US3783297A - X-ray image intensifier input phosphor screen and method of manufacture thereof - Google Patents

X-ray image intensifier input phosphor screen and method of manufacture thereof Download PDF

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US3783297A
US3783297A US00254065A US3783297DA US3783297A US 3783297 A US3783297 A US 3783297A US 00254065 A US00254065 A US 00254065A US 3783297D A US3783297D A US 3783297DA US 3783297 A US3783297 A US 3783297A
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ray image
image intensifier
set forth
phosphor screen
screen set
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J Houston
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General Electric Co
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General Electric Co
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J29/00Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
    • H01J29/02Electrodes; Screens; Mounting, supporting, spacing or insulating thereof
    • H01J29/10Screens on or from which an image or pattern is formed, picked up, converted or stored
    • H01J29/36Photoelectric screens; Charge-storage screens
    • H01J29/38Photoelectric screens; Charge-storage screens not using charge storage, e.g. photo-emissive screen, extended cathode
    • H01J29/385Photocathodes comprising a layer which modified the wave length of impinging radiation

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  • ABSTRACT A waffle-like light-reflective surface on a substrate member has slightly protruding ribs of the waffle pattern coated with a light-absorbing material.
  • the ribs absorb low-angle rearward traveling light photons generated in a transparent phosphor layer formed on the waffle surface and thereby, reduce degradation of x-ray image resolution and contrast whereas the floor of the waffle pattern reflects the light photons traveling rearward more normal to the floor surface, back through the phosphor layer to the photocathode of the x-ray image intensifier tube.
  • the method of fabricating the phosphor screen includes the intermediate step of forming a rubber replica of a metal master of the waffle surface from which a silicone resin replica is developed. The silicone resin replica is metal coated to provide the light reflective surface and the ribs are blackened to be light-absorbing.
  • the x-ray image intensifier tube is especially useful in the medical field for obtaining brighter x-ray images, particularly the images of body organs which generally are of low contrast.
  • Conventional x-ray image intensifiers employ in the input end thereof a uniform layer of a dense high atomic number'phosphor for absorbing the incident x-rays which have traversed through a patients body.
  • the x-ray photon is absorbed in the phosphor layer and light photons in the order of 1,000 light photons for each x-ray photon are'generated in the phosphor layer and emitted in all directions from the point of x-ray photon absorption.
  • a thin photoemitting "coating deposited on the surfaceo f the phosphor layer emits photoelectrons in response to light photons incident thereon.
  • the photoelectrons are accelerated and electron-optically focussed onto a second phosphor screen at the output end of theimageintensifier resulting in a brighter image than I at the input phosphor screen.
  • I t I The thickness of the phosphor layer.
  • Another object of my invention is to provide a rela-' tively thick input phosphor screen with means to substantially reduce degradation of resolution and contrast due to low-angle, rearward light scattering in the phos phor and the methodof manufacture thereof.
  • a further object of my invention is to provide a low cost fabrication process for manufacturing the improved input phosphor screen.
  • an x-ray image intensifier input phosphor screen wherein a phosphor layer is deposited on a waffle-like light-reflective surface of a substrate member wherein slightly protruding ribs of the waffle-pattern are coated with a light-absorbing material.
  • the rib height is much less than the phosphor layer thickness and the projected area of the ribs is much less than the area of the floor portion of the waffle pattern.
  • the other side of the substrate member is bonded to the x-ray image intensifier tube face plate which may be formed of glass or a low atomic number metal such as aluminum.
  • the substrate member spaced from the substrate member, is smooth and subthe photoemitter material while the slightly protruding ribs absorb the low angle-(more nearly lateral) portion of the rearward traveling light photons to thereby substantially reduce degradation of the image resolution and contrast due to low-angle rearward scattering of light in the phosphor layer.
  • My x-ray image intensifier input phosphor screen is.
  • A' sheet of metal mesh is formed by photoetching a thin metal sheet to produce an array of small holes therethrough wherein the hole width is much greater than the width of the walls separating adjacent holes.
  • the photoetched sheet is then diffusionbonded to aheavy planar metal sub strate to thereby obtain a wafile Iike surface wherein the slightly protruding wall projections definethe ribs of the waffle pattern.
  • This metal substrate having a waff le-like surface is usedas a master from which silicone rubber replicas are made.
  • Eachsilicone rubber replica has the rib indentation surface thereof coated with a silicone resin and such coated surfaceis drawn toward the concave side of the ,x-ray image intensifier face plate.
  • the silicone rubber replica Upon hardening of the silicone resin, the silicone rubber replica is removed, and "the concave-shaped resin structure has the rib-like projections of the metal master and is adhered to the face plate.
  • the waffle surface of the resin replica is then coated with a lightreflective material such as aluminum, and a black lightabs orbing material is deposited only on the ribs of the waffle surface;
  • a layerof transparent phosphor material is then deposited on the waffle-surface of thickness I much greater than the ribheightand forms a smooth outer surface upon which athin uniform coating of a photoemitter material is deposited to form the photocathode of the x-ray image intensifier tube.
  • FIG. 1a is an elevation sectional view of a conven tional x-ray image intensifier tube
  • FIGS. 1b and 1c are elevation sectional views of two 7 conventional phosphor screens utilized in FIG. la, but
  • FIG. 3 is an elevation sectional view of the photoetched metal sheet shown in FIGS. 2a, 2b bonded to the metallic substrate, but to a larger scale;
  • FIG. 4 is an elevation sectional view, to the same scale as FIG. la, ofa silicone rubber replica of the master illustrated partially in FIG. 3, retained on the x-ray image intensifier tube face plate, and a silicone resin coating on the rubber replica;
  • FIG. 5 is an elevation sectional view of the silicone resin replica subsequently formed on the face plate in FIG. 4, and also shows a light-reflective material coated on a first part of the resin replica, and the silicone rubber replica being peeled from the resin replica;
  • FIG. 6 is an elevation sectional view, to the same scale as FIGS. 1a, 4, 5 of a first means for coating the ribs of the resin replica with a light-absorbing material;
  • FIG. 7 is an elevation sectional view, to the same scale as FIG. lb, 16 after phosphor and photoemitter coatings are deposited on the coated resin replica;
  • FIG. 8 is an elevation sectional view of a second means for obtaining the light-absorbing ribs.
  • FIG. 9 is an elevation sectional view of a third means for obtaining the light-absorbing ribs.
  • a conventional x-ray image intensifier tube comprised of a glass envelope 10 having an input end (face plate) 10a which has a uniform phosphor layer 11 of thickness in the range of 0.005 to 0.012 inch deposited on the inner surface thereof.
  • the phosphor may be zinc cadmium sulfide or cesium iodide as typical materials onto which a thin film 12 of photoemitter material is deposited of thickness of approximately 100 Angstroms.
  • the photoelectrons emitted by the photoemitter coating 12 are focussed by electrode 13a maintained at a potential of several hundred volts and are accelerated to approximately 25 kilovolts by means of electrode 13b (connected to a suitable DC voltage source) at the output end of the image intensifier tube, the electrodes being suitably shaped to provide electron-optical focussing of the accelerated photoelectrons onto a second uniform phosphor screen (layer) 14 deposited on the inner surface of the glass envelope at the output end 10b thereof.
  • the image appearing on the second phosphor screen 14 is a brighter version of the image on the first phosphor screen 11 and can be viewed directly by the physician or be subjected to further processing.
  • the thickness of the input phosphor screen 11 in conventional x-ray image intensifier tubes is a compromise between a thick screen for high x-ray absorption and thin screen for high resolution which is determined primarily by lateral and low-angle rearward light scatter in the phosphor.
  • FIG. 1b illustrates a first approach conventionally utilized for obtaining improved performance from the input phosphor screen.
  • the inner surface of face plate 10a is coated with a suitable material to provide a light-reflective surface 16 to all of the rearward traveling light photons in the phosphor layer and thereby deliver more light to the photoemitter layer 12.
  • the low angle portion of the rearward directed light photons deliver (scattered) light to the photoemitter layer 12 which degrades image resolution and local image contrast. This degradation of image resolution and contrast due to lowangle rearward light scatter is avoided by a second approach illustrated in FIG.
  • My invention provides a new and improved high resolution x-ray image intensifier input phosphor screen which is adapted to absorb only the low-angle portion of the rearward traveling light photons while reflecting the high-angle (more nearly normal to the surface) portion thereof to thereby deliver more useful light to the photoemitter layer (i.e., improve sensitivity) without any substantial loss in resolution.
  • These desirable characteristics are obtained by the use of a waffle-like surface formed on the inner surface of the face plate wherein the floor portions of the waffle pattern are light-reflective to the high-angle portion of the rearward traveling light photons in the phosphor layer, and slightly protruding ribs of the waffle pattern are lightabsorbing to the low-angle'portion thereof.
  • My invention thus permits the use of a thicker phosphor screen for achieving higher x-ray absorption with substantially less attendant degradation of resolution and local contrast than is obtained in conventional image intensifiers, or a phosphor screen of conventional thickness but with a significantly higher resolution and local contrast.
  • the waffle-like surface is readily achieved by fabrication processes to be described hereinafter.
  • the fabrication process is initiated by selecting a sheet of metal suitable for photoetching such as nickel or stainless steel in the order of l to 2 mils thick.
  • An identical pattern (array) of holes is then photoetched through the metal sheet, the etched holes in the metal mesh sheet preferably having a square or hexagonal shape as illustrated in FIGS. 2a and 217, respectively,
  • the holes are of equal size and equally spaced from each other and form an array of identical rows and columns of holes to maximize the hole area in the mesh.
  • Other shape holes, such as triangular or circular could be used, however, such shaped holes produce less open area in the mesh.
  • the sheet 30 of metal mesh is positioned on a heavy planar substrate 31 of the same metal as the mesh and is subsequently diffusion bonded thereto.
  • the approximately 1 to 2 mil thick metal mesh 30 is diffusion bonded by bolting the photoetched sheet between two massive planes of metal, the upper one of which is thinly coated with an oxide such as MgO to prevent sticking, and this assembly is heated to a suitable temperature (e.g., approximately l,O00C when bonding nickel or stainless steel) in a hydrogen atmosphere or vacuum to accomplish the diffusion bonding.
  • a suitable temperature e.g., approximately l,O00C when bonding nickel or stainless steel
  • the slightly projecting walls 32, 33, 34 from the surface of substrate 31 are rectangular in the section taken vertically through the projecting walls although it should be obvious that the ribs may be rounded off at the top in some applications.
  • the wall projections will hereinafter be referred to as the ribs of the waffle surface to indicate the relatively small protrusion thereof, the floor portion of the waffle surface having an area relative to the projected area of the rib portion in the ratio of 2 to l or greater and being in accordance with the above-described hole spacing and hole separation in the etched metal sheet. Even more important is the rib height-to-spacing ratio which determines the cut-off point for the low-angle rearward light radiation absorption, and is approximately 1 to 4 for a cutoff angle of 14".
  • the diffusion bonding step results in a master substrate structure provided with a plurality of identical ribs wherein FIG. 2a or FIG. 2b represent the top view of the waffle surface shown in elevation sectional view in FIG. 3.
  • the ribs 32, 33, 34 of the waffle surface can be thinned to less than 1 mil thickness by a chemical etching process if a larger ratio of floor portion to rib area is required by the particular application.
  • the master substrate structure can be formed by directly photoetching the heavy planar substrate 31 to obtain the desired waffle surface, i.e., without using any additional metal sheet 30.
  • a phosphor material could be deposited on the waffle-like surface of the metal master structure in FIG. 3 to form a phosphor screen, however, the process hereinabove described is relatively expensive and in accordance with my invention, I fabricate many inexpensive silicone resin replicas of such original master whereby the cost per x-ray intensifier tube will be small. Also, at some stage in the process it is necessary to sag the planar surface of substrate 31, that is, to obtain it in a concave-shape conforming to the shape of the face plate 100 of the image intensifier tube.
  • the silicone rubber replica is fabricated by vacuum impregnation wherein the master is covered with a layer of liquid silicone rubber (e.g., General Electric RTV-l l) to which a small amount of a suitable curing catalyst has been added.
  • the coated master is then placedin a vacuum chamber for a few minutes in order to pump away all air bubbles and insure that the silicone rubber contacts all the crevices of the master.
  • the rubber is then allowed to cure for an appropriate period, e.g., 24 hours, in order to form an elastic, rubbery solid.
  • the silicone rubber replica is approximately 50 mils thick in order to remain somewhat flexible so that it can be subsequently easily removed by peeling from the silicone resin replica to be described hereinafter.
  • the rib-indented side a of the silicone rubber replica 45 is substantially uniformly coated with a silicone resin 46.
  • the face plate 10a of the image intensifier tube is then placed over the rubber replica 45, positioned in its proper orientation, and the two margins 45b, c along the rib-indented side 45a of the rubber replica are suitably retained against corresponding planar margins of the concave face plate 10a.
  • the entire assembly is then placed within a chamber wherein a vacuum is drawn between the rubber replica toward the concave face plate (as shown in part) to produce a silicone resin replica 46 of the FIG. 3 master waffle-like surface except that the resin replica 46 is curved into the concave shape of the image intensifier tube face plate 10a rather than being planar.
  • the resin-coated rubber replica and face plate assembly is then baked at approximately 250C to harden the silicone resin.
  • the silicone rubber replica 45 Upon hardening of the silicone resin, the silicone rubber replica 45 is removed therefrom by peeling it from the resin replica 46 as shown in FIG. 5, and the resin replica and face plate assembly is additionally air baked and then vacuum baked to outgas and cure the silicone resin.
  • the rubber replica may be reused to form additional resin replicas.
  • a possible problem may occur in peeling the rubber replica off the silicone resin replica if the two replicas tend to stick together. This sticking effect can be minimized, if it occurs, by treating the surface of the rubber replica with a parting agent such as a thin film of silicone oil.
  • the face plate 10a is fabricated of glass or a low atomic number metal such as aluminum.
  • the thickness of the floor portion of the resin replica is not critical and is generally in a range of 0 to 3 mils.
  • the whole waffle surface is then coated with a light-reflective material such as evaporated aluminum to obtain a relatively highly lightreflective surface 50.
  • the light-reflective coating is of thickness in the range of to 2,000 Angstroms and typically may be in the order of 1,000 A.
  • only the floor portions of the waffle surface are coated with the light-reflective material, and the ribs are incidentally and only partially coated in the process of coating the floor portions.
  • FIG. 6 illustrates a first means for accomplishing the rib-blackening process wherein the face plate 10a is supported and rotated relatively rapidly about a central vertical axis by means of rotatable vertical shaft 60 while an evaporation source 61 of suitable black matter retained in a suitable container 62 slowly pivots about the center of curvature of face plate 10a by means of pivot arm 63.
  • Container 62 is an open-ended hollowchamber connected to the free end of pivot arm 63.
  • container 62 is not critical but requires a suitable opening for the black matter to be emitted at the desired low angle.
  • Container 62 is oriented relative to the surface generated by the ends of the ribs such that the angle at which the evaporated black matter exits from the open end of container 62 remains constant while pivot arm 63 swings back and forth diametrically across such surface in slightly spaced apart relationship therefrom.
  • the feature of obtaining blackening only on the rib projections and not on the floor portions of the waffle surface (which are light-reflecting) is accomplished by selection of a small enough angle of container 62 relative to the surface defined by the rib ends, as well as by the proper spacing of adjacent ribs for a particular height thereof. A change in any of such parameters can generally be compensated for by a change in the angle of container 62. Thus, a closer spacing of the ribs would generally require an increase in the angle of container 62 in order to obtain blackening of the entire surfaces of the ribs.
  • a suitable phosphor material is deposited on the waffle surface using conventional techniques to form a uniform phosphor layer 62 which extends beyond the ends of the rib projections of the silicone resin replica 46 to a thickness greater than twice the rib height.
  • the phosphor 65 can be any transparent phosphor such as evaporated cesium iodide (CsI).
  • Evaporation of the CsI from vertically above the resin replica 46 may result in the outer surface of the phosphor layer 65 having a slight undulating form due to the projecting ribs of the resin replica, however, such undulations are generally not so severe as to upset either the electron-optics or the formation, and, or surface resistivity of the photocathode (to be described hereinafter). If desired, or necessary, such undulations may be readily smoothed out.
  • the phosphor layer 61 is approximately 12 mils thick as one typical example, and obviously can be made thicker if higher x-ray absorption is desired.
  • a thin uniform coating of a suitable photoemitter material 70 is deposited on the smooth surface of the phosphor layer 65 during the evacuation of the image intensifier tube to form the photocathode of such image intensifier tube.
  • the photoemitter material may be of the common types known as -20 (a compound of antimony, cesium, sodium and potassium) or S-1 1 (a compound of cesium, antimony and oxygen) as two typical examples and is a very thin coating in the order of 100 Angstroms.
  • an isolating layer of transparent alumina may be deposited between the phosphor 65 and photoemitter 70 layers in order to isolate the alkali metal of the photoemitter material from the phosphor, however, such isolating layer is not essential to the successful operation of my input phosphor screen.
  • the rib projections of the silicone resin replica 46 extend in a normal direction through less than 50 percent of the phosphor layer 65 thickness, and as shown in FIG. 7, typically extend through approximately percent of the phosphor layer.
  • the effect of the relatively highly light-absorbing rib projections is to absorb the low angle (more nearly lateral) portion of the rearward traveling light photons to thereby substantially reduce degradation of image resolution and especially local image contrast due to such low-angle rearward scattering of light in the phosphor layer 65 while the relatively highly light-reflecting floor portions of the waffle surface reflect the high-angle (more nearly normal) portion to thereby deliver more useful light to photocathode 70 and hence increase the tube sensitivity.
  • the reflection and absorption of the rearward traveling light photons is depicted by the arrows in FIG. 7.
  • the metal master can be made with more sheets of the metal mesh to thereby obtain a silicone resin replica having rib projections of greater height whereby a thicker phosphor layer 65 can be utilized for increased x-ray absorption, and thus increased sensitivity, while still maintaining the height of the ribs at less than the prescribed one half of the phosphor layer thickness.
  • FIG. 8 illustrates a second means for obtaining the light-absorbing ribs.
  • a waffle-like surface is formed on the light-reflective surface (which can be the inner surface of an aluminum face plate 10a, or a light-reflective coating 50 on the inner surface of a nonreflective face plate) by fastening a preferably blackened metal screen to the lightreflec-tive surface.
  • Screen 80 may be woven, as illustrated, in the manner of a window screen, from approximately 1 mil wire and having a pitch of 5 to 10 mils, that is, the dimensions and spacing of the ribs can be made the same as in the first embodiment.
  • the screen 80 can be fabricated of aluminum or other low atomic number metal such as iron, titanium or nickel.
  • the metal screen 80 is fastened to the light-reflective surface by a conventional process appropriate to the particular metals involved, and as one typical example, can be adhesively bonded thereto by means of a silicone resin.
  • an unblackened metal screen can be first fastened to the light-reflective surface, and the screen then blackened by oblique evaporation of the black material as in the first embodiment shown in FIG. 6.
  • the blackened metal screen besides absorbing lowangle rearward traveling light photons in the phosphor layer 65, also aids in holding the evaporated phosphor layer on the light-reflecting substrate face plate 10a while the reflective surface reflects the high-angle rearward traveling light photons.
  • FIG. 9 illustrates a third means for obtaining the light-absorbing ribs.
  • the inner surface of the face plate 10a is etched to produce the illustrated jagged, irregular (waffle) surface 90.
  • the size of the irregularity need not be large, and can be as small as a fraction of a mil, peak-to-peak. If the face plate 10a is aluminum, the light-absorbing ribs are completed by oblique evaporation of the black material on the peaks 91 of the irregularities as in FIG. 6.
  • the face plate is glass or another nonreflective material
  • a coating of a light-reflective material such as aluminum is deposited on the irregular surface prior to the oblique evaporation of the black material on the peaksv
  • the blackened peaks absorb the low-angle rearward traveling light photons while the unblackened portions of the irregularities reflect the high-angle rearward traveling light photons.
  • my invention attains the objectives set forth and makes available a new and improved x-ray image intensifier tube which has an input phosphor screen that simultaneously achieves both high x-ray absorption and thus high sensitivity) and high image resolution and contrast as well as providing methods of manufacturing such input phosphor screen.
  • the method of manufacturing the input phosphor screen is a low cost fabrication process due to the use of a silicone rubber replica which permits fabrication of many inexpensive silicone resin replicas of the original master in a first method of manufacture, the second and third described methods also being low cost.
  • the light-absorbing ribs of the waffle surface which are an important aspect of my invention, can be adjusted as to the height-to-spacing ratio thereof in the formation of the ribs and whereby the cut-off point for the low-angle rearward light radiation can be set at any desired angle. As a typical range, it would generally be desired to absorb the light photons which travel rearward at anglesup to approximately 15 from the plane in the phosphor layer parallel to the face plate, and containing the point at which an incident x-ray photon generates the light photons.
  • fle surface provides an input phosphor screen which avoids the compromise in conventional x-ray image intensifier tubes between high x-ray absorption and high image resolution Having described three specific embodiments of my waffle surface, it will be apparent to those skilled in the art that such waffle-like surface which constitutes the essence of my invention may take other forms than that specifically illustrated and described above, and the ribs may be blackened by other methods. Also, the support for the input phosphor screen, herein described as the face plate, may be slightly spaced from the input window of the tube glass envelope. Thus, it is to be understood that changes may be made in the particular embodiment of my invention as described which are within the full intended scope of the invention as defined by the appended claims.
  • An improved x-ray image intensifier input phosphor screen comprising a concave-shaped face plate forming a support for the input phosphor screen of an x-ray image intensifier tube and having a convex-shaped major outer side and a correspondingly concave-shaped major inner side,
  • a phosphor layer deposited on said waffle-like surface means and being of sufficient thickness to extend substantially beyond the outer ends of the riblike projections thereof and having a second surface concave-shaped and substantially parallel to the inner side of said face plate, and
  • the surface of the rib-like projections being relatively highly lightabsorbing and the surfaces of the floor portions being relatively highly light-reflective whereby the rib projections absorb the low-angle portion of rearward traveling light photons generated in the phosphor layer to thereby reduce degradation of image resolution and local image contrast due to the more lateral scattering of the light in the phosphor layer, and the floor portions reflect the highangle portion of the rearward traveling light photons to thereby deliver more useful light to the photoelectron emission means and obtain increased sensitivity.
  • said face plate is fabricated ofaluminum.
  • the x-ray image intensifier input phosphor screen phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means each being square shaped. 16. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means form equal size squares separated by equal size said riblike projections. 17. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means each being hexagon shaped. 18. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions form equal size hexagons separated by equal size said rib-like projections. 19. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein 1 1 12 the rib-like projections each extend outward in a 100 to 2,000 Angstroms.
  • the x-ray image intensifier input phosphor screen major Side f d f plata set fort n Claim 1 wherein 29.
  • the x-ray image intensifier input phosphor screen the floor portions each have a width dimension Set f th in claim 2 wherein greater than 4 milslo the blackened metal screen is woven of approxi- 22.
  • 23. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portion-to-rib projection area ratio is at least 2 to l.
  • 24. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections extend into the phosphor layer less than halfway therethrough.
  • the x-ray image intensifier input phosphor screen mately 1 mil wire.
  • the waffle-like surface means consists of the convexshaped major side of said face plate in etched form to produce a jagged, irregular surface, the peaks of the irregular surface forming the rib-like projections and being blackened to provide the lightabsorbing surface thereof.
  • tions of said substrate member is aluminum and is a llght'reflectlve matel'lal deposlted the "regular of thi k ess i th range f 500 to 5,000 A surface of the face plate prior to the peaks thereof str being blackened whereby the unblackened por- 27.
  • the x-ray image intensifier input phosphor screen tions of the surface irregularities form the lightset forth in claim 7 wherein reflective floor portions of the waffle-like surface the light-absorbing material coated on the rib projecmeans.
  • tions in carbon and is of thickness in the range of

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Abstract

A waffle-like light-reflective surface on a substrate member has slightly protruding ribs of the waffle pattern coated with a light-absorbing material. The ribs absorb low-angle rearward traveling light photons generated in a transparent phosphor layer formed on the waffle surface and thereby reduce degradation of xray image resolution and contrast whereas the floor of the waffle pattern reflects the light photons traveling rearward more normal to the floor surface, back through the phosphor layer to the photocathode of the x-ray image intensifier tube. The method of fabricating the phosphor screen includes the intermediate step of forming a rubber replica of a metal master of the waffle surface from which a silicone resin replica is developed. The silicone resin replica is metal coated to provide the light reflective surface and the ribs are blackened to be light-absorbing.

Description

United States Patent [191 Houston BZAC/(ZAVZW X-RAY IMAGE INTENSIFIER INPUT PHOSPHOR SCREEN AND METHOD OF MANUFACTURE THEREOF Inventor: John M. Houston, Schenectady,
General Electric Company, Schenectady, NY.
Filed: May 17, 1972 Appl. No.: 254,065
Assignee:
References Cited UNITED STATES PATENTS 9/1954 Hushley 250/80 X 4/ l 959 Vingerhoets 6/1971 Tinneym x. 250/80 PHOSPHOP PHOTUEZZ'CT/PGA/S 3,783,297 Jan. 1, 1974 [5 7] ABSTRACT A waffle-like light-reflective surface on a substrate member has slightly protruding ribs of the waffle pattern coated with a light-absorbing material. The ribs absorb low-angle rearward traveling light photons generated in a transparent phosphor layer formed on the waffle surface and thereby, reduce degradation of x-ray image resolution and contrast whereas the floor of the waffle pattern reflects the light photons traveling rearward more normal to the floor surface, back through the phosphor layer to the photocathode of the x-ray image intensifier tube. The method of fabricating the phosphor screen includes the intermediate step of forming a rubber replica of a metal master of the waffle surface from which a silicone resin replica is developed. The silicone resin replica is metal coated to provide the light reflective surface and the ribs are blackened to be light-absorbing.
32 Claims, 12 Drawing Figures FiS/IV #[PUCA 46 PATENTEDJAN H974 SHEET 1 OF 5 Qxi X-RAY IMAGE INTENS IFIER INPUT PHOSPHOR SCREEN AND METHODOF MANUFACTURE THEREOF i My invention relates to an x-ray image intensifier tube, and in particular, to the phosphor screen structure at the input end of the tube and method of manufacture thereof.
The x-ray image intensifier tube is especially useful in the medical field for obtaining brighter x-ray images, particularly the images of body organs which generally are of low contrast. Conventional x-ray image intensifiers employ in the input end thereof a uniform layer of a dense high atomic number'phosphor for absorbing the incident x-rays which have traversed through a patients body. The x-ray photon is absorbed in the phosphor layer and light photons in the order of 1,000 light photons for each x-ray photon are'generated in the phosphor layer and emitted in all directions from the point of x-ray photon absorption. A thin photoemitting "coating deposited on the surfaceo f the phosphor layer emits photoelectrons in response to light photons incident thereon. The photoelectrons are accelerated and electron-optically focussed onto a second phosphor screen at the output end of theimageintensifier resulting in a brighter image than I at the input phosphor screen. I t I The thickness of the phosphor layer. in conventional image intensifiers is typically 5 to 12 mils and is a compromise between ajthick layer necessary for high x-ray absorption and a thin layer necessaryfor high image resolution (a 12 mil thick layer yields a resolution of 40 to 50 line pairs per inch), resolution and local imag e contrast being degradeddueto lateral and rearward light scattering within the phosphor layer. Obviously, it'
would be highly desirable to'reduce degradation of resolution and contrast due to lateral lightscattering, and in particular that due to the low-angle rearward light scattering and thereby obtain increased resolution and contrast with a conventionalthickness' phosphor layer in the input end of the x-ray image intensifier tube, or al sl a yflt mp oy a thicksnph phdrlayer to thereby increase the x-ray absorption (and thus the sensitivity) with less loss in .resolution and local contrast than occurs in conventional imageintensifiers.
' Therefore,.one of the principal objects of my invention is to provide a new and improved x-ray image intensifier tube havingan input phosphor screen which simultaneously can achieve both high x-ray absorption and high image resolution and contrast, and the method of manufacture thereof. I
Another object of my invention is to provide a rela-' tively thick input phosphor screen with means to substantially reduce degradation of resolution and contrast due to low-angle, rearward light scattering in the phos phor and the methodof manufacture thereof.
A further object of my invention is to provide a low cost fabrication process for manufacturing the improved input phosphor screen.
Briefly stated, and in accordance with my invention, 1 provide, an x-ray image intensifier input phosphor screen wherein a phosphor layer is deposited on a waffle-like light-reflective surface of a substrate member wherein slightly protruding ribs of the waffle-pattern are coated with a light-absorbing material. The rib height is much less than the phosphor layer thickness and the projected area of the ribs is much less than the area of the floor portion of the waffle pattern. The other side of the substrate member is bonded to the x-ray image intensifier tube face plate which may be formed of glass or a low atomic number metal such as aluminum. The outer surface of the phosphor layer,
spaced from the substrate member, is smooth and subthe photoemitter material while the slightly protruding ribs absorb the low angle-(more nearly lateral) portion of the rearward traveling light photons to thereby substantially reduce degradation of the image resolution and contrast due to low-angle rearward scattering of light in the phosphor layer.
My x-ray image intensifier input phosphor screen is.
fabricated by the following method. A' sheet of metal mesh is formed by photoetching a thin metal sheet to produce an array of small holes therethrough wherein the hole width is much greater than the width of the walls separating adjacent holes. The photoetched sheet is then diffusionbonded to aheavy planar metal sub strate to thereby obtain a wafile Iike surface wherein the slightly protruding wall projections definethe ribs of the waffle pattern. This metal substrate having a waff le-like surface is usedas a master from which silicone rubber replicas are made. Eachsilicone rubber replica has the rib indentation surface thereof coated with a silicone resin and such coated surfaceis drawn toward the concave side of the ,x-ray image intensifier face plate. Upon hardening of the silicone resin, the silicone rubber replica is removed, and "the concave-shaped resin structure has the rib-like projections of the metal master and is adhered to the face plate. The waffle surface of the resin replica is then coated with a lightreflective material such as aluminum, and a black lightabs orbing material is deposited only on the ribs of the waffle surface; A layerof transparent phosphor material is then deposited on the waffle-surface of thickness I much greater than the ribheightand forms a smooth outer surface upon which athin uniform coating of a photoemitter material is deposited to form the photocathode of the x-ray image intensifier tube.
"The featureof my invention which I desire toprotect herein are pointed outwith particularity'in the tap pended claims. The invention itself, however, both as to its organization and method of operation together with further objects and advantages thereof may best be understood by reference to the following description taken in connection with the accompanying drawings wherein like partsin each of theseveral figures are identified by the same" reference character, and
wherein:
FIG. 1a is an elevation sectional view of a conven tional x-ray image intensifier tube;
FIGS. 1b and 1c are elevation sectional views of two 7 conventional phosphor screens utilized in FIG. la, but
form a waffle-like surface ona metallic substrate utilized in fabricating a master in accordance with my invention; t
FIG. 3 is an elevation sectional view of the photoetched metal sheet shown in FIGS. 2a, 2b bonded to the metallic substrate, but to a larger scale;
FIG. 4 is an elevation sectional view, to the same scale as FIG. la, ofa silicone rubber replica of the master illustrated partially in FIG. 3, retained on the x-ray image intensifier tube face plate, and a silicone resin coating on the rubber replica;
FIG. 5 is an elevation sectional view of the silicone resin replica subsequently formed on the face plate in FIG. 4, and also shows a light-reflective material coated on a first part of the resin replica, and the silicone rubber replica being peeled from the resin replica;
FIG. 6 is an elevation sectional view, to the same scale as FIGS. 1a, 4, 5 of a first means for coating the ribs of the resin replica with a light-absorbing material;
FIG. 7 is an elevation sectional view, to the same scale as FIG. lb, 16 after phosphor and photoemitter coatings are deposited on the coated resin replica;
FIG. 8 is an elevation sectional view of a second means for obtaining the light-absorbing ribs; and
FIG. 9 is an elevation sectional view of a third means for obtaining the light-absorbing ribs.
Referring now in particular to FIG. la, there is shown a conventional x-ray image intensifier tube comprised of a glass envelope 10 having an input end (face plate) 10a which has a uniform phosphor layer 11 of thickness in the range of 0.005 to 0.012 inch deposited on the inner surface thereof. The phosphor may be zinc cadmium sulfide or cesium iodide as typical materials onto which a thin film 12 of photoemitter material is deposited of thickness of approximately 100 Angstroms. The photoelectrons emitted by the photoemitter coating 12 are focussed by electrode 13a maintained at a potential of several hundred volts and are accelerated to approximately 25 kilovolts by means of electrode 13b (connected to a suitable DC voltage source) at the output end of the image intensifier tube, the electrodes being suitably shaped to provide electron-optical focussing of the accelerated photoelectrons onto a second uniform phosphor screen (layer) 14 deposited on the inner surface of the glass envelope at the output end 10b thereof. The image appearing on the second phosphor screen 14 is a brighter version of the image on the first phosphor screen 11 and can be viewed directly by the physician or be subjected to further processing. The paths of two photoelectrons between the photoemitter coating 12 and the second phosphor screen 14 are indicated by dashed line and arrowheads. As stated hereinabove, the thickness of the input phosphor screen 11 in conventional x-ray image intensifier tubes is a compromise between a thick screen for high x-ray absorption and thin screen for high resolution which is determined primarily by lateral and low-angle rearward light scatter in the phosphor.
FIG. 1b illustrates a first approach conventionally utilized for obtaining improved performance from the input phosphor screen. In this case, the inner surface of face plate 10a is coated with a suitable material to provide a light-reflective surface 16 to all of the rearward traveling light photons in the phosphor layer and thereby deliver more light to the photoemitter layer 12. However, as shown in FIG. lb, the low angle portion of the rearward directed light photons deliver (scattered) light to the photoemitter layer 12 which degrades image resolution and local image contrast. This degradation of image resolution and contrast due to lowangle rearward light scatter is avoided by a second approach illustrated in FIG. 1c wherein the face plate inner surface is coated with a suitable material to provide a light-absorbing surface 17 to all of the rearward traveling light photons. However, this second approach results in the loss of one half the light generated in the phosphor and thereby decreases the sensitivity by an equal amount.
My invention provides a new and improved high resolution x-ray image intensifier input phosphor screen which is adapted to absorb only the low-angle portion of the rearward traveling light photons while reflecting the high-angle (more nearly normal to the surface) portion thereof to thereby deliver more useful light to the photoemitter layer (i.e., improve sensitivity) without any substantial loss in resolution. These desirable characteristics are obtained by the use of a waffle-like surface formed on the inner surface of the face plate wherein the floor portions of the waffle pattern are light-reflective to the high-angle portion of the rearward traveling light photons in the phosphor layer, and slightly protruding ribs of the waffle pattern are lightabsorbing to the low-angle'portion thereof. My invention thus permits the use of a thicker phosphor screen for achieving higher x-ray absorption with substantially less attendant degradation of resolution and local contrast than is obtained in conventional image intensifiers, or a phosphor screen of conventional thickness but with a significantly higher resolution and local contrast. The waffle-like surface is readily achieved by fabrication processes to be described hereinafter.
The fabrication process is initiated by selecting a sheet of metal suitable for photoetching such as nickel or stainless steel in the order of l to 2 mils thick. An identical pattern (array) of holes is then photoetched through the metal sheet, the etched holes in the metal mesh sheet preferably having a square or hexagonal shape as illustrated in FIGS. 2a and 217, respectively,
with a typical center-to-center hole spacing of at least 4 mils and separation (wall thickness) of approximately I to 2 mils as indicated on the drawing. The holes are of equal size and equally spaced from each other and form an array of identical rows and columns of holes to maximize the hole area in the mesh. Other shape holes, such as triangular or circular could be used, however, such shaped holes produce less open area in the mesh.
Upon completion of the photoetching step, the sheet 30 of metal mesh is positioned on a heavy planar substrate 31 of the same metal as the mesh and is subsequently diffusion bonded thereto. The approximately 1 to 2 mil thick metal mesh 30 is diffusion bonded by bolting the photoetched sheet between two massive planes of metal, the upper one of which is thinly coated with an oxide such as MgO to prevent sticking, and this assembly is heated to a suitable temperature (e.g., approximately l,O00C when bonding nickel or stainless steel) in a hydrogen atmosphere or vacuum to accomplish the diffusion bonding. The diffusion bonding results in a waffle-like structure shown in FIG. 3 wherein the slightly projecting walls 32, 33, 34 from the surface of substrate 31 are rectangular in the section taken vertically through the projecting walls although it should be obvious that the ribs may be rounded off at the top in some applications. The wall projections will hereinafter be referred to as the ribs of the waffle surface to indicate the relatively small protrusion thereof, the floor portion of the waffle surface having an area relative to the projected area of the rib portion in the ratio of 2 to l or greater and being in accordance with the above-described hole spacing and hole separation in the etched metal sheet. Even more important is the rib height-to-spacing ratio which determines the cut-off point for the low-angle rearward light radiation absorption, and is approximately 1 to 4 for a cutoff angle of 14". Obviously, increasing the rib height-tospacing ratio will decrease the cut-off angle, resulting in greater absorption of the rearward traveling light photons and therefore less reflection thereof to the photoemitter layer. It is obvious that the diffusion bonding step results in a master substrate structure provided with a plurality of identical ribs wherein FIG. 2a or FIG. 2b represent the top view of the waffle surface shown in elevation sectional view in FIG. 3. The ribs 32, 33, 34 of the waffle surface can be thinned to less than 1 mil thickness by a chemical etching process if a larger ratio of floor portion to rib area is required by the particular application. Alternatively, the master substrate structure can be formed by directly photoetching the heavy planar substrate 31 to obtain the desired waffle surface, i.e., without using any additional metal sheet 30.
A phosphor material could be deposited on the waffle-like surface of the metal master structure in FIG. 3 to form a phosphor screen, however, the process hereinabove described is relatively expensive and in accordance with my invention, I fabricate many inexpensive silicone resin replicas of such original master whereby the cost per x-ray intensifier tube will be small. Also, at some stage in the process it is necessary to sag the planar surface of substrate 31, that is, to obtain it in a concave-shape conforming to the shape of the face plate 100 of the image intensifier tube.
In order to replicate the master illustrated in FIG. 3, i
an intermediate step of making one or more silicone rubber replicas is utilized. The silicone rubber replica is fabricated by vacuum impregnation wherein the master is covered with a layer of liquid silicone rubber (e.g., General Electric RTV-l l) to which a small amount of a suitable curing catalyst has been added. The coated master is then placedin a vacuum chamber for a few minutes in order to pump away all air bubbles and insure that the silicone rubber contacts all the crevices of the master. The rubber is then allowed to cure for an appropriate period, e.g., 24 hours, in order to form an elastic, rubbery solid. The silicone rubber replica is approximately 50 mils thick in order to remain somewhat flexible so that it can be subsequently easily removed by peeling from the silicone resin replica to be described hereinafter.
Referring now to FIG. 4, the rib-indented side a of the silicone rubber replica 45 is substantially uniformly coated with a silicone resin 46. The face plate 10a of the image intensifier tube is then placed over the rubber replica 45, positioned in its proper orientation, and the two margins 45b, c along the rib-indented side 45a of the rubber replica are suitably retained against corresponding planar margins of the concave face plate 10a. The entire assembly is then placed within a chamber wherein a vacuum is drawn between the rubber replica toward the concave face plate (as shown in part) to produce a silicone resin replica 46 of the FIG. 3 master waffle-like surface except that the resin replica 46 is curved into the concave shape of the image intensifier tube face plate 10a rather than being planar.
The resin-coated rubber replica and face plate assembly is then baked at approximately 250C to harden the silicone resin.
Upon hardening of the silicone resin, the silicone rubber replica 45 is removed therefrom by peeling it from the resin replica 46 as shown in FIG. 5, and the resin replica and face plate assembly is additionally air baked and then vacuum baked to outgas and cure the silicone resin. The rubber replica may be reused to form additional resin replicas. A possible problem may occur in peeling the rubber replica off the silicone resin replica if the two replicas tend to stick together. This sticking effect can be minimized, if it occurs, by treating the surface of the rubber replica with a parting agent such as a thin film of silicone oil. The face plate 10a is fabricated of glass or a low atomic number metal such as aluminum.
After the final silicone resin baking step, the resulting structure of the silicone resin replica 46 adhered to the concave side of the image intensifier face plate 10a as illustrated in FIG. 5 wherein the slight rib projections of the silicone resin replica 46 extend normal to the surface of face plate 10a: The thickness of the floor portion of the resin replica is not critical and is generally in a range of 0 to 3 mils. The whole waffle surface is then coated with a light-reflective material such as evaporated aluminum to obtain a relatively highly lightreflective surface 50. The light-reflective coating is of thickness in the range of to 2,000 Angstroms and typically may be in the order of 1,000 A. Alternatively, only the floor portions of the waffle surface are coated with the light-reflective material, and the ribs are incidentally and only partially coated in the process of coating the floor portions.
After the light-reflective material is deposited on the waffle surface, a relatively highly light-absorbing mate rial such as carbon is evaporated obliquely on the waffle surface substrate member so as to blacken only the protruding ribs thereof. FIG. 6 illustrates a first means for accomplishing the rib-blackening process wherein the face plate 10a is supported and rotated relatively rapidly about a central vertical axis by means of rotatable vertical shaft 60 while an evaporation source 61 of suitable black matter retained in a suitable container 62 slowly pivots about the center of curvature of face plate 10a by means of pivot arm 63. Container 62 is an open-ended hollowchamber connected to the free end of pivot arm 63. The shape of container 62 is not critical but requires a suitable opening for the black matter to be emitted at the desired low angle. Container 62 is oriented relative to the surface generated by the ends of the ribs such that the angle at which the evaporated black matter exits from the open end of container 62 remains constant while pivot arm 63 swings back and forth diametrically across such surface in slightly spaced apart relationship therefrom. By this process of source 61 pivoting slowly back and forth across the rotating waffle surface, all sides of the rib projections are thinly coated with the light-absorbing material to a thickness in the range of 100 to 2.,000 A. The feature of obtaining blackening only on the rib projections and not on the floor portions of the waffle surface (which are light-reflecting) is accomplished by selection of a small enough angle of container 62 relative to the surface defined by the rib ends, as well as by the proper spacing of adjacent ribs for a particular height thereof. A change in any of such parameters can generally be compensated for by a change in the angle of container 62. Thus, a closer spacing of the ribs would generally require an increase in the angle of container 62 in order to obtain blackening of the entire surfaces of the ribs.
After the ribs of the waffle surface have been made light-absorbing, a suitable phosphor material is deposited on the waffle surface using conventional techniques to form a uniform phosphor layer 62 which extends beyond the ends of the rib projections of the silicone resin replica 46 to a thickness greater than twice the rib height. The phosphor 65 can be any transparent phosphor such as evaporated cesium iodide (CsI). Evaporation of the CsI from vertically above the resin replica 46 may result in the outer surface of the phosphor layer 65 having a slight undulating form due to the projecting ribs of the resin replica, however, such undulations are generally not so severe as to upset either the electron-optics or the formation, and, or surface resistivity of the photocathode (to be described hereinafter). If desired, or necessary, such undulations may be readily smoothed out. The phosphor layer 61 is approximately 12 mils thick as one typical example, and obviously can be made thicker if higher x-ray absorption is desired.
Referring now to FIG. 7, a thin uniform coating of a suitable photoemitter material 70 is deposited on the smooth surface of the phosphor layer 65 during the evacuation of the image intensifier tube to form the photocathode of such image intensifier tube. The photoemitter material may be of the common types known as -20 (a compound of antimony, cesium, sodium and potassium) or S-1 1 (a compound of cesium, antimony and oxygen) as two typical examples and is a very thin coating in the order of 100 Angstroms. If desired, an isolating layer of transparent alumina, as one example, may be deposited between the phosphor 65 and photoemitter 70 layers in order to isolate the alkali metal of the photoemitter material from the phosphor, however, such isolating layer is not essential to the successful operation of my input phosphor screen.
The rib projections of the silicone resin replica 46 extend in a normal direction through less than 50 percent of the phosphor layer 65 thickness, and as shown in FIG. 7, typically extend through approximately percent of the phosphor layer. The effect of the relatively highly light-absorbing rib projections is to absorb the low angle (more nearly lateral) portion of the rearward traveling light photons to thereby substantially reduce degradation of image resolution and especially local image contrast due to such low-angle rearward scattering of light in the phosphor layer 65 while the relatively highly light-reflecting floor portions of the waffle surface reflect the high-angle (more nearly normal) portion to thereby deliver more useful light to photocathode 70 and hence increase the tube sensitivity. The reflection and absorption of the rearward traveling light photons is depicted by the arrows in FIG. 7.
Obviously, the metal master can be made with more sheets of the metal mesh to thereby obtain a silicone resin replica having rib projections of greater height whereby a thicker phosphor layer 65 can be utilized for increased x-ray absorption, and thus increased sensitivity, while still maintaining the height of the ribs at less than the prescribed one half of the phosphor layer thickness.
FIG. 8 illustrates a second means for obtaining the light-absorbing ribs. in this second embodiment, a waffle-like surface is formed on the light-reflective surface (which can be the inner surface of an aluminum face plate 10a, or a light-reflective coating 50 on the inner surface of a nonreflective face plate) by fastening a preferably blackened metal screen to the lightreflec-tive surface. Screen 80 may be woven, as illustrated, in the manner of a window screen, from approximately 1 mil wire and having a pitch of 5 to 10 mils, that is, the dimensions and spacing of the ribs can be made the same as in the first embodiment. The screen 80 can be fabricated of aluminum or other low atomic number metal such as iron, titanium or nickel. The metal screen 80 is fastened to the light-reflective surface by a conventional process appropriate to the particular metals involved, and as one typical example, can be adhesively bonded thereto by means of a silicone resin. Alternatively, an unblackened metal screen can be first fastened to the light-reflective surface, and the screen then blackened by oblique evaporation of the black material as in the first embodiment shown in FIG. 6. The blackened metal screen, besides absorbing lowangle rearward traveling light photons in the phosphor layer 65, also aids in holding the evaporated phosphor layer on the light-reflecting substrate face plate 10a while the reflective surface reflects the high-angle rearward traveling light photons.
FIG. 9 illustrates a third means for obtaining the light-absorbing ribs. In this third embodiment, the inner surface of the face plate 10a is etched to produce the illustrated jagged, irregular (waffle) surface 90. The size of the irregularity need not be large, and can be as small as a fraction of a mil, peak-to-peak. If the face plate 10a is aluminum, the light-absorbing ribs are completed by oblique evaporation of the black material on the peaks 91 of the irregularities as in FIG. 6. If the face plate is glass or another nonreflective material, a coating of a light-reflective material such as aluminum is deposited on the irregular surface prior to the oblique evaporation of the black material on the peaksv The blackened peaks absorb the low-angle rearward traveling light photons while the unblackened portions of the irregularities reflect the high-angle rearward traveling light photons.
From the foregoing description, it is apparent that my invention attains the objectives set forth and makes available a new and improved x-ray image intensifier tube which has an input phosphor screen that simultaneously achieves both high x-ray absorption and thus high sensitivity) and high image resolution and contrast as well as providing methods of manufacturing such input phosphor screen. The method of manufacturing the input phosphor screen is a low cost fabrication process due to the use of a silicone rubber replica which permits fabrication of many inexpensive silicone resin replicas of the original master in a first method of manufacture, the second and third described methods also being low cost. The light-absorbing ribs of the waffle surface, which are an important aspect of my invention, can be adjusted as to the height-to-spacing ratio thereof in the formation of the ribs and whereby the cut-off point for the low-angle rearward light radiation can be set at any desired angle. As a typical range, it would generally be desired to absorb the light photons which travel rearward at anglesup to approximately 15 from the plane in the phosphor layer parallel to the face plate, and containing the point at which an incident x-ray photon generates the light photons. The combination of the light-absorbing ribs and light-reflecting floor portions of the. fle surface provides an input phosphor screen which avoids the compromise in conventional x-ray image intensifier tubes between high x-ray absorption and high image resolution Having described three specific embodiments of my waffle surface, it will be apparent to those skilled in the art that such waffle-like surface which constitutes the essence of my invention may take other forms than that specifically illustrated and described above, and the ribs may be blackened by other methods. Also, the support for the input phosphor screen, herein described as the face plate, may be slightly spaced from the input window of the tube glass envelope. Thus, it is to be understood that changes may be made in the particular embodiment of my invention as described which are within the full intended scope of the invention as defined by the appended claims.
What I claim as new and desire to secure by Letters Patent of the United States is:
1. An improved x-ray image intensifier input phosphor screen comprising a concave-shaped face plate forming a support for the input phosphor screen of an x-ray image intensifier tube and having a convex-shaped major outer side and a correspondingly concave-shaped major inner side,
means disposed along the concave-shaped major side of said face plate for providing a waffle-like surface having floor portions and rib-like projections extending outward therefrom,
a phosphor layer deposited on said waffle-like surface means and being of sufficient thickness to extend substantially beyond the outer ends of the riblike projections thereof and having a second surface concave-shaped and substantially parallel to the inner side of said face plate, and
means deposited on the second surface of said phosphor layer for producing emission of photoelectrons therefrom in response to X-ray photons passing through said face plate and being converted to light photons in the phosphor layer, the surface of the rib-like projections being relatively highly lightabsorbing and the surfaces of the floor portions being relatively highly light-reflective whereby the rib projections absorb the low-angle portion of rearward traveling light photons generated in the phosphor layer to thereby reduce degradation of image resolution and local image contrast due to the more lateral scattering of the light in the phosphor layer, and the floor portions reflect the highangle portion of the rearward traveling light photons to thereby deliver more useful light to the photoelectron emission means and obtain increased sensitivity.
2. The x-ray image intensifier input set forth in claim 1 wherein the rib-like projections of the waffle surface means are solid.
3. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections are substantially normal to the floor portions of the waffle surface means.
4. The x-ray image intensifier input phosphor screen set forth in claim 3 wherein the floor portions of the waffle surface means are of thickness in the range of O to 3 mils.
phosphor screen 5. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means comprise a light-reflective surface of the concaveshaped major side of said face plate. 6. The x-ray image intensifier input phosphor screen set forth in claim 3 wherein the rib-like projections of the waffle surface means are of width in the range of approximately 1 to 2 mils. 7. The x-ray image intensifier input set forth in claim 1 wherein the rib-like projectionsand floor portions of the waffle surface means comprise a single substrate memher, the floor portions of the substrate member coated with a light-reflective material to provide the relatively highly light-reflective surfaces and the rib projections coated with a light-absorbing material to provide the relatively highly lightabsorbing surfaces. .8. The x-ray image intensifier input phosphor screen set forth in claim 7 wherein the single substrate member is fabricated of silicone resin. 9. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said face plate is fabricated ofaluminum. 10. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said face plate is fabricated of glass. 1 1. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said face plate is fabricated of a low atomic number metal. 12. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said phosphor layer comprises cesium iodide. 13. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said phosphor layer comprises a transparent phosphor material. 14. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections of the waffle surface means are solid and extend into the phosphorlayer less than halfway therethrough, and said phosphor layer comprises a transparent phosphor material. 15. The x-ray image intensifier input phosphor screen phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means each being square shaped. 16. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means form equal size squares separated by equal size said riblike projections. 17. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means each being hexagon shaped. 18. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions form equal size hexagons separated by equal size said rib-like projections. 19. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein 1 1 12 the rib-like projections each extend outward in a 100 to 2,000 Angstroms.
range of l to 2 mils. 28. The x-ray image intensifier input phosphor screen 20. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein set forth in Claim 1 wherein the rib-like projections of the waffle-like surface the rib-like Projections each have a Width dimension 5 means consist of a blackened metal screen fastened less than 2 mil to a light-reflective surface on the concave-shaped 21. The x-ray image intensifier input phosphor screen major Side f d f plata set fort n Claim 1 wherein 29. The x-ray image intensifier input phosphor screen the floor portions each have a width dimension Set f th in claim 2 wherein greater than 4 milslo the blackened metal screen is woven of approxi- 22. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib height-to-spacing ratio is approximately 1 to 4 and determines the angle cut-off point for the low angle rearward light radiation absorption. 23. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portion-to-rib projection area ratio is at least 2 to l. 24. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections extend into the phosphor layer less than halfway therethrough. 25. The x-ray image intensifier input phosphor screen mately 1 mil wire. 30. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the waffle-like surface means consists of the convexshaped major side of said face plate in etched form to produce a jagged, irregular surface, the peaks of the irregular surface forming the rib-like projections and being blackened to provide the lightabsorbing surface thereof. 31. The x-ray image intensifier input phosphor screen set forth in claim 30 wherein said face plate is fabricated of aluminum and the unblackened portions of the surface irregularities Set forth in claim 1 wherein forming the light-reflective floor portions of the the rib-like projections extend through approxiwaffle'hke S urface l mately 20 percent of the phosphor layer. 32. The x-ray image intenslfier input phosphor screen 26. The x-ray image intensifier input phosphor screen set forth m h Set f th in claim 7 wherein said face plate 1s fabricated of a nonreflective matethe light-reflective material coated on the floor por- 30 rial, and fuljlhel' comPfislng,
tions of said substrate member is aluminum and is a llght'reflectlve matel'lal deposlted the "regular of thi k ess i th range f 500 to 5,000 A surface of the face plate prior to the peaks thereof str being blackened whereby the unblackened por- 27. The x-ray image intensifier input phosphor screen tions of the surface irregularities form the lightset forth in claim 7 wherein reflective floor portions of the waffle-like surface the light-absorbing material coated on the rib projecmeans.
tions in carbon and is of thickness in the range of

Claims (31)

  1. 2. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections of the waffle surface means are solid.
  2. 3. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections are substantially normal to the floor portions of the waffle surface means.
  3. 4. The x-ray image intensifier input phosphor screen set forth in claim 3 wherein the floor portions of the waffle surface means are of thickness in the range of 0 to 3 mils.
  4. 5. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means comprise a light-reflective surface of the concave-shaped major side of said face plate.
  5. 6. The x-ray image intensifier input phosphor screen set forth in claim 3 wherein the rib-like projections of the waffle surface means are of width in the range of approximately 1 to 2 mils.
  6. 7. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections and floor portions of the waffle surface means comprise a single substrate member, the floor portions of the substrate member coated with a light-reflective material to provide the relatively highly light-reflective surfaces and the rib projections coated with a light-absorbing material to provide the relatively highly light-absorbing surfaces.
  7. 8. The x-ray image intensifier input phosphor screen set forth in claim 7 wherein the single substrate member is fabricated of silicone resin.
  8. 9. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said face plate is fabricated of aluminum.
  9. 10. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said face plate is fabricated of glass.
  10. 11. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said face plate is fabricated of a low atomic number metal.
  11. 12. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said phosphor layer comprises cesium iodide.
  12. 13. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein said phosphor layer comprises a transparent phosphor material.
  13. 14. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections of the waffle surface means are solid and extend into the phosphor layer less than halfway therethrough, and said phosphor layer comprises a transparent phosphor material.
  14. 15. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means each being square shaped.
  15. 16. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means form equal size squares separated by equal size said rib-like projections.
  16. 17. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions of the waffle surface means each being hexagon shaped.
  17. 18. The x-ray image intensifier input phosphor screen set forth in claim 1 wherEin the floor portions form equal size hexagons separated by equal size said rib-like projections.
  18. 19. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections each extend outward in a range of 1 to 2 mils.
  19. 20. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections each have a width dimension less than 2 mils.
  20. 21. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portions each have a width dimension greater than 4 mils.
  21. 22. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib height-to-spacing ratio is approximately 1 to 4 and determines the angle cut-off point for the low angle rearward light radiation absorption.
  22. 23. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the floor portion-to-rib projection area ratio is at least 2 to
  23. 24. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections extend into the phosphor layer less than halfway therethrough.
  24. 25. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections extend through approximately 20 percent of the phosphor layer.
  25. 26. The x-ray image intensifier input phosphor screen set forth in claim 7 wherein the light-reflective material coated on the floor portions of said substrate member is aluminum and is of thickness in the range of 500 to 5,000 Angstroms.
  26. 27. The x-ray image intensifier input phosphor screen set forth in claim 7 wherein the light-absorbing material coated on the rib projections in carbon and is of thickness in the range of 100 to 2,000 Angstroms.
  27. 28. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the rib-like projections of the waffle-like surface means consist of a blackened metal screen fastened to a light-reflective surface on the concave-shaped major side of said face plate.
  28. 29. The x-ray image intensifier input phosphor screen set forth in claim 28 wherein the blackened metal screen is woven of approximately 1 mil wire.
  29. 30. The x-ray image intensifier input phosphor screen set forth in claim 1 wherein the waffle-like surface means consists of the convex-shaped major side of said face plate in etched form to produce a jagged, irregular surface, the peaks of the irregular surface forming the rib-like projections and being blackened to provide the light-absorbing surface thereof.
  30. 31. The x-ray image intensifier input phosphor screen set forth in claim 30 wherein said face plate is fabricated of aluminum and the unblackened portions of the surface irregularities forming the light-reflective floor portions of the waffle-like surface means.
  31. 32. The x-ray image intensifier input phosphor screen set forth in claim 30 wherein said face plate is fabricated of a nonreflective material, and further comprising, a light-reflective material deposited on the irregular surface of the face plate prior to the peaks thereof being blackened whereby the unblackened portions of the surface irregularities form the light-reflective floor portions of the waffle-like surface means.
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Cited By (16)

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Publication number Priority date Publication date Assignee Title
US3904532A (en) * 1973-02-13 1975-09-09 Siemens Ag Inlet screen for intensifying x-ray images
US4032791A (en) * 1976-06-16 1977-06-28 Gte Sylvania Incorporated Fluorescent screen and method of making
US4069355A (en) * 1975-04-28 1978-01-17 General Electric Company Process of making structured x-ray phosphor screen
US4090085A (en) * 1975-08-28 1978-05-16 Dai Nippon Toryo Co., Ltd. Intensifying screen for radiographs
US4117365A (en) * 1977-01-14 1978-09-26 General Electric Company Continous photocathode for x-ray radiography having two-dimensional array of apertures
US4204125A (en) * 1978-03-27 1980-05-20 Minnesota Mining And Manufacturing Company High resolution X-ray intensifying screen with antireflecting substrate
US4209705A (en) * 1977-03-14 1980-06-24 Tokyo Shibaura Electric Co, Ltd. Image intensifier whose input screen phosphor layer is divided into light guiding mosaic blocks by metal protrusions
US4263061A (en) * 1978-03-27 1981-04-21 Minnesota Mining And Manufacturing Company Process for forming a high resolution X-ray intensifying screen with antireflecting substrate
US4626694A (en) * 1983-12-23 1986-12-02 Tokyo Shibaura Denki Kabushiki Kaisha Image intensifier
EP0242024A2 (en) * 1986-03-10 1987-10-21 Picker International, Inc. Radiation image intensifier tubes
US4778565A (en) * 1986-03-10 1988-10-18 Picker International, Inc. Method of forming panel type radiation image intensifier
US4855589A (en) * 1986-03-10 1989-08-08 Picker International, Inc. Panel type radiation image intensifier
WO1993003496A1 (en) * 1991-07-31 1993-02-18 The Regents Of The University Of California Improvements in particle detector spatial resolution
DE4319596A1 (en) * 1993-06-14 1994-12-15 Siemens Ag Input screen of an X-ray image intensifier
US5460980A (en) * 1993-09-27 1995-10-24 Minnesota Mining And Manufacturing Company Process for forming a phosphor
US20020115265A1 (en) * 2000-12-14 2002-08-22 Toshiaki Iwafuchi Method of transferring a device, a method of producing a device holding substrate, and a device holding substrate

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US2689189A (en) * 1951-12-05 1954-09-14 Westinghouse Electric Corp X-ray fluorescent screen
US2882413A (en) * 1953-12-04 1959-04-14 Vingerhoets Antonius Wilhelmus Luminescent screen
US3584216A (en) * 1968-09-12 1971-06-08 Bendix Corp Radiographic intensifying screen

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US2689189A (en) * 1951-12-05 1954-09-14 Westinghouse Electric Corp X-ray fluorescent screen
US2882413A (en) * 1953-12-04 1959-04-14 Vingerhoets Antonius Wilhelmus Luminescent screen
US3584216A (en) * 1968-09-12 1971-06-08 Bendix Corp Radiographic intensifying screen

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3904532A (en) * 1973-02-13 1975-09-09 Siemens Ag Inlet screen for intensifying x-ray images
US4069355A (en) * 1975-04-28 1978-01-17 General Electric Company Process of making structured x-ray phosphor screen
US4090085A (en) * 1975-08-28 1978-05-16 Dai Nippon Toryo Co., Ltd. Intensifying screen for radiographs
US4032791A (en) * 1976-06-16 1977-06-28 Gte Sylvania Incorporated Fluorescent screen and method of making
US4117365A (en) * 1977-01-14 1978-09-26 General Electric Company Continous photocathode for x-ray radiography having two-dimensional array of apertures
US4209705A (en) * 1977-03-14 1980-06-24 Tokyo Shibaura Electric Co, Ltd. Image intensifier whose input screen phosphor layer is divided into light guiding mosaic blocks by metal protrusions
US4204125A (en) * 1978-03-27 1980-05-20 Minnesota Mining And Manufacturing Company High resolution X-ray intensifying screen with antireflecting substrate
US4263061A (en) * 1978-03-27 1981-04-21 Minnesota Mining And Manufacturing Company Process for forming a high resolution X-ray intensifying screen with antireflecting substrate
US4626694A (en) * 1983-12-23 1986-12-02 Tokyo Shibaura Denki Kabushiki Kaisha Image intensifier
EP0242024A2 (en) * 1986-03-10 1987-10-21 Picker International, Inc. Radiation image intensifier tubes
EP0242024A3 (en) * 1986-03-10 1988-01-20 Picker International, Inc. Radiation image intensifier tubes
US4778565A (en) * 1986-03-10 1988-10-18 Picker International, Inc. Method of forming panel type radiation image intensifier
US4855589A (en) * 1986-03-10 1989-08-08 Picker International, Inc. Panel type radiation image intensifier
WO1993003496A1 (en) * 1991-07-31 1993-02-18 The Regents Of The University Of California Improvements in particle detector spatial resolution
DE4319596A1 (en) * 1993-06-14 1994-12-15 Siemens Ag Input screen of an X-ray image intensifier
US5460980A (en) * 1993-09-27 1995-10-24 Minnesota Mining And Manufacturing Company Process for forming a phosphor
US20020115265A1 (en) * 2000-12-14 2002-08-22 Toshiaki Iwafuchi Method of transferring a device, a method of producing a device holding substrate, and a device holding substrate
US6939729B2 (en) * 2000-12-14 2005-09-06 Sony Corporation Method of transferring a device, a method of producing a device holding substrate, and a device holding substrate

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