AR046988A1 - (hetero)ciclilcarboxanilidas para combatir hongos nocivos - Google Patents

(hetero)ciclilcarboxanilidas para combatir hongos nocivos

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Publication number
AR046988A1
AR046988A1 ARP040104855A ARP040104855A AR046988A1 AR 046988 A1 AR046988 A1 AR 046988A1 AR P040104855 A ARP040104855 A AR P040104855A AR P040104855 A ARP040104855 A AR P040104855A AR 046988 A1 AR046988 A1 AR 046988A1
Authority
AR
Argentina
Prior art keywords
phenyl
phenylalkyl
alkyl
haloalkenyl
halocycloalkyl
Prior art date
Application number
ARP040104855A
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English (en)
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Basf Ag
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Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of AR046988A1 publication Critical patent/AR046988A1/es

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81Amides; Imides
    • C07D213/82Amides; Imides in position 3
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/781,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/48Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —S—C≡N groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32Oximes
    • C07C251/34Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C251/36Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atoms of the oxyimino groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/38Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atoms of the oxyimino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D207/00Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D263/00Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/30Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D263/34Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D277/00Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/56Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D279/00Heterocyclic compounds containing six-membered rings having one nitrogen atom and one sulfur atom as the only ring hetero atoms
    • C07D279/101,4-Thiazines; Hydrogenated 1,4-thiazines
    • C07D279/121,4-Thiazines; Hydrogenated 1,4-thiazines not condensed with other rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/54Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/70Nitro radicals
    • C07D307/71Nitro radicals attached in position 5
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/38Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Pyridine Compounds (AREA)

Abstract

(Hetero)ciclilcarboxanilidas de la formula general (1), en la cual las variables tienen los siguientes significados: A es fenilo o un heterociclo de 5 o 6 miembros que esté interrumpido por lo menos en forma simple, con 1, 2 o 3 heteroátomos seleccionados de entre N, O, S, S(=O) y S(=O)2 como miembros del anillo, en el que el fenilo o heterociclo de 5 o 6 miembros que está insaturado por lo menos en forma simple, pueden estar no sustituidos o portar 1, 2 o 3 restos Ra, en los que: Ra representa halogeno, nitro, CN, alquilo-C1-4, cicloalquilo-C3-6, alquenilo-C2-4, alquinilo-C2-4, alcoxi-C1-4, haloalquilo-C1-4, halocicloalquilo-C3-6, haloalquenilo-C2-4, haloalquinilo-C2-4, haloalcoxi-C1-4 o fenilo, pudiendo el fenilo estar no sustituido o portar uno, dos o tres restos Rb, seleccionados de entre halogeno, nitro, CN, alquilo-C1-4, cicloalquilo-C3-6, alquenilo-C2-4, alquinilo-C2-4, alcoxi-C1-4, haloalquilo-C1-4, halocicloalquilo-C3-6, haloalquenilo-C2-4, haloalquinilo-C2-4 y haloalcoxi-C1-4; Y representa oxígeno o azufre; R1 representa Oh, OH, alquilo-C1-4, cicloalquilo-C3-6, alcoxi-C1-4, haloalquilo-C1-4, halocicloalquilo-C3-6 o haloalcoxi-C1-4; R2 es halogeno, nitro, CN, alquilo-C1-4, cicloalquilo-C3-6, alquenilo-C2- 4, alquinilo-C2-4, alcoxi-C1-4, haloalquilo-C1-4, halocicloalquilo-C3-6, haloalquenilo-C2-4, haloalquinilo-C2-4 o haloalcoxi-C1-4; R3m, R4m representan, independientemente el uno del otro, halogeno, hidrogeno, alquilo-C1-6, cicloalquilo-C3-6, alquenilo-C2-6, alquinilo-C2-6, fenilo, fenil-alquilo-(C1-4), fenilalquenilo-C2-4, fenilalquinilo-C2-4, haloalquilo-C1-6, halocicloalquilo-C3-6, haloalquenilo-C2-6, haloalquinilo-C2-6, fenilhaloalquilo-C1-4, fenilhaloalquenilo-C2-4 o fenilhaloalquinilo-C2-4, pudiendo el fenilo o el grupo fenilo de fenilalquilo-C1-4, fenilalquenilo-C2-4, fenilalquinilo-C2-4, fenilhaloalquilo-C1-4, fenilhaloalquenilo-C2-4 y fenilhaloalquinilo-C2-4 ser no sustituidos o portar uno, dos o tres restos Rb; representar m = 2 o 3, y las variables R32, R42 o, en su caso, R33, R43, representan también alcoxi-C1-6; R5 representa hidrogeno, alquilo-C1-6, cicloalquilo-C3-6, alquenilo-C2-6, alquinilo-C2-6, fenilo, fenilalquilo-C1-4, fenilalquenilo-C2-4, fenilalquinilo-C2-4, haloalquilo-C1-6, halocicloalquilo-C3-6, haloalquenilo-C2-6, haloalquinilo-C2-6, fenilhaloalquilo-C1-4, fenilhaloalquenilo-C2-4 o fenilhaloalquinilo-C2-4, pudiendo el fenilo o el grupo fenilo de fenilalquilo-C1-4, fenilalquenilo- C2-4, fenilalquinilo-C2-4, fenilhaloalquilo-C1-4, fenilhaloalquenilo-C2-4 y fenilhaloalquinilo-C2-4 ser no sustituidos o portar uno, dos o tres restos Rb; R6 representa hidrogeno, alquilo-C1-8, cicloalquilo-C3-6, alquenilo-C2-8, alquinilo-C2-8, haloalquilo-C1-8, halocicloalquilo-C3-6, haloalquenilo-C2-8, haloalquinilo-C2-8, fenilo, naftilo, fenilalquilo-C1-6, naftilalquilo-C1-6, fenilalquenilo-C2-6, fenilalquinilo-C2-6, fenilhaloalquilo-C1-6, fenilhaloalquenilo-C2-6 o fenilhaloalquinilo-C2- 6, pudiendo el fenilo y el naftilo en los 9 ultimos grupos mencionados estar no sustituidos o portar uno, dos o tres sustituyentes seleccionados de entre Rb y R7, representando R7-(CR8)=NOR9, en los que: R8 representa hidrogeno, alquilo-C1-6, cicloalquilo-C3-6, alquenilo-C2-6, alquinilo-C2-6, haloalquilo-C1-6, halocicloalquilo-C3-6, haloalquenilo-C2-6, haloalquinilo-C2-6, fenilo, bencilo, pudiendo el fenilo y el grupo fenilo en bencilo estar no sustituidos o portar uno, dos o tres restos Rb; y R9 representa alquilo-C1-6, cicloalquilo-C3-6, alquenilo-C2-6, alquinilo-C2-6, haloalquilo-C1-6, halocicloalquilo-C3-6, haloalquenilo-C2-6, haloalquinilo-C2-6, fenilo, fenilalquilo-C1-4, fenilhaloalquilo-C1-4, fenilalquenilo-C2-4, fenilhaloalquenilo-C2-4, fenilalquinilo-C2-4, fenilhaloalquinilo-C2-4, pudiendo el fenilo y el grupo fenilo en fenilalquilo-C1-4, fenilhaloalquilo-C1-4, fenilalquenilo-C2-4, fenilhaloalquenilo-C2-4, fenilalquinilo-C2-4 y fenilhaloalquinilo-C2-4, estar no sustituidos o portar uno, dos o tres restos Rb n representa 0, 1, 2, 3 o 4; y m representa 1, 2 o 3; y las sales utilizables en agricultura de éstos. Empleo de las (hetero)ciclilcarboxanilidas de la formula general (1) y sus sales utilizables en agricultura como fungicidas, así como a los fitoprotectores que las contienen.
ARP040104855A 2003-12-23 2004-12-22 (hetero)ciclilcarboxanilidas para combatir hongos nocivos AR046988A1 (es)

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DE10361005 2003-12-23

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US (1) US20070117852A1 (es)
EP (1) EP1699752B1 (es)
JP (1) JP2007517786A (es)
AR (1) AR046988A1 (es)
AT (1) ATE374176T1 (es)
DE (1) DE502004005096D1 (es)
PE (1) PE20050823A1 (es)
UY (1) UY28699A1 (es)
WO (1) WO2005063692A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1912504A1 (en) * 2005-08-05 2008-04-23 Basf Se Method for controlling rust infections in leguminous plants
WO2016131739A1 (en) * 2015-02-18 2016-08-25 Bayer Cropscience Aktiengesellschaft Substituted 2-difluoromethyl-nicotin(thio)carboxanilide derivatives and their use as fungicides

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1118609A3 (de) * 2000-01-21 2002-08-28 Basf Aktiengesellschaft Iminooxisubstituierte Benzylphenylether, Verfahren und Zwischenprodukte zu ihrer Herstellung, sie enthaltende Mittel sowie ihre Verwendung zur Bekämpfung von Schadpilzen
EP1305292B1 (de) * 2000-07-24 2012-06-20 Bayer CropScience AG Biphenylcarboxamide

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UY28699A1 (es) 2005-07-29
JP2007517786A (ja) 2007-07-05
DE502004005096D1 (de) 2007-11-08
WO2005063692A1 (de) 2005-07-14
PE20050823A1 (es) 2005-10-27
US20070117852A1 (en) 2007-05-24
ATE374176T1 (de) 2007-10-15
EP1699752B1 (de) 2007-09-26
EP1699752A1 (de) 2006-09-13

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