US3339588A - Continuous casting mold - Google Patents

Continuous casting mold Download PDF

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Publication number
US3339588A
US3339588A US463147A US46314765A US3339588A US 3339588 A US3339588 A US 3339588A US 463147 A US463147 A US 463147A US 46314765 A US46314765 A US 46314765A US 3339588 A US3339588 A US 3339588A
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US
United States
Prior art keywords
continuous casting
mold
ingot
cobalt
ingot mold
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US463147A
Inventor
Nilles Paul
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Centre de Recherches Metallurgiques CRM ASBL
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Centre de Recherches Metallurgiques CRM ASBL
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/07Alloys based on nickel or cobalt based on cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/041Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for vertical casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/04Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
    • B22D11/059Mould materials or platings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/934Electrical process
    • Y10S428/935Electroplating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/937Sprayed metal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12903Cu-base component
    • Y10T428/1291Next to Co-, Cu-, or Ni-base component

Definitions

  • the present invention relates to an ingot mold used for the continuous casting of metals and more particularly for the continuous casting of steel.
  • the molten metal is poured in a continuous fashion into a ingot mold which, usually, is made of copper and is open above and below.
  • the metal solidifies superficially in this mold to form a pseudo-ingot that is to say an ingot which is not completely solidified, which is drawn out from below down through the ingot mold.
  • the superficial solidification of the molten metal results from the intense cooling that it undergoes on making contact with the walls of the ingot mold which are cooled by the circulation of water.
  • the thin solidified skin tends to adhere or stick to the walls of the ingot mold so as to cause tearing as the ingot is drawn downwards by the extraction mechanism placed below the mold.
  • One particular object of the present invention is to provide a remedy for the disadvantages enumerated above.
  • the present invention is essentially characterised in that the faces of the ingot mold making contact with the ingot are constituted, partially or totally, of cobalt or a cobalt alloy.
  • the walls of the ingot mold can be covered with a protective coating of cobalt applied by spraying, for example by means of a metal coating gun by means of a so-called plasma torch, one or several layers being applied.
  • the protective skin of cobalt can be applied to the walls of the ingot electrolytically.
  • cobalt alloy As an example of the cobalt alloy which can be employed in my invention, it is possible to use an alloy sold under the name of UMCo 50 containing amongst other elements, 50% of cobalt and approximately 30% of chromium.
  • This alloy can of course be applied by metal spraying of electrolytically.
  • the walls themselves can be made of the alloy, UMCo 50.
  • the walls of the ingot mold can be made of cobalt.
  • FIG. 1 denotes the casing of the mold which is generally cylindrical and is separated from the inner part of the mold by a gap 2 serving for-the circulation of water which is supplied through annular ducts 3 and 4 respectively at the bottom and top of the ingot mold.
  • composition of UMCo 50 is as follows:
  • An ingot mold for the continuous casting of metals having metal-contacting faces formed of cobalt.
  • An ingot mold for the continuous casting of metals having metal-contacting faces formed of an alloy of cobalt containing 50% of cobalt and approximataely 30% of chromium.
  • An ingot mold for the continuous casting of steel having internal walls formed by a cobalt containing alloy.
  • An ingot mold for the continuous casting of steel having internal walls formed by a cobalt containing alloy containing 50% of cobalt and approximately 30% chromium.
  • An ingot mold for the continuous casting of steel having internal walls formed of an alloy consisting essentially of .05 to 12% carbon, 27% to 29% chromium, 48% to 52% cobalt and the balance essentially iron.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Continuous Casting (AREA)

Description

Filed June 11, 1965 United States Patent 3,339,588 CONTINUOUS CASTING MOLD Paul Nilles, Embourg, Belgium, assignor to Centre National de Recherches Metallurgiques, Brussels, Belgium, a Belgian company Filed June 11, 1965, Ser. No. 463,147 Claims priority, application g ilrembourg, June 13, 1964,
46, 6 Claims. (Cl. 138145) The present invention relates to an ingot mold used for the continuous casting of metals and more particularly for the continuous casting of steel.
In vertical continuous casting of metals, the molten metal is poured in a continuous fashion into a ingot mold which, usually, is made of copper and is open above and below. The metal solidifies superficially in this mold to form a pseudo-ingot that is to say an ingot which is not completely solidified, which is drawn out from below down through the ingot mold.
The superficial solidification of the molten metal results from the intense cooling that it undergoes on making contact with the walls of the ingot mold which are cooled by the circulation of water.
In the course of the peripheral solidification of the metal it is however noted that the thin solidified skin tends to adhere or stick to the walls of the ingot mold so as to cause tearing as the ingot is drawn downwards by the extraction mechanism placed below the mold.
Prior art workers have suggested various remedies for preventing this tearing. For instance it has been suggested that the internal walls of the ingot mold should be lubricated and/ or should be caused to reciprocate vertically. However all these suggestions appear to have substantial disadvantages. Moreover the use of copper molds for continuous casting has the disadvantage that small molten particles or copper are plucked off from the internal walls of the mold and diffuse into the steel. In consequence the steel becomes red short as is testified by the appearance of flaws. In order to overcome this disadvantage it has been suggested that the inside of the mold should be chromium plated since chromium does not dissolve in steel at least not when it is used for lining continuous casting molds. It has also been proposed to line ingot molds made of copper with other metals such as molybdenum.
One particular object of the present invention is to provide a remedy for the disadvantages enumerated above.
The present invention is essentially characterised in that the faces of the ingot mold making contact with the ingot are constituted, partially or totally, of cobalt or a cobalt alloy.
In accordance with the invention, the walls of the ingot mold can be covered with a protective coating of cobalt applied by spraying, for example by means of a metal coating gun by means of a so-called plasma torch, one or several layers being applied.
Alternatively, in accordance with the invention, the protective skin of cobalt can be applied to the walls of the ingot electrolytically.
As an example of the cobalt alloy which can be employed in my invention, it is possible to use an alloy sold under the name of UMCo 50 containing amongst other elements, 50% of cobalt and approximately 30% of chromium.
This alloy can of course be applied by metal spraying of electrolytically.
Alternatively, instead of applying the alloy to the inner walls of the ingot mold, the walls themselves can be made of the alloy, UMCo 50.
Furthermore the walls of the ingot mold can be made of cobalt.
One embodiment of the invention shown in the attached drawing which is a vertical section.
In this drawing 1 denotes the casing of the mold which is generally cylindrical and is separated from the inner part of the mold by a gap 2 serving for-the circulation of water which is supplied through annular ducts 3 and 4 respectively at the bottom and top of the ingot mold.
Inside the casing 2 there is a copper sheath 5 of annular cross section and this is coated internally, by a process known as explosive plating with UMCo 50. This coating is denoted by reference numeral 6 and reference numeral 7 is used to indicate the passage through which the solidifying ingot passes downwards through the mold.
The composition of UMCo 50 is as follows:
C 0.05-0.12 Mn 0.5-1 Si 0.5-1 P max 0.02 S max 0.02 Cr 27-29 Co 48-52 Fe Remainder Its physical properties are as follows:
Melting zone C 1380-1395 Specific gravit 8.05 Coeflicient of thermal expansion C 16.8. l0 Thermal conductivity (25 C.) 0.0215
While I have described several forms of my invention in order that those skilled in the art may put it into effect, it is to be understood that the invention is not limited to the particular forms described above but is to be delimited by the gist and scope of the following patent claims.
I claim:
1. An ingot mold for the continuous casting of metals, the ingot mold having metal-contacting faces formed of cobalt.
2. An ingot mold for the continuous casting of metals, the ingot mold having internal faces covered with a protective layer of cobalt.
3. An ingot mold for the continuous casting of metals, the ingot mold having metal-contacting faces formed of an alloy of cobalt containing 50% of cobalt and approximataely 30% of chromium.
4. An ingot mold for the continuous casting of steel having internal walls formed by a cobalt containing alloy.
5. An ingot mold for the continuous casting of steel having internal walls formed by a cobalt containing alloy containing 50% of cobalt and approximately 30% chromium.
6. An ingot mold for the continuous casting of steel having internal walls formed of an alloy consisting essentially of .05 to 12% carbon, 27% to 29% chromium, 48% to 52% cobalt and the balance essentially iron.
References Cited UNITED STATES PATENTS 2,358,171 9/ 1949 Lindemuth 2491 14 3,035,934 5/1962 Cape 117-131 X 3,055,089 9/1962 Drummond 117-131 X 3,059,325 10/1962 Taylor et al 117l31 X 3,102,044 8/1963 Joseph 11713l X 3,302,251 2/1967 Speith et al. 249-116 X LAVERNE D. GEIGER, Primary Examiner. C. L. HOUCK, Assistant Examiner.

Claims (1)

1. AN INGOT MOLD FOR THE CONTINUOUS CASTING OF METALS, THE INGOT MOLD HAVING METAL-CONTACTING FACES FORMED OF COBALT.
US463147A 1964-06-13 1965-06-11 Continuous casting mold Expired - Lifetime US3339588A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
LU46316 1964-06-13

Publications (1)

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US3339588A true US3339588A (en) 1967-09-05

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US (1) US3339588A (en)
BE (1) BE664575A (en)
GB (1) GB1090145A (en)
LU (1) LU46316A1 (en)
NL (1) NL6507471A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3990498A (en) * 1974-12-16 1976-11-09 Metallurgie Hoboken-Overpelt Method of continuous casting
US4037646A (en) * 1975-06-13 1977-07-26 Sumitomo Metal Industries, Ltd. Molds for continuously casting steel
US4235583A (en) * 1978-03-23 1980-11-25 General Motors Corporation Extrusion die and method for making same
US4633994A (en) * 1983-06-20 1987-01-06 Eaton Corporation Viscous fan drive and axially movable valve element
EP0144725B1 (en) * 1983-11-03 1988-06-01 Egon Evertz Continuous casting mould
US5626179A (en) * 1994-06-09 1997-05-06 Ald Vacuum Technologies Gmbh Process for manufacture of castings of reactive metals

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2358171A (en) * 1941-12-11 1944-09-12 Steel Ingot Production Inc Ingot mold
US3035934A (en) * 1957-05-13 1962-05-22 Coast Metals Inc Application of cobalt-base alloys to metal parts
US3055089A (en) * 1958-08-06 1962-09-25 Union Carbide Corp Gaseous metal product and processes
US3059325A (en) * 1956-06-21 1962-10-23 Taylor Tristram Allan Heat resisting alloys
US3102044A (en) * 1960-09-12 1963-08-27 United Aircraft Corp Applying protective coating from powdered material utilizing high temperature and low pressure
US3302251A (en) * 1962-10-18 1967-02-07 Mannesmann Ag Molybdenum lined mold for continuous casting

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2358171A (en) * 1941-12-11 1944-09-12 Steel Ingot Production Inc Ingot mold
US3059325A (en) * 1956-06-21 1962-10-23 Taylor Tristram Allan Heat resisting alloys
US3035934A (en) * 1957-05-13 1962-05-22 Coast Metals Inc Application of cobalt-base alloys to metal parts
US3055089A (en) * 1958-08-06 1962-09-25 Union Carbide Corp Gaseous metal product and processes
US3102044A (en) * 1960-09-12 1963-08-27 United Aircraft Corp Applying protective coating from powdered material utilizing high temperature and low pressure
US3302251A (en) * 1962-10-18 1967-02-07 Mannesmann Ag Molybdenum lined mold for continuous casting

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3990498A (en) * 1974-12-16 1976-11-09 Metallurgie Hoboken-Overpelt Method of continuous casting
US4037646A (en) * 1975-06-13 1977-07-26 Sumitomo Metal Industries, Ltd. Molds for continuously casting steel
US4235583A (en) * 1978-03-23 1980-11-25 General Motors Corporation Extrusion die and method for making same
US4633994A (en) * 1983-06-20 1987-01-06 Eaton Corporation Viscous fan drive and axially movable valve element
EP0144725B1 (en) * 1983-11-03 1988-06-01 Egon Evertz Continuous casting mould
US5626179A (en) * 1994-06-09 1997-05-06 Ald Vacuum Technologies Gmbh Process for manufacture of castings of reactive metals

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Publication number Publication date
NL6507471A (en) 1965-12-14
GB1090145A (en) 1967-11-08
BE664575A (en) 1965-09-16
LU46316A1 (en) 1972-01-01

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