ZA200400892B - Perfumed coloured speckle composition and particulate laundry detergent compositions containing it. - Google Patents
Perfumed coloured speckle composition and particulate laundry detergent compositions containing it. Download PDFInfo
- Publication number
- ZA200400892B ZA200400892B ZA200400892A ZA200400892A ZA200400892B ZA 200400892 B ZA200400892 B ZA 200400892B ZA 200400892 A ZA200400892 A ZA 200400892A ZA 200400892 A ZA200400892 A ZA 200400892A ZA 200400892 B ZA200400892 B ZA 200400892B
- Authority
- ZA
- South Africa
- Prior art keywords
- granular
- perfume
- detergent composition
- perfumed
- composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 38
- 239000003599 detergent Substances 0.000 title claims description 20
- 239000002304 perfume Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 9
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 239000012876 carrier material Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 239000011236 particulate material Substances 0.000 claims description 4
- -1 alkali metal aluminosilicate Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 150000003138 primary alcohols Chemical class 0.000 claims description 2
- 150000003333 secondary alcohols Chemical class 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 238000012505 colouration Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000012875 nonionic emulsifier Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0034—Fixed on a solid conventional detergent ingredient
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Description
) PERFUMED COLOURED SPECKLE COMPOSITION AND PARTICULATE
LAUNDRY DETERGENT COMPOSITIONS CONTAINING IT
The present invention relates to coloured perfumed speckles for use in granular laundry detergent compositions and a process for making them.
BACKGROUND AND PRIOR ART
Commercial laundry detergent washing powders often contain ingredients which do not provide any cleaning function but provide an additional benefit to the consumer. One such commonly used ingredient is perfume. Perfume is added to improve aesthetic appeal by imparting a pleasing odour both during storage and in use. Additionally it may impart a pleasing odour to the washed fabrics. By their very nature perfumes are highly volatile and the amount remaining on the washed clothes by the end of the washing process is usually a small fraction of that which was added at the beginning.
There have been many attempts to improve and control the release of perfume during the wash process.
WO 9734981 (Procter & Gamble) discloses a porous zeolite into which the perfume is absorbed and trapped by a release . inhibitor which hydrolyses during the wash thereby releasing the perfume in a controlled manner.
particle encapsulated in a glassy material and coated in a k water-soluble or dispersible compound. Preferably a perfume is supported or contained within the porous carrier.
EP 466235 (Quest) discloses a process of combining a perfume with one or more non-ionic emulsifiers to form a non-aqueous phase which is then mixed with an aqueous phase to form a structured emulsion containing liquid-crystal structures.
The emulsified perfume is added to a detergent powder and is said to enhance perfume delivery and possibly deposition.
Another ingredient which is commonly added and yet provides little or no washing function is visually striking ‘speckles’. Their primary function is to provide an attractive colouration to the powder and a cue to prompt the consumer into associating the speckles with a separate functional effect.
US 5 605 883 (Iliff et al) discloses a colourant speckle which exhibits reduced spotting of teated fabrics. It also states that the speckle may be used as a vehicle for carrying cosurfactants, enzymes, oxidants, bleach activators and fragrances.
US 4 097 418 (Procter & Gamble) discloses a granular coloured speckle having reduced staining properties and may . comprise up to 3% of enzymes, bleaching agents, antimicrobial agents, corrosion inhibitors and perfume.
Surprisingly the present inventors have discovered that the delivery of perfume may be significantly enhanced and prolonged if the perfume is included in coloured speckles.
Especially advantageous perfume delivery can be achieved if the perfume is incorporated in the speckles in aqueous emulsion form. Additionally the colouration of the speckles may provide an association with the enhanced perfume delivery in the mind of the consumer, thus reinforcing the consumer's appreciation of the wash process.
In a first aspect, the present invention provides a perfumed coloured granular composition for use as speckles in a particulate laundry detergent composition which comprises at least 1 wt% perfume.
In a second aspect, the present invention provides a process for the manufacture of a perfumed coloured granular composition for use as speckles in a particulate laundry detergent composition, comprising the steps of: (i) mixing an aqueous perfume emulsion and a colourant with an inorganic granular carrier material; and ' (ii) layering the resultant material with a finely divided porous particulate material.
In a third aspect, the present invention provides a perfumed particulate laundry detergent composition comprising a minor
) proportion of a coloured speckle composition wherein at least 10 wt% of the total amount of perfume in the detergent
LL) composition is located in the speckles.
The Speckles
The speckles (perfumed coloured granular composition) comprise a perfume, preferably in aqueous emulsion form, and a colourant, on an inorganic granular carrier material. The speckles comprise at least 1 wt% perfume and preferably comprise at least 1.5 wt%.
It is preferred that, before drying, the perfume is present in the form of an aqueous emulsion. In this case the speckles suitably comprise emulsifier. It is preferred that the speckles are obtainable from a process as defined in detail below.
The Perfume
As used herein the term "perfume" denotes one or a mixture of perfume components, optionally mixed with a suitable solvent, diluent or carrier, which is used to impart a desired odour to the particulate laundry detergent composition in the package and/or in use and/or to the . fabrics that are washed.
A range of perfumes and solvents which may be used are disclosed in EP 466 235 B (Quest).
) The Aqueous Emulsion ) The perfume is preferably incorporated in the speckles as an aqueous emulsion. Such emulsions suitably contain from 1 to 50 wt% of perfume, from 1 to 30 wt% of one or more non-ionic emulsifiers and from 20 to 98 wt% of water or an aqueous mixture containing water-soluble and/or water-dispersible materials, hereinafter jointly referred to as "aqueous phase". Such water-soluble or water-dispersible materials may form up to 30 wt¥%¥ of the aqueous phase.
It is particularly suitable that the weight ratio of total emulsifier to perfume lies within the range of from 1:5 to 3:1 and the weight ratio of non-aqueous phase to aqueous phase lies within the range of from 1:2 to 4:3, preferably within the range of from 1:2 to 1:1.
Non-ionic emulsifiers suitable for use in the present invention are exemplified in EP 466 235 B, for example the primary and secondary alcohol ethoxylates, especially the
Cg-Cpo aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the Cj10-Ci15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol, preferably from 4 to 9. Non-ethoxylated nonionic surfactants include alkylpoly- ) glycosides, glycerol moncethers, and polyhydroxyamides (glucamide) .
- [) -
An especially preferred nonionic emulsifier is C30-Cis, preferably Ci12-Cis, aliphatic alcohol ethoxylated with an average of from 4 to 9 moles of ethylene oxide, preferably 5 to 7, per mole of alcohol.
The emulsion may be produced by forming a non-aqueous phase comprising the perfume, a non-ionic emulsifier or mixture based on non-ionic emulsifiers, and optionally other adjuncts, which is mixed at a temperature at which the non- aqueous phase forms a homogeneous liquid; forming an aqueous phase consisting of water or an aqueous solution of water- soluble or water-dispersible materials; and finally mixing the two phases under shear conditions.
The Process
The perfumed coloured granular composition for use as speckles in a particulate laundry detergent composition according to the present invention may be manufactured by the following process: (i) mixing an aqueous perfume emulsion and a colourant with an inorganic granular carrier material; and (ii) layering the resultant material with a finely divided porous particulate material.
The colourant may be a pigment or a water-dispersible dye.
Optionally the inorganic carrier material may be layered prior to step (i) with a finely divided porous particulate
Claims (15)
1. A perfumed coloured granular composition for use as speckles in a particulate laundry detergent composition characterised in that it comprises at least 1 wt% perfume.
2. A granular composition as claimed in claim 1, characterised in that it comprises at least 1.5 wt% perfume.
3. A granular composition according to claim 1 or claim 2, characterised in that it comprises emulsifier.
4. A granular composition according to claim 3, characterised in that the emulsifier is a Cg to Cp primary or secondary alcohol ethoxylate ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol.
5. A process for the manufacture of a perfumed coloured granular composition for use as speckles in a particulate laundry detergent composition, characterised in that it comprises the steps of: (1) mixing an aqueous perfume emulsion and a colourant with an inorganic granular carrier material; and (ii) layering the resultant material with a finely divided porous particulate material. Amended Sheet —- 15-02-2005
6. A process according to claim 5, characterised in that the inorganic granular material is layered prior to step (i) with a finely divided porous particulate material.
7. A process according to claims 5 or claim 6, characterised in that the granular carrier material is sodium chloride.
8. A process according to any one of claims 5 to 7, characterised in that the porous particulate layering material comprises at least one material selected from silica and crystalline alkali metal aluminosilicate.
9. A perfumed coloured granular composition obtainable by a process according to any one of claims 5 to 8.
10. A perfumed particulate laundry detergent composition comprising a minor proportion of a coloured speckle composition characterised in that at least 10 wt% of the total amount of perfume in the detergent composition is located in the speckles.
11. A detergent composition according to claim 10, characterised in that at least 20 wt% of the total amount of perfume is located in the speckles. Amended Sheet - 15-02-2005
12. A detergent composition according to claim 10 or claim 11, characterised in that it comprises a granular composition according to any one of claims 1 to 4 and
9S.
13. A detergent composition according to claim 12, characterised in that it comprises from 1 to 10 wt% of the granular composition.
14. A detergent composition according to claim 13, characterised in that it comprises from 2 to 8 wt% of the granular composition.
15. A detergent composition according to any one of claims 10 to 14 characterised in that it comprises from 5 to 60 wt% surfactant and from 10 to 80 wt% builder.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0121176.2A GB0121176D0 (en) | 2001-08-31 | 2001-08-31 | Perfumed coloured speckle composition and particulate laundry detergent compositions containing it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200400892B true ZA200400892B (en) | 2005-04-26 |
Family
ID=9921340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200400892A ZA200400892B (en) | 2001-08-31 | 2004-02-03 | Perfumed coloured speckle composition and particulate laundry detergent compositions containing it. |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1421167B1 (en) |
| CN (1) | CN1578828A (en) |
| AR (1) | AR036308A1 (en) |
| AT (1) | ATE412044T1 (en) |
| BR (1) | BR0212135A (en) |
| DE (1) | DE60229532D1 (en) |
| ES (1) | ES2314085T3 (en) |
| GB (1) | GB0121176D0 (en) |
| WO (1) | WO2003020867A1 (en) |
| ZA (1) | ZA200400892B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0306152D0 (en) * | 2003-03-19 | 2003-04-23 | Givaudan Sa | Method |
| GB0315946D0 (en) * | 2003-07-08 | 2003-08-13 | Quest Int | Fabric freshener compositions |
| DE102004035552A1 (en) * | 2004-07-22 | 2006-02-16 | Henkel Kgaa | Non-ionic and / or perfume-containing soda-free particles for use in detergents or cleaners |
| DE102005043188A1 (en) * | 2005-09-09 | 2007-03-22 | Henkel Kgaa | Consumable products with changing odor images |
| GB0604676D0 (en) * | 2006-03-08 | 2006-04-19 | Reckitt Benckiser Nv | Method |
| FR2905954B1 (en) * | 2006-09-18 | 2012-09-28 | Roman Gerusz | PREVENTIVE AND / OR CURATIVE CLEANING AGENT FOR MATERIALS IN CONTACT WITH WATER |
| EP2206765A1 (en) | 2009-01-08 | 2010-07-14 | Unilever N.V. | Detergent composition |
| US9186642B2 (en) | 2010-04-28 | 2015-11-17 | The Procter & Gamble Company | Delivery particle |
| US9993793B2 (en) | 2010-04-28 | 2018-06-12 | The Procter & Gamble Company | Delivery particles |
| EP2694017B1 (en) | 2011-04-07 | 2019-05-22 | The Procter and Gamble Company | Personal cleansing compositions with increased deposition of polyacrylate microcapsules |
| WO2012138696A2 (en) | 2011-04-07 | 2012-10-11 | The Procter & Gamble Company | Shampoo compositions with increased deposition of polyacrylate microcapsules |
| MX2013010981A (en) | 2011-04-07 | 2013-10-30 | Procter & Gamble | Conditioner compositions with increased deposition of polyacrylate microcapsules. |
| GB201814981D0 (en) * | 2018-09-14 | 2018-10-31 | Reckitt Benckiser Finish Bv | Granulate |
| CN116507708A (en) * | 2020-11-19 | 2023-07-28 | 宝洁公司 | Process for preparing a detergent composition comprising perfume |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6166800A (en) * | 1984-09-07 | 1986-04-05 | 花王株式会社 | Modification of granular detergent |
| US5605883A (en) * | 1993-02-24 | 1997-02-25 | Iliff; Robert J. | Agglomerated colorant speckle exhibiting reduced colorant spotting |
| JPH11513062A (en) * | 1996-06-11 | 1999-11-09 | ザ、プロクター、エンド、ギャンブル、カンパニー | Method for producing granular laundry additive for fragrance delivery with improved physical properties |
| US6093258A (en) * | 1998-01-29 | 2000-07-25 | Mc Lean; Ildiko M. | Tint stain remover |
| GB0018774D0 (en) * | 2000-07-31 | 2000-09-20 | Unilever Plc | Coloured speckle composition and particulate laundry detergent compositions containing it |
-
2001
- 2001-08-31 GB GBGB0121176.2A patent/GB0121176D0/en not_active Ceased
-
2002
- 2002-08-13 AT AT02758462T patent/ATE412044T1/en not_active IP Right Cessation
- 2002-08-13 CN CN02821453.6A patent/CN1578828A/en active Pending
- 2002-08-13 ES ES02758462T patent/ES2314085T3/en not_active Expired - Lifetime
- 2002-08-13 DE DE60229532T patent/DE60229532D1/en not_active Expired - Lifetime
- 2002-08-13 EP EP02758462A patent/EP1421167B1/en not_active Expired - Lifetime
- 2002-08-13 WO PCT/EP2002/009051 patent/WO2003020867A1/en not_active Application Discontinuation
- 2002-08-13 BR BR0212135-2A patent/BR0212135A/en not_active Application Discontinuation
- 2002-08-29 AR ARP020103241A patent/AR036308A1/en active IP Right Grant
-
2004
- 2004-02-03 ZA ZA200400892A patent/ZA200400892B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE412044T1 (en) | 2008-11-15 |
| ES2314085T3 (en) | 2009-03-16 |
| EP1421167B1 (en) | 2008-10-22 |
| AR036308A1 (en) | 2004-08-25 |
| DE60229532D1 (en) | 2008-12-04 |
| WO2003020867A1 (en) | 2003-03-13 |
| GB0121176D0 (en) | 2001-10-24 |
| EP1421167A1 (en) | 2004-05-26 |
| BR0212135A (en) | 2004-08-24 |
| CN1578828A (en) | 2005-02-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4203851A (en) | Fabric softening compositions and methods for manufacture thereof | |
| ZA200400892B (en) | Perfumed coloured speckle composition and particulate laundry detergent compositions containing it. | |
| EP2145947B1 (en) | Laundry treatment compositions | |
| EP1948773B1 (en) | Fragrant consumer products comprising oxidizing agents | |
| EP1367118B1 (en) | Liquid laundry detergent with emulsion layer | |
| US4675127A (en) | Process for preparing particulate detergent compositions | |
| CA2094786C (en) | Rinse conditioner | |
| US7776812B2 (en) | Multiple emulsion hard surface cleaning compositions | |
| AU627734B2 (en) | Stable and homogeneous concentrated all purpose cleaner | |
| EP0466235A1 (en) | Process for preparing perfumed detergent products | |
| US20120165239A1 (en) | Solid fragrance-emitting composition | |
| MXPA05002497A (en) | Structuring systems for fabric treatment compositions. | |
| IE913342A1 (en) | Stable microemulsion disinfecting detergent composition | |
| CN101313060A (en) | Microcapsule and method of producing same | |
| CZ42694A3 (en) | Process for preparing particles protecting water-responsive material | |
| EP2038391A1 (en) | Washing, cleaning and care products | |
| JP2003504490A (en) | Microcapsule preparations and detergents and detergents containing microcapsules | |
| CA2115544A1 (en) | Solid, particulate fabric softener with protected, dryer-activated cyclodextrin/perfume complex | |
| WO2014044461A2 (en) | Stabilization of capsule systems in laundry detergents and other cleaning products | |
| IE60011B1 (en) | Stable liquid diperoxyacid bleach | |
| JPH10501296A (en) | Aqueous emulsion containing hydrophobic brightener, hydrophilic surfactant and hydrophobic surfactant | |
| EP3847229B1 (en) | Foamable cleaning composition | |
| GB2288813A (en) | Granular Detergent Composition | |
| JPH05502900A (en) | Non-caustic oven cleaner, method of manufacturing it and method of using it | |
| DK163308B (en) | ANTI-EFFICIENT EFFECTIVE LIQUID CLEANING BENTONITE |