AR098419A1 - COMPOUNDS DERIVED FROM PIRAZOL AS PESTICIDES - Google Patents

COMPOUNDS DERIVED FROM PIRAZOL AS PESTICIDES

Info

Publication number
AR098419A1
AR098419A1 ARP140104283A ARP140104283A AR098419A1 AR 098419 A1 AR098419 A1 AR 098419A1 AR P140104283 A ARP140104283 A AR P140104283A AR P140104283 A ARP140104283 A AR P140104283A AR 098419 A1 AR098419 A1 AR 098419A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
halo
halocycloalkyl
haloalkoxy
Prior art date
Application number
ARP140104283A
Other languages
Spanish (es)
Inventor
Dr Velten Robert
Dr Bhnke Niels
Werner Stefan
Dr Horstmann Sebastian
Dr Becker Angela
Dr Ilg Kerstin
Dr Portz Daniela
Dr Voerste Arnd
Grgens Ulrich
Dr Turberg Andreas
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of AR098419A1 publication Critical patent/AR098419A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom

Abstract

La presente solicitud se refiere a compuestos insecticidas, a procedimientos para su preparación, a su uso para el control de plagas de animales que incluyen artrópodos y en particular insectos. Reivindicación 1: Compuestos de fórmula (1) en la que A representa alquilo C₁₋₄, cicloalquilo C₃₋₆, haloalquilo C₁₋₄ o halocicloalquilo C₃₋₆, preferentemente metilo; R¹ representa 1-pirazolilo mono o disustituido en el que por lo menos un sustituyente está en la posición 4 del 1-pirazolilo y en el que un sustituyente es seleccionado de forma independiente del grupo que consiste en halo, ciano, alquilo C₁₋₄, cicloalquilo C₃₋₆, alcoxi C₁₋₄, haloalquilo C₁₋₄ halocicloalquilo C₃₋₆, o haloalcoxi C₁₋₄; n representa 0, 1, 2, 3, 4 ó 5; preferentemente 1, 2 ó 3; R² representa de forma independiente halo, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, tioalquilo C₁₋₄, halotioalquilo C₁₋₄, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, ciano, nitro, -CO(O)-alquilo C₁₋₄, -alquilo C₁₋₄-C(O)O-alquilo C₁₋₄, -alquilo C₁₋₄-C(O)O-haloalquilo C₁₋₄, -haloalquilo C₁₋₄-C(O)O-alquilo C₁₋₄, o -haloalquilo C₁₋₄-C(O)O-haloalquilo C₁₋₄; o dos R² en posiciones anulares adyacentes del anillo de fenilo de la estructura básica pueden formar junto con dichas dos posiciones anulares adyacentes un sistema carbocíclico o heterocíclico de 5 ó 6 miembros sustituido con halo de forma opcional; m representa 0, 1, 2, 3, 4 ó 5; preferentemente 0, 1, 2 ó 3, más preferentemente 1 ó 2; R³ representa de forma independiente halo, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, tioalquilo C₁₋₄, halotioalquilo C₁₋₄, cicloalquilo C₃₋₆, halocicloalquilo C₃₋₆, ciano, nitro, -CO(O)-alquilo C₁₋₄, -alquilo C₁₋₄-C(O)O-alquilo C₁₋₄, -alquilo C₁₋₄-C(O)O-haloalquilo C₁₋₄, -haloalquilo C₁₋₄-C(O)O-alquilo C₁₋₄, o -haloalquilo C₁₋₄-C(O)O-haloalquilo C₁₋₄; o dos R³ en posiciones anulares adyacentes del anillo de fenilo de la estructura básica pueden formar junto con dichas dos posiciones anulares adyacentes un sistema carbocíclico o heterocíclico de 5 ó 6 miembros sustituido con halo de forma opcional; R⁴ representa hidroxilo, halo, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄, haloalcoxi C₁₋₄, tioalquilo C₁₋₄, halotioalquilo C₁₋₄,O-acilo C₂₋₅, u O-haloacilo C₂₋₅; y sales, N-óxidos y formas tautoméricas de los compuestos de fórmula (1). Reivindicación 14: Un compuesto de acuerdo a la fórmula (2) en la que R³, R⁵ y m son como se ha definido en una cualquiera de las reivindicaciones 1 a 6.The present application relates to insecticidal compounds, processes for their preparation, their use for the control of pests of animals that include arthropods and in particular insects. Claim 1: Compounds of formula (1) wherein A represents C₁₋₄ alkyl, C₃₋₆ cycloalkyl, C₁₋₄ haloalkyl or C₃₋₆ halocycloalkyl, preferably methyl; R¹ represents mono or disubstituted 1-pyrazolyl in which at least one substituent is in the 4-position of the 1-pyrazolyl and in which a substituent is independently selected from the group consisting of halo, cyano, C₁₋₄ alkyl, C₃₋₆ cycloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkyl C₃₋₆ halocycloalkyl, or C₁₋₄ haloalkoxy; n represents 0, 1, 2, 3, 4 or 5; preferably 1, 2 or 3; R² independently represents halo, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄ thioalkyl, C₁₋₄ halothioalkyl, C₃₋₆ cycloalkyl, C₃₋₆ halocycloalkyl, cyano, nitro , -CO (O) -C₁₋₄ alkyl, -C₁₋₄-C alkyl (O) O-C₁₋₄ alkyl, -C₁₋₄-C (O) alkyl O-C₁₋₄ haloalkyl, -C₁₋ alkyl halo ₄-C (O) O-C₁₋₄ alkyl, or -haloalkyl C₁₋₄-C (O) O-haloalkyl C₁₋₄; or two R² at adjacent annular positions of the phenyl ring of the basic structure can form together with said two adjacent annular positions a 5 or 6-membered carbocyclic or heterocyclic system substituted by halo optionally; m represents 0, 1, 2, 3, 4 or 5; preferably 0, 1, 2 or 3, more preferably 1 or 2; R³ independently represents halo, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄ thioalkyl, C₁₋₄ halothioalkyl, C₃₋₆ cycloalkyl, C₃₋₆ halocycloalkyl, cyano, nitro , -CO (O) -C₁₋₄ alkyl, -C₁₋₄-C alkyl (O) O-C₁₋₄ alkyl, -C₁₋₄-C (O) alkyl O-C₁₋₄ haloalkyl, -C₁₋ alkyl halo ₄-C (O) O-C₁₋₄ alkyl, or -haloalkyl C₁₋₄-C (O) O-haloalkyl C₁₋₄; or two R³ at adjacent annular positions of the phenyl ring of the basic structure may together with said two adjacent annular positions a 5 or 6-membered carbocyclic or heterocyclic system substituted by halo optionally; R⁴ represents hydroxyl, halo, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₁₋₄ thioalkyl, C₁₋₄ halothioalkyl, C₂₋₅ O-acyl, or C₂₋₅ O-haloacyl ; and salts, N-oxides and tautomeric forms of the compounds of formula (1). Claim 14: A compound according to formula (2) wherein R³, R⁵ and m are as defined in any one of claims 1 to 6.

ARP140104283A 2013-11-14 2014-11-14 COMPOUNDS DERIVED FROM PIRAZOL AS PESTICIDES AR098419A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP13192878 2013-11-14

Publications (1)

Publication Number Publication Date
AR098419A1 true AR098419A1 (en) 2016-05-26

Family

ID=49582630

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP140104283A AR098419A1 (en) 2013-11-14 2014-11-14 COMPOUNDS DERIVED FROM PIRAZOL AS PESTICIDES

Country Status (4)

Country Link
AR (1) AR098419A1 (en)
TW (1) TW201609660A (en)
UY (1) UY35837A (en)
WO (1) WO2015071260A1 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2156807A (en) * 1984-04-05 1985-10-16 Ici Plc Azolyl propanols
DE4303658A1 (en) * 1993-02-09 1994-08-11 Bayer Ag Substituted tetrahydropyridazinecarboxamides
JPH07138233A (en) * 1993-11-12 1995-05-30 Ishihara Sangyo Kaisha Ltd Hydrazone-based compound or its salt, production therefor and pest control agent containing the same as the active component

Also Published As

Publication number Publication date
TW201609660A (en) 2016-03-16
WO2015071260A1 (en) 2015-05-21
UY35837A (en) 2015-06-30

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