US2119608A - Coated glassware - Google Patents

Coated glassware Download PDF

Info

Publication number
US2119608A
US2119608A US30343A US3034335A US2119608A US 2119608 A US2119608 A US 2119608A US 30343 A US30343 A US 30343A US 3034335 A US3034335 A US 3034335A US 2119608 A US2119608 A US 2119608A
Authority
US
United States
Prior art keywords
coating
metal
article
glass
shade
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US30343A
Inventor
Andrew H Stewart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phoenix Glass Co
Original Assignee
Phoenix Glass Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phoenix Glass Co filed Critical Phoenix Glass Co
Priority to US30343A priority Critical patent/US2119608A/en
Application granted granted Critical
Publication of US2119608A publication Critical patent/US2119608A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/38Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material

Definitions

  • My invention relates tothe coating and decorating of glassware whereby a closely adherent metallic surface layer is provided having certain desired characteristics such that it may be empioyed in connection with illuminating ware, sign plates, etc.
  • My invention has for its object the provision of glassware that will have a mirror-like coating of metal, which coating, while it is not so thick as to preclude passage therethrough of all rays of light, is sufficiently continuous to present what appears to be an unbroken minor surface, and is provided with a backing that will insure against minute rays of light shining through the coating.
  • Another object of my invention has been to as provide new and improved procedure for applying metal coatings to glass and similar types of articles.
  • I have particular reference to the steps of moving the glass article relative to the spray gun during the operation whereby a continuous band may be provided, and
  • I also have reference to the steps whereby a pinrality of spray guns are employed which utilize the same or different colored metals to produce desired designs upon the glass article.
  • Figure 1 is a schematic view showing apparatus for applying a metal coating to a lamp shade
  • Fig. 2 is a sectional view showing the shade with the metal coating in place
  • Fig. 3 is a sectional view so showing the backing material on the exposed side of the metal coating.
  • the numeral 3 represents a spray gun which may be of a well-known type, and which contains feed rollers for advancing a metal wire 4 from a spool or reel I.
  • a gas is supplied to the chamber of the gun for melting the wire as rapidly as it is advanced into the gun, and an air blast is also supplied by means of which the molten metal is discharged in an atomized condition, or sprayed from the nozzle 0 of the gun, against the surfaces to be coated.
  • I show a lamp globe or shade I that is supported on a blow pipe 0 by means of which it has been formed within a mold.
  • the blow pipe is rotated slowly upon a support 9 to present desired portions of the surface of the article to the spray.' Upon each revolution of the shade I, it and the gun are shifted relative to one another in a direction axially of the shade.
  • two guns can be employed, each spraying a difierent metal on the article.
  • a single coating ID of metal will perhaps be .0016 inch in thickness, while two spray coatings may have a thickness of .003 inch, it being obvious that the metal can be deposited to any desired thickness.
  • the metal can be sprayed interiorly of the shade instead of exteriorly thereof, if desired.
  • the coated ware can then be passed through an annealing lehr in the usual manner, since the metal coating does not interfere with the proper annealing of the ware, and since the metal coating and the glass body are both subjected to the annealing temperatures, there will be no ruptures developed, and the particles of metal and glass will adjust themselves to one another through the uniform cooling thereof at the discharge end of the lehr.
  • the interior thereof is highly reflective, particularly if one of the lighter colored metals are employed. If the shade be sprayed interlorly-thereof, the reflecting surface will, of course, be presented to the exterior of the .shade. While the exposed side of the deposited metal is somewhat rough, it can be polished readily, without danger of causingit to be chipped or peeled from the glass.
  • Flatglass also can be decorated in the manner described, and if silver, tin, aluminum, or similarly bright metals are employed as a coating material, a highly emcient mirror will be produced that is cheaper than and superior in durability to mirrors of the ordinary type. In cases where so great a percentage of reflection is not desired, some of the darker metals will be employed.
  • a mask of desired pattern may be placed against the article before spraying; also stripes and lines may be applied by the spray gun in desired colors, or two jets of different colors such as silver and gold can be applied to the articles.
  • a fairly thin metal coating When a fairly thin metal coating is applied to the glass, it will, when viewed from the interior of the shade 1, be in efiect a mirror, with no visible holes through the coating. However, when the shade is illuminated interiorly, and viewed from'the outside, pin holes of light are likely to be present, because the light will shine through minute holes in the coating.
  • This backing layer may be in the form of a paint consisting of either any opaque paiht, lacquer, aluminum powder and varnish, bronze powder and varnish, lead paint, etc.
  • the outer layer II will not only seal the metal coating against the discharge oi light, but will produce a smoother surface than that normally present on the exposed side of the metal coating.
  • the painted-on layer can be of the same color as the metal coating, or oi any other desired color or colors,in order to produce desired decorative eflects. Also, it can be of translucent tinted material which will give color effects to light rays that pass through pin holes in the coating.
  • a shaped glass article having a portion of its surface coated with metal sprayed thereon while the article is still hot from the shaping thereof, and having an outer protective coating of translucent tinted material applied to the metal coating and giving color effects to light rays that pass through minute openings in the metal coating.
  • a shaped glass article having a portion of its surface coated with molten metal applied thereto while the article is hot, said metal coating being light reflective when viewed through the glass article and having openings therein, the article having a coating of translucent tinted material applied to the metal coating over the openings therein and giving color effects to light rays that pass through the openings.
  • a shaped, glass article having a portion of its surface coated with molten metal of suitable color applied thereto while the article is hot, said coating having openings between portions thereof, said shaped glass article also having a coating of translucent tinted material applied thereto over the openings of the metal coating and giving color efiect's to light rays that pass through such openings.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)

Description

June 7, 1938. A. H. STEWART COATED GLASSWARE Filed July 8, 1935 INVENTOR Juno 7,
PATENT orrics aliases COATED GLASSWABE mum announce-immune Phomix Glass Company, Monaoa, PL, a corporationol'weat Application July a. 1935, Serial No. 30,343
-3 Claims.
My invention relates tothe coating and decorating of glassware whereby a closely adherent metallic surface layer is provided having certain desired characteristics such that it may be empioyed in connection with illuminating ware, sign plates, etc.
In the spraying of glassware with a light reflective metal coating,it is possible to secure a me'tal coating that appears to be smooth and i continuous when viewed from the opposite side of the glass, and which is highly reflective. However, if the metal coating is not of very great thickness, light which is present at the uncoated side of the glass body will be visible through the coating, in the form of tiny rays which come through what appear to be pin holes in the coating. It is usualLv undesirable to apply the metal layer so thickly that these pin holes are not present, since considerable time and expense is involved in spraying the glass to form a coating of a thickness sufllcient to totally prevent any light rays from passing therethrough. In addition to requiring a greater expenditure for metal, the thicker coating may add to the weight of the 26 article to an undesirable degree.
My invention has for its object the provision of glassware that will have a mirror-like coating of metal, which coating, while it is not so thick as to preclude passage therethrough of all rays of light, is sufficiently continuous to present what appears to be an unbroken minor surface, and is provided with a backing that will insure against minute rays of light shining through the coating.
Another object of my invention has been to as provide new and improved procedure for applying metal coatings to glass and similar types of articles. In this connection, I have particular reference to the steps of moving the glass article relative to the spray gun during the operation whereby a continuous band may be provided, and
I also have reference to the steps whereby a pinrality of spray guns are employed which utilize the same or different colored metals to produce desired designs upon the glass article.
In the accompanying drawing, Figure 1 is a schematic view showing apparatus for applying a metal coating to a lamp shade; Fig. 2 is a sectional view showing the shade with the metal coating in place, and Fig. 3 is a sectional view so showing the backing material on the exposed side of the metal coating.
As shown in the drawing, the numeral 3 represents a spray gun which may be of a well-known type, and which contains feed rollers for advancing a metal wire 4 from a spool or reel I.
A gas is supplied to the chamber of the gun for melting the wire as rapidly as it is advanced into the gun, and an air blast is also supplied by means of which the molten metal is discharged in an atomized condition, or sprayed from the nozzle 0 of the gun, against the surfaces to be coated. In the present case, I show a lamp globe or shade I that is supported on a blow pipe 0 by means of which it has been formed within a mold.
While the metal is being sprayed upon the exterior of the article, the blow pipe is rotated slowly upon a support 9 to present desired portions of the surface of the article to the spray.' Upon each revolution of the shade I, it and the gun are shifted relative to one another in a direction axially of the shade. If desired, two guns can be employed, each spraying a difierent metal on the article. By using metals of contrasting colors, stripes and other decorative effects can be secured. A single coating ID of metal will perhaps be .0016 inch in thickness, while two spray coatings may have a thickness of .003 inch, it being obvious that the metal can be deposited to any desired thickness. The metal can be sprayed interiorly of the shade instead of exteriorly thereof, if desired.
While it has been well-known that metal surfaces can be spray-coated with molten metal in the manner above-described, I have found that I hot glass coated in the manner above-explained is highly desirable for various purposes. Either machine or hand-blown articles as they come from the molds at temperatures of 1000" F. to 1500 F., when sprayed in the manner aboveexplained, will have, an extremely intimate contact with the metal coating. Satisfactory results are also secured when glass is approximately 800 F. To provide a physically adherent coating, I spray the molten metal while the article is still hot from the shaping operation.
The coated ware can then be passed through an annealing lehr in the usual manner, since the metal coating does not interfere with the proper annealing of the ware, and since the metal coating and the glass body are both subjected to the annealing temperatures, there will be no ruptures developed, and the particles of metal and glass will adjust themselves to one another through the uniform cooling thereof at the discharge end of the lehr.
Various metals may be employed such as silver, tin, chromium, aluminum, cadmium, stainless steel, iron, lead and various others, including brass. In the shade shown in the drawing, the
interior thereof is highly reflective, particularly if one of the lighter colored metals are employed. If the shade be sprayed interlorly-thereof, the reflecting surface will, of course, be presented to the exterior of the .shade. While the exposed side of the deposited metal is somewhat rough, it can be polished readily, without danger of causingit to be chipped or peeled from the glass.
Flatglass also can be decorated in the manner described, and if silver, tin, aluminum, or similarly bright metals are employed as a coating material, a highly emcient mirror will be produced that is cheaper than and superior in durability to mirrors of the ordinary type. In cases where so great a percentage of reflection is not desired, some of the darker metals will be employed. p
To produce decorative efiects, a mask of desired pattern may be placed against the article before spraying; also stripes and lines may be applied by the spray gun in desired colors, or two jets of different colors such as silver and gold can be applied to the articles.
When a fairly thin metal coating is applied to the glass, it will, when viewed from the interior of the shade 1, be in efiect a mirror, with no visible holes through the coating. However, when the shade is illuminated interiorly, and viewed from'the outside, pin holes of light are likely to be present, because the light will shine through minute holes in the coating. In order to overcome this objectionable feature, I apply a backing layer II to the metal c'oat ID. This backing layer may be in the form of a paint consisting of either any opaque paiht, lacquer, aluminum powder and varnish, bronze powder and varnish, lead paint, etc. The outer layer II will not only seal the metal coating against the discharge oi light, but will produce a smoother surface than that normally present on the exposed side of the metal coating.
The painted-on layer can be of the same color as the metal coating, or oi any other desired color or colors,in order to produce desired decorative eflects. Also, it can be of translucent tinted material which will give color effects to light rays that pass through pin holes in the coating. v
I claim as my invention:-
1. A shaped glass article having a portion of its surface coated with metal sprayed thereon while the article is still hot from the shaping thereof, and having an outer protective coating of translucent tinted material applied to the metal coating and giving color effects to light rays that pass through minute openings in the metal coating.
2. A shaped glass article having a portion of its surface coated with molten metal applied thereto while the article is hot, said metal coating being light reflective when viewed through the glass article and having openings therein, the article having a coating of translucent tinted material applied to the metal coating over the openings therein and giving color effects to light rays that pass through the openings.
3. A shaped, glass article having a portion of its surface coated with molten metal of suitable color applied thereto while the article is hot, said coating having openings between portions thereof, said shaped glass article also having a coating of translucent tinted material applied thereto over the openings of the metal coating and giving color efiect's to light rays that pass through such openings.
ANDREW H. STEWART.
US30343A 1935-07-08 1935-07-08 Coated glassware Expired - Lifetime US2119608A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US30343A US2119608A (en) 1935-07-08 1935-07-08 Coated glassware

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US30343A US2119608A (en) 1935-07-08 1935-07-08 Coated glassware

Publications (1)

Publication Number Publication Date
US2119608A true US2119608A (en) 1938-06-07

Family

ID=21853773

Family Applications (1)

Application Number Title Priority Date Filing Date
US30343A Expired - Lifetime US2119608A (en) 1935-07-08 1935-07-08 Coated glassware

Country Status (1)

Country Link
US (1) US2119608A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2432795A (en) * 1944-04-20 1947-12-16 Continental Can Co Method of spraying cone tops
US2434125A (en) * 1941-10-01 1948-01-06 Howard V Schweitzer Painting method
US2454270A (en) * 1945-04-10 1948-11-23 Tung Sol Lamp Works Inc Basing electric bulb
US2456653A (en) * 1942-12-10 1948-12-21 Sperry Corp Seal for high-frequency transmission lines
US2536399A (en) * 1946-03-23 1951-01-02 Phoenix Glass Company Glass article and procedure for making it
US2592262A (en) * 1948-03-10 1952-04-08 Eastman Kodak Co Slide mount
US2697671A (en) * 1952-02-27 1954-12-21 Joseph B Brennan Method of spray depositing metal on a base strip
US2824027A (en) * 1955-09-15 1958-02-18 Pennsalt Chemicals Corp Method of making low resistance contact with a lead dioxide electrode
US3117886A (en) * 1960-11-15 1964-01-14 Saint Gobain Corp Colored glass article
US3615327A (en) * 1969-08-20 1971-10-26 Owens Illinois Inc Methods and apparatus for applying oxide coating to glass containers
EP0595585A1 (en) * 1992-10-30 1994-05-04 Ford Motor Company Glass sheets having painted exterior surfaces

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2434125A (en) * 1941-10-01 1948-01-06 Howard V Schweitzer Painting method
US2456653A (en) * 1942-12-10 1948-12-21 Sperry Corp Seal for high-frequency transmission lines
US2432795A (en) * 1944-04-20 1947-12-16 Continental Can Co Method of spraying cone tops
US2454270A (en) * 1945-04-10 1948-11-23 Tung Sol Lamp Works Inc Basing electric bulb
US2536399A (en) * 1946-03-23 1951-01-02 Phoenix Glass Company Glass article and procedure for making it
US2592262A (en) * 1948-03-10 1952-04-08 Eastman Kodak Co Slide mount
US2697671A (en) * 1952-02-27 1954-12-21 Joseph B Brennan Method of spray depositing metal on a base strip
US2824027A (en) * 1955-09-15 1958-02-18 Pennsalt Chemicals Corp Method of making low resistance contact with a lead dioxide electrode
US3117886A (en) * 1960-11-15 1964-01-14 Saint Gobain Corp Colored glass article
US3615327A (en) * 1969-08-20 1971-10-26 Owens Illinois Inc Methods and apparatus for applying oxide coating to glass containers
EP0595585A1 (en) * 1992-10-30 1994-05-04 Ford Motor Company Glass sheets having painted exterior surfaces
US5328753A (en) * 1992-10-30 1994-07-12 Ford Motor Company Glass sheets having painted exterior surfaces

Similar Documents

Publication Publication Date Title
US2119608A (en) Coated glassware
KR940009675B1 (en) Method for preparation of a surface-coated metal-made ornamental article
US3455722A (en) Glass having a colored zone whose boundary has been blurred and method of producing the same
CN113275227B (en) Decoration surface treatment method
US2053923A (en) Glass articles and method of making the same
US3679460A (en) Composite wear resistant material and method of making same
US3787191A (en) Method of producing reflective surfaces and article
ES400128A1 (en) Process for the production of luster color coatings on ceramic, glass of similar bodies
JP2008045168A (en) Metal multi-layered film structure and film deposition method therefor
US3265520A (en) Method of decorating glass bottles
US3338732A (en) Porcelain enamel coating
US2004567A (en) Combinations of enamel and sprayed metal
US1963156A (en) Ornamental glassware
US1926732A (en) Diffusely reflecting surfaces and process of making same
US1706182A (en) Colored or diffusing coating for incandescent lamps and similar articles
US2231481A (en) Ornamental electric light bulb and method of manufacture thereof
US2434290A (en) Electrolytic tin plate
US3117886A (en) Colored glass article
CN206626531U (en) A kind of 3D lampshades with stereoscopic visual effect
US2116345A (en) Method of making lamp housings
US2021819A (en) Production of porcelain enameled articles of changeable color
US2635376A (en) Fire extinguisher
DK87482A (en) PROCEDURE FOR THE MANUFACTURING OF CAKE PRODUCTS
JPS59140363A (en) External parts for pocket watch
KR20180058670A (en) Interior film having hairline pattern and manufacturing process thereof