AR094325A1 - A POLYMERIZATION PROCESS TO PRODUCE ETHYLENE-BASED POLYMERS - Google Patents

A POLYMERIZATION PROCESS TO PRODUCE ETHYLENE-BASED POLYMERS

Info

Publication number
AR094325A1
AR094325A1 ARP130105082A ARP130105082A AR094325A1 AR 094325 A1 AR094325 A1 AR 094325A1 AR P130105082 A ARP130105082 A AR P130105082A AR P130105082 A ARP130105082 A AR P130105082A AR 094325 A1 AR094325 A1 AR 094325A1
Authority
AR
Argentina
Prior art keywords
based polymers
polymerization process
produce ethylene
ethylene
optionally
Prior art date
Application number
ARP130105082A
Other languages
Spanish (es)
Inventor
Demirors Mehmet
Figueroa Ruth
Klosin Jerzy
J Thomas Pulikkottil
Desjardins Sylvie
Kapur Mridula
P Fontaine Philip
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of AR094325A1 publication Critical patent/AR094325A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168Tetra- or multi-dentate ligand
    • C08F4/64186Dianionic ligand
    • C08F4/64189ONNO
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168Tetra- or multi-dentate ligand
    • C08F4/64186Dianionic ligand
    • C08F4/64193OOOO
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/60003Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/60168Tetra- or multi-dentate ligand
    • C08F4/60186Dianionic ligand
    • C08F4/60193OOOO
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La presente proporciona un proceso de polimerización para producir polímeros a base de etileno. En una forma de realización, la presente proporciona un proceso de polimerización para producir polímeros a base de etileno que comprende la polimerización de etileno con opcionalmente una o más a-olefinas en presencia de uno o más primeros sistemas catalizadores y opcionalmente uno o más segundos sistemas catalizadores en un sistema de reactores duales o un sistema de reactores múltiples, en donde el primer sistema catalizador comprende; (a) uno o más procatalizadores que comprenden un complejo de metal-ligando de la fórmula (1).This provides a polymerization process to produce ethylene-based polymers. In one embodiment, the present provides a polymerization process to produce ethylene-based polymers comprising the polymerization of ethylene with optionally one or more a-olefins in the presence of one or more first catalyst systems and optionally one or more second systems catalysts in a dual reactor system or a multiple reactor system, wherein the first catalyst system comprises; (a) one or more procatalysts comprising a metal-ligand complex of the formula (1).

ARP130105082A 2012-12-27 2013-12-27 A POLYMERIZATION PROCESS TO PRODUCE ETHYLENE-BASED POLYMERS AR094325A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201261746218P 2012-12-27 2012-12-27

Publications (1)

Publication Number Publication Date
AR094325A1 true AR094325A1 (en) 2015-07-29

Family

ID=49877056

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP130105082A AR094325A1 (en) 2012-12-27 2013-12-27 A POLYMERIZATION PROCESS TO PRODUCE ETHYLENE-BASED POLYMERS

Country Status (10)

Country Link
US (2) US9527940B2 (en)
EP (1) EP2938648B1 (en)
JP (1) JP6348912B2 (en)
KR (2) KR102251151B1 (en)
CN (1) CN104884485B (en)
AR (1) AR094325A1 (en)
BR (1) BR112015015548B1 (en)
ES (1) ES2720207T3 (en)
SG (1) SG11201505073SA (en)
WO (1) WO2014105414A1 (en)

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Also Published As

Publication number Publication date
CN104884485A (en) 2015-09-02
JP2016506445A (en) 2016-03-03
EP2938648A1 (en) 2015-11-04
BR112015015548A2 (en) 2017-07-11
SG11201505073SA (en) 2015-07-30
KR20200062375A (en) 2020-06-03
CN104884485B (en) 2017-11-21
ES2720207T3 (en) 2019-07-18
US10059787B2 (en) 2018-08-28
WO2014105414A1 (en) 2014-07-03
KR20150100845A (en) 2015-09-02
BR112015015548B1 (en) 2021-05-18
US20170066858A1 (en) 2017-03-09
KR102251151B1 (en) 2021-05-13
US9527940B2 (en) 2016-12-27
JP6348912B2 (en) 2018-06-27
US20150344602A1 (en) 2015-12-03
EP2938648B1 (en) 2019-01-30

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