US1947451A - Copperized paper - Google Patents
Copperized paper Download PDFInfo
- Publication number
- US1947451A US1947451A US636030A US63603032A US1947451A US 1947451 A US1947451 A US 1947451A US 636030 A US636030 A US 636030A US 63603032 A US63603032 A US 63603032A US 1947451 A US1947451 A US 1947451A
- Authority
- US
- United States
- Prior art keywords
- paper
- copper
- fiber
- chemical
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Definitions
- Sodium orthophenyl phenate is the most feasible form in which said chemical constituents may be used for our purpose; but it is soluble in water to such alimited degree that a solution of sufiicient strength to be applied as a dampening solution to the paper is not feasible.
- 1% of this chemical in the fiber it would require the adding of about 5% of water to the dry sheet in dampening the same with the chemical solution; and the latter furthermore would have to be abouta 20% solution of. the chemical, a degree of solution far beyond its, possibilities.
- our present invention consists in efiecting a solution of the necessary amount of sodium ortho phenyl phenate in the large volume of water used in the beater, whereby the'degree of solubility of the chemical is not exceeded and a solution of the necessary strength is obtained.
- slush and lap stock may be added to the desired consistency, and then the beating operation must be continued for about another half hour.
- the paper sheet so prepared contains an excess of 1% of a copper modification of the essential copper ortho phenyl phenate, and this paper web charged with the said chemical especially lends itself in super-calendering to transparency.
- a paper sheet characterized by the fiber thereof carrying a predetermined amount of cop per ortho phenyl phenate precipitate.
- a paper sheet characterized by thefiber thereof carrying a precipitate of copper ortho phenyl phenate of not less than 1%by weight.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
ing.
Patented F eb. 20, 1934 PATENT OFFICE 1,947,451 oorrsnrzep PAPER 7 William R. Barber, Albert G. Natwick, and Maurice W. Phelps, Camas, Wasln, assignors to Qrown Willamette Paper Company, San Francisco, CaliL, a corporation of Delaware No Drawing.
5 (Claims.
the toxic properties of the phenol carbolic acid) with those of copper, it is very desirable to use the same, but the incorporation of the orthophenyl phenol constituent of this chemical in the paper fiber presented serious dimculties which had to be overcome.
Sodium orthophenyl phenate is the most feasible form in which said chemical constituents may be used for our purpose; but it is soluble in water to such alimited degree that a solution of sufiicient strength to be applied as a dampening solution to the paper is not feasible. For, in order to incorporate 1% of this chemical in the fiber it would require the adding of about 5% of water to the dry sheet in dampening the same with the chemical solution; and the latter furthermore would have to be abouta 20% solution of. the chemical, a degree of solution far beyond its, possibilities.
Besides, the solution would not penetrate the sheet if applied by the dampening method. And, further, since this chemical is somewhat volatile, if the sheet is to be super-calendered this chemical would tend'to lose much of its value from the frictional heat of the super-calender Our present invention consists in efiecting a solution of the necessary amount of sodium ortho phenyl phenate in the large volume of water used in the beater, whereby the'degree of solubility of the chemical is not exceeded and a solution of the necessary strength is obtained.
Our procedure is as follows:- I
Assuming that we use unbleached sulphite, to each ton of this pulp we add in the beater 30 pounds of sodium ortho phenyl phenate, thelatter being added as a dry powder and first dissolved in the beater water; its solution being effected by circulation of the water in the beater for about 10 minutes which we found sufficient to effect complete solution.
The preliminary step of dissolving the chemical in the beater water we find necessary, since if the chemical is added either dry to the fiber Application October 3, 1932 Serial No. 636,030
already in the heater, or added wetted in water, it resists complete solution, due to particles clinging-to the fiber; and thus undissolved particles will then appear in the sheet as green specks of the copper combination, .which would detract from the appearance of the sheet.
After the chemical has been dissolved in the beater water, slush and lap stock may be added to the desired consistency, and then the beating operation must be continued for about another half hour.
Then we add 25 pounds of copper sulphate in solution. The stock will turn a delicate light green. After-the addition of the copper sulphate the stock isfurther beaten for about half an hour. z,
Tests of the back-water showed the same to be remarkably free from the presence of dissolved copper.
We also found that the copper retention by the fiber is remarkably high. It is our opinion that such high retention may come from some similarity of the copper ortho phenyl phenate to dye stuffs with regard to the latters properties of adherence and adsorption to the fiber.
The paper sheet so prepared contains an excess of 1% of a copper modification of the essential copper ortho phenyl phenate, and this paper web charged with the said chemical especially lends itself in super-calendering to transparency. v
The proportions above given are of course'variable if a greater or lesser amount of copper orthe phenyl phenate is to be incorporated in and retained by the paper fiber, and the beating periods are given approximately, in accordance with the best results obtained by us.
We claim:
1. A paper sheet characterized by the fiber thereof carrying a predetermined amount of cop per ortho phenyl phenate precipitate.
2. A paper sheet characterized by thefiber thereof carrying a precipitate of copper ortho phenyl phenate of not less than 1%by weight.
3. The process of incorporating -adefinite .amount of copper ortho phenyl phenate in the' fiber of a paper sheet comprising, dissolving an alkaline ortho phenyl phenate in the water of the beater before introducing the stock, then adding copper sulphate and beating the stock for a period, the chemicals being relatively proportioned to each other and the stock to'iefiect the precipitation of a'deflnite amount of copper ortho phenyl phenate in and on the fiber, substantially as described.
fiber of a paper 4. The process of incorporating a definite amount of copper ortho phenyl phenate in the sheet comprising,-disso1ving an alkaline ortho phenyl phenate in the water of the beater before ing copper sulph introducing the stock, then addate and beating the stock a period, the chemicals being relatively proportioned to each other and the stock to efiect the precipitation of not less than 1% of copper ortho phe- 10 nyl phenate in and on the fiber, substantially as described.
5. The proces s of incorporating a definite WILLIAM R. BARBER. ALBERT G. NATWICK. MAURICE W; PHELPS.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US636030A US1947451A (en) | 1932-10-03 | 1932-10-03 | Copperized paper |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US636030A US1947451A (en) | 1932-10-03 | 1932-10-03 | Copperized paper |
Publications (1)
Publication Number | Publication Date |
---|---|
US1947451A true US1947451A (en) | 1934-02-20 |
Family
ID=24550092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US636030A Expired - Lifetime US1947451A (en) | 1932-10-03 | 1932-10-03 | Copperized paper |
Country Status (1)
Country | Link |
---|---|
US (1) | US1947451A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3493464A (en) * | 1968-08-21 | 1970-02-03 | Mosinee Paper Mills Co | Fungus-resistant paper containing metallic quinolinolate formed in situ and process thereof |
WO2004088029A2 (en) * | 2003-04-01 | 2004-10-14 | The Cupron Corporation | Disposable, paper-based hospital and operating theater products |
US20040224005A1 (en) * | 2000-04-05 | 2004-11-11 | The Cupron Corporation | Antimicrobial and antiviral polymeric materials |
US20050150514A1 (en) * | 2000-04-05 | 2005-07-14 | The Cupron Corporation | Device for cleaning tooth and gum surfaces |
US20080311165A1 (en) * | 2004-11-07 | 2008-12-18 | The Cupron Corporation | Copper Containing Materials for Treating Wounds, Burns and Other Skin Conditions |
US20090010969A1 (en) * | 2004-11-09 | 2009-01-08 | The Cupron Corporation | Methods And Materials For Skin Care |
-
1932
- 1932-10-03 US US636030A patent/US1947451A/en not_active Expired - Lifetime
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3493464A (en) * | 1968-08-21 | 1970-02-03 | Mosinee Paper Mills Co | Fungus-resistant paper containing metallic quinolinolate formed in situ and process thereof |
US20040224005A1 (en) * | 2000-04-05 | 2004-11-11 | The Cupron Corporation | Antimicrobial and antiviral polymeric materials |
US20050150514A1 (en) * | 2000-04-05 | 2005-07-14 | The Cupron Corporation | Device for cleaning tooth and gum surfaces |
US7169402B2 (en) | 2000-04-05 | 2007-01-30 | The Cupron Corporation | Antimicrobial and antiviral polymeric materials |
US20070184079A1 (en) * | 2000-04-05 | 2007-08-09 | The Cupron Corporation | Antimicrobial and antiviral polymeric materials |
US9439437B2 (en) | 2000-04-05 | 2016-09-13 | Cupron Inc. | Antimicrobial and antiviral polymeric materials |
WO2004088029A2 (en) * | 2003-04-01 | 2004-10-14 | The Cupron Corporation | Disposable, paper-based hospital and operating theater products |
WO2004088029A3 (en) * | 2003-04-01 | 2004-12-29 | Cupron Corp | Disposable, paper-based hospital and operating theater products |
US20080311165A1 (en) * | 2004-11-07 | 2008-12-18 | The Cupron Corporation | Copper Containing Materials for Treating Wounds, Burns and Other Skin Conditions |
US20090010969A1 (en) * | 2004-11-09 | 2009-01-08 | The Cupron Corporation | Methods And Materials For Skin Care |
US9403041B2 (en) | 2004-11-09 | 2016-08-02 | Cupron Inc. | Methods and materials for skin care |
US9931283B2 (en) | 2004-11-09 | 2018-04-03 | Cupron Inc. | Methods and materials for skin care |
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