WO1997047452B1 - Methods for molding hinged starch-bound articles - Google Patents
Methods for molding hinged starch-bound articlesInfo
- Publication number
- WO1997047452B1 WO1997047452B1 PCT/US1997/010168 US9710168W WO9747452B1 WO 1997047452 B1 WO1997047452 B1 WO 1997047452B1 US 9710168 W US9710168 W US 9710168W WO 9747452 B1 WO9747452 B1 WO 9747452B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- article
- skin portion
- manufacturing
- interior
- polyol
- Prior art date
Links
- 238000000465 moulding Methods 0.000 title claims abstract 21
- 229920002472 Starch Polymers 0.000 title claims abstract 14
- 235000019698 starch Nutrition 0.000 title claims abstract 14
- 239000008107 starch Substances 0.000 title claims abstract 14
- 210000003491 Skin Anatomy 0.000 claims abstract 45
- 229920005862 polyol Polymers 0.000 claims abstract 16
- 150000003077 polyols Chemical class 0.000 claims abstract 16
- 239000000203 mixture Substances 0.000 claims abstract 14
- 230000001413 cellular Effects 0.000 claims abstract 10
- 239000011159 matrix material Substances 0.000 claims abstract 8
- 238000005452 bending Methods 0.000 claims abstract 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract 4
- 235000011187 glycerol Nutrition 0.000 claims abstract 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 4
- 230000000875 corresponding Effects 0.000 claims abstract 3
- 239000000463 material Substances 0.000 claims abstract 3
- 238000004519 manufacturing process Methods 0.000 claims 37
- 239000011248 coating agent Substances 0.000 claims 11
- 238000000576 coating method Methods 0.000 claims 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims 3
- 229920000126 Latex Polymers 0.000 claims 3
- 239000002202 Polyethylene glycol Substances 0.000 claims 3
- 229920001451 Polypropylene glycol Polymers 0.000 claims 3
- 238000001704 evaporation Methods 0.000 claims 3
- 230000000977 initiatory Effects 0.000 claims 3
- 239000004816 latex Substances 0.000 claims 3
- 229920000747 poly(lactic acid) polymer Polymers 0.000 claims 3
- 229920001223 polyethylene glycol Polymers 0.000 claims 3
- 239000004626 polylactic acid Substances 0.000 claims 3
- 239000000600 sorbitol Substances 0.000 claims 3
- 235000020639 clam Nutrition 0.000 claims 2
Abstract
Method and systems for forming hinged starch-bound matrices. Starch-based compositions are molded between heated molds in order to form a cellular matrix and also to remove water from the starch-based compositions in order to form a binding matrix of solidified starch. The molding apparatus is configured to form one or more creases (230) within the hinge structure (200) in order to define one or more lines upon which the hinge will bend. The molding apparatus is also configured such that the region of the mold corresponding to the inner surface of the hinge area will transfer heat more slowly to the interior skin portion (224) of the inner hinge surface, resulting in reduced thickness of the skin of the inner hinge. This increases the collapsibility, or ability of the inner surface of the hinge to fold or buckle, during the bending action. This in turn reduces the bending radius of the hinge such that the hinging action exerts less strain on the outer surface of the hinge. The inner surface of the hinge may optionally by treated with glycerine or other polyol to soften the inner surface. The exterior skin portion (226) of the hinge may optionally be coated with an elastomeric material, such as polyvinyl alcohol, in order to strengthen the outer surface and reduce its tendency to fracture during the hinging action.
Claims
1. A method for manufacturing an article having a starch-bound cellular matrix, the method comprising: molding an aqueous starch-based mixture into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation, thereby forming the starch-bound cellular matrix of the article, the molding step including forming a hinge structure within the article comprising an interior skin portion, an exterior skin portion, an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the molding step resulting in the interior skin portion having a thickness that is less than the thickness of the exterior skin portion; and demolding the article after the article has achieved form stability.
2. A method for manufacturing an article as defined in claim 1, wherein the molding step imparts less heat per unit time to the interior skin portion than to the exterior skin portion.
3. A method for manufacturing an article as defined in claim 1 , wherein the molding step is carried out using a heated mold apparatus.
4. A method for manufacturing an article as defined in claim 3, wherein the heated mold apparatus includes a molding strip corresponding to the interior skin portion having reduced heat diffusivity compared to the rest of the mold apparatus.
5. A method for manufacturing an article as defined in claim 1 , wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion.
6. A method for manufacturing an article as defined in claim 1 , wherein the molding step results in the exterior skin portion having at least one bending initiation groove.
7. A method for manufacturing an article as defined in claim 1 , further including the step of treating the interior skin portion of the hinge structure with a polyol.
8. A method for manufacturing an article as defined in claim 7, wherein the polyol is applied by means of an aqueous polyol solution.
9. A method for manufacturing an article as defined in claim 7, wherein the polyol comprises glycerin.
10. A method for manufacturing an article as defined in claim 7, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, .and mixtures of the foregoing.
11. A method for manufacturing an article as defined in claim 1 , further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure. 44
12. A method for manufacturing an article as defined in claim 11 , wherein the elastomeric coating comprises polyvinyl alcohol.
13. A method for manufacturing an article as defined in claim 1 1 , wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing.
14. A method for manufacturing an article having a starch-bound cellular matrix, the method comprising: molding an aqueous starch-based mixture into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation, thereby forming the starch-bound cellular matrix of the article, the molding step including forming a hinge structure within the article comprising an interior skin portion, an exterior skin portion, .an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the molding step imparting less heat per unit time to the interior skin portion than to the exterior skin portion such that the interior skin portion is formed having a thickness that is less than the thickness of the exterior skin portion; and demolding the article after the article has achieved form stability.
15. A method for manufacturing an article as defined in claim 14, wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion.
16. A method for manufacturing an article as defined in claim 14, wherein the molding step results in the exterior skin portion having at least one bending initiation groove.
17. A method for manufacturing an article as defined in claim 14, further including the step of treating the interior skin portion of the hinge structure with a polyol.
18. A method for manufacturing an article as defined in claim 17, wherein the polyol is applied by means of an aqueous polyol solution.
19. A method for manufacturing an article as defined in claim 17, wherein the polyol comprises glycerin.
20. A method for manufacturing an article as defined in claim 17, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, and mixtures of the foregoing.
21. A method for manufacturing an article as defined in claim 14, further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure. 45
22. A method for manufacturing an article as defined in claim 21 , wherein the elastomeric coating comprises polyvinyl alcohol.
23. A method for manufacturing an article as defined in claim 21 , wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing.
24. A method for manufacturing an article as defined in claim 14, further including the step of applying a wax-based coating material to the article.
25. A method for manufacturing an article as defined in claim 14, wherein the molding step yields a clam shell container.
26. A method for manufacturing an article having a starch-bound cellular matrix, the method comprising: molding an aqueous starch-based mixture within a heated mold apparatus into a desired shape of the article under elevated temperature in order to remove a substantial portion of the water from the mixture by evaporation, thereby forming the starch-bound cellular matrix of the article, the heated mold forming a hinge structure within the article comprising an interior skin portion, an exterior skin portion, an interior cellular core disposed between the interior skin portion and the exterior skin portion, and at least one depression in the interior skin portion, the heated mold being configured such that it imparts less heat per unit time to the interior skin portion than to the exterior skin portion such that the interior skin portion is formed having a thickness that is less than the thickness of the exterior skin portion; and demolding the article after the article has achieved form stability.
27. A method for manufacturing an article as defined in claim 26, wherein the molding step yields a multiple hinge having at least two depressions in the interior skin portion.
28. A method for manufacturing an article as defined in claim 26, wherein the molding step results in the exterior skin portion having at least one bending initiation groove.
29. A method for manufacturing an article as defined in claim 26, further including the step of treating the interior skin portion of the hinge structure with a polyol.
30. A method for manufacturing an article as defined in claim 29, wherein the polyol is applied by means of an aqueous polyol solution.
31. A method for manufacturing an article as defined in claim 29, wherein the polyol comprises glycerin.
32. A method for manufacturing an article as defined in claim 29, wherein the polyol is selected from the group consisting of polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, and mixtures of the foregoing.
33. A method for manufacturing an article as defined in claim 26, further including the step of applying an elastomeric coating to the exterior skin portion of the hinge structure.
34. A method for manufacturing an article as defined in claim 33, wherein the elastomeric coating comprises polyvinyl alcohol.
35. A method for manufacturing an article as defined in claim 33, wherein the elastomeric coating is selected from the group consisting of polylactic acid, natural latex, derivatives of the foregoing, and mixtures of the foregoing.
36. A method for manufacturing an article as defined in claim 26, further including the step of applying a wax-based coating material to the article.
37. A method for manufacturing an article as defined in claim 26, wherein the molding step yields a clam shell container.
47
STATEMENT UNDER ARTICLE 19
Claims 2, 14 and 26 have been amended to recite that less heat per unit time is imparted to the interior skin portion "than to the exterior skin portion." The claims submitted herewith place this application into conformity with the amendments entered into the corresponding U.S. application.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR9709671-7A BR9709671A (en) | 1996-06-10 | 1997-06-10 | Method for molding articles glued with starch in chaining |
NZ332294A NZ332294A (en) | 1996-06-10 | 1997-06-10 | Methods for manufacturing moulded hinged starch-based articles having a cellular matrix |
AT97929948T ATE239599T1 (en) | 1996-06-10 | 1997-06-10 | SHAPES OF FOLDABLE STARCH-CONTAINED OBJECTS |
AU33890/97A AU717469B2 (en) | 1996-06-10 | 1997-06-10 | Methods for molding articles which include a hinged starch-bound cellular matrix |
EP97929948A EP0920371B1 (en) | 1996-06-10 | 1997-06-10 | Moulding hinged articles containing starch |
JP50181898A JP3361813B2 (en) | 1996-06-10 | 1997-06-10 | Method for molding an article comprising a hinged starch bound cellular matrix |
DE69721782T DE69721782T2 (en) | 1996-06-10 | 1997-06-10 | Shapes of hinged, starchy objects |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/661,224 | 1996-06-10 | ||
US08/661,224 US5776388A (en) | 1994-02-07 | 1996-06-10 | Methods for molding articles which include a hinged starch-bound cellular matrix |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1997047452A1 WO1997047452A1 (en) | 1997-12-18 |
WO1997047452B1 true WO1997047452B1 (en) | 1998-02-05 |
Family
ID=24652690
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1997/010168 WO1997047452A1 (en) | 1996-06-10 | 1997-06-10 | Methods for molding hinged starch-bound articles |
Country Status (11)
Country | Link |
---|---|
US (1) | US5776388A (en) |
EP (1) | EP0920371B1 (en) |
JP (1) | JP3361813B2 (en) |
KR (1) | KR20000015774A (en) |
AT (1) | ATE239599T1 (en) |
AU (1) | AU717469B2 (en) |
BR (1) | BR9709671A (en) |
CA (1) | CA2250717A1 (en) |
DE (1) | DE69721782T2 (en) |
NZ (1) | NZ332294A (en) |
WO (1) | WO1997047452A1 (en) |
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US5523293A (en) | 1994-05-25 | 1996-06-04 | Iowa State University Research Foundation, Inc. | Soy protein-based thermoplastic composition for preparing molded articles |
US5506277A (en) | 1994-06-30 | 1996-04-09 | Kimberly-Clark Corporation | Starch foams for absorbent articles |
US5466493A (en) | 1994-10-26 | 1995-11-14 | Michelman, Inc. | Non-skid surface composition for paper products |
US5487813A (en) | 1994-12-02 | 1996-01-30 | The Procter & Gamble Company | Strong and soft creped tissue paper and process for making the same by use of biodegradable crepe facilitating compositions |
US5665285A (en) | 1995-01-24 | 1997-09-09 | Mitsubishi Yuka Badische Co., Ltd. | Method for producing a molded foam article with an integral skin |
US5620510A (en) | 1995-06-23 | 1997-04-15 | Cpc International Inc. | Swollen starches as papermaking additives |
-
1996
- 1996-06-10 US US08/661,224 patent/US5776388A/en not_active Expired - Lifetime
-
1997
- 1997-06-10 BR BR9709671-7A patent/BR9709671A/en not_active Application Discontinuation
- 1997-06-10 EP EP97929948A patent/EP0920371B1/en not_active Expired - Lifetime
- 1997-06-10 JP JP50181898A patent/JP3361813B2/en not_active Expired - Fee Related
- 1997-06-10 AU AU33890/97A patent/AU717469B2/en not_active Ceased
- 1997-06-10 NZ NZ332294A patent/NZ332294A/en unknown
- 1997-06-10 KR KR1019980709322A patent/KR20000015774A/en not_active Application Discontinuation
- 1997-06-10 DE DE69721782T patent/DE69721782T2/en not_active Expired - Fee Related
- 1997-06-10 WO PCT/US1997/010168 patent/WO1997047452A1/en active IP Right Grant
- 1997-06-10 AT AT97929948T patent/ATE239599T1/en not_active IP Right Cessation
- 1997-06-10 CA CA 2250717 patent/CA2250717A1/en not_active Abandoned
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