WO1994004753A1 - Impregnating agent for producing papers with high resistance to the penetration of grease, oil and aqueous media - Google Patents
Impregnating agent for producing papers with high resistance to the penetration of grease, oil and aqueous media Download PDFInfo
- Publication number
- WO1994004753A1 WO1994004753A1 PCT/DE1993/000724 DE9300724W WO9404753A1 WO 1994004753 A1 WO1994004753 A1 WO 1994004753A1 DE 9300724 W DE9300724 W DE 9300724W WO 9404753 A1 WO9404753 A1 WO 9404753A1
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- WIPO (PCT)
- Prior art keywords
- polyvinyl alcohol
- grease
- alcohol solution
- impregnating agent
- aqueous media
- Prior art date
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/10—Phosphorus-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/11—Halides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/57—Polyureas; Polyurethanes
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
- D21H21/20—Wet strength agents
Definitions
- Impregnation agent for the production of papers with high penetration resistance against fats, oils and aqueous media Impregnation agent for the production of papers with high penetration resistance against fats, oils and aqueous media
- the invention relates to an agent for the production of impregnated papers inside or outside the paper machine, with which the paper is given high penetration resistance to fats, oils and aqueous media by means of surface finishing.
- Impregnation media for coating papers inside and outside of paper machines which contain silicone oil dispersions and / or silicone wax dispersions are also known. With these impregnations, the paper is given very good penetration resistance to fats, oils and also aqueous media, but the papers treated in this way no longer accept adhesive solutions and are therefore not suitable for the application Production of composite materials suitable. Methods are also known for the grease and water-tight finishing of papers outside the paper machine, in which the tightness features are achieved by dispersion or extrusion coatings or also by lamination with metal or plastic films or also by vapor deposition with metal. All of these methods and agents have high penetration resistance to fats, oils and aqueous media, but make the products more difficult to recycle.
- the aim of the invention is to design an impregnation system for the production of grease, oil and water-tight, recyclable papers inside and outside the paper machine.
- the invention is based on the object of developing an impregnating medium for producing greaseproof, oilproof, waterproof and nevertheless recyclable papers inside and outside the paper machine, which compared to the prior art of impregnating media used inside the paper machine, while maintaining the fat density, it increases the penetration resistance against water and still ensures sufficient absorption capacity for laminating adhesives.
- the object is achieved in that a prepared polyvinyl alcohol solution of 2 to 6% concentration, preferably 3%, 3 to 10 volume percent based on the polyvinyl alcohol solution, preferably 6% of an anionic aliphatic-aromatic polyester-polyurethane dispersion of Shore A hardness of 40 to 60 and the molecular weight range from 10,000 to 30,000 and a concentration of 40% is added and mixed in that the mixture now present is a separately prepared mixture consisting of 5 to 20 percent by mass based on polyvinyl alcohol, preferably 15%, made of hydrophobicized precipitated silica in methanol and 1 to 3 percent by volume based on the polyvinyl alcohol dole solution, preferably 2%, an anionic Akylketen dimer dispersion with a concentration of 11% and a particle size of 0.2 to 0.9 micron, is added and mixed in well, the mixture now present 0.5 to 3 volume percent based on the polyvinyl alcohol solution, preferably 2%, of an anionic perfluoroalky
- this impregnation medium for the impregnation of paper within the paper machine with one of the known application methods and subsequent drying in the after-dryer section allows the production of grease and oil-tight, recyclable papers, which are also due to the proportionate use of an anionic polyester-polyurethane dispersion and hydrophobic precipitated silica have a very high penetration resistance against aqueous media.
- Example 1 serves for comparison with the prior art.
- Table 1 The relevant test results determined on the finished paper are shown in Table 1.
- the impregnation media described in Examples 1 and 2 are applied to both sides using a size press in a paper machine on unsized base paper with a freeness of 40 to 42 SR, a basis weight of 50 g / m and a speed of 350 m / min and then immediately dried in the after-dryer section.
- the application weight is approximately 1.2 g / m on each side of the paper.
- Example 1 Example 2 (Invention (State of the Art))
- Fat density according to Tappi 454 (sec.) Over 1800 resistance to water penetration according to ISO 5633: 2 days between 6 in days or hours and 24.00 hours recyclability (time until complete defibration in the laboratory server): in min. 20.00 18.00 Wet tensile strength: in N 18.00 16.00
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
Paper production, impregnating agent, polyester-polyurethane dispersion, waterproofed precipitation silicic acid, perfluoroalkylethyl phosphatediethanol ammonium salt, styrene-butyl acrylate copolymer, alkyl ketene dimer dispersion, grease-proofing and water-proofing are disclosed. An impregnating agent is used to produce grease-proof and oil-proof recyclable papers with high resistance against the penetration of aqueous media. Besides the state-of-the-art perfluorocompounds and glueing agents, a waterproofed precipitation silicic acid and an aliphatic-aromatic polyester-polyurethane dispersion are used.
Description
Imprägniermittel zur Herstellung von Papieren mit hohem Durchdringungswiderstand gegen Fette, öle und wässrige MedienImpregnation agent for the production of papers with high penetration resistance against fats, oils and aqueous media
Die Erfindung betrifft ein Mittel zur Herstellung von imprägnierten Papieren innerhalb oder außerhalb der Pa¬ piermaschine, mit welchem dem Papier auf dem Wege der Oberflächenveredlung hohe Durchdringungswiderstände ge¬ gen Fette, öle und wässrige Medien verliehen werden.The invention relates to an agent for the production of impregnated papers inside or outside the paper machine, with which the paper is given high penetration resistance to fats, oils and aqueous media by means of surface finishing.
Bekannt sind verschiedene technische Verfahren zur fett- und wasserdichten Ausrüstung von Papieren innerhalb und außerhalb der Papiermaschine. Innerhalb der Papiermaschi¬ ne werden zu diesem Zweck Kombinationen von Stärkelösunl5 gen und/oder Polyvinylalkohollösungen mit Zusätzen von Fluorchemikalien, synthetischen Hydrophobierungsmitteln, wie Alkylketendimerleime und/oder Copolymerisatleime aus Styrol- und Butylacrylaten unter Zusatz verschiedener Vernetzer, wie Glyoxal , Melaminformaldehydharze bzw. Epi- chlorhydrinharze verwendet.Various technical processes for the grease and waterproof finishing of papers inside and outside the paper machine are known. For this purpose, combinations of starch solutions and / or polyvinyl alcohol solutions with additions of fluorochemicals, synthetic water repellents, such as alkyl ketene dimer glues and / or copolymer glues from styrene and butyl acrylates with the addition of various crosslinking agents, such as glyoxal, melamine formaldehyde resins or epichlorohydrin, are used within the paper machine for this purpose used.
Diese Zusammensetzung von Imprägniermedien gestattet zwar die Herstellung von Papieren mit hoher Fettdichte, jedoch die Wasserdichte entspricht oft noch nicht den anwen- dungstechnischen Forderungen.Although this composition of impregnation media permits the production of papers with a high fat density, the water density often does not yet meet the application requirements.
Bekannt sind weiterhin Imprägniermedien zur Beschichtung von Papieren innerhalb und außerhalb von Papiermaschinen, die Silikonöldispersionen und/oder Silikonwachsdispersio¬ nen enthalten. Mit diesen Imprägnierungen werden dem Pa- pier zwar sehr gute Durchdringungswiderstände gegen Fet¬ te, öle und auch wässrige Medien verliehen, jedoch nehmen die so behandelten Papiere keine Klebstofflösungen mehr an und sind somit anwendungstechnisch nicht für die
Herstellung von Verbundmaterialien geeignet. Bekannt sind weiterhin Verfahren zur fett- und wasser¬ dichten Veredlung von Papieren außerhalb der Papierma¬ schine, bei denen die Dichtheitsmerkmale durch Disper- sions- oder Extrusionsbeschichtungen oder auch durch Kaschieren mit Metall- oder Plastikfolien oder auch durch Bedampfen mit Metall erreicht werden. Alle diese Verfahren und Mittel bewirken zwar hohe Durchdringungs¬ widerstände gegen Fette, öle und wässrige Medien, er- schweren jedoch stark die Recyclefähigkeit der Produkte.Impregnation media for coating papers inside and outside of paper machines which contain silicone oil dispersions and / or silicone wax dispersions are also known. With these impregnations, the paper is given very good penetration resistance to fats, oils and also aqueous media, but the papers treated in this way no longer accept adhesive solutions and are therefore not suitable for the application Production of composite materials suitable. Methods are also known for the grease and water-tight finishing of papers outside the paper machine, in which the tightness features are achieved by dispersion or extrusion coatings or also by lamination with metal or plastic films or also by vapor deposition with metal. All of these methods and agents have high penetration resistance to fats, oils and aqueous media, but make the products more difficult to recycle.
Die Erfindung hat zum Ziel, ein Imprägniermittelsystem zu gestalten zur Herstellung von fett-, öl- und wasser dichten, recyclebaren Papieren innerhalb und außerhalb der Papiermaschine.The aim of the invention is to design an impregnation system for the production of grease, oil and water-tight, recyclable papers inside and outside the paper machine.
Der Erfindung liegt die Aufgabe zugrunde, ein Imprägnier¬ medium zur Herstellung von fettdichten, öldichten, was¬ serdichten und dennoch recyclebaren Papieren innerhalb und außerhalb der Papiermaschine zu entwickeln, das ge¬ genüber dem Stand der Technik von innerhalb der Papier¬ maschine angewendeten Imprägniermedien, bei Beibehaltung der Fettdichte, einen erhöhten Durchdringungswiderstand gegen Wasser bewirkt und dennoch ein ausreichende Auf- nahmefähigkeit für Kaschierklebstoffe sichert.The invention is based on the object of developing an impregnating medium for producing greaseproof, oilproof, waterproof and nevertheless recyclable papers inside and outside the paper machine, which compared to the prior art of impregnating media used inside the paper machine, while maintaining the fat density, it increases the penetration resistance against water and still ensures sufficient absorption capacity for laminating adhesives.
Erfindungsgemäß wird die Aufgabe dadurch gelöst, daß einer vorbereiteten Polyvinylalkohollösung von 2 bis 6 % Konzentration, vorzugsweise 3 %, 3 bis 10 Volumenprozent bezogen auf die Polyvinylalkohollösung, vorzugsweise 6 % einer anionischen aliphatisch-aromatischen Polyester- Polyurethan-Dispersion der Shore A-Härte von 40 bis 60 und des Molmassenbereiches von 10.000 bis 30.000 und
einer Konzentration von 40 % zugegeben und eingemischt werden, daß der nun vorliegenden Mischung eine gesondert vorbereitete Mischung, bestehend aus 5 bis 20 Massepro¬ zent bezogen auf Polyvinylalkohol , vorzugsweise 15 %, in Methanol angeteigter hydrophobierter Fällungskieselsäure und 1 bis 3 Volumenprozent bezogen auf die Polyvinylalko hollösung, vorzugsweise 2„%, einer anionischen Akylketen dimer-Dispersion mit einer Konzentration von 11 % und einer Teilchengröße von 0,2 bis 0,9 Mikron, zugesetzt un gut eingemischt wird, der nun vorliegenden Mischung 0,5 bis 3 Volumenprozent bezogen auf die Polyvinylalkohol¬ lösung, vorzugsweise 2 %, einer anionischen Perfluor- alkylethylphosphat-Diethanolam oniumsalzlösung in Isopro- pylalkohol mit einer Konzentration von 33 % zugegeben un eingemischt werden und daß abschließend der nun vorlie¬ genden Mischung 0,2 bis 1,0 Volumenprozent bezogen auf die Polyvinylalkohollösung, vorzugsweise 0,5 %, Glyoxal zugesetzt und eingemischt werden und diese Gesamtmischun zur Papierimprägnierung innerhalb der Papiermaschine ver wendet wird.According to the invention the object is achieved in that a prepared polyvinyl alcohol solution of 2 to 6% concentration, preferably 3%, 3 to 10 volume percent based on the polyvinyl alcohol solution, preferably 6% of an anionic aliphatic-aromatic polyester-polyurethane dispersion of Shore A hardness of 40 to 60 and the molecular weight range from 10,000 to 30,000 and a concentration of 40% is added and mixed in that the mixture now present is a separately prepared mixture consisting of 5 to 20 percent by mass based on polyvinyl alcohol, preferably 15%, made of hydrophobicized precipitated silica in methanol and 1 to 3 percent by volume based on the polyvinyl alcohol dole solution, preferably 2%, an anionic Akylketen dimer dispersion with a concentration of 11% and a particle size of 0.2 to 0.9 micron, is added and mixed in well, the mixture now present 0.5 to 3 volume percent based on the polyvinyl alcohol solution, preferably 2%, of an anionic perfluoroalkylethylphosphate-diethanolam onium salt solution in isopropyl alcohol with a concentration of 33% is added and mixed in and that finally the mixture presently present is 0.2 to 1.0 percent by volume based on the polyvinyl alcohol solution, preferably 0.5%, glyoxal added and mixed in and this total mixture is used for paper impregnation within the paper machine.
Die Verwendung dieses Imprägniermediums zur Imprägnierun von Papier innerhalb der Papiermaschine mit einem der bekannten Auftragsverfahren und anschließender Trocknung in der Nachtrockenpartie gestattet die Herstellung von fett- und öldichten, recyclebaren Papieren, die zudem infolge der anteiligen Verwendung einer anionischen Poly ester-Polyurethan-Dispersion und einer hydrophobierten Fällungskieselsäure einen sehr hohen Durchdringungswider stand gegen wässrige Medien besitzen.The use of this impregnation medium for the impregnation of paper within the paper machine with one of the known application methods and subsequent drying in the after-dryer section allows the production of grease and oil-tight, recyclable papers, which are also due to the proportionate use of an anionic polyester-polyurethane dispersion and hydrophobic precipitated silica have a very high penetration resistance against aqueous media.
Die Erfindung soll nachstehend an Beispiel 1 erläutert werden, das Beispiel 2 dient dem Vergleich mit dem Stand der Technik.
Die am fertigen Papier ermittelten maßgeblichen Prüfer¬ gebnisse sind aus der Tabelle 1 ersichtlich. Die in den Beispielen 1 und 2 beschriebenen Imprägniermedien werden mit einer Leimpresse in einer Papiermaschiene auf unge- leimtes Rohpapier mit einem Mahlgrad des Stoffes von 40 bis 42 SR, einem Flächengewicht von 50 g/m und bei einer Geschwindigkeit von 350 m/min beidseitig aufgetragen und sofort anschließend in der Nachtrockenpartie getrocknet. Das Auftragsgewicht beträgt ca. 1,2 g/m auf jeder Seite des Papiers.The invention will be explained below using example 1, example 2 serves for comparison with the prior art. The relevant test results determined on the finished paper are shown in Table 1. The impregnation media described in Examples 1 and 2 are applied to both sides using a size press in a paper machine on unsized base paper with a freeness of 40 to 42 SR, a basis weight of 50 g / m and a speed of 350 m / min and then immediately dried in the after-dryer section. The application weight is approximately 1.2 g / m on each side of the paper.
Beispiel 1 Beispiel 2Example 1 Example 2
(erfindungs- (Stand der gemäß) Technik)(Invention (state of the art) technology)
Polyvinylalkohollösung 6000,00 1 6000,00 1 mit ca. 3 % Feststoff oderPolyvinyl alcohol solution 6000.00 1 6000.00 1 with approx. 3% solid or
Stärkelösung 6000,00 1 oder Pflanzenschleimlösung 6000,00 1Starch solution 6000.00 1 or plant gum solution 6000.00 1
Polyester-Polyurethan-dis- 37,50 1 persion m.ca.40% FeststoffPolyester-polyurethane-dis- 37.50 1 persion with approx. 40% solid
Methanol 100,00 1Methanol 100.00 1
hydrophobierte Kieselsäure 35,00 kghydrophobic silica 35.00 kg
Alkylketendimerdispersion 140,00 1 140,00 1 mit ca. 11 % Feststoff oderAlkyl ketene dimer dispersion 140.00 1 140.00 1 with approx. 11% solid or
Copolymerisat aus Styrol- und 140,00 1 Butylacrylat m.ca.20% Feststoff
- 5 -Copolymer of styrene and 140.00 1 butyl acrylate with approx. 20% solid - 5 -
Beispiel 1 Beispiel 2Example 1 Example 2
Perfluoralkylethylphosphat- 120,00 1 120,00 1 Diethanolammoniumsalz in Isopro- pylalkohol m. ca. 33 % Feststoff Glyoxal 30,00 1 30,00 1Perfluoroalkyl ethyl phosphate 120.00 1 120.00 1 diethanolammonium salt in isopropyl alcohol m. approx. 33% solid glyoxal 30.00 1 30.00 1
Tabelle 1 - Prüfergebnisse am Papier - GegenüberstellungTable 1 - Test results on paper - comparison
Beispiel 1 Beispiel 2 (erfindungs¬ (Stand der gemäß) Technik)Example 1 Example 2 (Invention (State of the Art))
Stoffmahlgrad: in SR 41,00 42,00 Flächengewicht: in g/m 50,30 51,00 Auftragsgewicht: in g/m 1,22 1,18 Feuchtegehalt: in % 5,80 5,90Fabric grinding degree: in SR 41.00 42.00 basis weight: in g / m 50.30 51.00 application weight: in g / m 1.22 1.18 moisture content: in% 5.80 5.90
Fettdichte nach Tappi 454: (sec.) überlδOO über 1800 Widerstand gegen Wasserdurch¬ dringung nach ISO 5633: 2 Tage zwischen 6 in Tagen bzw. Std. und 24,00 Std Recyclebarkeit (Zeitdauer bis zur vollständigen Zerfaserung im Laboraufschläger): in min. 20,00 18,00 Naßreißkraft: in N 18,00 16,00Fat density according to Tappi 454: (sec.) Over 1800 resistance to water penetration according to ISO 5633: 2 days between 6 in days or hours and 24.00 hours recyclability (time until complete defibration in the laboratory server): in min. 20.00 18.00 Wet tensile strength: in N 18.00 16.00
Wasseraunahme nach Cobb in 5 min: in g/m 22,00 29,00Water intake according to Cobb in 5 min: in g / m 22.00 29.00
Beim Vergleich der maßgeblichen Papierprüfwerte der Ta¬ belle 1 läßt sich feststellen, daß sich infolge der zu¬ sätzlichen Verwendung von hydrophobierter Fällungskiesel¬ säure und von einer anionischen Polyester-Polyurethan- Dispersion gegenüber dem Stand der Technik erhebliche Verbesserungen im Durchdringungswiderstand des Papieres gegen Wasser ergeben.
A comparison of the relevant paper test values in Table 1 shows that the additional use of hydrophobicized precipitated silica and an anionic polyester-polyurethane dispersion compared to the prior art results in considerable improvements in the penetration resistance of the paper against water .
Claims
1. Imprägniermittel zur Fett- und Wasserdichtausrüstung von Papieren, dadurch gekennzeichnet, daß es aus einer 2 bis 6 % konzentrierten Polyvinylalkohollösung, vor¬ zugsweise 3 % konzentriert, 3 bis 10 Volumenprozent bezogen auf die Polyvinylalkohollösung, vorzugsweise 6 %, einer anionischen aliphatisch-aromatischen Poly¬ ester-Polyurethan-Dispersion des Molmassebereiches 10.000 bis 30.000 und einer Konzentration von 40 %,1. Impregnating agent for grease and waterproofing of papers, characterized in that it consists of a 2 to 6% concentrated polyvinyl alcohol solution, preferably 3% concentrated, 3 to 10 volume percent based on the polyvinyl alcohol solution, preferably 6%, of an anionic aliphatic-aromatic Polyester-polyurethane dispersion with a molecular weight of 10,000 to 30,000 and a concentration of 40%,
5 bis 20 Masseprozent hydrophobierter Fällungskiesel¬ säure bezogen auf Polyvinylalkohol , 1 bis 3 Volumen¬ prozent bezogen auf die Polyvinylalkohollösung, vor¬ zugsweise 2 %, anionischer Alkylketendimer-Dispersion mit einer Konzentration von 11 % und einer Teilchen¬ größe von 0,2 bis 0,9 Mikron, 0,5 bis 3 Volumenprozent bezogen auf die Polyvinylalkohollösung, vorzugsweise 2 % einer anionischen Perfluoralkylethylphosphat- Diethanolammoniumsalzlösung in Isopropylalkohol mit einer Konzentration von 33 %, 0,2 bis 1 Volumenprozent bezogen auf Polyvinylalkohollösung, vorzugsweise 0,5 %, Glyoxal besteht.5 to 20 percent by weight of hydrophobicized precipitated silica based on polyvinyl alcohol, 1 to 3 percent by volume based on the polyvinyl alcohol solution, preferably 2%, anionic alkyl ketene dimer dispersion with a concentration of 11% and a particle size of 0.2 to 0 , 9 microns, 0.5 to 3 volume percent based on the polyvinyl alcohol solution, preferably 2% of an anionic perfluoroalkylethylphosphate-diethanolammonium salt solution in isopropyl alcohol with a concentration of 33%, 0.2 to 1 volume percent based on polyvinyl alcohol solution, preferably 0.5%, glyoxal .
2. Verfahren zur Herstellung des Imprägniermediums nach Anspruch 1, dadurch gekennzeichnet, daß die hydrophobierte Kieselsäure in Methanol angeteigt wird, dieser Anteigung die Alkylketendimer-Dispersion zugesetz wird und dieses Gemisch der Polyvinylalkohol¬ lösung zugesetzt wird. 2. A process for the preparation of the impregnating medium according to claim 1, characterized in that the hydrophobized silica is pasted in methanol, this pasting is added to the alkyl ketene dimer dispersion and this mixture is added to the polyvinyl alcohol solution.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU49416/93A AU4941693A (en) | 1992-08-17 | 1993-08-12 | Impregnating agent for producing papers with high resistance to the penetration of grease, oil and aqueous media |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19924227184 DE4227184C2 (en) | 1992-08-17 | 1992-08-17 | Impregnation agent for the production of papers with high penetration resistance against fats, oils and aqueous media and process for its production |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994004753A1 true WO1994004753A1 (en) | 1994-03-03 |
Family
ID=6465721
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1993/000724 WO1994004753A1 (en) | 1992-08-17 | 1993-08-12 | Impregnating agent for producing papers with high resistance to the penetration of grease, oil and aqueous media |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU4941693A (en) |
DE (1) | DE4227184C2 (en) |
WO (1) | WO1994004753A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0683267A3 (en) * | 1994-05-18 | 1996-07-03 | Minnesota Mining & Mfg | Fluorine-containing phosphates, and their use in papermaking. |
WO2003031720A1 (en) * | 2001-10-09 | 2003-04-17 | Tetra Laval Holdings & Finance S.A. | A laminated packaging material, a method of producing the same, as well as a packaging container produced from the packaging material |
CN102926290A (en) * | 2012-11-01 | 2013-02-13 | 福建希源纸业有限公司 | Transfer printing paper product and manufacturing method thereof |
CN104018393A (en) * | 2014-06-12 | 2014-09-03 | 苏州经贸职业技术学院 | Macromolecule sizing agent and preparation method thereof |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4407878C2 (en) * | 1994-03-09 | 1996-07-04 | Bernhard Dettling | Aroma and vapor barrier coated paper or cardboard |
ATE162866T1 (en) | 1995-09-08 | 1998-02-15 | Bernhard Dettling | METHOD FOR COATING PAPER OR CARDBOARD |
BR0011744A (en) * | 1999-06-11 | 2002-11-26 | Unidur Gmbh | Composition for impregnating paper, method for producing it, impregnated and laminated paper comprising said impregnated paper |
ITFI20120031A1 (en) * | 2012-02-21 | 2013-08-22 | Francesco Toschi | WATERPROOF COUPLED FOR FOOD USE |
DE102012206832A1 (en) * | 2012-04-25 | 2013-10-31 | Kuraray Europe Gmbh | Polyvinyl alcohols as a mineral oil barrier in paper and cardboard |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD290106A7 (en) * | 1985-11-06 | 1991-05-23 | Vereinigte Papier- U. Kartonfabriken Niederschlema,Werk Faehrbruecke,De | METHOD FOR PRODUCING MINERALOELIMPEGRATED LOCHBAND PAPER |
GB2241966A (en) * | 1990-03-15 | 1991-09-18 | Nacional Moneda Timbre | Process for the manufacture of paper |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3545195A1 (en) * | 1985-12-20 | 1987-06-25 | Hoechst Ag | ISOCYANATE-FREE POLYURETHANE DISPERSIONS |
DE3920379A1 (en) * | 1989-06-22 | 1991-01-03 | Heinr Aug Schoeller Soehne Gmb | METHOD FOR TREATING THE SURFACE OF A NATURAL PAPER |
GB8920456D0 (en) * | 1989-09-11 | 1989-10-25 | Albright & Wilson | Active sizing compositions |
DE4001237A1 (en) * | 1990-01-18 | 1991-07-25 | Basf Ag | STABILIZED AQUEOUS ALKYLDICETE EMULSIONS |
EP0462063A1 (en) * | 1990-06-13 | 1991-12-18 | Ciba-Geigy Ag | Fluorinated paper sizes |
-
1992
- 1992-08-17 DE DE19924227184 patent/DE4227184C2/en not_active Expired - Fee Related
-
1993
- 1993-08-12 WO PCT/DE1993/000724 patent/WO1994004753A1/en active Application Filing
- 1993-08-12 AU AU49416/93A patent/AU4941693A/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD290106A7 (en) * | 1985-11-06 | 1991-05-23 | Vereinigte Papier- U. Kartonfabriken Niederschlema,Werk Faehrbruecke,De | METHOD FOR PRODUCING MINERALOELIMPEGRATED LOCHBAND PAPER |
GB2241966A (en) * | 1990-03-15 | 1991-09-18 | Nacional Moneda Timbre | Process for the manufacture of paper |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0683267A3 (en) * | 1994-05-18 | 1996-07-03 | Minnesota Mining & Mfg | Fluorine-containing phosphates, and their use in papermaking. |
US5714266A (en) * | 1994-05-18 | 1998-02-03 | Minnesota Mining And Manufacturing Company | Fluorine-containing phosphates |
WO2003031720A1 (en) * | 2001-10-09 | 2003-04-17 | Tetra Laval Holdings & Finance S.A. | A laminated packaging material, a method of producing the same, as well as a packaging container produced from the packaging material |
CN100362164C (en) * | 2001-10-09 | 2008-01-16 | 利乐拉瓦尔集团及财务有限公司 | A laminated packaging material, a method of producing the same, as well as a packaging container produced from the packaging material |
US7482055B2 (en) | 2001-10-09 | 2009-01-27 | Tetra Laval Holdings & Finance S.A. | Laminated packaging material, a method of producing the same, as well as a packaging container produced from the packaging material |
CN102926290A (en) * | 2012-11-01 | 2013-02-13 | 福建希源纸业有限公司 | Transfer printing paper product and manufacturing method thereof |
CN104018393A (en) * | 2014-06-12 | 2014-09-03 | 苏州经贸职业技术学院 | Macromolecule sizing agent and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
DE4227184A1 (en) | 1994-02-24 |
AU4941693A (en) | 1994-03-15 |
DE4227184C2 (en) | 1997-09-25 |
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