AR083456A1 - PIRIMIDINE COMPOUND AND ITS USE FOR PEST CONTROL - Google Patents

PIRIMIDINE COMPOUND AND ITS USE FOR PEST CONTROL

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Publication number
AR083456A1
AR083456A1 ARP110103820A AR083456A1 AR 083456 A1 AR083456 A1 AR 083456A1 AR P110103820 A ARP110103820 A AR P110103820A AR 083456 A1 AR083456 A1 AR 083456A1
Authority
AR
Argentina
Prior art keywords
group
optionally substituted
halogens
group optionally
alkyl
Prior art date
Application number
Other languages
Spanish (es)
Inventor
Yoshihiko Nokura
Hiroshi Ikegami
Hiroki Tomioka
Daisuke Takaoka
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Publication of AR083456A1 publication Critical patent/AR083456A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Que tiene una excelente actividad de control de plagas.Reivindicación 1: Un compuesto de pirimidina de la fórmula (1), caracterizado porque R1 es grupo hidrocarbonado de cadena C1-3 opcionalmente sustituido con uno o varios halógenos, hidrógeno, halógeno, o grupo amino; R2 es grupo hidrocarbonado de cadena C1-3 opcionalmente sustituido con uno o varios halógenos, hidrógeno, halógeno, grupo hidroxi, grupo mercapto o grupo amino; G1 es nitrógeno o -CR5=, en donde R5 es grupo hidrocarbonato de cadena C1-3 opcionalmente sustituido con uno o varios halógenos, hidrógeno, halógeno o grupo amino; R3 es grupo hidrocarbonado de cadena C1-3 opcionalmente sustituido con uno o varios halógenos, hidrógeno, halógeno, grupo amino, grupo nitro o grupo ciano; R4 es grupo hidrocarbonado de cadena C1-6 opcionalmente sustituido con uno o varios halógenos, grupo cicloalquilo C3-8 opcionalmente sustituido con uno o varios halógenos, grupo alcoxi C1-6 opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-tio opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-sulfinilo opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-sulfonilo opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-amino opcionalmente sustituido con uno o varios halógenos, grupo dialquil C2-8-amino opcionalmente sustituido con uno o varios halógenos, grupo alquil C2-6-carbonilamino opcionalmente sustituido con uno o varios halógenos, grupo alcoxi C2-6-carbonilamino opcionalmente sustituido con uno o varios halógenos, grupo alquil C2-6-carbonilo opcionalmente sustituido con uno o varios halógenos, grupo alcoxi C2-6-carbonilo opcionalmente sustituido con uno o varios halógenos, grupo alquil C2-6-carbamoilo opcionalmente sustituido con uno o varios halógenos, grupo dialquil C2-8-carbamoilo opcionalmente sustituido con uno o varios halógenos, grupo fenilo opcionalmente sustituido con uno o varios átomos o grupos seleccionados del siguiente grupo a, grupo heterocíclico aromático de 5 a 6 miembros opcionalmente sustituido con uno o varios átomos o grupos seleccionados del siguiente grupo a, hidrógeno, halógeno, grupo hidroxi, grupo mercapto, grupo amino, grupo nitro, grupo ciano o grupo formilo; Q es oxígeno o -S(O)r-, en donde r es 0, 1 ó 2; Cyc es grupo heterocíclico saturado de 3 a 8 miembros que contiene un átomo o grupo seleccionado del grupo que consiste en oxígeno, -S(=O)n- y -NR6- como un componente del anillo, en donde n es 0, 1 ó 2 y R6 es grupo hidrocarbonado de cadena C1-6 opcionalmente sustituido con uno o varios halógenos, grupo alquil C2-6-carbonilo opcionalmente sustituido con uno o varios halógenos, grupo alcoxi C2-6-carbonilo opcionalmente sustituido con uno o varios halógenos o hidrógeno; grupo heterocíclico saturado de 5 a 8 miembros que contiene dos átomos o grupos seleccionados del grupo que consiste en oxígeno, -S(=O)n- y -NR6- como un componente del anillo, en donde n y R6 son como se definieron con anterioridad, siempre que los dos átomos o grupos no sean adyacentes entre sí; grupo cicloalquilo C3-8; o grupo cicloalquenilo C5-8, cualquiera de los grupos definidos como Cyc puede estar opcionalmente sustituido con uno o varios átomos o grupos seleccionados, de modo independiente, de los siguientes grupos b1 a b3, siempre que, cuando uno o varios grupos están seleccionados del grupo b2, cada grupo seleccionado del grupo b2 está unido al mismo átomo de carbono del anillo definido como Cyc y cuando uno o varios grupos están seleccionados del grupo b3, cada grupo seleccionado del grupo b3 está unido a dos átomos de carbono adyacentes del anillo definido como Cyc; A es un enlace simple, grupo metileno opcionalmente sustituido con uno o varios átomos o grupos seleccionados del grupo que consiste en grupo alquilo C1-3 y halógeno o grupo etileno opcionalmente sustituido con uno o varios átomos o grupos seleccionados del grupo que consiste en grupo alquilo C1-3 y halógeno y A está unido al átomo de carbono del anillo definido como Cyc; el grupo a consiste en grupo hidrocarbonado de cadena C1-6 opcionalmente sustituido con uno o varios halógenos, grupo alcoxi C1-6 opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-tio opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-sulfinilo opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-sulfonilo opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-amino opcionalmente sustituido con uno o varios halógenos, grupo dialquil C2-8-amino opcionalmente sustituido con uno o varios halógenos, halógeno, grupo hidroxi, grupo mercapto, grupo amino, grupo ciano y grupo nitro; el grupo b1 consiste en grupo hidrocarbonado de cadena C1-6 opcionalmente sustituido con uno o varios halógenos, grupo alcoxi C1-6 opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-tio opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-sulfinilo opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-sulfonilo opcionalmente sustituido con uno o varios halógenos, grupo alquil C1-6-amino opcionalmente sustituido con uno o varios halógenos, grupo dialquil C2-8-amino opcionalmente sustituido con uno o varios halógenos, grupo alquil C2-6-carbonilamino opcionalmente sustituido con uno o varios halógenos, grupo alcoxi C2-6-carbonilamino opcionalmente sustituido con uno o varios halógenos, grupo alquil C2-6-carbonilo opcionalmente sustituido con uno o varios halógenos, grupo alcoxi C2-6-carbonilo opcionalmente sustituido con uno o varios halógenos, grupo alquil C2-6-carbamoilo opcionalmente sustituido con uno o varios halógenos, grupo dialquil C2-8-carbamoilo opcionalmente sustituido con uno o varios halógenos, halógeno, grupo hidroxi, grupo mercapto, grupo amino, grupo nitro, grupo ciano y grupo formilo; el grupo b2 consiste en radicales bivalentes mostrados por =S, =O, =NOR7 y -X1-T1-X2-, en donde R7 es grupo alquilo C1-3 opcionalmente sustituido con uno o varios halógenos o hidrógeno, X1 y X2 están seleccionados, de modo independiente, del grupo que consiste en oxígeno y azufre y T1 es grupo metileno opcionalmente sustituido con uno o varios halógenos o grupo etileno opcionalmente sustituido con uno o varios halógenos; y el grupo b3 consiste en radicales bivalentes mostrados por -T2- y -X3-T3-X4-, en donde X3 y X4 están seleccionados, de modo independiente, del grupo que consiste en oxígeno y azufre y T2 y T3 están seleccionados, de modo independiente, del grupo que consiste en grupo metileno opcionalmente sustituido con uno o varios halógenos; pero excluyendo el compuesto de pirimidina de la fórmula (1), en donde Q es oxígeno; G1 es -CH=; R1, R2 y R3 son todos hidrógeno; R4 es grupo amino o grupo nitro; A es un enlace simple; y Cyc es grupo ciclohexilo.Having an excellent pest control activity. Claim 1: A pyrimidine compound of the formula (1), characterized in that R1 is C1-3 chain hydrocarbon group optionally substituted with one or more halogens, hydrogen, halogen, or amino group ; R2 is C1-3 chain hydrocarbon group optionally substituted with one or more halogens, hydrogen, halogen, hydroxy group, mercapto group or amino group; G1 is nitrogen or -CR5 =, wherein R5 is C1-3 chain hydrocarbonate group optionally substituted with one or more halogens, hydrogen, halogen or amino group; R3 is C1-3 chain hydrocarbon group optionally substituted with one or more halogens, hydrogen, halogen, amino group, nitro group or cyano group; R4 is C1-6 chain hydrocarbon group optionally substituted with one or more halogens, C3-8 cycloalkyl group optionally substituted with one or more halogens, C1-6 alkoxy group optionally substituted with one or more halogens, C1-6-thio alkyl group optionally substituted with one or more halogens, C1-6 alkyl sulfinyl group optionally substituted with one or more halogens, C1-6 alkyl sulfonyl group optionally substituted with one or more halogens, C1-6 alkyl group optionally substituted with one or several halogens, C2-8-amino dialkyl group optionally substituted with one or more halogens, C2-6 alkylcarbonylamino group optionally substituted with one or more halogens, C2-6 alkoxycarbonylamino group optionally substituted with one or more halogens, alkyl group C2-6-carbonyl optionally substituted with one or more halogens, C2-6-alkoxy group optionally substituted with one or more halogens, C2-6-ca alkyl group rbamoyl optionally substituted with one or more halogens, C2-8 dialkyl-carbamoyl group optionally substituted with one or more halogens, phenyl group optionally substituted with one or more atoms or groups selected from the following group a, 5- to 6-membered aromatic heterocyclic group optionally substituted with one or several atoms or groups selected from the following group a, hydrogen, halogen, hydroxy group, mercapto group, amino group, nitro group, cyano group or formyl group; Q is oxygen or -S (O) r-, where r is 0, 1 or 2; Cyc is a 3 to 8-membered saturated heterocyclic group that contains an atom or group selected from the group consisting of oxygen, -S (= O) n- and -NR6- as a ring component, where n is 0, 1 or 2 and R6 is C1-6 chain hydrocarbon group optionally substituted with one or more halogens, C2-6 alkylcarbonyl group optionally substituted with one or more halogens, C2-6 alkoxycarbonyl group optionally substituted with one or more halogens or hydrogen ; 5 to 8-membered saturated heterocyclic group containing two atoms or groups selected from the group consisting of oxygen, -S (= O) n- and -NR6- as a ring component, where n and R6 are as defined above. , provided that the two atoms or groups are not adjacent to each other; C3-8 cycloalkyl group; or C5-8 cycloalkenyl group, any of the groups defined as Cyc may be optionally substituted with one or several atoms or groups selected, independently, from the following groups b1 to b3, provided that, when one or more groups are selected from group b2, each group selected from group b2 is attached to the same carbon atom of the ring defined as Cyc and when one or more groups are selected from group b3, each group selected from group b3 is attached to two adjacent carbon atoms of the defined ring as Cyc; A is a single bond, methylene group optionally substituted with one or several atoms or groups selected from the group consisting of C1-3 alkyl group and halogen or ethylene group optionally substituted with one or several atoms or groups selected from the group consisting of alkyl group C1-3 and halogen and A is attached to the ring carbon atom defined as Cyc; group a consists of C1-6 chain hydrocarbon group optionally substituted with one or more halogens, C1-6 alkoxy group optionally substituted with one or more halogens, C1-6-thio alkyl group optionally substituted with one or more halogens, alkyl group C1-6-sulfinyl optionally substituted with one or more halogens, C1-6 alkyl sulfonyl group optionally substituted with one or more halogens, C1-6-amino alkyl group optionally substituted with one or more halogens, C2-8-amino dialkyl group optionally substituted with one or more halogens, halogen, hydroxy group, mercapto group, amino group, cyano group and nitro group; group b1 consists of C1-6 chain hydrocarbon group optionally substituted with one or more halogens, C1-6 alkoxy group optionally substituted with one or more halogens, C1-6-thio alkyl group optionally substituted with one or more halogens, alkyl group C1-6-sulfinyl optionally substituted with one or more halogens, C1-6 alkyl sulfonyl group optionally substituted with one or more halogens, C1-6-amino alkyl group optionally substituted with one or more halogens, C2-8-amino dialkyl group optionally substituted with one or more halogens, C2-6 alkylcarbonylamino group optionally substituted with one or more halogens, C2-6 alkoxycarbonylamino group optionally substituted with one or more halogens, C2-6 alkylcarbonyl group optionally substituted with one or several halogens, C2-6-alkoxycarbonyl group optionally substituted with one or more halogens, C2-6-carbamoyl alkyl group optionally substituted with one or more halogens s, C2-8-carbamoyl dialkyl group optionally substituted with one or more halogens, halogen, hydroxy group, mercapto group, amino group, nitro group, cyano group and formyl group; group b2 consists of bivalent radicals shown by = S, = O, = NOR7 and -X1-T1-X2-, where R7 is C1-3 alkyl group optionally substituted with one or more halogens or hydrogen, X1 and X2 are selected , independently, of the group consisting of oxygen and sulfur and T1 is methylene group optionally substituted with one or more halogens or ethylene group optionally substituted with one or more halogens; and group b3 consists of bivalent radicals shown by -T2- and -X3-T3-X4-, where X3 and X4 are independently selected from the group consisting of oxygen and sulfur and T2 and T3 are selected, from independent mode, of the group consisting of methylene group optionally substituted with one or more halogens; but excluding the pyrimidine compound of the formula (1), wherein Q is oxygen; G1 is -CH =; R1, R2 and R3 are all hydrogen; R4 is amino group or nitro group; A is a simple link; and Cyc is cyclohexyl group.

ARP110103820 2010-10-15 2011-10-14 PIRIMIDINE COMPOUND AND ITS USE FOR PEST CONTROL AR083456A1 (en)

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US8572724B2 (en) 2011-08-15 2013-10-29 Bank Of America Corporation Method and apparatus for network session validation
US9361443B2 (en) 2011-08-15 2016-06-07 Bank Of America Corporation Method and apparatus for token-based combining of authentication methods
US8458781B2 (en) 2011-08-15 2013-06-04 Bank Of America Corporation Method and apparatus for token-based attribute aggregation
US9159065B2 (en) 2011-08-15 2015-10-13 Bank Of America Corporation Method and apparatus for object security session validation
US8752123B2 (en) 2011-08-15 2014-06-10 Bank Of America Corporation Apparatus and method for performing data tokenization
US8850515B2 (en) 2011-08-15 2014-09-30 Bank Of America Corporation Method and apparatus for subject recognition session validation
US8726340B2 (en) 2011-08-15 2014-05-13 Bank Of America Corporation Apparatus and method for expert decisioning
US8752157B2 (en) 2011-08-15 2014-06-10 Bank Of America Corporation Method and apparatus for third party session validation
US8572686B2 (en) 2011-08-15 2013-10-29 Bank Of America Corporation Method and apparatus for object transaction session validation
US9253197B2 (en) 2011-08-15 2016-02-02 Bank Of America Corporation Method and apparatus for token-based real-time risk updating
US8572687B2 (en) 2011-08-15 2013-10-29 Bank Of America Corporation Apparatus and method for performing session validation

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DE102005000747A1 (en) * 2005-01-05 2006-07-13 Bayer Cropscience Ag Substituted pyrimidines
TW200804349A (en) 2005-12-23 2008-01-16 Kalypsys Inc Novel substituted pyrimidinyloxy ureas as inhibitors of protein kinases
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WO2009005690A2 (en) 2007-06-29 2009-01-08 Gilead Sciences, Inc. Antiviral compounds
WO2010119879A1 (en) * 2009-04-16 2010-10-21 Sumitomo Chemical Company, Limited Pyrimidine compound and its use for pest control
WO2010119878A1 (en) * 2009-04-16 2010-10-21 Sumitomo Chemical Company, Limited Pyrimidine compound and its use for pest control

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