AR004882A1 - A PROCEDURE THAT INCLUDES REACTIONING ONE OR MORE REAGENTS IN THE PRESENCE OF A COMPLEX CATALYST OF METAL-ORGANOPOLYPHOSPHITE LEAGUE AND LIGAND OF OPTIONALLY FREE ORGANOPOLYPHOSPHITE AND A QUANTITY OF ORIGANOPHOSPHOROUSLY LABORATED MATERIALS - Google Patents

A PROCEDURE THAT INCLUDES REACTIONING ONE OR MORE REAGENTS IN THE PRESENCE OF A COMPLEX CATALYST OF METAL-ORGANOPOLYPHOSPHITE LEAGUE AND LIGAND OF OPTIONALLY FREE ORGANOPOLYPHOSPHITE AND A QUANTITY OF ORIGANOPHOSPHOROUSLY LABORATED MATERIALS

Info

Publication number
AR004882A1
AR004882A1 ARP960105530A ARP960105530A AR004882A1 AR 004882 A1 AR004882 A1 AR 004882A1 AR P960105530 A ARP960105530 A AR P960105530A AR P960105530 A ARP960105530 A AR P960105530A AR 004882 A1 AR004882 A1 AR 004882A1
Authority
AR
Argentina
Prior art keywords
organopolyphosphite
metal
ligand
complex catalyst
complex
Prior art date
Application number
ARP960105530A
Other languages
Spanish (es)
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Publication of AR004882A1 publication Critical patent/AR004882A1/en

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Abstract

La presente invención se refiere a un procedimiento que comprende hacer reaccionar uno o más reactivos en presencia de un catalizador complejo deligando de organopolifosfito-metal y ligando de organopolifosfito opcionalmente libre y una cantidadde ligando de organofosforo estéricamente impedidodiferente al ligando de organopolifosfito-metal para producir uno o más productos, caracterizado porque dicho ligando de organofosforo estéricamenteimpedido (i) tiene una fuerza decoordinació n con respecto al metal de dicho catalizador complejo de ligando de organopolifosfito-metal (ii) cuando formaun complejo con el metal para formar un catalizador complejo de ligando de organofosforo estéricamente impedido y metalprovee un índ ice de reacción de almenos el 25 por ciento del índice de reacción provisto poe el ligando de organopolifosfito de dicho catalizador complejo de ligando deorganopolifosfito-metal,(iii) opcionalmente tiene una fuerza decoordinación con resp ecto al metal de dicho catalizador complejo de ligando deorganopolifosfito-metal mayor que el monóxido de carbono y (iv) opcionalmente cuando forma un complejo con el metal para formar un catalizador complejo deligando deorganofosforo estéricamente impedido y metal, provee una relación de isómero de producto normal: ramificado menor a la relación de isómero deproducto nornal: ramificado provista por el ligando de organopolifosfito de dicho catalizador complejode ligando de organopolifosfi to-metal. Además serefiere a un método para monitorear el agotamiento de dicho ligando de organopolifosfito, a una mezcla de reacción preparada mediante dichoprocedimiento y a una composición de precursor decatalizador empleada en dicho pro cedimiento.The present invention relates to a process which comprises reacting one or more reagents in the presence of an organopolyphosphite-metal deligand complex catalyst and optionally free organopolyphosphite ligand and a quantity of sterically hindered organophosphorus ligand different from the organopolyphosphite-metal ligand to produce one or more products, characterized in that said sterically hindered organophosphorus ligand (i) has a coordinating strength with respect to metal of said organopolyphosphite-metal ligand complex catalyst (ii) when it complexes with the metal to form a complex ligand catalyst. sterically hindered organophosphorous and metal provides a reaction rate of at least 25 percent of the reaction rate provided by the organopolyphosphite ligand of said organopolyphosphite-metal ligand complex catalyst, (iii) optionally has a coordination strength with respect to the metal of gave This complex organopolyphosphite-metal ligand complex catalyst is greater than carbon monoxide and (iv) optionally when it complexes with the metal to form a complex catalyst by delineating sterically hindered organophosphorous and metal, it provides a ratio of normal product: branched isomer to less than the normal: branched product isomer ratio provided by the organopolyphosphite ligand of said organopolyphosphite to metal complex ligand catalyst. Furthermore, it refers to a method for monitoring the depletion of said organopolyphosphite ligand, to a reaction mixture prepared by said procedure, and to a decatalyst precursor composition used in said procedure.

ARP960105530A 1995-12-06 1996-12-06 A PROCEDURE THAT INCLUDES REACTIONING ONE OR MORE REAGENTS IN THE PRESENCE OF A COMPLEX CATALYST OF METAL-ORGANOPOLYPHOSPHITE LEAGUE AND LIGAND OF OPTIONALLY FREE ORGANOPOLYPHOSPHITE AND A QUANTITY OF ORIGANOPHOSPHOROUSLY LABORATED MATERIALS AR004882A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US828995P 1995-12-06 1995-12-06

Publications (1)

Publication Number Publication Date
AR004882A1 true AR004882A1 (en) 1999-03-10

Family

ID=21730803

Family Applications (10)

Application Number Title Priority Date Filing Date
ARP960105528A AR004880A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR PRODUCING ONE OR MORE PRODUCTS IN A COVER REACTOR THAT HAS MORE THAN ONE REACTIVE STAGE.
ARP960105529A AR004881A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR SEPARATING ONE OR MORE PHOSPHORIC ACID COMPOUNDS FROM A REACTION PRODUCT FLUID CONTAINING ONE OR MORE PHOSPHORUS ACID COMPOUNDS, AN ORGANOPHYPHOSPHYTIC LIGAND-LIGAND-LIGAND COMPOSITE CATALYST
ARP960105535A AR004887A1 (en) 1995-12-06 1996-12-06 A PROCEDURE THAT INCLUDES REACTIONING ONE OR MORE REAGENTS IN THE PRESENCE OF A METAL COMPLEX CATALYST-LINKING ORGANOPHOSPHITE AND AGUADISUELTA AND OPTIONALLY LINKING ORGANOFOSFITO LIBRE
ARP960105532A AR004884A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR SEPARATING ONE OR MORE PHOSPHORIC ACID COMPOUNDS FROM A REACTION PRODUCT FLUID CONTAINING ONE OR MORE PHOSPHORUS ACID COMPOUNDS, AN ORGANOPHOSPHITE AND OPTIONALLY ORGANOPHOSTIC METALLIC-LIGAND COMPOUND CATALYST
ARP960105527A AR004879A1 (en) 1995-12-06 1996-12-06 METHOD FOR STABILIZING A COMPLEX ORGANOPOLYPHOSPHYTE-METAL LEAGUE CATALYZER AGAINST DEACTIVATION AND DEHYDROFORMILATION, HYDROAMIDATION, HYDROESTERIFICATION OR CARBONYLATION PROCEDURE USING SUCH A STABILIZED CATALYST
ARP960105531A AR004883A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR SEPARATING ONE OR MORE PHOSPHORIC ACID COMPOUNDS FROM A REATION PRODUCT FLUID CONTAINING ONE OR MORE PHOSPHORUS ACID COMPOUNDS, A CATALYST OF METAL-LIGAND ORGANOPHOSPHITE COMPOUND AND OPTIONALLY LIGATING ORGANOPHOSPHITE
ARP960105536A AR004888A1 (en) 1995-12-06 1996-12-06 A PROCEDURE THAT INCLUDES REACTIONING ONE OR MORE REAGENTS IN THE PRESENCE OF A METAL-LIGAND ORGANOPOLYPHOSPHITE COMPLEX CATALYST
ARP960105530A AR004882A1 (en) 1995-12-06 1996-12-06 A PROCEDURE THAT INCLUDES REACTIONING ONE OR MORE REAGENTS IN THE PRESENCE OF A COMPLEX CATALYST OF METAL-ORGANOPOLYPHOSPHITE LEAGUE AND LIGAND OF OPTIONALLY FREE ORGANOPOLYPHOSPHITE AND A QUANTITY OF ORIGANOPHOSPHOROUSLY LABORATED MATERIALS
ARP960105534A AR004886A1 (en) 1995-12-06 1996-12-06 A PROCEDURE THAT INCLUDES THE REACTION OF ONE OR MORE REAGENTS IN THE PRESENCE OF A COMPLEX METAL-ORGANOPOLYPHOSPHITE BINDING CATALYST TO PRODUCE A REACTION PRODUCT FLUID COMPRISING ONE OR MORE PRODUCTS
ARP960105533A AR004885A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR SEPARATING ONE OR MORE PHOSPHORIC ACID COMPOUNDS FROM A REACTION PRODUCT FLUID CONTAINING ONE OR MORE PHOSPHORUS ACID COMPOUNDS, AN ORGANOPHOSPHYT-LIGAND-ORIGANPHOSPHITE-LIGAND COMPOUND CATALYST AND OPTIONALLY

Family Applications Before (7)

Application Number Title Priority Date Filing Date
ARP960105528A AR004880A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR PRODUCING ONE OR MORE PRODUCTS IN A COVER REACTOR THAT HAS MORE THAN ONE REACTIVE STAGE.
ARP960105529A AR004881A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR SEPARATING ONE OR MORE PHOSPHORIC ACID COMPOUNDS FROM A REACTION PRODUCT FLUID CONTAINING ONE OR MORE PHOSPHORUS ACID COMPOUNDS, AN ORGANOPHYPHOSPHYTIC LIGAND-LIGAND-LIGAND COMPOSITE CATALYST
ARP960105535A AR004887A1 (en) 1995-12-06 1996-12-06 A PROCEDURE THAT INCLUDES REACTIONING ONE OR MORE REAGENTS IN THE PRESENCE OF A METAL COMPLEX CATALYST-LINKING ORGANOPHOSPHITE AND AGUADISUELTA AND OPTIONALLY LINKING ORGANOFOSFITO LIBRE
ARP960105532A AR004884A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR SEPARATING ONE OR MORE PHOSPHORIC ACID COMPOUNDS FROM A REACTION PRODUCT FLUID CONTAINING ONE OR MORE PHOSPHORUS ACID COMPOUNDS, AN ORGANOPHOSPHITE AND OPTIONALLY ORGANOPHOSTIC METALLIC-LIGAND COMPOUND CATALYST
ARP960105527A AR004879A1 (en) 1995-12-06 1996-12-06 METHOD FOR STABILIZING A COMPLEX ORGANOPOLYPHOSPHYTE-METAL LEAGUE CATALYZER AGAINST DEACTIVATION AND DEHYDROFORMILATION, HYDROAMIDATION, HYDROESTERIFICATION OR CARBONYLATION PROCEDURE USING SUCH A STABILIZED CATALYST
ARP960105531A AR004883A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR SEPARATING ONE OR MORE PHOSPHORIC ACID COMPOUNDS FROM A REATION PRODUCT FLUID CONTAINING ONE OR MORE PHOSPHORUS ACID COMPOUNDS, A CATALYST OF METAL-LIGAND ORGANOPHOSPHITE COMPOUND AND OPTIONALLY LIGATING ORGANOPHOSPHITE
ARP960105536A AR004888A1 (en) 1995-12-06 1996-12-06 A PROCEDURE THAT INCLUDES REACTIONING ONE OR MORE REAGENTS IN THE PRESENCE OF A METAL-LIGAND ORGANOPOLYPHOSPHITE COMPLEX CATALYST

Family Applications After (2)

Application Number Title Priority Date Filing Date
ARP960105534A AR004886A1 (en) 1995-12-06 1996-12-06 A PROCEDURE THAT INCLUDES THE REACTION OF ONE OR MORE REAGENTS IN THE PRESENCE OF A COMPLEX METAL-ORGANOPOLYPHOSPHITE BINDING CATALYST TO PRODUCE A REACTION PRODUCT FLUID COMPRISING ONE OR MORE PRODUCTS
ARP960105533A AR004885A1 (en) 1995-12-06 1996-12-06 A PROCEDURE FOR SEPARATING ONE OR MORE PHOSPHORIC ACID COMPOUNDS FROM A REACTION PRODUCT FLUID CONTAINING ONE OR MORE PHOSPHORUS ACID COMPOUNDS, AN ORGANOPHOSPHYT-LIGAND-ORIGANPHOSPHITE-LIGAND COMPOUND CATALYST AND OPTIONALLY

Country Status (3)

Country Link
AR (10) AR004880A1 (en)
CZ (3) CZ175098A3 (en)
MY (1) MY115227A (en)

Also Published As

Publication number Publication date
CZ175498A3 (en) 1998-11-11
AR004881A1 (en) 1999-03-10
AR004888A1 (en) 1999-03-10
AR004885A1 (en) 1999-03-10
AR004880A1 (en) 1999-03-10
CZ175198A3 (en) 1998-10-14
MY115227A (en) 2003-04-30
AR004886A1 (en) 1999-03-10
CZ175098A3 (en) 1998-11-11
AR004887A1 (en) 1999-03-10
AR004884A1 (en) 1999-03-10
AR004883A1 (en) 1999-03-10
AR004879A1 (en) 1999-03-10

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