WO2007068061A1 - Freeze indicating device - Google Patents
Freeze indicating device Download PDFInfo
- Publication number
- WO2007068061A1 WO2007068061A1 PCT/AU2006/001912 AU2006001912W WO2007068061A1 WO 2007068061 A1 WO2007068061 A1 WO 2007068061A1 AU 2006001912 W AU2006001912 W AU 2006001912W WO 2007068061 A1 WO2007068061 A1 WO 2007068061A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- liquid
- vessel
- indicating device
- indicating
- temperature
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K11/00—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00
- G01K11/06—Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00 using melting, freezing, or softening
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K2207/00—Application of thermometers in household appliances
- G01K2207/02—Application of thermometers in household appliances for measuring food temperature
- G01K2207/06—Application of thermometers in household appliances for measuring food temperature for preparation purposes
Definitions
- the present invention relates to a temperature indicating device.
- the present invention relates to a freeze indicating device for providing a visible record that the environment local to the device has been subject to a freezing temperature.
- US Patent No. 4,132,186 describes a freeze indicating device comprising a constant total volume container having a first chamber, where the first chamber includes a reservoir portion and an elongated portion with a passage communicating at one end with said reservoir portion and at the other end of said device with an indicating material; a second chamber having an expandable wall, said second chamber located within the reservoir of said first chamber; an aqueous first liquid in said second chamber; a second liquid substantially filling said reservoir portion of the first chamber and having a fluid character at the freezing point of said aqueous liquid; a visible indicating material for said second liquid at the vented end of said passage; and the length of said passage and the position of said indicating material being such that upon the freezing and expansion of said aqueous liquid, the second liquid in said reservoir is forced through said passage and into contact with said visible indicating material.
- this device has the disadvantage of incorporating two separate liquids and a number of chambers, one of these chambers including an expandable wall. This makes the device overly complicated to manufacture.
- US Patent No. 4,145,918 describes a device for indicating that an environment has reached or passed through the temperature near a freezing point of a liquid comprising: a frangible sealed ampule, a liquid being enclosed in said ampule, said liquid having the characteristic of expanding in volume at or near its freezing point, said ampule having at least a first and a second face, said first face having an indentation projecting relatively close to but spaced from said second face inside of said ampule, said indentation forming a sharp acute angle inside of said ampule, said indentation performing the dual function of providing a site for encouraging crystal growth when said liquid is at or near its freezing point and further providing a mechanism for strengthening said first face of said ampule relative to said second face whereby said frangible, sealed ampule will consistently break upon the expansion of said liquid, thereby indicating that the environment has reached or passed through a temperature near the freezing point of said liquid.
- the complicated internal structure of the ampule makes this device difficult to fabricate making the unit cost of each device high
- US Patent No. 4,191,125 describes a freeze indicator comprising a frangible container, said container housing a liquid which expands upon freezing, thereby fracturing said container, said liquid having a nucleating agent disbursed therein, said nucleating agent being substantially insoluble in said liquid, liquid responsive indicator means, said nucleating agent and said liquid having substantially similar molecular space groupings whereby undercooling of said liquid is substantially prevented; said container further housing a surfactant which is mixed with said liquid and said nucleating agent before freezing of said liquid for providing increased contact between said nucleating agent and said liquid and further providing a decrease in surface tension between said container, when fractured, and said liquid whereby a substantial immediate indication of freezing is provided on said liquid responsive indicating means.
- the use of a number of different chemical materials such as surfactants and a nucleating agent adds to the complexity of this freeze indicator again making the associated costs of manufacture relatively high.
- the present invention accordingly provides a freeze indicating device for indicating that the device has been subjected to a freezing temperature, the device including: a vessel having an open end, the vessel containing an amount of a liquid that expands at or near the freezing temperature; and sealing means for sealing the open end of the vessel, wherein the sealing means interacts with the liquid upon freezing of the liquid and undergoes displacement with respect to the vessel to indicate that the liquid has frozen.
- displacement of the sealing means exposes an indicating region to indicate that the liquid has frozen.
- the indicating region is located on the sealing means.
- the indicating region is located on an external surface of the vessel.
- the amount of the liquid causes the sealing means to be separated from the vessel upon freezing of the liquid.
- the device further includes liquid indicator means to interact with the liquid on thawing.
- the liquid indicator means includes an absorbent member incorporating a liquid soluble indicator which dissipates into the absorbent member on contact with the liquid on thawing.
- the vessel is open at both ends and includes corresponding sealing means located at each end which undergo displacement on freezing of the liquid.
- the present invention accordingly provides a temperature range indicating device for indicating that the device has been subjected to a temperature outside of a predetermined temperature range, the predetermined temperature ranged defined at a lower end by a freezing temperature and at an upper end by a raised temperature, the device including: a vessel having a first chamber wherein the first chamber includes an amount of a liquid that expands at or near the freezing temperature and sealing means for sealing an open end of the chamber, wherein the sealing means interacts with the liquid upon freezing of the liquid and undergoes displacement with respect to the vessel to indicate that the liquid has frozen; and raised temperature indicating means to provide a visual indication when the vessel has been subjected to the raised temperature.
- the raised temperature indicating means includes a second chamber for the vessel, the second chamber including: a reservoir of indicating material being solid below the raised temperature and liquid at or above the raised temperature; and a wicking member arranged in contact with the reservoir so that the indicating material migrates from the reservoir when in liquid form to the wicking member to provide the visual indication of the raised temperature.
- the sealing means is adapted to melt at the raised temperature, thereby providing the visual indication of the raised temperature.
- FIGURES Ia and Ib are front perspective and sectional views of a freeze indicating device according to a first embodiment of the present invention.
- FIGURES 2a and 2b are front perspective and sectional views of the freeze indicating device illustrated in Figures Ia and Ib after freezing;
- FIGURES 3a and 3b are front perspective and sectional views of a freeze indicating device according to a second embodiment of the present invention;
- FIGURES 4a and 4b are front perspective and sectional views of the freeze indicating device illustrated in Figures 3a and 3b after freezing;
- FIGURES 5a and 5b are front perspective and sectional views of the freeze indicating device illustrated in Figures 4a and 4b after subsequent thawing;
- FIGURES 6a and 6b are front perspective and sectional views of a freeze indicating device according to a third embodiment of the present invention.
- FIGURES 7a and 7b are front perspective and sectional views of the freeze indicating device illustrated in Figures 6a and 6b after freezing;
- FIGURE 8 is a front sectional view of a temperature range indicating device according to a further embodiment of the present invention.
- FIGURE 9 is a front sectional view of the temperature range indicating device illustrated in Figure 8 after freezing; and FIGURE 10 is a front sectional view of the temperature range indicating device illustrated in Figure 8 after being exposed to a predetermined raised temperature.
- Freeze indicating device 100 includes a vessel 110 open at one end and filled to approximately 95% capacity with an aqueous substance 120.
- vessel 110 is a clear tube formed from a suitable rigid plastic or alternatively glass, it would be apparent to those skilled in the art that vessel 110 need not be tubular but may have any other regular or non-regular sectional or tapered shape as required.
- aqueous substance 120 that has been employed in this embodiment is water
- any other liquid substance which expands on freezing is contemplated to be within the scope of the invention.
- compositions or admixtures of liquid substances and other materials such as nucleating agents are also considered to be within the scope of the invention.
- temperature at which the liquid substance freezes may be modified to some extent by changing its composition.
- a stopper or plug 130 Inserted into the open end of vessel 110 is a stopper or plug 130 which functions as a sealing means and is formed of a resilient material such as injection moulded polypropylene or other suitably resilient compound.
- Plug 130 includes a number of circumferential ridges 131 which aid in forming a seal between the inner wall of vessel 110 and plug 130.
- Plug 130 is inserted into vessel 110 a distance less than the amount that the aqueous substance would be expected to traverse on expansion due to freezing.
- the sealing force between plug 130 and vessel 110 is adapted to be less than that of the expansion force of aqueous substance 120 as it freezes. This results in plug 130 being displaced with respect to or relative to vessel 110.
- aqueous substance 120 freezes it gradually forces plug 130 from vessel 110, eventually causing it to be displaced completely resulting in plug 130 being separated from vessel 110, thereby providing a clear visual indication that freeze indicating device 100 has been subjected to a temperature sufficient to cause such freezing to occur.
- vessel 110 is transparent, clearly vessel 110 may be opaque and plug 130 be of a suitable contrasting colour to vessel 110 to provide an indicating region as required.
- vessel 110 may be open at both ends with corresponding plugs 130 which each undergo displacement with respect to vessel 110 as aqueous substance 120 freezes.
- aqueous substance 120 will simply melt and leave vessel 110. Where an object is spoiled due to this freezing, the presence of the aqueous substance 120 in liquid form is not an issue. However, if there is a requirement to prevent any liquid from freeze indicating device 100 from further interacting with the object whose temperature is being monitored, then indicating device may be enclosed in a further blister package or other suitable packaging sufficient to allow plug 130 to be displaced from vessel 110 as aqueous substance 120 freezes. If the plug 130 is not fully ejected from vessel 110 and if the aqueous substance 120 further re-thaws, then plug 130 may be drawn back or retract partially into vessel 110 due to the vacuum force provided by the sealed vessel.
- plug 130 and/ or end of the vessel are modified so as to break the seal as plug 130 is initially displaced by the freezing of aqueous substance 120. This may be achieved in one embodiment by tapering plug 130.
- a freeze indicating device 200 according to a second embodiment of the present invention.
- a freeze indicating device 100 of the first embodiment is attached to a portion of indicator paper 210 which functions as a liquid indicator means and incorporates a layer of water soluble ink or other water soluble indicator.
- plug 130 will be separated from vessel 110 in the process providing a clear indication that the local environment to the indicating device has reached a sufficiently low temperature.
- aqueous substance 120 begins to thaw, it will gradually be absorbed by indicator paper 210 or more generally absorbent member, in the process causing water soluble ink 220 to dissipate in indicator paper 210 (as best seen in Figures 5a and 5b), thereby providing further indication that temperature indicating device 200 has frozen and subsequently thawed.
- freeze indicating device 200 may be suitably packaged to isolate it from the immediate environment as required.
- Indicating device 300 includes a vessel 310 open at one end containing an aqueous substance 320 and a cover or cap member 330 which sealingly engages with the open end of vessel 310 to prevent the escape of aqueous substance 320.
- Cap member 330 may include internal ridges or other sealing means to improve the seal.
- cap member 330 and the exposed surface 316 of vessel 310 are opaque. The amount of aqueous substance 320 is fixed to cause cap member 330 to be displaced but to not be completely separated from vessel 310 due to the expansion forces resulting from the freezing of aqueous substance 320.
- freeze indicating device 300 after being subjected to suitably cold temperatures to cause freezing of aqueous substance 320.
- cap member 330 is displaced with respect to vessel 310, indicating region 315 which is located on the exposed surface 316 of vessel 310 is exposed, thereby providing a clear visual indication that the aqueous substance 320 has frozen.
- freeze indicating device 300 would also be suitable for those applications where it is important that aqueous substance 320 be fully enclosed and not allowed to escape from vessel 310.
- Temperature range indicating device 400 includes a tubular member 410 open at both ends and incorporating a central partition or wall 460 dividing tubular member into a first chamber 411 and second chamber 412.
- First chamber 411 contains aqueous substance 420 and cap member 430 and is filled to a predetermined level whereby on freezing of aqueous substance 420, cap member 430 is displaced revealing indicator portion 415 (as best shown in Figure 9). Otherwise the outside surface of first chamber 411 is generally opaque.
- Second chamber 412 includes a reservoir 440 of indicating material which in this embodiment is blotting paper impregnated with a coloured organic compound such as a fatty acid or an alcohol or their derivatives.
- a coloured organic compound such as a fatty acid or an alcohol or their derivatives.
- any form of sponge or woven or non-woven fibrous material may also be employed as a reservoir.
- wicking member 450 In contact with reservoir 440 is a wicking member 450 which is a thin sheet of blotting paper. Alternatively, any form of woven or non-woven sheet material having the required wicking properties would be suitable. In another embodiment, reservoir 440 is incorporated into wicking member 450.
- the surface of second chamber 412 is this embodiment is transparent allowing full view of reservoir 440 and wicking member 450 but alternatively the outside surface may be partially opaque and include a viewing aperture with indicator markings to view the wicking member 450. Providing a seal against dust and the like, second chamber 412 also includes a cap member 470.
- indicating device 400 once indicating device 400 becomes exposed to a predetermined raised temperature, the indicator material located in reservoir 440 will migrate from reservoir 440 into wicking member 450 providing a visual indication 445 of the raised temperature environment and functioning as a raised temperature indicating means.
- a barrier member (not shown) may be incorporated into wicking member 450 so that there is only a visual indication once the indicator material has migrated past barrier member, thereby indicating that a predetermined raised temperature history has occurred.
- temperature indicating device 400 provides an indicator that the temperature of a given environment or an object to which the indicating device has been attached has stayed within a certain range defined at a lower end by the temperature at which aqueous substance 420 freezes (as best seen in Figure 9) and at an upper end by the temperature at which indicating material in reservoir 440 migrates into wicking member 450 (as best seen in Figure 10).
- the cap member or plug may be formed of a material that has a melting point corresponding to the upper end of temperature range indicating device, thereby also functioning as a raised temperature indicating means. In this manner, the combination of the aqueous substance escaping the vessel and the destruction of the cap member or plug will indicate that the device has been exposed to raised temperatures. At the lower temperature end, displacement of the cap member or plug will indicate that the aqueous substance has frozen.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Measuring Temperature Or Quantity Of Heat (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2006324303A AU2006324303A1 (en) | 2005-12-16 | 2006-12-15 | Freeze indicating device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2005907080A AU2005907080A0 (en) | 2005-12-16 | Freeze indicating device | |
AU2005907080 | 2005-12-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007068061A1 true WO2007068061A1 (en) | 2007-06-21 |
Family
ID=38162494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AU2006/001912 WO2007068061A1 (en) | 2005-12-16 | 2006-12-15 | Freeze indicating device |
Country Status (2)
Country | Link |
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AU (1) | AU2006324303A1 (en) |
WO (1) | WO2007068061A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7415939B2 (en) * | 2003-04-24 | 2008-08-26 | Tatiana Maciulis Dip | Temperature sensitive indicator |
WO2013034467A1 (en) | 2011-09-06 | 2013-03-14 | Novo Nordisk A/S | A piston rod foot |
WO2014099831A2 (en) * | 2012-12-20 | 2014-06-26 | Eli Lilly And Company | Locking assembly for preventing dispensing of dose from medication dispensing device |
WO2016155975A1 (en) | 2015-03-27 | 2016-10-06 | Novo Nordisk A/S | Deformable piston washer |
US9732851B2 (en) | 2011-09-06 | 2017-08-15 | Novo Nordisk A/S | Piston rod foot |
EP3640568A1 (en) | 2018-10-16 | 2020-04-22 | Vestel Elektronik Sanayi ve Ticaret A.S. | Freezing sensor |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2144620A1 (en) * | 1971-07-02 | 1973-02-16 | Pellet Jean | |
US4132186A (en) * | 1977-10-31 | 1979-01-02 | Minnesota Mining And Manufacturing Company | Freeze indicating device |
US4313452A (en) * | 1980-08-24 | 1982-02-02 | Mellard George K | Self-actuating variable rate water pipe bleeder |
FR2665957A1 (en) * | 1990-08-14 | 1992-02-21 | Loustaunau Albert | Temperature monitor |
US6302054B1 (en) * | 1998-05-08 | 2001-10-16 | Mayer, Iii Robert A. | Freezing weather indicator and method |
WO2005003705A1 (en) * | 2003-04-24 | 2005-01-13 | Tatiana Maciulis Dip | Indicative sensor for stock control |
-
2006
- 2006-12-15 AU AU2006324303A patent/AU2006324303A1/en not_active Abandoned
- 2006-12-15 WO PCT/AU2006/001912 patent/WO2007068061A1/en active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2144620A1 (en) * | 1971-07-02 | 1973-02-16 | Pellet Jean | |
US4132186A (en) * | 1977-10-31 | 1979-01-02 | Minnesota Mining And Manufacturing Company | Freeze indicating device |
US4313452A (en) * | 1980-08-24 | 1982-02-02 | Mellard George K | Self-actuating variable rate water pipe bleeder |
FR2665957A1 (en) * | 1990-08-14 | 1992-02-21 | Loustaunau Albert | Temperature monitor |
US6302054B1 (en) * | 1998-05-08 | 2001-10-16 | Mayer, Iii Robert A. | Freezing weather indicator and method |
WO2005003705A1 (en) * | 2003-04-24 | 2005-01-13 | Tatiana Maciulis Dip | Indicative sensor for stock control |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7415939B2 (en) * | 2003-04-24 | 2008-08-26 | Tatiana Maciulis Dip | Temperature sensitive indicator |
US9101718B2 (en) | 2011-09-06 | 2015-08-11 | Novo Nordisk A/S | Piston rod foot |
WO2013034467A1 (en) | 2011-09-06 | 2013-03-14 | Novo Nordisk A/S | A piston rod foot |
CN103781505A (en) * | 2011-09-06 | 2014-05-07 | 诺沃—诺迪斯克有限公司 | A piston rod foot |
US9732851B2 (en) | 2011-09-06 | 2017-08-15 | Novo Nordisk A/S | Piston rod foot |
WO2014099831A2 (en) * | 2012-12-20 | 2014-06-26 | Eli Lilly And Company | Locking assembly for preventing dispensing of dose from medication dispensing device |
KR20150087332A (en) * | 2012-12-20 | 2015-07-29 | 일라이 릴리 앤드 캄파니 | Locking assembly for preventing dispensing of dose from medication dispensing device |
CN104853790A (en) * | 2012-12-20 | 2015-08-19 | 伊莱利利公司 | Locking assembly for preventing dispensing of dose from medication dispensing device |
KR101662470B1 (en) | 2012-12-20 | 2016-10-04 | 일라이 릴리 앤드 캄파니 | Locking assembly for preventing dispensing of dose from medication dispensing device |
WO2014099831A3 (en) * | 2012-12-20 | 2014-08-28 | Eli Lilly And Company | Locking assembly for preventing dispensing of dose from medication dispensing device |
WO2016155975A1 (en) | 2015-03-27 | 2016-10-06 | Novo Nordisk A/S | Deformable piston washer |
US10786628B2 (en) | 2015-03-27 | 2020-09-29 | Novo Nordisk A/S | Deformable piston washer |
EP3640568A1 (en) | 2018-10-16 | 2020-04-22 | Vestel Elektronik Sanayi ve Ticaret A.S. | Freezing sensor |
Also Published As
Publication number | Publication date |
---|---|
AU2006324303A1 (en) | 2007-06-21 |
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