WO1997000163A1

WO1997000163A1 - Method for manufacturing solid elastomeric gels

Info

Publication number: WO1997000163A1
Application number: PCT/US1996/006855
Authority: WO
Inventors: Glen H. Bayer, Jr.; Robert J. Wolf; James G. Wolf; Timothy D. Bredahl
Original assignee: Minnesota Mining And Manufacturing Company
Priority date: 1995-06-15
Filing date: 1996-05-14
Publication date: 1997-01-03
Also published as: KR19990022862A; JPH11507881A; TW352361B; AU5792596A; EP0837766A1; CA2222645A1

Abstract

Solid elastomeric gel is produced in a continuous process using a twin screw extruder (10). Gel from the extruder (10) can be fed through a die (21) to form a length of the gel (20) with a uniform cross section and then cut to length to provide pieces of the gel (20) for use in a pad. Alternatively, gel from the extruder (10) may be injected into a chamber between a rigid base portion and a thermoplastic sheet to form that sheet and a surface of the layer of gel in the cavity against a surface in a cavity, thereby producing a pad including the layer of gel that has a precise predetermined peripheral shape corresponding to the surface in the cavity and is covered by the sheet which also has that peripheral shape and is wrinkle free.

Description

METHOD FOR MANUFACTURING SOLID ELASTOMERIC GELS

Field ofthe Invention

The present invention relates to the manufacture of solid elastomeric gels and to the.formation of pads including layers of such gels.

Background Pads including layers of solid elastomeric gels such as those described in

U.S. Patent No. 3,676,387 have been proven to be highly effective in reducing the affect of pressure points on portions of a person supported on the pads, thereby reducing tissue inflammation (e.g., "bed sores") and loss of circulation to extremities due to restriction of blood flow. U.S. Patent Applications Nos. 08/253,510 filed June 3, 1994, and

08/324,734 filed October 18, 1994, describe wrist rests adapted to be used by a computer operator which include covered layers of solid elastomeric gel on which the wrists ofthe computer operator may be supported. The layers of solid elastomeric gel in those pads retain their shape and provide a conformable contour that distributes the weight of a users hands and/or forearms across a broad surface area.

Heretofore, the solid elastomeric gels used in such pads have been made in batch processes and subsequently molded to a desired shape. U.S. Patent No. 3,676,387 describes batch processes for making several gel constructions, each of which processes includes placing a polymer and a plasticizer such a mineral oil in a heated vessel, mixing the polymer and plasticizer under medium to high shear for a determined time, and then emptying the vessel. Such batch processes typically require long mixing times and can cause mechanical degradation due to agitation and or can thermal degradation ofthe polymers due to oxidation. Stabilizers may be added to reduce thermal degradation, but they are limited in their effectiveness and add cost to the process.

^■l - Disclosure ofthe Invention

The present invention provides a method for making solid elastomeric gels more quickly and with less mechanical and thermal degradation than is possible with the batch process described above; together with improved methods for forming pads that include layers of solid elastomeric gel.

Generally, the method according to the present invention is for making solid elastomeric gel from copolymer and plasticizer and includes the steps of (1) providing an extruder having multiple infeed sections each followed by a mixing section along a barrel ofthe extruder; (2) introducing the copolymer into one ofthe infeed sections ofthe operating extruder, (3) heating and shearing the copolymer in a subsequent mixing section, (4) introducing the plasticizer to the copolymer through at least one ofthe feeding sections in a pattern and at a rate that produces solid elastomeric gel at room temperature that will retain its shape after repeated compression and decompression ofthe gel, and (5) ejecting the gel from the extruder.

The ejecting step may include ejecting the gel through a die to form a length ofthe gel having a predetermined cross section, and the method may further include (6) cutting the extruded gel into lengths to form pieces ofthe gel with uniform cross sections that can be used in pads. Alternatively, the method can further include the steps of (6) providing a die having a cavity defined by a cavity surface with a predetermined shape and a support surface around the periphery ofthe cavity; (7) forming a preliminary structure including (a) a rigid base portion adapted to engage the support surface of the die, that has inner and outer surfaces and an inlet passageway communicating between those surfaces; and (b) a thermoplastic sheet having a periphery attached to the periphery ofthe base portion with the sheet extending over its inner surface to define a chamber between the thermoplastic sheet and the inner surface ofthe base portion, which chamber has a volume less than the volume ofthe cavity; and (8) positioning the base portion against the support surface ofthe die with the thermoplastic sheet positioned in the cavity at a position spaced from the cavity surface. The ejecting step may then include ejecting the gel through the inlet passageway into the chamber to thermally deform the sheet into intimate engagement against the cavity surface and to form, when the gel has cooled, a pad including a piece of solid elastomeric gel having a surface covered by the polymeric sheet that corresponds in shape to the cavity surface.

Brief Description ofthe Drawing

The present invention will be further described with reference to the accompanying drawing wherein like reference numerals refer to like parts in the several views, and wherein; Figure 1 is a schematic view of an extruder used in the method according to the present invention;

Figure 2 is an enlarged fragmentary view of portions ofthe screws from the extruder illustrated in Figure 1 ;

Figure 3 is a sectional view taken approximately along line 3-3 of Figure 2; Figure 4 is a sectional view taken approximately along line 4-4 of Figure 2;

Figure 5 is a schematic view illustrating a first modification ofthe method illustrated in Figure 1 ;

Figure 6 is an enlarged sectional view of a die used in the method modification illustrated in Figure 5; Figure 7 is an enlarged perspective view of a piece of solid elastomeric gel made using the method modification illustrated in Figure 5;

Figures 8 and 9 are sectional views illustrating a second modification ofthe method illustrated in Figure 1 ; and

Figure 10 is a perspective view of a pad made using the second method modification illustrated in Figures 8 and 9.

Detailed Description

Referring now to Figures 1 through 4 there is illustrated a method according to the present invention for making solid elastomeric gel from copolymer and plasticizer. Generally, that method includes the steps of (1) providing a twin screw extruder 10 (e.g., a Werner Pfleiderer Model ZSK 30 twin screw co-rotating extruder) that has multiple infeed sections l la, l ib, l ie and 1 Id into which material may be fed through hoppers 16, each of which infeed sections l la, l ib, 1 lc and 1 Id is followed by a mixing section 12 along a barrel 13 ofthe extruder; (2) introducing the copolymer into one ofthe infeed sections (e.g., 1 la) ofthe extruder 10, (3) heating and shearing the copolymer in a subsequent mixing section 12; (3) introducing the plasticizer to the copolymer through at least one ofthe infeed sections 1 lb, l ie and 1 Id in a pattern and at a rate to produce solid elastomeric gel that at room temperature that will retain its shape after repeated compression and decompression cycles ofthe gel; and (4) ejecting the solid elastomeric gel from the extruder 10.

Figure 2 illustrates portions of twin screws 14 in the extruder 10 at two of the infeed and mixing sections l la, l ib, and 12 ofthe twin screw extruder 10. Figures 3 and 4 illustrate the cross sectional shapes ofthe twin screws 14 at the mixing and infeed sections respectively. While the specific pitch and type of mixing and infeed sections used is not critical, those sections should be selected to provide sufficient residence time in the various sections to accomplish homogeneous mixing and plasticizing ofthe copolymer.

The polymer is introduced into the first infeed section 1 la ofthe barrel 13, and is then heated to between 200 and 350 degrees Fahrenheit in the following short mixing section 12. Plasticizer is introduced at the second infeed section l ib and is then heated to a temperature in the range of 200 to 350 degrees Fahrenheit in the next mixing section 12. The mixture then passes through another mixing section 1 lc heated to a temperature in the range of 250 to 350 degrees Fahrenheit. The barrel 13 and the screws 14 may include any number of infeed and mixing sections 1 1 and 12 needed to achieve the desired softness for the solid elastomeric gel. After the final mixing section 11, the mixed gel is passed through a cooling feed section 15 to reduce the temperature, and thereby increase the viscosity ofthe molten gel so that it can be fed either ( ] ) into a storage container (not shown) for later processing, or (2) through a profile extrusion die 21 as will be explained below with reference to Figures 5 through 7, or (3) into an injection mold or die 30 as will also be explained below with reference to Figures 8 through 10, or (4) into a form- fill-seal device to fill a flexible sleeve with the gel to form a pad of a desired shape.

Figures 5 through 7 illustrate a first modification ofthe method illustrated in Figures 1 through 4 that can be used to make pieces 20 ofthe solid elastomeric gel with uniform cross sections (see Figure 7) that can be used in pads. To make such pieces 20 of solid elastomeric gel, the molten gel from the extruder 10 is pushed through a profile extrusion die 21 onto a conveyor 25 where the at least partially cooled and solidified gel extruded through the die 21 is cut into lengths by a cutting device 22 to form the pieces 20 ofthe gel with uniform cross sections that can be used in pads.

Figure 6 illustrates details ofthe profile extrusion die 21 which has an inlet port 23 into which molten gel is fed from the extruder 10 at a temperature and rate that allows the periphery ofthe gel to conform to the shape of an outlet orifice 24 ofthe die 21 and, upon being exposed to room temperature air, to solidify to an extent that its peripheral shape in cross section is retained upon further cooling. The profile extrusion die 21 includes a central temperature control section having openings 27 through which heated or cooled liquids or air may circulated or electric heaters may be positioned to help provide temperature control for the gel passing through the die 21. While Figure 5 illustrates feeding molten gel directly from the extruder 10 into the profile extrusion die 21 , solid elastomeric gel made using the extruder 10 or by a batch process at an earlier time may be made molten and fed through the profile extrusion die 21 using means other than the extruder 10, such as a melt pump (not shown). Figures 8 through 10 illustrate a second modification ofthe method illustrated in Figures 1 through 4 that can be used to make pads including pieces 28 ofthe solid elastomeric gel with precise predetermined peripheral shapes. That method further includes the steps of providing the die 30 (Figures 8 and 9) having a cavity defmed by a cavity surface 32 with a predetermined shape, and a support surface 34 around the periphery ofthe cavity. A preliminary structure is formed that includes a rigid base portion 35 (e.g., of polystyrene plastic) adapted to engage the support surface 34 ofthe die 30, having inner and outer surfaces 36 and 37, and having an inlet passageway 38 and small air vents (not shown) communicating between its inner and outer surfaces 36 and 37. Also provided is a thermoplastic sheet 40 having a periphery 41 attached to the periphery ofthe base portion 35 with the sheet 40 extending over the inner surface 36 to define a chamber 42 between the thermoplastic sheet 40 and the inner surface 36 ofthe base portion 35, which chamber 42 has a volume less than the volume ofthe cavity in the die 30 between the inner surface 36 and the cavity surface 32. The base portion 35 is positioned and may be clamped if necessary against the support surface 34 ofthe die 30 with the thermoplastic sheet 40 positioned in the cavity at a position spaced from the cavity surface 32 (Figure 8). The molten gel is then injected by the extruder 10 through the inlet passageway 38 into the chamber 42 to thermally deform the sheet 40 into intimate engagement against the cavity surface 32 (Figure 9). When the gel has cooled there is formed a pad 44 including the 28 piece of solid elastomeric gel having a surface very precisely corresponding in shape to the cavity surface 32 and overlaid by the sheet 40. The sheet 40 also corresponds very precisely to the cavity surface 32, has an inner surface coextensive with the top and side surfaces of said layer of gel, and is smooth and free of wrinkles.

The sheet 40 can be a laminate of an inner oil impervious thermoplastic polymeric film and an outer conformable layer that provides a pleasing surface texture for contact by a persons hands and arms. As an example, a polyurethane blown microfiber web laminated to a polyurethane film has been found quite suitable. Such a laminate is described in U.S. Patent Application No. 08/490,464, filed June 14, 1995, Attorney Docket No. 51823USA9A. The sheet 40 can be attached to the base portion 35 by heat sealing or other means, such as are described in U.S. Patent Applications Nos. 08/253,510 filed June 3, 1994, and 08/324,734 filed October 18, 1994.

While, as described above, molten gel can be fed directly from the extruder 10 into the chamber 42, solid elastomeric gel made using the extruder 10 or by a batch process at an earlier time may be made molten and fed into the chamber 42 using means other than the extruder 10, such as by a melt pump (not shown). Example 1 :

Solid elastomeric gel has been produced by the following continuous extrusion process. A copolymer commercially designated "Kraton (t.m.) 1107" and available from Shell Petroleum Company was introduced into a first infeed section l la ofthe co-rotating twin screw extruder 10. The screw design ofthe extruder 10 was such that multiple mixing sections 12 each followed different multiple infeed sections 1 1 along the barrel 13 ofthe extruder 10. The copolymer introduced in the extruder was heated and sheared in the first mixing section 12 immediately following its introduction into the first infeed section 1 1 a. Mineral oil plasticizer similar to that described in U.S. Patent No. 3,676,387 was introduced at approximately a 1 : 1 ratio by weight with the copolymer at the second infeed section 1 lb ofthe extruder 10. Additional plasticizer was introduced at the third infeed section 1 lc at a ratio of about 3: 1 by weight with the copolymer, and still additional plasticizer introduced at the fourth infeed section at a ratio of about 4: 1 by weight with the copolymer. The extruder 10 was fed with copolymer and plasticizer at a rate that produced 50 pounds per hour ofthe gel.

For purposes of comparison, solid elastomeric gel was also produced by the following batch process.

A 75 gallon heated kettle was filled with the same ratio ofthe copolymer "Kraton (t.m.) 1 107" and the mineral oil plasticizer described above to which was added a small amount of "Irgonox (t.m.) 1076 stabilizer. The mixture was agitated at medium shear for 8 hours. The solid elastomeric gels produced by the above two processes were analyzed using gel permeatation chromatography analysis ("gpc") to compare the percentages of tri-block and di-block copolymers in the gels, and thereby compare the amount of thermal and/or mechanical degradation the gels had undergone in their manufacturing processes (i.e., tri-block copolymers degrade to di-block copolymers, so that the level of di-block copolymers in the gel is an indication of the amount of degradation that has occurred in the manufacturing process). The gel made by the extrusion process contained 66.7 percent tri-block copolymers and 33.1 percent di-block copolymers, whereas the gel made by the batch process contained 52.7 percent tri-block copolymers and 47.3 percent di-block copolymers which indicated that significantly less thermal degradation had occurred in the extrusion process than in the batch process.

The present invention has now been described with reference to one embodiment together with several modifications thereof. It will be apparent to those skilled in the art that many changes can be made in the embodiment and modifications described above without departing from the scope ofthe present invention. Thus the scope ofthe present invention should not be limited to the methods and structures described in this application, but only by the methods and structures described by the language ofthe claims and the equivalents of those methods and structures.

Claims

Claims:

1. A method for making solid elastomeric gel from copolymer and plasticizer including the steps of. providing an extruder having multiple infeed sections each followed by a mixing sections along a barrel ofthe extruder; operating the extruder while introducing the copolymer into one ofthe infeed sections ofthe extruder to heat and shear the copolymer in a subsequent mixing section; introducing the plasticizer to the copolymer through at least one ofthe feeding sections in a pattern and at a rate to produce solid elastomeric gel that at room temperature that will retain its shape after repeated compression and decompression cycles ofthe gel; and ejecting the gel from the extruder.

2. A method according to claim 1 further comprising the steps of: passing the gel through a die having a predetermined peripheral shape; and cutting the extruded gel into lengths to form pieces ofthe gel with uniform cross sections that can be used in pads.

3. A method according to claim 1 further comprising the step of passing the gel through a die having a predetermined peripheral shape.

4. A method according to claim 1 further comprising the steps of: providing a die having a cavity defined by a cavity surface with a predetermined shape and a support surface around the periphery ofthe cavity; forming a preliminary structure including a rigid base portion adapted to engage the support surface ofthe die, having inner and outer surfaces, and having an inlet passageway communicating between said inner and outer surfaces; and a thermoplastic sheet having a periphery attached to the periphery ofthe base portion with the sheet extending over said inner surface to define a chamber between the thermoplastic sheet and the inner surface ofthe base portion, said chamber having a volume less than the volume of said cavity; positioning the base portion against the support surface ofthe die with the thermoplastic sheet positioned in the cavity at a position spaced from the cavity surface; and extruding the heated solid elastomeric gel through the inlet passageway into the chamber to thermally deform the sheet into intimate engagement against the cavity surface and to form, when the gel has cooled, a pad including a piece of solid elastomeric gel having a surface corresponding in shape to the die surface.

5. A method for forming a pad comprising the steps of: providing a die having a cavity defined by a cavity surface with a predetermined shape and a support surface around the periphery ofthe cavity; forming a preliminary structure including a rigid base portion adapted to engage the support surface ofthe die, having inner and outer surfaces, and having an inlet passageway communicating between said inner and outer surfaces; and a thermoplastic sheet having a periphery attached to the periphery ofthe base portion with the sheet extending over the inner surface to define a chamber between the thermoplastic sheet and the inner surface ofthe base portion, which chamber has a volume less than the volume of said cavity; positioning the base portion against the support surface ofthe die with the thermoplastic sheet positioned in the cavity at a position spaced from the cavity surface; heating solid elastomeric gel to a fluid state; and injecting the heated solid elastomeric gel through the inlet passageway into the chamber to thermally deform the sheet into intimate engagement against the cavity surface and to form, when the gel has cooled, a pad including a piece of solid elastomeric gel having a surface corresponding in shape to the die surface between the deformed thermoplastic sheet and the base portion.

6. A pad comprising a layer of solid elastomeric gel having top side and bottom surfaces, a rigid base portion having a periphery along said bottom surface, and a flexible oil impervious thermoplastic sheet having a periphery attached to the periphery of said base portion to form a chamber between said base portion and sheet, said sheet having an inner surface coextensive with the top and side surfaces of said layer of gel and being free of wrinkles.

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