WO2016141367A3 - Pre-processing bio-oil before hydrotreatment - Google Patents

Pre-processing bio-oil before hydrotreatment Download PDF

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Publication number
WO2016141367A3
WO2016141367A3 PCT/US2016/021084 US2016021084W WO2016141367A3 WO 2016141367 A3 WO2016141367 A3 WO 2016141367A3 US 2016021084 W US2016021084 W US 2016021084W WO 2016141367 A3 WO2016141367 A3 WO 2016141367A3
Authority
WO
WIPO (PCT)
Prior art keywords
oil
bio
stabilized
hydrotreatment
stabilized bio
Prior art date
Application number
PCT/US2016/021084
Other languages
French (fr)
Other versions
WO2016141367A2 (en
Inventor
Zia Abdullah
Rachid Taha
Daniel Garbark
Huamin Wang
Guo-Shuh J. Lee
Original Assignee
Battelle Memorial Institute
Versa Renewables, Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Battelle Memorial Institute, Versa Renewables, Llc filed Critical Battelle Memorial Institute
Publication of WO2016141367A2 publication Critical patent/WO2016141367A2/en
Publication of WO2016141367A3 publication Critical patent/WO2016141367A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

Described are methods and systems for preparing stabilized bio-oil suitable for subsequent hydrotreatment and forming a hydrocarbon product from a stabilized bio-oil. For example, preparing stabilized bio-oil suitable for subsequent hydrotreatment may include filtering bio-oil effective to remove at least a portion of particles having an effective particulate diameter greater than about 10 micrometers; treating the bio-oil effective to remove at least a portion of inorganic species from the bio-oil; and catalytically stabilizing the bio-oil to provide the stabilized bio-oil suitable for subsequent hydrotreatment. Forming a hydrocarbon product from a stabilized bio-oil may include hydrotreating the stabilized bio-oil by, for example, contacting the stabilized bio-oil to a hydrotreatment catalyst in the presence of hydrogen, thereby providing the hydrocarbon product. Also included are stabilized bio-oil and hydrocarbon products derived therefrom.
PCT/US2016/021084 2015-03-05 2016-03-05 Pre-processing bio-oil before hydrotreatment WO2016141367A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201562129007P 2015-03-05 2015-03-05
US62/129,007 2015-03-05
US201562245423P 2015-10-23 2015-10-23
US62/245,423 2015-10-23

Publications (2)

Publication Number Publication Date
WO2016141367A2 WO2016141367A2 (en) 2016-09-09
WO2016141367A3 true WO2016141367A3 (en) 2016-11-03

Family

ID=56848195

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2016/021084 WO2016141367A2 (en) 2015-03-05 2016-03-05 Pre-processing bio-oil before hydrotreatment

Country Status (2)

Country Link
US (1) US20160257889A1 (en)
WO (1) WO2016141367A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2599372A (en) * 2020-09-25 2022-04-06 Abundia Biomass To Liquids Ltd Converting biomass to jet-fuel
GB2599374A (en) * 2020-09-25 2022-04-06 Abundia Biomass To Liquids Ltd Converting biomass to LPG
GB2599373A (en) * 2020-09-25 2022-04-06 Abundia Biomass To Liquids Ltd Converting biomass to naphtha
GB2599371A (en) * 2020-09-25 2022-04-06 Abundia Biomass To Liquids Ltd Converting biomass to diesel
US20240100480A1 (en) 2020-12-17 2024-03-28 Shell Oil Company Process for pre-treating renewable feedstocks
GB2602484B (en) * 2020-12-31 2023-06-14 Abundia Biomass To Liquids Ltd Converting biomass to diesel
GB2602485B (en) * 2020-12-31 2023-06-14 Abundia Biomass To Liquids Ltd Converting biomass to gasoline
US11578276B2 (en) * 2021-07-01 2023-02-14 Saudi Arabian Oil Company Two stage catalytic process for pyrolysis oil upgrading to BTX
US11377400B1 (en) 2021-07-01 2022-07-05 Saudi Arabian Oil Company Three stage catalytic process for pyrolysis oil upgrading to xylenes

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4271905A (en) * 1978-11-16 1981-06-09 Alberta Oil Sands Technology And Research Authority Gaseous and solvent additives for steam injection for thermal recovery of bitumen from tar sands
US20120023810A1 (en) * 2010-07-29 2012-02-02 Conocophillips Company Metal impurity and high molecular weight components removal of biomass derived biocrude
US20120317871A1 (en) * 2011-06-16 2012-12-20 Uop Llc Methods and apparatuses for forming low-metal biomass-derived pyrolysis oil
CN103816923A (en) * 2012-11-16 2014-05-28 万华化学集团股份有限公司 Method for regenerating ruthenium hydrogenation catalyst
WO2014145223A1 (en) * 2013-03-15 2014-09-18 Battelle Memorial Institute Vapor phase catalytic reactor for upgrade of fuels produced by fast pyrolysis of biomass
WO2014190321A1 (en) * 2013-05-23 2014-11-27 Battelle Memorial Institute Falling bed reactor
WO2015026412A1 (en) * 2013-08-23 2015-02-26 Battelle Memorial Institute Bi-functional catalyst and processes for conversion of biomass to fuel-range hydrocarbons

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5792340A (en) * 1990-01-31 1998-08-11 Ensyn Technologies, Inc. Method and apparatus for a circulating bed transport fast pyrolysis reactor system
US6433104B1 (en) * 2000-06-13 2002-08-13 Exxonmobil Chemical Patents Inc. Hydrogenation process
WO2007132857A1 (en) * 2006-05-17 2007-11-22 Nippon Oil Corporation Hydrorefining process
US8471081B2 (en) * 2009-12-28 2013-06-25 Uop Llc Production of diesel fuel from crude tall oil
US8394900B2 (en) * 2010-03-18 2013-03-12 Syntroleum Corporation Profitable method for carbon capture and storage
US20120017495A1 (en) * 2010-07-26 2012-01-26 Uop Llc Methods for deoxygenating biomass-derived pyrolysis oils
US20120017494A1 (en) * 2010-07-26 2012-01-26 Uop Llc Processes for producing low acid biomass-derived pyrolysis oils
US8629310B2 (en) * 2012-03-09 2014-01-14 Phillips 66 Company Transportation fuels from biomass oxygenates

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4271905A (en) * 1978-11-16 1981-06-09 Alberta Oil Sands Technology And Research Authority Gaseous and solvent additives for steam injection for thermal recovery of bitumen from tar sands
US20120023810A1 (en) * 2010-07-29 2012-02-02 Conocophillips Company Metal impurity and high molecular weight components removal of biomass derived biocrude
US20120317871A1 (en) * 2011-06-16 2012-12-20 Uop Llc Methods and apparatuses for forming low-metal biomass-derived pyrolysis oil
CN103816923A (en) * 2012-11-16 2014-05-28 万华化学集团股份有限公司 Method for regenerating ruthenium hydrogenation catalyst
WO2014145223A1 (en) * 2013-03-15 2014-09-18 Battelle Memorial Institute Vapor phase catalytic reactor for upgrade of fuels produced by fast pyrolysis of biomass
WO2014190321A1 (en) * 2013-05-23 2014-11-27 Battelle Memorial Institute Falling bed reactor
WO2015026412A1 (en) * 2013-08-23 2015-02-26 Battelle Memorial Institute Bi-functional catalyst and processes for conversion of biomass to fuel-range hydrocarbons

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
CARPENTER, D ET AL.: "Field-to-fuel performance testing of various biomass feedstocks.", SYMPOSIUM ON THERMAL AND CATALYTIC SCIENCES FOR BIOFUELS AND BIOBASED PRODUCTS., pages 2, XP055326291, Retrieved from the Internet <URL:http://www.nrel.gov/ducs/fy14ostl/62897.pdf> *
INGLEZAKIS, VJ ET AL.: "Effects of operating conditions on the removal of heavy metals by zeolite in fixed bed reactors.", JOURNAL OF HAZARDOUS MATERIALS B112, vol. 112, no. 1-2, 4 June 2004 (2004-06-04), pages 37 - 43, XP055326293 *
PARAPATI, DR ET AL.: "Catalyst Screening for Single-Stage Catalytic Hydro-processing of Bio-oil in a Continuous Packed-bed Reactor for the Production of Hydrocarbon Fuel.", JOURNAL OF FOREST PRODUCTS AND INDUSTRIES., vol. 3, no. 6, 2014, pages 266 - 277, XP055326335 *
RINGER, M ET AL.: "Large-scale pyrolysis oil production; a technology assessment and economic analysis.", TECHNICAL REPORT. NREL/TP-510-37779., November 2006 (2006-11-01), pages 6, XP055326280, Retrieved from the Internet <URL:http://www.nrel.gov/docs/fy07osti/37779.pdf> *
SCAHILL, J ET AL.: "Removal of residual char fines from pyrolysis vapors by hot gas filtration.", DEVELOPMENTS IN THERMOCHEMICAL BIOMASS CONVERSION., 1997, pages 253 - 266, XP055326298 *
VESES, A ET AL.: "Catalytic upgrading of biomass derived pyrolysis vapors over metal-loaded ZSM-5 zeolites: Effect of different metal cations on the bio-oil final properties.", MICROPOROUS AND MESOPOROUS MATERIALS., vol. 209, 26 January 2015 (2015-01-26), pages 189 - 196, XP029147230 *
VISPUTE, T: "Pyrolysis Oils: Characterization, Stability Analysis, and Catalytic Upgrading to Fuels and Chemicals.", DISSERTATION, 1 February 2011 (2011-02-01), pages 11, XP055326330, Retrieved from the Internet <URL:http://scholarworks.umass.edu/cgi/viewcontent.cgi?article=1354&context=open_access_dissertations> *

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Publication number Publication date
US20160257889A1 (en) 2016-09-08
WO2016141367A2 (en) 2016-09-09

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