer to produce the bio-derived copolymer product.

ARP190101368A 2018-05-22 2019-05-22 PROCESSES TO PRODUCE BIODERIVED AROMATIC COMPOUNDS AND DERIVED THEREOF AR115153A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201862674751P 2018-05-22 2018-05-22

Publications (1)

Publication Number Publication Date
AR115153A1 true AR115153A1 (en) 2020-12-02

Family

ID=68615981

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP190101368A AR115153A1 (en) 2018-05-22 2019-05-22 PROCESSES TO PRODUCE BIODERIVED AROMATIC COMPOUNDS AND DERIVED THEREOF

Country Status (3)

Country Link
AR (1) AR115153A1 (en)
TW (1) TW202003440A (en)
WO (1) WO2019226570A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MA41507A (en) 2015-02-13 2017-12-19 Novomer Inc POLYMER PRODUCTION SYSTEMS AND PROCESSES

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2898386A (en) * 1956-02-06 1959-08-04 Shell Dev Catalytic process for conversion of hydrocarbons in the presence of iodine
JP2005298380A (en) * 2004-04-08 2005-10-27 Daicel Chem Ind Ltd Method for producing aromatic carboxylic acid
US20070203323A1 (en) * 2006-02-10 2007-08-30 Gyorgyi Fenyvesi Food compositions comprising biologically-based biodegradable 1,3-propanediol esters
USH2291H1 (en) * 2011-09-27 2014-05-06 Invista North America S.Ar.L. Polyester polymerization process
SG11201610058QA (en) * 2014-05-30 2016-12-29 Novomer Inc Integrated methods for chemical synthesis

Also Published As

Publication number Publication date
WO2019226570A1 (en) 2019-11-28
TW202003440A (en) 2020-01-16

Similar Documents

Publication Publication Date Title
De Hoe et al. Sustainable polyester elastomers from lactones: synthesis, properties, and enzymatic hydrolyzability
MX2017000880A (en) Catalysts.
de Espinosa et al. Plant oils: The perfect renewable resource for polymer science?!
MX2020000101A (en) Alkoxylated polycarboxylic acid esters.
UA110121C2 (en) Normal;heading 1;heading 2;heading 3;PROCESS FOR THE PRODUCTION OF METHACRYLIC ACID AND ITS DERIVATIVES AND POLYMERS PRODUCED THEREFROM
AR115153A1 (en) PROCESSES TO PRODUCE BIODERIVED AROMATIC COMPOUNDS AND DERIVED THEREOF
MY165638A (en) Lubricant composition of matter and methods of preparation
MY169226A (en) Preparation of biopolyol esters for lubricant application
NZ602429A (en) Branched polyester polymers and coatings comprising the same
DE602007011509D1 (en) Process for the simultaneous production of olefins and diesters or diacids by homometathesis of unsaturated fatty substances in nonaqueous, ionic liquids
WO2013076733A3 (en) A process for synthesis of ethylene polymers
MY195498A (en) Novel method to produce acrylic acid with acetaldehyde as the main by-product
BR112017026515A2 (en) coating composition, substrate and electronic device or electronic component
PH12019550297A1 (en) Process and apparatus for preparing biodegradable polyesters
MX2023007769A (en) Polyester polymer.
WO2016020937A3 (en) Modified polybutylene naphthalate for improved performance and process of making thereof
Wang et al. Making Polyisoprene Self‐Healable through Microstructure Regulation by Rare‐Earth Catalysts
BR112018013948A2 (en) process for producing low gel functionalized ethylene polymers
MX2020013136A (en) Lubricating base oils from esterified alkoxylated polyols using saturated long-chain fatty acids.
BR112022020891A2 (en) BIODEGRADABLE POLYMER COMPOSITION FOR THE PRODUCTION OF MOLDED ARTICLES
MY165885A (en) A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom
MY172657A (en) Branched broad mwd conjugated diene polymer
MY167073A (en) Method for producing polyester
WO2017053652A8 (en) Boron-based cycloaddition catalysts and methods for the production of bio-based terephthalic acid, isophthalic acid and poly (ethylene terephthalate)
AR117356A1 (en) METHODS FOR PRODUCING C₂ TO C₅ PARAFFINS USING A HYBRID CATALYST INCLUDING GALLIUM METAL OXIDE

Legal Events

Date Code Title Description
FB Suspension of granting procedure