US3726651A - Synthetic fireplace log - Google Patents

Synthetic fireplace log Download PDF

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US3726651A
US3726651A US00885177A US3726651DA US3726651A US 3726651 A US3726651 A US 3726651A US 00885177 A US00885177 A US 00885177A US 3726651D A US3726651D A US 3726651DA US 3726651 A US3726651 A US 3726651A
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logs
log
charcoal
ridges
weight
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C Ronden
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Husky Briquetting Inc
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/04Raw material of mineral origin to be used; Pretreatment thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • Synthetic fireplace logs are provided in the form of elongated, indurated bodies composed of a uniform mixture comprising charcoal (or charcoal and coal), sawdust and binder material. Particular compositions are employed which result in easily ignitable, clean, strong logs of controlled density and burning characteristics approximating those of natural woods.
  • the outer longitudinal surface of the log is made up of a series of longitudinally extending ridges and valleys which increase the surface area, the ridges having at least one sharp longitudinal edge. These outer surface characteristics combine with the characteristics afforded by the compositions to provide easy lighting of the log.
  • This invention relates to synthetic fuel bodies and more particularly to synthetic fireplace logs and their production.
  • synthetic logs according to the invention are characterized both by a particular composition, which yields the desired strength and burning properties, and by an external configuration providing an enlarged total surface and a plurality of longitudinally extending sharp edges, making easy lighting of the log possible.
  • the logs are extruded from a composition comprising charcoal (or charcoal and coal), sawdust, and a binder, the charcoal and sawdust having critical particle sizes, and the binder comprising a certain proportion of paraffin wax.
  • the density of the log is controlled to a predetermined range which, for the particular composition employed, assures the necessary burning characteristics.
  • FIG. 1 is a flow diagram illustrating one manner in which fireplace logs can be produced according to the invention
  • FIG. 2 is a longitudinal sectional view of an extrusion die employed in producing fireplace logs according to the invention.
  • FIGS. 3 and 4 are end elevational views of two fireplace logs produced in accordance with the flow diagram of FIG. 1.
  • the synthetic fireplace logs of the invention can be produced in the manner set out in the flow sheet of FIG. 1, using a conventional mixing and extruding apparatus providing a mixing stage, a vacuum dewatering stage, and an extru sion stage, but with the apparatus being equipped with a heated die constructed according to FIG. 2.
  • the initial feed to the mixing and extruding apparatus comprises charcoal (or charcoal and coal), sawdust, a binder and water and can include at least one igniter compound, and, if desired, one or more flame colorants.
  • the first stage of the apparatus provides a mixing action adequate to assure uniformity of the mixture.
  • the second stage which can also provide a further mixing action, subjects the mixture to vacuum dewatering to reduce the moisture from the relatively high level required for uniform mixing to a lower level suitable for extrusion and which reduces the time and temperature of the curing step which follows extrusion.
  • the charcoal employed can be any finely particulate charcoal produced by partial combustion of organic material such as coal or wood. Finely divided charcoal is required, with an average particle size such that essentially all of the charcoal passes a 200 mesh screen. Though particularly satisfactory logs can be prepared using charcoal as the only carbonaceous fuel ingredient, up to of the charcoal can be replaced by powdered lignite coal to bituminous coal, with the coal having a particle size such that essentially all thereof will pass a 200 mesh screen.
  • Sawdusts from soft woods and hard woods are suitable.
  • the invention has been practiced successfully with sawdust from pine, spruce, fir, cedar, birch and various hard woods, with pine sawdust being particularly advantageous. While in particulate form, the sawdust must be coarser than the charcoal. Thus, all of the sawdust should pass a 60 mesh screen, with all being retained on a 200' mesh screen. If the particle size of the sawdust is not significantly larger than that of the charcoal, the finished product will be too dense, and the flame spread characteristics will be inadequate. Additionally, with the relative particle sizes specified, a better bonding action of the binder is achieved.
  • the binder material employed comprises parafiin wax as the primary binder additive, and advantageously additionally includes a substantial proportion of starch or a starchy cereal flour. Relatively smaller proportions of other binder additives can advantageously be included, particularly bentonite and thermoplastic polymeric materials selected from the group consisting of the polyvinyl alcohols and the long chain alkyl vinyl ethers.
  • parafiin wax can be employed in any suitable form, it should have a melting point of l20-140 F. and best results are achieved with aqueous wax emulsions containing 45-55% solids. Wax emulsions provide the wax in the finest practical subdivision, so that mixing tends readily to distribute the wax uniformly through the total formulation. Further, wax emulsions can provide all or a substantial part of the water necessary for the formulation. I
  • the initial mixture employed comprises 40-50% by weight of carbonaceous fuel material selected from the group consisting of charcoal, lignite coal and bituminous coal, with the charcoal amounting to at least 30% of the total Weight of carbonaceous fuel material.
  • the sawdust is employed in a proportion equal to 12-30% of the weight of the total mixture. Satisfactory results can be obtained when the proportion of water employed, either separately added or introduced at least in part as Water of an aqueous parafiin wax emulsion, equals 10- 3'0% of the total formulation weight.
  • the proportion of paraffin wax employed should be at least 4%, and can be increased to as much as 15%, of the total formula weight.
  • Starch, or a starchy cereal flour can amount to 2-6% of the total formulation weight.
  • Wood flour can be included as a minor ingredient in amounts up to 5% of the total weight.
  • At least one igniter selected from the group consisting of sodium nitrate, potassium nitrate and potassium chloride can be included.
  • Conventional flame coloring agents, such as copper sulfate, can be used in amounts in the range of 0.5-2% by weight.
  • the extrusion die 1 comprises a cylindrical throat portion 2, forwardly and outwardly tapering portion 3 which forms a decompression zone within the die, a cylindrical body portion 4, a forwardly and inwardly tapering frusto-conical portion 5 which forms a compression zone within the die, and a cylindrical lip portion 6.
  • Lip portion 6 is provided, on its inner surface, with a plurality of straight longitudinally extending flutes 7 for the purpose of forming the outer surface of the extruded product into a series of longitudinally extending ridges each having at least one sharp longitudinal edge, as hereinafter described in detail.
  • the die further includes an axially extending mandrel 8 supported by spiders 9.
  • mandrel 8 has an enlarged cylindrical nose portion 10 of a diameter equal to approximately of the internal diameter of lip portion 6, nose portion 10 being joined to the smaller diameter main portion of the mandrel by a forwardly and outwardly tapering frusto-conical portion 11.
  • the die is heated, as by conventional external heating bands indicated at 12.
  • Heating of the extrusion die is of particular importance to successful production of synthetic fireplace logs having the characteristics described, and best results are achieved by maintaining the die at a temperature of 150- 200 F.
  • the effect of maintaining the die at such an elevated temperature during extrusion is to assure proper fiow of the paraflin wax and to achieve a better and more uniform bond in the extruded product.
  • the continuously extruded product can be cut to desired lengths by any conventional cutting device adjacent the die, and the individual logs so provided are carried through a drying tunnel or curing oven, as by means of a chain conveyor.
  • the nature of the extruded green logs is such that the logs can be handled without damage, and the moisture content can be reduced to below 10%, and advantageously below 2%, by weight by subjecting them to a curing temperature of -180 F. for 6-10 minutes.
  • the cured logs have a density of 40- 70 pounds per cu. ft., advantageously 50-55 pounds per cu. ft., and are in the form of uniform, indurated bodies capable of withstanding the conditions of shipping and handling normally encountered.
  • compositions employed according to the invention provide good mechanical properties and burning characteristics. Further, these compositions make it possible to produce, 'by use of a die constructed according to FIG. 2, an extruded product having its longitudinal outer surface made up of a plurality of longitudinally extending ridges, with the ridges having a longitudinally extending sharp edge or edges, so that the exposed surface area is greatly increased and the surface is such as to assure ease of lighting without requiring the usual highly volatile starter fluids.
  • the ridges 13 can be of triangular transverse cross section, with each adjacent pair of the ridges 13 defining an intervening valley 14 having a triangular transverse cross section which matches that of the ridges.
  • the log 15 of FIG. 3 also has a cylindrical through bore 16, formed by mandrel nose portion 10 of the die. Through bore 16 provides a chimney action to provide a better spread of flame over the entire log, and also serves to provide a greater exposed surface area for a log of given Weight.
  • log 17 has a plurality of ridges 18 in the form of splines, each ridge 18 extending longitudinally for the full length of the log and presenting two sharp edges or corners 19. Between each adjacent pair of ridges 18, there is a longitudinally extending valley 20 defined by the corresponding sides of the adjacent ridges plus the bottom surface 21. Surfaces 21, and the outer faces 22 of ridges 18, are cylindrical segments. The cross-sectional dimensions of the ridges 18 and valleys 20 are such that the ridges and valleys are of the same transverse cross-sectional configuration and dimensions, with the valleys of course being inverted relative to the ridges. As in the case of the log shown in FIG. 3, the log 17, FIG. 4, has a cylindrical through bore 23.
  • FIGS. 3 and 4 While the configurations illustrated in FIGS. 3 and 4 are advantageous, it will be understood that, using dies similar to that shown in FIG. 2, logs having various other configurations can be extruded according to the invention. Thus, for example, logs of generally rectangular and of generally triangular transverse cross section can be formed. Similarly, the ridges and valleys can have different transverse configurations from those shown in the illustrative embodiments of FIGS. 3 and 4.
  • EXAMPLE 1 The apparatus employed was a conventional clay extruder having a mixing section, a vacuum dewatering section, and an extruding section, the apparatus being equipped with the die shown in FIG. 2, the flutes 7 of the die being of triangular transverse cross section and of such shape and dimension as to provide the outer surface seen in FIG. 3.
  • the internal diameter of die lip portion 6 was 4 in.
  • the mixing and extrusion apparatus was employed in conjunction with a conventional drying tunnel equipped with a chain conveyor, the continuously extruded product being cut into green" bodies which were 14 inches long and which were deposited successively on the conveyor of the drying tunnel.
  • the mixture supplied to the feed hopper of the mixing and extruding apparatus had the following composition:
  • the extruder was operated at a head pressure of 1,000 lbs. per sq. in.
  • the temperature of die body portion 4 maintained at approximately 200 F. and the die lip portion 6 maintained at approximately 195 F.
  • the drying tunnel was operated at approximately 175" F., with good air evacuation continuously afforded by an exhaust fan. Retention time of the product in the drying tunnel was approximately 15 minutes.
  • Logs produced in accordance with this example had a density within the range of 50-55 lbs. per cu. ft., determined by a weight v. volume calculation after drying at 250 F. for 48 hrs. to eliminate the moisture weight as a significant factor in determining the density. In all cases, tunnel drying times of 15 min. brought the moisture content of the cured log below 2% by weight.
  • the logs so produced could be ignited by holding an open flame to the exterior longitudinal surface of the log, with ignition first occurring at the sharp edges provided by the longitudinal ridges 13, FIG. 3.
  • the logs exhibited an even flame spreading characteristic and a burning time of at least 2 hours before disintegration, when burned in a conventional fireplace.
  • the logs were hard, rigid, and adequately shock resistant to withstand the rigors of normal shipping and usage.
  • Example 2 The procedure of Example 1 was duplicated, save that the binder material employed consisted of 5 parts by weight starch, 5 parts by weight paraflin wax, 2 parts by weight bentonite, and 1 part by weight of a water-compatible polymer of vinyl methyl ether.
  • the finished fireplace logs had all of the characteristics of those obtained according to Example 1, and exhibited an observable increase in strength and resistance to chipping.
  • Lignite charcoal Parts by weight Lignite charcoal, all finer than 200 mesh 50 Pine sawdust, all between 60 mesh and 200 mesh 20
  • Example 5 The procedure of Example 4 was repeated, save that 25 parts by weight of charcoal was used, and the remaining 25 parts by weight of the formulation was lignite coal having a particle size smaller than 200 mesh.
  • the cured logs were generally similar to those obtained in Example 4, through significantly less clean insofar as handling and storage are concerned.
  • the same is advantageously introduced into the initial mixture so as to be distributed uniformly throughout the body of the finished log.
  • the igniter can be applied as a coating to the outer surface of the log.
  • this density is to be taken as the density after drying the cured product at 250-260" F. for 48 hours to eliminate most of the residual moisture.
  • a synthetic fireplace log in the form of an extruded elongated indurated body composed of a uniform mixture of 40-50% by weight of a finely particulate carbonaceous fuel material selected from the group consisting of charcoal, lignite coal and bituminous coal,
  • said carbonaceous fuel material being charcoal; 12-30% by weight sawdust having a particle size in the range of 60-200 mesh,
  • the particles of said sawdust being significantly larger than those of said carbonaceous fuel material
  • said body having a moisture content not exceeding 10% by weight, a density of 40-70 lbs. per cu. ft., and sufficient strength to withstand normal shipping and handling conditions,
  • the longitudinal surface of said body being made up of a series of longitudinally extending ridges and valleys with the ridges each presenting at least one longitudinally extending sharp edge
  • said synthetic fireplace log having flame spread characteristics similar to natural dry woods and a burning life of at least 2. hours.
  • Wax emulsion 20 75 wherein said ridges and valleys are straight and are of generally triangular transverse cross section.

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Abstract

SYNTHETIC FIREPLACE LOGS ARE PROVIDED IN THE FORM OF ELONGATED, INDURATED BODIES COMPOSED OF A UNIFORM MIXTURE COMPRISING CHARCOAL (OR CHARCOAL AND COAL), SAWDUST AND BINDER MATERIAL. PARTICULAR COMPOSITIONS ARE EMPLOYED WHICH RESULT IN EASILY IGNITABLE, CLEAN, STRONG LOGS OF CONTROLLED DENSITY AND BURNING CHARACTERISTICS APPROXIMATING THOSE OF NATURAL WOODS. THE OUTER LONGITUDINAL SURFACE OF THE LOG IS MADE UP OF A SERIES OF LONGITUDINALLY EXTENDING RIDGES AND VALLEYS WHICH INCREASE THE SURFACE AREA, THE RIDGES HAVING AT LEAST ONE SHARP LONGITUDINAL EDGE. THESE OUTER SURFACE CHARACTERISTICS COMBINE WITH THE CHARACTERISTICS AFFORDED BY THE COMPOSITIONS TO PROVIDE EASY LIGHTINING OF THE LOG.

Description

April 10, 1973 c. P. RONDEN 3,726,651
SYNTHET I C F IREPLACE LOG Filed Dec. 15, 1969 2 Sheets-Sheet l Cl/AECOAL SA WDUST W4 TE 2 B/NDE/Z lG/V/TEE FLAMECOL ozA/vr DEW/475B 'XTEUDE THROUGH HEATED D/E f/AV/NG FLUTED DIE LIPS TO PROV/DE LOA/G/TUD/A/ALLY EX- TEND/NG 2/0658 AND VALLEYS CUT 7'0 DES/RED LENGTH c025 7'0 MO/STUQE' co/vrewr A/or xc0uvc 2 Z By we/ewr ATTORNEYS April 10, 1973 c. P. RONDEN 3,726,651
SYNTHET I C FIREPLACE LOG Filed Dec. 15, 1969 2 Sheets-Sheet 2 INVENTOR CL IFF'OED R EONDEN BM @AMQMz ATTORNEY5 United States Patent US. C]. 4414 4 Claims ABSTRACT OF THE DISCLOSURE Synthetic fireplace logs are provided in the form of elongated, indurated bodies composed of a uniform mixture comprising charcoal (or charcoal and coal), sawdust and binder material. Particular compositions are employed which result in easily ignitable, clean, strong logs of controlled density and burning characteristics approximating those of natural woods. The outer longitudinal surface of the log is made up of a series of longitudinally extending ridges and valleys which increase the surface area, the ridges having at least one sharp longitudinal edge. These outer surface characteristics combine with the characteristics afforded by the compositions to provide easy lighting of the log.
This application is a continuation-in-part of my copending application Ser. No. 756,864, filed Sept. 3, 1968 now abandoned.
This invention relates to synthetic fuel bodies and more particularly to synthetic fireplace logs and their production.
Increasing demand for fireplace fuel, and decreasing availability of natural wood logs, have caused a critical need for a synthetic product satisfactory as a substitute for wood logs. Despite the fact that this need has been well recognized, efforts of prior-art workers to provide a commercially acceptable synthetic fireplace log have not been truly successful. One reason for lack of success heretofore has been inability to provide a synthetic log having burning characteristics approximating those of natural wood logs. In this regard, burning times to the disintegration point for typical, prior-art synthetic logs have been so short that a relatively large number of logs is required for an evenings fire, and the use of such logs has accordingly been very expensive. Conversely, despite their relatively short burning times, prior-art logs have been difiicult to ignite, ignition times of 20-45 min., to full flame burning, being typical.
It is accordingly a general object of the invention to provide a synthetic fireplace log which can be accepted commercially as the equivalent of a natural wood log. Another object is to provide such a product which possesses both adequate strength to withstand shipping and handling and the ability to be both quickly and easily lighted. A further object is to provide synthetic fireplace logs which, produced in normal sizes for fireplace use, will have flame spread characteristics similar to natural dry woods and will have at least a two-hour burning life without disintegrating.
Broadly considered, synthetic logs according to the invention are characterized both by a particular composition, which yields the desired strength and burning properties, and by an external configuration providing an enlarged total surface and a plurality of longitudinally extending sharp edges, making easy lighting of the log possible. The logs are extruded from a composition comprising charcoal (or charcoal and coal), sawdust, and a binder, the charcoal and sawdust having critical particle sizes, and the binder comprising a certain proportion of paraffin wax. The density of the log is controlled to a predetermined range which, for the particular composition employed, assures the necessary burning characteristics.
In order that the manner in which the foregoing and other objects are achieved in accordance with the invention can be more readily understood, particularly advantageous embodiments thereof will be described in detail with reference to the accompanying drawings, which form a part of the original disclosure of this application, and wherein:
FIG. 1 is a flow diagram illustrating one manner in which fireplace logs can be produced according to the invention;
FIG. 2 is a longitudinal sectional view of an extrusion die employed in producing fireplace logs according to the invention; and
FIGS. 3 and 4 are end elevational views of two fireplace logs produced in accordance with the flow diagram of FIG. 1.
Turning now to the drawings in detail, the synthetic fireplace logs of the invention can be produced in the manner set out in the flow sheet of FIG. 1, using a conventional mixing and extruding apparatus providing a mixing stage, a vacuum dewatering stage, and an extru sion stage, but with the apparatus being equipped with a heated die constructed according to FIG. 2.
The initial feed to the mixing and extruding apparatus comprises charcoal (or charcoal and coal), sawdust, a binder and water and can include at least one igniter compound, and, if desired, one or more flame colorants. The first stage of the apparatus provides a mixing action adequate to assure uniformity of the mixture. The second stage, which can also provide a further mixing action, subjects the mixture to vacuum dewatering to reduce the moisture from the relatively high level required for uniform mixing to a lower level suitable for extrusion and which reduces the time and temperature of the curing step which follows extrusion.
The charcoal employed can be any finely particulate charcoal produced by partial combustion of organic material such as coal or wood. Finely divided charcoal is required, with an average particle size such that essentially all of the charcoal passes a 200 mesh screen. Though particularly satisfactory logs can be prepared using charcoal as the only carbonaceous fuel ingredient, up to of the charcoal can be replaced by powdered lignite coal to bituminous coal, with the coal having a particle size such that essentially all thereof will pass a 200 mesh screen.
Sawdusts from soft woods and hard woods are suitable. The invention has been practiced successfully with sawdust from pine, spruce, fir, cedar, birch and various hard woods, with pine sawdust being particularly advantageous. While in particulate form, the sawdust must be coarser than the charcoal. Thus, all of the sawdust should pass a 60 mesh screen, with all being retained on a 200' mesh screen. If the particle size of the sawdust is not significantly larger than that of the charcoal, the finished product will be too dense, and the flame spread characteristics will be inadequate. Additionally, with the relative particle sizes specified, a better bonding action of the binder is achieved.
The binder material employed comprises parafiin wax as the primary binder additive, and advantageously additionally includes a substantial proportion of starch or a starchy cereal flour. Relatively smaller proportions of other binder additives can advantageously be included, particularly bentonite and thermoplastic polymeric materials selected from the group consisting of the polyvinyl alcohols and the long chain alkyl vinyl ethers.
While the parafiin wax can be employed in any suitable form, it should have a melting point of l20-140 F. and best results are achieved with aqueous wax emulsions containing 45-55% solids. Wax emulsions provide the wax in the finest practical subdivision, so that mixing tends readily to distribute the wax uniformly through the total formulation. Further, wax emulsions can provide all or a substantial part of the water necessary for the formulation. I
The initial mixture employed comprises 40-50% by weight of carbonaceous fuel material selected from the group consisting of charcoal, lignite coal and bituminous coal, with the charcoal amounting to at least 30% of the total Weight of carbonaceous fuel material. The sawdust is employed in a proportion equal to 12-30% of the weight of the total mixture. Satisfactory results can be obtained when the proportion of water employed, either separately added or introduced at least in part as Water of an aqueous parafiin wax emulsion, equals 10- 3'0% of the total formulation weight. The proportion of paraffin wax employed should be at least 4%, and can be increased to as much as 15%, of the total formula weight. Starch, or a starchy cereal flour, can amount to 2-6% of the total formulation weight. Wood flour can be included as a minor ingredient in amounts up to 5% of the total weight. To improve ignition characteristics, 0.75-1.5% by weight of at least one igniter selected from the group consisting of sodium nitrate, potassium nitrate and potassium chloride can be included. Conventional flame coloring agents, such as copper sulfate, can be used in amounts in the range of 0.5-2% by weight.
The relative proportions of charcoal, coal (if employed), sawdust, water and paraffin Wax are of particular importance. In general, while increasing proportions of coal decrease cost, they also tend to make the product less clean and more diflicultly bound to satisfactory form.
The extrusion die 1, FIG. 2, comprises a cylindrical throat portion 2, forwardly and outwardly tapering portion 3 which forms a decompression zone within the die, a cylindrical body portion 4, a forwardly and inwardly tapering frusto-conical portion 5 which forms a compression zone within the die, and a cylindrical lip portion 6. Lip portion 6 is provided, on its inner surface, with a plurality of straight longitudinally extending flutes 7 for the purpose of forming the outer surface of the extruded product into a series of longitudinally extending ridges each having at least one sharp longitudinal edge, as hereinafter described in detail. The die further includes an axially extending mandrel 8 supported by spiders 9. Within lip portion 6 of the die, mandrel 8 has an enlarged cylindrical nose portion 10 of a diameter equal to approximately of the internal diameter of lip portion 6, nose portion 10 being joined to the smaller diameter main portion of the mandrel by a forwardly and outwardly tapering frusto-conical portion 11. The die is heated, as by conventional external heating bands indicated at 12.
Heating of the extrusion die is of particular importance to successful production of synthetic fireplace logs having the characteristics described, and best results are achieved by maintaining the die at a temperature of 150- 200 F. The effect of maintaining the die at such an elevated temperature during extrusion is to assure proper fiow of the paraflin wax and to achieve a better and more uniform bond in the extruded product.
The continuously extruded product can be cut to desired lengths by any conventional cutting device adjacent the die, and the individual logs so provided are carried through a drying tunnel or curing oven, as by means of a chain conveyor. When the particular compositions of the invention are employed, the nature of the extruded green logs is such that the logs can be handled without damage, and the moisture content can be reduced to below 10%, and advantageously below 2%, by weight by subjecting them to a curing temperature of -180 F. for 6-10 minutes. Depending upon the particular composition employed, the cured logs have a density of 40- 70 pounds per cu. ft., advantageously 50-55 pounds per cu. ft., and are in the form of uniform, indurated bodies capable of withstanding the conditions of shipping and handling normally encountered.
The particular compositions employed according to the invention provide good mechanical properties and burning characteristics. Further, these compositions make it possible to produce, 'by use of a die constructed according to FIG. 2, an extruded product having its longitudinal outer surface made up of a plurality of longitudinally extending ridges, with the ridges having a longitudinally extending sharp edge or edges, so that the exposed surface area is greatly increased and the surface is such as to assure ease of lighting without requiring the usual highly volatile starter fluids. In accordance with the embodiment shown in FIG. 3, the ridges 13 can be of triangular transverse cross section, with each adjacent pair of the ridges 13 defining an intervening valley 14 having a triangular transverse cross section which matches that of the ridges. To attain such a configuration, the flutes 7 of the die portion 6 are simply made with the triangular transverse cross section desired for the valleys 14. The log 15 of FIG. 3 also has a cylindrical through bore 16, formed by mandrel nose portion 10 of the die. Through bore 16 provides a chimney action to provide a better spread of flame over the entire log, and also serves to provide a greater exposed surface area for a log of given Weight.
In the embodiment shown in FIG. 4, log 17 has a plurality of ridges 18 in the form of splines, each ridge 18 extending longitudinally for the full length of the log and presenting two sharp edges or corners 19. Between each adjacent pair of ridges 18, there is a longitudinally extending valley 20 defined by the corresponding sides of the adjacent ridges plus the bottom surface 21. Surfaces 21, and the outer faces 22 of ridges 18, are cylindrical segments. The cross-sectional dimensions of the ridges 18 and valleys 20 are such that the ridges and valleys are of the same transverse cross-sectional configuration and dimensions, with the valleys of course being inverted relative to the ridges. As in the case of the log shown in FIG. 3, the log 17, FIG. 4, has a cylindrical through bore 23.
While the configurations illustrated in FIGS. 3 and 4 are advantageous, it will be understood that, using dies similar to that shown in FIG. 2, logs having various other configurations can be extruded according to the invention. Thus, for example, logs of generally rectangular and of generally triangular transverse cross section can be formed. Similarly, the ridges and valleys can have different transverse configurations from those shown in the illustrative embodiments of FIGS. 3 and 4.
The following examples are illustrative:
EXAMPLE 1 The apparatus employed was a conventional clay extruder having a mixing section, a vacuum dewatering section, and an extruding section, the apparatus being equipped with the die shown in FIG. 2, the flutes 7 of the die being of triangular transverse cross section and of such shape and dimension as to provide the outer surface seen in FIG. 3. The internal diameter of die lip portion 6 was 4 in. The mixing and extrusion apparatus was employed in conjunction with a conventional drying tunnel equipped with a chain conveyor, the continuously extruded product being cut into green" bodies which were 14 inches long and which were deposited successively on the conveyor of the drying tunnel.
The mixture supplied to the feed hopper of the mixing and extruding apparatus had the following composition:
The extruder was operated at a head pressure of 1,000 lbs. per sq. in. The temperature of die body portion 4 maintained at approximately 200 F. and the die lip portion 6 maintained at approximately 195 F.
The drying tunnel was operated at approximately 175" F., with good air evacuation continuously afforded by an exhaust fan. Retention time of the product in the drying tunnel was approximately 15 minutes.
Logs produced in accordance with this example had a density within the range of 50-55 lbs. per cu. ft., determined by a weight v. volume calculation after drying at 250 F. for 48 hrs. to eliminate the moisture weight as a significant factor in determining the density. In all cases, tunnel drying times of 15 min. brought the moisture content of the cured log below 2% by weight.
The logs so produced could be ignited by holding an open flame to the exterior longitudinal surface of the log, with ignition first occurring at the sharp edges provided by the longitudinal ridges 13, FIG. 3. The logs exhibited an even flame spreading characteristic and a burning time of at least 2 hours before disintegration, when burned in a conventional fireplace. The logs were hard, rigid, and adequately shock resistant to withstand the rigors of normal shipping and usage.
EXAMPLE 2 The procedure of Example 1 was duplicated, save that the binder material employed consisted of 5 parts by weight starch, 5 parts by weight paraflin wax, 2 parts by weight bentonite, and 1 part by weight of a water-compatible polymer of vinyl methyl ether. The finished fireplace logs had all of the characteristics of those obtained according to Example 1, and exhibited an observable increase in strength and resistance to chipping.
EXAMPLE 3 EXAMPLE 4 The procedure of Example 1 was duplicated, using the following formulation:
Ingredient: Parts by weight Lignite charcoal, all finer than 200 mesh 50 Pine sawdust, all between 60 mesh and 200 mesh 20 An aqueous emulsion of paraflln wax with e. solids content of 47% by weight, the paraflin wax having a. melting point of 123-135 F.
The cured logs were equivalent to those attained in Example 1.
EXAMPLE 5 The procedure of Example 4 was repeated, save that 25 parts by weight of charcoal was used, and the remaining 25 parts by weight of the formulation was lignite coal having a particle size smaller than 200 mesh. The cured logs were generally similar to those obtained in Example 4, through significantly less clean insofar as handling and storage are concerned.
When an igniter compound is employed, the same is advantageously introduced into the initial mixture so as to be distributed uniformly throughout the body of the finished log. Alternatively, the igniter can be applied as a coating to the outer surface of the log.
In production of logs according to the invention, it is desirable to accomplish curing of the extruded green logs under conditions which will bring the moisture content below 2% by weight in a reasonably short time. Care must be taken, however, to avoid such rigorous conditions as will result in excessive surface cracking, resulting from shrinkage of the extruded body. If the curing temperature is maintained in the range of F., it is not practical to extend the curing time beyond 20 min., and, if the temperature is maintained near the upper limit of that range, best results are achieved with a curing time not exceeding 10 min.
When, in the appended claims,-the density of the cured logs is specified, this density is to be taken as the density after drying the cured product at 250-260" F. for 48 hours to eliminate most of the residual moisture.
What is claimed is:
1. A synthetic fireplace log in the form of an extruded elongated indurated body composed of a uniform mixture of 40-50% by weight of a finely particulate carbonaceous fuel material selected from the group consisting of charcoal, lignite coal and bituminous coal,
at least 30% of said carbonaceous fuel material being charcoal; 12-30% by weight sawdust having a particle size in the range of 60-200 mesh,
the particles of said sawdust being significantly larger than those of said carbonaceous fuel material; and
4-15% by weight of parafiin wax distributed uniformly through said body and binding said particles,
said body having a moisture content not exceeding 10% by weight, a density of 40-70 lbs. per cu. ft., and sufficient strength to withstand normal shipping and handling conditions,
the longitudinal surface of said body being made up of a series of longitudinally extending ridges and valleys with the ridges each presenting at least one longitudinally extending sharp edge,
said synthetic fireplace log having flame spread characteristics similar to natural dry woods and a burning life of at least 2. hours.
2. A synthetic fireplace log according to claim 1, wherein said body has a density of 50-55 lbs. per cu. ft.
3. A synthetic fireplace log according to claim 1, wherein said carbonaceous fuel material is essentially all charcoal.
4. A synthetic fireplace log according to claim 1,
Wax emulsion 20 75 wherein said ridges and valleys are straight and are of generally triangular transverse cross section.
References Cited UNITED STATES PATENTS 8 v r, Williams et a1. 4414 Ronzio 4417 Eyre, Jr. 44-10 X Lockhart 4410 X Starr 44-17 US. Cl. X.R.
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Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3947255A (en) * 1973-01-10 1976-03-30 American Can Company Method of extruding bark and of forming a solid synthetic fuel
US4040796A (en) * 1975-06-30 1977-08-09 The Kingsford Company Fast lighting artificial firelog
US4042343A (en) * 1975-09-26 1977-08-16 The Clorox Company Fire log process and apparatus
US4043765A (en) * 1975-07-11 1977-08-23 Linwo Industries Ltd. Artificial fireplace logs with ignition strips
US4062655A (en) * 1969-06-20 1977-12-13 Business Controls, Inc. Artificial fire place logs which burn with colored flame and process for making same
US4083697A (en) * 1975-07-11 1978-04-11 Reckitt & Colman Products Limited Combustible composition
US4104034A (en) * 1976-07-15 1978-08-01 Duraflame, Inc. Easy lighting fireplace log
US4169709A (en) * 1975-07-01 1979-10-02 Colgate-Palmolive Company Artificial fireplace logs
US4179269A (en) * 1978-04-12 1979-12-18 Lee Floyd W Synthetic log production
FR2449121A1 (en) * 1979-02-14 1980-09-12 Dg Shelter Prod Co ARTIFICIAL BRIQUETTE
US4243393A (en) * 1977-10-13 1981-01-06 Banner Energy Corporation Coal article
US4308033A (en) * 1980-10-23 1981-12-29 Gunnerman Rudolf W Fuel pellet and process for making it by shaping under pressure an organic fibrous material
US4612017A (en) * 1981-02-18 1986-09-16 Georgia-Pacific Corporation Pelletizing wood
US4883498A (en) * 1988-07-01 1989-11-28 Sebring Forest Industries, Inc. Artificial firelog
US5112365A (en) * 1991-01-25 1992-05-12 Sebring Forest Industries, Inc. Fuel block
US5679248A (en) * 1995-12-19 1997-10-21 Kimberly-Clark Worldwide, Inc. Coextruded blocks and applications therefor
US5711766A (en) * 1996-02-26 1998-01-27 Forest Technology Corporation Wood fire starter having improved stacking properties
US5858036A (en) * 1997-05-28 1999-01-12 Conros Corporation Artificial fire log
ES2142260A1 (en) * 1998-01-16 2000-04-01 Esfaxa Explotaciones Forestale Method for the manufacture of combustible briquettes
US6071320A (en) * 1996-10-21 2000-06-06 Meske; Albin F. Apparatus for starting a log fire
US6086646A (en) * 1996-10-21 2000-07-11 Meske; Albin F. Apparatus for starting a log fire
US6139786A (en) * 1989-02-09 2000-10-31 Corry; Arthur A. Method of forming a flexible mold and resulting article
US20040247720A1 (en) * 1998-10-01 2004-12-09 Peterson Gregory J. Artificial firelog and firestarter chip producing apparatus and method and products produced therefrom
US20050011113A1 (en) * 2003-04-07 2005-01-20 Gomez Jose J. Synthetic fireplace log
US20100263271A1 (en) * 2009-04-21 2010-10-21 Lai Kuei Tsai Clean burning bio-coal
US11162043B2 (en) * 2016-07-22 2021-11-02 Campfire Innovations, Llc Combustible log torch

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4062655A (en) * 1969-06-20 1977-12-13 Business Controls, Inc. Artificial fire place logs which burn with colored flame and process for making same
US3947255A (en) * 1973-01-10 1976-03-30 American Can Company Method of extruding bark and of forming a solid synthetic fuel
US4040796A (en) * 1975-06-30 1977-08-09 The Kingsford Company Fast lighting artificial firelog
US4169709A (en) * 1975-07-01 1979-10-02 Colgate-Palmolive Company Artificial fireplace logs
US4043765A (en) * 1975-07-11 1977-08-23 Linwo Industries Ltd. Artificial fireplace logs with ignition strips
US4083697A (en) * 1975-07-11 1978-04-11 Reckitt & Colman Products Limited Combustible composition
US4042343A (en) * 1975-09-26 1977-08-16 The Clorox Company Fire log process and apparatus
US4104034A (en) * 1976-07-15 1978-08-01 Duraflame, Inc. Easy lighting fireplace log
US4243393A (en) * 1977-10-13 1981-01-06 Banner Energy Corporation Coal article
US4179269A (en) * 1978-04-12 1979-12-18 Lee Floyd W Synthetic log production
FR2449121A1 (en) * 1979-02-14 1980-09-12 Dg Shelter Prod Co ARTIFICIAL BRIQUETTE
US4243394A (en) * 1979-02-14 1981-01-06 Dg Shelter Products Company Pie segment shaped flammable artificial firelog
US4308033A (en) * 1980-10-23 1981-12-29 Gunnerman Rudolf W Fuel pellet and process for making it by shaping under pressure an organic fibrous material
US4612017A (en) * 1981-02-18 1986-09-16 Georgia-Pacific Corporation Pelletizing wood
US4883498A (en) * 1988-07-01 1989-11-28 Sebring Forest Industries, Inc. Artificial firelog
US6139786A (en) * 1989-02-09 2000-10-31 Corry; Arthur A. Method of forming a flexible mold and resulting article
US5112365A (en) * 1991-01-25 1992-05-12 Sebring Forest Industries, Inc. Fuel block
US5679248A (en) * 1995-12-19 1997-10-21 Kimberly-Clark Worldwide, Inc. Coextruded blocks and applications therefor
US5711766A (en) * 1996-02-26 1998-01-27 Forest Technology Corporation Wood fire starter having improved stacking properties
US6086646A (en) * 1996-10-21 2000-07-11 Meske; Albin F. Apparatus for starting a log fire
US6071320A (en) * 1996-10-21 2000-06-06 Meske; Albin F. Apparatus for starting a log fire
US5858036A (en) * 1997-05-28 1999-01-12 Conros Corporation Artificial fire log
ES2142260A1 (en) * 1998-01-16 2000-04-01 Esfaxa Explotaciones Forestale Method for the manufacture of combustible briquettes
US20040247720A1 (en) * 1998-10-01 2004-12-09 Peterson Gregory J. Artificial firelog and firestarter chip producing apparatus and method and products produced therefrom
US7445442B2 (en) * 1998-10-01 2008-11-04 Peterson Gregory J Artificial firelog and firestarter chip producing apparatus and method and products produced therefrom
US20050011113A1 (en) * 2003-04-07 2005-01-20 Gomez Jose J. Synthetic fireplace log
US20090151239A1 (en) * 2003-04-07 2009-06-18 Gomez Jose J Synthetic fireplace log
US20150020442A1 (en) * 2003-04-07 2015-01-22 Jose J. Gomez Synthetic fireplace log
US20100263271A1 (en) * 2009-04-21 2010-10-21 Lai Kuei Tsai Clean burning bio-coal
US11162043B2 (en) * 2016-07-22 2021-11-02 Campfire Innovations, Llc Combustible log torch

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