AR008869A1 - CATALYSTS AND A METHOD FOR CURING A COMPOSITION INCLUDING A HYDROXYL-CONTAINING POLYMER WITH AN ISOCIANATE-CONTAINING COMPOUND - Google Patents
CATALYSTS AND A METHOD FOR CURING A COMPOSITION INCLUDING A HYDROXYL-CONTAINING POLYMER WITH AN ISOCIANATE-CONTAINING COMPOUNDInfo
- Publication number
- AR008869A1 AR008869A1 ARP970104522A ARP970104522A AR008869A1 AR 008869 A1 AR008869 A1 AR 008869A1 AR P970104522 A ARP970104522 A AR P970104522A AR P970104522 A ARP970104522 A AR P970104522A AR 008869 A1 AR008869 A1 AR 008869A1
- Authority
- AR
- Argentina
- Prior art keywords
- isocianate
- catalysts
- hydroxyl
- curing
- containing polymer
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- -1 aluminum orthoester Chemical class 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- WYNCHZVNFNFDNH-UHFFFAOYSA-N Oxazolidine Chemical compound C1COCN1 WYNCHZVNFNFDNH-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000008139 complexing agent Substances 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- KHVCOYGKHDJPBZ-WDCZJNDASA-N tetrahydrooxazine Chemical compound OC[C@H]1ONC[C@@H](O)[C@@H]1O KHVCOYGKHDJPBZ-WDCZJNDASA-N 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/226—Sulfur, e.g. thiocarbamates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
- C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/31—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Paints Or Removers (AREA)
Abstract
Un catalizador que comprende el producto de la reaccion de: (a) el producto de reaccion de un ortoéster de titanio, zirconio, hafnio o aluminio y una beta-dicetona o beta-cetoester que tiene la formula general donde R1, R2 y R3 pueden seleccionarse independientemente del grupo seleccionado por hidrogeno ygrupos de alquilo, arilo, cicloalquilo, alcoxi, ariloxi, hidroxialquilo, alcoxialquilo e hidroxialcoxialquilo que contienen hasta ocho átomos de carbonoy (b) un agente complejanteseleccionado de un compuesto de mercapto o una oxazolidina o una tetrahidro-oxazina que tiene la formula general (A) o (B),respectivamente o sus mezclas. El catalizador es paarticularmente util para preparar composiciones para revestimientoque tienen una vida util dealmacenamiento y que puede curarse a temperatura ambiente. Se describe además un método para usar una composicion que comprende un polímero que contienehidrosilos y un compuesto que contiene isocianato.A catalyst comprising the product of the reaction of: (a) the reaction product of a titanium, zirconium, hafnium or aluminum orthoester and a beta-diketone or beta-ketoster having the general formula where R1, R2 and R3 can independently selected from the group selected by hydrogen and groups of alkyl, aryl, cycloalkyl, alkoxy, aryloxy, hydroxyalkyl, alkoxyalkyl and hydroxyalkoxyalkyl containing up to eight carbon atoms and (b) a complexing agent selected from a mercapto compound or an oxazolidine or a tetrahydro-oxazine having the general formula (A) or (B), respectively or their mixtures. The catalyst is particularly useful for preparing coating compositions that have a shelf life and can cure at room temperature. Further disclosed is a method of using a composition comprising a hydrosily-containing polymer and an isocyanate-containing compound.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9620808.7A GB9620808D0 (en) | 1996-10-05 | 1996-10-05 | Catalysts |
| GBGB9701911.1A GB9701911D0 (en) | 1997-01-30 | 1997-01-30 | Catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR008869A1 true AR008869A1 (en) | 2000-02-23 |
Family
ID=26310173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP970104522A AR008869A1 (en) | 1996-10-05 | 1997-10-01 | CATALYSTS AND A METHOD FOR CURING A COMPOSITION INCLUDING A HYDROXYL-CONTAINING POLYMER WITH AN ISOCIANATE-CONTAINING COMPOUND |
Country Status (18)
| Country | Link |
|---|---|
| EP (1) | EP0929585A1 (en) |
| JP (1) | JP2001501534A (en) |
| KR (1) | KR20000048918A (en) |
| CN (1) | CN1239484A (en) |
| AR (1) | AR008869A1 (en) |
| AU (1) | AU735671B2 (en) |
| BR (1) | BR9711862A (en) |
| CA (1) | CA2267773A1 (en) |
| CZ (1) | CZ118099A3 (en) |
| HU (1) | HUP0000438A2 (en) |
| ID (1) | ID17410A (en) |
| IL (1) | IL129303A0 (en) |
| NO (1) | NO991616L (en) |
| NZ (1) | NZ335210A (en) |
| PL (1) | PL332641A1 (en) |
| TR (1) | TR199901203T2 (en) |
| TW (1) | TW394782B (en) |
| WO (1) | WO1998015585A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9815029D0 (en) * | 1998-07-11 | 1998-09-09 | Ici Plc | Polyisocyanate compositions |
| EP1116501A3 (en) * | 1999-12-14 | 2005-09-28 | Dunlop Sports Group Americas Inc. | Method for coating golf balls with a dry-on-line clear polyurethane composition |
| DE10142296C1 (en) | 2001-08-29 | 2003-02-13 | Bayer Ag | Polyurethane elastomers, used for making moldings, e.g. shoe soles, are produced using an amine catalyst and a catalyst mixture of organic titanium and/or zirconium and lithium compounds in reaction of isocyanate and polyether polyol |
| JP2006509070A (en) * | 2002-12-04 | 2006-03-16 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニー | Organometallic catalyst composition and polyurethane production process using said catalyst |
| US9745401B2 (en) | 2008-10-22 | 2017-08-29 | Akzo Nobel Coatings International B.V. | Coating composition comprising a polyisocyanate and a polyol |
| GB201002279D0 (en) * | 2010-02-11 | 2010-03-31 | Johnson Matthey Plc | Method of preparing a polymer and compositions thereof |
| CN102513156B (en) * | 2011-11-23 | 2013-11-06 | 湖北新蓝天新材料股份有限公司 | Preparation method of titanium complex with high catalytic activity |
| CN102786910B (en) * | 2012-07-26 | 2013-08-07 | 广东欧利雅化工有限公司 | Catalyst composition for silicone sealant, silicone sealant and preparation method for catalyst composition |
| CN106944125B (en) * | 2016-01-07 | 2019-04-12 | 中国石油化工股份有限公司 | A kind of preparation method of hydrocracking catalyst |
| CN106986976A (en) * | 2016-01-20 | 2017-07-28 | 新纶科技（常州）有限公司 | A kind of carbon monoxide-olefin polymeric |
| CN108084386B (en) * | 2017-12-21 | 2020-08-28 | 万华化学集团股份有限公司 | Polythiourethane resin for optical material and preparation method thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE577999A (en) * | 1958-04-25 | |||
| GB890280A (en) * | 1959-02-25 | 1962-02-28 | Ici Ltd | Improvements in or relating to the manufacture of foamed polyurethanes |
| NL259740A (en) * | 1960-10-05 | |||
| DE1923934A1 (en) * | 1969-05-10 | 1970-11-19 | Dynamit Nobel Ag | Process for the production of polyurethanes |
| US4391937A (en) * | 1981-10-05 | 1983-07-05 | Dow Corning Corporation | Color stable chelated titanate compositions |
| US4788083A (en) * | 1986-03-27 | 1988-11-29 | Ashland Oil, Inc. | Tin or bismuth complex catalysts and trigger cure of coatings therewith |
| DE3739174A1 (en) * | 1987-11-19 | 1989-06-01 | Huels Chemische Werke Ag | CONDENSED ACETIC ACID ESTERS TITANCHELATES AND METHOD FOR THE PRODUCTION THEREOF |
| DE4242622A1 (en) * | 1992-12-17 | 1994-06-23 | Bayer Ag | New titanium (IV) chelates and their use in polysiloxane compositions |
-
1997
- 1997-09-19 AU AU43126/97A patent/AU735671B2/en not_active Ceased
- 1997-09-19 PL PL97332641A patent/PL332641A1/en unknown
- 1997-09-19 NZ NZ335210A patent/NZ335210A/en unknown
- 1997-09-19 WO PCT/GB1997/002565 patent/WO1998015585A1/en not_active Application Discontinuation
- 1997-09-19 CA CA002267773A patent/CA2267773A1/en not_active Abandoned
- 1997-09-19 HU HU0000438A patent/HUP0000438A2/en unknown
- 1997-09-19 CZ CZ991180A patent/CZ118099A3/en unknown
- 1997-09-19 CN CN97180286A patent/CN1239484A/en active Pending
- 1997-09-19 TR TR1999/01203T patent/TR199901203T2/en unknown
- 1997-09-19 JP JP10517274A patent/JP2001501534A/en active Pending
- 1997-09-19 BR BR9711862-1A patent/BR9711862A/en not_active Application Discontinuation
- 1997-09-19 KR KR1019990702949A patent/KR20000048918A/en not_active Application Discontinuation
- 1997-09-19 EP EP97941101A patent/EP0929585A1/en not_active Withdrawn
- 1997-09-19 IL IL12930397A patent/IL129303A0/en unknown
- 1997-10-01 AR ARP970104522A patent/AR008869A1/en not_active Application Discontinuation
- 1997-10-03 ID IDP973356A patent/ID17410A/en unknown
- 1997-10-04 TW TW086114514A patent/TW394782B/en not_active IP Right Cessation
-
1999
- 1999-04-06 NO NO991616A patent/NO991616L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| PL332641A1 (en) | 1999-09-27 |
| IL129303A0 (en) | 2000-02-17 |
| TR199901203T2 (en) | 1999-08-23 |
| NO991616D0 (en) | 1999-04-06 |
| KR20000048918A (en) | 2000-07-25 |
| JP2001501534A (en) | 2001-02-06 |
| CN1239484A (en) | 1999-12-22 |
| NZ335210A (en) | 2000-01-28 |
| WO1998015585A1 (en) | 1998-04-16 |
| CZ118099A3 (en) | 1999-09-15 |
| AU4312697A (en) | 1998-05-05 |
| AU735671B2 (en) | 2001-07-12 |
| BR9711862A (en) | 2001-08-28 |
| EP0929585A1 (en) | 1999-07-21 |
| TW394782B (en) | 2000-06-21 |
| ID17410A (en) | 1997-12-24 |
| NO991616L (en) | 1999-06-04 |
| HUP0000438A2 (en) | 2000-06-28 |
| CA2267773A1 (en) | 1998-04-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |