US20050263247A1 - Plasma processing apparatus and plasma processing method - Google Patents
Plasma processing apparatus and plasma processing method Download PDFInfo
- Publication number
- US20050263247A1 US20050263247A1 US11/060,598 US6059805A US2005263247A1 US 20050263247 A1 US20050263247 A1 US 20050263247A1 US 6059805 A US6059805 A US 6059805A US 2005263247 A1 US2005263247 A1 US 2005263247A1
- Authority
- US
- United States
- Prior art keywords
- photon detection
- plasma processing
- plasma
- wafer stage
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32917—Plasma diagnostics
- H01J37/32935—Monitoring and controlling tubes by information coming from the object and/or discharge
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/12—Testing dielectric strength or breakdown voltage ; Testing or monitoring effectiveness or level of insulation, e.g. of a cable or of an apparatus, for example using partial discharge measurements; Electrostatic testing
- G01R31/1227—Testing dielectric strength or breakdown voltage ; Testing or monitoring effectiveness or level of insulation, e.g. of a cable or of an apparatus, for example using partial discharge measurements; Electrostatic testing of components, parts or materials
- G01R31/1263—Testing dielectric strength or breakdown voltage ; Testing or monitoring effectiveness or level of insulation, e.g. of a cable or of an apparatus, for example using partial discharge measurements; Electrostatic testing of components, parts or materials of solid or fluid materials, e.g. insulation films, bulk material; of semiconductors or LV electronic components or parts; of cable, line or wire insulation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/02—Details
- H01J2237/0203—Protection arrangements
- H01J2237/0206—Extinguishing, preventing or controlling unwanted discharges
Definitions
- the present invention relates to a plasma processing apparatus, and to a plasma processing method, for processing a semiconductor wafer or the like and, more particularly, to a plasma processing apparatus and to a plasma processing method capable of monitoring, in real time, an abnormal discharge phenomenon that can occur during plasma processing.
- Plasma processes such as etching, thin-film deposition, etc. are indispensable for achieving high-quality, high-functionality semiconductor devices.
- one problem involved with such plasma processes is that an abnormal discharge can occur abruptly during processing in a plasma processing apparatus. If an abnormal discharge occurs, etching and thin-film deposition conditions change and, as a result, the characteristics of the produced semiconductor device substantially change. In the worst case, the processing-apparatus may be damaged. Accordingly, in order to produce high-reliability semiconductor devices while ensuring high productivity, it is essential to monitor the occurrence of an abnormal discharge, in real time, during plasma processing and to take quick and appropriate action to deal with the abnormality.
- An abnormal discharge occurs when the large electric charge accumulated on the inside wall of the plasma chamber, etc. either exceeds a limit or is discharged for some reason during plasma processing. As such discharge occurs in an unpredictable manner, and as there are no effective sensing methods for detecting the occurrence, with a prior known plasma processing apparatus, it has not been possible to take appropriate action by detecting the occurrence of such an abnormal discharge in real time, and this has led to the degradation of the productivity, as well as the reliability, of the produced semiconductor device.
- An on-wafer monitoring system has already been proposed that measures the plasma processing state by a sensor build into a semiconductor wafer (Japanese Unexamined Patent Publication 2003-282546).
- This system is one that monitors the energy distribution, ion current, etc., for example, of the ions, electrons, and other particles generated by the plasma, but, as these changes manifest themselves relatively slowly on the semiconductor wafer in contrast with an instantaneous change in the plasma state such as an abnormal discharge, the proposed system is not suitable for real-time monitoring of an abnormal discharge.
- a photon detection sensor for measuring an ultraviolet-light-induced current is placed on a circumferential portion of a substrate mounting surface of the wafer stage.
- the photon detection sensor comprises a semiconductor substrate, an insulating film formed over the semiconductor substrate, an electrode layer embedded in the insulating film, a means for applying a bias voltage to the electrode layer, and a means for detecting a current flowing in the electrode layer.
- the plasma density appreciably drops at that instant because of the discharge, and the generation of ions, neutral particles, electrons, and ultraviolet light by the plasma decreases.
- the photon detection sensor When the photon detection sensor is installed, during the generation of the plasma a certain amount of current induced by the ultraviolet light generated from the plasma is observed in a steady-state condition; however, when the plasma density drops due to an abnormal discharge, and the amount of ultraviolet light generation decreases, then a spike-like current drop is observed. Accordingly, by installing the photon detection sensor on the wafer stage in the plasma processing apparatus, and by monitoring the sensor output in real time, the occurrence of an abnormal discharge manifesting itself as a spike-like current drop can be detected in real time. As a result, quick and appropriate action can be taken to deal with the abnormal discharge.
- the photon detection sensor further comprises a second electrode formed on the insulating film.
- a second electrode formed on the insulating film.
- a plurality of sensors are arranged spaced apart from each other on the wafer stage. With this arrangement, it becomes possible to know the spatial distribution indicating the extent to which the effect of the abnormal discharge has spread, thus making it easier to determine, for example, which devices on the semiconductor wafer are affected.
- a plasma processing method comprises the steps of: placing a plurality of photon detection sensors, each for measuring an ultraviolet-light-induced current, on a wafer stage provided within a plasma chamber; placing the substrate to be processed on the wafer stage; performing plasma processing in the plasma chamber in which the photon detection sensors and the substrate to be processed are placed; and monitoring an output current from each of the photon detection sensors while the plasma processing is being performed.
- the plasma processing method further comprises a step in which, when a spike-like current drop different from a steady-state current is observed in the monitoring step of the photon detection sensors, the spike-like current drop is recognized as indicating the occurrence of an abnormal discharge.
- the current induced by the ultraviolet light generated from the plasma is detected by the photon detection sensor mounted on the wafer stage while the plasma processing of the substrate is being performed; in this way, any abnormal discharge occurring in the plasma chamber can be detected in real time in the form of a change in current value. Accordingly, quick action can be taken to deal with the abnormality, offering the effect of enhancing the reliability and productivity of semiconductor devices.
- FIG. 1 is a diagram showing in simplified form the configuration of a plasma processing apparatus according to one embodiment of the present invention
- FIG. 2 is a plan view of a wafer stage in the plasma processing apparatus shown in FIG. 1 ;
- FIG. 3 is a diagram showing the result of the measurement of an electric current value of a photon detection sensor
- FIG. 4 is a diagram showing a first embodiment of the photon detection sensor used in the plasma processing apparatus of the present invention.
- FIG. 5A is a diagram for explaining one fabrication step for the photon detection sensor shown in FIG. 4 ;
- FIG. 5B is a diagram for explaining another fabrication step for the photon detection sensor shown in FIG. 4 ;
- FIG. 5C is a diagram for explaining a further fabrication step for the photon detection sensor shown in FIG. 4 ;
- FIG. 5D is a diagram for explaining a still further fabrication step for the photon detection sensor shown in FIG. 4 ;
- FIG. 6A is a cross-sectional view in one fabrication step for the photon detection sensor shown in FIG. 4 ;
- FIG. 6B is a plan view of the photon detection sensor shown in FIG. 6A ;
- FIG. 7 is a diagram showing a second embodiment of the photon detection sensor used in the plasma processing apparatus of the present invention.
- FIG. 1 is a diagram showing, in simplified form, the configuration of a plasma processing apparatus according to one embodiment of the present invention.
- Reference numeral 1 is a chamber for performing a plasma process therein; the chamber 1 is equipped with a wafer stage 3 for mounting thereon a substrate to be processed, i.e., a semiconductor wafer 2 .
- a gas excited into a plasma state (hereinafter simply referred to as the plasma) 4 is introduced into the chamber 1 , and a plasma process such as etching or thin-film deposition is performed on the semiconductor wafer 2 .
- the plasma 4 can also be formed within the chamber 1 by applying high-frequency energy from outside the chamber to a gas introduced into the chamber 1 .
- an insulating film for preventing the discharge of the plasma 4 is formed on the inside wall of the chamber 1 .
- FIG. 2 is a plan view of the wafer stage 3 .
- one or more photon detection sensors 5 are arranged on the surface 3 a of the wafer stage 3 on which the semiconductor wafer 2 is to be mounted. The structure of the photon detection sensor and its sensor mechanism will be described later.
- the photon detection sensors 5 are arranged at equally spaced intervals around the circumferential portion of the surface 3 a of the wafer stage 3 .
- a data processing apparatus 6 which performs data processing by detecting a change in an electric current being output from each photon detection sensor 5 , is connected to the photon detection sensors 5 .
- the plasma processing apparatus shown in FIG. 1 detects a change in the electric current value of each of the plurality of photon detection sensors 5 while performing processing of the semiconductor wafer 2 by exposing it to the plasma.
- the present inventor has discovered that when an abnormal discharge occurs within the chamber 1 , the output, i.e., the electric current value, of the photon detection sensor 5 drops in a spike-like manner. Accordingly, by observing the output of each photon detection sensor 5 during the processing of the semiconductor wafer 2 , any abnormal discharge occurring in the chamber 1 can be detected. Further, by simultaneously monitoring the outputs of the plurality of photon detection sensors 5 , it becomes possible to detect the spatial distribution of the abnormal discharge, which shows which portions of the semiconductor wafer 2 are affected by the abnormal discharge.
- FIG. 3 shows one example of how the output of the photon detection sensor 5 changes.
- the ordinate represents the ultraviolet-light-induced current value of the photon detection sensor 5 measured in arbitrarily chosen units, and the abscissa represents the time.
- a current 8 induced by the ultraviolet light generated from the plasma is constantly observed in accordance with a mechanism to be described later and, during that process, a spike-like drop 7 in the electric current value is observed.
- the present inventor has discovered that the spike-like drop 7 is caused by an abnormal discharge occurring in the chamber 1 .
- the time of occurrence, the magnitude, and the spatial distribution of the abnormal discharge in the chamber 1 can be deduced from the detected occurrence of the drop 7 , its magnitude, and the position on the wafer stage 3 of the photon detection sensor 5 whose output exhibited the drop.
- FIG. 4 shows a first embodiment of the photon detection sensor 5 .
- the photon detection sensor 5 is shown as being mounted directly on the bottom of the chamber, but in practice, the sensor is mounted on the wafer stage 3 on which the semiconductor wafer is to be held, as shown in FIG. 1 .
- the same reference numerals as those in FIGS. 1 and 2 designate the same or similar component elements, and the description of such elements will not be repeated here.
- reference numeral 10 is a Si semiconductor substrate
- 11 is a first insulating film formed from SiO 2 or the like
- 12 is an electrode formed from Al
- 13 is a second insulating film formed from SiO 2 or the like.
- a portion of the second insulating film 13 is removed by suitable means such as etching to expose a portion of the electrode 12 .
- a wiring line 14 is connected to the exposed portion, and the current flowing in the electrode 12 is measured by an ammeter 15 .
- Reference numeral 16 is a power supply for applying a bias voltage to the electrode 12 .
- Ions, neutral particles, electrons, and ultraviolet light are generated in the plasma.
- this ultraviolet radiation there is radiation that has large energy and cannot pass through the insulating films 12 and 13 .
- Such ultraviolet radiation is absorbed by the insulating films 12 and 13 and forms electron-hole pairs in the films.
- the holes, whose mobility is lower than the electrons, are trapped by defects formed in the insulating films 12 and 13 , and thus form positive fixed charges.
- a bias voltage is applied to the electrode 12 , these charges can be detected as a hole current by the ammeter 15 .
- the SiO 2 /Si interface there exist many defects formed by so-called dangling bonds of Si.
- the holes formed in the SiO 2 film by absorbing high-energy light such as vacuum ultraviolet light are trapped by such defects formed at the SiO 2 /Si interface, and thus form positive fixed charges. Accordingly, the electric current value measured by the ammeter 15 during plasma processing has correlation with the amount of fixed charge at the SiO 2 /Si interface.
- the steady-state current value 8 shown in FIG. 3 has a relationship with the current generated based on the positive fixed charges.
- the number of positive fixed charges greatly affects the device characteristics. Accordingly, the characteristics of the semiconductor device being produced can be predicted to a certain extent from the measured electric current value.
- the inside surface of the plasma chamber 1 is treated with an insulating film to prevent contact with the high-energy plasma 4 and thereby prevent discharge of the plasma energy. Accordingly, as the plasma process progresses, a large electric charge is accumulated on the insulating film. When the charge accumulation exceeds a limit, or when the accumulated charge is discharged for some reason, an abnormal discharge occurs in the chamber 1 .
- the energy of the plasma 4 is released, and the plasma density thus drops.
- the ultraviolet light generated by the plasma 4 substantially decreases, and the number of electron-hole pairs to be formed in the insulating layers 12 and 13 substantially decreases in a corresponding manner. This decrease is observed by the ammeter 15 as a spike-like drop in the current value, as shown in FIG. 3 .
- FIGS. 5 and 6 are diagrams showing a fabrication process for the ultraviolet-light-induced current measuring photon detection sensor 5 having the structure shown in FIG. 4 .
- the Si substrate 10 is subjected to wet thermal oxidation for 30 minutes at 1000° C., to form the SiO 2 film 11 .
- the thickness of the film 11 is 3 ⁇ m.
- Al as the electrode material is deposited (Al film thickness of 100 nm) to form an electrode layer 12 ′.
- the electrode layer 12 ′ is etched by phosphoric acid (H 3 PO 4 ), to form the electrode 12 of the desired shape as shown in FIG. 5C .
- H 3 PO 4 phosphoric acid
- plasma TEOS tetraethoxysilane, Si(OC 2 H 5 ) 4
- a current measuring lead wire (not shown) is connected to the exposed portion 12 ′′ of the electrode 12 .
- the device is covered with an insulating film (not shown) to prevent charged particles from entering the device through the periphery of the lead wire.
- FIG. 6B is a plan view showing the device shown in FIG. 6A as viewed from the top; here, the electrode 12 is shown through the overlying SiO 2 film 13 , with the portion 12 ′′ of the electrode exposed through the opening formed in the SiO 2 film 13 .
- the sensor When the photon detection sensor 5 is formed as described above, the sensor is mounted on the wafer stage 3 in the plasma chamber 1 , and connected to the power supply 16 and the ammeter 15 outside the chamber 1 via a current lead terminal (not shown) connected to the electrode 12 , and the ammeter 15 measures the electric current value when a bias voltage of 0 to 30 V is applied from the power supply 16 .
- the electric current value when the plasma is not applied is about 10 to 20 pA, which means that virtually no current is flowing.
- the measured sensor output is processed by the data processing apparatus 6 and monitored by the user.
- FIG. 7 is a diagram showing a second embodiment of the photon detection sensor used in the plasma processing apparatus of the present invention.
- the photon detection sensor 50 of this embodiment differs from the photon detection sensor 5 of the structure shown in FIG. 4 in that the SiO 2 film 13 is covered with an Al film 17 about 100 nm in thickness.
- Reference numeral 12 a indicates the lead terminal of the electrode 12 .
- the SiO 2 film 13 is affected by charged particles such as ions and electrons, causing a variation in the measured current value.
- the film 13 is covered with the Al thin film 17 to prevent such particles from penetrating into the film 13 . It is known that ultraviolet light with wavelengths of about 17 nm to 90 nm passes through the Al film. Therefore, by depositing the Al film 17 over the SiO 2 film 13 , the influence only of vacuum ultraviolet light of 90 nm and shorter wavelengths that pass through can be observed by eliminating the influence of ions and electrons.
- the Al film 17 is grounded during plasma exposure.
- the insulating film has been formed from SiO 2 , but the present invention is not limited to this particular material; for example, the insulating film can be equally achieved by using, for example, a nitride film or the like.
- the insulating film need only be formed using the same material as the insulating film formed on the semiconductor wafer or to be formed thereon and processed by etching.
- any abnormal discharge phenomenon occurring in the plasma chamber can be detected in real time during the processing of the semiconductor wafer. Accordingly, when an abnormal discharge occurs, corrective action can be taken quickly, and as a result, semiconductor devices having high reliability can be produced while ensuring high productivity. Further, by arranging a plurality of photon detection sensors on the wafer stage, it becomes possible to know the spatial distribution of the abnormal discharge, so that more appropriate action can be taken to deal with the abnormal discharge.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Drying Of Semiconductors (AREA)
- Plasma Technology (AREA)
Abstract
In a plasma processing apparatus which includes a chamber (1) equipped with a wafer stage (3) for mounting thereon a substrate (2) to be processed, and which processes the substrate (2) by exposure to a plasma (4), a photon detection sensor (5) for measuring an ultraviolet-light-induced current is placed on a circumferential portion of a substrate mounting surface (3 a) of the wafer stage (3) so that the occurrence of an abnormal discharge can be detected, in real time, from a change in the output of the photon detection sensor (5).
Description
- This application claims priority of Japanese Patent Application No. 2004-159531, filed on May 28, 2004.
- The present invention relates to a plasma processing apparatus, and to a plasma processing method, for processing a semiconductor wafer or the like and, more particularly, to a plasma processing apparatus and to a plasma processing method capable of monitoring, in real time, an abnormal discharge phenomenon that can occur during plasma processing.
- Plasma processes such as etching, thin-film deposition, etc. are indispensable for achieving high-quality, high-functionality semiconductor devices. However, one problem involved with such plasma processes is that an abnormal discharge can occur abruptly during processing in a plasma processing apparatus. If an abnormal discharge occurs, etching and thin-film deposition conditions change and, as a result, the characteristics of the produced semiconductor device substantially change. In the worst case, the processing-apparatus may be damaged. Accordingly, in order to produce high-reliability semiconductor devices while ensuring high productivity, it is essential to monitor the occurrence of an abnormal discharge, in real time, during plasma processing and to take quick and appropriate action to deal with the abnormality.
- An abnormal discharge occurs when the large electric charge accumulated on the inside wall of the plasma chamber, etc. either exceeds a limit or is discharged for some reason during plasma processing. As such discharge occurs in an unpredictable manner, and as there are no effective sensing methods for detecting the occurrence, with a prior known plasma processing apparatus, it has not been possible to take appropriate action by detecting the occurrence of such an abnormal discharge in real time, and this has led to the degradation of the productivity, as well as the reliability, of the produced semiconductor device.
- An on-wafer monitoring system has already been proposed that measures the plasma processing state by a sensor build into a semiconductor wafer (Japanese Unexamined Patent Publication 2003-282546). This system is one that monitors the energy distribution, ion current, etc., for example, of the ions, electrons, and other particles generated by the plasma, but, as these changes manifest themselves relatively slowly on the semiconductor wafer in contrast with an instantaneous change in the plasma state such as an abnormal discharge, the proposed system is not suitable for real-time monitoring of an abnormal discharge.
- In view of the above situation, it is an object of the present invention to provide a plasma processing apparatus and plasma processing method that can monitor the plasma state in real time during processing and, more particularly, can monitor in real time the occurrence of an abnormal discharge.
- To achieve the above object, in a plasma processing apparatus according to the present invention which includes a chamber equipped with a wafer stage for mounting thereon a substrate, for example, a semiconductor wafer, to be processed, and which processes the substrate by exposure to a plasma, a photon detection sensor for measuring an ultraviolet-light-induced current is placed on a circumferential portion of a substrate mounting surface of the wafer stage.
- The photon detection sensor comprises a semiconductor substrate, an insulating film formed over the semiconductor substrate, an electrode layer embedded in the insulating film, a means for applying a bias voltage to the electrode layer, and a means for detecting a current flowing in the electrode layer.
- When an abnormal discharge occurs in the plasma chamber, the plasma density appreciably drops at that instant because of the discharge, and the generation of ions, neutral particles, electrons, and ultraviolet light by the plasma decreases. When the photon detection sensor is installed, during the generation of the plasma a certain amount of current induced by the ultraviolet light generated from the plasma is observed in a steady-state condition; however, when the plasma density drops due to an abnormal discharge, and the amount of ultraviolet light generation decreases, then a spike-like current drop is observed. Accordingly, by installing the photon detection sensor on the wafer stage in the plasma processing apparatus, and by monitoring the sensor output in real time, the occurrence of an abnormal discharge manifesting itself as a spike-like current drop can be detected in real time. As a result, quick and appropriate action can be taken to deal with the abnormal discharge.
- The photon detection sensor further comprises a second electrode formed on the insulating film. With the provision of this electrode, the influence of only the ultraviolet light can be observed by eliminating the influence of particles other than the vacuum ultraviolet light, such as ions and electrons. This serves to enhance the accuracy in detecting the occurrence of an abnormal discharge.
- Further, a plurality of sensors, each identical to the above-described photon detection sensor, are arranged spaced apart from each other on the wafer stage. With this arrangement, it becomes possible to know the spatial distribution indicating the extent to which the effect of the abnormal discharge has spread, thus making it easier to determine, for example, which devices on the semiconductor wafer are affected.
- To achieve the above object, a plasma processing method according to the present invention comprises the steps of: placing a plurality of photon detection sensors, each for measuring an ultraviolet-light-induced current, on a wafer stage provided within a plasma chamber; placing the substrate to be processed on the wafer stage; performing plasma processing in the plasma chamber in which the photon detection sensors and the substrate to be processed are placed; and monitoring an output current from each of the photon detection sensors while the plasma processing is being performed.
- The plasma processing method further comprises a step in which, when a spike-like current drop different from a steady-state current is observed in the monitoring step of the photon detection sensors, the spike-like current drop is recognized as indicating the occurrence of an abnormal discharge.
- According to the above method, the current induced by the ultraviolet light generated from the plasma is detected by the photon detection sensor mounted on the wafer stage while the plasma processing of the substrate is being performed; in this way, any abnormal discharge occurring in the plasma chamber can be detected in real time in the form of a change in current value. Accordingly, quick action can be taken to deal with the abnormality, offering the effect of enhancing the reliability and productivity of semiconductor devices.
-
FIG. 1 is a diagram showing in simplified form the configuration of a plasma processing apparatus according to one embodiment of the present invention; -
FIG. 2 is a plan view of a wafer stage in the plasma processing apparatus shown inFIG. 1 ; -
FIG. 3 is a diagram showing the result of the measurement of an electric current value of a photon detection sensor; -
FIG. 4 is a diagram showing a first embodiment of the photon detection sensor used in the plasma processing apparatus of the present invention; -
FIG. 5A is a diagram for explaining one fabrication step for the photon detection sensor shown inFIG. 4 ; -
FIG. 5B is a diagram for explaining another fabrication step for the photon detection sensor shown inFIG. 4 ; -
FIG. 5C is a diagram for explaining a further fabrication step for the photon detection sensor shown inFIG. 4 ; -
FIG. 5D is a diagram for explaining a still further fabrication step for the photon detection sensor shown inFIG. 4 ; -
FIG. 6A is a cross-sectional view in one fabrication step for the photon detection sensor shown inFIG. 4 ; -
FIG. 6B is a plan view of the photon detection sensor shown inFIG. 6A ; -
FIG. 7 is a diagram showing a second embodiment of the photon detection sensor used in the plasma processing apparatus of the present invention. -
FIG. 1 is a diagram showing, in simplified form, the configuration of a plasma processing apparatus according to one embodiment of the present invention.Reference numeral 1 is a chamber for performing a plasma process therein; thechamber 1 is equipped with awafer stage 3 for mounting thereon a substrate to be processed, i.e., asemiconductor wafer 2. A gas excited into a plasma state (hereinafter simply referred to as the plasma) 4 is introduced into thechamber 1, and a plasma process such as etching or thin-film deposition is performed on thesemiconductor wafer 2. Here, the plasma 4 can also be formed within thechamber 1 by applying high-frequency energy from outside the chamber to a gas introduced into thechamber 1. Usually, an insulating film for preventing the discharge of the plasma 4 is formed on the inside wall of thechamber 1. -
FIG. 2 is a plan view of thewafer stage 3. As shown, one or morephoton detection sensors 5 are arranged on thesurface 3 a of thewafer stage 3 on which thesemiconductor wafer 2 is to be mounted. The structure of the photon detection sensor and its sensor mechanism will be described later. As shown, thephoton detection sensors 5 are arranged at equally spaced intervals around the circumferential portion of thesurface 3 a of thewafer stage 3. Adata processing apparatus 6, which performs data processing by detecting a change in an electric current being output from eachphoton detection sensor 5, is connected to thephoton detection sensors 5. - The plasma processing apparatus shown in
FIG. 1 detects a change in the electric current value of each of the plurality ofphoton detection sensors 5 while performing processing of thesemiconductor wafer 2 by exposing it to the plasma. The present inventor has discovered that when an abnormal discharge occurs within thechamber 1, the output, i.e., the electric current value, of thephoton detection sensor 5 drops in a spike-like manner. Accordingly, by observing the output of eachphoton detection sensor 5 during the processing of thesemiconductor wafer 2, any abnormal discharge occurring in thechamber 1 can be detected. Further, by simultaneously monitoring the outputs of the plurality ofphoton detection sensors 5, it becomes possible to detect the spatial distribution of the abnormal discharge, which shows which portions of thesemiconductor wafer 2 are affected by the abnormal discharge. -
FIG. 3 shows one example of how the output of thephoton detection sensor 5 changes. In the figure, the ordinate represents the ultraviolet-light-induced current value of thephoton detection sensor 5 measured in arbitrarily chosen units, and the abscissa represents the time. In thephoton detection sensor 5, a current 8 induced by the ultraviolet light generated from the plasma is constantly observed in accordance with a mechanism to be described later and, during that process, a spike-like drop 7 in the electric current value is observed. The present inventor has discovered that the spike-like drop 7 is caused by an abnormal discharge occurring in thechamber 1. - Accordingly, the time of occurrence, the magnitude, and the spatial distribution of the abnormal discharge in the
chamber 1 can be deduced from the detected occurrence of thedrop 7, its magnitude, and the position on thewafer stage 3 of thephoton detection sensor 5 whose output exhibited the drop. - Next, the structure of the
photon detection sensor 5 used in the present invention, its operating principle, and the mechanism by which an abnormal discharge is detected using the photon detection sensor will be described with reference toFIGS. 4 and 5 . -
FIG. 4 shows a first embodiment of thephoton detection sensor 5. InFIG. 4 , for convenience of explanation, thephoton detection sensor 5 is shown as being mounted directly on the bottom of the chamber, but in practice, the sensor is mounted on thewafer stage 3 on which the semiconductor wafer is to be held, as shown inFIG. 1 . In the figures hereinafter given, the same reference numerals as those inFIGS. 1 and 2 designate the same or similar component elements, and the description of such elements will not be repeated here. - In the
photon detection sensor 5 shown inFIG. 4 ,reference numeral 10 is a Si semiconductor substrate, 11 is a first insulating film formed from SiO2 or the like, 12 is an electrode formed from Al, and 13 is a second insulating film formed from SiO2 or the like. A portion of the second insulatingfilm 13 is removed by suitable means such as etching to expose a portion of theelectrode 12. Awiring line 14 is connected to the exposed portion, and the current flowing in theelectrode 12 is measured by anammeter 15.Reference numeral 16 is a power supply for applying a bias voltage to theelectrode 12. - Ions, neutral particles, electrons, and ultraviolet light are generated in the plasma. In this ultraviolet radiation, there is radiation that has large energy and cannot pass through the insulating
films films films electrode 12, these charges can be detected as a hole current by theammeter 15. - At the interface between the Si semiconductor substrate and the insulating film, for example, the SiO2/Si interface, there exist many defects formed by so-called dangling bonds of Si. The holes formed in the SiO2 film by absorbing high-energy light such as vacuum ultraviolet light are trapped by such defects formed at the SiO2/Si interface, and thus form positive fixed charges. Accordingly, the electric current value measured by the
ammeter 15 during plasma processing has correlation with the amount of fixed charge at the SiO2/Si interface. - It is presumed that the steady-state
current value 8 shown inFIG. 3 has a relationship with the current generated based on the positive fixed charges. In a MOS transistor or the like, the number of positive fixed charges greatly affects the device characteristics. Accordingly, the characteristics of the semiconductor device being produced can be predicted to a certain extent from the measured electric current value. - It is known that the energy of the plasma 4 fluctuates in cyclic fashion based on its generation process. This fluctuation of the plasma is observed as a fluctuation in the steady-state current value, as shown by reference numeral 9 in
FIG. 3 , when measuring the electric current value of thephoton detection sensor 5. Accordingly, by detecting the fluctuation of the electric current value of thesensor 5, the fluctuation of the plasma can be observed, which has not been possible with the prior art. - Usually, the inside surface of the
plasma chamber 1 is treated with an insulating film to prevent contact with the high-energy plasma 4 and thereby prevent discharge of the plasma energy. Accordingly, as the plasma process progresses, a large electric charge is accumulated on the insulating film. When the charge accumulation exceeds a limit, or when the accumulated charge is discharged for some reason, an abnormal discharge occurs in thechamber 1. - When an abnormal discharge occurs, the energy of the plasma 4 is released, and the plasma density thus drops. As a result, the ultraviolet light generated by the plasma 4 substantially decreases, and the number of electron-hole pairs to be formed in the insulating
layers ammeter 15 as a spike-like drop in the current value, as shown inFIG. 3 . - Therefore, when a spike-like drop is detected in the current value, it can be determined that an abnormal discharge has occurred in the
chamber 1. Here, when an abnormal discharge occurs, the density of the plasma 4 appreciably drops at that instant, and this greatly affects the plasma process in progress such as insulating film etching or thin-film deposition. This can significantly degrade or damage the characteristics of the semiconductor device being produced. Therefore, in order to improve the reliability and productivity of semiconductor devices, it is extremely important to detect the occurrence of an abnormal discharge during plasma processing, the magnitude of the abnormal discharge, and the spatial distribution of the abnormal discharge that occurred. -
FIGS. 5 and 6 are diagrams showing a fabrication process for the ultraviolet-light-induced current measuringphoton detection sensor 5 having the structure shown inFIG. 4 . As shown inFIG. 5A , first theSi substrate 10 is subjected to wet thermal oxidation for 30 minutes at 1000° C., to form the SiO2 film 11. The thickness of thefilm 11 is 3 μm. Next, as shown inFIG. 5B , Al as the electrode material is deposited (Al film thickness of 100 nm) to form anelectrode layer 12′. Then, theelectrode layer 12′ is etched by phosphoric acid (H3PO4), to form theelectrode 12 of the desired shape as shown inFIG. 5C . - Next, plasma TEOS (tetraethoxysilane, Si(OC2H5)4) is deposited to a thickness of 200 nm to form the
oxide film 13, as shown inFIG. 5D , after which a portion of theoxide film 13 is etched off by hydrofluoric acid (HF:H2O=1:50) to expose aportion 12″ of theelectrode 12, as shown inFIG. 6A . Finally, a current measuring lead wire (not shown) is connected to the exposedportion 12″ of theelectrode 12. After the lead wire is connected, the device is covered with an insulating film (not shown) to prevent charged particles from entering the device through the periphery of the lead wire. -
FIG. 6B is a plan view showing the device shown inFIG. 6A as viewed from the top; here, theelectrode 12 is shown through the overlying SiO2 film 13, with theportion 12″ of the electrode exposed through the opening formed in the SiO2 film 13. - When the
photon detection sensor 5 is formed as described above, the sensor is mounted on thewafer stage 3 in theplasma chamber 1, and connected to thepower supply 16 and theammeter 15 outside thechamber 1 via a current lead terminal (not shown) connected to theelectrode 12, and theammeter 15 measures the electric current value when a bias voltage of 0 to 30 V is applied from thepower supply 16. The electric current value when the plasma is not applied is about 10 to 20 pA, which means that virtually no current is flowing. The measured sensor output is processed by thedata processing apparatus 6 and monitored by the user. -
FIG. 7 is a diagram showing a second embodiment of the photon detection sensor used in the plasma processing apparatus of the present invention. Thephoton detection sensor 50 of this embodiment differs from thephoton detection sensor 5 of the structure shown inFIG. 4 in that the SiO2 film 13 is covered with anAl film 17 about 100 nm in thickness.Reference numeral 12 a indicates the lead terminal of theelectrode 12. - Ions, neutral particles, electrons, and ultraviolet light are generated in the plasma. Therefore, in the
photon detection sensor 5 ofFIG. 4 , the SiO2 film 13 is affected by charged particles such as ions and electrons, causing a variation in the measured current value. In thephoton detection sensor 50 shown inFIG. 7 , thefilm 13 is covered with the Althin film 17 to prevent such particles from penetrating into thefilm 13. It is known that ultraviolet light with wavelengths of about 17 nm to 90 nm passes through the Al film. Therefore, by depositing theAl film 17 over the SiO2 film 13, the influence only of vacuum ultraviolet light of 90 nm and shorter wavelengths that pass through can be observed by eliminating the influence of ions and electrons. TheAl film 17 is grounded during plasma exposure. - In the
photon detection sensors FIGS. 4 and 7 , the insulating film has been formed from SiO2, but the present invention is not limited to this particular material; for example, the insulating film can be equally achieved by using, for example, a nitride film or the like. The insulating film need only be formed using the same material as the insulating film formed on the semiconductor wafer or to be formed thereon and processed by etching. - As described above with reference to the various embodiments, in the plasma processing apparatus of the present invention, with the ultraviolet-light-induced current measuring photon detection sensor mounted on the wafer stage, any abnormal discharge phenomenon occurring in the plasma chamber can be detected in real time during the processing of the semiconductor wafer. Accordingly, when an abnormal discharge occurs, corrective action can be taken quickly, and as a result, semiconductor devices having high reliability can be produced while ensuring high productivity. Further, by arranging a plurality of photon detection sensors on the wafer stage, it becomes possible to know the spatial distribution of the abnormal discharge, so that more appropriate action can be taken to deal with the abnormal discharge.
Claims (8)
1. A plasma processing apparatus comprising:
a chamber equipped with a wafer stage for mounting thereon a substrate to be processed;
a means for providing plasma on said substrate mounted on said wafer stage; and
a photon detection sensor for measuring an ultraviolet-light-induced current placed on a circumferential portion of a substrate mounting surface of said wafer stage.
2. A plasma processing apparatus as claimed in claim 1 , wherein said photon detection sensor comprises a semiconductor substrate, an insulating film formed over said semiconductor substrate, an electrode layer embedded in said insulating film, a means for applying a bias voltage to said electrode layer, and a means for detecting a current flowing in said electrode layer.
3. A plasma processing apparatus as claimed in claim 2 , wherein said photon detection sensor further comprises a second electrode formed on said insulating film.
4. A plasma processing apparatus as claimed in claim 1 , wherein a plurality of said photon detection sensors are arranged around the circumferential portion of said substrate mounting surface of said wafer stage.
5. A plasma processing method for processing a substrate, comprising:
providing a plurality of photon detection sensors, each for measuring an ultraviolet-light-induced current, on a wafer stage provided within a plasma chamber;
providing said substrate to be processed on said wafer stage,
performing plasma processing in said plasma chamber in which said photon detection sensors and said substrate to be processed are placed, and
monitoring an output current from each of said photon detection sensors while said plasma processing is being performed.
6. A plasma processing method as claimed in claim 5 , wherein when a spike-like current drop different from a steady-state current is observed during the monitoring of said photon detection sensors, said spike-like current drop is recognized as indicating the occurrence of an abnormal discharge.
7. A plasma processing apparatus as claimed in claim 2 , wherein a plurality of said photon detection sensors are arranged around the circumferential portion of said substrate mounting surface of said wafer stage.
8. A plasma processing apparatus as claimed in claim 3 , wherein a plurality of said photon detection sensors are arranged around the circumferential portion of said substrate mounting surface of said wafer stage.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/585,119 US20090325328A1 (en) | 2004-05-28 | 2009-09-03 | Plasma processing apparatus and plasma processing method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004159531A JP3957705B2 (en) | 2004-05-28 | 2004-05-28 | Plasma processing equipment |
JP2004-159531(PAT.) | 2004-05-28 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/585,119 Division US20090325328A1 (en) | 2004-05-28 | 2009-09-03 | Plasma processing apparatus and plasma processing method |
Publications (1)
Publication Number | Publication Date |
---|---|
US20050263247A1 true US20050263247A1 (en) | 2005-12-01 |
Family
ID=35423921
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/060,598 Abandoned US20050263247A1 (en) | 2004-05-28 | 2005-02-18 | Plasma processing apparatus and plasma processing method |
US12/585,119 Abandoned US20090325328A1 (en) | 2004-05-28 | 2009-09-03 | Plasma processing apparatus and plasma processing method |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/585,119 Abandoned US20090325328A1 (en) | 2004-05-28 | 2009-09-03 | Plasma processing apparatus and plasma processing method |
Country Status (2)
Country | Link |
---|---|
US (2) | US20050263247A1 (en) |
JP (1) | JP3957705B2 (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080099434A1 (en) * | 2006-10-30 | 2008-05-01 | Chandrachood Madhavi R | Plasma mask etch method of controlling a reactor tunable element in accordance with the output of an array of optical sensors viewing the mask backside |
US20080100222A1 (en) * | 2006-10-30 | 2008-05-01 | Applied Materials, Inc. | Mask etch plasma reactor with cathode providing a uniform distribution of etch rate |
US20080102202A1 (en) * | 2006-10-30 | 2008-05-01 | Applied Materials, Inc. | Mask etch plasma reactor with variable process gas distribution |
US20080099450A1 (en) * | 2006-10-30 | 2008-05-01 | Applied Materials, Inc. | Mask etch plasma reactor with backside optical sensors and multiple frequency control of etch distribution |
US20080100223A1 (en) * | 2006-10-30 | 2008-05-01 | Richard Lewington | Plasma reactor for processing a workpiece and having a tunable cathode |
US20080099432A1 (en) * | 2006-10-30 | 2008-05-01 | Applied Materials, Inc. | Process for etching a transparent workpiece including backside endpoint detection steps |
US20080099437A1 (en) * | 2006-10-30 | 2008-05-01 | Richard Lewington | Plasma reactor for processing a transparent workpiece with backside process endpoint detection |
US20080102001A1 (en) * | 2006-10-30 | 2008-05-01 | Chandrachood Madhavi R | Mask etch plasma reactor having an array of optical sensors viewing the workpiece backside and a tunable element controlled in response to the optical sensors |
US20090058432A1 (en) * | 2007-08-31 | 2009-03-05 | Oki Electric Industry Co., Ltd. | Ultraviolet light monitoring system |
US20090131580A1 (en) * | 2007-10-30 | 2009-05-21 | Cheng-Chien Yang | Organic siloxane composite material containing polyaniline/carbon black and preparation method thereof |
US20100244861A1 (en) * | 2009-03-26 | 2010-09-30 | Oki Semiconductor Co., Ltd. | Plasma monitoring method |
CN105259527A (en) * | 2015-10-09 | 2016-01-20 | 国网新疆电力公司检修公司 | Test method for calibrating detection results of different ultraviolet imaging instruments |
US9254397B2 (en) | 2011-11-22 | 2016-02-09 | National Institute Of Advanced Industrial Science And Technology | Plasma evaluation apparatus |
US20190025370A1 (en) * | 2017-07-20 | 2019-01-24 | Tokyo Electron Limited | Substrate Mounting Table and Substrate Inspection Apparatus |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009283838A (en) * | 2008-05-26 | 2009-12-03 | Oki Semiconductor Co Ltd | System for monitoring ultraviolet light |
US8497591B2 (en) | 2010-12-29 | 2013-07-30 | General Electric Company | System and method for off-highway vehicle engine cranking |
US20200088784A1 (en) | 2018-04-27 | 2020-03-19 | Femtometrix, Inc. | Systems and methods for determining characteristics of semiconductor devices |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20010014520A1 (en) * | 2000-02-16 | 2001-08-16 | Tatehito Usui | Process monitoring methods in a plasma processing apparatus, monitoring units, and a sample processing method using the monitoring units |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5863327A (en) * | 1997-02-10 | 1999-01-26 | Micron Technology, Inc. | Apparatus for forming materials |
US7157710B1 (en) * | 2003-11-19 | 2007-01-02 | Kaiser Systems, Inc. | Corona discharge detection |
-
2004
- 2004-05-28 JP JP2004159531A patent/JP3957705B2/en not_active Expired - Fee Related
-
2005
- 2005-02-18 US US11/060,598 patent/US20050263247A1/en not_active Abandoned
-
2009
- 2009-09-03 US US12/585,119 patent/US20090325328A1/en not_active Abandoned
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20010014520A1 (en) * | 2000-02-16 | 2001-08-16 | Tatehito Usui | Process monitoring methods in a plasma processing apparatus, monitoring units, and a sample processing method using the monitoring units |
Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1918969A1 (en) * | 2006-10-30 | 2008-05-07 | Applied Materials, Inc. | Mask etch plasma reactor with backside optical sensors and multiple frequency control of etch distribution |
US20080102202A1 (en) * | 2006-10-30 | 2008-05-01 | Applied Materials, Inc. | Mask etch plasma reactor with variable process gas distribution |
US20080099434A1 (en) * | 2006-10-30 | 2008-05-01 | Chandrachood Madhavi R | Plasma mask etch method of controlling a reactor tunable element in accordance with the output of an array of optical sensors viewing the mask backside |
US10170280B2 (en) | 2006-10-30 | 2019-01-01 | Applied Materials, Inc. | Plasma reactor having an array of plural individually controlled gas injectors arranged along a circular side wall |
US20080100223A1 (en) * | 2006-10-30 | 2008-05-01 | Richard Lewington | Plasma reactor for processing a workpiece and having a tunable cathode |
US20080099432A1 (en) * | 2006-10-30 | 2008-05-01 | Applied Materials, Inc. | Process for etching a transparent workpiece including backside endpoint detection steps |
US20080099437A1 (en) * | 2006-10-30 | 2008-05-01 | Richard Lewington | Plasma reactor for processing a transparent workpiece with backside process endpoint detection |
US20080102001A1 (en) * | 2006-10-30 | 2008-05-01 | Chandrachood Madhavi R | Mask etch plasma reactor having an array of optical sensors viewing the workpiece backside and a tunable element controlled in response to the optical sensors |
US8017029B2 (en) | 2006-10-30 | 2011-09-13 | Applied Materials, Inc. | Plasma mask etch method of controlling a reactor tunable element in accordance with the output of an array of optical sensors viewing the mask backside |
US20080100222A1 (en) * | 2006-10-30 | 2008-05-01 | Applied Materials, Inc. | Mask etch plasma reactor with cathode providing a uniform distribution of etch rate |
US20080099450A1 (en) * | 2006-10-30 | 2008-05-01 | Applied Materials, Inc. | Mask etch plasma reactor with backside optical sensors and multiple frequency control of etch distribution |
US8012366B2 (en) | 2006-10-30 | 2011-09-06 | Applied Materials, Inc. | Process for etching a transparent workpiece including backside endpoint detection steps |
US9218944B2 (en) | 2006-10-30 | 2015-12-22 | Applied Materials, Inc. | Mask etch plasma reactor having an array of optical sensors viewing the workpiece backside and a tunable element controlled in response to the optical sensors |
US7967930B2 (en) | 2006-10-30 | 2011-06-28 | Applied Materials, Inc. | Plasma reactor for processing a workpiece and having a tunable cathode |
US7976671B2 (en) | 2006-10-30 | 2011-07-12 | Applied Materials, Inc. | Mask etch plasma reactor with variable process gas distribution |
US8002946B2 (en) | 2006-10-30 | 2011-08-23 | Applied Materials, Inc. | Mask etch plasma reactor with cathode providing a uniform distribution of etch rate |
US7732783B2 (en) * | 2007-08-31 | 2010-06-08 | Oki Semiconductor Co., Ltd. | Ultraviolet light monitoring system |
US20090058432A1 (en) * | 2007-08-31 | 2009-03-05 | Oki Electric Industry Co., Ltd. | Ultraviolet light monitoring system |
US8349918B2 (en) * | 2007-10-30 | 2013-01-08 | Chung Shan Institute Of Science And Technology, Armaments Bureau, M.N.D. | Organic siloxane composite material containing polyaniline/carbon black and preparation method thereof |
US20090131580A1 (en) * | 2007-10-30 | 2009-05-21 | Cheng-Chien Yang | Organic siloxane composite material containing polyaniline/carbon black and preparation method thereof |
US8427168B2 (en) * | 2009-03-26 | 2013-04-23 | Oki Semiconductor Co., Ltd. | Plasma monitoring method |
US20100244861A1 (en) * | 2009-03-26 | 2010-09-30 | Oki Semiconductor Co., Ltd. | Plasma monitoring method |
US9254397B2 (en) | 2011-11-22 | 2016-02-09 | National Institute Of Advanced Industrial Science And Technology | Plasma evaluation apparatus |
CN105259527A (en) * | 2015-10-09 | 2016-01-20 | 国网新疆电力公司检修公司 | Test method for calibrating detection results of different ultraviolet imaging instruments |
US20190025370A1 (en) * | 2017-07-20 | 2019-01-24 | Tokyo Electron Limited | Substrate Mounting Table and Substrate Inspection Apparatus |
US10663511B2 (en) * | 2017-07-20 | 2020-05-26 | Tokyo Electron Limited | Substrate mounting table and substrate inspection apparatus |
Also Published As
Publication number | Publication date |
---|---|
JP3957705B2 (en) | 2007-08-15 |
JP2005340632A (en) | 2005-12-08 |
US20090325328A1 (en) | 2009-12-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20050263247A1 (en) | Plasma processing apparatus and plasma processing method | |
US9412567B2 (en) | Plasma monitoring method and plasma monitoring system | |
US7184134B2 (en) | Real-time monitoring apparatus for plasma process | |
US6967109B2 (en) | Process monitoring methods in a plasma processing apparatus, monitoring units, and a sample processing method using the monitoring units | |
US7864502B2 (en) | In situ monitoring of wafer charge distribution in plasma processing | |
KR20200038440A (en) | wafer for measuring plasma condition | |
US5940682A (en) | Method of measuring electron shading damage | |
US6143579A (en) | Efficient method for monitoring gate oxide damage related to plasma etch chamber processing history | |
US8427168B2 (en) | Plasma monitoring method | |
US6114182A (en) | Measurement of electron shading damage | |
US6943427B2 (en) | Semiconductor device for charge-up damage evaluation and charge-up damage evaluation method | |
US7132354B2 (en) | Inspection methods for a semiconductor device | |
US8419892B2 (en) | Plasma process detecting sensor | |
KR20190130864A (en) | wafer for measuring plasma condition | |
Gabriel | Gate oxide damage: Testing approaches and methodologies | |
KR20190130858A (en) | wafer for measuring plasma condition | |
KR20090013881A (en) | Test wafer, method for fabricating the same and measuring method for plasma damage | |
KR102056085B1 (en) | wafer for measuring plasma condition | |
TWI488234B (en) | Release accumulative charges on wafers using o2 neutralization | |
KR101939634B1 (en) | Method for diagnosing inner wall of plasma reactor | |
CN113539903A (en) | Method and apparatus for detecting leak rate of processing chamber | |
Beyer et al. | Plasma induced damage monitoring for HDP processes | |
KR100905822B1 (en) | Method of monitoring for semiconductor device | |
KR20200038900A (en) | wafer for measuring plasma condition | |
KR20200038441A (en) | wafer for measuring plasma condition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: SEMICONDUCTOR TECHNOLOGY ACADEMIC RESEARCH CENTER, Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SAMUKAWA, SEIJI;NISHIKAWA, SATOSHI;KADOMURA, SHINGO;REEL/FRAME:016558/0183 Effective date: 20050322 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |