AR042191A2 - Proceso catalitico para producir peroxido de hidrogeno - Google Patents

Proceso catalitico para producir peroxido de hidrogeno

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Publication number
AR042191A2
AR042191A2 ARP030104223A ARP030104223A AR042191A2 AR 042191 A2 AR042191 A2 AR 042191A2 AR P030104223 A ARP030104223 A AR P030104223A AR P030104223 A ARP030104223 A AR P030104223A AR 042191 A2 AR042191 A2 AR 042191A2
Authority
AR
Argentina
Prior art keywords
hydrogen peroxide
value
group
catalytic process
hydrogen
Prior art date
Application number
ARP030104223A
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English (en)
Original Assignee
Univ Princeton
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Princeton filed Critical Univ Princeton
Publication of AR042191A2 publication Critical patent/AR042191A2/es

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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
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    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
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    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
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    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polyethers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Proceso catalítico para producir peróxido de hidrógeno a partir de oxígeno e hidrógeno que comprende los siguientes pasos: A) el tratamiento de una suspensión acuosa de catalizador heterogéneo con una fuente de oxígeno y una fuente de hidrógeno; B) la separación del catalizador; y C) el aislamiento del peróxido de hidrógeno producido, donde dicho catalizador es una composición de la fórmula: [[(Y1O3-Z-Y2O3). K*p(X2/p-)]1-n(Y3O3R3)2nMe2]]*Pt*Pd donde Y1, Y2 e Y3 independientemente uno del otro, es fósforo o arsénico; Z es un grupo divalente que forma, reversiblemente, una forma reducida estable, dicho grupo contiene dos centros catiónicos conjugados que juntos tienen un valor E° red negativo; Me2 es un metal trivalente o tetravalente del grupo III, IVA o IVB con un número atómico de por lo menos 21 o un lantánido; X es un anión; n tiene un valor de 0 a 0,8; y p tiene un valor de 1, 2 ó 3; y R3 es un grupo cubierto no reducible.
ARP030104223A 1995-08-21 2003-11-14 Proceso catalitico para producir peroxido de hidrogeno AR042191A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/517,095 US5906892A (en) 1993-08-09 1995-08-21 Electron acceptor compositions on polymer templates

Publications (1)

Publication Number Publication Date
AR042191A2 true AR042191A2 (es) 2005-06-15

Family

ID=24058340

Family Applications (4)

Application Number Title Priority Date Filing Date
AR33490196A AR000612A1 (es) 1995-08-21 1996-01-02 Composición aceptora de electrones estable con estados de separación de carga fotoinducidos método para producirla polímero util como medio de unión yproceso catalitico para producir peróxido de hidr ógeno
ARP030104221A AR042189A2 (es) 1995-08-21 2003-11-14 Polimero derivado utilizable como medio de union en composiciones aceptoras de electrones estables que tienen estados de separacion foto inducido
ARP030104223A AR042191A2 (es) 1995-08-21 2003-11-14 Proceso catalitico para producir peroxido de hidrogeno
ARP030104222A AR042190A2 (es) 1995-08-21 2003-11-14 Un metodo para preparar composiciones aceptoras de electrones estables con estados de separacion de carga fotoinducidos

Family Applications Before (2)

Application Number Title Priority Date Filing Date
AR33490196A AR000612A1 (es) 1995-08-21 1996-01-02 Composición aceptora de electrones estable con estados de separación de carga fotoinducidos método para producirla polímero util como medio de unión yproceso catalitico para producir peróxido de hidr ógeno
ARP030104221A AR042189A2 (es) 1995-08-21 2003-11-14 Polimero derivado utilizable como medio de union en composiciones aceptoras de electrones estables que tienen estados de separacion foto inducido

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ARP030104222A AR042190A2 (es) 1995-08-21 2003-11-14 Un metodo para preparar composiciones aceptoras de electrones estables con estados de separacion de carga fotoinducidos

Country Status (9)

Country Link
US (2) US5906892A (es)
EP (3) EP0846082B1 (es)
JP (2) JP3919221B2 (es)
AR (4) AR000612A1 (es)
AT (1) ATE251593T1 (es)
AU (1) AU4738896A (es)
DE (3) DE69535421T2 (es)
ES (1) ES2214979B1 (es)
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Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2287937A3 (en) * 1997-07-11 2012-02-22 The University of Southern California Charge generators in heterolamellar multilayer thin films
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
MXPA06000470A (es) * 2003-07-15 2006-08-23 Grt Inc Sintesis de hidrocarburos.
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
JP2005255651A (ja) * 2004-03-15 2005-09-22 Kyoto Univ 有機金属錯体構造体及びその製造方法、並びに、該有機金属錯体構造体を用いた機能性膜、機能性複合材料、機能性構造体及び吸脱着センサー
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20080275284A1 (en) * 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
GB0514478D0 (en) * 2005-07-14 2005-08-17 Birkeland Innovasjon As Compounds
UA95943C2 (ru) 2006-02-03 2011-09-26 ДжиАрТи, ИНК. Отделение легких газов от галогенов
AU2007215476B2 (en) 2006-02-03 2011-11-10 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US7357909B2 (en) * 2006-06-28 2008-04-15 Lyondell Chemical Technology, L.P. Process for producing hydrogen peroxide
KR20100027141A (ko) 2007-05-24 2010-03-10 지알티, 인코포레이티드 가역적으로 할로겐화수소를 흡수 및 방출할 수 있는 존 반응기
US7501532B1 (en) * 2007-11-20 2009-03-10 Lyondell Chemical Technology, L.P. Process for producing hydrogen peroxide
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
KR101740419B1 (ko) 2008-07-18 2017-05-26 지알티, 인코포레이티드 천연 가스를 액체 탄화수소로 변환시키는 연속 공정
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9346242B2 (en) * 2011-12-13 2016-05-24 Samsung Electronics Co., Ltd. Multi-layer thin film assembly and barrier film for electronic device including the same
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
MX2022008423A (es) 2020-01-13 2022-08-08 Procter & Gamble Botellas transparentes que incluyen paredes laterales facetadas.

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE582855A (es) * 1958-09-22
DE1570586A1 (de) * 1965-07-03 1970-02-05 Bayer Ag Verfahren zur Herstellung von festen Poly-2-vinylpyridin-N-oxyd
GB1516418A (en) * 1976-03-09 1978-07-05 Air Prod & Chem Synthesis of hydrogen peroxide
DE2727245C3 (de) * 1977-06-16 1980-06-26 Brintzinger, Hans, Prof. Dr., 7750 Konstanz Polymergebundene CyclopentadienylÜbergangsmetall-Verbindungen und ihre Ligand-Substitutions-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
GB2074040B (en) * 1980-04-22 1984-05-10 Air Prod & Chem Catalysts for the synthesis of hydrogen peroxide
US4336240A (en) * 1981-04-22 1982-06-22 Air Products And Chemicals, Inc. Method of manufacturing hydrogen peroxide
US4439302A (en) * 1981-11-24 1984-03-27 Massachusetts Institute Of Technology Redox mediation and hydrogen-generation with bipyridinium reagents
US4473695A (en) * 1982-01-15 1984-09-25 Massachusetts Institute Of Technology Synthesis of N,N'-dialkyl-4'bipyridinium reagents
US4895705A (en) * 1984-11-23 1990-01-23 Massachusetts Institute Of Technology Molecule-based microelectronic devices
US4721601A (en) * 1984-11-23 1988-01-26 Massachusetts Institute Of Technology Molecule-based microelectronic devices
US5034192A (en) * 1984-11-23 1991-07-23 Massachusetts Institute Of Technology Molecule-based microelectronic devices
US4868343A (en) * 1986-04-16 1989-09-19 Catalytica Inc. Acid catalyzed process
US4832938A (en) * 1988-05-13 1989-05-23 E. I. Du Pont De Nemours And Company Hydrogen peroxide production method using platinum/palladium catalysts
US5191029A (en) * 1988-12-29 1993-03-02 Deldonno Theodore A Phosphorus-containing polymer compositions containing water-soluble polyvalent metal compounds
GB8914575D0 (en) * 1989-06-24 1989-08-16 Ici Plc Catalysts
US5457564A (en) * 1990-02-26 1995-10-10 Molecular Displays, Inc. Complementary surface confined polymer electrochromic materials, systems, and methods of fabrication therefor
US5344891A (en) * 1990-07-07 1994-09-06 Mitsubishi Rayon Co., Ltd. Biodegradable polymers
IT1243781B (it) * 1990-08-03 1994-06-28 Eniricerche Spa Composizione solida cristallina mesoporosa di difosfonato-fosfito di un metallo tetravalente, con una stretta distribuzione di mesopori
US5695890A (en) * 1993-08-09 1997-12-09 The Trustees Of Princeton University Heterolamellar photoelectrochemical films and devices
US5500297A (en) * 1993-08-09 1996-03-19 The Trustees Of Princeton University Electron acceptor compositions technical field
US5573882A (en) * 1995-08-25 1996-11-12 Xerox Corporation Liquid developer compositions with charge director block copolymers

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EP0846082A4 (en) 1998-09-02
EP0846082A2 (en) 1998-06-10
DE69531903D1 (de) 2003-11-13
ATE251593T1 (de) 2003-10-15
ES2214979A1 (es) 2004-09-16
DE69531903T2 (de) 2004-09-09
HK1062670A1 (en) 2004-11-19
AR042190A2 (es) 2005-06-15
WO1997006661A3 (en) 1997-05-01
US6187871B1 (en) 2001-02-13
WO1997006661A2 (en) 1997-02-27
EP1386884B1 (en) 2007-03-07
DE69535421T2 (de) 2007-12-06
DE69534409D1 (de) 2005-09-29
JP3919221B2 (ja) 2007-05-23
AU4738896A (en) 1997-03-12
US5906892A (en) 1999-05-25
DE69535421D1 (de) 2007-04-19
AR042189A2 (es) 2005-06-15
ES2214979B1 (es) 2007-05-01
EP0846082B1 (en) 2003-10-08
EP1394185A1 (en) 2004-03-03
EP1386884A1 (en) 2004-02-04
JP2006321714A (ja) 2006-11-30
AR000612A1 (es) 1997-07-10
HK1062690A1 (en) 2004-11-19
EP1394185B1 (en) 2005-08-24
DE69534409T2 (de) 2006-06-08

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