TWI580567B - Method and article for forming metal / ceramic article with no laser sintering powder lumping device - Google Patents

Method and article for forming metal / ceramic article with no laser sintering powder lumping device Download PDF

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TWI580567B
TWI580567B TW103117441A TW103117441A TWI580567B TW I580567 B TWI580567 B TW I580567B TW 103117441 A TW103117441 A TW 103117441A TW 103117441 A TW103117441 A TW 103117441A TW I580567 B TWI580567 B TW I580567B
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metal
laser
powder
finished product
ceramic
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TW201544312A (en
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Yu Chen
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Yu Chen
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以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法及其製品 Method for molding metal/ceramic articles by laser-free sintered powder laminating device and product thereof

本發明係有關於一種以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法及其製品,尤指一種透過無雷射燒結粉末積層裝置輸出半成品,再經高溫燒結而得成品的製造方法及其製品。 The present invention relates to a method for molding a metal/ceramic article by a laser-free sintered powder laminating device and a product thereof, and more particularly to a method for producing a finished product by outputting a semi-finished product through a laser-free sintered powder laminating device and then sintering at a high temperature. Its products.

目前之金屬製品,大多數是以傳統機械加工成型,由於傳統機械加工無法開模成型一些特殊的造形,因此近來已有業者開發出一種藉由射出方式將呈塑化狀態之金屬粉末注入一模具中成型,並於開模後取出半成品,並將該半成品經燒結而得一金屬製品,該製造方法可如我國發明專利申請案第097110042號「金屬射出成型品及其製造方法」,公告編號為第I398311號所示,該習知金屬射出之製造方法,係提供一螺柱,該螺柱內開設一螺紋孔;將金屬粉末與粘結劑均勻混煉成餵料;將該餵料製成2~15微米之顆粒;將該顆粒加熱至塑化狀態下注入一注射模具之模腔內成型出一坯體,該坯體形成有一配合孔,該配合孔之形狀及大小與該螺柱之形狀及大小相當;將該螺柱置於該坯體之配合孔內而形成預成型品;對該預成型品進行脫脂處理而去除該坯體內之粘結劑;及將該經脫脂後之預成型品進行燒結處理。 At present, most of the metal products are formed by conventional mechanical processing. Since the conventional machining cannot mold some special shapes, recently, a manufacturer has developed a metal powder which is plasticized into a mold by injection. In the middle molding, the semi-finished product is taken out after the mold is opened, and the semi-finished product is sintered to obtain a metal product. The manufacturing method can be, for example, the "metal injection molded article and its manufacturing method" of the invention patent application No. 097110042, the bulletin number is No. I398311, the conventional metal injection manufacturing method provides a stud with a threaded hole in the stud; the metal powder and the binder are uniformly mixed into a feed; the feed is made 2~15 micron particles; the granule is heated into a plasticized state and injected into a cavity of an injection mold to form a blank body, the blank body is formed with a matching hole, the shape and size of the matching hole and the stud The shape and the size are equivalent; the stud is placed in the mating hole of the blank to form a preform; the preform is degreased to remove the binder in the blank; After degreasing of the preform sintering process.

於上述習知專利前案所公開的製造方法中得知,該方法必須先製備一模具,藉由該模具之模穴達到成型半成品,因此,該習知的製造 方法,生產者每一種形狀之物品時,便必須負擔製造模具的成本與模具的的損耗損失,造成製造成本的增加,這對中小企業、小型造形工作室或個人而言,是根本無法負擔的成本,導致無法普遍的運用該項技術;另外,由於該習知前案,模具在脫模時,受制於所需退模路徑的安排,因此並無法成型任意的形狀,例如複雜的彎曲面或者多層鏤空體,而顯見有改進的必要。 It is known in the manufacturing method disclosed in the above-mentioned prior patents that the method must first prepare a mold to form a semi-finished product by the cavity of the mold, and thus the conventional manufacturing. In this way, when the producers of each shape of the article, they must bear the cost of manufacturing the mold and the loss of the mold, resulting in an increase in manufacturing costs, which is simply unaffordable for small and medium-sized enterprises, small-scale studios or individuals. The cost has led to the inability to use the technology in general; in addition, due to the prior art, the mold is subject to the required ejection path during demolding, and therefore cannot be shaped into any shape, such as a complicated curved surface or Multi-layer hollow body, and it is obvious that there is a need for improvement.

本案之發明人有鑑於此,乃加予研究創新,而揭示出本發明所揭示之製造方法。 In view of this, the inventors of the present invention have added research and innovation to disclose the manufacturing method disclosed by the present invention.

本發明之目的旨在提供一種以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法及其製品,該方法係將金屬粉末或陶瓷粉末與接合劑混合成混合物,並透過無雷射燒結之粉末積層裝置輸出成型,再經高溫燒結而得成品的製造方法;而其製品係指經由上述方法所獲得之製品。 The object of the present invention is to provide a method for molding a metal/ceramic article by a laser-free sintered powder laminating device and a product thereof, which are obtained by mixing a metal powder or a ceramic powder with a bonding agent into a mixture and passing through a laser-free sintering process. The powder laminating device is output molded, and then subjected to high-temperature sintering to obtain a finished product manufacturing method; and the product thereof refers to a product obtained by the above method.

上述之無雷射燒結之粉末積層裝置(3D Printer),係已普遍運用於成型塑膠等非金屬或陶瓷材料,其結構並非本發明之申請標的,故不予贅述。 The above-mentioned laser-free sintered powder laminating device (3D Printer) has been widely used for molding non-metallic or ceramic materials such as plastics, and its structure is not the subject of the present invention, and therefore will not be described.

本發明所揭示以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,係將85%~95%重量比的金屬粉末或陶瓷粉末,與5%~15%重量比的接合劑混合行成混合物後,將該混合物置入於市售無雷射燒結粉末積層裝置中,該無雷射燒結粉末積層裝置係接收一指令,並依該指令在3度空間中逐層地堆積該已與接合劑混合之金屬粉末或陶瓷粉末(additive manufacturing),以完成與輸入指令相對應的半成品。上述之指令係指透過 繪圖軟體、多媒體載具、無線或有線方式傳送至該無雷射燒結粉末積層裝置之電子訊號者。 The method for molding a metal/ceramic article by a laser-free sintered powder laminating device discloses a method of mixing 85% to 95% by weight of metal powder or ceramic powder with a binder of 5% to 15% by weight. After the mixture, the mixture is placed in a commercially available, non-laser sintered powder laminating apparatus that receives an instruction and stacks the bonded and layered layers in a 3 degree space according to the instruction. The metal powder or additive manufacturing is mixed to complete the semi-finished product corresponding to the input instruction. The above instructions refer to A graphics software, multimedia carrier, wireless or wired transmission to the electronic signal of the laser-free sintered powder lamination device.

本發明所揭示以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,其中金屬粉末或陶瓷粉末與接合劑混合成混合物,便可以將混合物直接利用一般市售較低階不具雷射燒結之粉末積層裝置,進行成型,而形成半成品,藉由積層逐層成型的特性,可形成內部具有任意形狀之半成品,而不受傳統模具成型在造形上的限制,本發明半成品置於高溫爐中進行600~1800℃的燒結,以獲得金屬或陶瓷成品。 The invention discloses a method for molding a metal/ceramic article by a laser-free sintered powder laminating device, wherein a metal powder or a ceramic powder is mixed with a bonding agent to form a mixture, and the mixture can be directly utilized by a commercially available lower-order non-laser sintering. The powder laminating device is formed into a semi-finished product, and by forming the layer-by-layer forming property, a semi-finished product having an arbitrary shape inside can be formed without being restricted by the conventional mold forming, and the semi-finished product of the present invention is placed in a high-temperature furnace. Sintering at 600~1800 °C to obtain finished metal or ceramic.

本發明所揭示以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,係包括:1.將金屬粉末或陶瓷粉末與接合劑混合行成混合物後,直接將該混合物經由不具雷射燒結粉末積層裝置成型所得之半成品;2.將半成品經脫脂製程,以去除半成品中之接合劑;以及3.將脫脂後之半成品,置入600~1800℃進行燒結,以獲得成品。 The invention discloses a method for molding a metal/ceramic article by a laser-free sintered powder laminating device, which comprises: 1. mixing a metal powder or a ceramic powder with a bonding agent, and directly passing the mixture through a non-laser sintering powder. The semi-finished product obtained by laminating the layering device; 2. the semi-finished product is subjected to a degreasing process to remove the bonding agent in the semi-finished product; and 3. The semi-finished product after degreasing is placed at 600-1800 ° C for sintering to obtain a finished product.

上述之製造方法中,該脫脂製程係可以溶劑脫脂或置入150~550℃的高溫區中,進行高溫脫脂,本發明並不自限其脫脂方式。 In the above manufacturing method, the degreasing process can be degreased or placed in a high temperature zone of 150 to 550 ° C for high temperature degreasing, and the present invention does not limit its degreasing method.

本發明所揭示之成型方法,其中該接合劑,係指熱塑性塑膠、石臘、熱硬性塑膠等。 The molding method disclosed in the present invention, wherein the bonding agent refers to a thermoplastic plastic, a paraffin wax, a thermosetting plastic or the like.

本發明所揭示之方法,可由以下之說明及所附各圖示,而得以明晰。 The method disclosed in the present invention can be clarified by the following description and the accompanying drawings.

(1)‧‧‧無雷射燒結粉末積層裝置 (1)‧‧‧Without laser sintered powder laminating device

(2)‧‧‧爐具 (2) ‧‧‧ stove

第一圖:係本發明第一實施例之流程圖。 First Figure: A flow chart of a first embodiment of the present invention.

第二圖:係本發明第二實施例之流程圖。 Second Figure: A flow chart of a second embodiment of the present invention.

請參閱第一圖所示,本發明係有關於一種以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法及其製品,該方法係將金屬粉末或陶瓷粉末與接合劑混合行成混合物後,將該混合物透過無雷射燒結粉末積層裝置(1)輸出成型半成品,再經高溫燒結而得成品的製造方法;而其製品係指經由上述方法所獲得之製品。 Referring to the first figure, the present invention relates to a method for molding a metal/ceramic article by a laser-free sintered powder laminating apparatus and an article thereof, which are obtained by mixing a metal powder or a ceramic powder with a bonding agent. The mixture is passed through a laser-free sintered powder laminating apparatus (1) to output a semi-finished product, and then sintered at a high temperature to obtain a finished product. The product is a product obtained by the above method.

本發明所揭示以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,其中,係將85%~95%重量比的金屬粉末或陶瓷粉末,與5%~15%重量比的接合劑混合形成混合物後,將該混合物置入於市售無雷射燒結粉末積層裝置(1,如用以成型非金屬模型之3D Printer)中,該無雷射燒結粉末積層裝置(1)係接收一指令,並依該指令在立體空間中,逐層地堆積該已與接合劑混合之金屬粉末或陶瓷粉末(additive manufacturing),以完成與輸入指令相對應的半成品。上述之輸入指令係指透過繪圖軟體、多媒體載具、無線或有線方式傳送至該無雷射燒結粉末積層裝置之電子訊號者。上述之指令係指透過繪圖軟體、多媒體載具〔如抽取式記憶體、光碟片、攜帶式硬碟…等〕、無線或有線方式傳送至該無雷射燒結粉末積層裝置者。 The invention discloses a method for molding a metal/ceramic article by a laser-free sintered powder laminating device, wherein a metal powder or a ceramic powder of 85% to 95% by weight is mixed with a binder of 5% to 15% by weight. After forming the mixture, the mixture is placed in a commercially available laser-free sintered powder laminating apparatus (1, such as a 3D Printer for molding a non-metallic model), and the laser-free sintered powder laminating apparatus (1) receives an instruction. According to the instruction, in the three-dimensional space, the metal powder or additive manufacturing which has been mixed with the bonding agent is stacked layer by layer to complete the semi-finished product corresponding to the input instruction. The above input command refers to an electronic signal transmitted to the laser-free sintered powder laminating device through a drawing software, a multimedia carrier, a wireless or a wired method. The above instructions are transmitted to the laser-free sintered powder laminating apparatus through a drawing software, a multimedia carrier (such as a removable memory, a compact disc, a portable hard disk, etc.), wirelessly or by wire.

述該金屬粉末與接合劑、陶瓷粉末與接合劑,係置於100~300℃的環境中進行混煉,而獲得接合劑可以均勻地包覆於金屬粉末或陶瓷粉末外圍的混合物,亦即使各該金屬粉末或陶瓷粉末之顆粒外圍可以為接合劑包覆,以增進在積層成型時,各金屬粉末或陶瓷粉末間可以穩定 地接著定型。 The metal powder, the bonding agent, the ceramic powder and the bonding agent are kneaded in an environment of 100 to 300 ° C, and the bonding agent can be uniformly coated on the mixture of the metal powder or the ceramic powder, even if each The periphery of the particles of the metal powder or ceramic powder may be coated with a bonding agent to enhance stability between the metal powders or ceramic powders during the lamination molding. The ground is then shaped.

本發明所揭示之方法,其主要特徵,係將金屬粉末或陶瓷粉末,與接合劑混合成混合物後,便可以直接利用一般市售較低階不具雷射燒結之粉末積層裝置進行成型,藉由積層逐層成型的特性,可形成內部具有任意形狀之半成品,而不受傳統模具成型再形狀上的限制,本發明再將該半成品,置於高溫爐中進行600~1800℃的燒結,以獲得金屬成品或陶瓷成品。 The main feature of the method disclosed in the present invention is that after the metal powder or the ceramic powder is mixed with the bonding agent to form a mixture, the powder can be directly formed by using a commercially available lower-order non-laser-sintering powder laminating device. The layer-by-layer forming property can form a semi-finished product having an arbitrary shape inside, and is not limited by the conventional mold forming and shape. The semi-finished product of the present invention is placed in a high-temperature furnace for sintering at 600 to 1800 ° C to obtain Finished metal or ceramic finished product.

本發明所揭示之方法,其中所選用之金屬粉末或陶瓷粉末其顆粒粒度係介於0.1μm~100μm間者。 The method disclosed in the present invention, wherein the selected metal powder or ceramic powder has a particle size of between 0.1 μm and 100 μm.

本發明所揭示之方法,猶可如第二圖所示,係包括:1.將金屬粉末或陶瓷粉末,與接合劑混合形成混合物後,直接經由無雷射燒結粉末積層裝置(1)成型,而得半成品;2.將半成品經脫脂製程,以去除半成品中之接合劑;以及3.將脫脂後之半成品,置入600~1800℃進行燒結,以獲得成品。 The method disclosed in the present invention, as shown in the second figure, includes: 1. After metal powder or ceramic powder is mixed with a bonding agent to form a mixture, directly formed by a laser-free sintered powder laminating device (1), The semi-finished product is obtained; 2. The semi-finished product is subjected to a degreasing process to remove the bonding agent in the semi-finished product; and 3. The degreased semi-finished product is placed at 600-1800 ° C for sintering to obtain a finished product.

上述之方法中,該脫脂製程係以溶劑脫脂或置入150~550℃的高溫區中,進行高溫脫脂,本發明並不自限其脫脂方式。 In the above method, the degreasing process is degreased by a solvent or placed in a high temperature zone of 150 to 550 ° C for high temperature degreasing, and the present invention does not limit its degreasing method.

本發明所之方法,其中該金屬粉末係可指鋁、鈦、鎢、鐵、合金……等,而該陶瓷粉末係指氧化鋁、氧化鋯……等,本發明並不予限制該金屬粉末或陶瓷粉末的種類;本發明所揭示之方法,其中應用於鋁金屬粉末成型之燒結溫度可為600℃;鎢金屬粉末成型之燒結溫度可為1500℃;陶瓷粉末的燒結溫度可為1800℃。 The method of the present invention, wherein the metal powder may be aluminum, titanium, tungsten, iron, alloy, etc., and the ceramic powder refers to alumina, zirconia, etc., and the metal powder is not limited in the present invention. Or the type of the ceramic powder; the method disclosed in the present invention, wherein the sintering temperature applied to the aluminum metal powder molding may be 600 ° C; the sintering temperature of the tungsten metal powder molding may be 1500 ° C; and the sintering temperature of the ceramic powder may be 1800 ° C.

本發明於第二圖所示之實施方式中,其中經由無雷射燒結粉 末積層裝置(1)成型,而得半成品,係可置於一爐具(2)中,於升溫的過程中,完成脫脂與燒結過程。 The invention is in the embodiment shown in the second figure, wherein the laser-free sintered powder is passed The final layering device (1) is formed, and the semi-finished product can be placed in a stove (2), and the degreasing and sintering process is completed during the heating process.

本發明揭示之方法,由於該無雷射燒結粉末積層裝置,具有低價、易取得、體積小不佔空間的優點,因此本發明更容易為一般中小企業使用者、SOHO族、個人造型工作室接受及使用,使本發明所揭示之製造方法具有極高經濟價值;另外,本發明可以解決目前成品藉由金屬開模射出方式,無法製成特殊物品形狀的缺點,藉由本發明,可以使成型之形狀不再受限,更符合產業上的需求,而顯其新穎性及進步性。 According to the method disclosed in the present invention, since the laser-free sintered powder laminating device has the advantages of low cost, easy availability, small volume and no space occupation, the present invention is more easily used for general SME users, SOHO families, and personal modeling studios. The invention discloses that the manufacturing method disclosed by the invention has extremely high economic value; in addition, the invention can solve the defects that the current finished product can not be made into a shape of a special article by means of metal mold opening, and the invention can be formed by the invention. The shape is no longer limited, more in line with the needs of the industry, and its novelty and progress.

本發明所揭示之方法,可於不違本發明之精神及範疇下予以修飾應用,本發明並不予自限。 The method disclosed in the present invention can be modified and applied without departing from the spirit and scope of the invention, and the invention is not limited.

(1)‧‧‧無雷射燒結粉末積層裝置 (1)‧‧‧Without laser sintered powder laminating device

Claims (7)

一種以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,該方法係將金屬粉末或陶瓷粉末與接合劑混合形成混合物後,將該混合物透過無雷射燒結粉末積層裝置輸出成型半成品,再經高溫燒結而得成品的製造方法;其中該混合物係以85%~95%重量比的金屬粉末或陶瓷粉末,與5%~15%重量比的接合劑混合,並經100~300℃的環境中進行混煉而得之混合物。 A method for molding a metal/ceramic article by a laser-free sintered powder laminating device, which comprises mixing a metal powder or a ceramic powder with a bonding agent to form a mixture, and then passing the mixture through a laser-free sintered powder laminating device to output a semi-finished product, and then a method for producing a finished product by high-temperature sintering; wherein the mixture is mixed with a metal powder or a ceramic powder of 85% to 95% by weight, mixed with a binder of 5% to 15% by weight, and subjected to an environment of 100 to 300 ° C Mixture obtained by mixing. 如請求項1所述以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,其中燒結溫度為600~1800℃。 A method of molding a metal/ceramic article by a laser-free sintered powder laminating apparatus as claimed in claim 1, wherein the sintering temperature is 600 to 1800 °C. 如請求項1所述以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,其中所選用之金屬粉末或陶瓷粉末其顆粒粒度係介於0.1μm~100μm間者。 A method of molding a metal/ceramic article by a laser-free sintered powder laminating apparatus as claimed in claim 1, wherein the selected metal powder or ceramic powder has a particle size of between 0.1 μm and 100 μm. 如請求項1所述以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,其中於燒結前,該半成品係經脫脂製程,以去除半成品中之接合劑。 A method of molding a metal/ceramic article by a laser-free sintered powder laminating apparatus as claimed in claim 1, wherein the semi-finished product is subjected to a degreasing process to remove the bonding agent in the semi-finished product before sintering. 如請求項4所述以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,其中該脫脂製程係以溶劑脫脂。 A method of molding a metal/ceramic article by a laser-free sintered powder laminating apparatus as claimed in claim 4, wherein the degreasing process is degreased with a solvent. 如請求項4所述以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法,係將半成品置入150~550℃的高溫區中,進行高溫脫脂。 According to the method of claim 4, the metal/ceramic article is formed by the laser-free sintered powder laminating device, and the semi-finished product is placed in a high temperature region of 150 to 550 ° C for high-temperature degreasing. 如請求項4所述以無雷射燒結粉末積層裝置成型金屬/陶瓷物品之方法而得半成品,係置於一爐具中,於升溫的過程中,完成脫脂與燒結過程。 The semi-finished product is obtained by the method of molding the metal/ceramic article without the laser-sintered powder laminating device as described in claim 4, and is placed in a stove, and the degreasing and sintering process is completed during the heating process.
TW103117441A 2014-05-19 2014-05-19 Method and article for forming metal / ceramic article with no laser sintering powder lumping device TWI580567B (en)

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JPH0820808A (en) * 1994-07-06 1996-01-23 Olympus Optical Co Ltd Production of sintered compact
CN103769586A (en) * 2013-11-26 2014-05-07 王利民 Metal 3D printing product production method by means of low-power laser sintering

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0820808A (en) * 1994-07-06 1996-01-23 Olympus Optical Co Ltd Production of sintered compact
CN103769586A (en) * 2013-11-26 2014-05-07 王利民 Metal 3D printing product production method by means of low-power laser sintering

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