US1167472A - Process of protecting metal articles heated by the combustion of powdered coal. - Google Patents

Process of protecting metal articles heated by the combustion of powdered coal. Download PDF

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Publication number
US1167472A
US1167472A US85711014A US1914857110A US1167472A US 1167472 A US1167472 A US 1167472A US 85711014 A US85711014 A US 85711014A US 1914857110 A US1914857110 A US 1914857110A US 1167472 A US1167472 A US 1167472A
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United States
Prior art keywords
combustion
metal articles
powdered coal
protecting metal
articles heated
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Expired - Lifetime
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US85711014A
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William P Barba
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MIDVALE STEEL Co
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MIDVALE STEEL Co
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Publication date
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Priority to US85711014A priority Critical patent/US1167472A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber

Definitions

  • My invention relates to the process of burning powdered coal in a furnace containforging
  • sufiicient to raise the melting point of the ash to the extent required to cause it to adhere to the billets and form a protective coating therefor to minimize scale and in suflicient to elevate such melting point to adegree which would destroy its adherent property, substantially as described.

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Description

n Ans an WILLIAM P. BAR-BA, OFPHILADELPHIA, PENNSYLvANIA, ASSIGNOR TO THE MIDVALE PHILADELPHIA, PENNSYLVANIA, A CORPORATION OF PENN- s'r EL COMPANY, OF sYLvANIA.
' PROCESS OF PROTECTING METAL ARTICLES HEATED BY THE COMBUSTION F POWDERED COAL.
NO Drawing.
To all whom it may concern: Be it known that I, WILLIAM a citizen of the United States, residing at Philadelphia,'county of Philadelphia, and State of Pennsylvania, .have invented a new and useful Improvement in Processes of Protecting Metal Articles Heated by the lombustion of Powdered Goal, of which the following is a full, clear, and exact description.
My invention relates to the process of burning powdered coal in a furnace containforging;
ing billets or other articles of metal to be heat-treated or to be heated preparatory to The known advantage of this process is that it supplies heat at a relatively low price. The processinvolves the deposition' of the ash upon the articles undergoing treatment, which has certain advantages in that it aifords a coating that acts to reduce oxidaton. The process, however, has 'certain deleterious effects upon the articles undergoing treatn'lent. Vhile the coatingof the articles with ash tends to reduce oxidation, the ash usually fails to fuse with the scale to such an extent as to form a perfectly satisfactory protective coating, which scale is not only therefore so great in depth;
as to involve a considerable loss of metal but often adheres so closely to the articles Specification of Letters latent.
Application fi led August 17, 1914. Serial No. 857,110.
. fusing point to an extent which would de- P. BARBA,
stroy the adherent properties of the modified ash. I have found that the maximum percentage of calcium carbonate that will serve to produce the desired effect is about .65 per cent. ofthe ash-forming constituents of the coal and the best results are produced .if the quantity added is'net over per cent. If calcium oxid is used I prefer to add about 25 per cent. of the weight of the ashforming constituents of the coal. The result is that not only is the scale thus formed comparatively thin, but its toughness and brittleness is so modified that it possesses weak adherent properties and can be readily removed before forging.
Having 'now fully described my invention, what I claim and desire to protect by Let ters Patent is:
The process of protecting metal articles in a furnace in which'the coal is burned in a powdered form, which consists in burning in a furnace containing such metal articles powdered coal mixed with an inorganic basic substance in a proportion to the weight of the ash forming constituents of the coal,
sufiicient to raise the melting point of the ash to the extent required to cause it to adhere to the billets and form a protective coating therefor to minimize scale and in suflicient to elevate such melting point to adegree which would destroy its adherent property, substantially as described.
In testimony of which invention, I have hereunto set my hand, at Philadelphia, on this 27th day ,of July, 1914.
'WILLIAM P. BARBA.
' Witnesses:
JosEPn ENTWISLE, ARTHUR KRON EMANN.
US85711014A 1914-08-17 1914-08-17 Process of protecting metal articles heated by the combustion of powdered coal. Expired - Lifetime US1167472A (en)

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US85711014A US1167472A (en) 1914-08-17 1914-08-17 Process of protecting metal articles heated by the combustion of powdered coal.

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US85711014A US1167472A (en) 1914-08-17 1914-08-17 Process of protecting metal articles heated by the combustion of powdered coal.

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US1167472A true US1167472A (en) 1916-01-11

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4465000A (en) * 1982-02-08 1984-08-14 Conoco Inc. Method of increasing the efficiency of cyclone-fired boilers using high sodium lignite fuel
US20060210463A1 (en) * 2005-03-17 2006-09-21 Comrie Douglas C Reducing mercury emissions from the burning of coal
US20070168213A1 (en) * 2006-01-18 2007-07-19 Comrie Douglas C Methods of operating a coal burning facility
US20070184394A1 (en) * 2006-02-07 2007-08-09 Comrie Douglas C Production of cementitious ash products with reduced carbon emissions
US20080286703A1 (en) * 2004-06-28 2008-11-20 Nox Ii International Ltd. Reducing Sulfur Gas Emissions Resulting from the Burning of Carbonaceous Fuels
US7758827B2 (en) 2005-03-17 2010-07-20 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US8124036B1 (en) 2005-10-27 2012-02-28 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
US8372362B2 (en) 2010-02-04 2013-02-12 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US8383071B2 (en) 2010-03-10 2013-02-26 Ada Environmental Solutions, Llc Process for dilute phase injection of dry alkaline materials
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US8524179B2 (en) 2010-10-25 2013-09-03 ADA-ES, Inc. Hot-side method and system
US8784757B2 (en) 2010-03-10 2014-07-22 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US8974756B2 (en) 2012-07-25 2015-03-10 ADA-ES, Inc. Process to enhance mixing of dry sorbents and flue gas for air pollution control
US9017452B2 (en) 2011-11-14 2015-04-28 ADA-ES, Inc. System and method for dense phase sorbent injection
US10350545B2 (en) 2014-11-25 2019-07-16 ADA-ES, Inc. Low pressure drop static mixing system
US10465137B2 (en) 2011-05-13 2019-11-05 Ada Es, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US10767130B2 (en) 2012-08-10 2020-09-08 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions

Cited By (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4465000A (en) * 1982-02-08 1984-08-14 Conoco Inc. Method of increasing the efficiency of cyclone-fired boilers using high sodium lignite fuel
US20080286703A1 (en) * 2004-06-28 2008-11-20 Nox Ii International Ltd. Reducing Sulfur Gas Emissions Resulting from the Burning of Carbonaceous Fuels
US9133408B2 (en) 2004-06-28 2015-09-15 Nox Ii, Ltd. Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
US8574324B2 (en) 2004-06-28 2013-11-05 Nox Ii, Ltd. Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
US9416967B2 (en) 2005-03-17 2016-08-16 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US11732888B2 (en) 2005-03-17 2023-08-22 Nox Ii, Ltd. Sorbents for coal combustion
US20090117019A1 (en) * 2005-03-17 2009-05-07 Comrie Douglas C Reducing mercury emissions from the burning of coal
US7674442B2 (en) 2005-03-17 2010-03-09 Comrie Douglas C Reducing mercury emissions from the burning of coal
US7758827B2 (en) 2005-03-17 2010-07-20 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US7776301B2 (en) 2005-03-17 2010-08-17 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US7955577B2 (en) 2005-03-17 2011-06-07 NOx II, Ltd Reducing mercury emissions from the burning of coal
US20110203499A1 (en) * 2005-03-17 2011-08-25 Nox Ii, Ltd. Reducing Mercury Emissions From The Burning Of Coal
US8920158B2 (en) 2005-03-17 2014-12-30 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US10641483B2 (en) 2005-03-17 2020-05-05 Nox Ii, Ltd. Sorbents for coal combustion
US8226913B2 (en) 2005-03-17 2012-07-24 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US9169453B2 (en) 2005-03-17 2015-10-27 Nox Ii, Ltd. Sorbents for coal combustion
US10670265B2 (en) 2005-03-17 2020-06-02 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US9945557B2 (en) 2005-03-17 2018-04-17 Nox Ii, Ltd. Sorbents for coal combustion
US10962224B2 (en) 2005-03-17 2021-03-30 Nox Ii, Ltd. Sorbents for coal combustion
US8501128B2 (en) 2005-03-17 2013-08-06 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US10612779B2 (en) 2005-03-17 2020-04-07 Nox Ii, Ltd. Sorbents for coal combustion
US8545778B2 (en) 2005-03-17 2013-10-01 Nox Ii, Ltd. Sorbents for coal combustion
US10359192B2 (en) 2005-03-17 2019-07-23 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US8658115B2 (en) 2005-03-17 2014-02-25 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US8703081B2 (en) 2005-03-17 2014-04-22 Nox Ii, Ltd. Sorbents for coal combustion
US9822973B2 (en) 2005-03-17 2017-11-21 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US11060723B2 (en) 2005-03-17 2021-07-13 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal by remote sorbent addition
US7507083B2 (en) 2005-03-17 2009-03-24 Douglas C Comrie Reducing mercury emissions from the burning of coal
US20060210463A1 (en) * 2005-03-17 2006-09-21 Comrie Douglas C Reducing mercury emissions from the burning of coal
US11732889B2 (en) 2005-03-17 2023-08-22 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal by remote sorbent addition
US9702554B2 (en) 2005-03-17 2017-07-11 Nox Ii, Ltd. Sorbents for coal combustion
US8293196B1 (en) 2005-10-27 2012-10-23 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
US8124036B1 (en) 2005-10-27 2012-02-28 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
US20070168213A1 (en) * 2006-01-18 2007-07-19 Comrie Douglas C Methods of operating a coal burning facility
US8150776B2 (en) 2006-01-18 2012-04-03 Nox Ii, Ltd. Methods of operating a coal burning facility
US20070184394A1 (en) * 2006-02-07 2007-08-09 Comrie Douglas C Production of cementitious ash products with reduced carbon emissions
US9352275B2 (en) 2010-02-04 2016-05-31 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US9221013B2 (en) 2010-02-04 2015-12-29 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US10427096B2 (en) 2010-02-04 2019-10-01 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US9884286B2 (en) 2010-02-04 2018-02-06 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US8372362B2 (en) 2010-02-04 2013-02-12 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US9149759B2 (en) 2010-03-10 2015-10-06 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
US8784757B2 (en) 2010-03-10 2014-07-22 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
US8383071B2 (en) 2010-03-10 2013-02-26 Ada Environmental Solutions, Llc Process for dilute phase injection of dry alkaline materials
US10730015B2 (en) 2010-10-25 2020-08-04 ADA-ES, Inc. Hot-side method and system
US10124293B2 (en) 2010-10-25 2018-11-13 ADA-ES, Inc. Hot-side method and system
US9657942B2 (en) 2010-10-25 2017-05-23 ADA-ES, Inc. Hot-side method and system
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US8524179B2 (en) 2010-10-25 2013-09-03 ADA-ES, Inc. Hot-side method and system
US10465137B2 (en) 2011-05-13 2019-11-05 Ada Es, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US9017452B2 (en) 2011-11-14 2015-04-28 ADA-ES, Inc. System and method for dense phase sorbent injection
US10159931B2 (en) 2012-04-11 2018-12-25 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US10758863B2 (en) 2012-04-11 2020-09-01 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US9889405B2 (en) 2012-04-11 2018-02-13 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US9409123B2 (en) 2012-04-11 2016-08-09 ASA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8974756B2 (en) 2012-07-25 2015-03-10 ADA-ES, Inc. Process to enhance mixing of dry sorbents and flue gas for air pollution control
US10767130B2 (en) 2012-08-10 2020-09-08 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions
US10350545B2 (en) 2014-11-25 2019-07-16 ADA-ES, Inc. Low pressure drop static mixing system
US11369921B2 (en) 2014-11-25 2022-06-28 ADA-ES, Inc. Low pressure drop static mixing system

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