AR102574A1 - IONIC LIQUID COMPOUND TRANSALQUILATION PROCESS - Google Patents

IONIC LIQUID COMPOUND TRANSALQUILATION PROCESS

Info

Publication number
AR102574A1
AR102574A1 ARP150103625A ARP150103625A AR102574A1 AR 102574 A1 AR102574 A1 AR 102574A1 AR P150103625 A ARP150103625 A AR P150103625A AR P150103625 A ARP150103625 A AR P150103625A AR 102574 A1 AR102574 A1 AR 102574A1
Authority
AR
Argentina
Prior art keywords
compound
ionic liquid
varies
integer
liquid compound
Prior art date
Application number
ARP150103625A
Other languages
Spanish (es)
Inventor
Uppara Parasuveera
Dhawade Rahul
Suresh Iyengar B
Kumar Aduri Pavan
Sakhalkar Mangesh
Kotra Viswanath
Original Assignee
Reliance Ind Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reliance Ind Ltd filed Critical Reliance Ind Ltd
Publication of AR102574A1 publication Critical patent/AR102574A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0279—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the cationic portion being acyclic or nitrogen being a substituent on a ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La presente revelación se refiere a un proceso de transalquilación para la conversión de compuestos aromáticos pesados en un compuesto alquilaromático liviano usando sal líquida, tales como, pero sin limitación, compuesto líquido iónico. En otra forma de realización, el compuesto líquido iónico es una amina y compuesto líquido iónico a base de sal metálica. La presente descripción también se refiere a un sistema para el proceso de transalquilación en presencia del compuesto líquido iónico. Reivindicación 1: Un proceso de transalquilación para convertir un compuesto aromático pesado en un compuesto alquilaromático liviano, donde dicho proceso comprende una etapa de puesta en contacto de una mezcla que comprende un compuesto aromático pesado y un compuesto aromático no sustituido o un compuesto aromático sustituido de metilo con compuesto líquido iónico de la fórmula (1): -[(NR¹R²R³)ⁱM¹]ⁿ⁺[(M²Yₖ)LXʲ]ⁿ⁻ (1) en donde NR¹R²R³ es amina; R¹, R² y R³ se seleccionan, de modo independiente, de un grupo que comprende alquilo, arilo y H o cualquiera de sus combinaciones, en donde R¹ = R² = R³ o R¹ = R² ¹ R³ o R¹ = R³ ¹ R² o R³ = R² ¹ R¹; M¹ y M² son, de modo independiente, metales seleccionados de un grupo que comprende Al, Fe, Zn, Mn, Mg, Ti, Sn, Pd, Pt, Rh, Cu, Cr, Co, Ce, Ni, Ga, In, Sb y Zr o cualquiera de sus combinaciones; X e Y se seleccionan, de modo independiente, de un grupo que comprende ión, haluro, nitrato, sulfato, sulfonato, carbonato, fosfonato citrato, ión cianuro, nitrito, fosfato y acetato o cualquiera de sus combinaciones; n es un número entero que varía de aproximadamente 1 a 4; i es un número entero que varía de aproximadamente 1 a 6; j es un número entero que varía de aproximadamente 1 a 4; k es un número entero que varía de aproximadamente 1 a 4; L es un número entero que varía de aproximadamente 1 a 7; M¹ = M² o M¹ ¹ M² y X = Y o X ¹ Y para obtener el compuesto alquilaromático liviano.The present disclosure relates to a transalkylation process for the conversion of heavy aromatic compounds into a light alkylaromatic compound using liquid salt, such as, but not limited to, ionic liquid compound. In another embodiment, the ionic liquid compound is an amine and ionic liquid compound based on metal salt. The present description also refers to a system for the transalkylation process in the presence of the ionic liquid compound. Claim 1: A transalkylation process for converting a heavy aromatic compound into a light alkylaromatic compound, wherein said process comprises a step of contacting a mixture comprising a heavy aromatic compound and an unsubstituted aromatic compound or a substituted aromatic compound of methyl with ionic liquid compound of the formula (1): - [(NR¹R²R³) ⁱM¹] ⁿ⁺ [(M²Yₖ) LXʲ] ⁿ⁻ (1) wherein NR¹R²R³ is amine; R¹, R² and R³ are independently selected from a group comprising alkyl, aryl and H or any combination thereof, wherein R¹ = R² = R³ or R¹ = R² ¹ R³ or R¹ = R³ ¹ R² or R³ = R² ¹ R¹; M¹ and M² are independently selected metals from a group comprising Al, Fe, Zn, Mn, Mg, Ti, Sn, Pd, Pt, Rh, Cu, Cr, Co, Ce, Ni, Ga, In, Sb and Zr or any of their combinations; X and Y are independently selected from a group comprising ion, halide, nitrate, sulfate, sulphonate, carbonate, phosphonate citrate, cyanide ion, nitrite, phosphate and acetate or any combination thereof; n is an integer that varies from about 1 to 4; i is an integer that varies from about 1 to 6; j is an integer that varies from about 1 to 4; k is an integer that varies from about 1 to 4; L is an integer that varies from about 1 to 7; M¹ = M² or M¹ ¹ M² and X = Y or X ¹ Y to obtain the lightweight alkylaromatic compound.

ARP150103625A 2014-11-07 2015-11-06 IONIC LIQUID COMPOUND TRANSALQUILATION PROCESS AR102574A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IN2551MU2014 2014-11-07

Publications (1)

Publication Number Publication Date
AR102574A1 true AR102574A1 (en) 2017-03-08

Family

ID=55024175

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP150103625A AR102574A1 (en) 2014-11-07 2015-11-06 IONIC LIQUID COMPOUND TRANSALQUILATION PROCESS

Country Status (3)

Country Link
AR (1) AR102574A1 (en)
TW (1) TW201623195A (en)
WO (1) WO2016071871A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020121154A1 (en) * 2018-12-09 2020-06-18 Reliance Industries Limited Process for preparing linear alkyl benzene

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2222632A (en) 1938-10-08 1940-11-26 Socony Vacuum Oil Co Inc Dealkylation process
US3385906A (en) 1965-05-25 1968-05-28 Union Carbide Corp Production of cumene
US3410921A (en) 1966-06-27 1968-11-12 Universal Oil Prod Co Transalkylation of polyalkylated aromatic compounds using a crystalline aluminosilicate catalyst
GB1190592A (en) 1967-02-07 1970-05-06 Rank Organisation Ltd Blanking Circuit.
US3769360A (en) 1971-04-09 1973-10-30 Gulf Research Development Co Process for transalkylating diethyl benzene
US3843739A (en) 1971-04-09 1974-10-22 Gulf Research Development Co Process for transalkylating diethyl benzene
US3776971A (en) 1971-08-13 1973-12-04 Gulf Research Development Co Process for preparing a monoalkyl aromatic
US3778415A (en) 1971-08-13 1973-12-11 Gulf Research Development Co Process for preparing a monoalkyl aromatic
US3751504A (en) 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US4459426A (en) 1980-04-25 1984-07-10 Union Oil Company Of California Liquid-phase alkylation and transalkylation process
US4599470A (en) 1982-11-18 1986-07-08 The British Petroleum Company P.L.C. Process for the transalkylation or dealkylation of alkyl aromatic hydrocarbons
US4885426A (en) 1987-09-02 1989-12-05 Mobil Oil Corporation Transalkylation of polyaromatics
US4774377A (en) 1987-09-11 1988-09-27 Uop Inc. Alkylation/transalkylation process
US4891458A (en) 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US5157180A (en) 1989-05-26 1992-10-20 Union Oil Company Of California Alkylation and transalkylation processes
AU1672100A (en) * 1999-01-15 2000-08-01 Bp Chemicals Limited Ionic liquid catalyst for alkylation
EP1358141B8 (en) 2001-02-07 2008-02-13 ExxonMobil Chemical Patents Inc. Production of alkylaromatic compounds
US6740788B1 (en) 2002-12-19 2004-05-25 Uop Llc Integrated process for aromatics production
CN101020619B (en) * 2006-02-13 2011-09-14 黑龙江大学 Ionic liquid catalyzed transalkylation process for preparing 2,6-dimethyl naphthalene
US8148592B2 (en) 2006-05-08 2012-04-03 Cepsa Quimica, S.A. Catalytic transalkylation of dialkyl benzenes
US7414163B1 (en) 2006-07-28 2008-08-19 Uop Llc Iridium and germanium-containing catalysts and alkylaromatic transalkylation processes using such catalysts
US7566810B2 (en) 2006-09-12 2009-07-28 Uop Llc Xylene production processes employing rhenium-containing catalysts
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WO2014178075A2 (en) * 2013-04-19 2014-11-06 Reliance Industries Limited Ionic liquid compound

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Publication number Publication date
TW201623195A (en) 2016-07-01
WO2016071871A1 (en) 2016-05-12

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