M3 62111 八、新型說明： 【新型所屬之技術領域】 本創作涉及一種連續性強化纖維積層體結構，尤其3 具有預浸熱塑性樹脂的連續性強化纖維。 、疋 【先前技術】 在「節能減碳」的全球議題上與行動資訊科技M3 62111 VIII. New description: [New technical field] This creation involves a continuous reinforced fiber laminate structure, especially 3 continuous reinforcing fibers with prepreg thermoplastic resin.疋 【Prior Art】 On the global issue of “energy saving and carbon reduction” and mobile information technology
Uniorraation Technol〇gy ’汀)產品發展迅速需求下，業 界無不開始追求更具耐衝擊力、防電磁波且可被回收處理 再利用並減少石化樹脂用量的素材，以期符合全球的^保 要求以及相關產業的需求。 一 目前，連續賴化纖維積層業界所使_素材有麵 維（Carbon Fiber)、玻璃強化纖維⑹咖灿的、聚^ 纖維(Polyester)及芳香族聚醯胺類纖維(Kevlar)等，而連 • 續性強化麟—般係具有連續性強化纖維，經熱固性樹脂 (如Epoxy)的預浸處理’使得熱固性樹脂包覆纖維表面，由 人工將含次熱固性樹脂未熟化(·^)的連續性強化纖維 積層鋪陳在模具内，再由適當麵裝置加熱、抽真空熟化 (CUring)成固定形狀或將纖維積層在模具内熱壓塑型，加 • 熱使熱固性樹脂熟化，熟化的熱固性塑膠可緊緊的與纖維 表面結合’可利用熱固性塑膠與纖維間的界面吸收外來的 衝擊力能量’進而形成高耐衝擊力的結構。 M362111 熱固性塑膠的特性是，一旦將具可流動性的熱固性樹 脂加熱而熟化成固態的熱固性塑膠後，該熱固性塑膠便不 會文後績的加熱而變形，亦即仍保持原有的固態形狀。熱 固性塑膠也是-種無法重複回收使用（N〇n_recyc labi e)的 樹脂。 在習用技術中，纖維堆積層在模具内塑型加熱加壓 時’預浸樹脂會職力、溫度鱗縣異而造成結晶硬化， 在纖維間造成部分難t不足以覆蓋所㈣麟表面或填 滿、截維間的空隙’使得塑型成品表面凹陷，不僅造成外觀 缺失，也帶來結翻度影響之慮。為改善上賴失，塑型 成品的凹陷部位需經補土塗裝、打拋光才能達到外觀要 求πΡ又瞻費工，打拋光造成的粉塵也容易造成污染， 需要大量人工成本卻又難以大量生產。 此外，習用技術大都採用熱固性樹脂的環氧樹脂作為 預^:樹脂’ f要_長的功以完成結晶、冷卻至硬化塑 型的熟化過程，且一旦被塑型固化後，與任何素材結合都 ^要塗佈介面溶劑樹脂以改善結合力，因此造成後續應用 時增加額外的製造成本與環保疑慮。 姓因此’需要一種具熱塑性預浸樹脂的強化纖維積層體 結構，使得在f結合不同材f的組件時，能以加熱方式達 成’而不需塗佈界面溶劑樹脂以改善結合力，同時熱塑性 預浸樹脂錢形過财具擁雜，且在㈣、加壓時不 * M362111 * 會產生部分固化，進而能避免產品外觀發生凹陷，以解決 上述習用技術的所有缺點。 【新型内容】 本創作之主要目的在提供一種連續性強化纖維積層體 結構，係包括複數個含浸第一熱塑性樹脂的連續性強化纖 維層堆積、再熱壓合而成的「連續性強化纖維積層體」，每 • 個連續性強化纖維層具有可陵曲的連續性纖維布與含浸的 第一熱塑性樹脂’第-熱塑性樹脂徹底包覆可曉曲的連續 布’第—熱雜樹脂層具有可以直接被第二熱塑性 樹脂射出成型包覆，「含浸在連續性強化纖維層的第—熱塑 可在加熱加壓下在模具内進—步麵成具堆積層 二構的所需形狀。並進-步與模内射出（0ver_m〇lding) 的第二熱紐_鏡融-聽合成純雜的結構設計 部品。 处本創作之另一目的在提供一種連續性強化纖維積層體 、σ構該結構具有複數個連續性強化纖維層與面材目標 物面材目標物係預浸第一熱塑性樹脂再藉加熱愿合而貼 ‘ 输触纖料上，而不需使_外的膠合溶顏 — $省成本並&尚產品的品質，避免結構強度的疑慮。 M362111 【實施方式】 ⑽件符料摘奴實齡式做更詳 =的賴俾使熟習該項技藝者在研讀本說明書後能據以實 參閱第—圖，本創作第—實施例之連續性強化纖維積層 體結構的不意圖。如第一圖所示，連續性強化纖維積層體結 構10包括複數個連續性強化纖維層2G，每個連續性強化纖维 層20包括可隱曲的連續性纖維布與含浸的第—熱塑性樹脂 40 ’其中連續性纖維布具有複數個可_的連續性強化纖唯 30，連續性纖維布預浸在第—熱塑性樹脂4〇中，使得第一熱 塑性樹脂4G包覆住所有的連續性強化纖維3{)。可將數個連續 性強化纖輔20堆疊成連續性強化_積層體結構，並利用 加熱加壓方式，使每個連續性強化纖維層⑼的第—熱塑性樹 脂40產生膠化而形成結合，進而將連續性強化纖維積層體結 構結合成-體。此外，可進一步利用成形模具，在加熱加壓 下’將該積層體結構塑型成所需的形狀，如第—圖中的彎折 狀3D立體塑型。 要注意的是，圖式巾只齡出二連續㈣化纖維層以方 便說明，而補作的範_包括概鱗續性触纖維層。 為進一步顯示本創作第一實施例的特點，請參閱第二 圖，係第-®的立體示意圖，其巾連續性触纖維積層體結 構10經成形模具以加熱加壓塑型後具有複雜的形狀。 * M362111 本創作的第一熱塑性樹脂係包括丙烯腈-丁二烯-苯乙稀 共聚物（人(：巧1〇1^1：1^16-61^(^61^-3七7^此483)、聚笨乙 烯（Polystyrene，PS)、聚碳酸酯（p〇iycarbonate，pC)、聚 乙烯(Polyethylene ’ PE)、丙烯腈-苯乙稀共聚物 (Acrylonitrile- Styrene，AS)、聚曱基丙烯酸甲酯 (Polymethylmethacrylate，PMMA)、聚對苯二甲酸乙二醇酯 (Polyethylene Ter印hthalate ’ PET)、聚醯胺(p〇lyamide， PA)、聚對本—甲酸乙丁二醇g旨（p〇iybothleneUniorraation Technol〇gy 'Ting' products under the rapid development of demand, the industry is all about to pursue more impact-resistant, anti-electromagnetic waves and can be recycled and reused and reduce the amount of petrochemical resin materials, in order to meet the global warranty requirements and related Industry demand. At present, the continuous lysing fiber layer industry makes _materials include Carbon Fiber, Glass Reinforced Fiber (6) Coffee Can, Polyester and Aromatic Polyamine Fiber (Kevlar). • Continuation-enhanced lining-like continuous reinforced fiber, pre-impregnated with thermosetting resin (such as Epoxy) to make the surface of the fiber coated with thermosetting resin, artificially un-cooked secondary thermosetting resin (·^) continuity The reinforced fiber layer is laid in the mold, heated by a suitable surface device, vacuum-cured (CUring) into a fixed shape or the fiber laminate is hot-pressed in the mold, and the heat is used to cure the thermosetting resin, and the cured thermosetting plastic can be tightly pressed. The tight combination with the fiber surface 'utilizes the interface between the thermosetting plastic and the fiber to absorb the external impact energy' to form a structure with high impact resistance. The characteristic of M362111 thermosetting plastic is that once the thermosetting resin with flowability is heated and matured into a solid thermosetting plastic, the thermosetting plastic will not be deformed by the heating of the post, that is, the original solid shape will remain. Thermosetting plastics are also resins that cannot be recycled (N〇n_recyc labi e). In the conventional technology, when the fiber accumulation layer is heated and pressurized in the mold, the prepreg resin will cause the work to be hardened, and the temperature and scale will cause the crystal to harden, causing some difficulties between the fibers to cover the surface of the (four) lining or filling. The gap between the full and the cut-off dimension makes the surface of the finished product concave, which not only causes the appearance to be missing, but also affects the influence of the knot turning degree. In order to improve the loss, the concave part of the finished plastic product needs to be repaired by soil and polished to achieve the appearance requirement. The dust caused by polishing is also easy to cause pollution, which requires a lot of labor costs but is difficult to mass produce. . In addition, most of the conventional techniques use epoxy resin of thermosetting resin as the pre-curing resin to complete the crystallization process, cooling to the hardening process, and once it is molded, it is combined with any material. ^The interface solvent resin is applied to improve the bonding force, thus causing additional manufacturing costs and environmental concerns in subsequent applications. The surname therefore requires 'a reinforced fiber laminate structure with a thermoplastic prepreg resin, so that when f is combined with a component of a different material f, it can be achieved by heating' without the need to coat the interface solvent resin to improve the bonding force, while the thermoplastic pretreatment The resin-impregnated money is rich in possession, and in the case of (4), when pressed, *M362111* will be partially cured, thereby preventing the appearance of the product from being sunken, to solve all the shortcomings of the above-mentioned conventional technology. [New content] The main purpose of this creation is to provide a continuous reinforced fiber laminate structure comprising a plurality of continuous reinforcing fiber layers impregnated with a first thermoplastic resin and reheat-compressed. Body, each continuous reinforcing fiber layer has a woven continuous fiber cloth and an impregnated first thermoplastic resin 'the first thermoplastic resin is completely coated with the succinct continuous cloth'-the hot resin layer has Directly coated by the second thermoplastic resin, "the first thermoplastic impregnated in the continuous reinforcing fiber layer can be introduced into the mold under heat and pressure into a desired shape with a stacked layer." Step and in-mold injection (0ver_m〇lding) of the second thermal _ mirror fusion-audio synthesis of pure structural design parts. Another purpose of this creation is to provide a continuous reinforced fiber laminate, σ structure has A plurality of continuous reinforcing fiber layers and a surface material target surface material target system are pre-impregnated with the first thermoplastic resin and then attached to the fiber by the heating, without the need to make the outer rubber颜 - $Save the cost and quality of the product, avoid the doubts about the strength of the structure. M362111 [Embodiment] (10) The material of the material is more detailed and the more detailed = Lai Yi makes the skilled person study this manual. In the first embodiment, the continuous reinforcing fiber laminate structure 10 includes a plurality of continuous reinforcing fibers as shown in the first figure. Layer 2G, each continuous reinforcing fiber layer 20 comprises a slidable continuous fiber cloth and an impregnated first thermoplastic resin 40' wherein the continuous fiber cloth has a plurality of continuous reinforcing fibers 30, continuity The fiber cloth is pre-impregnated in the first thermoplastic resin 4〇 so that the first thermoplastic resin 4G covers all of the continuous reinforcing fibers 3{). Several continuous reinforcing fiber auxiliary 20 can be stacked into a continuous strengthening_layered body The structure is heated and pressurized to cause the first thermoplastic resin 40 of each of the continuous reinforcing fiber layers (9) to be gelled to form a bond, and the continuous reinforcing fiber laminate structure is combined into a body. Further, the forming mold can be further used to shape the laminated body structure into a desired shape under heat and pressure, such as the curved 3D three-dimensional molding in the first drawing. It should be noted that the pattern towel is only aged. Two continuous (four) chemical fiber layers are provided for convenience of explanation, and the supplementary method includes a substantially continuous contact fiber layer. To further show the features of the first embodiment of the present creation, please refer to the second figure, which is a perspective view of the first-- The towel continuous contact fiber laminate structure 10 has a complicated shape after being heated and pressed by a forming mold. * M362111 The first thermoplastic resin of the present invention includes an acrylonitrile-butadiene-styrene copolymer ( People (: Qiao 1〇1^1:1^16-61^(^61^-37 7^this 483), Polystyrene (PS), Polycarbonate (p〇iycarbonate, pC), Poly Polyethylene 'PE, Acrylonitrile- Styrene (AS), Polymethylmethacrylate (PMMA), Polyethylene terephthalate (Polyethylene Terinhart) PET), polypamine (PA), poly-p-butyl-ethylene butyrate g (p〇iybothlene
Terephthalate，PBT)、聚苯醚醚酮（Polyether EtherTerephthalate, PBT), Polyether Ether Ketone (Polyether Ether)
Ketone ’ PEEK)以及聚醯胺酸(p〇iyetherimide，pE丨）的至少 其中之一。本創作的連續性纖維包括連續性碳纖維、玻璃纖 維、石棉纖維、工程塑膠纖維以及天然纖維的其中之一。 >閱第二圖，本創作第二實施例之連續性強化纖維積層 體結構的示意圖。如第三圖所示，在最上層的連續性強化纖 、准層20 _L具有熱塑性樹脂層22 ’該熱塑性樹脂層μ包括包 覆目標物5G以及第二熱塑性樹脂6G，其中第二熱塑性樹脂 60係匕设住5亥包覆目標物5〇。此外，本創作第二實施例之連 、、以強化、截、准積層體結構可具有複數個熱塑性樹脂層π，因 ^第三圖顯示出單層的熱塑性樹脂層22只是方便解說本創作 特點而已，並_以_本創作。可藉加熱加壓方式， 將第一熱塑性樹脂60包覆住該包覆目標物50而形成平板狀 * M362111Ketone 'PEEK) and at least one of polyphosphonic acid (p〇iyetherimide, pE丨). The continuous fibers of this creation include one of continuous carbon fiber, glass fiber, asbestos fiber, engineering plastic fiber, and natural fiber. > Referring to the second drawing, a schematic diagram of the continuous reinforcing fiber laminate structure of the second embodiment of the present invention is shown. As shown in the third figure, the uppermost continuous reinforcing fiber, the quasi layer 20_L has a thermoplastic resin layer 22' which includes a coating target 5G and a second thermoplastic resin 6G, wherein the second thermoplastic resin 60 The system set 5 包覆 cladding target 5 〇. In addition, the second embodiment of the present invention may have a plurality of thermoplastic resin layers π in a reinforcing, cross-cutting, or colloidal layer structure, because the third layer shows that the single-layer thermoplastic resin layer 22 is only convenient to explain the creative features. Only, and _ by _ this creation. The first thermoplastic resin 60 may be coated with the coating target 50 by heat and pressure to form a flat plate. * M362111
P 的包覆熱塑性樹脂的連續性強化纖維積層體， 式，將平板狀的包覆熱紐樹脂峨缩匕 纖維積層體貼附到連續性強化纖、 二實施例之連續性強化纖維積層體結構弟 =—熱_時，將第二熱塑二: =祕5g結合到連續性強化纖維修形成第二實施例之 連，'，貝性強化纖維積層體結構12。P is a continuous reinforcing reinforced fiber laminate coated with a thermoplastic resin, and a flat-shaped coated thermo-resin 峨 匕 匕 fiber laminate is attached to a continuous reinforcing fiber, and the second embodiment is a continuous reinforced fiber laminated body structure. = - Heat_, the second thermoplastic 2: = secret 5g is bonded to the continuous reinforcing fiber to form the second embodiment, ', shell-shaped reinforced fiber laminate structure 12.
為進步顯不本創作第二實施例的特點，請參閱第四 圖，係第三圖的立體示意圖，罝中 /、肀連、只性強化纖維積層體結 構2包括含浸包覆的熱塑性樹脂層22以及-連續性強化纖 維預積層體結構，而該連續性強化纖維預積層體結構係第一 貫施例之連續性強化纖維積層體結構1()。如第_所示，熱 塑性樹脂層22倾翻㈣贴瞻第—魏獻連續性強化 纖維積層體結構1G的内部邊緣。要注意的是，本實施例只是 本創作的示範性解說實例，並不是用以限定本創作範圍，亦 即被模内射出_性樹觸22位於第—之連續性強化 纖維積層體結構10外部的結構係仍落在本創作範圍内。 本創作的第二熱塑性樹脂係包括ABS、ps、pc、pE、As、 BiMA、PET、PA、PBT、P腿、PEUx麟任—前述樹脂添加— 填充材貝而成的合成樹脂(AH〇y Resin)，該填充材質包括滑 石粉(Talc)、碳纖維(carb〇n Fiber)以及玻璃纖維(GlassIn order to improve the features of the second embodiment, please refer to the fourth figure, which is a perspective view of the third figure. The 罝/, 肀, and reinforced fiber laminate structure 2 includes an impregnated coated thermoplastic resin layer. 22 and - a continuous reinforcing fiber pre-laminated body structure, and the continuous reinforcing fiber pre-laminated body structure is a continuous reinforcing fiber laminated body structure 1 () of the first embodiment. As shown in the figure _, the thermoplastic resin layer 22 is tipped over (4). The inner edge of the 1G of the fiber-reinforced laminated structure is continuously strengthened. It should be noted that this embodiment is merely an exemplary illustrative example of the present invention, and is not intended to limit the scope of the present invention, that is, the in-mold shot _ sex tree touch 22 is located outside the first continuous reinforced fiber laminate structure 10. The structure of the system is still within the scope of this creation. The second thermoplastic resin of the present invention includes ABS, ps, pc, pE, As, BiMA, PET, PA, PBT, P-leg, PEUx-Rin--the resin-added-filled synthetic resin (AH〇y). Resin), the filling material includes talc (Talc), carbon fiber (carb〇n Fiber) and glass fiber (Glass)
Fiber)的至少其中之一。本創作的包覆目標物5〇係包括金屬 ；M362111 構件陶磁構件、域能雜紗㈣触膠構件。 要;主思的是，圖式中只顯示出單-熱塑性樹脂層以方便 '而本朗乍的範圍係涵蓋包括夾層複數個熱塑性樹脂芦 的連‘性強化纖維積層體結構。 _參閱第五圖，本創作第三實關之連續性触纖維結構 7不思圖。如第五圖所示，利用熱塑性谬合樹脂別將面材目 私物70貼附到一連續性強化纖維預積層體結構上，而該連續 • 性強化纖維預積層體結構係第-實施例之連續性強化纖維^ 層體結構10，以形成具面材目標物之連續性強化纖維積層體 結構16。面材目標物70包括精美印刷過的薄膜片材（1肋曰）f 杈内漆印的轉寫膜(臟）、布料、竹薄片、木薄片以及皮革等 片狀異素材，以達到保護、美化、廣告、宣傳鱗示的功能。 因此’對於需要多種素材或色樣之外觀的機構部品或外殼的 產品市場需求而言，不需任何喷塗、印稱後製程，可直接 φ 藉本創作之結構而完成。 本創作的第三熱塑性樹脂係包括ABS、pS、pc、pE、AS、 P臟、PET、PA、PBT、PEEK以及pEI的至少其中之一。 參閱第六圖，本婦第四實施例之連姐触纖維積層 ，體結_示；|圖。如第六圖卿’第四實施例之賴性強化 纖維積層體結構18包括面材目標物7〇以及—連續性強化纖 維預積層體結構上，而該連續性強化纖維預積層體結構係第 一實施例之連續性強化纖維積層體結構1〇，其中面材目標物 M362111 70可加熱物續化纖維層2g中的熱塑性樹脂40可 人3 '又有第熱塑性樹月旨的面材目標物70結合，不需額 外的熱塑性膠合樹脂。 者僅翻贿縣辦讀佳實關，並非企 ==_任何形式上·，砂，凡有在相同之 神下所作麵摘作之任娜飾或敎，皆仍應包括 在本創作意圖保護之範轉。 •【圖式簡單說明】 第-圖為本創作第—實_之連續性強化纖維積層體結構 的示意圖。 第二圖為第一圖的立體示意圖。 第二圖為本創作第二實施例之連續性強化纖維積層體結構 的示意圖。 第四圖為第三圖的立體示意圖。 _第五圖為本創作第三實施例之連續性強化纖維積層體結構 的示意圖。 第六圖為本創作第四實施例之連續性強化纖維積層體結構 的示意圖。 【主要元件符號說明】 10、12、16、18連續性強化纖維積層體結構 12 •M362111 20連續性強化纖維層 22熱塑性樹脂層 30連續性纖維 40第一熱塑性樹脂 50包覆目標物 60第二熱塑性樹脂 '70面材目標物 -80熱塑性膠合樹脂At least one of Fiber). The coated object 5 of the present invention includes metal; M362111 member ceramic member, domain can (4) contact member. The main idea is that only a single-thermoplastic resin layer is shown in the drawings for convenience. The scope of this reading includes a sturdy reinforced fiber laminate structure including a plurality of sandwiches of thermoplastic resin. _Refer to the fifth picture, the third continuous physical contact fiber structure of this creation 7 does not think. As shown in the fifth figure, the surface material 70 is attached to a continuous reinforcing fiber pre-laminated structure by using a thermoplastic resin, and the continuous reinforcing fiber pre-laminated structure is the first embodiment. The continuous reinforcing fiber layer structure 10 is formed to form a continuous reinforcing fiber laminate structure 16 having a face material target. The facestock target 70 includes a beautifully printed film sheet (1 rib) f 杈 varnished transfer film (dirty), cloth, bamboo flakes, wood flakes, and leather, and the like, for protection, The function of beautification, advertising, and publicity. Therefore, for the market demand for the parts of the mechanism or the outer casing that require the appearance of various materials or color samples, no need for any spraying or post-printing process can be directly achieved by the structure of the creation. The third thermoplastic resin of the present invention includes at least one of ABS, pS, pc, pE, AS, P dirty, PET, PA, PBT, PEEK, and pEI. Referring to the sixth figure, the fourth embodiment of the woman's fourth sister's contact with the fibrous layer, body knot _ show; The reinforced reinforcing fiber laminate structure 18 of the fourth embodiment of the sixth figure includes a surface material target 7 〇 and a continuous reinforcing fiber pre-laminated body structure, and the continuous reinforcing fiber pre-laminated body structure system The continuous reinforcing fiber laminate structure of one embodiment, wherein the surface material M362111 70 heats the thermoplastic resin 40 in the fiber layer 2g, and the surface material of the first thermoplastic material 70 combination, no additional thermoplastic glue resin is required. Only the bribery county to read Jiashiguan, is not enterprise == _ any form, sand, where any of the same gods made under the face of Ren Na ornaments or 敎, should still be included in this creative intention to protect The turn of the van. • [Simplified Schematic Description] The first-graph is a schematic diagram of the continuous reinforcing fiber layer structure of the first-real _. The second figure is a perspective view of the first figure. The second figure is a schematic view showing the structure of the continuous reinforcing fiber laminate of the second embodiment of the present invention. The fourth figure is a perspective view of the third figure. The fifth figure is a schematic view of the continuous reinforcing fiber laminate structure of the third embodiment of the present invention. Fig. 6 is a schematic view showing the structure of the continuous reinforcing fiber laminate of the fourth embodiment of the present invention. [Main component symbol description] 10, 12, 16, 18 continuous reinforcing fiber laminate structure 12 • M362111 20 continuous reinforcing fiber layer 22 thermoplastic resin layer 30 continuous fiber 40 first thermoplastic resin 50 coated target 60 second Thermoplastic Resin '70 Face Material Target - 80 Thermoplastic Glue Resin