WO2014026476A1 - Detergent composition for darkening hair and method for preparing same - Google Patents

Detergent composition for darkening hair and method for preparing same Download PDF

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Publication number
WO2014026476A1
WO2014026476A1 PCT/CN2013/071879 CN2013071879W WO2014026476A1 WO 2014026476 A1 WO2014026476 A1 WO 2014026476A1 CN 2013071879 W CN2013071879 W CN 2013071879W WO 2014026476 A1 WO2014026476 A1 WO 2014026476A1
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Prior art keywords
hair
color
detergent
weight
parts
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PCT/CN2013/071879
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French (fr)
Chinese (zh)
Inventor
宋子奎
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Song Zikui
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Publication of WO2014026476A1 publication Critical patent/WO2014026476A1/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87Polyurethanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/897Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing halogen, e.g. fluorosilicones
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9794Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/10Preparations for permanently dyeing the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

Definitions

  • the present invention relates to the field of hair washing technology, and more particularly to a detergent composition for color increasing hair and a method for preparing the same. Background technique
  • existing hair washing detergents are mainly composed of detergents and additives such as conditioners, foam boosters, anti-dandruff agents, preservatives and flavors, such as the Chinese patent of CN1121203C.
  • the literature discloses a hair care cosmetic composition comprising a detergent base comprising an anionic surfactant and a C10 ⁇ C14 alkyl betaine amphoteric surfactant, at least one cationic guar gum and at least one A non-silicone conditioning system for hair washing and care.
  • a hair care cosmetic composition comprising a detergent base comprising an anionic surfactant and a C10 ⁇ C14 alkyl betaine amphoteric surfactant, at least one cationic guar gum and at least one A non-silicone conditioning system for hair washing and care.
  • the present invention provides a detergent composition for color-increasing hair and a preparation method thereof, and the detergent composition for color-increasing hair provided by the present invention can make the original hair color deepened after washing, after dyeing The original color of the hair after washing is fixed, and its color is deepened.
  • the present invention provides a detergent composition for color enhancement, comprising:
  • a deepening agent being one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin;
  • the resin is one or more of an organic fluororesin, a silicone resin, a polyamine resin, and a polyurethane resin.
  • the silicone oil compound is one or more of a hydroxy silicone oil, an alkyl silicone oil, an amino silicone oil, a dimercapto silicone oil, a fluorine-containing silicone oil, and a polyether modified silicone oil.
  • the fixing agent is a cationic resin fixing agent, a reactive fixing agent, a quaternary ammonium salt fixing agent or a silicone fixing agent.
  • the hair detergent is composed of a detergent and an additive.
  • the detergent is an anionic surfactant detergent and/or a nonionic surfactant detergent.
  • the additive is an oleaginous substance, a hydrolyzed protein, an alcohol, an inorganic salt, a preservative, a foam booster, an antidandruff agent, a surface active conditioner, a nonionic conditioner, a cationic conditioner, a fragrance, and a pigment.
  • a hydrolyzed protein e.g., a hydrolyzed protein
  • an alcohol e.g., a benzyl alcohol
  • a preservative e.g., a preservative
  • a foam booster e.g., a preservative, e.g., a preservative, a foam booster, an antidandruff agent, a surface active conditioner, a nonionic conditioner, a cationic conditioner, a fragrance, and a pigment.
  • it further comprises 5 to 95 parts by weight of a traditional Chinese medicine urinary agent.
  • the traditional Chinese medicine Wufa agent is one or more of Shouwu extract, ginseng extract, Astragalus extract, Aloe extract, Angelica extract and Lycium barbarum extract.
  • the present invention also provides a method for preparing a detergent composition for color enhancement, comprising the steps of:
  • a deepening agent 2 to 98 parts by weight of a deepening agent, the deepening agent being one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin; 3 to 96 parts by weight of a fixing agent;
  • the raw materials were mixed at a temperature of 0 to 550 ° C to obtain a detergent composition for coloring hair.
  • the detergent composition for color-increasing hair comprises 5 to 95 parts by weight of a hair detergent, 2 to 98 parts by weight of a deepening agent, and the deepening agent is chitin.
  • a hair detergent 2 to 98 parts by weight of a deepening agent
  • the deepening agent is chitin.
  • various excipients such as a deepening agent and a fixing agent are added to the detergent for hair to obtain a detergent composition for coloring the hair.
  • the resin, the chitin, the chitosan or the silicone oil compound can form a uniform low refractive index film on the surface of the hair.
  • the tough and transparent film has a fixing effect on the original color of the hair, and at the same time, can reduce the reflection and scattering ability of the hair to light, so that more visible light enters the inside of the hair, so that the hair is selectively absorbed by the light.
  • the chitin, the chitosan or the rare earth can be combined with the hair dye on the hair dye, so that the molecular weight of the hair dye is increased, and the color is deepened, so that the original color of the hair dye after being washed is Deepen.
  • the hair treated with the detergent composition for color-increasing hair provided by the present invention is fixed in color and deepened.
  • the present invention provides a detergent composition for color enhancement, comprising:
  • a deepening agent being one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin;
  • the detergent composition for color-increasing hair provided by the present invention is mainly composed of a hair detergent, a deepening agent and a fixing agent. After washing the original hair or the dyed hair, the color of the hair is fixed and increased. Deep, so that the original hair or dyed hair achieves the usual effect of washing.
  • the detergent composition for color-increasing hair contains 5 to 95 parts by weight of a detergent for hair, preferably 10 to 90 parts by weight of a detergent for hair, more preferably 50 to 80 parts by weight of hair.
  • the hair detergent is preferably composed of a detergent and an additive. The ratio of the detergent and the additive is not particularly limited in the present invention, and the commonly used hair detergent can be used for better decontamination and the like. .
  • the detergent may be an anionic surfactant detergent, a cationic surfactant detergent, a zwitterionic surfactant detergent or a nonionic surfactant detergent, or may be a compound surface as described above.
  • a mixed detergent of active agents preferably an anionic surfactant detergent and/or a nonionic surfactant detergent, wherein the anionic surfactant detergent includes, but is not limited to, lauryl benzene cross S sodium washing Agent, sodium oleate ethyl sulfonate detergent, oleoylamino sodium detergent and N, N-oleoyl hydrazino sodium taurate detergent; the nonionic surfactant such as nonylphenol ethoxylate wash Agent, alkyl glycoside detergent, and the like.
  • the additive is preferably one of an oily substance, a hydrolyzed protein, an alcohol, an inorganic salt, a preservative, a foam booster, an antidandruff agent, a surface active conditioner, a nonionic conditioner, a cationic conditioner, a fragrance, and a pigment. Or a variety.
  • the oleaginous substance is preferably ethoxylated coconut oil monoethanolamine, almond oil, olive oil, water-soluble lanolin, sunflower oil, licorice oil, chamomile oil, sea turtle oil, squalene, eucalyptus oil, liquid paraffin, meat
  • the hydrolyzed protein is preferably hydrolyzed keratin or hydrolyzed animal glue, which can have a good nursing effect on hair.
  • the alcohol is preferably ethanol or isopropanol, which is an excellent solvent.
  • the inorganic salt is preferably one or more of sodium chloride, ammonium chloride, potassium chloride, metaphosphate, orthophosphate and sulfate, and can serve as a thickening effect.
  • the preservative is preferably p-hydroxybenzoic acid and does not pose a health hazard.
  • the suds booster is preferably coconut oil diethanolamine for ease of application.
  • the antidandruff agent is preferably one or more of zinc pyrithione, selenium sulfide, sulfur, salicylic acid and undecylenic acid derivatives, which can relieve itching and dandruff.
  • the surface active conditioning agent is preferably a malt oil derivative having a thickening action and conditioning effects such as hairdressing and hair care.
  • the nonionic conditioning agent is preferably a fatty alcohol polyoxyethylene ether or polysorbate, which has the functions of emulsification, foaming and decontamination.
  • the cationic conditioning agent is preferably a polyquaternium, an acrylamide polymer or a cationic guar gum, which can thicken and increase hair It has a lightening effect and keeps the hair easy to comb and so on.
  • the flavor and the pigment are respectively used in the art, and the present invention is not particularly limited.
  • the detergent composition for color-increasing hair contains 2 to 98 parts by weight of a deepening agent, preferably 10 to 80 parts by weight of a deepening agent, more preferably 20 to 50 parts by weight of a deepening agent.
  • the deepening agent is one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin, preferably a rare earth and/or a resin, and has a good fixing effect and a deepening effect.
  • the color of hair is determined by hue, purity and lightness (gloss), under different hue and luster, if the reflectance and transmittance of light waves are different, the shades and the degree of light reception are different, and the visual effects of light and dark levels are exhibited.
  • the luster of the hair is the result of a combination of positive and negative chromatic light, surface reflected light, and scattered light from the interior, where the reflected light is the bulk portion.
  • the main way to increase the color depth of the hair is to reduce its ability to reflect and scatter light, allowing more visible light to enter the hair, allowing the hair to be selectively absorbed to produce a darker effect.
  • the resin, the silicone oil compound, the chitin or the chitosan have strong adsorption to hair, can be tightly combined with active groups in the hair fiber, and can form a layer on the hair surface.
  • a uniform low-refractive-index film that weakens the ability of the hair to reflect and scatter light, allowing more visible light to enter the interior of the hair, thereby allowing the hair to selectively absorb light and produce a dark color effect; due to the film-forming light formed on the surface of the hair The reflection is different from the absorption, the brightness of the hair is reduced, the color looks darker, although the film formed is very thin, about 0.5 ⁇ ⁇ , but the hair is a collection of hair fibers, and this effect of a large number of wool fibers is combined.
  • the resin, the silicone oil compound, the chitin or the chitosan have the function of fixing color, smoothing hair, straightening and the like, killing and inhibiting bacteria, reducing inflammation and relieving pain, promoting hair wounds The health benefits of healing.
  • the resin is preferably one or more of an organic fluororesin, a silicone resin, a polyamine resin, and a urethane resin.
  • the silicone oil compound is preferably one or more of a hydroxy silicone oil, an alkyl silicone oil, an amino silicone oil, a dimercapto silicone oil, a fluorine-containing silicone oil, and a polyether modified silicone oil, wherein the dimercapto silicone oil is also called a silicone oil, Silicone oil, etc., is a polyorganosiloxane of different polymerization degree chain structure, and its preparation
  • the method comprises the following steps: dimercaptodichlorosilane is hydrolyzed by hydrolysis to obtain a polycondensation ring, and the ring body is subjected to cracking and rectification to obtain a low ring body, and then the ring body, the heading agent and the catalyst are mixed and condensed to obtain different degrees of polymerization.
  • the mixture is subjected to distillation under reduced pressure to remove low boilers to obtain a dimercaptosilicone oil.
  • the dimercaptosilicone oil such as SILANOL SF9188, SILANOLSF9103 has a refractive index of generally 1.40 to 1.45; and the fluorine-containing silicone oil has a refractive index of generally 1.38 or less.
  • the chitin is also known as chitin, chitin, and has the chemical name (1-4)-2-acetamido-2-deoxy- ⁇ -D-glucose, or polyacetamide-based glucose.
  • the chitosan is also called chitosan, chitosan, which is a kind of chitin which is mainly derived from shells of aquatic shellfish such as shrimps and crabs, and is hydrolyzed under alkaline conditions to form an acetyl group.
  • the soluble chitin, chemical name is (1-4) _2-amino-2-deoxy-8-0-glucose, or simply polyaminoglucose.
  • the chitin and the chitosan have an unsaturated cationic group, and have a strong adsorption effect on the negatively charged hair, forming a film layer of molecular thickness, which has a very low reflectance and allows injection into the hair.
  • the surface light produces refraction and diffuse reflection on the surface of the hair, so that the absorption of incident light by the hair is greatly increased, and the reflected light is reduced to achieve a deepening effect.
  • the chitin and the chitosan can also be combined with the hair dye on the dyed hair, which not only can improve the color fastness of the hair dye, but also increase the molecular weight of the hair dye, resulting in dyeing.
  • the hair has a darker color, which has a deepening effect.
  • the chitin and the chitosan are rich in source and low in price, and are suitable for popularization and application.
  • the rare earth can first cooperate with the hydroxyl oxygen atom, the azo nitrogen atom, the sulfonic acid oxygen atom in the hair dye molecule on the dyed hair, and can not only make the hair dye and the non-polar hair of the dyed hair.
  • the intermolecular interaction between the sexual parts is increased, the color fastness is improved, and the molecular weight of the hair dye is increased, and the color is deepened, so that the dyed hair after washing maintains the depth of the original color and the color vividness is improved;
  • the rare earth can activate the colored substance of the dirt on the wool fiber, reduce the activation energy of the washing reaction, and make the reaction of the dirt and the detergent easier, that is, the active reaction of the hair washing reaction, thereby making the hair more clean.
  • the rare earth itself has a maximum absorption wavelength of 580 nm, and has the ability to selectively absorb yellow light of gray, yellow, or light-colored hair, and deepens the color of the yellowish-lightened hair. Therefore, the rare earth can deepen the color of the original hair after washing, so that the color of the dyed hair after washing is deep and bright, the color is pure, and the color fastness is high.
  • the rare earth has a strong complexing property, and when it enters the amorphous region of the wool fiber, it can form a complex by means of a coordination bond or a covalent bond, and functions as a crosslinking agent. And the strength of the hair is improved.
  • the type of the rare earth in the present invention is not particularly limited, and a mixed rare earth cerium oxide (La203) having a purity of more than 99.9999% or a single rare earth oxidized yttrium (NdZO) may be used.
  • a mixed rare earth cerium oxide (La203) having a purity of more than 99.9999% or a single rare earth oxidized yttrium (NdZO) may be used.
  • the detergent composition for color-increasing hair contains 3 to 96 parts by weight of a fixing agent, preferably 10 to 90 parts by weight of a fixing agent, more preferably 20 to 40 parts by weight of a fixing agent.
  • the fixing agent can improve the color fastness of the dyed hair, and is preferably a cationic resin fixing agent, a reactive fixing agent, a quaternary ammonium salt fixing agent or a silicone fixing agent, more preferably a cationic resin solid.
  • the cationic resin fixing agent such as fixing agent Y, fixing agent ⁇ and fixing agent FLZOIL-810, etc.
  • the reactive fixing agent such as fixing agent NGC, fixing agent C and fixing agent DR -100, etc.
  • the quaternary ammonium salt fixing agent such as fixing agent ECEOTIXFD-3, fixing agent ECEOTIXNF-50 and fixing agent TCD-R, etc.
  • the silicone fixing agent comprises silicone, cationic reaction type Silicone and acid-free silicone.
  • the fixing principle of the fixing agent may be: a cationic group is contacted with an alkaline aqueous solution to form a hydrogel, which adsorbs heavy metal ions and pigments, and can form on the surface of the wool fiber after drying. A layer of film, which plays a good role in fixing and protecting the hair dye.
  • the detergent composition for color-increasing hair preferably further comprises 5 to 95 parts by weight of a traditional Chinese medicine, and more preferably 10 to 50 parts by weight of a traditional Chinese medicine.
  • the traditional Chinese medicine Wufa agent can be used as a traditional Chinese medicine Wufa extract in the field, and preferably why one or more of Shouwu extract, ginseng extract, Astragalus membranaceus extract, Aloe extract, Angelica extract and Lycium barbarum extract are extracted. More preferably, one or more of Shouwu extract, ginseng extract, Astragalus extract, Angelica extract and Lycium barbarum extract.
  • the present invention also provides a method for preparing a detergent composition for color enhancement, comprising the steps of:
  • a deepening agent 2 to 98 parts by weight of a deepening agent, the deepening agent being one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin; 3 to 96 parts by weight of a fixing agent;
  • the raw materials were mixed at a temperature of 0 to 550 ° C to obtain a detergent composition for coloring hair.
  • the raw materials are weighed according to the above-mentioned parts by weight, and then mixed at a temperature of 0 to 550 ° C, preferably 10 ° C to 250 ° C, more preferably 30 ° C to 160 ° C to obtain a detergent for coloring hair. combination.
  • the present invention preferably further comprises mixing 5 to 95 parts by weight of a traditional Chinese medicine urinary agent.
  • the present invention is not particularly limited to other conditions such as the mixed device.
  • the hair of each color or the dyed hair is washed a plurality of times, and the washing may be a dipping or a shower, wherein the dipping is specifically : at a temperature of 0 to 70 ° C, 0.1 ml to 100 mL of the coloring hair detergent composition is dissolved in 1 mL to 100 mL of water, stirred uniformly, and then at a temperature of 0 to 100 ° C, lg ⁇ 1000g of hair to be washed is immersed in it, after lmin ⁇ 100min, it is dried by water or dried naturally.
  • the spraying is specifically: spraying the coloring hair with a detergent composition directly onto the dry hair to be washed by a mist generator, after lmin ⁇ 100min, drying or drying naturally.
  • the above raw materials were mixed at a temperature of 30 ° C to obtain a detergent composition for color enhancement of hair.
  • the dyed hair to be washed in red, yellow, blue, purple and black is sprayed with the detergent composition for color-increasing hair respectively, and after being treated 10 times, the color of the dyed hair after washing is red and yellow. , blue, purple and black.
  • Comparative example 1 5 parts by weight of sodium dodecylbenzene s-sodium detergent and 81 parts by weight of water were weighed and mixed at a temperature of 30 ° C to obtain a hair detergent composition.
  • the hair washing composition is sprayed with red, yellow, blue, purple and black dyed hair, respectively, after being treated for 10 times, and the color of the dyed hair after washing is light red and light yellow. , light blue, light purple and grey.
  • the above raw materials were mixed at a temperature of 50 ° C to obtain a detergent composition for color enhancement of hair.
  • the red, yellow, blue, purple and black dyed hairs to be washed are respectively washed with the detergent composition for color-increasing hair, and after being treated 10 times, the color of the dyed hair after washing is red and bright. Yellow, blue, purple and black.
  • the above raw materials were mixed at a temperature of 30 ° C to obtain a detergent composition for color enhancement of hair.
  • the dyed hair to be washed in red, yellow, blue, purple and black is digested with the detergent composition for color-increasing hair respectively, and after being treated 10 times, the color of the dyed hair after washing is red and yellow. , blue, purple and black.
  • the above raw materials were mixed at a temperature of 110 ° C to obtain a detergent composition for color-increasing hair.
  • the dyed hair to be washed in red, yellow, blue, purple and black is sprayed with the detergent composition for color-increasing hair respectively, and after being treated 10 times, the color of the dyed hair after washing is red and yellow. , blue, purple and black.
  • the above raw materials were mixed at a temperature of 50 ° C to obtain a detergent composition for color enhancement of hair.
  • the dyed hair to be washed in red, yellow, blue, purple and black is digested with the detergent composition for color-increasing hair, respectively. After washing 10 times, the color of the dyed hair after washing is red and yellow. , blue, purple and black.

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Abstract

Disclosed is a detergent composition for darkening hair comprising: 5 - 95 parts by weight of a hair detergent; 2 - 98 parts by weight of a darkening agent, the darkening agent being one or more of chitin, chitosan, silicone oil compounds, rare-earth and resins; 3 - 96 parts by weight of a colour-fixing agent. In the present invention, various auxiliary materials, such as a darkening agent and a colour-fixing agent, are added into a hair detergent so as to obtain a detergent composition for darkening hair, and the composition enables the colour of the original hair after washing to be darkened in multiples, and the original colour of the dyed hair after washing to be fixed, and the colour thereof darkened, thus achieving the effects that the more times the hair is washed, the deeper the colour becomes, and that frequent washing brings about a more vibrant colour for all kinds of hair. Also provided in the present invention is a method for preparing a detergent composition for darkening hair.

Description

一种增色毛发用洗涤剂组合物及其制备方法  Detergent composition for color increasing hair and preparation method thereof
本申请要求于 2012 年 08 月 13 日提交中国专利局、 申请号为 201210287129.6、 发明名称为 "一种增色毛发用洗涤剂组合物及其制备方 法" 的中国专利申请的优先权, 其全部内容通过引用结合在本申请中。  The present application claims priority to Chinese Patent Application No. 201210287129.6, entitled "A Detergent Composition for Color Enhancing Hair and a Method for Preparing the Same", filed on August 13, 2012, the entire contents of which are incorporated by reference. The citations are incorporated herein by reference.
技术领域 Technical field
本发明涉及毛发洗涤技术领域,特别涉及一种增色毛发用洗涤剂组合 物及其制备方法。 背景技术  The present invention relates to the field of hair washing technology, and more particularly to a detergent composition for color increasing hair and a method for preparing the same. Background technique
一般来说, 现有的洗涤毛发的毛发用洗涤剂主要由洗涤剂和添加剂 如调理剂、 增泡剂、 抗头屑剂、 防腐剂和香精等成分组成, 如授权公告号 为 CN1121203C 的中国专利文献公开了一种护发用洗涤化妆品组合物, 其包含由阴离子表面活性剂和 C10〜C14烷基甜菜碱两性表面活性剂组成 的洗涤基剂、含有至少一种阳离子瓜尔胶和至少一种不溶聚硅氧烷的调理 剂系统,可用于头发的洗涤和护理。采用现有的毛发用洗涤剂洗涤毛发时, 其对毛发具有一定的去污、 去垢、 除脂、 去屑等功能, 使毛发在洗后较为 干净, 其颜色仍为原有的深度。  In general, existing hair washing detergents are mainly composed of detergents and additives such as conditioners, foam boosters, anti-dandruff agents, preservatives and flavors, such as the Chinese patent of CN1121203C. The literature discloses a hair care cosmetic composition comprising a detergent base comprising an anionic surfactant and a C10~C14 alkyl betaine amphoteric surfactant, at least one cationic guar gum and at least one A non-silicone conditioning system for hair washing and care. When the hair is washed with the existing hair detergent, it has certain functions of decontamination, descaling, degreasing, anti-dandruff and the like on the hair, so that the hair is clean after washing, and the color is still the original depth.
目前, 为了达到增加装饰效果或美观等目的, 采用染发剂对毛发进 行染色已成为常见的做法之一。然而,采用现有的毛发用洗涤剂洗涤染色 后的毛发时,染色后的毛发在洗后的颜色一般会变浅。 虽然在染发剂的色 牢度较好的情况下, 对于单次洗发的掉色, 目测时通常可忽略不计, 但是 当洗发的频率较高或洗发的次数累计到一定限量时,染色后的毛发在洗后 的颜色则会表现为整体变浅,甚至变回染色前毛发原来的颜色,从而导致 减弱甚至无法起到增加装饰效果或美观等方面的作用。 同时,对于先天颜 色较浅且染色效果不佳的毛发,采用现有的毛发用洗涤剂洗涤后,毛发的 颜色仍旧不饱和, 影响美观。  At present, it has become a common practice to dye hair with a hair dye for the purpose of increasing the decorative effect or aesthetics. However, when the dyed hair is washed with the existing hair detergent, the color of the dyed hair is generally shallow after washing. Although the color fastness of the hair dye is good, the color drop of a single shampoo is usually negligible when visual inspection, but when the frequency of shampoo is high or the number of shampoos is accumulated to a certain limit, after dyeing The color of the hair after washing will be lightened as a whole, and even change back to the original color of the hair before dyeing, which may result in weakening or even failing to increase the decorative effect or aesthetics. At the same time, for hairs with a lighter color and poor dyeing effect, after washing with the existing hair detergent, the color of the hair is still not saturated, which affects the appearance.
因此,需要一种使洗涤后原有毛发颜色被成倍增深或染色后的毛发原 有颜色被固色, 而且每次洗涤都对毛发的颜色有增深作用的洗涤剂。  Therefore, there is a need for a detergent which has a color which is doubled or dyed after washing, and which has a color which is solidified, and which has a deepening effect on the color of the hair.
发明内容 为了解决以上技术问题 ,本发明提供一种增色毛发用洗涤剂组合物及 其制备方法,本发明提供的增色毛发用洗涤剂组合物能使原有毛发颜色在 洗后被增深,染色后的毛发在洗后的原有颜色被固色,而且其颜色被增深。 Summary of the invention In order to solve the above problems, the present invention provides a detergent composition for color-increasing hair and a preparation method thereof, and the detergent composition for color-increasing hair provided by the present invention can make the original hair color deepened after washing, after dyeing The original color of the hair after washing is fixed, and its color is deepened.
本发明提供一种增色毛发用洗涤剂组合物, 包含:  The present invention provides a detergent composition for color enhancement, comprising:
5〜95重量份的毛发用洗涤剂;  5 to 95 parts by weight of a hair detergent;
2〜98重量份的增深剂, 所述增深剂为曱壳素、 壳聚糖、 硅油类化合 物、 稀土和树脂中的一种或多种;  2 to 98 parts by weight of a deepening agent, the deepening agent being one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin;
3〜96重量份的固色剂。  3 to 96 parts by weight of a fixing agent.
优选的, 所述树脂为有机氟树脂、 有机硅树脂、 聚胺类树脂和聚氨 酯树脂中的一种或多种。  Preferably, the resin is one or more of an organic fluororesin, a silicone resin, a polyamine resin, and a polyurethane resin.
优选的, 所述硅油类化合物为羟基硅油、 烷基硅油、 氨基硅油、 二 曱基硅油、 含氟硅油和聚醚改性硅油中的一种或多种。  Preferably, the silicone oil compound is one or more of a hydroxy silicone oil, an alkyl silicone oil, an amino silicone oil, a dimercapto silicone oil, a fluorine-containing silicone oil, and a polyether modified silicone oil.
优选的, 所述固色剂为阳离子树脂固色剂、 反应型固色剂、 季铵盐 固色剂或有机硅类固色剂。  Preferably, the fixing agent is a cationic resin fixing agent, a reactive fixing agent, a quaternary ammonium salt fixing agent or a silicone fixing agent.
优选的, 所述毛发用洗涤剂由洗涤剂和添加剂组成。  Preferably, the hair detergent is composed of a detergent and an additive.
优选的, 所述洗涤剂为阴离子表面活性剂洗涤剂和 /或非离子表面活 性剂洗涤剂。  Preferably, the detergent is an anionic surfactant detergent and/or a nonionic surfactant detergent.
优选的, 所述添加剂为油脂性物质、 水解蛋白质、 醇、 无机盐、 防 腐剂、 增泡剂、 抗头屑剂、 表面活性调理剂、 非离子调理剂、 阳离子调理 剂、 香精和色素中的一种或多种。  Preferably, the additive is an oleaginous substance, a hydrolyzed protein, an alcohol, an inorganic salt, a preservative, a foam booster, an antidandruff agent, a surface active conditioner, a nonionic conditioner, a cationic conditioner, a fragrance, and a pigment. One or more.
优选的, 还包含 5〜95重量份的中药乌发剂。  Preferably, it further comprises 5 to 95 parts by weight of a traditional Chinese medicine urinary agent.
优选的, 所述中药乌发剂为何首乌提取物、 人参提取物、 黄芪提取 物、 芦荟提取物、 当归提取物和枸杞提取物中的一种或多种。  Preferably, the traditional Chinese medicine Wufa agent is one or more of Shouwu extract, ginseng extract, Astragalus extract, Aloe extract, Angelica extract and Lycium barbarum extract.
本发明还提供一种增色毛发用洗涤剂组合物的制备方法, 包括以下 步骤:  The present invention also provides a method for preparing a detergent composition for color enhancement, comprising the steps of:
称取如下重量份的原料:  Weigh the following parts by weight:
5〜95重量份的毛发用洗涤剂;  5 to 95 parts by weight of a hair detergent;
2〜98重量份的增深剂, 所述增深剂为曱壳素、 壳聚糖、 硅油类化合 物、 稀土和树脂中的一种或多种; 3〜96重量份的固色剂; 2 to 98 parts by weight of a deepening agent, the deepening agent being one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin; 3 to 96 parts by weight of a fixing agent;
将所述原料在温度为 0〜550°C的条件下混合,得到增色毛发用洗涤剂 组合物。  The raw materials were mixed at a temperature of 0 to 550 ° C to obtain a detergent composition for coloring hair.
与现有技术相比, 本发明提供的增色毛发用洗涤剂组合物包含 5〜95 重量份的毛发用洗涤剂、 2〜98 重量份的增深剂, 所述增深剂为曱壳素、 壳聚糖、 硅油类化合物、 稀土和树脂中的一种或多种, 以及 3〜96重量份 的固色剂。 本发明在毛发用洗涤剂中添加增深剂、 固色剂等各种辅料, 得 到增色毛发用洗涤剂组合物。采用本发明提供的增色毛发用洗涤剂组合物 洗涤毛发时, 所述树脂、 所述曱壳素、 所述壳聚糖或所述硅油类化合物能 在毛发表面形成一层均匀的低折射率薄膜,这种坚韧透明的薄膜对毛发的 原有颜色有固色作用, 同时能减弱毛发对光的反射和散射能力,使更多的 可见光进入毛发内部, 从而使毛发对光发生选择性吸收后产生深色效果; 同时所述曱壳素、所述壳聚糖或所述稀土能与染发上的染发剂结合,使染 发剂的分子量增大, 色泽加深, 从而使染发在洗后原有颜色被增深。 实验 表明,经过本发明提供的增色毛发用洗涤剂组合物处理的毛发,其原有颜 色被固色、 增深。 具体实施方式  Compared with the prior art, the detergent composition for color-increasing hair provided by the present invention comprises 5 to 95 parts by weight of a hair detergent, 2 to 98 parts by weight of a deepening agent, and the deepening agent is chitin. One or more of chitosan, a silicone oil compound, a rare earth and a resin, and 3 to 96 parts by weight of a fixing agent. In the present invention, various excipients such as a deepening agent and a fixing agent are added to the detergent for hair to obtain a detergent composition for coloring the hair. When the hair is washed with the detergent composition for color-increasing hair provided by the present invention, the resin, the chitin, the chitosan or the silicone oil compound can form a uniform low refractive index film on the surface of the hair. The tough and transparent film has a fixing effect on the original color of the hair, and at the same time, can reduce the reflection and scattering ability of the hair to light, so that more visible light enters the inside of the hair, so that the hair is selectively absorbed by the light. Dark color effect; at the same time, the chitin, the chitosan or the rare earth can be combined with the hair dye on the hair dye, so that the molecular weight of the hair dye is increased, and the color is deepened, so that the original color of the hair dye after being washed is Deepen. Experiments have shown that the hair treated with the detergent composition for color-increasing hair provided by the present invention is fixed in color and deepened. detailed description
为了进一步理解本发明,下面结合实施例对本发明优选实施方案进行 描述, 但是应当理解, 这些描述只是为进一步说明本发明的特征和优点, 而不是对本发明权利要求的限制。  The present invention is described in detail with reference to the preferred embodiments of the present invention, and the description of the present invention.
本发明提供了一种增色毛发用洗涤剂组合物, 包含:  The present invention provides a detergent composition for color enhancement, comprising:
5〜95重量份的毛发用洗涤剂;  5 to 95 parts by weight of a hair detergent;
2〜98重量份的增深剂, 所述增深剂为曱壳素、 壳聚糖、 硅油类化合 物、 稀土和树脂中的一种或多种;  2 to 98 parts by weight of a deepening agent, the deepening agent being one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin;
3〜96重量份的固色剂。  3 to 96 parts by weight of a fixing agent.
本发明提供的增色毛发用洗涤剂组合物主要由毛发用洗涤剂、增深剂 和固色剂等原料组成,采用其洗涤原有毛发或染色后的毛发后,毛发的颜 色被固色、 增深, 从而使原有毛发或染色后的毛发达到常洗常新的效果。 在本发明中, 所述增色毛发用洗涤剂组合物包含 5〜95重量份的毛发 用洗涤剂, 优选包含 10-90 重量份的毛发用洗涤剂, 更优选包含 50-80 重量份的毛发用洗涤剂。 所述毛发用洗涤剂优选由洗涤剂和添加剂组成, 本发明对所述洗涤剂和所述添加剂的比例没有特殊限制,采用常用的毛发 用洗涤剂能起到较好的去污等作用即可。 The detergent composition for color-increasing hair provided by the present invention is mainly composed of a hair detergent, a deepening agent and a fixing agent. After washing the original hair or the dyed hair, the color of the hair is fixed and increased. Deep, so that the original hair or dyed hair achieves the usual effect of washing. In the present invention, the detergent composition for color-increasing hair contains 5 to 95 parts by weight of a detergent for hair, preferably 10 to 90 parts by weight of a detergent for hair, more preferably 50 to 80 parts by weight of hair. Detergent. The hair detergent is preferably composed of a detergent and an additive. The ratio of the detergent and the additive is not particularly limited in the present invention, and the commonly used hair detergent can be used for better decontamination and the like. .
在本发明中,所述洗涤剂可以为阴离子表面活性剂洗涤剂、 阳离子表 面活性剂洗涤剂、 两性离子表面活性剂洗涤剂或非离子表面活性剂洗涤 剂,也可以是上述能复配的表面活性剂的混合洗涤剂,优选为阴离子表面 活性剂洗涤剂和 /或非离子表面活性剂洗涤剂, 其中, 所述阴离子表面活 性剂洗涤剂包括但不限于十二烷基苯横 S史钠洗涤剂、油酸乙酯磺酸钠洗涤 剂、 油酰氨基酸钠洗涤剂和 N, N-油酰曱基牛磺酸钠洗涤剂; 所述非离 子表面活性剂如壬基酚聚氧乙烯醚洗涤剂、 烷基糖苷洗涤剂等。  In the present invention, the detergent may be an anionic surfactant detergent, a cationic surfactant detergent, a zwitterionic surfactant detergent or a nonionic surfactant detergent, or may be a compound surface as described above. a mixed detergent of active agents, preferably an anionic surfactant detergent and/or a nonionic surfactant detergent, wherein the anionic surfactant detergent includes, but is not limited to, lauryl benzene cross S sodium washing Agent, sodium oleate ethyl sulfonate detergent, oleoylamino sodium detergent and N, N-oleoyl hydrazino sodium taurate detergent; the nonionic surfactant such as nonylphenol ethoxylate wash Agent, alkyl glycoside detergent, and the like.
所述添加剂优选为油脂性物质、 水解蛋白质、 醇、 无机盐、 防腐剂、 增泡剂、 抗头屑剂、 表面活性调理剂、 非离子调理剂、 阳离子调理剂、 香 精和色素中的一种或多种。  The additive is preferably one of an oily substance, a hydrolyzed protein, an alcohol, an inorganic salt, a preservative, a foam booster, an antidandruff agent, a surface active conditioner, a nonionic conditioner, a cationic conditioner, a fragrance, and a pigment. Or a variety.
其中, 所述油脂性物质优选为乙氧化椰子油单乙醇胺、 杏仁油、 橄 榄油、 水溶性羊毛脂、 葵花油、 甘草精油、 春黄菊油、 海龟油、 鲨烯、 貉 油、 液体石蜡、 肉豆蔻酸辛基月桂酯、棕榈酸异丙酯和液体异烷烃中的一 种或多种, 能起到稳泡作用、 促泡作用和润滑、 滋养毛发等调理作用。 所 述水解蛋白质优选为水解角蛋白或水解动物胶,对毛发能起到良好的护理 作用。 所述醇优选为乙醇或异丙醇, 其属于优良的溶剂。 所述无机盐优选 为氯化钠、 氯化铵、 氯化钾、 偏磷酸盐、 正磷酸盐和硫酸盐中的一种或多 种, 可起到增稠作用。 所述防腐剂优选为对羟基苯曱酸, 不会对健康造成 危害。 所述增泡剂优选为椰子油二乙醇胺,便于应用。 所述抗头屑剂优选 为巯基吡啶氧化锌、硫化硒、硫、 水杨酸和十一烯酸衍生物中的一种或多 种, 能止痒去头屑。 所述表面活性调理剂优选为麦芽油衍生物, 具有增稠 作用和美发、护发等调理作用。所述非离子调理剂优选为脂肪醇聚氧乙烯 醚或聚山梨醇酯, 具有乳化、发泡和去污等作用。 所述阳离子调理剂优选 为聚季铵盐、 丙烯酰胺聚合物或阳离子瓜尔胶, 能起到增稠作用和增加毛 发光泽、保持毛发易梳理等调理作用。所述香精和所述色素分别采用本领 域常用的即可, 本发明对其均没有特殊限制。 Wherein, the oleaginous substance is preferably ethoxylated coconut oil monoethanolamine, almond oil, olive oil, water-soluble lanolin, sunflower oil, licorice oil, chamomile oil, sea turtle oil, squalene, eucalyptus oil, liquid paraffin, meat One or more of octyl lauryl myristate, isopropyl palmitate and liquid isoalkane, which can stabilize the foaming effect, promote foaming, and lubricate and nourish the hair. The hydrolyzed protein is preferably hydrolyzed keratin or hydrolyzed animal glue, which can have a good nursing effect on hair. The alcohol is preferably ethanol or isopropanol, which is an excellent solvent. The inorganic salt is preferably one or more of sodium chloride, ammonium chloride, potassium chloride, metaphosphate, orthophosphate and sulfate, and can serve as a thickening effect. The preservative is preferably p-hydroxybenzoic acid and does not pose a health hazard. The suds booster is preferably coconut oil diethanolamine for ease of application. The antidandruff agent is preferably one or more of zinc pyrithione, selenium sulfide, sulfur, salicylic acid and undecylenic acid derivatives, which can relieve itching and dandruff. The surface active conditioning agent is preferably a malt oil derivative having a thickening action and conditioning effects such as hairdressing and hair care. The nonionic conditioning agent is preferably a fatty alcohol polyoxyethylene ether or polysorbate, which has the functions of emulsification, foaming and decontamination. The cationic conditioning agent is preferably a polyquaternium, an acrylamide polymer or a cationic guar gum, which can thicken and increase hair It has a lightening effect and keeps the hair easy to comb and so on. The flavor and the pigment are respectively used in the art, and the present invention is not particularly limited.
在本发明中, 所述增色毛发用洗涤剂组合物包含 2〜98重量份的增深 剂, 优选包含 10〜80重量份的增深剂, 更优选包含 20〜50重量份的增深 剂。  In the present invention, the detergent composition for color-increasing hair contains 2 to 98 parts by weight of a deepening agent, preferably 10 to 80 parts by weight of a deepening agent, more preferably 20 to 50 parts by weight of a deepening agent.
所述增深剂为曱壳素、 壳聚糖、硅油类化合物、稀土和树脂中的一种 或多种, 优选为稀土和 /或树脂, 固色作用和增深效果较好。  The deepening agent is one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin, preferably a rare earth and/or a resin, and has a good fixing effect and a deepening effect.
由于毛发的颜色由色相、 纯度和明度(光泽) 决定, 在不同的色相、 光泽下, 如果光波的反射率、透射率不同, 含有浓淡和受光程度不同而表 现出明暗层次的视觉效果。毛发的光泽是正反色光、表面反射光和来自内 部的散射光共同作用的结果,其中的反射光是主体部分。提高毛发颜色深 度的主要途径是减弱其对光的反射和散射能力,使更多的可见光进入毛发 内部, 使毛发发生选择性吸收后产生深色效果。  Since the color of hair is determined by hue, purity and lightness (gloss), under different hue and luster, if the reflectance and transmittance of light waves are different, the shades and the degree of light reception are different, and the visual effects of light and dark levels are exhibited. The luster of the hair is the result of a combination of positive and negative chromatic light, surface reflected light, and scattered light from the interior, where the reflected light is the bulk portion. The main way to increase the color depth of the hair is to reduce its ability to reflect and scatter light, allowing more visible light to enter the hair, allowing the hair to be selectively absorbed to produce a darker effect.
所述树脂、所述硅油类化合物、所述曱壳素或所述壳聚糖对毛发具有 极强的吸附性,可以与毛纤维中的活性基团紧密地结合, 能在毛发表面形 成一层均匀的低折射率薄膜,减弱毛发对光的反射和散射能力,使更多的 可见光进入毛发内部, 从而使毛发对光发生选择性吸收后产生深色效果; 由于在毛发表面形成的膜对光的反射与吸收不同, 毛发的明度有所下降, 颜色看上去变深, 虽然所形成的膜很薄, 约为 0.5 μ ηι, 但是毛发是毛纤 维的集合体, 大量毛纤维的这种效应合并在一起, 增深效果便较为突出, 因此在深度较高的毛发上的增深效果更为明显。所述树脂、所述硅油类化 合物、 所述曱壳素或所述壳聚糖同时具有固色的功能、使毛发滑爽、顺直 等养护作用及杀螨抑菌、 消炎止痛、 促进头发伤口愈合的保健作用。  The resin, the silicone oil compound, the chitin or the chitosan have strong adsorption to hair, can be tightly combined with active groups in the hair fiber, and can form a layer on the hair surface. A uniform low-refractive-index film that weakens the ability of the hair to reflect and scatter light, allowing more visible light to enter the interior of the hair, thereby allowing the hair to selectively absorb light and produce a dark color effect; due to the film-forming light formed on the surface of the hair The reflection is different from the absorption, the brightness of the hair is reduced, the color looks darker, although the film formed is very thin, about 0.5 μ ηι, but the hair is a collection of hair fibers, and this effect of a large number of wool fibers is combined. Together, the effect of deepening is more prominent, so the deepening effect on the hair with higher depth is more obvious. The resin, the silicone oil compound, the chitin or the chitosan have the function of fixing color, smoothing hair, straightening and the like, killing and inhibiting bacteria, reducing inflammation and relieving pain, promoting hair wounds The health benefits of healing.
在本发明中, 所述树脂优选为有机氟树脂、有机硅树脂、 聚胺类树脂 和聚氨酯树脂中的一种或多种。所述树脂的折射率越低,其增深效果就越 好, 所述树脂优选为折射率在 1.5以下的树脂。  In the present invention, the resin is preferably one or more of an organic fluororesin, a silicone resin, a polyamine resin, and a urethane resin. The lower the refractive index of the resin, the better the deepening effect, and the resin is preferably a resin having a refractive index of 1.5 or less.
所述硅油类化合物优选为羟基硅油、烷基硅油、氨基硅油、二曱基硅 油、含氟硅油和聚醚改性硅油中的一种或多种, 其中, 二曱基硅油又称有 机硅油、硅油等, 是一种不同聚合度链状结构的聚有机硅氧烷, 其制备方 法包括: 二曱基二氯硅烷加水水解制得初缩聚环体, 环体经裂解、精馏制 得低环体, 然后把环体、 封头剂、 催化剂混合调聚, 得到聚合度不同的混 合物, 经减压蒸馏除去低沸物, 即得二曱基硅油。 所述二曱基硅油如 SILANOL SF9188、 SILANOLSF9103 , 折射率一般为 1.40〜1.45; 所述含 氟硅油的折射率一般在 1.38以下。 The silicone oil compound is preferably one or more of a hydroxy silicone oil, an alkyl silicone oil, an amino silicone oil, a dimercapto silicone oil, a fluorine-containing silicone oil, and a polyether modified silicone oil, wherein the dimercapto silicone oil is also called a silicone oil, Silicone oil, etc., is a polyorganosiloxane of different polymerization degree chain structure, and its preparation The method comprises the following steps:: dimercaptodichlorosilane is hydrolyzed by hydrolysis to obtain a polycondensation ring, and the ring body is subjected to cracking and rectification to obtain a low ring body, and then the ring body, the heading agent and the catalyst are mixed and condensed to obtain different degrees of polymerization. The mixture is subjected to distillation under reduced pressure to remove low boilers to obtain a dimercaptosilicone oil. The dimercaptosilicone oil such as SILANOL SF9188, SILANOLSF9103 has a refractive index of generally 1.40 to 1.45; and the fluorine-containing silicone oil has a refractive index of generally 1.38 or less.
所述曱壳素又称曱壳质、几丁质,化学名称为(1-4 ) -2-乙酰胺基 -2- 脱氧 - β -D-葡萄糖,或简称聚乙酰胺基葡萄糖。所述壳聚糖又称脱乙酰曱 壳素、 曱壳胺, 其是一种由主要来源于虾、 蟹等水生贝壳动物外壳的曱壳 素在碱性条件下水解, 脱掉乙酰基而形成的可溶性曱壳素, 化学名称为 ( 1-4 ) _2-氨基-2-脱氧-8-0-葡萄糖, 或简称聚胺基葡萄糖。 所述曱壳素 与所述壳聚糖带有不饱和阳离子基团,对带有负电荷的毛发具有强大的吸 附作用, 形成分子厚度的薄膜层, 其具有极低反射率,使射入毛发表面的 光在毛发表面产生折射、漫反射,从而使毛发对入射光的吸收量大大增加, 反射光减少, 达到增深效果。 同时, 所述曱壳素与所述壳聚糖还能与染色 后的毛发上的染发剂结合,不但能使染发剂的色牢度提高, 而且能使染发 剂的分子量增大,导致染色后的毛发色泽加深,从而具有增深作用。另外, 所述曱壳素与所述壳聚糖的来源丰富, 价格低廉, 较为适于推广应用。  The chitin is also known as chitin, chitin, and has the chemical name (1-4)-2-acetamido-2-deoxy-β-D-glucose, or polyacetamide-based glucose. The chitosan is also called chitosan, chitosan, which is a kind of chitin which is mainly derived from shells of aquatic shellfish such as shrimps and crabs, and is hydrolyzed under alkaline conditions to form an acetyl group. The soluble chitin, chemical name is (1-4) _2-amino-2-deoxy-8-0-glucose, or simply polyaminoglucose. The chitin and the chitosan have an unsaturated cationic group, and have a strong adsorption effect on the negatively charged hair, forming a film layer of molecular thickness, which has a very low reflectance and allows injection into the hair. The surface light produces refraction and diffuse reflection on the surface of the hair, so that the absorption of incident light by the hair is greatly increased, and the reflected light is reduced to achieve a deepening effect. At the same time, the chitin and the chitosan can also be combined with the hair dye on the dyed hair, which not only can improve the color fastness of the hair dye, but also increase the molecular weight of the hair dye, resulting in dyeing. The hair has a darker color, which has a deepening effect. In addition, the chitin and the chitosan are rich in source and low in price, and are suitable for popularization and application.
所述稀土首先能与染色后的毛发上的染发剂分子中羟基氧原子、偶氮 基氮原子、磺酸基氧原子间存在络合作用,不但能使染发剂与染色后的毛 发的非极性部分之间的分子间作用力增大, 色牢度提高, 而且能使染发剂 的分子量增大, 色泽加深,从而使洗后的染发保持原有颜色的深度、 色泽 鲜艳度提高; 其次, 所述稀土能使毛纤维上污垢的有色物质活化, 降低洗 涤反应的活化能, 使污垢与洗涤剂的反应更容易进行, 即, 对毛发的洗涤 反应有活性催化作用,从而使毛发更为洁净; 再次, 所述稀土本身的最大 吸收波长为 580nm, 具有对泛灰、 泛黄或颜色变浅的毛发的黄光进行选 择性吸收的能力, 使泛黄变浅的毛发的颜色增深。 因此, 所述稀土能使原 有毛发在洗后的颜色增深,使染色后的毛发的在洗后的颜色深而艳、 色光 纯正、 色牢度高。 另外, 所述稀土具有较强络合作用, 其进入毛纤维的无 定形区时能借助配位键、共价键形成络合物,起到一种交联剂的作用, 从 而使毛发的强力得以提高。本发明对所述稀土的种类没有特殊限制,可采 用纯度在 46%以上的混合氯化稀土, 也可采用以纯度在 99.9999%以上的 单一稀土氧化镧( La203 )、单一稀土氧化钦 ( NdZO )为原料生产的 CR-1、 CR-2、 CR-3等产品。 The rare earth can first cooperate with the hydroxyl oxygen atom, the azo nitrogen atom, the sulfonic acid oxygen atom in the hair dye molecule on the dyed hair, and can not only make the hair dye and the non-polar hair of the dyed hair. The intermolecular interaction between the sexual parts is increased, the color fastness is improved, and the molecular weight of the hair dye is increased, and the color is deepened, so that the dyed hair after washing maintains the depth of the original color and the color vividness is improved; The rare earth can activate the colored substance of the dirt on the wool fiber, reduce the activation energy of the washing reaction, and make the reaction of the dirt and the detergent easier, that is, the active reaction of the hair washing reaction, thereby making the hair more clean. Further, the rare earth itself has a maximum absorption wavelength of 580 nm, and has the ability to selectively absorb yellow light of gray, yellow, or light-colored hair, and deepens the color of the yellowish-lightened hair. Therefore, the rare earth can deepen the color of the original hair after washing, so that the color of the dyed hair after washing is deep and bright, the color is pure, and the color fastness is high. In addition, the rare earth has a strong complexing property, and when it enters the amorphous region of the wool fiber, it can form a complex by means of a coordination bond or a covalent bond, and functions as a crosslinking agent. And the strength of the hair is improved. The type of the rare earth in the present invention is not particularly limited, and a mixed rare earth cerium oxide (La203) having a purity of more than 99.9999% or a single rare earth oxidized yttrium (NdZO) may be used. CR-1, CR-2, CR-3 and other products produced for raw materials.
在本发明中, 所述增色毛发用洗涤剂组合物包含 3〜96重量份的固色 剂, 优选包含 10〜90重量份的固色剂, 更优选包含 20-40重量份的固色 剂。  In the present invention, the detergent composition for color-increasing hair contains 3 to 96 parts by weight of a fixing agent, preferably 10 to 90 parts by weight of a fixing agent, more preferably 20 to 40 parts by weight of a fixing agent.
所述固色剂能提高染色后的毛发颜色的牢度, 优选为阳离子树脂固 色剂、反应型固色剂、 季铵盐固色剂或有机硅类固色剂, 更优选为阳离子 树脂固色剂、反应型固色剂或季铵盐固色剂。 其中, 所述阳离子树脂固色 剂如固色剂 Y、 固色剂 Μ和固色剂 FLZOIL-810等; 所述反应型固色剂 如固色剂 NGC、 固色剂 C和固色剂 DR-100等; 所述季铵盐固色剂如固 色剂 ECEOTIXFD-3、 固色剂 ECEOTIXNF-50和固色剂 TCD-R等; 所述 有机硅类固色剂包括有机硅、阳离子反应型有机硅和无酸有机硅等。所述 固色剂的固色原理可以为: 阳离子性基团与碱性水溶液接触,析出形成含 水凝胶,这种含水凝胶可吸附重金属离子和色素,并能在干燥后在毛纤维 表面形成一层薄膜, 从而对染发剂起到良好的固定、 保护作用。  The fixing agent can improve the color fastness of the dyed hair, and is preferably a cationic resin fixing agent, a reactive fixing agent, a quaternary ammonium salt fixing agent or a silicone fixing agent, more preferably a cationic resin solid. A toner, a reactive fixing agent or a quaternary ammonium salt fixing agent. Wherein, the cationic resin fixing agent such as fixing agent Y, fixing agent Μ and fixing agent FLZOIL-810, etc.; the reactive fixing agent such as fixing agent NGC, fixing agent C and fixing agent DR -100, etc.; the quaternary ammonium salt fixing agent such as fixing agent ECEOTIXFD-3, fixing agent ECEOTIXNF-50 and fixing agent TCD-R, etc.; the silicone fixing agent comprises silicone, cationic reaction type Silicone and acid-free silicone. The fixing principle of the fixing agent may be: a cationic group is contacted with an alkaline aqueous solution to form a hydrogel, which adsorbs heavy metal ions and pigments, and can form on the surface of the wool fiber after drying. A layer of film, which plays a good role in fixing and protecting the hair dye.
在本发明中, 所述增色毛发用洗涤剂组合物优选还包含 5〜95重量份 的中药乌发剂, 更优选还包含 10〜50重量份的中药乌发剂。  In the present invention, the detergent composition for color-increasing hair preferably further comprises 5 to 95 parts by weight of a traditional Chinese medicine, and more preferably 10 to 50 parts by weight of a traditional Chinese medicine.
所述中药乌发剂采用本领域常用的中药乌发提取物即可, 优选为何 首乌提取物、 人参提取物、 黄芪提取物、 芦荟提取物、 当归提取物和枸杞 提取物中的一种或多种, 更优选为何首乌提取物、人参提取物、 黄芪提取 物、 当归提取物和枸杞提取物中的一种或多种。  The traditional Chinese medicine Wufa agent can be used as a traditional Chinese medicine Wufa extract in the field, and preferably why one or more of Shouwu extract, ginseng extract, Astragalus membranaceus extract, Aloe extract, Angelica extract and Lycium barbarum extract are extracted. More preferably, one or more of Shouwu extract, ginseng extract, Astragalus extract, Angelica extract and Lycium barbarum extract.
本发明还提供了一种增色毛发用洗涤剂组合物的制备方法, 包括以 下步骤:  The present invention also provides a method for preparing a detergent composition for color enhancement, comprising the steps of:
称取如下重量份的原料:  Weigh the following parts by weight:
5〜95重量份的毛发用洗涤剂;  5 to 95 parts by weight of a hair detergent;
2〜98重量份的增深剂, 所述增深剂为曱壳素、 壳聚糖、 硅油类化合 物、 稀土和树脂中的一种或多种; 3〜96重量份的固色剂; 2 to 98 parts by weight of a deepening agent, the deepening agent being one or more of chitin, chitosan, a silicone oil compound, a rare earth and a resin; 3 to 96 parts by weight of a fixing agent;
将所述原料在温度为 0〜550°C的条件下混合,得到增色毛发用洗涤剂 组合物。  The raw materials were mixed at a temperature of 0 to 550 ° C to obtain a detergent composition for coloring hair.
本发明按照上述重量份称取上述原料后, 将其在 0〜550°C、 优选 10 °C〜250°C、 更优选 30°C〜160°C的温度下混合, 得到增色毛发用洗涤剂组 合物。 为了进一步达到美发目的, 本发明优选还包括混入 5〜95重量份的 中药乌发剂。 本发明对所述混合的设备等其他条件没有特殊限制。  In the present invention, the raw materials are weighed according to the above-mentioned parts by weight, and then mixed at a temperature of 0 to 550 ° C, preferably 10 ° C to 250 ° C, more preferably 30 ° C to 160 ° C to obtain a detergent for coloring hair. combination. In order to further achieve the purpose of hairdressing, the present invention preferably further comprises mixing 5 to 95 parts by weight of a traditional Chinese medicine urinary agent. The present invention is not particularly limited to other conditions such as the mixed device.
得到增色毛发用洗涤剂组合物后, 采用其对各种颜色的毛发或染色 后的毛发进行多次洗涤, 所述洗涤可以是浸洗, 也可以是喷淋, 其中, 所 述浸洗具体为: 在 0〜70°C的温度下, 将 0. lmL〜100mL所述增色毛发用洗 涤剂组合物用 lmL〜100mL的水溶解,搅拌均匀后,在 0〜100°C的温度下, 将 lg〜1000g待洗的毛发浸入其中, lmin〜100min后, 吸水吹干或自然晾 干。 所述喷淋具体为: 通过雾状发生器, 将所述增色毛发用洗涤剂组合物 直接喷淋到干燥的待洗的毛发上, lmin〜100min后, 烘干或自然晾干。  After the detergent composition for color-increasing hair is obtained, the hair of each color or the dyed hair is washed a plurality of times, and the washing may be a dipping or a shower, wherein the dipping is specifically : at a temperature of 0 to 70 ° C, 0.1 ml to 100 mL of the coloring hair detergent composition is dissolved in 1 mL to 100 mL of water, stirred uniformly, and then at a temperature of 0 to 100 ° C, lg ~1000g of hair to be washed is immersed in it, after lmin~100min, it is dried by water or dried naturally. The spraying is specifically: spraying the coloring hair with a detergent composition directly onto the dry hair to be washed by a mist generator, after lmin~100min, drying or drying naturally.
实验表明, 经过本发明提供的增色毛发用洗涤剂组合物处理的原有 毛发或染色后的毛发, 不但干净, 而且其颜色被增深、 增艳, 达到越洗越 深、 常洗常新的效果, 能免除反复染色及其形成的污染等问题,从而使美 发更为简单方便, 同时也节约了大量生活资金。  Experiments have shown that the original hair or dyed hair treated by the detergent composition for color-increasing hair provided by the present invention is not only clean, but also its color is deepened and brightened, and the deeper the wash, the more often it is washed. The effect can avoid the problems of repeated dyeing and the pollution caused by it, which makes the hairdressing simpler and more convenient, and also saves a lot of living capital.
为了进一步理解本发明, 下面结合实施例对本发明提供的增色毛发 用洗涤剂组合物及其制备方法进行详细地描述。  In order to further understand the present invention, the detergent composition for color-increasing hair provided by the present invention and a method for producing the same are described in detail below with reference to the examples.
实施例 1  Example 1
称取 5 重量份的十二烷基苯横 S史钠洗涤剂、 98重量份的壳聚糖、 3 重量份的固色剂 Y;  Weigh 5 parts by weight of dodecylbenzene cross S sodium detergent, 98 parts by weight of chitosan, 3 parts by weight of fixing agent Y;
将上述原料在温度为 30°C的条件下混合, 得到增色毛发用洗涤剂组 合物。  The above raw materials were mixed at a temperature of 30 ° C to obtain a detergent composition for color enhancement of hair.
分别采用所述增色毛发用洗涤剂组合物喷淋红色、 黄色、 蓝色、 紫 色和黑色的待洗的染色后的头发, 处理 10次后, 被洗的染色后的头发的 颜色为红色、 黄色、 蓝色、 紫色和黑色。  The dyed hair to be washed in red, yellow, blue, purple and black is sprayed with the detergent composition for color-increasing hair respectively, and after being treated 10 times, the color of the dyed hair after washing is red and yellow. , blue, purple and black.
比较例 1 称取 5重量份的十二烷基苯横 S史钠洗涤剂和 81重量份的水, 在温度 为 30°C的条件下混合, 得到毛发洗涤剂组合物。 Comparative example 1 5 parts by weight of sodium dodecylbenzene s-sodium detergent and 81 parts by weight of water were weighed and mixed at a temperature of 30 ° C to obtain a hair detergent composition.
分别采用所述毛发洗涤剂组合物喷淋红色、 黄色、 蓝色、 紫色和黑 色的待洗的染色后的头发, 处理 10次后, 被洗的染色后的头发的颜色为 浅红色、 浅黄色、 浅蓝色、 浅紫色和灰色。  The hair washing composition is sprayed with red, yellow, blue, purple and black dyed hair, respectively, after being treated for 10 times, and the color of the dyed hair after washing is light red and light yellow. , light blue, light purple and grey.
实施例 2  Example 2
称取 94重量份的壬基酚聚氧乙烯醚洗涤剂、 0.1重量份的氯化钠、 0.1 重量份的乙氧化椰子油单乙醇胺、 0.1重量份的乙醇、 0.1重量份的水解角 蛋白、 0.1重量份的对羟基苯曱酸、 0.2重量份的椰子油二乙醇胺、 0.1重 量份的水杨酸、 0.2 重量份的阳离子瓜尔胶、 2 重量份的稀土产品 CR-1 和 96重量份的固色剂 Y;  Weigh 94 parts by weight of nonylphenol ethoxylate detergent, 0.1 part by weight of sodium chloride, 0.1 part by weight of ethoxylated coconut oil monoethanolamine, 0.1 part by weight of ethanol, 0.1 part by weight of hydrolyzed keratin, 0.1 Parts by weight of p-hydroxybenzoic acid, 0.2 parts by weight of coconut oil diethanolamine, 0.1 parts by weight of salicylic acid, 0.2 parts by weight of cationic guar gum, 2 parts by weight of rare earth product CR-1 and 96 parts by weight of solid Toner Y;
将上述原料在温度为 50°C的条件下混合, 得到增色毛发用洗涤剂组 合物。  The above raw materials were mixed at a temperature of 50 ° C to obtain a detergent composition for color enhancement of hair.
分别采用所述增色毛发用洗涤剂组合物浸洗红色、 黄色、 蓝色、 紫 色和黑色的待洗的染色后的头发, 处理 10次后, 被洗的染色后的头发的 颜色为红色、 艳黄色、 蓝色、 紫色和黑色。  The red, yellow, blue, purple and black dyed hairs to be washed are respectively washed with the detergent composition for color-increasing hair, and after being treated 10 times, the color of the dyed hair after washing is red and bright. Yellow, blue, purple and black.
实施例 3  Example 3
称取 19重量份的烷基糖苷洗涤剂、 40重量份的 SILANOL SF9188 和 25重量份的固色剂 Y;  Weighing 19 parts by weight of alkyl glycoside detergent, 40 parts by weight of SILANOL SF9188 and 25 parts by weight of fixing agent Y;
将上述原料在温度为 30°C的条件下混合, 得到增色毛发用洗涤剂组 合物。  The above raw materials were mixed at a temperature of 30 ° C to obtain a detergent composition for color enhancement of hair.
分别采用所述增色毛发用洗涤剂组合物浸洗红色、 黄色、 蓝色、 紫 色和黑色的待洗的染色后的头发, 处理 10次后, 被洗的染色后的头发的 颜色为红色、 黄色、 蓝色、 紫色和黑色。  The dyed hair to be washed in red, yellow, blue, purple and black is digested with the detergent composition for color-increasing hair respectively, and after being treated 10 times, the color of the dyed hair after washing is red and yellow. , blue, purple and black.
实施例 4  Example 4
称取 77重量份的油酸乙酯磺酸钠洗涤剂、 11重量份的聚氨酯、 3重 量份的稀土产品 CR-2和 16重量份的固色剂 Y;  Weighing 77 parts by weight of sodium oleate ethyl sulfonate detergent, 11 parts by weight of polyurethane, 3 parts by weight of rare earth product CR-2 and 16 parts by weight of fixing agent Y;
将上述原料在温度为 110°C的条件下混合,得到增色毛发用洗涤剂组 合物。 分别采用所述增色毛发用洗涤剂组合物喷淋红色、 黄色、 蓝色、 紫 色和黑色的待洗的染色后的头发, 处理 10次后, 被洗的染色后的头发的 颜色为红色、 黄色、 蓝色、 紫色和黑色。 The above raw materials were mixed at a temperature of 110 ° C to obtain a detergent composition for color-increasing hair. The dyed hair to be washed in red, yellow, blue, purple and black is sprayed with the detergent composition for color-increasing hair respectively, and after being treated 10 times, the color of the dyed hair after washing is red and yellow. , blue, purple and black.
实施例 5  Example 5
称取 20重量份的十二烷基苯横 S史钠洗涤剂、 Ί重量份的烷基糖苷洗 涤剂、 36重量份的聚醚改性硅油、 5重量份的稀土产品 CR-3、 51重量份 的固色剂 Y和 5重量份的枸杞提取物;  Weigh 20 parts by weight of dodecylbenzene cross S sodium detergent, hydrazine part by weight alkyl glycoside detergent, 36 parts by weight of polyether modified silicone oil, 5 parts by weight of rare earth product CR-3, 51 weight Parts of fixing agent Y and 5 parts by weight of cockroach extract;
将上述原料在温度为 50°C的条件下混合, 得到增色毛发用洗涤剂组 合物。  The above raw materials were mixed at a temperature of 50 ° C to obtain a detergent composition for color enhancement of hair.
分别采用所述增色毛发用洗涤剂组合物浸洗红色、 黄色、 蓝色、 紫 色和黑色的待洗的染色后的头发, 洗涤 10次后, 被洗的染色后的头发的 颜色为红色、 黄色、 蓝色、 紫色和黑色。  The dyed hair to be washed in red, yellow, blue, purple and black is digested with the detergent composition for color-increasing hair, respectively. After washing 10 times, the color of the dyed hair after washing is red and yellow. , blue, purple and black.
由以上实施例和比较例可知, 采用本发明提供的增色毛发用洗涤剂 组合物洗涤染色后的毛发时,对毛发的颜色有增深作用,从而能使洗后的 染发的原有颜色被固色的同时, 其颜色被增深。  It can be seen from the above examples and comparative examples that when the dyed hair is washed by the detergent composition for color-increasing hair provided by the present invention, the color of the hair is deepened, so that the original color of the dyed hair after washing is solidified. At the same time, its color is deepened.
以上实施例的说明只是用于帮助理解本发明的方法及其核心思想。应 当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前 提下,还可以对本发明进行若干改进和修饰,这些改进和修饰也落入本发 明权利要求的保护范围内。  The above description of the embodiments is merely to assist in understanding the method of the present invention and its core idea. It is to be understood that those skilled in the art can make various modifications and changes to the present invention without departing from the spirit and scope of the invention.
+ +

Claims

权 利 要 求 Rights request
1、 一种增色毛发用洗涤剂组合物, 包含: 1. A detergent composition for color-enhancing hair, comprising:
5〜95重量份的毛发用洗涤剂; 5 to 95 parts by weight of hair detergent;
2〜98重量份的增深剂, 所述增深剂为曱壳素、 壳聚糖、 硅油类化合 物、 稀土和树脂中的一种或多种; 2 to 98 parts by weight of a deepening agent, which is one or more of chitin, chitosan, silicone oil compounds, rare earths and resins;
3〜96重量份的固色剂。 3~96 parts by weight of color fixing agent.
2、 根据权利要求 1所述的增色毛发用洗涤剂组合物, 其特征在于, 所述树脂为有机氟树脂、有机硅树脂、聚胺类树脂和聚氨酯树脂中的一种 或多种。 2. The detergent composition for color-increasing hair according to claim 1, characterized in that the resin is one or more of organic fluorine resin, silicone resin, polyamine resin and polyurethane resin.
3、 根据权利要求 1所述的增色毛发用洗涤剂组合物, 其特征在于, 所述硅油类化合物为羟基硅油、 烷基硅油、 氨基硅油、 二曱基硅油、 含氟 硅油和聚醚改性硅油中的一种或多种。 3. The detergent composition for color-increasing hair according to claim 1, characterized in that the silicone oil compound is hydroxyl silicone oil, alkyl silicone oil, amino silicone oil, dimethyl silicone oil, fluorine-containing silicone oil and polyether modified One or more types of silicone oil.
4、 根据权利要求 1所述的增色毛发用洗涤剂组合物, 其特征在于, 所述固色剂为阳离子树脂固色剂、反应型固色剂、季铵盐固色剂或有机硅 类固色剂。 4. The detergent composition for color-increasing hair according to claim 1, characterized in that the color-fixing agent is a cationic resin color-fixing agent, a reactive color-fixing agent, a quaternary ammonium salt color-fixing agent or an organic silicone-based color-fixing agent. Toner.
5、 根据权利要求 1所述的增色毛发用洗涤剂组合物, 其特征在于, 所述毛发用洗涤剂由洗涤剂和添加剂组成。 5. The color-enhancing hair detergent composition according to claim 1, characterized in that the hair detergent consists of detergent and additives.
6、 根据权利要求 5所述的增色毛发用洗涤剂组合物, 其特征在于, 所述洗涤剂为阴离子表面活性剂洗涤剂和 /或非离子表面活性剂洗涤剂。 6. The detergent composition for color-enhancing hair according to claim 5, characterized in that the detergent is an anionic surfactant detergent and/or a nonionic surfactant detergent.
7、 根据权利要求 5所述的增色毛发用洗涤剂组合物, 其特征在于, 所述添加剂为油脂性物质、 水解蛋白质、 醇、 无机盐、 防腐剂、 增泡剂、 抗头屑剂、 表面活性调理剂、 非离子调理剂、 阳离子调理剂、 香精和色素 中的一种或多种。 7. The detergent composition for color-enhancing hair according to claim 5, characterized in that the additives are greasy substances, hydrolyzed proteins, alcohols, inorganic salts, preservatives, foaming agents, anti-dandruff agents, surface One or more of active conditioners, non-ionic conditioners, cationic conditioners, flavors and pigments.
8、 根据权利要求 1所述的增色毛发用洗涤剂组合物, 其特征在于, 还包含 5〜95重量份的中药乌发剂。 8. The detergent composition for color-enhancing hair according to claim 1, characterized in that it also contains 5 to 95 parts by weight of a traditional Chinese medicine hair-blackening agent.
9、 根据权利要求 8所述的增色毛发用洗涤剂组合物, 其特征在于, 所述中药乌发剂为何首乌提取物、人参提取物、黄芪提取物、芦荟提取物、 当归提取物和枸杞提取物中的一种或多种。 9. The detergent composition for hair color enhancement according to claim 8, characterized in that the traditional Chinese medicine black hair agent is polygonum multiflorum extract, ginseng extract, astragalus extract, aloe extract, angelica extract and wolfberry extract. one or more of the things.
10、 一种增色毛发用洗涤剂组合物的制备方法, 包括以下步骤: 称取如下重量份的原料: 10. A method for preparing a detergent composition for hair coloring, including the following steps: Weigh the following raw materials in parts by weight:
5〜95重量份的毛发用洗涤剂; 5 to 95 parts by weight of hair detergent;
2〜98重量份的增深剂, 所述增深剂为曱壳素、 壳聚糖、 硅油类化合 2 to 98 parts by weight of deepening agent, the deepening agent is chitin, chitosan, silicone oil compounds
物、 稀土和树脂中的一种或多种; One or more of materials, rare earths and resins;
3〜96重量份的固色剂; 3~96 parts by weight of color fixing agent;
将所述原料在温度为 0〜550°C的条件下混合,得到增色毛发用洗涤剂 组合物。 The raw materials are mixed at a temperature of 0 to 550°C to obtain a hair coloring detergent composition.
+ +
PCT/CN2013/071879 2012-08-13 2013-02-26 Detergent composition for darkening hair and method for preparing same WO2014026476A1 (en)

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102772336B (en) * 2012-08-13 2015-03-18 宋子奎 Washing agent composition for colored hairs and preparation method for washing agent composition
CN103556464B (en) * 2013-10-29 2015-06-10 宋子奎 Fabric function repair agent composition and preparation method of fabric function repair agent composition
CN104721069B (en) * 2015-04-09 2018-08-21 宋子奎 A kind of deep composition for hair dying of increasing
CN109939061B (en) * 2019-05-14 2020-11-27 连云港诗碧曼生物科技有限公司 Safe and non-irritant white hair blackening essence and preparation method thereof
CN111643397B (en) * 2020-07-09 2021-07-02 昆明理工大学 Green mordant, hair dye and hair dyeing method
CN113520947A (en) * 2021-08-04 2021-10-22 广州葆妍生物科技有限公司 Color-fixing hair-care composition and preparation and application thereof
CN115387140A (en) * 2021-10-27 2022-11-25 青岛融美发制品集团有限公司 Wig color fixation treatment mode and color fixing agent used by wig color fixation treatment mode

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995034271A1 (en) * 1994-06-15 1995-12-21 Wella Aktiengesellschaft Hair-cleaning agent with good hair-hold characteristics
WO2010074810A1 (en) * 2008-12-15 2010-07-01 Dow Corning Corporation Home and personal care compositions
WO2011079187A1 (en) * 2009-12-23 2011-06-30 Momentive Performance Materials Inc. Network copolymer crosslinked compositions and products comprising the same
WO2011107713A2 (en) * 2010-03-03 2011-09-09 Rhodia Operations Novel agent for improving the deposition of oil on hair
CN102366382A (en) * 2011-09-26 2012-03-07 谢建武 Plant hair dye with isomerized C10 ethoxylate as penetrating agent and its preparation method
CN102772336A (en) * 2012-08-13 2012-11-14 宋子奎 Washing agent composition for colored hairs and preparation method for washing agent composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101214210A (en) * 2008-01-21 2008-07-09 杨钊 Liquid shampoo

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995034271A1 (en) * 1994-06-15 1995-12-21 Wella Aktiengesellschaft Hair-cleaning agent with good hair-hold characteristics
WO2010074810A1 (en) * 2008-12-15 2010-07-01 Dow Corning Corporation Home and personal care compositions
WO2011079187A1 (en) * 2009-12-23 2011-06-30 Momentive Performance Materials Inc. Network copolymer crosslinked compositions and products comprising the same
WO2011107713A2 (en) * 2010-03-03 2011-09-09 Rhodia Operations Novel agent for improving the deposition of oil on hair
CN102366382A (en) * 2011-09-26 2012-03-07 谢建武 Plant hair dye with isomerized C10 ethoxylate as penetrating agent and its preparation method
CN102772336A (en) * 2012-08-13 2012-11-14 宋子奎 Washing agent composition for colored hairs and preparation method for washing agent composition

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