AR086718A1 - DERIVATIVE OF 3-ARYLFENYL SULFIDE AND ITS USE AS A PESTICIDE - Google Patents
DERIVATIVE OF 3-ARYLFENYL SULFIDE AND ITS USE AS A PESTICIDEInfo
- Publication number
- AR086718A1 AR086718A1 ARP120102239A ARP120102239A AR086718A1 AR 086718 A1 AR086718 A1 AR 086718A1 AR P120102239 A ARP120102239 A AR P120102239A AR P120102239 A ARP120102239 A AR P120102239A AR 086718 A1 AR086718 A1 AR 086718A1
- Authority
- AR
- Argentina
- Prior art keywords
- atom
- different
- same
- substituted
- alkyl
- Prior art date
Links
- 239000000575 pesticide Substances 0.000 title abstract 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 13
- 229910052757 nitrogen Inorganic materials 0.000 abstract 7
- 125000000217 alkyl group Chemical group 0.000 abstract 6
- 125000001188 haloalkyl group Chemical group 0.000 abstract 5
- 229910052736 halogen Inorganic materials 0.000 abstract 4
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 4
- 229910052717 sulfur Inorganic materials 0.000 abstract 4
- 125000004434 sulfur atom Chemical group 0.000 abstract 4
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- 101100440695 Dictyostelium discoideum corB gene Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 2
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000004440 haloalkylsulfinyl group Chemical group 0.000 abstract 1
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 abstract 1
- 125000004995 haloalkylthio group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000004076 pyridyl group Chemical group 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C323/01—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton
- C07C323/09—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton having sulfur atoms of thio groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
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- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/14—Ethers
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- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
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- A01N33/18—Nitro compounds
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
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- C07D285/01—Five-membered rings
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- C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
- C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
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Abstract
La proporción de un pesticida. La presente proporciona un compuesto representado por la fórmula (1) o su sal, y un pesticida que lo contiene como ingrediente activo.Reivindicación 1: Un compuesto representado por la fórmula (1) o su sal, donde cada uno de R1 y R2 que son independientes entre sí, es un átomo de hidrógeno, un átomo de halógeno, alquilo, haloalquilo, alcoxi, haloalcoxi o ciano; R3 es alquilo o haloalquilo; n es un número entero de 0 ó 1; y es Q cualquiera de las fórmulas [Q-1] a [Q-6], donde cada uno de A1 a A8 que pueden ser iguales o diferentes entre sí, es CH o un átomo de nitrógeno, siempre que cuando cualquiera de A1 a A8 sea CH, éste pueda estar sustituido con R4, y entre A1 a A8, el número de grupos que pueden ser átomos de nitrógeno, es de 0 a 3; cada uno de B1 a B4 que pueden ser iguales o diferentes entre sí, es CH o un átomo de nitrógeno, siempre que cuando cualquiera de B1 a B4 sea CH, éste pueda estar sustituido con R4, y entre B1 a B4, el número de grupos que pueden ser átomos de nitrógeno, es de 0 a 1; cada uno de B5 a B7 que pueden ser iguales o diferentes entre sí, es C(R5)(R6), un átomo de oxígeno, un átomo de azufre, SO o SO2; cada uno de E1 a E4 que pueden ser iguales o diferentes entre sí, es CH o un átomo de nitrógeno, siempre que cuando cualquiera de E1 a E4 sea CH, éste pueda estar sustituido con R4, y entre E1 a E4, el número de grupos que pueden ser átomos de nitrógeno, es de 0 a 1; cada uno de E5 a E8 que pueden ser iguales o diferentes entre sí, es C(R5)(R6), un átomo de oxígeno, un átomo de azufre, SO o SO2; cada uno de G1 a G5 y G7 que pueden ser iguales o diferentes entre sí, es CH o un átomo de nitrógeno, siempre que cuando cualquiera de G1 a G5 y G7 es CH, éste pueda estar sustituido con R4, y entre G1 a G5 y G7, el número de grupos que pueden ser átomos de nitrógeno, es de 0 a 3; G6 es un átomo de oxígeno o un átomo de azufre; cada uno de J1 a J6 que pueden ser iguales o diferentes entre sí, es CH o un átomo de nitrógeno, siempre que cuando cualquiera de J1 a J6 es CH, éste puede estar sustituido con R4, y entre J1 a J6, el número de grupos que pueden ser átomos de nitrógeno es de 0 a 2; cada uno de L1 a L5 que pueden ser iguales o diferentes entre sí, es CH o un átomo de nitrógeno, siempre que cuando cualquiera de L1 a L5 es CH, éste puede estar sustituido con R4, y entre L1 a L5, el número de grupos que pueden ser átomos de nitrógeno, es de 0 a 2; L6 es un átomo de oxígeno o un átomo de azufre; R4 es un átomo de halógeno, alquilo, haloalquilo, alcoxi, haloalcoxi, ciano, nitro, COR7, CO2R7, N(R8)COR7, N(R8)CO2R7, NR9R10, CONR9R10, alquiltio, haloalquiltio, alquilsulfinilo, haloalquilsulfinilo, alquilsulfonilo, haloalquilsulfonilo, fenilo que puede estar sustituido con R11, o piridilo que puede estar sustituido con R11, a condición de que cuando el número de R4 sea dos o más, la pluralidad de R4 puede ser igual o diferente, cada uno de R5 y R6, que son independientes entre sí, es un átomo de hidrógeno, un átomo de halógeno, alquilo o haloalquilo, a condición de que cuando el número de R5 o R6 sea dos o más, la pluralidad de R5 o R6 puede ser igual o diferente, cada uno de R7, R8, R9 y R10 que son independientes entre sí, es un átomo de hidrógeno o alquilo; cuando R9 y R10 son alquilo, R9 y R10 pueden, junto con el átomo de nitrógeno al que están unidos, formar un anillo de 5 ó 6 miembros; y R11 es un átomo de halógeno, alquilo, haloalquilo, alcoxi o haloalcoxi.The proportion of a pesticide. This provides a compound represented by the formula (1) or its salt, and a pesticide containing it as an active ingredient. Claim 1: A compound represented by the formula (1) or its salt, wherein each of R1 and R2 which they are independent of each other, it is a hydrogen atom, a halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or cyano atom; R3 is alkyl or haloalkyl; n is an integer of 0 or 1; and is Q any of the formulas [Q-1] to [Q-6], where each of A1 to A8 that may be the same or different from each other, is CH or a nitrogen atom, provided that when any of A1 to A8 be CH, this may be substituted with R4, and between A1 to A8, the number of groups that can be nitrogen atoms is 0 to 3; each of B1 to B4 that may be the same or different from each other, is CH or a nitrogen atom, provided that any one of B1 to B4 is CH, it may be substituted with R4, and between B1 to B4, the number of groups that can be nitrogen atoms, is 0 to 1; each of B5 to B7 that may be the same or different from each other, is C (R5) (R6), an oxygen atom, a sulfur atom, SO or SO2; each of E1 to E4 that may be the same or different from each other, is CH or a nitrogen atom, provided that any one of E1 to E4 is CH, it may be substituted with R4, and between E1 to E4, the number of groups that can be nitrogen atoms, is 0 to 1; each of E5 to E8 that may be the same or different from each other, is C (R5) (R6), an oxygen atom, a sulfur atom, SO or SO2; each of G1 to G5 and G7 which may be the same or different from each other, is CH or a nitrogen atom, provided that any one of G1 to G5 and G7 is CH, it may be substituted with R4, and between G1 to G5 and G7, the number of groups that can be nitrogen atoms, is 0 to 3; G6 is an oxygen atom or a sulfur atom; each of J1 to J6 that may be the same or different from each other, is CH or a nitrogen atom, provided that when any of J1 to J6 is CH, it may be substituted with R4, and between J1 to J6, the number of groups that can be nitrogen atoms is from 0 to 2; each of L1 to L5 which may be the same or different from each other, is CH or a nitrogen atom, provided that when any of L1 to L5 is CH, it may be substituted with R4, and between L1 to L5, the number of groups that can be nitrogen atoms, is from 0 to 2; L6 is an oxygen atom or a sulfur atom; R4 is a halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, cyano, nitro, COR7, CO2R7, N (R8) COR7, N (R8) CO2R7, NR9R10, CONR9R10, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, haloalkyl , phenyl which may be substituted with R11, or pyridyl which may be substituted with R11, provided that when the number of R4 is two or more, the plurality of R4 may be the same or different, each of R5 and R6, which they are independent of each other, it is a hydrogen atom, a halogen, alkyl or haloalkyl atom, provided that when the number of R5 or R6 is two or more, the plurality of R5 or R6 can be the same or different, each of R7, R8, R9 and R10 which are independent of each other, is a hydrogen or alkyl atom; when R9 and R10 are alkyl, R9 and R10 can, together with the nitrogen atom to which they are attached, form a 5- or 6-membered ring; and R11 is a halogen, alkyl, haloalkyl, alkoxy or haloalkoxy atom.
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