US2288184A - Method of making stainless-clad sheet steel - Google Patents

Method of making stainless-clad sheet steel Download PDF

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US2288184A
US2288184A US266607A US26660739A US2288184A US 2288184 A US2288184 A US 2288184A US 266607 A US266607 A US 266607A US 26660739 A US26660739 A US 26660739A US 2288184 A US2288184 A US 2288184A
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sheets
rolls
steel
stainless steel
sheet
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US266607A
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Howard W Dodson
David G Neuman
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K11/00Resistance welding; Severing by resistance heating
    • B23K11/16Resistance welding; Severing by resistance heating taking account of the properties of the material to be welded
    • B23K11/20Resistance welding; Severing by resistance heating taking account of the properties of the material to be welded of different metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K11/00Resistance welding; Severing by resistance heating
    • B23K11/002Resistance welding; Severing by resistance heating specially adapted for particular articles or work
    • B23K11/0026Welding of thin articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K11/00Resistance welding; Severing by resistance heating
    • B23K11/06Resistance welding; Severing by resistance heating using roller electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/939Molten or fused coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/94Pressure bonding, e.g. explosive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12951Fe-base component
    • Y10T428/12972Containing 0.01-1.7% carbon [i.e., steel]
    • Y10T428/12979Containing more than 10% nonferrous elements [e.g., high alloy, stainless]

Definitions

  • the present invention relates to a certain new and useful method of making stainless clad steel, although the method of the present invention may be applied to any other composite sheet metal formed of two pie-formed sheets of metal.
  • Stainless steel is an expensive metal compared to the more common ferrous metals, such as structural steel, or ordinary sheet steel of various grades and analyses, and for this reason stainless steel is more or less limited in its uses by economic considerations. For this reason, various attempts have been made to make what is sometimes referred to as armored stainless steel sheets wherein some part of the total thickness of the sheet would be ordinary steel of suitable grade and some other part of the thickness would be stainless steel, so that the sheetwill present a stainless steel surface on one side and an ordinary steel-surface of the other side. Such armored stainless steel sheets wereintended wherever stainless steel surface was desired, but
  • Figure 1 represents a diagrammatic view of apparatus for carrying out the present invention
  • Figure 2 represents a similar diagrammatic View of a modified form of apparatus.
  • Figure 3 represents a diagrammatic perspective view of the welding rolls.
  • a preformed sheet 5 of stainless steel alloy and a preformed sheet 6 of any suitable carbon steel are provided, preferably supplied from corresponding coiled-up supplies I and 8 coiled up on suitable supply rolls 8 and ill.
  • the sheets 5 and 6 may be of any suitable thickness and may indeed be quite thin, running down to small fractions of an inch.
  • the stainless steel sheet 5 may be five or ten thousandths of an inch, while the backing steel sheet 6 may be of any desired thickness depending on the structural strength desired in the resultant two-ply sheet I I.
  • the sheets 5 and 6 may be of any suitable width depending on the current available and the capacity of the machine.
  • the sheets 5 and 6 are fed from the rolls 9 and ID in superposed positions as indicated in the general manner shown in Figure 1, to between a pair of juxtaposed welding rolls l2 and I3 mounted in electrically insulated housings and suitably journalled and having connected to them the opposite terminals of an electrical circuit as indicated in the drawing.
  • Suitable backing rolls l4 and I5 serve to press against the respective welding rolls i2 and I3 and to maintain the pressure therebetween.
  • the welding rolls l2 and i3 are electrically insulated with respect to each other so that current must pass through the sheets 5 and 6.
  • the sheets may either be wound directly upon a take-up roll [6 after they leave the welding rolls l2 and 13, or they may be first passed through one ormore sets of rolls like I! and I8 backed by suitable backing rolls i9 and 20, which serve as a strip mill to reduce the over-all thickness of the composite two ply sheet II to any desired extent. This reduction may be only slight or it may be substantial depending on the desired result.
  • the sheets and 6 are cleaned preliminary to the process hereinabove indicated, by any suitable pickling or cleaning methods, so that the juncture surfaces 2
  • and 22 must be entirely free of scale or other surface formations.
  • All the rolls including the supply rolls 9 and Ill and take-up roll, etc., as well as the welding rolls and strip mill rolls, are suitably journalled in bearings supported by housings in the manner similar to that employed in rolling mills, and these parts are not here shown because they may be of any desired construction indicated by good engineering practice applicable to rolling mills.
  • the working rolls or welding rolls I2 and I3 are made of metal having high electrical con-- ductivity and maximum hardness. Such materials are now known and used as electrodes in resistance welding methods known in the art. These rolls'l2 and I3 may be suitably cooled by water or other meansso as to reduce or minimize the heat efiect thereon by reason of the welding operation.
  • the present method permitsfine reduction in the thickness of the composite or two-ply stainless clad sheet steel, without creating work hardness. It also eliminates or minimizes work hardness already created.
  • the welding heat being accurately controllable acts as an annealing agent. For this reason the method of the present invention permits rolling lighter gauges than heretofore commercially practicable.
  • the present invention also permits a stainless clad steel product at lower cost thereby allowing such composite two-ply sheet metal to enter fields not now using stainless steel because of cost, such as for instance acid and chemical tanks; liquid storage and transportation tanks in general; barrels; water piping; building construction; structural work and the like.
  • the pressure used between the welding rolls l2 and B may be increased so as to assistin the reduction of the thickness, thereby relieving some of the work to be done by the rolls l1 and I8 or other successive pairs of rolls of the same kind.
  • the process or method of the present invention is readily adaptable to continuous mill operations or continuous mill line-up, entailing little or no substantial changes to other machinery or processes.
  • any strips which have been rejected as imperfect or otherwise deficient for commercial use may be built up and re-processed.
  • the amount of current and therefore the heat may be controlled and also the time interval during which each passage of current is permitted to flow through the metal.
  • sheets of various gauges and analyses may be readily assembled on short notice and without detailed scheduling.
  • the relative thickness of the stainless steel alloy sheet and the ordinary sheet steel may be varied, and the analysis or quality ofthe stainless steel and regular steel may also be varied.
  • any two sheets may readily be combined to produce a composite two-ply stainless steel clad sheet having any desired over-all thickness and having any desired thickness of stainless steel alloy and regular steel and having any desired analyses in either of the two plies.
  • the time interval during which each charge of current is passed through is correlated to the speed at which the rolls rotate or the linear speeds of the sheets.
  • the rotation of the rolls l2 and I3 and the movement of the sheets at the welding point may be made intermittent with the motion timed in relation to the passage of current so that with each/passage of current the sheets maybe stationary forthe duration of the current-passage after which thesheets are moved a slight amount for the passage of the next charge of current and so forth. This may not be necessary, however, because the rotation of the rolls I2 and I3 and the linear motion of the sheets 5 and 6 at the welding points may be continuous.
  • the operation of the one or more sets of strip mill rolls may nevertheless be continuous, due allowance being made for allowing a slight slack between the rolls I1 and I8 and the rolls l2 and I3; this slack being made up by any suitable variable or yieldable tensioning device which will maintain the more or less uniform tension notwithstanding the intermittent motion of the rolls l2 and I3 and the continuous motion of the rolls I1 and I8.
  • a generally continuous method of making twoply stainless-clad sheet-steel which comprises bringing together a preformed relatively thin and relatively wide sheet of stainless steel-alloy and a pro-formed sheet of ordinary steel of generally like width, along a line across the sheets, exerting pressure upon said sheets simultaneously to press said sheets together on said line while the widths of said sheets are in substantial registration with each other along said line of pressedcontact, continuously moving successive portions of said sheets into said pressed-line contact in a direction transversely of said line, and intersaid two sheets together substantially continumlttently passing a welding electrical current through said two sheets through substantially the entire line of pressed-contact as successive portions of said sheets are moved into said pressed-line contact, of an intensity and volume and for a sufllcient length of time in relation to the speed of the motion of said sheets to weld 5 said sheets.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Description

June 30, 1942. H. w. DODSON ETAL 2,288,184
METHOD 0? MAKING sumwsswmn SHEET-STEEL Filed April 7, 1939 INVENTOR. .Efoward ED003011 Patented June 30, 1942 METHOD OF MAKING STAINLESS-GLAD SHEET STEEL Howard W. Dodson and David G. Neuman,
Philadelphia, Pa.
Application April 7, 1939, Serial No. 266,607
1 Claim.
The present invention relates to a certain new and useful method of making stainless clad steel, although the method of the present invention may be applied to any other composite sheet metal formed of two pie-formed sheets of metal.
Stainless steel is now well recognized in the art, and for the various compositions or analyses and for the various methods of making stainless steel reference may be had to the known and published art. 1
Stainless steel is an expensive metal compared to the more common ferrous metals, such as structural steel, or ordinary sheet steel of various grades and analyses, and for this reason stainless steel is more or less limited in its uses by economic considerations. For this reason, various attempts have been made to make what is sometimes referred to as armored stainless steel sheets wherein some part of the total thickness of the sheet would be ordinary steel of suitable grade and some other part of the thickness would be stainless steel, so that the sheetwill present a stainless steel surface on one side and an ordinary steel-surface of the other side. Such armored stainless steel sheets wereintended wherever stainless steel surface was desired, but
where the tensile strength of stainless steel was not necessary, that is, where a stainless steel 7 Was not used for structural strength but largely for corrosion resistance, and where an ordinary steel would amply serve for structural strength.
One of the practices in the past has been to make an ingot of a suitable stainless steel alloy and another ingot of anordinary steel of suitable grade, as for instance soft steel, both ingots being the same size. placed one on top of the other while hot and plastic, and the two ingots were then rolled together through rapid rolling operations until the united ingots were thinned down and spread out into a single two-ply sheet in much the same way as that in which ordinary sheet metal is rolled. As the two ingots are flattened out in successive rolling operations they are also firmly united with each other. One of the difficulties encountered by this process has been a comparative lack of uniformity because of the difference in plasticity of the two nigots and therefore the difference in yield under the rolling operation. This process has been unable to produce comparatively thin two-ply armored stainless steel sheets.
One'of the objects of the present invention These two ingots were then 7 and which will be much thinner and hence suitable for many purposes for which a thick sheet is not suitable, and which will be more uniform in the thicknesses of the two different metal layers.
In the accompanying drawing in which like reference characters indicate like parts,
Figure 1 represents a diagrammatic view of apparatus for carrying out the present invention;
Figure 2 represents a similar diagrammatic View of a modified form of apparatus.
Figure 3 represents a diagrammatic perspective view of the welding rolls.
According to the present invention, a preformed sheet 5 of stainless steel alloy and a preformed sheet 6 of any suitable carbon steel are provided, preferably supplied from corresponding coiled-up supplies I and 8 coiled up on suitable supply rolls 8 and ill. The sheets 5 and 6 may be of any suitable thickness and may indeed be quite thin, running down to small fractions of an inch. Thus, the stainless steel sheet 5 may be five or ten thousandths of an inch, while the backing steel sheet 6 may be of any desired thickness depending on the structural strength desired in the resultant two-ply sheet I I.
The sheets 5 and 6 may be of any suitable width depending on the current available and the capacity of the machine.
The sheets 5 and 6 are fed from the rolls 9 and ID in superposed positions as indicated in the general manner shown in Figure 1, to between a pair of juxtaposed welding rolls l2 and I3 mounted in electrically insulated housings and suitably journalled and having connected to them the opposite terminals of an electrical circuit as indicated in the drawing. Suitable backing rolls l4 and I5 serve to press against the respective welding rolls i2 and I3 and to maintain the pressure therebetween. The welding rolls l2 and i3 are electrically insulated with respect to each other so that current must pass through the sheets 5 and 6.
By passing either a continuous but preferably a series of intermittent electrical charges of suitable voltage and amperage and for suitable periods through the rolls l2 and I3, and hence the sheets 5 and 6, these sheets are welded to each other as indicated in Figure 3, the resistance of the sheets 5 and '6 serving to produce heat therein. When using intermittent or individual electrical charges, the successive electrical charges are so timed in relation to the rotation of the rolls l2 and I3 and in relation to the linear speed of the sheets 5 and 6 that the weld produced by one electrical charge passing through the sheets will be slightly overlapped by the next weld produced by the next electrical charge passing through the sheets, and so on, so that the net efl'ect will be a generally continuous weld between the sheets.
The sheets may either be wound directly upon a take-up roll [6 after they leave the welding rolls l2 and 13, or they may be first passed through one ormore sets of rolls like I! and I8 backed by suitable backing rolls i9 and 20, which serve as a strip mill to reduce the over-all thickness of the composite two ply sheet II to any desired extent. This reduction may be only slight or it may be substantial depending on the desired result.
The sheets and 6 are cleaned preliminary to the process hereinabove indicated, by any suitable pickling or cleaning methods, so that the juncture surfaces 2| and 22 thereof are clean and conducive to production of a good wel juncture or union.
Thus, the surfaces 2| and 22 must be entirely free of scale or other surface formations.
All the rolls, including the supply rolls 9 and Ill and take-up roll, etc., as well as the welding rolls and strip mill rolls, are suitably journalled in bearings supported by housings in the manner similar to that employed in rolling mills, and these parts are not here shown because they may be of any desired construction indicated by good engineering practice applicable to rolling mills.
The working rolls or welding rolls I2 and I3 are made of metal having high electrical con-- ductivity and maximum hardness. Such materials are now known and used as electrodes in resistance welding methods known in the art. These rolls'l2 and I3 may be suitably cooled by water or other meansso as to reduce or minimize the heat efiect thereon by reason of the welding operation.
The present method permitsfine reduction in the thickness of the composite or two-ply stainless clad sheet steel, without creating work hardness. It also eliminates or minimizes work hardness already created. The welding heat being accurately controllable acts as an annealing agent. For this reason the method of the present invention permits rolling lighter gauges than heretofore commercially practicable. The present invention also permits a stainless clad steel product at lower cost thereby allowing such composite two-ply sheet metal to enter fields not now using stainless steel because of cost, such as for instance acid and chemical tanks; liquid storage and transportation tanks in general; barrels; water piping; building construction; structural work and the like. I
The pressure used between the welding rolls l2 and B may be increased so as to assistin the reduction of the thickness, thereby relieving some of the work to be done by the rolls l1 and I8 or other successive pairs of rolls of the same kind.
The process or method of the present invention is readily adaptable to continuous mill operations or continuous mill line-up, entailing little or no substantial changes to other machinery or processes.
By the present method also any strips which have been rejected as imperfect or otherwise deficient for commercial use may be built up and re-processed.
The amount of current and therefore the heat may be controlled and also the time interval during which each passage of current is permitted to flow through the metal.
By the present process or method, sheets of various gauges and analyses may be readily assembled on short notice and without detailed scheduling. Thus, the relative thickness of the stainless steel alloy sheet and the ordinary sheet steel may be varied, and the analysis or quality ofthe stainless steel and regular steel may also be varied. Thus, by merely carrying in stock stainless steel sheets ofrelatively few thicknesses or gauges and of relatively few compositions or analyses, and by carrying in stock an assortment of ordinary ,steelsheet metal of various gauges and analyses,. any two sheets may readily be combined to produce a composite two-ply stainless steel clad sheet having any desired over-all thickness and having any desired thickness of stainless steel alloy and regular steel and having any desired analyses in either of the two plies.
As hereinabove pointed out, the time interval during which each charge of current is passed through is correlated to the speed at which the rolls rotate or the linear speeds of the sheets. If desired, however, the rotation of the rolls l2 and I3 and the movement of the sheets at the welding point may be made intermittent with the motion timed in relation to the passage of current so that with each/passage of current the sheets maybe stationary forthe duration of the current-passage after which thesheets are moved a slight amount for the passage of the next charge of current and so forth. This may not be necessary, however, because the rotation of the rolls I2 and I3 and the linear motion of the sheets 5 and 6 at the welding points may be continuous. If, however, an intermittent motion is used at that point, the operation of the one or more sets of strip mill rolls may nevertheless be continuous, due allowance being made for allowing a slight slack between the rolls I1 and I8 and the rolls l2 and I3; this slack being made up by any suitable variable or yieldable tensioning device which will maintain the more or less uniform tension notwithstanding the intermittent motion of the rolls l2 and I3 and the continuous motion of the rolls I1 and I8.
The term ordinary steel where used in the following claim has reference to steel other than the stainless steel used in making up the twoply sheet.
The present invention may be embodied in not restrictive, reference being had-to the appended claim rather than to the foregoing description to indicate the scope of the invention.
Having thus described the invention, what is hereby claimed as new and desired to be secured by Letters Patent, is:
A generally continuous method of making twoply stainless-clad sheet-steel, which comprises bringing together a preformed relatively thin and relatively wide sheet of stainless steel-alloy and a pro-formed sheet of ordinary steel of generally like width, along a line across the sheets, exerting pressure upon said sheets simultaneously to press said sheets together on said line while the widths of said sheets are in substantial registration with each other along said line of pressedcontact, continuously moving successive portions of said sheets into said pressed-line contact in a direction transversely of said line, and intersaid two sheets together substantially continumlttently passing a welding electrical current through said two sheets through substantially the entire line of pressed-contact as successive portions of said sheets are moved into said pressed-line contact, of an intensity and volume and for a sufllcient length of time in relation to the speed of the motion of said sheets to weld 5 said sheets.
ously throughout their contiguous major surfaces by closely-spaced generally parallel line-welds, each formed simultaneously across the width of HOWARD W. DODSON. DAVID G. NEUMAN.
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2515191A (en) * 1946-08-29 1950-07-18 Babcock & Wilcox Co Method of joining metals
US2619715A (en) * 1947-01-07 1952-12-02 Colvilles Ltd Bonding together of metals
US2620552A (en) * 1947-04-11 1952-12-09 Northrop Aircraft Inc Method of spotfastening thin sheets
US2677877A (en) * 1948-04-30 1954-05-11 Cutler Hammer Inc Glass to metal seal and parts thereof and method of making same
US2747064A (en) * 1952-08-22 1956-05-22 North American Aviation Inc Apparatus for making corrugated core structural sheet material
US2787046A (en) * 1951-10-20 1957-04-02 James B Wagstaff Rolling process and apparatus
US2895037A (en) * 1956-06-01 1959-07-14 Western Electric Co Tape welders
US3059094A (en) * 1960-09-23 1962-10-16 Anna Vang Pressure transformer
US3089228A (en) * 1957-07-26 1963-05-14 Post Office Magnetic strip material
US3159463A (en) * 1961-11-24 1964-12-01 Union Carbide Canada Ltd Wear-resistant composite article
US3283118A (en) * 1956-12-10 1966-11-01 Hexcel Products Inc Resistance welded honeycomb core and method of and machine for making same
DE1264218B (en) * 1957-05-22 1968-03-21 Texas Instruments Inc Continuous process for plating forgeable, metallic partners in the solid phase
US3392437A (en) * 1967-11-29 1968-07-16 Olin Mathieson Process for obtaining a composite article
US3597571A (en) * 1968-09-09 1971-08-03 Gillette Co Welding method and apparatus
US3762243A (en) * 1972-03-13 1973-10-02 R Borrkfield Methods of making sharp-edge cutting elements
US4999259A (en) * 1986-11-26 1991-03-12 Nippon Steel Corp. Chrome-coated stainless steel having good atmospheric corrosion resistance

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2515191A (en) * 1946-08-29 1950-07-18 Babcock & Wilcox Co Method of joining metals
US2619715A (en) * 1947-01-07 1952-12-02 Colvilles Ltd Bonding together of metals
US2620552A (en) * 1947-04-11 1952-12-09 Northrop Aircraft Inc Method of spotfastening thin sheets
US2677877A (en) * 1948-04-30 1954-05-11 Cutler Hammer Inc Glass to metal seal and parts thereof and method of making same
US2787046A (en) * 1951-10-20 1957-04-02 James B Wagstaff Rolling process and apparatus
US2747064A (en) * 1952-08-22 1956-05-22 North American Aviation Inc Apparatus for making corrugated core structural sheet material
US2895037A (en) * 1956-06-01 1959-07-14 Western Electric Co Tape welders
US3283118A (en) * 1956-12-10 1966-11-01 Hexcel Products Inc Resistance welded honeycomb core and method of and machine for making same
DE1264218B (en) * 1957-05-22 1968-03-21 Texas Instruments Inc Continuous process for plating forgeable, metallic partners in the solid phase
US3089228A (en) * 1957-07-26 1963-05-14 Post Office Magnetic strip material
US3059094A (en) * 1960-09-23 1962-10-16 Anna Vang Pressure transformer
US3159463A (en) * 1961-11-24 1964-12-01 Union Carbide Canada Ltd Wear-resistant composite article
US3392437A (en) * 1967-11-29 1968-07-16 Olin Mathieson Process for obtaining a composite article
US3597571A (en) * 1968-09-09 1971-08-03 Gillette Co Welding method and apparatus
US3762243A (en) * 1972-03-13 1973-10-02 R Borrkfield Methods of making sharp-edge cutting elements
US4999259A (en) * 1986-11-26 1991-03-12 Nippon Steel Corp. Chrome-coated stainless steel having good atmospheric corrosion resistance

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