WO2023169087A1 - Thermal management and thermal spread suppression method for power battery based on lumped model - Google Patents

Thermal management and thermal spread suppression method for power battery based on lumped model Download PDF

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WO2023169087A1
WO2023169087A1 PCT/CN2023/072481 CN2023072481W WO2023169087A1 WO 2023169087 A1 WO2023169087 A1 WO 2023169087A1 CN 2023072481 W CN2023072481 W CN 2023072481W WO 2023169087 A1 WO2023169087 A1 WO 2023169087A1
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thermal
power battery
battery
management
thermal management
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PCT/CN2023/072481
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French (fr)
Chinese (zh)
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崔纳新
周剑文
李长龙
陆东
张承慧
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山东大学
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Publication of WO2023169087A1 publication Critical patent/WO2023169087A1/en

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    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F30/00Computer-aided design [CAD]
    • G06F30/10Geometric CAD
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F30/00Computer-aided design [CAD]
    • G06F30/20Design optimisation, verification or simulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/613Cooling or keeping cold
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/62Heating or cooling; Temperature control specially adapted for specific applications
    • H01M10/625Vehicles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6556Solid parts with flow channel passages or pipes for heat exchange
    • H01M10/6557Solid parts with flow channel passages or pipes for heat exchange arranged between the cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/656Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
    • H01M10/6567Liquids
    • H01M10/6568Liquids characterised by flow circuits, e.g. loops, located externally to the cells or cell casings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/659Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F2119/00Details relating to the type or aim of the analysis or the optimisation
    • G06F2119/08Thermal analysis or thermal optimisation
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F2119/00Details relating to the type or aim of the analysis or the optimisation
    • G06F2119/14Force analysis or force optimisation, e.g. static or dynamic forces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present disclosure belongs to the field of battery management technology, and specifically relates to a power battery thermal management and thermal spread suppression method based on a lumped model.
  • Lithium-ion batteries are commonly used as power sources for electric vehicles due to their high energy and power density, no memory effect, and long cycle life.
  • the safety of power batteries is the first issue to be considered and solved in the development process of electric vehicles, as battery energy density continues to increase. Thermal runaway accidents of electric vehicle batteries occur frequently, which limits the large-scale application of electric vehicles. Therefore, research on power battery thermal management needs to be carried out.
  • the battery pack of electric vehicles needs to apply real-time thermal management methods to ensure and predict the safe use of the battery.
  • thermal management methods of battery packs under normal operating conditions at room temperature have been relatively complete, including air cooling, liquid cooling, phase change materials and other thermal management methods. management methods and a combination of multiple thermal management methods.
  • thermal management structure that suppresses the spread of thermal runaway. If the heat dissipation direction is consistent with the direction of thermal runaway spread, it may even aggravate the spread of thermal runaway; in addition, existing thermal runaway devices that incorporate thermal management systems Most of the spread models are finite element models, which results in slow calculation speed. It is difficult to apply to actual vehicles; currently, none of the existing models for quickly predicting the spread of thermal runaway has incorporated a thermal management system.
  • the present disclosure proposes a power battery thermal management and thermal spread suppression method based on a lumped model.
  • a structure based on a combination of phase change materials and liquid-cooled small micro-channels is used as a thermal management system to suppress the spread of thermal runaway.
  • the liquid cooling flow direction is vertical direction, there is no possibility of aggravating the spread of thermal runaway, and the effect of suppressing thermal runaway is fast and effective.
  • the solution of the present disclosure provides a lumped model-based power battery thermal management and thermal spread suppression method, adopting the following technical solution:
  • a lumped model-based power battery thermal management and thermal spread suppression method includes the following steps:
  • the thermal management geometry of the power battery is constructed based on liquid-cooled small micro-channels and phase change materials
  • a management module to suppress the spread of thermal runaway is added to the lumped model, predicts the temperature change of the power battery based on the lumped model, determines the conditions for triggering thermal runaway of the power battery, and starts all the thermal runaway triggering conditions of the power battery before reaching it.
  • the liquid-cooled small micro-channels suppress the spread of thermal runaway and achieve thermal management of power batteries.
  • the phase change material is wrapped around each single cell, and the liquid cooling small micro-channels are arranged along the single cell. Vertical arrangement of batteries.
  • the thermal management geometry uses the phase change material to dissipate heat; when the single battery enters a thermal runaway state, the thermal management geometry restarts the liquid-cooled small micro-channel for heat dissipation. Suppress the spread of thermal runaway in power batteries.
  • the single cell heat production model includes the heat production of the single cell during normal operation and the heat production of the single cell when thermal runaway occurs.
  • the physical parameters of the thermal management geometric structure include the heat capacity of the single cell, the thermal resistance of the single cell, the contact thermal resistance between single cells, the heat capacity of the thermal management material, the thermal resistance of the single cell, The contact thermal resistance to the thermal management material, the convective thermal resistance of the single cell, and the convective thermal resistance of the thermal management material.
  • the lumped thermal resistance network of the power battery is established based on the established single battery heat generation model and physical parameters, and the lumped thermal resistance of the power battery is established based on the equivalent circuit. Model.
  • the heat transfer characteristics of the battery such as the heat capacity of the single cell, the conductive thermal resistance inside the single cell, and the contact thermal resistance between single cells were obtained.
  • the obtained lumped thermal resistance network is represented by an equivalent circuit, the output of the equivalent current source is used to represent the heat generation model of the single cell; the equivalent capacitance is used to represent the heat capacity of the single cell; the equivalent resistance is used Indicates the thermal conduction resistance inside the battery, the contact thermal resistance between batteries, etc.
  • the final equivalent circuit is built using MATLAB Simulink.
  • the lumped thermal resistance network of the power battery includes a battery thermal resistance network for normal operation of the power battery and a power battery thermal resistance network containing small micro-channels.
  • the lumped model is represented by an equivalent circuit composed of an equivalent current source, an equivalent resistance and an equivalent capacitance; wherein the output of the equivalent current source represents the single cell heat generation model; The equivalent capacitance represents the heat capacity of the single cell; the equivalent resistance represents the thermal resistance.
  • the management module for suppressing the spread of thermal runaway includes a phase change material module and a liquid cooling module; the phase change material module around the single cell is treated as a whole.
  • the phase change material undergoes a phase change from solid to liquid when the material is heated to the melting temperature.
  • the thermal management module consists of a phase change material module and a liquid cooling module.
  • the thermal management starts the liquid cooling module.
  • the phase change material model and the liquid cooling module run at the same time.
  • the liquid cooling and phase change materials jointly dissipate heat to inhibit the spread of thermal runaway of the power battery; the thermal management module is added to the equivalent
  • the method in the circuit model is as follows. For the phase change material module, the phase change material around a battery is considered as a whole.
  • the heat capacity of the phase change material around a battery is represented by a variable capacitor, and the contact thermal resistance between the battery and the thermal management material is represented by a resistance; for the liquid cooling module, in order to allow the model to simulate the effect of the liquid cooling flow, a small micro
  • the liquid in the channel is divided into two parts. Two capacitors are used to represent the heat capacity of the entire small microchannel. The heat dissipation cycle is realized through the switch control of the circuit and the simulation of liquid cooling is realized.
  • the power battery when it is determined that the power battery triggers thermal runaway conditions, when the power battery temperature exceeds the preset value of the thermal runaway temperature or the power battery temperature rise rate exceeds the preset value of the thermal runaway temperature rise rate, the power battery undergoes thermal runaway.
  • This disclosure is based on a structure that combines phase change materials and liquid-cooled small micro-channels as a thermal management system to suppress the spread of thermal runaway. It fully considers the possible spread direction of thermal runaway.
  • the liquid cooling flow direction is in the vertical direction, and there is no aggravation of the spread of thermal runaway. The possibility of suppressing thermal runaway is fast and effective.
  • Figure 1 is a flow chart of a power battery thermal management and thermal spread suppression method based on a lumped model in an embodiment of the present disclosure
  • Figure 2 is a structural schematic diagram of the thermal management geometry of a power battery in an embodiment of the present disclosure
  • Figure 3 is another structural schematic diagram of the thermal management geometry of the power battery in an embodiment of the present disclosure.
  • Figure 4 is a schematic structural diagram of a thermal resistance network of a power battery in an embodiment of the present disclosure
  • Figure 5 is a schematic structural diagram of a thermal resistance network of small microchannels in an embodiment of the present disclosure
  • Figure 6 is an equivalent circuit diagram of a lumped model in an embodiment of the present disclosure.
  • Figure 7 is a schematic diagram of a simulation of a small microchannel in an embodiment of the present disclosure.
  • Figure 8(a) is a schematic diagram of temperature changes of a thermal runaway triggered battery in an embodiment of the present disclosure
  • Figure 8(b) is a schematic diagram of temperature changes of adjacent batteries in an embodiment of the present disclosure.
  • Figure 9 is a schematic diagram comparing the calculation time of the model in the embodiment of the present disclosure.
  • FIG 10 is a schematic diagram of temperature changes of a thermal runaway triggered battery (Battery-1) and an adjacent battery (Battery-2) in an embodiment of the present disclosure
  • Figure 11 is a schematic diagram of the temperature changes of a thermal runaway triggered battery and adjacent batteries when liquid cooling is added or not in an embodiment of the present disclosure
  • Figure 12 is a schematic diagram of temperature changes when multiple batteries simultaneously trigger thermal runaway in an embodiment of the present disclosure
  • Embodiment 1 of the present disclosure introduces a power battery thermal management and thermal spread suppression method based on a lumped model.
  • a power battery thermal management and thermal spread suppression method based on a lumped model includes the following steps:
  • the thermal management geometry of the power battery is constructed based on liquid-cooled small micro-channels and phase change materials
  • a management module to suppress the spread of thermal runaway is added to the lumped model, predicts the temperature change of the power battery based on the lumped model, determines the conditions for triggering thermal runaway of the power battery, and starts all the thermal runaway triggering conditions of the power battery before reaching it.
  • the liquid-cooled small micro-channels suppress the spread of thermal runaway and achieve thermal management of power batteries.
  • the thermal management geometry consists of small liquid-cooled microchannels and a phase change material. Paraffin is selected as a filler for the phase change material.
  • the phase change material is wrapped around the battery.
  • the phase change material is wrapped around each battery. It is 20g.
  • Small liquid-cooled micro-channels are arranged along the vertical direction of the battery.
  • the material of the micro-channel is an aluminum shell, and water is used as the coolant.
  • the total flow rate around each battery is 10L/min.
  • the thermal Manage geometry Structure the battery pack consists of a total of 12 batteries; when the batteries are working normally, only the PCM model is used for heat dissipation. When a battery enters a thermal runaway state, the system starts the liquid cooling module to inhibit the spread of thermal runaway of the battery.
  • the characteristic of the liquid-cooling micro-channel design is that it is composed of multiple small liquid-cooling channels. There are 12 channels distributed on both sides of the wide surface of each battery. The distribution method is that 6 channels are evenly distributed on both sides of the wide surface between each battery. channel, the liquid cooling flow direction is vertical.
  • the heat transfer relationship is established based on the connection mode between the battery and the thermal management system, and the thermal parameters of the lumped model are determined based on the heat transfer relationship.
  • the thermal parameters include the heat capacity of the battery, the thermal resistance inside the battery, Contact thermal resistance between batteries, heat capacity of thermal management materials, contact thermal resistance between batteries and thermal management materials, convection thermal resistance of batteries, and convection thermal resistance of thermal management materials.
  • the heat capacity of the battery is determined by the mass and specific heat capacity of the battery.
  • the thermal resistance inside the battery is determined by the axial thermal conductivity of the battery, the radial thermal conductivity of the battery and the geometric size of the battery.
  • the heat capacity of the thermal management material is determined by the thermal management material.
  • the mass and specific heat capacity of the battery are determined.
  • the thermal conduction resistance between the batteries is determined by the thermal conductivity and contact area between the batteries.
  • the thermal conduction resistance between the battery and the thermal management material is determined by the thermal conductivity and contact area of the battery and the thermal management material.
  • the thermal conductivity of the battery The convection thermal resistance is determined by the thermal conductivity and contact area between the battery and the air.
  • the convection thermal resistance of the thermal management material is determined by the thermal conductivity and contact area between the thermal management material and the air.
  • the formula for calculating the heat capacity of the battery is:
  • represents the battery density
  • C p represents the battery specific heat capacity
  • V represents the battery volume
  • the thermal resistance calculation formula inside the battery is:
  • ⁇ x, y, z represents the thickness in the x, y, and z directions inside the battery
  • ⁇ x, y, z represents the thermal conductivity in the x, y, and z directions inside the battery.
  • h c represents the convection heat transfer coefficient between batteries and between batteries and thermal management materials
  • A represents the contact area between batteries and between batteries and thermal management materials.
  • h cov is the convection heat transfer coefficient between the battery surface and the environment
  • a cov represents the contact area between the battery surface and the environment.
  • the thermal power of a single battery is composed of the heat generated when the battery is operating normally and the heat generated when the battery is thermally runaway.
  • the heat production rate of the battery during normal operation is determined by the Bernardi formula, and the expression is as follows:
  • I is the current
  • U is the battery terminal voltage
  • U oc is the battery open circuit voltage
  • V is the battery volume
  • T is the thermodynamic temperature
  • the heat-generating power of chemical reactions of various materials inside the battery can be expressed by a unified formula, namely
  • Q x (t) represents the reaction heat power of each battery component x, and the subscript x can be SEI, anode, electrolyte, cathode, etc.; c x d (t) represents the normalized concentration of the reactant.
  • ⁇ H x is the enthalpy of chemical reaction of reactant x, that is, the total heat released after the reactant reacts completely.
  • ⁇ H e represents the total electric energy of the battery when an internal short circuit occurs
  • ⁇ t represents the average time for electric energy release.
  • ⁇ t is set to 10 seconds.
  • a battery lumped thermal resistance parameter network is established; a lumped thermal resistance network is established based on the heat transfer relationship between the battery and the thermal management system.
  • the thermal resistance network of the battery during normal operation consists of the battery pack and the phase change material module.
  • the thermal resistance network of the power battery is shown in Figure 4. Heat is transferred between the thermal resistance and adjacent batteries, the external environment and the phase change material module.
  • the phase change material around a battery is also considered as a whole, represented by a temperature node, and heat is transferred between the battery and the external environment through thermal resistance.
  • T c represents the temperature of the central cell
  • T neight represents the temperature of adjacent cells
  • R c represents the contact resistance between cells
  • R h represents the convection resistance between the cell surface and the surrounding environment
  • R x , R y , R z means respectively in the battery cell part and The conductive resistance in the x, y and z directions between the cell surfaces
  • R pcm represents the conductive thermal resistance inside the phase change material.
  • the energy balance equation at the battery node is, as follows
  • Q represents the heat generation rate when the battery is thermally runaway.
  • M c and C p,cell represent the mass and specific heat capacity of the battery respectively.
  • FIG. 5 A section of small microchannels is considered as a whole and represented by a temperature node, which transfers heat to adjacent cells through thermal resistance.
  • TL represents the temperature of the small microchannel
  • RL represents the contact resistance between the battery and the small microchannel.
  • the model is represented by an equivalent circuit, which consists of an equivalent current source, an equivalent thermal resistance and an equivalent capacitance, as shown in Figure 6.
  • the heat-generating power of the battery is represented by the output of the current source
  • the heat capacity of the battery is represented by the capacitance.
  • the conductive thermal resistance between the battery and the battery is represented by resistance
  • the convection thermal resistance between the battery and the air is represented by resistance.
  • the thermal management module is added based on the battery lumped thermal resistance parameter model.
  • the heat capacity is represented by a variable capacitance
  • the thermal resistance between the battery and the thermal management material is represented by a resistance
  • the liquid cooling module in order for the model to simulate the effect of liquid cooling flow, the liquid in a small microchannel is divided into two parts, Two capacitors are used to represent the heat capacity of the entire small microchannel, and the heat dissipation cycle is realized through the switch control of the circuit to realize the simulation of liquid cooling, as shown in Figure 7.
  • the battery reaches thermal runaway condition.
  • the power battery temperature exceeds 150°C, or the temperature rise rate dT/dt exceeds 1°C/s, the power battery is considered to have thermal runaway.
  • thermal management model In order to verify the accuracy of the thermal resistance model, COMSOL was used to establish a three-dimensional thermal management model that suppresses the spread of thermal runaway.
  • the thermal runaway of the battery is triggered by acupuncture.
  • the thermal management model consists of liquid-cooled small micro-channels and phase change materials.
  • the phase change material Wrapped around the battery, liquid-cooled small micro-channels are arranged along the vertical direction of the battery; the same thermal management model for suppressing the spread of thermal runaway is established using the lumped thermal resistance model of the present invention, and the results of the two models for suppressing the spread of thermal runaway are compared.
  • Figure 8(a) and Figure 8(b) respectively show the temperature changes of the thermal runaway triggered battery and adjacent batteries. It can be seen that the thermal management system inhibits the spread of thermal runaway. At the same time, the results of the two models are very close, proving that Reliability of lumped models.
  • the liquid-cooled small micro-channel module After starting the thermal management system to suppress thermal runaway, the liquid-cooled small micro-channel module also started to work. At this time, the system began to predict the temperature of each battery cell based on the current cooling situation, and observed the thermal runaway triggered battery (Battery-1 ) and the temperature change of the adjacent battery (battery-2) of the thermal runaway triggered battery, as shown in Figure 11. The maximum temperature of the adjacent battery is predicted to be 83°C. After 700s, the thermal runaway triggered battery drops below 100°C, indicating thermal runaway. Spread is well suppressed.

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Abstract

A thermal management and thermal spread suppression method for a power battery based on a lumped model, which method relates to the technical field of battery management. The method comprises the following steps: constructing a thermal management geometric structure of a power battery on the basis of a liquid-cooling small/ micro-channel and a phase change material; acquiring physical property parameters of the thermal management geometric structure, and establishing battery cell thermal production models; according to a plurality of battery cell thermal production models and the physical property parameters combined with an equivalent circuit, constructing a lumped model of the power battery; and adding, into the lumped model, a management module for suppressing thermal runaway spread, predicting a temperature change of the power battery on the basis of the lumped model, determining that the power battery triggers a thermal runaway condition, and before a thermal runaway trigger condition of the power battery is met, starting the liquid-cooling small/micro-channel, so as to suppress thermal runaway spread. Therefore, thermal management of the power battery is realized.

Description

基于集总模型的动力电池热管理及热蔓延抑制方法Power battery thermal management and thermal spread suppression method based on lumped model
本发明要求于2022年3月10日提交中国专利局、申请号为202210238421.2、发明名称为“基于集总模型的动力电池热管理及热蔓延抑制方法”的中国专利申请的优先权,其全部内容通过引用结合在本发明中。This invention claims the priority of the Chinese patent application submitted to the China Patent Office on March 10, 2022, with the application number 202210238421.2 and the invention name "Power battery thermal management and thermal spread suppression method based on lumped model", and its entire content incorporated herein by reference.
技术领域Technical field
本公开属于电池管理技术领域,具体涉及一种基于集总模型的动力电池热管理及热蔓延抑制方法。The present disclosure belongs to the field of battery management technology, and specifically relates to a power battery thermal management and thermal spread suppression method based on a lumped model.
背景技术Background technique
本部分的陈述仅仅是提供了与本公开相关的背景技术信息,不必然构成在先技术。The statements in this section merely provide background technical information related to the present disclosure and do not necessarily constitute prior art.
锂离子电池由于其能量和功率密度高、无记忆效应和循环寿命长等优点,通常被用作电动汽车的电源。然而,动力电池的安全性是电动汽车发展过程中首先要考虑和解决的问题,随着电池能量密度不断提高。电动汽车的电池热失控事故时有发生,限制了电动汽车的大规模应用,因此需要开展动力电池热管理方面的研究。Lithium-ion batteries are commonly used as power sources for electric vehicles due to their high energy and power density, no memory effect, and long cycle life. However, the safety of power batteries is the first issue to be considered and solved in the development process of electric vehicles, as battery energy density continues to increase. Thermal runaway accidents of electric vehicle batteries occur frequently, which limits the large-scale application of electric vehicles. Therefore, research on power battery thermal management needs to be carried out.
电动汽车的电池组需要应用实时热管理方法来保证和预测电池的安全使用,目前电池组在常温下正常工况时的热管理方法已经较为完善,有风冷、液冷、相变材料等热管理方式以及多种热管理方式相结合的方法。The battery pack of electric vehicles needs to apply real-time thermal management methods to ensure and predict the safe use of the battery. At present, the thermal management methods of battery packs under normal operating conditions at room temperature have been relatively complete, including air cooling, liquid cooling, phase change materials and other thermal management methods. management methods and a combination of multiple thermal management methods.
据发明人了解,目前对于抑制热失控蔓延的热管理结构存在不合理的问题,若散热方向与热失控蔓延方向一致甚至可能会加剧热失控的蔓延;另外现有的加入热管理系统的热失控蔓延模型大部分是有限元模型,这就存在着计算速度慢, 难以应用于实车上;而目前已有的快速预测热失控蔓延模型都没有加入热管理系统,已有的快速预测热失控蔓延的模型有利用基于等效传热实验的热量传递函数来快速预测电池热失控后的蔓延情况,还有基于热阻建立电路模型快速预测热失控,两者不能做到有机结合,缺乏模型在有热管理系统抑制下的热失控蔓延情况的快速预测。According to the inventor's understanding, there are currently unreasonable problems with the thermal management structure that suppresses the spread of thermal runaway. If the heat dissipation direction is consistent with the direction of thermal runaway spread, it may even aggravate the spread of thermal runaway; in addition, existing thermal runaway devices that incorporate thermal management systems Most of the spread models are finite element models, which results in slow calculation speed. It is difficult to apply to actual vehicles; currently, none of the existing models for quickly predicting the spread of thermal runaway has incorporated a thermal management system. Existing models for quickly predicting the spread of thermal runaway use heat transfer functions based on equivalent heat transfer experiments to quickly predict The spread of battery thermal runaway and the rapid prediction of thermal runaway by building a circuit model based on thermal resistance cannot be organically combined, and there is a lack of models that can quickly predict the spread of thermal runaway under the suppression of a thermal management system.
发明内容Contents of the invention
为了解决上述问题,本公开提出了一种基于集总模型的动力电池热管理及热蔓延抑制方法,基于相变材料和液冷小微通道相结合的结构作为热管理系统来抑制热失控的蔓延,充分考虑热失控可能的蔓延方向,液冷流向为竖直方向,不存在加剧热失控蔓延的可能性,抑制热失控速度快效果好。In order to solve the above problems, the present disclosure proposes a power battery thermal management and thermal spread suppression method based on a lumped model. A structure based on a combination of phase change materials and liquid-cooled small micro-channels is used as a thermal management system to suppress the spread of thermal runaway. , fully consider the possible spreading direction of thermal runaway, the liquid cooling flow direction is vertical direction, there is no possibility of aggravating the spread of thermal runaway, and the effect of suppressing thermal runaway is fast and effective.
根据一些实施例,本公开的方案提供了一种基于集总模型的动力电池热管理及热蔓延抑制方法,采用如下的技术方案:According to some embodiments, the solution of the present disclosure provides a lumped model-based power battery thermal management and thermal spread suppression method, adopting the following technical solution:
一种基于集总模型的动力电池热管理及热蔓延抑制方法,包括以下步骤:A lumped model-based power battery thermal management and thermal spread suppression method includes the following steps:
基于液冷小微通道和相变材料构建动力电池的热管理几何结构;The thermal management geometry of the power battery is constructed based on liquid-cooled small micro-channels and phase change materials;
获取所述热管理几何结构的物性参数,建立单体电池产热模型;Obtain the physical parameters of the thermal management geometric structure and establish a single cell heat generation model;
根据多个单体电池产热模型构建动力电池的集总模型;Construct a lumped model of the power battery based on multiple single cell heat production models;
在所述集总模型中加入抑制热失控蔓延管理模块,基于所述集总模型预测所述动力电池的温度变化,确定动力电池触发热失控条件,在达到动力电池的热失控触发条件之前启动所述液冷小微通道,抑制热失控蔓延,实现动力电池的热管理。A management module to suppress the spread of thermal runaway is added to the lumped model, predicts the temperature change of the power battery based on the lumped model, determines the conditions for triggering thermal runaway of the power battery, and starts all the thermal runaway triggering conditions of the power battery before reaching it. The liquid-cooled small micro-channels suppress the spread of thermal runaway and achieve thermal management of power batteries.
作为进一步的技术限定,在所述构建动力电池的热管理几何结构的过程中,将所述相变材料包裹在每个单体电池的周围,将所述液冷小微通道设置为沿单体电池的竖直方向排列。 As a further technical limitation, in the process of constructing the thermal management geometry of the power battery, the phase change material is wrapped around each single cell, and the liquid cooling small micro-channels are arranged along the single cell. Vertical arrangement of batteries.
进一步的,单体电池正常工作时,所述热管理几何结构采用所述相变材料散热;单体电池进入热失控状态时,所述热管理几何结构再启动所述液冷小微通道散热,抑制动力电池的热失控蔓延。Further, when the single battery is operating normally, the thermal management geometry uses the phase change material to dissipate heat; when the single battery enters a thermal runaway state, the thermal management geometry restarts the liquid-cooled small micro-channel for heat dissipation. Suppress the spread of thermal runaway in power batteries.
作为进一步的技术限定,所述单体电池产热模型包括单体电池正常运行的产热量和单体电池热失控时的产热量。As a further technical limitation, the single cell heat production model includes the heat production of the single cell during normal operation and the heat production of the single cell when thermal runaway occurs.
作为进一步的技术限定,所述热管理几何结构的物性参数包括单体电池的热容、单体电池的热阻、单体电池之间的接触热阻、热管理材料的热容、单体电池与热管理材料的接触热阻、单体电池的对流热阻和热管理材料的对流热阻。As a further technical limitation, the physical parameters of the thermal management geometric structure include the heat capacity of the single cell, the thermal resistance of the single cell, the contact thermal resistance between single cells, the heat capacity of the thermal management material, the thermal resistance of the single cell, The contact thermal resistance to the thermal management material, the convective thermal resistance of the single cell, and the convective thermal resistance of the thermal management material.
进一步的,在构建动力电池的集总模型的过程中,基于所建立的单体电池产热模型和物性参数建立动力电池的集总热阻网络,结合等效电路建立动力电池的集总热阻模型。Furthermore, in the process of constructing the lumped model of the power battery, the lumped thermal resistance network of the power battery is established based on the established single battery heat generation model and physical parameters, and the lumped thermal resistance of the power battery is established based on the equivalent circuit. Model.
具体的,建立集总热阻网络后,得到了单体电池的热容、单体电池内部的传导热阻、单体电池之间的接触热阻等电池的传热特性。将得到的集总热阻网络用等效电路表示出来,用等效电流源的输出表示所述单体电池产热模型;用等效电容表示所述单体电池的热容;用等效电阻表示电池内部的传导热阻、电池之间的接触热阻等,最后等效电路用MATLAB Simulink进行搭建。Specifically, after establishing the lumped thermal resistance network, the heat transfer characteristics of the battery such as the heat capacity of the single cell, the conductive thermal resistance inside the single cell, and the contact thermal resistance between single cells were obtained. The obtained lumped thermal resistance network is represented by an equivalent circuit, the output of the equivalent current source is used to represent the heat generation model of the single cell; the equivalent capacitance is used to represent the heat capacity of the single cell; the equivalent resistance is used Indicates the thermal conduction resistance inside the battery, the contact thermal resistance between batteries, etc. The final equivalent circuit is built using MATLAB Simulink.
进一步的,所述动力电池的集总热阻网络包括动力电池正常工作的电池热阻网络和含小微通道的动力电池热阻网络。Further, the lumped thermal resistance network of the power battery includes a battery thermal resistance network for normal operation of the power battery and a power battery thermal resistance network containing small micro-channels.
进一步的,所述集总模型通过由等效电流源、等效电阻和等效电容构成的等效电路表示;其中,所述等效电流源的输出表示所述单体电池产热模型;所述等效电容表示所述单体电池的热容;所述等效电阻表示热阻。Further, the lumped model is represented by an equivalent circuit composed of an equivalent current source, an equivalent resistance and an equivalent capacitance; wherein the output of the equivalent current source represents the single cell heat generation model; The equivalent capacitance represents the heat capacity of the single cell; the equivalent resistance represents the thermal resistance.
作为进一步的技术限定,所述抑制热失控蔓延管理模块包括相变材料模块和液冷模块组成;将单体电池周围的所述相变材料模块作为一个整体,当所述相变 材料被加热到熔化温度时,所述相变材料产生从固态到液态的相变。As a further technical limitation, the management module for suppressing the spread of thermal runaway includes a phase change material module and a liquid cooling module; the phase change material module around the single cell is treated as a whole. When the phase change The phase change material undergoes a phase change from solid to liquid when the material is heated to the melting temperature.
具体的,热管理模块由相变材料模块和液冷模块组成,在电池正常单体电池正常工作时,热管理只有相变材料模型在运行,即只有相变材料散热;当单体电池进入热失控状态时,热管理启动液冷模块,此时相变材料模型和液冷模块同时运行,液冷和相变材料共同散热,抑制动力电池的热失控蔓延;将热管理模块加入到在等效电路模型中的方法如下,对于相变材料模块,将一节电池周围的相变材料看成一个整体,同时因为相变材料在加热到熔化温度时,会产生从固态到液态的相变,所以一节电池周围的相变材料的热容用一个可变电容表示,电池与热管理材料的接触热阻用电阻表示;对于液冷模块,为了使模型模拟液体冷却流的效果,将一个小微通道的液体分为两个部分,用两个电容表示整节小微通道的热容,通过电路的开关控制实现散热循环,实现液体冷却的模拟。Specifically, the thermal management module consists of a phase change material module and a liquid cooling module. When the battery is operating normally, only the phase change material model is running in the thermal management, that is, only the phase change material dissipates heat; when the single battery enters the thermal In the runaway state, the thermal management starts the liquid cooling module. At this time, the phase change material model and the liquid cooling module run at the same time. The liquid cooling and phase change materials jointly dissipate heat to inhibit the spread of thermal runaway of the power battery; the thermal management module is added to the equivalent The method in the circuit model is as follows. For the phase change material module, the phase change material around a battery is considered as a whole. At the same time, because the phase change material will undergo a phase change from solid to liquid when heated to the melting temperature, so The heat capacity of the phase change material around a battery is represented by a variable capacitor, and the contact thermal resistance between the battery and the thermal management material is represented by a resistance; for the liquid cooling module, in order to allow the model to simulate the effect of the liquid cooling flow, a small micro The liquid in the channel is divided into two parts. Two capacitors are used to represent the heat capacity of the entire small microchannel. The heat dissipation cycle is realized through the switch control of the circuit and the simulation of liquid cooling is realized.
作为进一步的技术限定,在确定动力电池触发热失控条件时,当动力电池温度超过热失控温度预设值或动力电池温升速率超过热失控温升速率预设值时,动力电池发生热失控。As a further technical limitation, when it is determined that the power battery triggers thermal runaway conditions, when the power battery temperature exceeds the preset value of the thermal runaway temperature or the power battery temperature rise rate exceeds the preset value of the thermal runaway temperature rise rate, the power battery undergoes thermal runaway.
与现有技术相比,本公开的有益效果为:Compared with the existing technology, the beneficial effects of the present disclosure are:
本公开基于相变材料和液冷小微通道相结合的结构作为热管理系统来抑制热失控的蔓延,充分考虑热失控可能的蔓延方向,液冷流向为竖直方向,不存在加剧热失控蔓延的可能性,抑制热失控速度快效果好。This disclosure is based on a structure that combines phase change materials and liquid-cooled small micro-channels as a thermal management system to suppress the spread of thermal runaway. It fully considers the possible spread direction of thermal runaway. The liquid cooling flow direction is in the vertical direction, and there is no aggravation of the spread of thermal runaway. The possibility of suppressing thermal runaway is fast and effective.
附图说明Description of drawings
构成本公开的一部分的说明书附图用来提供对本公开的进一步理解,本公开的示意性实施例及其说明用于解释本公开,并不构成对本公开的不当限定。The description drawings that form a part of the present disclosure are used to provide a further understanding of the present disclosure. The illustrative embodiments of the present disclosure and their descriptions are used to explain the present disclosure and do not constitute an improper limitation of the present disclosure.
图1是本公开实施例中的基于集总模型的动力电池热管理及热蔓延抑制方法的流程图; Figure 1 is a flow chart of a power battery thermal management and thermal spread suppression method based on a lumped model in an embodiment of the present disclosure;
图2是本公开实施例中的动力电池的热管理几何结构的一种结构示意图;Figure 2 is a structural schematic diagram of the thermal management geometry of a power battery in an embodiment of the present disclosure;
图3是本公开实施例中的动力电池的热管理几何结构的另一种结构示意图;Figure 3 is another structural schematic diagram of the thermal management geometry of the power battery in an embodiment of the present disclosure;
图4是本公开实施例中的动力电池的热阻网络结构示意图;Figure 4 is a schematic structural diagram of a thermal resistance network of a power battery in an embodiment of the present disclosure;
图5是本公开实施例中的小微通道的热阻网络结构示意图;Figure 5 is a schematic structural diagram of a thermal resistance network of small microchannels in an embodiment of the present disclosure;
图6是本公开实施例中的集总模型的等效电路图;Figure 6 is an equivalent circuit diagram of a lumped model in an embodiment of the present disclosure;
图7是本公开实施例中的小微通道的模拟示意图;Figure 7 is a schematic diagram of a simulation of a small microchannel in an embodiment of the present disclosure;
图8(a)是本公开实施例中的热失控触发电池的温度变化示意图;Figure 8(a) is a schematic diagram of temperature changes of a thermal runaway triggered battery in an embodiment of the present disclosure;
图8(b)是本公开实施例中的相邻电池的温度变化示意图;Figure 8(b) is a schematic diagram of temperature changes of adjacent batteries in an embodiment of the present disclosure;
图9是本公开实施例中的模型的计算时间比较示意图;Figure 9 is a schematic diagram comparing the calculation time of the model in the embodiment of the present disclosure;
图10是本公开实施例中的热失控触发电池(电池-1)以及相邻电池(电池-2)的温度变化示意图;Figure 10 is a schematic diagram of temperature changes of a thermal runaway triggered battery (Battery-1) and an adjacent battery (Battery-2) in an embodiment of the present disclosure;
图11是本公开实施例中的加无液冷时热失控触发电池和相邻电池的温度变化示意图;Figure 11 is a schematic diagram of the temperature changes of a thermal runaway triggered battery and adjacent batteries when liquid cooling is added or not in an embodiment of the present disclosure;
图12是本公开实施例中的多节电池同时触发热失控的温度变化示意图;Figure 12 is a schematic diagram of temperature changes when multiple batteries simultaneously trigger thermal runaway in an embodiment of the present disclosure;
其中,1、1号电池,2、2号电池,3、3号电池,4、4、号电池,5、5号电池,6、6号电池,7、7号电池,8、8号电池,9、9号电池,10、10号电池,11、11号电池,12、12号电池,13、电池,14、相变材料,15、液冷通道,16、冷却液入口,17、冷却液出口,18、冷却液热容,19、电路开关,20、与电池的接触热阻,21、与外界的接触热阻。Among them, No. 1 and No. 1 batteries, No. 2 and No. 2 batteries, No. 3 and No. 3 batteries, No. 4 and No. 4 batteries, No. 5 and No. 5 batteries, No. 6 and No. 6 batteries, No. 7 and No. 7 batteries, No. 8 and No. 8 batteries , 9. AA battery, 10. AA battery, 11. AA battery, 12. AA battery, 13. Battery, 14. Phase change material, 15. Liquid cooling channel, 16. Coolant inlet, 17. Cooling Liquid outlet, 18. Coolant heat capacity, 19. Circuit switch, 20. Contact thermal resistance with the battery, 21. Contact thermal resistance with the outside world.
具体实施方式Detailed ways
下面结合附图与实施例对本公开作进一步说明。The present disclosure will be further described below in conjunction with the accompanying drawings and examples.
应该指出,以下详细说明都是例示性的,旨在对本公开提供进一步的说明。除非另有指明,本文使用的所有技术和科学术语具有与本公开所属技术领域的普 通技术人员通常理解的相同含义。It should be noted that the following detailed description is illustrative and is intended to provide further explanation of the present disclosure. Unless otherwise defined, all technical and scientific terms used herein have common meaning in the technical fields to which this disclosure belongs. have the same meaning as commonly understood by those skilled in the art.
需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本公开的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、操作、器件、组件和/或它们的组合。It should be noted that the terms used herein are for the purpose of describing specific embodiments only and are not intended to limit the exemplary embodiments according to the present disclosure. As used herein, the singular forms are also intended to include the plural forms unless the context clearly indicates otherwise. Furthermore, it will be understood that when the terms "comprises" and/or "includes" are used in this specification, they indicate There are features, steps, operations, means, components and/or combinations thereof.
在不冲突的情况下,本公开中的实施例及实施例中的特征可以相互组合。The embodiments and features of the embodiments in the present disclosure may be combined with each other without conflict.
本公开实施例一介绍了一种基于集总模型的动力电池热管理及热蔓延抑制方法。Embodiment 1 of the present disclosure introduces a power battery thermal management and thermal spread suppression method based on a lumped model.
如图1所示的一种基于集总模型的动力电池热管理及热蔓延抑制方法,包括以下步骤:As shown in Figure 1, a power battery thermal management and thermal spread suppression method based on a lumped model includes the following steps:
基于液冷小微通道和相变材料构建动力电池的热管理几何结构;The thermal management geometry of the power battery is constructed based on liquid-cooled small micro-channels and phase change materials;
获取所述热管理几何结构的物性参数,建立单体电池产热模型;Obtain the physical parameters of the thermal management geometric structure and establish a single cell heat generation model;
根据多个单体电池产热模型构建动力电池的集总模型;Construct a lumped model of the power battery based on multiple single cell heat production models;
在所述集总模型中加入抑制热失控蔓延管理模块,基于所述集总模型预测所述动力电池的温度变化,确定动力电池触发热失控条件,在达到动力电池的热失控触发条件之前启动所述液冷小微通道,抑制热失控蔓延,实现动力电池的热管理。A management module to suppress the spread of thermal runaway is added to the lumped model, predicts the temperature change of the power battery based on the lumped model, determines the conditions for triggering thermal runaway of the power battery, and starts all the thermal runaway triggering conditions of the power battery before reaching it. The liquid-cooled small micro-channels suppress the spread of thermal runaway and achieve thermal management of power batteries.
作为一种或多种实施方式,热管理几何结构由液冷小微通道和相变材料组成,相变材料选择石蜡作为填充物,相变材料包裹在电池周围每个电池周围包裹的相变材料为20g,液冷小微通道沿电池竖直方向排列,微通道的材料采用铝壳,用水作为冷却液,每节电池周围的总流量为10L/min,如图2和图3所示的热管理几何 结构,电池组共有12块电池组成;其中电池正常工作时只采用PCM模型散热,当有电池进入热失控状态时系统启动液冷模块,抑制电池热失控的蔓延。As one or more embodiments, the thermal management geometry consists of small liquid-cooled microchannels and a phase change material. Paraffin is selected as a filler for the phase change material. The phase change material is wrapped around the battery. The phase change material is wrapped around each battery. It is 20g. Small liquid-cooled micro-channels are arranged along the vertical direction of the battery. The material of the micro-channel is an aluminum shell, and water is used as the coolant. The total flow rate around each battery is 10L/min. As shown in Figures 2 and 3, the thermal Manage geometry Structure, the battery pack consists of a total of 12 batteries; when the batteries are working normally, only the PCM model is used for heat dissipation. When a battery enters a thermal runaway state, the system starts the liquid cooling module to inhibit the spread of thermal runaway of the battery.
液冷小微通道设计的特点是由多个小型液冷通道组成,每节电池宽面两侧分布了12节通道,分布方式为在每块电池之间沿宽面方向两侧各均匀分布6条通道,液冷流向为竖直方向。The characteristic of the liquid-cooling micro-channel design is that it is composed of multiple small liquid-cooling channels. There are 12 channels distributed on both sides of the wide surface of each battery. The distribution method is that 6 channels are evenly distributed on both sides of the wide surface between each battery. channel, the liquid cooling flow direction is vertical.
作为一种或多种实施方式,根据电池与热管理系统之间连接方式确立传热关系,根据传热关系确定集总模型的热参数,热参数包括电池的热容、电池内部的热阻、电池之间的接触热阻、热管理材料的热容、电池与热管理材料的接触热阻、电池的对流热阻、热管理材料的对流热阻。As one or more embodiments, the heat transfer relationship is established based on the connection mode between the battery and the thermal management system, and the thermal parameters of the lumped model are determined based on the heat transfer relationship. The thermal parameters include the heat capacity of the battery, the thermal resistance inside the battery, Contact thermal resistance between batteries, heat capacity of thermal management materials, contact thermal resistance between batteries and thermal management materials, convection thermal resistance of batteries, and convection thermal resistance of thermal management materials.
其中电池的热容由电池的质量与比热容确定,电池内部的热阻由电池的轴向热导率、电池径向热导率以及电池的几何尺寸确定,热管理材料的热容由热管理材料的质量与比热容确定,电池之间的传导热阻由电池之间的导热系数与接触面积确定,电池与热管理材料的传导热阻由电池与热管理材料的导热系数与接触面积确定,电池的对流热阻由电池与空气的导热系数与接触面积确定,热管理材料的对流热阻由热管理材料与空气的导热系数与接触面积确定。The heat capacity of the battery is determined by the mass and specific heat capacity of the battery. The thermal resistance inside the battery is determined by the axial thermal conductivity of the battery, the radial thermal conductivity of the battery and the geometric size of the battery. The heat capacity of the thermal management material is determined by the thermal management material. The mass and specific heat capacity of the battery are determined. The thermal conduction resistance between the batteries is determined by the thermal conductivity and contact area between the batteries. The thermal conduction resistance between the battery and the thermal management material is determined by the thermal conductivity and contact area of the battery and the thermal management material. The thermal conductivity of the battery The convection thermal resistance is determined by the thermal conductivity and contact area between the battery and the air. The convection thermal resistance of the thermal management material is determined by the thermal conductivity and contact area between the thermal management material and the air.
电池的热容计算公式为:The formula for calculating the heat capacity of the battery is:
C=ρVCp       (1)C=ρVC p (1)
其中,ρ表示电池密度,Cp表示电池比热容,V表示电池体积。Among them, ρ represents the battery density, C p represents the battery specific heat capacity, and V represents the battery volume.
电池内部的热阻计算公式为:The thermal resistance calculation formula inside the battery is:
其中,δx,y,z表示电池内部x,y,z方向的厚度,λx,y,z表示电池内部x,y,z方向的导热系数。Among them, δ x, y, z represents the thickness in the x, y, and z directions inside the battery, and λ x, y, z represents the thermal conductivity in the x, y, and z directions inside the battery.
电池之间以及电池与热管理材料之间的传导热阻计算公式为:The calculation formula for conductive thermal resistance between batteries and between batteries and thermal management materials is:
其中,hc表示电池之间以及电池与热管理材料之间的对流换热系数,A表示电池之间以及电池与热管理材料之间的接触面积。Among them, h c represents the convection heat transfer coefficient between batteries and between batteries and thermal management materials, and A represents the contact area between batteries and between batteries and thermal management materials.
电池的对流热阻计算公式为:The calculation formula of the battery's convection thermal resistance is:
其中,hcov为电池表面与环境之间的对流换热系数,Acov表示电池表面与环境之间的接触面积。Among them, h cov is the convection heat transfer coefficient between the battery surface and the environment, and A cov represents the contact area between the battery surface and the environment.
作为一种或多种实施方式,单体电池产热功率由电池正常运行时的产热量与电池热失控时的产热量组成。As one or more embodiments, the thermal power of a single battery is composed of the heat generated when the battery is operating normally and the heat generated when the battery is thermally runaway.
电池正常运行时的产热率由Bernardi公式确定,表达式如下: The heat production rate of the battery during normal operation is determined by the Bernardi formula, and the expression is as follows:
其中,I为电流,U为电池端电压,Uoc为电池开路电压,V为电池体积,为电池熵热系数,T表示热力学温度。Among them, I is the current, U is the battery terminal voltage, U oc is the battery open circuit voltage, V is the battery volume, is the battery entropy thermal coefficient, and T represents the thermodynamic temperature.
电池热失控时的产热量通过单体电池绝热热失控实验测得,绝热测试环境下,电池产生的热量完全被电池吸收并造成ΔT的温升。在电池的热容Cp已知的情况下,就可以准确获得绝热环境下的热失控产热量ΔH=MCpΔT。根据实验测得的产热量与电池的各种化学成分即可拟合出绝热热失控模型。 The heat generated by the battery during thermal runaway is measured through a single cell adiabatic thermal runaway experiment. Under the adiabatic test environment, the heat generated by the battery is completely absorbed by the battery and causes a temperature rise of ΔT. When the heat capacity C p of the battery is known, the thermal runaway heat production ΔH=MC p ΔT in an adiabatic environment can be accurately obtained. The adiabatic thermal runaway model can be fitted based on the experimentally measured heat production and various chemical components of the battery.
电池内部各种材料的化学反应的产热功率可以用统一的公式进行表达,即The heat-generating power of chemical reactions of various materials inside the battery can be expressed by a unified formula, namely
其中,Qx(t)表示各个电池组份x的反应产热功率,下标x可以是SEI,anode,electrolyte,cathode等;cx d(t)表示反应物的归一化浓度。ΔHx是反应物x的化学反应生成焓,即该反应物完全反应之后,放出的总热量。Among them, Q x (t) represents the reaction heat power of each battery component x, and the subscript x can be SEI, anode, electrolyte, cathode, etc.; c x d (t) represents the normalized concentration of the reactant. ΔH x is the enthalpy of chemical reaction of reactant x, that is, the total heat released after the reactant reacts completely.
热失控时内短路产生的热量为The heat generated by the internal short circuit during thermal runaway is
其中,ΔHe代表电池在内短路发生时所具有的总电能;Δt代表电能释放的平均时间,在绝热热失控模型中,Δt被设定为10秒。Among them, ΔH e represents the total electric energy of the battery when an internal short circuit occurs; Δt represents the average time for electric energy release. In the adiabatic thermal runaway model, Δt is set to 10 seconds.
所以单体电池热失控时的产热为:Therefore, the heat generated by a single battery when it is thermally runaway is:
Q(t)=Qe(t)+Qx(t)        (7)Q(t)=Q e (t)+Q x (t) (7)
作为一种或多种实施方式,建立电池集总热阻参数网络;根据电池与热管理系统之间的传热关系建立集总热阻网络。As one or more embodiments, a battery lumped thermal resistance parameter network is established; a lumped thermal resistance network is established based on the heat transfer relationship between the battery and the thermal management system.
(1)正常工作时的电池热阻网络(1) Battery thermal resistance network during normal operation
正常工作时的电池热阻网络由电池组与相变材料模块组成,动力电池的热阻网络如图4所示,通过热阻与相邻电池,外界环境和相变材料模块之间传热。把一节电池周围的相变材料也看成一个整体,用一个温度节点表示,通过热阻与电池和外界环境和之间传热。与其中Tc表示中心电池的温度;Tneight表示相邻电池的温度;Rc表示电池之间的接触电阻;Rh表示细胞表面和周围环境之间的对流阻力;Rx、Ry、Rz表示分别在电池芯部分和 电池表面之间的x、y和z方向上的导电电阻;Rpcm表示相变材料内部的传导热阻。The thermal resistance network of the battery during normal operation consists of the battery pack and the phase change material module. The thermal resistance network of the power battery is shown in Figure 4. Heat is transferred between the thermal resistance and adjacent batteries, the external environment and the phase change material module. The phase change material around a battery is also considered as a whole, represented by a temperature node, and heat is transferred between the battery and the external environment through thermal resistance. where T c represents the temperature of the central cell; T neight represents the temperature of adjacent cells; R c represents the contact resistance between cells; R h represents the convection resistance between the cell surface and the surrounding environment; R x , R y , R z means respectively in the battery cell part and The conductive resistance in the x, y and z directions between the cell surfaces; R pcm represents the conductive thermal resistance inside the phase change material.
根据热阻网络,电池节点处的能量平衡方程为,下式According to the thermal resistance network, the energy balance equation at the battery node is, as follows
其中,Q表示电池热失控时的产热率。Mc和Cp,cell分别代表电池的质量和比热容。Among them, Q represents the heat generation rate when the battery is thermally runaway. M c and C p,cell represent the mass and specific heat capacity of the battery respectively.
(2)加入小微通道的电池热阻网络(2) Adding small micro-channels to the battery thermal resistance network
以一节小微通道为例,它们的热阻网络结构如图5所示,将一节小微通道看成一个整体,用一个温度节点表示,通过热阻与相邻电池之间传热。Taking a section of small microchannels as an example, their thermal resistance network structure is shown in Figure 5. A section of small microchannels is considered as a whole and represented by a temperature node, which transfers heat to adjacent cells through thermal resistance.
小微通道的能量平衡方程为下式:The energy balance equation of the small microchannel is as follows:
其中,TL表示小微通道的温度;RL表示电池与小微通道的接触电阻。Among them, TL represents the temperature of the small microchannel; RL represents the contact resistance between the battery and the small microchannel.
根据建立的电池集总热阻网络建立集总模型Establish a lumped model based on the established battery lumped thermal resistance network
模型用等效电路表示,由等效电流源、等效热阻和等效电容构成如图6,在模型中电池的产热功率用电流源的输出表示,电池的热容用电容表示,电池与电池之间的传导热阻用电阻表示,电池与空气的对流热阻用电阻表示。The model is represented by an equivalent circuit, which consists of an equivalent current source, an equivalent thermal resistance and an equivalent capacitance, as shown in Figure 6. In the model, the heat-generating power of the battery is represented by the output of the current source, and the heat capacity of the battery is represented by the capacitance. The conductive thermal resistance between the battery and the battery is represented by resistance, and the convection thermal resistance between the battery and the air is represented by resistance.
在电池集总热阻参数模型的基础上加入热管理模块。在模型中,因为相变材料在加热到熔化温度时,会产生从固态到液态的相变,所以热容用可变电容表示,电池与热管理材料的热阻用电阻表示;对于液冷模块,为了使模型模拟液体冷却流的效果,将一个小微通道的液体分为两个部分, 用两个电容表示整节小微通道的热容,通过电路的开关控制实现散热循环,实现液体冷却的模拟,如图7所示。The thermal management module is added based on the battery lumped thermal resistance parameter model. In the model, because the phase change material will undergo a phase change from solid to liquid when heated to the melting temperature, the heat capacity is represented by a variable capacitance, and the thermal resistance between the battery and the thermal management material is represented by a resistance; for the liquid cooling module , in order for the model to simulate the effect of liquid cooling flow, the liquid in a small microchannel is divided into two parts, Two capacitors are used to represent the heat capacity of the entire small microchannel, and the heat dissipation cycle is realized through the switch control of the circuit to realize the simulation of liquid cooling, as shown in Figure 7.
启动模型,判断电池是否到达热失控条件,如果达到热失控条件,启动抑制热失控的液冷模块后,观察热失控的蔓延情况,计算何时降到安全温度。Start the model to determine whether the battery reaches thermal runaway conditions. If it reaches thermal runaway conditions, start the liquid cooling module that suppresses thermal runaway, observe the spread of thermal runaway, and calculate when it will drop to a safe temperature.
电池到达热失控条件当动力电池温度超过150℃,或者温升速率dT/dt超过1℃/s,则认为动力电池发生热失控。The battery reaches thermal runaway condition. When the power battery temperature exceeds 150°C, or the temperature rise rate dT/dt exceeds 1°C/s, the power battery is considered to have thermal runaway.
为了验证热阻模型的准确性,用COMSOL建立了三维抑制热失控蔓延的热管理模型,电池的热失控由针刺触发,热管理模型由液冷小微通道和相变材料组成,相变材料包裹在电池周围,液冷小微通道沿电池竖直方向排列;采用本发明的集总热阻模型建立了相同的抑制热失控蔓延的热管理模型,将两个模型对热失控蔓延抑制的结果进行了比较。图8(a)和图8(b)分别表示热失控触发电池和相邻电池的温度变化,可以看出,热管理系统抑制了热失控的蔓延,同时两个模型的结果非常接近,证明了集总模型的可靠性。In order to verify the accuracy of the thermal resistance model, COMSOL was used to establish a three-dimensional thermal management model that suppresses the spread of thermal runaway. The thermal runaway of the battery is triggered by acupuncture. The thermal management model consists of liquid-cooled small micro-channels and phase change materials. The phase change material Wrapped around the battery, liquid-cooled small micro-channels are arranged along the vertical direction of the battery; the same thermal management model for suppressing the spread of thermal runaway is established using the lumped thermal resistance model of the present invention, and the results of the two models for suppressing the spread of thermal runaway are compared. A comparison was made. Figure 8(a) and Figure 8(b) respectively show the temperature changes of the thermal runaway triggered battery and adjacent batteries. It can be seen that the thermal management system inhibits the spread of thermal runaway. At the same time, the results of the two models are very close, proving that Reliability of lumped models.
通过对比COMSOL三维模型与集总热阻模型这两种方法的计算时间,如图9所示,可以看出,本发明的集总热阻网络方法的计算速度要明显快于COMSOL模型的计算速度,这将大大提升热失控过程的预测效率。By comparing the calculation times of the two methods, the COMSOL three-dimensional model and the lumped thermal resistance model, as shown in Figure 9, it can be seen that the calculation speed of the lumped thermal resistance network method of the present invention is significantly faster than the calculation speed of the COMSOL model. , which will greatly improve the prediction efficiency of thermal runaway processes.
对本热管理系统的具体运行进行演示,首先在电池正常工作时,假设一节电池(电池-1)因针刺导致温度急剧上升,此时系统开始对电池各节电池的温度进行预测,模拟结果说明电池(电池-1)热失控发生后,热量逐渐蔓延到相邻电池,410s时已经引发相邻电池热失控,如图10所示是热失控触发电池(电池-1)以及相邻电池(电池-2)的温度变化示意图。此时系统判 定电池将要到达热失控条件,立刻启动抑制热失控的热管理系统。To demonstrate the specific operation of this thermal management system, first, when the battery is working normally, assume that the temperature of one battery (battery-1) rises sharply due to acupuncture. At this time, the system begins to predict the temperature of each battery cell. The simulation results It shows that after the thermal runaway occurs in the battery (Battery-1), the heat gradually spreads to the adjacent batteries. At 410s, the thermal runaway of the adjacent batteries has been triggered. As shown in Figure 10, the thermal runaway triggers the battery (Battery-1) and the adjacent battery ( Schematic diagram of temperature changes of battery-2). At this time, the system determines If it is determined that the battery is about to reach a thermal runaway condition, the thermal management system that suppresses thermal runaway will be activated immediately.
启动抑制热失控的热管理系统后,液冷小微通道模块也开始工作,此时系统在根据当前的冷却情况开始对电池各节电池的温度进行预测,观察了热失控触发电池(电池-1)与热失控触发电池的相邻电池(电池-2)的温度变化,如图11所示,预测相邻电池的最高温度为83℃,700s后热失控触发电池降低到100℃以下,热失控蔓延得到了很好的抑制。After starting the thermal management system to suppress thermal runaway, the liquid-cooled small micro-channel module also started to work. At this time, the system began to predict the temperature of each battery cell based on the current cooling situation, and observed the thermal runaway triggered battery (Battery-1 ) and the temperature change of the adjacent battery (battery-2) of the thermal runaway triggered battery, as shown in Figure 11. The maximum temperature of the adjacent battery is predicted to be 83°C. After 700s, the thermal runaway triggered battery drops below 100°C, indicating thermal runaway. Spread is well suppressed.
即使发生了多节电池同时触发热失控的情况,本模型中的相变材料和液冷结合的方式也可以很好的抑制这种极端情况。设定有两节电池(电池-1、7)触发热失控,观察了热失控触发电池(电池-1)与热失控触发电池的相邻电池(电池-2,3,4)的温度变化,如图12所示,相邻电池没有触发热失控,900s后热失控触发电池降低到100℃以下,证明了该热管理系统抑制热失控蔓延的良好效果。Even if multiple batteries trigger thermal runaway at the same time, the combination of phase change materials and liquid cooling in this model can well suppress this extreme situation. Two batteries (Battery-1, 7) were set to trigger thermal runaway, and the temperature changes of the thermal runaway-triggered battery (Battery-1) and the adjacent batteries (Battery-2, 3, 4) of the thermal runaway-triggered battery were observed. As shown in Figure 12, the adjacent battery did not trigger thermal runaway, and the thermal runaway triggered the battery to drop below 100°C after 900 seconds, proving the good effect of the thermal management system in inhibiting the spread of thermal runaway.
以上所述仅为本公开的优选实施例而已,并不用于限制本公开,对于本领域的技术人员来说,本公开可以有各种更改和变化。凡在本公开的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本公开的保护范围之内。 The above descriptions are only preferred embodiments of the present disclosure and are not intended to limit the present disclosure. For those skilled in the art, the present disclosure may have various modifications and changes. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of this disclosure shall be included in the protection scope of this disclosure.

Claims (10)

  1. 一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,包括以下步骤:A power battery thermal management and thermal spread suppression method based on a lumped model, which is characterized by including the following steps:
    基于液冷小微通道和相变材料构建动力电池的热管理几何结构;The thermal management geometry of the power battery is constructed based on liquid-cooled small micro-channels and phase change materials;
    获取所述热管理几何结构的物性参数,构建动力电池的集总模型;Obtain the physical parameters of the thermal management geometric structure and construct a lumped model of the power battery;
    在所述集总模型中加入抑制热失控蔓延管理模块,基于所述集总模型预测所述动力电池的温度变化,确定动力电池触发热失控条件,在达到动力电池的热失控触发条件之前启动所述液冷小微通道,抑制热失控蔓延,实现动力电池的热管理。A management module to suppress the spread of thermal runaway is added to the lumped model, predicts the temperature change of the power battery based on the lumped model, determines the conditions for triggering thermal runaway of the power battery, and starts all the thermal runaway triggering conditions of the power battery before reaching it. The liquid-cooled small micro-channels suppress the spread of thermal runaway and achieve thermal management of power batteries.
  2. 如权利要求1中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,在所述构建动力电池的热管理几何结构的过程中,将所述相变材料包裹在每个单体电池的周围,将所述液冷小微通道设置为沿单体电池的竖直方向排列。A power battery thermal management and thermal spread suppression method based on a lumped model as claimed in claim 1, characterized in that, in the process of constructing the thermal management geometry of the power battery, the phase change material is Wrapped around each single cell, the liquid-cooled small micro-channels are arranged to be arranged along the vertical direction of the single cell.
  3. 如权利要求2中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,单体电池正常工作时,所述热管理几何结构采用所述相变材料散热;单体电池进入热失控状态时,所述热管理几何结构再启动所述液冷小微通道散热,抑制动力电池的热失控蔓延。A power battery thermal management and thermal spread suppression method based on a lumped model as claimed in claim 2, characterized in that when the single battery is operating normally, the thermal management geometry uses the phase change material to dissipate heat; When a single battery enters a thermal runaway state, the thermal management geometry restarts the liquid-cooled small micro-channels for heat dissipation to inhibit the spread of thermal runaway of the power battery.
  4. 如权利要求1中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,所述单体电池产热模型包括单体电池正常运行的产热量和单体电池热失控时的产热量。A power battery thermal management and thermal spread suppression method based on a lumped model as claimed in claim 1, characterized in that the single cell heat production model includes the heat production of the single cell in normal operation and the heat spread of the single cell. Heat production during thermal runaway.
  5. 如权利要求1中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,所述热管理几何结构的物性参数包括单体电池的热容、单体电池的热阻、单体电池之间的接触热阻、热管理材料的热容、单体电池与热管理 材料的接触热阻、单体的对流热阻和热管理材料的对流热阻。A power battery thermal management and thermal spread suppression method based on a lumped model as claimed in claim 1, characterized in that the physical parameters of the thermal management geometric structure include the heat capacity of a single battery, Thermal resistance, thermal contact resistance between single cells, thermal capacity of thermal management materials, single cells and thermal management Contact thermal resistance of materials, convection thermal resistance of monomers, and convection thermal resistance of thermal management materials.
  6. 如权利要求5中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,在构建动力电池的集总模型的过程中,基于所建立的单体电池产热模型和物性参数建立动力电池的集总热阻网络,结合等效电路建立动力电池的集总热阻模型。A power battery thermal management and heat spread suppression method based on a lumped model as claimed in claim 5, characterized in that, in the process of constructing a lumped model of the power battery, based on the established single battery heat generation The model and physical parameters are used to establish the lumped thermal resistance network of the power battery, and the equivalent circuit is combined to establish the lumped thermal resistance model of the power battery.
  7. 如权利要求6中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,所述动力电池的集总热阻网络包括动力电池正常工作的电池热阻网络和含小微通道的动力电池热阻网络。A power battery thermal management and heat spread suppression method based on a lumped model as claimed in claim 6, characterized in that the lumped thermal resistance network of the power battery includes a battery thermal resistance network of a normal working battery of the power battery and Power battery thermal resistance network containing small microchannels.
  8. 如权利要求7中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,所述集总模型通过由等效电流源、等效电阻和等效电容构成的等效电路表示;其中,所述等效电流源的输出表示所述单体电池产热模型;所述等效电容表示所述单体电池的热容;所述等效电阻表示热阻。A power battery thermal management and thermal spread suppression method based on a lumped model as claimed in claim 7, characterized in that the lumped model consists of an equivalent current source, an equivalent resistance and an equivalent capacitance. Equivalent circuit representation; wherein, the output of the equivalent current source represents the heat generation model of the single cell; the equivalent capacitance represents the heat capacity of the single cell; and the equivalent resistance represents the thermal resistance.
  9. 如权利要求8中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,所述抑制热失控蔓延管理模块包括相变材料模块和液冷模块组成;将单体电池周围的所述相变材料模块作为一个整体,当所述相变材料被加热到熔化温度时,所述相变材料产生从固态到液态的相变。A power battery thermal management and thermal spread suppression method based on a lumped model as claimed in claim 8, characterized in that the thermal runaway spread suppression management module includes a phase change material module and a liquid cooling module; The phase change material module surrounding the volume cell as a whole, when the phase change material is heated to the melting temperature, the phase change material produces a phase change from solid to liquid.
  10. 如权利要求1中所述的一种基于集总模型的动力电池热管理及热蔓延抑制方法,其特征在于,在确定动力电池触发热失控条件时,当动力电池温度超过热失控温度预设值或动力电池温升速率超过热失控温升速率预设值时,动力电池发生热失控。 A power battery thermal management and thermal spread suppression method based on a lumped model as claimed in claim 1, characterized in that when the power battery trigger thermal runaway conditions are determined, when the power battery temperature exceeds the thermal runaway temperature preset value Or when the temperature rise rate of the power battery exceeds the preset value of the thermal runaway temperature rise rate, the power battery will experience thermal runaway.
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