AR059725A1 - PROCESS FOR MODIFICATION OF BIODEGRADABLE POLYMERS - Google Patents

PROCESS FOR MODIFICATION OF BIODEGRADABLE POLYMERS

Info

Publication number
AR059725A1
AR059725A1 ARP070100886A ARP070100886A AR059725A1 AR 059725 A1 AR059725 A1 AR 059725A1 AR P070100886 A ARP070100886 A AR P070100886A AR P070100886 A ARP070100886 A AR P070100886A AR 059725 A1 AR059725 A1 AR 059725A1
Authority
AR
Argentina
Prior art keywords
polymer
alkyl
modification
aryl
copolymer
Prior art date
Application number
ARP070100886A
Other languages
Spanish (es)
Inventor
Andreas H Hogt
Wilhelm K Frijlink
Original Assignee
Akzo Nobel Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel Nv filed Critical Akzo Nobel Nv
Publication of AR059725A1 publication Critical patent/AR059725A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/912—Polymers modified by chemical after-treatment derived from hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Proceso para la modificacion de un polímero o copolímero con la estructura general (1) para una o más de las unidades repetitivas donde n es un entero, m es un entero dentro del rango entre 0 y 6, y R se selecciona entre hidrogeno, alquilo C1-20 sustituido o no sustituido, cicloalquilo C3-20, arilo C6-20, aniquilo C7-20, y alcarilo C7-20, donde dichos grupos pueden incluir unidades alquilo lineal o ramificado; donde los uno o más sustituyentes opcionales se seleccionan entre el grupo que consiste en los grupos hidroxi, alcoxi, alqu(en)ilo lineal o ramificado, ariloxi, halogeno, ácido carboxílico, éster, carboxi, nitrilo, y amido, donde dicho proceso incluye poner en contacto el polímero o copolímero con un peroxido orgánico cíclico en las condiciones necesarias para que se descomponga por lo menos parte de dicho peroxido. Este proceso da corno resultado un (co)polímero con un alta grado de ramificacion pero libre de formacion de gel.Process for the modification of a polymer or copolymer with the general structure (1) for one or more of the repetitive units where n is an integer, m is an integer within the range between 0 and 6, and R is selected from hydrogen, alkyl C1-20 substituted or unsubstituted, C3-20 cycloalkyl, C6-20 aryl, C7-20 aniquyl, and C7-20 alkaryl, wherein said groups may include linear or branched alkyl units; wherein the one or more optional substituents are selected from the group consisting of the linear or branched hydroxy, alkoxy, alkyl (aryl), aryloxy, halogen, carboxylic acid, ester, carboxy, nitrile, and amido groups, wherein said process includes contacting the polymer or copolymer with a cyclic organic peroxide under the conditions necessary for at least part of said peroxide to decompose. This process results in a (co) polymer with a high degree of branching but free of gel formation.

ARP070100886A 2006-03-03 2007-03-02 PROCESS FOR MODIFICATION OF BIODEGRADABLE POLYMERS AR059725A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06110664 2006-03-03

Publications (1)

Publication Number Publication Date
AR059725A1 true AR059725A1 (en) 2008-04-23

Family

ID=36603547

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP070100886A AR059725A1 (en) 2006-03-03 2007-03-02 PROCESS FOR MODIFICATION OF BIODEGRADABLE POLYMERS

Country Status (9)

Country Link
CN (1) CN101395199B (en)
AR (1) AR059725A1 (en)
AT (1) ATE478909T1 (en)
BR (1) BRPI0708460B1 (en)
DE (1) DE602007008692D1 (en)
ES (1) ES2351526T3 (en)
PT (1) PT1991601E (en)
RU (1) RU2418818C2 (en)
TW (1) TWI567103B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115340760B (en) * 2022-09-21 2024-08-02 浙江德龙新材料科技有限公司 Long-branched polylactic acid material and preparation method thereof
CN116284718A (en) * 2023-04-14 2023-06-23 常州大学 A kind of high melt strength polylactic acid and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI99125C (en) * 1993-12-31 1997-10-10 Neste Oy Polylaktidsammansättning
US5932660A (en) * 1994-07-21 1999-08-03 Akzo Nobel Nv Modification of (co) polymers with cyclic ketone peroxides
DE69806262T2 (en) * 1997-09-18 2003-03-13 Metabolix, Inc. MODIFIED POLYHYDROXYALKANOATES FOR THE PREPARATION OF COATINGS AND FILMS
EP1186618A1 (en) * 2000-09-08 2002-03-13 ATOFINA Research Controlled rheology polypropylene heterophasic copolymers

Also Published As

Publication number Publication date
TWI567103B (en) 2017-01-21
ATE478909T1 (en) 2010-09-15
DE602007008692D1 (en) 2010-10-07
BRPI0708460B1 (en) 2018-04-03
CN101395199B (en) 2011-12-14
PT1991601E (en) 2010-11-29
CN101395199A (en) 2009-03-25
TW200740876A (en) 2007-11-01
ES2351526T3 (en) 2011-02-07
RU2008139288A (en) 2010-04-10
RU2418818C2 (en) 2011-05-20
BRPI0708460A2 (en) 2011-05-31

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Legal Events

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FG Grant, registration
FD Application declared void or lapsed, e.g., due to non-payment of fee