US2559091A - Method and solution for producing insecticidal aerosols - Google Patents
Method and solution for producing insecticidal aerosols Download PDFInfo
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- US2559091A US2559091A US632175A US63217545A US2559091A US 2559091 A US2559091 A US 2559091A US 632175 A US632175 A US 632175A US 63217545 A US63217545 A US 63217545A US 2559091 A US2559091 A US 2559091A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
- B05B9/08—Apparatus to be carried on or by a person, e.g. of knapsack type
- B05B9/0805—Apparatus to be carried on or by a person, e.g. of knapsack type comprising a pressurised or compressible container for liquid or other fluent material
- B05B9/0833—Apparatus to be carried on or by a person, e.g. of knapsack type comprising a pressurised or compressible container for liquid or other fluent material comprising a compressed gas container, e.g. a nitrogen cartridge
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- the present invention relates to the production of aerosols or aerocolloids.
- liquefied gases such as Freon-12 as the solvent or carrier for the material to be dispersed, which solvent or carrier evaporates rapidly when the solution or mixture is sprayed into the atmosphere is objectionable for domestic insect sprays, because of explosion hazards and other dangers involved, since storage and transportation under high pressure is necessary to maintain the liquefied gases in the liquid phase.
- Solvents such as acetone or alcohol that are liquid at atmospheric temperature but have a boiling point sufficiently low to evaporate fairly readily and that are dispersed by a gas such as carbon dioxide dissolved therein are also objectionable for domestic insect sprays because they are characterized by one or more of the following objections: inflammability, toxicity, irritancy to the eyes, the nasal and the bronchial tracts, and injuriousness to drapes, wall paper and furniture.
- solubility for carbon dioxide gas which solubility is not so great that an inordinately large amount must be dissolved to obtain the desired dispersion of the carrier or solvent and yet is adequate to produce a solution by dissolving a relatively small amount, say from 8 to 10 grams, in about 100 cc. of the solvent, from which solution, when sprayed, carbon dioxide gas escapes with explosive force to form particles so minute that their surface area is large compared to their volume and the solvent or carrier content of which particles promptly evaporates to produce the desired aerosol particles.
- Another object is to provide as a new article of commerce, 2, novel solution or mixture of a parasiticide, disinfectant, or other material to be dispersed in a solvent or carrier, which solution or mixture has properties which render it eminently satisfactory for producing an aerosol of such material.
- Still another object is to provide an improved apparatus for producing aerosols, which apparatus is designed to use a readily available carbon dioxide bulb or cartridge, such as the well-known Sparklet containing a relatively small amount of carbon dioxide, from 8 to 10 grams, and does not require a special charging device for introducing the carbon dioxide into the solution of material to be dispersed when it is desired to form the aerosol.
- a readily available carbon dioxide bulb or cartridge such as the well-known Sparklet containing a relatively small amount of carbon dioxide, from 8 to 10 grams
- trichlor monofluor methane which is liquid at ordinary atmospheric tempera-; tures, uniquely presents the desired properties of importance for insecticide or disinfectant sprays for domestic use. More especially, trichlor monofluor methane has a relatively low boiling point of about 25 C. (at 760 mm.
- the material to be dispersed in the form of an aerosol or aerocolloid is dissolved in or mixed with trichlor monofluor methane, and the resultant solution, when it is desired to produce the aerosol, placed under super-atmospheric pressure, such that when the pressure is released the solution is dispersed in finely divided form into the atmosphere to form the desired aerosol.
- the pressure under which the solution is placed when it is desired to produce the aerosol may be created in any suitable manner.
- carbon dioxide or other gas is dissolved in the solution, thereby placing the solution under a pressure, desirably of at least 40 pounds per square inch gauge, preferably within the range of to 225 pounds per square. inch gauge.
- the solution may be placed under such pressure by heating it as disclosed in copending application Serial No. 638,879 of Z. M. Roehr, now issued as Patent No. 2,440,915, dated May 4, 1948, to increase the vapor pressure of the solution when it is desired to produce the aerosol.
- This invention includes broadly the placing of a solution or mixture of trichlor monofluor methane and material to be dispersed as solute under pressure in any desired manner, and includes specifically the charging of such solution or mixture with carbon dioxide to place the same under the desired pressure, followed by release of the pressure when it is desired to produce the aerosol, the carbon dioxide thereby flashing into the atmosphere, dispersing the solution in small droplets; upon evaporation of the solvent or carrier, which results in further subdivision of the particle size of the material to be dispersed, the desired aerosol results.
- DDT chloro diphenyl trichlorethane
- pyrethrins pyrethrins
- rotenone sesame oil and other insecticides
- fungicides fungicides
- fumigants soluble or dispersible in trichlor monofluor methane.
- This invention is particularly effective for producing aerosols of DDT and pyrethrin mixtures, which mixtures combine the desirable properties of pyrethrins, which has the efiect of giving rapid but notlasting control when used, for example, to control flies or mosquitoes, and DDT which gives initially slow but lasting control when used to combat flies and mosquitoes.
- This invention accordingly includes solutions or mixtures of parasiticides and other materials to be dispersed in trichlor monofiuor methane, specifically solutions of DDT, pyrethrin, and mixtures of DDT and pyrethrin in trichlor monoiluor methane.
- disinfectants which may be employed are triethylene glycol and propylene glycol.
- disinfectants While not soluble in trichlor monofluor methane, are soluble for example ina mixture of. trichlor monofluor meth ane and methylene chloride, or amixture of trichlor monofiuor methane and acetone; for example, the constituents may be mixed in the proportion-of- 10 parts by weight of triethylene glycol to 65 parts of the trichlor monofiuor methane and 25 parts of methylene chloride.
- the amount of material to be dispersed, dissolved in or admixed with trichlor monofluor methane, will depend on the. intended use for the aerosols, the conditions under which. it is used, e.. g., the size of the room, chamber, cabin or other spaceto-be treated for the purpose of killing inse'ct pests, fumigating or disinfecting the room, chamber. or other space, the temperature and pressure. conditions prevailing therein,v the degreeof infestation in the case where the aerosol is used to control insect pests, etc. proximately 5 to 25 parts by weight of material to be dispersed per 100 parts of solvent or carri'er will usually be found satisfactory.
- the solution or mixture of material to be dispersed in the trichlor monofiuor methane may be stored and shipped as an article of commerce, oralternatively the individual constituents may be stored and shipped separately and combined when it is desired to produce the aerosol. Since the parasiticidal materials, disinfectants or other materials to be dispersed in general have little or no. appreciable. vapor pressure, the resultant solution thereof in or mixture thereof with trichlor. monofluor methane has a vapor pressure which. is equal to or slightly below that of the trichlor monofluor methane, and hence the solutions or mixtures can bestored and transported in arsimilar manner to aqueous solutions. When it.
- the solution or mixture may be placed in a container capable of From apwithstanding high pressures of the order of 125 to 225 pounds per square inch gauge, which con tainer is equipped, for example, with a carbon dioxide charging device such as the well-known and readily available bulbs or cartridges containing from 8 to 10 grams of liquid carbon dioxide under a pressure of from 800 to 1000 pounds per square inch.
- a carbon dioxide charging device such as the well-known and readily available bulbs or cartridges containing from 8 to 10 grams of liquid carbon dioxide under a pressure of from 800 to 1000 pounds per square inch.
- Figure I is a. vertical section through one form of apparatus embodying this invention, showing the parts of the apparatus in position such that the solution of material to be dispersed and the carbon dioxide are stored separately, no flow of carbon dioxide taking place into the solution;
- Figure 2 is a vertical section through the apparatus, showing the parts in position such that fiow'of carbon dioxidetakes place from the carbon dioxide cartridge into the solution of the material to be dispersed.
- container l0 desirably of steel or other metal capable of withstanding relatively high pressures of the order of to 225 pounds per square inch, has a discharge tube H therein extending from a point just above base 12 into head 13.
- a needle valve I4 is provided in the head 13- for controlling flow through orifice l5, valve M being operated by handle 16 connected to valve stem H1 in threaded engagement with a threaded cylindrical opening in head 43.
- Orifice l5 and the needle valve M are dimensioned and designed to produce atomization of solution discharged through the orifice I5.
- Container II] is provided with anopening I8 which is normally maintained closed by plug l9, which opening permits the introduction of the solution into the container ID.
- Base [2 of container ID has depending therefrom a threaded cylindrical flange 18.
- a housing [9 has its top 20 in threaded engagement with the threaded portion of flange l8.
- Collar 22 is provided with a rubber gasket 24 which may be in the form of a disc as. shown in the drawing or may be of annular shape.
- a check valve 28 desirably in the form of a rubber or other flexible material diaphragm having one end 28 cemented or otherwise secured to base I2 and the other end. free to permit upward movement of the free end is. disposed at the top of plug 2! to close the upper portion of the hollow pin 25, preventing flow of liquid in. container l0 through this hollow pin.
- Check. valve 28 permits flow of gas through the hollow pin into the container 50, as will be hereinafter more fully described.
- a carbon dioxide cartridge or bulb 239 such as the well-known Sparklet, is disposed in housing i9 resting on concave support 39 on base 35 of housing l9.
- the upper neck portion of the bulb engages rubber gasket 24, collar 22' being so dimensioned that a gas-tight seal is produced.
- a tween the neck portion of the bulb andthe collar 22 preventing escape of gas from the bulb, when a wall thereof has been penetrated, into the housing I9, and causing substantially the entire gascontent of the cartridge to flow into container I 0.
- these parts may be associated with the top portion of container Ill so that when the carbon dioxide cartridge is pierced, the carbon dioxide flows into the top of container Hi. In the latter design, it is unnecessary to use a check valve for preventing flow of solution into the carbon dioxide cartridge.
- the apparatus may be shipped in commerce with or without the container l9 filled with the solution of material to be dispersed and desirably without the carbon dioxide cartridge or bulb in housing i9.
- a carbon dioxide cartridge or bulb is placed in housing l9 as shown in Fig. 1, with the sharp end of the pin 26 in contact with the upper wall of the cartridge, or if a disc type gasket 24 is used, as shown in the drawing, in contact with the upper wall of this gasket.
- the housing is is threaded on to the flange l8, so that the cartridge is held firmly in position between collar 22 and support 30, without the sharp end of pin 26 penetrating the wall of the cartridge. If the solution of material to be dispersed in trichlor monofluor methane has not previously been introduced in container [0, it is introduced thereinto and the needle valve H! is closed.
- the housing I9 When it is desired to produce the aerosol, the housing I9 is moved into the position shown in Fig. 2, to move the cartridge vertically upwardly, so that the pin 26 penetrates the upper wall thereof, as shown in Fig. 2, causing the carbon dioxide to flow from the cartridge 29 into the solution in container l0. Flow of solution from container i0 is prevented by the check valve 28 and needle valve it; check valve 28 permitting flow of the carbon dioxide into the solution but preventing flow of solution in a downward direction, into the housing IE3 or cartridge 29.
- container preferably is dimensioned so that, with the container half to threequarters filled, a standard carbon dioxide bulb used for producing carbonated water will result in the production of a pressure of from 125 to 225 pounds per square inch in the solution.
- container I 6 may be made larger and two or more carbon dioxide bulbs used to place the solution under the desired pressure.
- the handle 16 of the needle valve may be moved to efiect partial opening of the needle valve.
- the pressure within the container causes the solution to flow through the discharge tube H into and through the discharge orifice l5.
- the solution flashes into the atmosphere due to the re- .lease of the carbon dioxide and is thereby subdivided into small droplets of the material to be dispersed in the solvent trichlor monofluor methane.
- the solute is further subdivided, producing a stable aerosol.
- Container It! may be refilled whenever desired, the solvent being supplied from a bottle or can containing it at a normal pressure.
- the process and apparatus herein described are particularly applicable to the production of aerosols of DDT and pyrethrins to combat flies, mosquitoes and other insect pests.
- trichlor monofluor methane as the solvent or carrier for the material to be dispersed eliminates the dangers and hazards attendant upon the storage and transportation of liquefied gases heretofore employed in the production of aerosols, since trichlor monofluor methane can be stored andtransported without danger at a normal pressure.
- trichlor monofluor methane combines, to anexceptional extent, the desirable properties required for the production of aerosols; namely, it is'not inflammable, has a slight but agreeable odor, is of high density, is a good solvent for commonly used parasiticides, disinfectants and fumigants, has just the proper solubility characteristic for carbon dioxide permitting use of this gas for effecting dispersion of the solvent or carrier and the contained material to be dispersed, is re-.
- the apparatus of this invention employs readily available carbon dioxide bulbs or cartridges such as the well known Sparklets for placing the solution under superatmospheric pressure when it is desired to produce the aerosol, and hence eliminates the need for special charging devices for this purpose.
- the method of producing an aerosol which comprises storing a solution of the material to be dispersed in trichlor monofluor methane under a pressure not greatly differing from the vapor pressure of trichlor monofluor methane, storing said solution in an air tight container at approximately atmospheric pressure, dissolving liquefied carbon dioxide in said solution to produce a solution under a pressure of from to 225 pounds per square inch gauge, and releasing the pressure to disperse the solution into the atmosphere in finely divided form, whereby the solute is dispersed into the atmosphere to form the aerosol.
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Description
July 3, 1951 J. R. REASENB'ERG 9,
METHOD AND SOLUTION FOR PRODUCING INSECTICIDAL AEROSOLS Filed Dec. 1, 1945 s 1? 19' J5 9' \l g K 18 42 58 8 --Q6 v 2 #18 7 20 N INVENTOR I JaZzdnEJFeasnfie/y ATTORNEYS Patented July 3, 1951 METHOD AND SOLUTION FOR PRODUCING INSECTICIDAL AEROSOLS Julian R. Reasenberg, Brooklyn, N. Y., assignor to Mizzy, Inc., a corporation of New York Application December 1, 1945, Serial N 0. 632,175
4 Claims. 1
The present invention relates to the production of aerosols or aerocolloids.
The use of liquefied gases such as Freon-12 as the solvent or carrier for the material to be dispersed, which solvent or carrier evaporates rapidly when the solution or mixture is sprayed into the atmosphere is objectionable for domestic insect sprays, because of explosion hazards and other dangers involved, since storage and transportation under high pressure is necessary to maintain the liquefied gases in the liquid phase.
Solvents such as acetone or alcohol that are liquid at atmospheric temperature but have a boiling point sufficiently low to evaporate fairly readily and that are dispersed by a gas such as carbon dioxide dissolved therein are also objectionable for domestic insect sprays because they are characterized by one or more of the following objections: inflammability, toxicity, irritancy to the eyes, the nasal and the bronchial tracts, and injuriousness to drapes, wall paper and furniture.
It is among the objects of the present invention to provide a method for producing aerosols, employing a carrier or solvent, which though liquid at or near room temperature, has a boiling point materially lower than those of acetone and alcohol, which is non-inflammable, non-corrosive, non-toxic, non-irritant to the bronchial or nasal tracts, which is an excellent solvent or carrier for a wide variety of insecticides and disinfectants, which has a relatively high density so that a relatively small volume is required to form a dispersion consisting of a definite weight of the solvent or carrier, and which has a. solubility for carbon dioxide gas, which solubility is not so great that an inordinately large amount must be dissolved to obtain the desired dispersion of the carrier or solvent and yet is adequate to produce a solution by dissolving a relatively small amount, say from 8 to 10 grams, in about 100 cc. of the solvent, from which solution, when sprayed, carbon dioxide gas escapes with explosive force to form particles so minute that their surface area is large compared to their volume and the solvent or carrier content of which particles promptly evaporates to produce the desired aerosol particles.
Another object is to provide as a new article of commerce, 2, novel solution or mixture of a parasiticide, disinfectant, or other material to be dispersed in a solvent or carrier, which solution or mixture has properties which render it eminently satisfactory for producing an aerosol of such material.
Still another object is to provide an improved apparatus for producing aerosols, which apparatus is designed to use a readily available carbon dioxide bulb or cartridge, such as the well-known Sparklet containing a relatively small amount of carbon dioxide, from 8 to 10 grams, and does not require a special charging device for introducing the carbon dioxide into the solution of material to be dispersed when it is desired to form the aerosol.
Other objects and advantages of this invention will be apparent from the following description thereof.
I have discovered that a specific compound more particularly trichlor monofluor methane, which is liquid at ordinary atmospheric tempera-; tures, uniquely presents the desired properties of importance for insecticide or disinfectant sprays for domestic use. More especially, trichlor monofluor methane has a relatively low boiling point of about 25 C. (at 760 mm. of mercury pressure), has a high vapor pressure so that it evaporates readily, is non-inflammable, has a slight but agreeable odor, is non-toxic and non-irritant, is an excellent solvent or carrier for various parasiticides including insecticides and fungicides, and disinfectants that are commonly used, has a high density about 1.5, and has just the proper solubility characteristics for carbon dioxide, absorbing as it does about thirt times its volume of such gas at pounds per square inch gauge pressure.
According to this discovery, the material to be dispersed in the form of an aerosol or aerocolloid is dissolved in or mixed with trichlor monofluor methane, and the resultant solution, when it is desired to produce the aerosol, placed under super-atmospheric pressure, such that when the pressure is released the solution is dispersed in finely divided form into the atmosphere to form the desired aerosol. The pressure under which the solution is placed when it is desired to produce the aerosol may be created in any suitable manner. Preferably, carbon dioxide or other gas is dissolved in the solution, thereby placing the solution under a pressure, desirably of at least 40 pounds per square inch gauge, preferably within the range of to 225 pounds per square. inch gauge. The solution may be placed under such pressure by heating it as disclosed in copending application Serial No. 638,879 of Z. M. Roehr, now issued as Patent No. 2,440,915, dated May 4, 1948, to increase the vapor pressure of the solution when it is desired to produce the aerosol. This invention includes broadly the placing of a solution or mixture of trichlor monofluor methane and material to be dispersed as solute under pressure in any desired manner, and includes specifically the charging of such solution or mixture with carbon dioxide to place the same under the desired pressure, followed by release of the pressure when it is desired to produce the aerosol, the carbon dioxide thereby flashing into the atmosphere, dispersing the solution in small droplets; upon evaporation of the solvent or carrier, which results in further subdivision of the particle size of the material to be dispersed, the desired aerosol results.
Among the materials which may be dispersed in the form of an aerosol employing as the solvent or carrier trichlor monofiuor methane in accordance with this invention, are DDT (clichloro diphenyl trichlorethane), pyrethrins, rotenone, sesame oil and other insecticides, fungicides, disinfectants and fumigants soluble or dispersible in trichlor monofluor methane. This invention is particularly effective for producing aerosols of DDT and pyrethrin mixtures, which mixtures combine the desirable properties of pyrethrins, which has the efiect of giving rapid but notlasting control when used, for example, to control flies or mosquitoes, and DDT which gives initially slow but lasting control when used to combat flies and mosquitoes. This invention accordingly includes solutions or mixtures of parasiticides and other materials to be dispersed in trichlor monofiuor methane, specifically solutions of DDT, pyrethrin, and mixtures of DDT and pyrethrin in trichlor monoiluor methane. Examples of disinfectants which may be employed are triethylene glycol and propylene glycol. These disinfectants, While not soluble in trichlor monofluor methane, are soluble for example ina mixture of. trichlor monofluor meth ane and methylene chloride, or amixture of trichlor monofiuor methane and acetone; for example, the constituents may be mixed in the proportion-of- 10 parts by weight of triethylene glycol to 65 parts of the trichlor monofiuor methane and 25 parts of methylene chloride.
The amount of material to be dispersed, dissolved in or admixed with trichlor monofluor methane, will depend on the. intended use for the aerosols, the conditions under which. it is used, e.. g., the size of the room, chamber, cabin or other spaceto-be treated for the purpose of killing inse'ct pests, fumigating or disinfecting the room, chamber. or other space, the temperature and pressure. conditions prevailing therein,v the degreeof infestation in the case where the aerosol is used to control insect pests, etc. proximately 5 to 25 parts by weight of material to be dispersed per 100 parts of solvent or carri'er will usually be found satisfactory.
The solution or mixture of material to be dispersed in the trichlor monofiuor methane may be stored and shipped as an article of commerce, oralternatively the individual constituents may be stored and shipped separately and combined when it is desired to produce the aerosol. Since the parasiticidal materials, disinfectants or other materials to be dispersed in general have little or no. appreciable. vapor pressure, the resultant solution thereof in or mixture thereof with trichlor. monofluor methane has a vapor pressure which. is equal to or slightly below that of the trichlor monofluor methane, and hence the solutions or mixtures can bestored and transported in arsimilar manner to aqueous solutions. When it. isdesired to form the aerosols, the solution or mixture may be placed in a container capable of From apwithstanding high pressures of the order of 125 to 225 pounds per square inch gauge, which con tainer is equipped, for example, with a carbon dioxide charging device such as the well-known and readily available bulbs or cartridges containing from 8 to 10 grams of liquid carbon dioxide under a pressure of from 800 to 1000 pounds per square inch.
In the accompanying drawing forming a part of this specification and showing, for purposes of exemplification, a preferred form of apparatus for practicing the process of this invention, without limiting the claimed invention to such illustrative instance,
Figure I is a. vertical section through one form of apparatus embodying this invention, showing the parts of the apparatus in position such that the solution of material to be dispersed and the carbon dioxide are stored separately, no flow of carbon dioxide taking place into the solution; and
Figure 2 is a vertical section through the apparatus, showing the parts in position such that fiow'of carbon dioxidetakes place from the carbon dioxide cartridge into the solution of the material to be dispersed.
In the drawing, container l0, desirably of steel or other metal capable of withstanding relatively high pressures of the order of to 225 pounds per square inch, has a discharge tube H therein extending from a point just above base 12 into head 13. A needle valve I4 is provided in the head 13- for controlling flow through orifice l5, valve M being operated by handle 16 connected to valve stem H1 in threaded engagement with a threaded cylindrical opening in head 43. Orifice l5 and the needle valve M are dimensioned and designed to produce atomization of solution discharged through the orifice I5. Container II] is provided with anopening I8 which is normally maintained closed by plug l9, which opening permits the introduction of the solution into the container ID.
Base [2 of container ID has depending therefrom a threaded cylindrical flange 18. A housing [9 has its top 20 in threaded engagement with the threaded portion of flange l8. A central opening. in base I2 is closed by a plug 2!, having a depending collar 22, the upper portion of which is in gas-tight. engagement with the underside of the base 12; packing 23 is inserted in the annular space between the underside of base i2 and the=upper portion of collar 22 to produce this gas-tight seal. Collar 22 is provided with a rubber gasket 24 which may be in the form of a disc as. shown in the drawing or may be of annular shape.
Extending through plug 2| is a hollow pin 25 having a pointed end 21. A check valve 28 desirably in the form of a rubber or other flexible material diaphragm having one end 28 cemented or otherwise secured to base I2 and the other end. free to permit upward movement of the free end is. disposed at the top of plug 2! to close the upper portion of the hollow pin 25, preventing flow of liquid in. container l0 through this hollow pin. Check. valve 28 permits flow of gas through the hollow pin into the container 50, as will be hereinafter more fully described.
A carbon dioxide cartridge or bulb 239,, such as the well-known Sparklet, is disposed in housing i9 resting on concave support 39 on base 35 of housing l9. The upper neck portion of the bulb engages rubber gasket 24, collar 22' being so dimensioned that a gas-tight seal is produced. be-
a tween the neck portion of the bulb andthe collar 22, preventing escape of gas from the bulb, when a wall thereof has been penetrated, into the housing I9, and causing substantially the entire gascontent of the cartridge to flow into container I 0. Instead of having the support and connection for the carbon dioxide cartridge with the base of container 10, these parts may be associated with the top portion of container Ill so that when the carbon dioxide cartridge is pierced, the carbon dioxide flows into the top of container Hi. In the latter design, it is unnecessary to use a check valve for preventing flow of solution into the carbon dioxide cartridge.
The apparatus may be shipped in commerce with or without the container l9 filled with the solution of material to be dispersed and desirably without the carbon dioxide cartridge or bulb in housing i9. Just before it is desired to produce the aerosol, a carbon dioxide cartridge or bulb is placed in housing l9 as shown in Fig. 1, with the sharp end of the pin 26 in contact with the upper wall of the cartridge, or if a disc type gasket 24 is used, as shown in the drawing, in contact with the upper wall of this gasket. The housing is is threaded on to the flange l8, so that the cartridge is held firmly in position between collar 22 and support 30, without the sharp end of pin 26 penetrating the wall of the cartridge. If the solution of material to be dispersed in trichlor monofluor methane has not previously been introduced in container [0, it is introduced thereinto and the needle valve H! is closed.
When it is desired to produce the aerosol, the housing I9 is moved into the position shown in Fig. 2, to move the cartridge vertically upwardly, so that the pin 26 penetrates the upper wall thereof, as shown in Fig. 2, causing the carbon dioxide to flow from the cartridge 29 into the solution in container l0. Flow of solution from container i0 is prevented by the check valve 28 and needle valve it; check valve 28 permitting flow of the carbon dioxide into the solution but preventing flow of solution in a downward direction, into the housing IE3 or cartridge 29. For household use, container preferably is dimensioned so that, with the container half to threequarters filled, a standard carbon dioxide bulb used for producing carbonated water will result in the production of a pressure of from 125 to 225 pounds per square inch in the solution. For
industrial uses, container I 6 may be made larger and two or more carbon dioxide bulbs used to place the solution under the desired pressure.
After the solution has been charged with the carbon dioxide resulting in the production of a pressure in container ID of at least 40 pounds per square inch gauge, preferably within the range of 125 to 225 pounds per square inch gauge, the handle 16 of the needle valve may be moved to efiect partial opening of the needle valve. The pressure within the container causes the solution to flow through the discharge tube H into and through the discharge orifice l5. The solution flashes into the atmosphere due to the re- .lease of the carbon dioxide and is thereby subdivided into small droplets of the material to be dispersed in the solvent trichlor monofluor methane. Upon evaporation of the solvent content of the droplets which takes place rapidly due'to the relatively high vapor pressure of this solvent, the solute is further subdivided, producing a stable aerosol.
Container It! may be refilled whenever desired, the solvent being supplied from a bottle or can containing it at a normal pressure.
The process and apparatus herein described are particularly applicable to the production of aerosols of DDT and pyrethrins to combat flies, mosquitoes and other insect pests.
It will be noted the use of trichlor monofluor methane as the solvent or carrier for the material to be dispersed eliminates the dangers and hazards attendant upon the storage and transportation of liquefied gases heretofore employed in the production of aerosols, since trichlor monofluor methane can be stored andtransported without danger at a normal pressure. Furthermore, trichlor monofluor methane combines, to anexceptional extent, the desirable properties required for the production of aerosols; namely, it is'not inflammable, has a slight but agreeable odor, is of high density, is a good solvent for commonly used parasiticides, disinfectants and fumigants, has just the proper solubility characteristic for carbon dioxide permitting use of this gas for effecting dispersion of the solvent or carrier and the contained material to be dispersed, is re-.
markably non-toxic to human beings, is non-irritating and is of relatively high volatility at room temperatures. Moreover, the apparatus of this invention employs readily available carbon dioxide bulbs or cartridges such as the well known Sparklets for placing the solution under superatmospheric pressure when it is desired to produce the aerosol, and hence eliminates the need for special charging devices for this purpose.
The term solution i used in the specification and claims in a broad sense and is intended to include not only true solutions, but also colloidal solutions, dispersions and mixtures in which the material to be dispersed in the form of an aerosol is distributed in trichlor monofluor methane alone or with added materials such as methylene chloride.
As many changes could be made in the above process and apparatus and many apparently widely different embodiments of this invention could be made without departing from the scope of the claims, it is intended that all matter contained in the above description or shown in the accompanying drawings, shall be interpreted as illustrative and not in a limiting sense.
Having thus described my invention, what I claim as new and desire to secure by Letters Pat-- ent of the United States is:
1. The method of producing an aerosol which comprises storing a solution of the material to be dispersed in trichlor monofluor methane under a pressure not greatly differing from the vapor pressure of trichlor monofluor methane, storing said solution in an air tight container at approximately atmospheric pressure, dissolving liquefied carbon dioxide in said solution to produce a solution under a pressure of from to 225 pounds per square inch gauge, and releasing the pressure to disperse the solution into the atmosphere in finely divided form, whereby the solute is dispersed into the atmosphere to form the aerosol.
2. A liquid solution of a parasiticide in trichlor monofluor methane and carbon dioxide under pressure.
3. A liquid solution of dichloro diphenyl trichlorethane in trichlor monofluor methane and carbon dioxide under pressure.
4. A liquid solution of dichloro diphenyl trichlorethane and pyrethrin in tri'chlor monofiuor methane and carbon dioxide under pressure.
JULIAN R. REASENBERG.
REFERENCES. CITED/ The following references are of record in the file of this patent? UNITED STATES PATENTS.
Number Name Date- Ka-uff'man Apr. 30, 1967 Mason May 2, 1933 Altmann Nov. 21 1933 Shrader et a1; Apr. 14, 1936 Id'di'ngs Feb, 9, 1937- Gleave Jan. 7, 193 8 Rotheim Aug. 30, 1938 Plastaras Mar. '7, 1939 Number I Number Name Date Sullivan June 6, 1942 Goodhue June 8, 1943 Robertson Nov; 2, 1943 Rich Apr. 4, 1944 Rotheim May 16, 1944 McGora'n Sept. 26, 1944 Rhodes Sept. 21, 1948 FOREIGN PATENTS Country Date Great Britain Sept. 1'7, 1925 OTHER REFERENCES Smith et al.: J. Econ. Entomology, vol. 38, No.
2, April 1945, page 175.
Soap and Sanitary Chemicals, vol. 20, No. 5, May 1944, pages 111 and 113.
Claims (1)
- 2. A LIQUID SOLUTION OF A PARASITICIDE IN TRICHLOR MONOFLUOR METHANE AND CARBON DIOXIDE UNDER PRESSURE.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US632175A US2559091A (en) | 1945-12-01 | 1945-12-01 | Method and solution for producing insecticidal aerosols |
Applications Claiming Priority (1)
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US632175A US2559091A (en) | 1945-12-01 | 1945-12-01 | Method and solution for producing insecticidal aerosols |
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US2559091A true US2559091A (en) | 1951-07-03 |
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US632175A Expired - Lifetime US2559091A (en) | 1945-12-01 | 1945-12-01 | Method and solution for producing insecticidal aerosols |
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Cited By (42)
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US2694602A (en) * | 1950-12-09 | 1954-11-16 | Knapp Monarch Co | Liquid dispenser |
US2729124A (en) * | 1950-12-21 | 1956-01-03 | Farandatos Denis | Cork extractor with gas pressure generating means |
US2820761A (en) * | 1953-09-25 | 1958-01-21 | Specialties Dev Corp | Carbon dioxide composition |
US2964165A (en) * | 1956-11-13 | 1960-12-13 | Chempel Inc | Corrosion resistant aerosol package containing hydrolyzable material |
US3166096A (en) * | 1961-10-03 | 1965-01-19 | Lang Helmut | Dispenser for liquid additives to fluid streams |
US3188954A (en) * | 1958-05-14 | 1965-06-15 | Paul G Roach | Gas ejection bomb for dispersing solid particulates |
US3192950A (en) * | 1962-09-21 | 1965-07-06 | Zeldin | Apparatus for injecting material into a fluid flow |
US3239412A (en) * | 1962-07-23 | 1966-03-08 | Johnson & Son Inc S C | Method of pressure packaging products having a petroleum base |
US3251420A (en) * | 1964-04-20 | 1966-05-17 | Fire Guard Corp | Fire extinguisher with bottom mounted cartridge |
US3342672A (en) * | 1964-05-07 | 1967-09-19 | Air Reduction | Combination propellant system using nitrous oxide |
US3727840A (en) * | 1971-08-19 | 1973-04-17 | Gillette Co | Dispersant container and dispenser |
US3853125A (en) * | 1971-10-05 | 1974-12-10 | W Clark | Disposable needleless injector |
US3993245A (en) * | 1975-02-06 | 1976-11-23 | Shell Oil Company | Method and apparatus for spraying agrochemicals |
WO1983000316A1 (en) * | 1981-07-27 | 1983-02-03 | SZABO, Miklós | Device for discharging pourable material from closed space by means of gas of over-atmospheric pressure |
US4385714A (en) * | 1980-11-25 | 1983-05-31 | Miklos Szabo | Apparatus for and method of spreading gaseous, liquid and powdered materials |
DE3445977A1 (en) * | 1984-01-06 | 1985-07-18 | Duna Elelmiszer és Vegyiáru Kereskedelmi Vállalat, Budapest | APPARATUS FOR DISPENSING LIQUID MEDIA FROM A CONTAINER WITH THE AID OF COMPRESSED AIR, AND METHOD AND DEVICE FOR APPLYING, OR REFILLING OF SUCH CONTAINERS |
DE3640199A1 (en) * | 1986-11-25 | 1988-06-01 | Dekanovsky Walter | AEROSOL PACKAGING |
EP0425300A2 (en) * | 1989-10-27 | 1991-05-02 | Roussel-Uclaf | Metering and dispensing system |
US5954268A (en) * | 1997-03-03 | 1999-09-21 | Joshi; Ashok V. | Fluid delivery system |
US20050100646A1 (en) * | 2003-11-12 | 2005-05-12 | Giacobbe Frederick W. | Cold shock method improvements |
US20080179763A1 (en) * | 2004-01-22 | 2008-07-31 | Ewald Schmon | Paint Reservoir System For A Paint Spray Gun |
DE102007027412A1 (en) * | 2007-06-11 | 2008-12-18 | Dräger, Karl-Heinz | Method for improvement of quantitative throughput and holding width of irritants and lacrimators, involves applying pressure and discharge pressure of liquid solution gas in increased manner |
US20110174901A1 (en) * | 2008-10-29 | 2011-07-21 | Peter Dettlaff | Gravity cup for a paint sprayer |
USD740393S1 (en) | 2013-09-27 | 2015-10-06 | Sata Gmbh & Co. Kg | Paint spray gun |
US9327301B2 (en) | 2008-03-12 | 2016-05-03 | Jeffrey D. Fox | Disposable spray gun cartridge |
USD758537S1 (en) | 2014-07-31 | 2016-06-07 | Sata Gmbh & Co. Kg | Paint spray gun rear portion |
US9409197B2 (en) | 2013-12-18 | 2016-08-09 | Sata Gmbh & Co. Kg | Air nozzle closure for a spray gun |
USD768820S1 (en) | 2014-09-03 | 2016-10-11 | Sata Gmbh & Co. Kg | Paint spray gun with pattern |
USD770593S1 (en) | 2014-07-31 | 2016-11-01 | Sata Gmbh & Co. Kg | Paint spray gun |
US9533317B2 (en) | 2009-07-08 | 2017-01-03 | Sata Gmbh & Co. Kg | Paint spray gun |
US9782785B2 (en) | 2010-12-02 | 2017-10-10 | Sata Gmbh & Co. Kg | Spray gun and accessories |
US9782784B2 (en) | 2010-05-28 | 2017-10-10 | Sata Gmbh & Co. Kg | Nozzle head for a spray device |
US9878336B2 (en) | 2006-12-05 | 2018-01-30 | Sata Gmbh & Co. Kg | Fluid reservoir for a paint spray gun |
US10189037B2 (en) | 2011-06-30 | 2019-01-29 | Sata Gmbh & Co. Kg | Easy-to-clean spray gun, accessories therefor, and mounting and dismounting methods |
US10464076B2 (en) | 2015-12-21 | 2019-11-05 | Sata Gmbh & Co. Kg | Air cap and nozzle assembly for a spray gun, and spray gun |
US10471449B2 (en) | 2016-08-19 | 2019-11-12 | Sata Gmbh & Co. Kg | Air cap arrangement and spray gun |
US10702879B2 (en) | 2014-07-31 | 2020-07-07 | Sata Gmbh & Co. Kg | Spray gun manufacturing method, spray gun, spray gun body and cover |
US10835911B2 (en) | 2016-08-19 | 2020-11-17 | Sata Gmbh & Co. Kg | Trigger for a spray gun and spray gun having same |
US11141747B2 (en) | 2015-05-22 | 2021-10-12 | Sata Gmbh & Co. Kg | Nozzle arrangement for a spray gun |
US11801521B2 (en) | 2018-08-01 | 2023-10-31 | Sata Gmbh & Co. Kg | Main body for a spray gun, spray guns, spray gun set, method for producing a main body for a spray gun and method for converting a spray gun |
US11826771B2 (en) | 2018-08-01 | 2023-11-28 | Sata Gmbh & Co. Kg | Set of nozzles for a spray gun, spray gun system, method for embodying a nozzle module, method for selecting a nozzle module from a set of nozzles for a paint job, selection system and computer program product |
US11865558B2 (en) | 2018-08-01 | 2024-01-09 | Sata Gmbh & Co. Kg | Nozzle for a spray gun, nozzle set for a spray gun, spray guns and methods for producing a nozzle for a spray gun |
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Cited By (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2694602A (en) * | 1950-12-09 | 1954-11-16 | Knapp Monarch Co | Liquid dispenser |
US2729124A (en) * | 1950-12-21 | 1956-01-03 | Farandatos Denis | Cork extractor with gas pressure generating means |
US2820761A (en) * | 1953-09-25 | 1958-01-21 | Specialties Dev Corp | Carbon dioxide composition |
US2964165A (en) * | 1956-11-13 | 1960-12-13 | Chempel Inc | Corrosion resistant aerosol package containing hydrolyzable material |
US3188954A (en) * | 1958-05-14 | 1965-06-15 | Paul G Roach | Gas ejection bomb for dispersing solid particulates |
US3166096A (en) * | 1961-10-03 | 1965-01-19 | Lang Helmut | Dispenser for liquid additives to fluid streams |
US3239412A (en) * | 1962-07-23 | 1966-03-08 | Johnson & Son Inc S C | Method of pressure packaging products having a petroleum base |
US3192950A (en) * | 1962-09-21 | 1965-07-06 | Zeldin | Apparatus for injecting material into a fluid flow |
US3251420A (en) * | 1964-04-20 | 1966-05-17 | Fire Guard Corp | Fire extinguisher with bottom mounted cartridge |
US3342672A (en) * | 1964-05-07 | 1967-09-19 | Air Reduction | Combination propellant system using nitrous oxide |
US3727840A (en) * | 1971-08-19 | 1973-04-17 | Gillette Co | Dispersant container and dispenser |
US3853125A (en) * | 1971-10-05 | 1974-12-10 | W Clark | Disposable needleless injector |
US3993245A (en) * | 1975-02-06 | 1976-11-23 | Shell Oil Company | Method and apparatus for spraying agrochemicals |
US4385714A (en) * | 1980-11-25 | 1983-05-31 | Miklos Szabo | Apparatus for and method of spreading gaseous, liquid and powdered materials |
WO1983000316A1 (en) * | 1981-07-27 | 1983-02-03 | SZABO, Miklós | Device for discharging pourable material from closed space by means of gas of over-atmospheric pressure |
DE3445977A1 (en) * | 1984-01-06 | 1985-07-18 | Duna Elelmiszer és Vegyiáru Kereskedelmi Vállalat, Budapest | APPARATUS FOR DISPENSING LIQUID MEDIA FROM A CONTAINER WITH THE AID OF COMPRESSED AIR, AND METHOD AND DEVICE FOR APPLYING, OR REFILLING OF SUCH CONTAINERS |
DE3640199A1 (en) * | 1986-11-25 | 1988-06-01 | Dekanovsky Walter | AEROSOL PACKAGING |
EP0425300A2 (en) * | 1989-10-27 | 1991-05-02 | Roussel-Uclaf | Metering and dispensing system |
EP0425300A3 (en) * | 1989-10-27 | 1992-01-22 | The Wellcome Foundation Limited | Metering and dispensing system |
US5954268A (en) * | 1997-03-03 | 1999-09-21 | Joshi; Ashok V. | Fluid delivery system |
US20050100646A1 (en) * | 2003-11-12 | 2005-05-12 | Giacobbe Frederick W. | Cold shock method improvements |
US20080179763A1 (en) * | 2004-01-22 | 2008-07-31 | Ewald Schmon | Paint Reservoir System For A Paint Spray Gun |
US7819341B2 (en) * | 2004-01-22 | 2010-10-26 | Sata Gmbh & Co. Kg | Paint reservoir system for a paint spray gun |
US9878336B2 (en) | 2006-12-05 | 2018-01-30 | Sata Gmbh & Co. Kg | Fluid reservoir for a paint spray gun |
DE102007027412B4 (en) * | 2007-06-11 | 2011-07-21 | Dräger, Karl-Heinz, 10117 | Method and device for delivering irritants and warfare agents |
DE102007027412A1 (en) * | 2007-06-11 | 2008-12-18 | Dräger, Karl-Heinz | Method for improvement of quantitative throughput and holding width of irritants and lacrimators, involves applying pressure and discharge pressure of liquid solution gas in increased manner |
US9327301B2 (en) | 2008-03-12 | 2016-05-03 | Jeffrey D. Fox | Disposable spray gun cartridge |
US8925836B2 (en) | 2008-10-29 | 2015-01-06 | Sata Gmbh & Co. Kg | Gravity cup for a paint sprayer |
US20110174901A1 (en) * | 2008-10-29 | 2011-07-21 | Peter Dettlaff | Gravity cup for a paint sprayer |
US9533317B2 (en) | 2009-07-08 | 2017-01-03 | Sata Gmbh & Co. Kg | Paint spray gun |
US9782784B2 (en) | 2010-05-28 | 2017-10-10 | Sata Gmbh & Co. Kg | Nozzle head for a spray device |
US9782785B2 (en) | 2010-12-02 | 2017-10-10 | Sata Gmbh & Co. Kg | Spray gun and accessories |
US10189037B2 (en) | 2011-06-30 | 2019-01-29 | Sata Gmbh & Co. Kg | Easy-to-clean spray gun, accessories therefor, and mounting and dismounting methods |
USD740393S1 (en) | 2013-09-27 | 2015-10-06 | Sata Gmbh & Co. Kg | Paint spray gun |
US9409197B2 (en) | 2013-12-18 | 2016-08-09 | Sata Gmbh & Co. Kg | Air nozzle closure for a spray gun |
US10702879B2 (en) | 2014-07-31 | 2020-07-07 | Sata Gmbh & Co. Kg | Spray gun manufacturing method, spray gun, spray gun body and cover |
USD770593S1 (en) | 2014-07-31 | 2016-11-01 | Sata Gmbh & Co. Kg | Paint spray gun |
USD835235S1 (en) | 2014-07-31 | 2018-12-04 | Sata Gmbh & Co. Kg | Paint spray gun |
USD758537S1 (en) | 2014-07-31 | 2016-06-07 | Sata Gmbh & Co. Kg | Paint spray gun rear portion |
USD798419S1 (en) | 2014-07-31 | 2017-09-26 | Sata Gmbh & Co. Kg | Paint spray gun |
USD768820S1 (en) | 2014-09-03 | 2016-10-11 | Sata Gmbh & Co. Kg | Paint spray gun with pattern |
US11141747B2 (en) | 2015-05-22 | 2021-10-12 | Sata Gmbh & Co. Kg | Nozzle arrangement for a spray gun |
US10464076B2 (en) | 2015-12-21 | 2019-11-05 | Sata Gmbh & Co. Kg | Air cap and nozzle assembly for a spray gun, and spray gun |
US10471449B2 (en) | 2016-08-19 | 2019-11-12 | Sata Gmbh & Co. Kg | Air cap arrangement and spray gun |
US10835911B2 (en) | 2016-08-19 | 2020-11-17 | Sata Gmbh & Co. Kg | Trigger for a spray gun and spray gun having same |
US11801521B2 (en) | 2018-08-01 | 2023-10-31 | Sata Gmbh & Co. Kg | Main body for a spray gun, spray guns, spray gun set, method for producing a main body for a spray gun and method for converting a spray gun |
US11826771B2 (en) | 2018-08-01 | 2023-11-28 | Sata Gmbh & Co. Kg | Set of nozzles for a spray gun, spray gun system, method for embodying a nozzle module, method for selecting a nozzle module from a set of nozzles for a paint job, selection system and computer program product |
US11865558B2 (en) | 2018-08-01 | 2024-01-09 | Sata Gmbh & Co. Kg | Nozzle for a spray gun, nozzle set for a spray gun, spray guns and methods for producing a nozzle for a spray gun |
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