WO2011119697A1 - Nitrogen rejection and liquifier system for liquified natural gas production - Google Patents

Nitrogen rejection and liquifier system for liquified natural gas production Download PDF

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Publication number
WO2011119697A1
WO2011119697A1 PCT/US2011/029575 US2011029575W WO2011119697A1 WO 2011119697 A1 WO2011119697 A1 WO 2011119697A1 US 2011029575 W US2011029575 W US 2011029575W WO 2011119697 A1 WO2011119697 A1 WO 2011119697A1
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Prior art keywords
natural gas
flash
gas
heat exchanger
liquefied natural
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PCT/US2011/029575
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French (fr)
Inventor
Rustam H. Sethna
Guillaume Pages
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Linde Aktiengesellschaft
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Publication of WO2011119697A1 publication Critical patent/WO2011119697A1/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/105—Removal of contaminants of nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
    • F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
    • F25J1/0219—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0258—Construction and layout of liquefaction equipments, e.g. valves, machines vertical layout of the equipments within in the cold box
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0259—Modularity and arrangement of parts of the liquefaction unit and in particular of the cold box, e.g. pre-fabrication, assembling and erection, dimensions, horizontal layout "plot"
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0262—Details of the cold heat exchange system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0262—Details of the cold heat exchange system
    • F25J1/0264—Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0291—Refrigerant compression by combined gas compression and liquid pumping
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/60—Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/66—Landfill or fermentation off-gas, e.g. "Bio-gas"
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30—Compression of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00—Processes or apparatus involving steps for recycling of process streams
    • F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00—Processes or apparatus involving steps for recycling of process streams
    • F25J2245/90—Processes or apparatus involving steps for recycling of process streams the recycled stream being boil-off gas from storage
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/32—Details on header or distribution passages of heat exchangers, e.g. of reboiler-condenser or plate heat exchangers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/62—Details of storing a fluid in a tank
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the invention relates to the integration of a liquefied natural gas (LNG) liquefier system with a nitrogen rejection unit (NRU) so as to minimize the capital and operating costs while maintaining liquefied natural gas product purity requirements.
  • LNG liquefied natural gas
  • NRU nitrogen rejection unit
  • renewable methane can be recovered from a number of sources, such as anaerobic digestion of municipal or industrial waste streams, the degradation of biomass in landfills, the gasification of waste and biomass streams, amongst others.
  • this renewable methane require purification before it can be used and/or sold into higher valued markets, such as injection into the pipeline grid, as a feedstock for liquefied natural gas, as a vehicle fuel, or as a feedstock for the production of hydrogen.
  • the energy that is required to purify the renewable methane is significant.
  • the stream is then treated for bulk carbon dioxide removal by a membrane or adsorption process and then is treated for removal of nitrogen. All these purification steps are necessary before the biogas/landfill gas can be liquefied and stored in anticipation of being dispensed, or directed towards other uses, such as pipeline injection, energy production with fuel cells or smail-scale hydrogen production. LNG production is particularly challenging since all condensable contaminants including carbon dioxide must be removed to low ppm levels.
  • the invention will allow for maximizing the methane recovery while maintaining high liquefied natural gas product purity.
  • the operator can utilize a smaller nitrogen rejection unit and can optimize power consumption.
  • the process of using the nitrogen rejection unit integrated with the liquefied natural gas liquefier system achieves greater product purity (>96 mol % methane) and greater than 89% methane recovery than conventional non-integrated
  • the invention further allows the operator to optimize power consumption while allowing for significantly higher product purity and methane recovery than conventional or unitegrated NRU and liquefier
  • the invention is a method for recovering liquefied natural gas comprising the steps:
  • the invention is a method for recovering liquefied natural gas comprising the steps:
  • the invention further comprises an apparatus comprising a nitrogen rejection unit, a liquefier heat exchanger and a flash vessel.
  • the raw feed gas is first compressed and pre-conditioned which entails the removal of water, carbon dioxide, non-methane organic compounds (NMOCs) and sulfur compounds by known methods.
  • the partially purified gas is fed to the nitrogen rejection unit where much of the nitrogen is rejected. Since product purity and methane recovery are inversely related, nitrogen rejection is limited to maximize the methane recovery for the smallest equipment cost.
  • the resulting gas which contains significantly lower amounts of inerts is fed to the liquefier heat exchanger where it is liquefied at pressure to a subcooled state. Typical pressures range from 30 bar to 6 bar with a tradeoff between mixed refrigeration compressor power and compression power for the purification system. This liquid is expanded through a valve whereby further cooling is effected to about 2 bar (range is 1 to 5 bar).
  • the two-phase mixture is separated in a flash vessel and the resulting liquid is directed to the storage tanks, while the flash gas which is richer in nitrogen is recycled back to the nitrogen rejection unit.
  • the flash gas can also be combined with the raw natural gas/biogas at the front end of the overall process if the nitrogen rejection unit does not have a recycle compressor. Clearly additional flash gas from the storage tank will be produced. This too is recycled back to the nitrogen rejection unit or to the front end of the cleanup process.
  • the only methane that will be lost is the nitrogen rejection unit waste stream which is nitrogen-rich but otherwise very pure and can be flared or converted into power using a gas engine or a fuel cell.
  • the end flash from the flash vessel has an additional advantage in that the liquid outlet of a flash is at equilibrium which implies that it will produce some more gas inside the line between the end flash and storage tank because of product line pressure drop. Therefore, it is best practice that the flash pressure be lower than the storage pressure.
  • the first flash within the flash vessel is effected at a pressure lower than the storage tank pressure, whence, the liquid coming down from the end-flash tank will be sub-cooled at storage pressure.
  • a cryogenic pump can be utilized to overcome this concern, but involves additional cost, maintenance and potential reliability issues. Therefore it is advisable to have horizontal storage tanks, and a cold box layout so that the liquid level inside the end flash will be higher by a few hundreds of mbar of equivalent liquefied natural gas head that the top of the storage and to use that additional head to pressurize Figure 2c.
  • Figure 1 is a typical mixed refrigerant liquefied natural gas liquefier.
  • Figure 2a is an integrated mixed refrigerant liquefied natural gas liquefier.
  • Figure 2b depicts a different embodiment of an integrated mixed refrigerant liquefied natural gas liquefier.
  • Figure 2c depicts another embodiment of an integrated mixed refrigerant liquefied natural gas liquefier.
  • Figure 3 shows methane recovery versus nitrogen rejection unit product methane content.
  • Figure 4 shows a liquefier embodied in the invention.
  • Figure 5a shows a liquefier having a lower cost to operate.
  • Figure 5b shows a different embodiment of a lower cost to operate liquefier.
  • Landfill gas is purified and ail the water, sulfur compounds, NMOCs and carbon dioxide are removed in a pre-purification process.
  • the purified gas contains methane, nitrogen and oxygen and has the following composition:
  • the gas is further purified in an adsorption system so that the carbon dioxide level is reduced below 50 ppmv and a large portion of the nitrogen is removed.
  • Oxygen usually does not adsorb appreciably and about 50% of the oxygen is removed in each case.
  • Figure 1 illustrates a typical MR liquefier stream without process integration. In this case both storage tank losses and nitrogen rejection unit waste streams are not recovered.
  • Figure 1 represents a base case mixed refrigerant liquefied natural gas liquefier. Purified natural gas is fed through line 1 through main heat exchanger A where it will be warmed and fed through valve V1 and line 2 as liquefied natural gas to a storage container, not shown.
  • a cold water stream (CWS) is fed through line 1 1 to heat exchanger E as well as through valve V6 and line 13 to line 12 as cold water return (CWR).
  • CWS cold water stream
  • the cold mixed refrigerant is fed through line 9 to knockout drum B where it will proceed through line 7A to refrigerant pump C and through open valve V4 to contact line 3 in heat exchanger A.
  • valve V4 is closed and valve V5 is open the mixed refrigerant will re-enter knock out drum B through line 7.
  • the overhead from knockout drum B will travel through line 3 to heat exchanger A and enter valve V2 to column unit D where it will exit unit D through overhead line 4 as well as through the bottom of unit D through line 5A.
  • FIG. 2a an integrated mixed refrigerant liquefied natural gas liquefier system is shown per the operation of the invention.
  • Nitrogen containing biogas or other source of natural gas such as landfill gas feed is fed through line 23 to nitrogen rejection unit R which is typically a vacuum swing adsorption (VSA) system.
  • Waste gas is fed through line 25 to blower S and released into the atmosphere.
  • Depressurization gas is released through line 25A into line 22 where it will travel through recycle compressor Q and reenter the nitrogen containing landfill or biogas feed line 23.
  • VSA vacuum swing adsorption
  • the nitrogen recovery unit product/liquefier feed natural gas is fed through line 24 into heat exchanger I where it will pass through valve V12 and enter flash tank J.
  • the now liquefied natural gas will exit through vaive V1 1 and line 25 to line 26 where it will enter storage tank K and can be accessed through line 21 and valve V10 for later use.
  • Vent gas from the storage tank K will exit through line 20 where it will join line 22 and be fed back through the recycle compressor Q to the nitrogen containing biogas feed line 23.
  • Heat exchanger T is fed cold water through line 35A to provide a cooling medium which will also feed to the cold water return line 35 through valve V16.
  • Line 24A directs warm water leaving heat exchanger T.
  • the cold refrigerant is fed through line 36 to knock out drum P which feeds the cold refrigerant to the heat exchanger I through line 28 and which passes through valve V13 to the column unit L where refrigerant from the top exits through line 31 and through the bottom through 31 A which joins line 31 and passes through heat exchanger I and line 31 will be fed to inlet separator M where refrigerant exits through line 33 and is fed to mixed refrigerant column unit U which feeds mixed refrigerant, now warmer to the heat exchanger T through line 24.
  • the bottoms from the inlet separator M is fed through line 32 and transfer pump N back to knock out drum P.
  • the bottoms from the knockout drum P are fed through line 30 and refrigerant pump O to valve V15 for reentry back into the knockout drum P.
  • BZ designates the cold box boundary.
  • the refrigerant from the knockout drum P may also enter line 29 and open valve V14 where it will feed into line 31 and entry into the inlet separator M.
  • Figure 2b is a similar version of the integrated mixed refrigerant liquefied natural gas liquefier system of Figure 2A with the numbering being the same as Figure 2A.
  • This embodiment has compressor Q on line 23 rather than line 22 and no return line 25A from the nitrogen rejection unit R to line 22.
  • line 30A connects with valve V15A to heat exchanger I such that refrigerant from knock out drum P is directed to the heat exchanger I.
  • Figure 2c is another embodiment of the invention showing an integrated mixed refrigerant liquefied natural gas liquefier.
  • Natural gas such as that from landfill gas or biogas from a nitrogen recovery unit, not shown, is fed through line 40 into heat exchanger V.
  • the natural gas is liquefied and its pressure is higher as it exits through line 40A through temperature control valve V17.
  • the liquefied natural gas enters end flash unit W where the flashed liquefied natural gas is fed through line 41 and open pressure control valve V18 and recycled back to heat exchanger V where it will exit and be fed through line 42 to a nitrogen recovery unit, not shown.
  • the bottoms from the flash unit W exit through line 43 and open valve V19 where it will enter horizontal cryogenic storage tank Y. Additional static head is maintained between the liquid level in the end flash unit W and the horizontal cryogenic storage tank Y such that it is equivalent to subcooling at storage level and pressure.
  • Line BZ represents the cold box boundary.
  • Figure 3 shows the effect of methane product purity on methane recovery. Methane recovery decreases as the nitrogen recovery unit product methane content in mole % increases.
  • Figure 4 shows a preferred liquefier embodiment. Natural gas such as that found in landfill gas or biogas is fed through line 64 to heat exchanger AA where it will exit as liquefied natural gas through open valve V20 and be fed to flash tank AB. The liquefied natural gas from the bottoms of the flash tank AB will exit through line 66 and open valve V22 where it will be fed to storage, not shown. The gaseous natural gas tops of the flash tank will exit through line 65 and re-enter heat exchanger AA where it will be fed to a mixed gas nitrogen recovery unit, not shown.
  • Natural gas such as that found in landfill gas or biogas is fed through line 64 to heat exchanger AA where it will exit as liquefied natural gas through open valve V20 and be fed to flash tank AB.
  • the liquefied natural gas from the bottoms of the flash tank AB will exit through line 66 and open valve V22 where it will be fed to storage, not shown.
  • the gaseous natural gas tops of the flash tank will exit through line 65
  • Cold water is fed through line 60 into heat exchanger Al to provide a cooling medium and also fed through line 61 and open valve V25 to the cold water return line 62.
  • Refrigerant will exit through line 64 and be fed through to a knockout drum AD where refrigerant is fed through line 51 and refrigerant pump AE through open valve V24 to line 52 passing through heat exchanger AA.
  • valve V24 When valve V24 is closed and valve V24A is open, the refrigerant is fed through line 55 back to knockout drum AD. Refrigerant is also fed through line 56 from the top of the knockout drum AD to line 52 passing through heat exchanger AA. Line 52 will deliver the refrigerant through open valve V21 to a column unit AC where the bottoms from said unit are fed through line 53 to rejoin with the tops which exit unit AG through line 54. Line 54 passes through heat exchanger AA where it will be fed to inlet separator AF. [0037] The refrigerant in line 54 is occasionally supplemented from the knockout drum AD through open valve V23 and line 57 which connects with the tops from the knockout drum AD through line 56.
  • Line 54 will enter the inlet separator AF where its bottoms are transferred through line 58A and transfer pump AG to line 50 which returns to the knockout drum AD.
  • the tops from the inlet separator AF exit through line 58 and enter mixed refrigerant column unit AH where mixed refrigerant will enter the heat exchanger Al for cooling and reentry into the knockout drum AD for entry into heat exchanger AA.
  • Figure 5a shows a lower cost embodiment liquefier. Natural gas such as that found in landfill gas or biogas is fed through line 79 and open valve V30 where it will enter flash tank BA. Liquefied natural gas exits through line 77 and open valve V33 to storage, not shown. Natural gas will exit the flash tank BA through line 78 where it will pass through economizer BC and exit to a nitrogen recovery unit, not shown. Valve V32 can be opened and excess nitrogen can be recovered through line 78A, unit TIC back into flash tank BA.
  • Natural gas such as that found in landfill gas or biogas is fed through line 79 and open valve V30 where it will enter flash tank BA. Liquefied natural gas exits through line 77 and open valve V33 to storage, not shown. Natural gas will exit the flash tank BA through line 78 where it will pass through economizer BC and exit to a nitrogen recovery unit, not shown. Valve V32 can be opened and excess nitrogen can be recovered through line 78A, unit TIC back into flash tank BA.
  • Cold water is fed through line 83 to heat exchanger BJ and through line 85 and open valve V39 to cold water return line 84.
  • Refrigerant will exit through line 85A and be fed to knockout drum BH where it will exit through the bottom of the knockout drum through open valve V36 and refrigerant pump Bl to be fed to line 74 passing through heat exchanger BD.
  • Valve V36 can be closed and valve V38 open such that refrigerant will pass through line 75 back to knockout drum BH.
  • the tops from the knockout drum BH will be fed through line 70 to line 74 passing through heat exchanger BD.
  • the refrigerant will pass through open valve V35 and be fed to column unit BE where the bottoms from the unit exit through line 71 and join with the tops from the unit BE line 72 which passes refrigerant through heat exchanger BD.
  • This refrigerant will enter inlet separator BG through line 72 where the bottoms from the inlet separator BG are fed through line 80 and transfer pump BF back to the knockout drum BH.
  • Figure 5b is virtually identical to Figure 5a designating a lower cost liquefier embodiment.
  • the numbering is the same and there is no return embodiment on top of the flash tank BA, thus line 78A, valve V32 and TIC control mechanism are not present.
  • the cold box boundary BZ is also broader and covers the flash tank BA which is not seen in Figure 5a.
  • Typical nitrogen rejection performance is shown in Figure 3 for a vacuum swing adsorption (VSA) nitrogen rejection unit.
  • the invention is shown in Figure 2a.
  • the nitrogen rejection amount was varied while ensuring that the final LNG product contained 98% + methane.
  • Three cases were considered for illustrative purposes where the NRU prod uct liquefier feed gas contained 90.6, 98.2 and 98% methane (C1 ).
  • the relative equipment size, which determines capital cost and the power were calculated and compared. The results are as indicated in Tables 2 and 3 below.

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Abstract

A method for recovering liquefied natural gas from a gas mixture containing natural gas and impurities by subjecting the natural gas to a series of steps beginning with feeding a natural gas stream containing impurities to a nitrogen rejection unit; feeding the purified natural gas stream to a liquefier heat exchanger; expanding the liquefied natural gas and feeding the expanded liquefied natural gas to a flash vessel; flashing the liquid natural gas and separating the liquefied natural gas from the flash gas; and feeding the liquefied natural gas to storage and the flash gas to the nitrogen rejection unit.

Description

NITROGEN REJECTION AND LIQUIFIER SYSTEM FOR LIQUIFIED NATURAL
GAS PRODUCTION
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority from US provisional patent application serial number 61/317,466, filed March 25, 2010.
BACKGROUND OF THE INVENTION
[0002] The invention relates to the integration of a liquefied natural gas (LNG) liquefier system with a nitrogen rejection unit (NRU) so as to minimize the capital and operating costs while maintaining liquefied natural gas product purity requirements.
[0003] Renewable methane can be recovered from a number of sources, such as anaerobic digestion of municipal or industrial waste streams, the degradation of biomass in landfills, the gasification of waste and biomass streams, amongst others. In many instances, this renewable methane require purification before it can be used and/or sold into higher valued markets, such as injection into the pipeline grid, as a feedstock for liquefied natural gas, as a vehicle fuel, or as a feedstock for the production of hydrogen. Further, the energy that is required to purify the renewable methane is significant.
[0004] The cleanup of biogas/landfill gas is both capital and power intensive because it contains a large number of trace and bulk contaminants in fairly large concentrations. Various methods are employed to remove these including chilling, cryogenic methods and various adsorption and scrubbing processes. However, these processes can be expensive in both capital and operating costs and it is important to minimize these costs to achieve an economically viable process. [0005] A typical process for the purification of the methane from biogas/landfill gas requires several steps. Sulfur removal is generally followed by drying. The dried gas stream is then treated for contaminants such a volatile organic compounds by process such as adsorption, CO2 washing or by cryogenic methods. The stream is then treated for bulk carbon dioxide removal by a membrane or adsorption process and then is treated for removal of nitrogen. All these purification steps are necessary before the biogas/landfill gas can be liquefied and stored in anticipation of being dispensed, or directed towards other uses, such as pipeline injection, energy production with fuel cells or smail-scale hydrogen production. LNG production is particularly challenging since all condensable contaminants including carbon dioxide must be removed to low ppm levels.
[0006] The invention will allow for maximizing the methane recovery while maintaining high liquefied natural gas product purity. The operator can utilize a smaller nitrogen rejection unit and can optimize power consumption. The process of using the nitrogen rejection unit integrated with the liquefied natural gas liquefier system achieves greater product purity (>96 mol % methane) and greater than 89% methane recovery than conventional non-integrated
combinations.
[0007] By integration of the liquefied natural gas liquefier system with a nitrogen rejection unit, the overall system becomes more compact and efficient. This further enables the operator to maximize methane recovery while
maintaining high liquefied natural gas product purity while enable a smaller nitrogen rejection unit. The invention further allows the operator to optimize power consumption while allowing for significantly higher product purity and methane recovery than conventional or unitegrated NRU and liquefier
combinations which are limited to 96 mol% methane and 80% methane recovery.
SUMMARY OF THE INVENTION [0008] The invention is a method for recovering liquefied natural gas comprising the steps:
Feeding a natural gas stream containing impurities to a nitrogen rejection unit;
Feeding the purified natural gas stream to a !iquefier heat exchanger;
Expanding the liquefied natural gas and feeding the expanded liquefied natural gas to a flash vessel;
Flashing the liquid natural gas and separating the liquefied natural gas from the flash gas;
Feeding the liquefied natural gas to storage and the flash gas to said nitrogen rejection unit.
[0009] Alternatively, the invention is a method for recovering liquefied natural gas comprising the steps:
Feeding a natural gas stream containing impurities to a nitrogen rejection unit;
Feeding the purified natural gas stream to a liquefier heat exchanger;
Expanding the liquefied natural gas and feeding the expanded liquefied natural gas to a flash vessel;
Flashing the liquid natural gas and separating the liquefied natural gas from the flash gas;
Recovering refrigeration from said flash gas; and Feeding the liquefied natural gas to storage and the flash gas to said nitrogen rejection unit.
[0010] The invention further comprises an apparatus comprising a nitrogen rejection unit, a liquefier heat exchanger and a flash vessel.
[0011] The raw feed gas is first compressed and pre-conditioned which entails the removal of water, carbon dioxide, non-methane organic compounds (NMOCs) and sulfur compounds by known methods. The partially purified gas is fed to the nitrogen rejection unit where much of the nitrogen is rejected. Since product purity and methane recovery are inversely related, nitrogen rejection is limited to maximize the methane recovery for the smallest equipment cost. The resulting gas which contains significantly lower amounts of inerts is fed to the liquefier heat exchanger where it is liquefied at pressure to a subcooled state. Typical pressures range from 30 bar to 6 bar with a tradeoff between mixed refrigeration compressor power and compression power for the purification system. This liquid is expanded through a valve whereby further cooling is effected to about 2 bar (range is 1 to 5 bar).
[0012] The two-phase mixture is separated in a flash vessel and the resulting liquid is directed to the storage tanks, while the flash gas which is richer in nitrogen is recycled back to the nitrogen rejection unit. The flash gas can also be combined with the raw natural gas/biogas at the front end of the overall process if the nitrogen rejection unit does not have a recycle compressor. Clearly additional flash gas from the storage tank will be produced. This too is recycled back to the nitrogen rejection unit or to the front end of the cleanup process. The only methane that will be lost is the nitrogen rejection unit waste stream which is nitrogen-rich but otherwise very pure and can be flared or converted into power using a gas engine or a fuel cell.
[0013] The end flash from the flash vessel has an additional advantage in that the liquid outlet of a flash is at equilibrium which implies that it will produce some more gas inside the line between the end flash and storage tank because of product line pressure drop. Therefore, it is best practice that the flash pressure be lower than the storage pressure. To maximize liquefied natural gas
production and minimize product flash losses, the first flash within the flash vessel is effected at a pressure lower than the storage tank pressure, whence, the liquid coming down from the end-flash tank will be sub-cooled at storage pressure. A cryogenic pump can be utilized to overcome this concern, but involves additional cost, maintenance and potential reliability issues. Therefore it is advisable to have horizontal storage tanks, and a cold box layout so that the liquid level inside the end flash will be higher by a few hundreds of mbar of equivalent liquefied natural gas head that the top of the storage and to use that additional head to pressurize Figure 2c.
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] Figure 1 is a typical mixed refrigerant liquefied natural gas liquefier.
[0015] Figure 2a is an integrated mixed refrigerant liquefied natural gas liquefier.
[0016] Figure 2b depicts a different embodiment of an integrated mixed refrigerant liquefied natural gas liquefier.
[0017] Figure 2c depicts another embodiment of an integrated mixed refrigerant liquefied natural gas liquefier.
[0018] Figure 3 shows methane recovery versus nitrogen rejection unit product methane content.
[0019] Figure 4 shows a liquefier embodied in the invention.
[0020] Figure 5a shows a liquefier having a lower cost to operate. [0021J Figure 5b shows a different embodiment of a lower cost to operate liquefier.
DETAILED DESCRIPTION OF THE INVENTION
[0022] Landfill gas is purified and ail the water, sulfur compounds, NMOCs and carbon dioxide are removed in a pre-purification process. The purified gas contains methane, nitrogen and oxygen and has the following composition:
[0023] Table 1 : NRU Feed Gas Composition
Species Mole Fraction
Carbon Dioxide 0.0100
Nitrogen 0.2160
Methane 0.7720
Oxygen 0.0020
[0024] The gas is further purified in an adsorption system so that the carbon dioxide level is reduced below 50 ppmv and a large portion of the nitrogen is removed. Oxygen usually does not adsorb appreciably and about 50% of the oxygen is removed in each case. Figure 1 illustrates a typical MR liquefier stream without process integration. In this case both storage tank losses and nitrogen rejection unit waste streams are not recovered.
[0025] Turning to the figures, Figure 1 , represents a base case mixed refrigerant liquefied natural gas liquefier. Purified natural gas is fed through line 1 through main heat exchanger A where it will be warmed and fed through valve V1 and line 2 as liquefied natural gas to a storage container, not shown.
[0026] A cold water stream (CWS) is fed through line 1 1 to heat exchanger E as well as through valve V6 and line 13 to line 12 as cold water return (CWR). The cold mixed refrigerant is fed through line 9 to knockout drum B where it will proceed through line 7A to refrigerant pump C and through open valve V4 to contact line 3 in heat exchanger A. When valve V4 is closed and valve V5 is open the mixed refrigerant will re-enter knock out drum B through line 7. The overhead from knockout drum B will travel through line 3 to heat exchanger A and enter valve V2 to column unit D where it will exit unit D through overhead line 4 as well as through the bottom of unit D through line 5A. This will exit heat exchanger A through line 5 and connect to inlet separator G where the bottoms will travel through line 8 and transfer pump H to line 6 which will enter the knockout drum B. The refrigerant will leave the inlet separator G through line 8A and connect to mixed refrigerant column unit F where the mixed refrigerant will travel through line 10 back to heat exchanger E.
[0027] In Figure 2a, an integrated mixed refrigerant liquefied natural gas liquefier system is shown per the operation of the invention. Nitrogen containing biogas or other source of natural gas such as landfill gas feed is fed through line 23 to nitrogen rejection unit R which is typically a vacuum swing adsorption (VSA) system. Waste gas is fed through line 25 to blower S and released into the atmosphere. Depressurization gas is released through line 25A into line 22 where it will travel through recycle compressor Q and reenter the nitrogen containing landfill or biogas feed line 23.
[0028] The nitrogen recovery unit product/liquefier feed natural gas is fed through line 24 into heat exchanger I where it will pass through valve V12 and enter flash tank J. The now liquefied natural gas will exit through vaive V1 1 and line 25 to line 26 where it will enter storage tank K and can be accessed through line 21 and valve V10 for later use. Vent gas from the storage tank K will exit through line 20 where it will join line 22 and be fed back through the recycle compressor Q to the nitrogen containing biogas feed line 23.
[0029] Heat exchanger T is fed cold water through line 35A to provide a cooling medium which will also feed to the cold water return line 35 through valve V16. Line 24A directs warm water leaving heat exchanger T. The cold refrigerant is fed through line 36 to knock out drum P which feeds the cold refrigerant to the heat exchanger I through line 28 and which passes through valve V13 to the column unit L where refrigerant from the top exits through line 31 and through the bottom through 31 A which joins line 31 and passes through heat exchanger I and line 31 will be fed to inlet separator M where refrigerant exits through line 33 and is fed to mixed refrigerant column unit U which feeds mixed refrigerant, now warmer to the heat exchanger T through line 24. The bottoms from the inlet separator M is fed through line 32 and transfer pump N back to knock out drum P. The bottoms from the knockout drum P are fed through line 30 and refrigerant pump O to valve V15 for reentry back into the knockout drum P. BZ designates the cold box boundary.
[0030] The refrigerant from the knockout drum P may also enter line 29 and open valve V14 where it will feed into line 31 and entry into the inlet separator M.
[0031] Figure 2b is a similar version of the integrated mixed refrigerant liquefied natural gas liquefier system of Figure 2A with the numbering being the same as Figure 2A. This embodiment has compressor Q on line 23 rather than line 22 and no return line 25A from the nitrogen rejection unit R to line 22. Also, line 30A connects with valve V15A to heat exchanger I such that refrigerant from knock out drum P is directed to the heat exchanger I.
[0032] Figure 2c is another embodiment of the invention showing an integrated mixed refrigerant liquefied natural gas liquefier. Natural gas such as that from landfill gas or biogas from a nitrogen recovery unit, not shown, is fed through line 40 into heat exchanger V. The natural gas is liquefied and its pressure is higher as it exits through line 40A through temperature control valve V17. The liquefied natural gas enters end flash unit W where the flashed liquefied natural gas is fed through line 41 and open pressure control valve V18 and recycled back to heat exchanger V where it will exit and be fed through line 42 to a nitrogen recovery unit, not shown. [0033] The bottoms from the flash unit W exit through line 43 and open valve V19 where it will enter horizontal cryogenic storage tank Y. Additional static head is maintained between the liquid level in the end flash unit W and the horizontal cryogenic storage tank Y such that it is equivalent to subcooling at storage level and pressure. Line BZ represents the cold box boundary.
[0034] Figure 3 shows the effect of methane product purity on methane recovery. Methane recovery decreases as the nitrogen recovery unit product methane content in mole % increases.
[0035] Figure 4 shows a preferred liquefier embodiment. Natural gas such as that found in landfill gas or biogas is fed through line 64 to heat exchanger AA where it will exit as liquefied natural gas through open valve V20 and be fed to flash tank AB. The liquefied natural gas from the bottoms of the flash tank AB will exit through line 66 and open valve V22 where it will be fed to storage, not shown. The gaseous natural gas tops of the flash tank will exit through line 65 and re-enter heat exchanger AA where it will be fed to a mixed gas nitrogen recovery unit, not shown.
[0036] Cold water is fed through line 60 into heat exchanger Al to provide a cooling medium and also fed through line 61 and open valve V25 to the cold water return line 62. Refrigerant will exit through line 64 and be fed through to a knockout drum AD where refrigerant is fed through line 51 and refrigerant pump AE through open valve V24 to line 52 passing through heat exchanger AA.
When valve V24 is closed and valve V24A is open, the refrigerant is fed through line 55 back to knockout drum AD. Refrigerant is also fed through line 56 from the top of the knockout drum AD to line 52 passing through heat exchanger AA. Line 52 will deliver the refrigerant through open valve V21 to a column unit AC where the bottoms from said unit are fed through line 53 to rejoin with the tops which exit unit AG through line 54. Line 54 passes through heat exchanger AA where it will be fed to inlet separator AF. [0037] The refrigerant in line 54 is occasionally supplemented from the knockout drum AD through open valve V23 and line 57 which connects with the tops from the knockout drum AD through line 56. Line 54 will enter the inlet separator AF where its bottoms are transferred through line 58A and transfer pump AG to line 50 which returns to the knockout drum AD. The tops from the inlet separator AF exit through line 58 and enter mixed refrigerant column unit AH where mixed refrigerant will enter the heat exchanger Al for cooling and reentry into the knockout drum AD for entry into heat exchanger AA.
[0038] Figure 5a shows a lower cost embodiment liquefier. Natural gas such as that found in landfill gas or biogas is fed through line 79 and open valve V30 where it will enter flash tank BA. Liquefied natural gas exits through line 77 and open valve V33 to storage, not shown. Natural gas will exit the flash tank BA through line 78 where it will pass through economizer BC and exit to a nitrogen recovery unit, not shown. Valve V32 can be opened and excess nitrogen can be recovered through line 78A, unit TIC back into flash tank BA.
[0039] Part of the natural gas feed from line 78 is fed through open valve V31 to line 76 which passes through heat exchanger BD and open valve V34 back to the flash tank BA as liquefied natural gas.
[0040] Cold water is fed through line 83 to heat exchanger BJ and through line 85 and open valve V39 to cold water return line 84. Refrigerant will exit through line 85A and be fed to knockout drum BH where it will exit through the bottom of the knockout drum through open valve V36 and refrigerant pump Bl to be fed to line 74 passing through heat exchanger BD. Valve V36 can be closed and valve V38 open such that refrigerant will pass through line 75 back to knockout drum BH.
[0041] The tops from the knockout drum BH will be fed through line 70 to line 74 passing through heat exchanger BD. The refrigerant will pass through open valve V35 and be fed to column unit BE where the bottoms from the unit exit through line 71 and join with the tops from the unit BE line 72 which passes refrigerant through heat exchanger BD. This refrigerant will enter inlet separator BG through line 72 where the bottoms from the inlet separator BG are fed through line 80 and transfer pump BF back to the knockout drum BH.
[0042] The tops from the inlet separator will exit through line 81 to mixed refrigerant unit BK. The mixed refrigerant from unit BK is fed back to heat exchanger BJ as a warm fluid through line 82 where it will be cooled down and ultimately fed back into heat exchanger BD after passing through knockout drum BH. Line BZ designates the cold box boundary.
[0043] Figure 5b is virtually identical to Figure 5a designating a lower cost liquefier embodiment. In this embodiment, the numbering is the same and there is no return embodiment on top of the flash tank BA, thus line 78A, valve V32 and TIC control mechanism are not present. In Figure 5b, the cold box boundary BZ is also broader and covers the flash tank BA which is not seen in Figure 5a.
[0044] Typical nitrogen rejection performance is shown in Figure 3 for a vacuum swing adsorption (VSA) nitrogen rejection unit. The invention is shown in Figure 2a. The nitrogen rejection amount was varied while ensuring that the final LNG product contained 98% + methane. Three cases were considered for illustrative purposes where the NRU prod uct liquefier feed gas contained 90.6, 98.2 and 98% methane (C1 ). The relative equipment size, which determines capital cost and the power were calculated and compared. The results are as indicated in Tables 2 and 3 below. In Table 2, both the pre-cleanup system, which is used to remove all contaminants other than nitrogen and oxygen, and the four bed VSA system are compared in terms of size which is directly proportional to the kg-moles/hr of NRU feed to be processed or the nitrogen to be rejected. Case 3 clearly shows significant benefits when a less pure NRU product is fed to the liquefier with a pre-cleanup system that is 17% smaller and a NRU that is 23% smaller than the first case. [0045] Table 2: Effect of Liquefier Feed Composition on Overall Methane Recovery and Equipment Size
C1 in Liquefier Pre-Cleanup NRU Wobbe index
Feed (mo I %) Relative Size Relative Size (MJ/m3)
Case l 98.0 1 .17 1 .23 50.37
Case 2 96.2 1 .06 1.10 50.11
Case 3 90.6 1 .00 1.00 49.35
[0046] In addition, the relative power for ail 3 cases is compared in Table 3 which shows that the extra power needed for liquefaction and recycle with higher inerts (case 1 ) is compensated by the vacuum pump power needed for higher NRU purity (case 3). Hence, there is no appreciable net power penalty.
[0047] Table 3: Effect of Liquefier Feed Composition on Net Power
C1 in Liquefier Feed Relative Power
(mol %) (%)
Case l 98.0 100.5
Case 2 96.2 99.6
Case 3 90.6 100.0
[0048] Other embodiments of the invention are illustrated in Figures 5a and 5b, both of which are lower capital cost options and do not require a separate pass in the main heat exchanger, or a larger cold box. Nevertheless, both embodiments do not allow for full cold recovery and are less efficient.
Additionally, if all the purified natural gas from the NRU is fed to the
economizer, a very large temperature gradient will result at the cold end of this exchanger. Therefore, it is desired that only a portion of the NRU product is fed to the economizer so that it can be liquefied, or cooled close to the liquefaction temperature. The portion of the NRU product gas cooled in the economizer can be sent to flash tank labeled BA in Figures 5a and 5b as sub- cooled liquid or to the main heat exchanger.
[0049] While this invention has been described with respect to particular embodiments thereof, it is apparent that numerous other forms and
modifications of the invention will be obvious to those skilled in the art. The appended claims in this invention generally should be construed to cover all such obvious forms and modifications which are within the true spirit and scope of the invention.

Claims

Having thus described the invention, what we claim is:
1. A method for recovering liquefied natural gas comprising the steps: feeding a natural gas stream containing impurities to a nitrogen rejection unit; feeding the purified natural gas stream to a liquefier heat exchanger; expanding the liquefied natural gas and feeding the expanded liquefied natural gas to a flash vessel; flashing the liquid natural gas and separating the liquefied natural gas from the flash gas; and feeding the liquefied natural gas to storage and the flash gas to said nitrogen rejection unit.
2. The method as claimed in claim 1 wherein said impurities are selected from the group consisting of water, carbon dioxide, non-methane organic compounds and sulfur compounds.
3. The method as claimed in claim 1 wherein nitrogen is recovered from said nitrogen rejection unit.
4. The method as claimed in claim 1 wherein the pressure in said liquefier heat exchanger range from 6 to 30 bar.
5. The method as claimed in claim 1 wherein said liquefied natural gas is expanded to a pressure of 1 to 5 bar.
6. The method as claimed in claim 1 wherein said flash gas is richer in nitrogen than natural gas.
7. The method as claimed in claim 1 wherein said natural gas stream is selected from the group consisting of landfill gas and biogas.
8. The method as claimed in claim 1 wherein said flash gas is recycled to said natural gas feed.
9. The method as claimed in claim 1 wherein flash pressure is lower than storage pressure.
10. The method as claimed in claim 1 wherein said nitrogen rejection unit is a vacuum swing adsorption unit.
11. The method as claimed in claim 1 wherein said recovered natural gas is fed to a storage unit.
12. The method as claimed in claim 1 wherein said storage unit is situated horizontally.
13. A method for recovering liquefied natural gas comprising the steps: feeding a natural gas stream containing impurities to a nitrogen rejection unit; feeding the purified natural gas stream to a Itquefier heat exchanger; expanding the liquefied natural gas and feeding the expanded liquefied natural gas to a flash vessel; flashing the liquid natural gas and separating the liquefied natural gas from the flash gas; recovering refrigeration from said flash gas; and feeding the liquefied natural gas to storage and the flash gas to said nitrogen rejection unit.
14. The method as claimed in claim 13 wherein said impurities are selected from the group consisting of water, carbon dioxide, non-methane organic compounds and sulfur compounds.
15. The method as claimed in claim 13 wherein nitrogen is recovered from said nitrogen rejection unit.
16. The method as claimed in claim 13 wherein the pressure in said liquefier heat exchanger range from 6 to 30 bar.
17. The method as claimed in claim 13 wherein said liquefied natural gas is expanded to a pressure of 1 to 5 bar.
18. The method as claimed in claim 13 wherein said flash gas is richer in nitrogen than natural gas.
19. The method as claimed in claim 13 wherein said natural gas stream is selected from the group consisting of landfill gas and biogas.
20. The method as claimed in claim 13 wherein said flash gas is recycled to said natural gas feed.
21. The method as claimed in claim 13 wherein flash pressure is lower than storage pressure.
22. The method as claimed in claim 13 wherein said nitrogen rejection unit is a vacuum swing adsorption unit.
23. The method as claimed in claim 13 wherein said recovered natural gas is fed to a storage unit.
24. The method as claimed in claim 13 wherein said storage unit is situated horizontally.
25. The method as claimed in claim 13 wherein said recovered
refrigeration provides cooling to a heat exchanger.
26. The method as claimed in claim 13 wherein said heat exchanger is in thermal contact with the liquefier feed.
27. An apparatus comprising a nitrogen rejection unit, a liquefier heat exchanger and a flash vessel.
28. The apparatus as claimed in claim 27 wherein said nitrogen rejection unit is a vacuum swing adsorption unit.
29. The apparatus as claimed in claim 27 wherein said liquefier heat exchanger is in thermal communication with said flash vessel.
30. The apparatus as claimed in claim 27 wherein said nitrogen rejection unit is in thermal communication with said liquefier heat exchanger.
31. The apparatus as acclaimed in claim 27 wherein said flash vessel is in fluid communication with a storage tank.
32. The apparatus as claimed in claim 27 further comprising a second heat exchanger.
PCT/US2011/029575 2010-03-25 2011-03-23 Nitrogen rejection and liquifier system for liquified natural gas production WO2011119697A1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016026533A1 (en) * 2014-08-21 2016-02-25 Statoil Petroleum As Heat pump system
FR3101406A1 (en) * 2019-09-27 2021-04-02 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Installation of a hydrocarbon fluid liquefaction system and its system

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013177700A1 (en) 2012-05-28 2013-12-05 Hydrogenics Corporation Electrolyser and energy system
US20140020408A1 (en) * 2012-07-23 2014-01-23 Global Cooling, Inc. Vehicle and storage lng systems
RU2015135574A (en) * 2013-01-24 2017-03-03 Эксонмобил Апстрим Рисерч Компани PRODUCTION OF LIQUEFIED NATURAL GAS
CA2855383C (en) 2014-06-27 2015-06-23 Rtj Technologies Inc. Method and arrangement for producing liquefied methane gas (lmg) from various gas sources
CA2903679C (en) 2015-09-11 2016-08-16 Charles Tremblay Method and system to control the methane mass flow rate for the production of liquefied methane gas (lmg)
CN106051459B (en) * 2016-07-14 2018-08-21 青岛华控能源科技有限公司 Tire nitrogen vulcanizes two-step supercharging and recycles energy conserving system
FR3099557B1 (en) * 2019-08-01 2021-07-30 Air Liquide Natural gas liquefaction process with improved circulation of a mixed refrigerant stream

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6758060B2 (en) * 2002-02-15 2004-07-06 Chart Inc. Separating nitrogen from methane in the production of LNG
US6978638B2 (en) * 2003-05-22 2005-12-27 Air Products And Chemicals, Inc. Nitrogen rejection from condensed natural gas
US7250074B2 (en) * 2003-08-29 2007-07-31 Velocys, Inc. Process for separating nitrogen from methane using microchannel process technology
US7311763B2 (en) * 2005-04-22 2007-12-25 David Lloyd Neary Gas separation vessel apparatus
US20100011663A1 (en) * 2008-07-18 2010-01-21 Kellogg Brown & Root Llc Method for Liquefaction of Natural Gas

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RS20060418A (en) * 2004-01-22 2008-09-29 Acetex (Cyprus) Limited, Integrated process for acetic acid and methanol
MXPA06010219A (en) * 2004-03-11 2007-03-07 Advanced Extraction Technol Use of cryogenic temperatures in processing gases containing light components with physical solvents.
WO2007021351A1 (en) * 2005-08-09 2007-02-22 Exxonmobil Upstream Research Company Natural gas liquefaction process for lng
US8173009B2 (en) * 2009-02-06 2012-05-08 Uop Llc Process for improving a hydrotreated stream

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6758060B2 (en) * 2002-02-15 2004-07-06 Chart Inc. Separating nitrogen from methane in the production of LNG
US6978638B2 (en) * 2003-05-22 2005-12-27 Air Products And Chemicals, Inc. Nitrogen rejection from condensed natural gas
US7250074B2 (en) * 2003-08-29 2007-07-31 Velocys, Inc. Process for separating nitrogen from methane using microchannel process technology
US7311763B2 (en) * 2005-04-22 2007-12-25 David Lloyd Neary Gas separation vessel apparatus
US20100011663A1 (en) * 2008-07-18 2010-01-21 Kellogg Brown & Root Llc Method for Liquefaction of Natural Gas

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016026533A1 (en) * 2014-08-21 2016-02-25 Statoil Petroleum As Heat pump system
FR3101406A1 (en) * 2019-09-27 2021-04-02 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Installation of a hydrocarbon fluid liquefaction system and its system
US11592234B2 (en) 2019-09-27 2023-02-28 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Hydrocarbon fluid liquefaction system installation and system therefor

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