WO1997047452B1 - Methods for molding hinged starch-bound articles - Google Patents

Methods for molding hinged starch-bound articles

Info

Publication number
WO1997047452B1
WO1997047452B1 PCT/US1997/010168 US9710168W WO9747452B1 WO 1997047452 B1 WO1997047452 B1 WO 1997047452B1 US 9710168 W US9710168 W US 9710168W WO 9747452 B1 WO9747452 B1 WO 9747452B1
Authority
WO
WIPO (PCT)
Prior art keywords
article
skin portion
manufacturing
interior
polyol
Prior art date
Application number
PCT/US1997/010168
Other languages
French (fr)
Other versions
WO1997047452A1 (en
Filing date
Publication date
Priority claimed from US08/661,224 external-priority patent/US5776388A/en
Application filed filed Critical
Priority to BR9709671-7A priority Critical patent/BR9709671A/en
Priority to NZ332294A priority patent/NZ332294A/en
Priority to AT97929948T priority patent/ATE239599T1/en
Priority to AU33890/97A priority patent/AU717469B2/en
Priority to EP97929948A priority patent/EP0920371B1/en
Priority to JP50181898A priority patent/JP3361813B2/en
Priority to DE69721782T priority patent/DE69721782T2/en
Publication of WO1997047452A1 publication Critical patent/WO1997047452A1/en
Publication of WO1997047452B1 publication Critical patent/WO1997047452B1/en

Links

Abstract

Method and systems for forming hinged starch-bound matrices. Starch-based compositions are molded between heated molds in order to form a cellular matrix and also to remove water from the starch-based compositions in order to form a binding matrix of solidified starch. The molding apparatus is configured to form one or more creases (230) within the hinge structure (200) in order to define one or more lines upon which the hinge will bend. The molding apparatus is also configured such that the region of the mold corresponding to the inner surface of the hinge area will transfer heat more slowly to the interior skin portion (224) of the inner hinge surface, resulting in reduced thickness of the skin of the inner hinge. This increases the collapsibility, or ability of the inner surface of the hinge to fold or buckle, during the bending action. This in turn reduces the bending radius of the hinge such that the hinging action exerts less strain on the outer surface of the hinge. The inner surface of the hinge may optionally by treated with glycerine or other polyol to soften the inner surface. The exterior skin portion (226) of the hinge may optionally be coated with an elastomeric material, such as polyvinyl alcohol, in order to strengthen the outer surface and reduce its tendency to fracture during the hinging action.

Claims

43AMENDED CLAIMS[received by the International Bureau on 9 December 1997 (09.12.97); original claims 2, 14 and 26 amended; remaining claims unchanged (4 pages)]
1. A method for manufacturing an article having a starch-bound cellular matrix, the method comprising: molding an aqueous starch-based mixture into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation, thereby forming the starch-bound cellular matrix of the article, the molding step including forming a hinge structure within the article comprising an interior skin portion, an exterior skin portion, an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the molding step resulting in the interior skin portion having a thickness that is less than the thickness of the exterior skin portion; and demolding the article after the article has achieved form stability.
2. A method for manufacturing an article as defined in claim 1, wherein the molding step imparts less heat per unit time to the interior skin portion than to the exterior skin portion.
3. A method for manufacturing an article as defined in claim 1 , wherein the molding step is carried out using a heated mold apparatus.
4. A method for manufacturing an article as defined in claim 3, wherein the heated mold apparatus includes a molding strip corresponding to the interior skin portion having reduced heat diffusivity compared to the rest of the mold apparatus.
5. A method for manufacturing an article as defined in claim 1 , wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion.
6. A method for manufacturing an article as defined in claim 1 , wherein the molding step results in the exterior skin portion having at least one bending initiation groove.
7. A method for manufacturing an article as defined in claim 1 , further including the step of treating the interior skin portion of the hinge structure with a polyol.
8. A method for manufacturing an article as defined in claim 7, wherein the polyol is applied by means of an aqueous polyol solution.
9. A method for manufacturing an article as defined in claim 7, wherein the polyol comprises glycerin.
10. A method for manufacturing an article as defined in claim 7, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, .and mixtures of the foregoing.
11. A method for manufacturing an article as defined in claim 1 , further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure. 44
12. A method for manufacturing an article as defined in claim 11 , wherein the elastomeric coating comprises polyvinyl alcohol.
13. A method for manufacturing an article as defined in claim 1 1 , wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing.
14. A method for manufacturing an article having a starch-bound cellular matrix, the method comprising: molding an aqueous starch-based mixture into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation, thereby forming the starch-bound cellular matrix of the article, the molding step including forming a hinge structure within the article comprising an interior skin portion, an exterior skin portion, .an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the molding step imparting less heat per unit time to the interior skin portion than to the exterior skin portion such that the interior skin portion is formed having a thickness that is less than the thickness of the exterior skin portion; and demolding the article after the article has achieved form stability.
15. A method for manufacturing an article as defined in claim 14, wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion.
16. A method for manufacturing an article as defined in claim 14, wherein the molding step results in the exterior skin portion having at least one bending initiation groove.
17. A method for manufacturing an article as defined in claim 14, further including the step of treating the interior skin portion of the hinge structure with a polyol.
18. A method for manufacturing an article as defined in claim 17, wherein the polyol is applied by means of an aqueous polyol solution.
19. A method for manufacturing an article as defined in claim 17, wherein the polyol comprises glycerin.
20. A method for manufacturing an article as defined in claim 17, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, and mixtures of the foregoing.
21. A method for manufacturing an article as defined in claim 14, further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure. 45
22. A method for manufacturing an article as defined in claim 21 , wherein the elastomeric coating comprises polyvinyl alcohol.
23. A method for manufacturing an article as defined in claim 21 , wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing.
24. A method for manufacturing an article as defined in claim 14, further including the step of applying a wax-based coating material to the article.
25. A method for manufacturing an article as defined in claim 14, wherein the molding step yields a clam shell container.
26. A method for manufacturing an article having a starch-bound cellular matrix, the method comprising: molding an aqueous starch-based mixture within a heated mold apparatus into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation, thereby forming the starch-bound cellular matrix of the article, the heated mold forming a hinge structure within the article comprising an interior skin portion, an exterior skin portion, an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the heated mold being configured such that it imparts less heat per unit time to the interior skin portion than to the exterior skin portion such that the interior skin portion is formed having a thickness that is less than the thickness of the exterior skin portion; and demolding the article after the article has achieved form stability.
27. A method for manufacturing an article as defined in claim 26, wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion.
28. A method for manufacturing an article as defined in claim 26, wherein the molding step results in the exterior skin portion having at least one bending initiation groove.
29. A method for manufacturing an article as defined in claim 26, further including the step of treating the interior skin portion of the hinge structure with a polyol.
30. A method for manufacturing an article as defined in claim 29, wherein the polyol is applied by means of an aqueous polyol solution.
31. A method for manufacturing an article as defined in claim 29, wherein the polyol comprises glycerin.
32. A method for manufacturing an article as defined in claim 29, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, and mixtures of the foregoing.
33. A method for manufacturing an article as defined in claim 26, further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure.
34. A method for manufacturing an article as defined in claim 33, wherein the elastomeric coating comprises polyvinyl alcohol.
35. A method for manufacturing an article as defined in claim 33, wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing.
36. A method for manufacturing an article as defined in claim 26, further including the step of applying a wax-based coating material to the article.
37. A method for manufacturing an article as defined in claim 26, wherein the molding step yields a clam shell container.
47
STATEMENT UNDER ARTICLE 19
Claims 2, 14 and 26 have been amended to recite that less heat per unit time is imparted to the interior skin portion "than to the exterior skin portion." The claims submitted herewith place this application into conformity with the amendments entered into the corresponding U.S. application.
PCT/US1997/010168 1996-06-10 1997-06-10 Methods for molding hinged starch-bound articles WO1997047452A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BR9709671-7A BR9709671A (en) 1996-06-10 1997-06-10 Method for molding articles glued with starch in chaining
NZ332294A NZ332294A (en) 1996-06-10 1997-06-10 Methods for manufacturing moulded hinged starch-based articles having a cellular matrix
AT97929948T ATE239599T1 (en) 1996-06-10 1997-06-10 SHAPES OF FOLDABLE STARCH-CONTAINED OBJECTS
AU33890/97A AU717469B2 (en) 1996-06-10 1997-06-10 Methods for molding articles which include a hinged starch-bound cellular matrix
EP97929948A EP0920371B1 (en) 1996-06-10 1997-06-10 Moulding hinged articles containing starch
JP50181898A JP3361813B2 (en) 1996-06-10 1997-06-10 Method for molding an article comprising a hinged starch bound cellular matrix
DE69721782T DE69721782T2 (en) 1996-06-10 1997-06-10 Shapes of hinged, starchy objects

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/661,224 1996-06-10
US08/661,224 US5776388A (en) 1994-02-07 1996-06-10 Methods for molding articles which include a hinged starch-bound cellular matrix

Publications (2)

Publication Number Publication Date
WO1997047452A1 WO1997047452A1 (en) 1997-12-18
WO1997047452B1 true WO1997047452B1 (en) 1998-02-05

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1997/010168 WO1997047452A1 (en) 1996-06-10 1997-06-10 Methods for molding hinged starch-bound articles

Country Status (11)

Country Link
US (1) US5776388A (en)
EP (1) EP0920371B1 (en)
JP (1) JP3361813B2 (en)
KR (1) KR20000015774A (en)
AT (1) ATE239599T1 (en)
AU (1) AU717469B2 (en)
BR (1) BR9709671A (en)
CA (1) CA2250717A1 (en)
DE (1) DE69721782T2 (en)
NZ (1) NZ332294A (en)
WO (1) WO1997047452A1 (en)

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