1310414 九、發明說明： 【發明所屬之技術領域】 、土二2關於一種去氧核醣核酸(dna)防偽纖維缝制 造用的嘴絲嘴及方法，特別是關於一種應用^衣 被仿冒用防偽纖維的製造。 、、、’織品 【先前技術】 由、、=酿核酸防偽的主要原理是將去氧核酿核酸，瘦 由f&或附者於特定媒材的方式(如顏料、膠水、齡 等)’以去氧核醣核酸獨特複雜且難 二;生由 來保=品纽被仿冒，以增加營收，同時&製商的幾特性， 織品尚未=品Γ:冒’具有加入特殊機能物質之纺 W口口向禾見於市面，目前所知，為達 殊機能物質於纖維以供儀器辨識之主要方法有σ入特 第-類為利用表面改f ，命乙群於纖維。第二類為以酵素處理纖維==維 2成防偽可辨識效果。第三類之 用 術，將狀舰點之錢_核 包覆技 中，達成防偽機能。 I成微膠囊摻入纖維 以上二種方式各有優劣，且似伞+A 有效防偽及儀器直接_探知之=可達成紡織品快速 闕製程及後加工流程加以分柄森旦仔細就紡織品相 ，真正有效達 一·前處理精練漂白影響 1310414 一般天然纖維因其成分多含有油脂及大量灰土故+ 以鹼類及皂類加以洗滌，而以酵素處理接枝甲殼素，達: 防偽辨識效果之纖維，若已在此摻入，將會發生脫落而失 效之情況，因為曱殼素（幾丁 (chitin(p-Poly-N-acetly-D-glucosaming))、幾丁聚 (chitosan(p-Ploy-D-glucosaming)))是不同於其它的'夕醣 類’它能產生強大的正電性，因此可與特定的化學物Z 化學鍵結，尤其是針對帶負電荷之油脂產生強大的姓人处 力，所以在精練漂白製程中會與動植物 二 結合而溶於含息驗之_水中（故工 理廢水，吸附油污及其他可能的有毒物質），因 j處 防偽辨識效果；甲殼素為自然界中唯_的自然=纖維 =在於昆蟲、甲殼類動物之硬殼及菌類 :： 維之製造應相當不錯，但若要作為防偽之::於，性纖 極易遭到仿冒。所以在纺織品快速有效防偽方=有不當’ 應用將會受到極大限制。 、、/及機制之 一.布胚高溫高壓染整處理影響 紡織品在製成布胚之後，後處理加 整處理製成具多樣色彩之布料，所以 =^于兩溫染 製布胚均需以水添加各類有機或無機;^種纖維材料所 布胚必需雜在120·2()()度高溫溫染色， 左右才能達成較佳之處理效果；因此=2G.30分鐘 電衆處理纖維表面接植維他命 j、錢面改質技術以 维’將會纽-高訂射㈣㈣ ^10414 、、=是水溶性物質，所以在高溫高壓水處理後將會完全被 ^条而消失於布胚中，而且如同甲殼素—般取得容易、不 一有獨特單一之特性以及可作為機能性纖維之製造，所以 在紡織品快速有效防偽方法及機制之應用亦會受到極大之 限制。 而苐二類採用微膠囊包覆技術將設定特點 醣，酸包成微膠囊摻人纖維中，達成防偽機能之方式，由 於是含在纖維中所以並不容易發生流失現象，且其具備極 佳之耐熱性與抗酸鹼性，受熱達25〇度維持四十分鐘後仍 能保有原始之狀態，最重要的是，去氧核醣核酸具有較佳 隱密性與獨躲’所以應較適合作為快速有效防偽之方法 及機制。但是如何均勻有效的把去氧核醣核酸轉植於纖維 中並提升牛度，進而製出具去氧核醣核酸防偽技術之紡織 品將是一大挑戰。 微膠囊之結構組成是由囊心和囊膜兩部分所組成，壁 材可為各種天然或合成高分子物質，其大小一般約為直徑 10〜200微米’形狀多為球形或多面体，一般製造多採用相 分離法和界面聚合法但也可利用其他特殊方法加以製造； 微膠囊技術最早在五零年代出現’最初應用於非碳複寫紙 之轉印油墨之製作，近年來更已成功地應用於印刷、醫藥、 生化、液晶4領域。隨者環保意識的抬頭其在公害廢水防 治上亦有相當之成效，尤其在紡織染整工業上對於分散、 酸性、陽離子、還原、活性及油溶性染料等均能以已微膠 囊加以包覆而利於後續廢水之處理，更能以此技術將某些 特定機能之合成物以微膠囊附著於織物上而達成機能性紡 1310414 織品之製作，所以近年來微膠囊技術在此一領域有相當大 之發展’目前主要應用於染色與印花、功能 田 吸收、化學㈣、漂白及齡等。 备、外線 法為聚合物經化學處理，變成能溶解之鹽 性固體ΓΤΓ纺成絲，通過凝固槽’再還原成非溶解 己，' ν然’其後還需做牽伸處理。纺液的黏度要調 黏度太小，拉絲時容易斷裂成液滴，黏 =r 一時_易=: 穩：。紡好的絲還要再經過後延伸加工以穩定尺 工5又備龐大而複雜。 寸八加 殊二二=核醣核酸防偽纖維具有特 絲方法必須有所調整，以達到纖 化，而習用的喷絲嘴與紡絲疋與设備簡單 .此’如何改善上述㈣手段;足所需的功效。因 動機。 缺失，係為發展本案之主要 悉心=故並:=:七述習用技術之缺失，經 【發明内容】 1310414 本案之第一構想為：提出一種製造合成纖維的嘴絲 嘴，包括一聚合物溶液進流道及一對供水進流道，且中間 的聚合物溶液進流道與兩侧的該對供水進流道匯合為__混 成流道，並在混成流道出口產生合成鐵維。如此，可以省 略傳統紡絲的後延伸加工設備，達成降低製造成本的功效。 本案之第二構想為：提出一種製造去氧核酿核酸防偽 纖維的方法’首先，將複數個去氧核醣核酸微膠囊現合入 一原料溶液中，成為一聚合物溶液；接著，在流動的聚合 馨物溶液與流動的兩股酸解用水之間形成匯合介面；然後， 產生一去氧核聽核酸防偽纖維。而藉由控制兩股酸解用水 的匯合條件，以產生不同品質的去氧核醣核酸防偽纖維。 本案之第二構想為：提出一種去氧核醣核酸防偽纖 維，其是由第二構想的製造方法所製造的。 根據第一構想所提出之較佳實施例中，一種製造合成 纖維的嘴絲嘴’包括一聚合物溶液進流道及一對供水進流 f^其中’聚合物溶液進流道用以供應製造—合成纖維的 • 聚合物溶液，該對供水進流道，位於聚合物溶液進流道 2側’用以供應兩股酸解用水；而聚合物溶液進流道與該 人，水進流道匯合為一混成流道，並在混成流道出口產生 &成纖維。 較佳者，上述之合成纖維為一去氧核醣核酸防偽纖 錢包括複數個去氧核醣核酸微勝囊。 曱酸'ϋ述之聚合物溶液是先由—尼龍6溶解於一 一此。„轉_個去氧_核酸微雜製成。 1310414 較佳者，上述之該等兩股酸解用水的水 水，溫度是攝氏60度。 只疋去離子 較佳者，上狀鋪供錢條騎巾 稱於該聚合物溶魏流_流道 、％ 道的兩條流道巾‘讀夾妓9G度。I且謂供水進流 較佳者’上述之製造合成纖維的喷絲嘴，盆 =s:r兩股酸解用水在兩侧爽擊該聚:物溶二 骒以產生酸解作用。 m 根據第二構想所提出之較佳實施例中， 核·核酸防偽纖維的方法，包括下列步驟：k去乳 氧访If ’製備—聚合物溶液’聚合物溶液包括複數個去 乳核酶核酸微膠囊；接著，驅叙 酸解L取L 液’並驅動兩股 物、、t 液兩側；織，匯合職動的聚合 防^維料流動的兩股酸解用水，產生—去氧核酷核酸 較佳者’上述之製造去氧核雜酸防偽纖維的方法包 括下列前處理步驟： 預先淨化該等兩股轉用水的水質為—去離子水；及 加熱該等兩股酸解用水為溫度攝氏60度。 較佳者，上述之製備一聚合物溶液的步驟為，溶解一 甲酸’產生—尼龍6甲酸溶液，混合該等複 物、容液氧核_織郷囊進人尼龍6曱酸溶液，產生聚合 較佳者，上述之匯合該流動的聚合物溶液與該等流動 的兩股酸解用水的步驟更包括下列步驟： 1310414 藉由該等流動的兩股酸解用水在 物溶液，產生酸解作用；及藉_整聚合 流率，控制該去氧核醣核酸防偽纖維成形的直徑與=的 【實施方式】 為了敘述清楚本案所提出之去氧核 其製造用的_嘴及方法，下⑥· ^ 纖維與 說明： 狀方法列舉—個較佳實施例加以 請參閱第1，其為本案所提出之製造合成纖維的喷 絲嘴的〜道不意圖。在第一圖中，製造合成纖維的嗔絲嘴 80包括-聚合物溶液麟道31及—對供水進流道A%; 其中’聚合物驗進流道31用以供應製造—合成纖維的一 聚合物溶液化該對供水進流道32、％位於該聚合物溶 液進流道31兩侧，用以供應兩股酸解用水幻、43 ;而聚 合物溶液進流道31與該對供水進流道32、33匯合為一混 成流道34，並在該混成流道34出口產生該合成纖維。 在製造合成纖維的噴絲嘴80中，聚合物溶液進流道 31位於中間，且流過所欲製造合成纖維的聚合物溶液41， 而所欲製造的合成纖維在本實施例中為一去氧核醣核酸防 偽纖維，但亦可應用於其他類型的合成纖維的製造。當所 欲製造的合成纖維為一去氧核醣核酸防偽纖維時，聚合物 溶液41包括複數個去氧核醣核酸微膠囊。 本實施例的聚合物溶液41是先由一尼龍6溶解於一甲 酸’然後混合該等複數個去氧核醣核酸微膠囊製成。但旅 不限定僅應用於尼龍6纖維材質與曱酸溶劑。 1310414 在聚合物溶液進流道31的兩 32、33，該對供水進流道32、3 :十供水進-道 聚合物溶液進流道31的流道中線對稱於 133的兩條流道中心線爽角是小：;=對 ^ 於180度。在本實施例 ^。°請供水進流道32、33的兩條流道中心線夾角是90 該對供水進歧32、33 _____ _，酸解用水42、43的水 二1310414 IX. Description of the invention: [Technical field to which the invention pertains], and the method and method for manufacturing a DNA microparticle (dna) anti-counterfeit fiber seam, in particular, an anti-counterfeiting fiber for use in counterfeiting Manufacturing. ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, It is unique and difficult to use with deoxyribonucleic acid; it is counterfeited to increase the revenue, and at the same time, several characteristics of the manufacturer, the fabric has not yet = Γ: take the textile with the addition of special functional substances The mouth is seen in the market, and it is known that the main method for the identification of Dash’s functional substances in the fiber is to use the surface to change the f-type to the fiber. The second type is the treatment of fiber with enzyme == dimension 2 into an anti-counterfeit identifiable effect. In the third category, the anti-counterfeiting function is achieved in the money-nuclear coating technology. I into microcapsules into the fiber above the two ways have their own advantages and disadvantages, and like umbrella + A effective anti-counterfeiting and instrument direct _ detect the = can reach the textile rapid 阙 process and post-processing process to split the handle to the textile phase, really Effective up to 1. Pre-treatment scouring and bleaching effect 1310414 Generally, natural fiber is washed with alkali and soap because of its multi-component oil and a large amount of ash, and the chitin is treated with enzyme to achieve: anti-counterfeiting effect fiber. If it has been incorporated here, it will fall off and fail, because chitin (p-Poly-N-acetly-D-glucosaming), chitosan (p-Ploy- D-glucosaming))) is different from other 'sweet sugars' which produce strong positive electricity and therefore can be chemically bonded to specific chemicals, especially for negatively charged oils. Force, so in the scouring and bleaching process, it will be combined with animals and plants and dissolved in the _ water (including engineering wastewater, adsorption oil and other possible toxic substances), because of the anti-counterfeiting identification effect; chitin is in nature Only _ = Ran = fiber wherein insects, crustaceans and the hard shell of the manufacturing dimensional :: fungi shall quite good, but in the counterfeit was to, as the security of the fiber easily ::. Therefore, the application of fast and effective anti-counterfeiting of textiles = improperly will be greatly limited. One of the mechanisms, and/or the mechanism. The high temperature and high pressure dyeing and finishing of the cloth embryo affects the textile after the fabric is made into a cloth, and the post-processing and finishing process is made into a fabric with various colors. Therefore, it is necessary to dye the cloth embryo at both temperatures. Water is added to various types of organic or inorganic materials; the embryos of the fiber materials must be mixed at a temperature of 120·2()(), and the temperature can be dyed at a high temperature to achieve a better treatment effect; therefore, the surface of the fiber is treated with 2G.30 minutes. Plant vitamin V, money surface modification technology to maintain 'will New-high order (4) (four) ^ 10414,, = is a water-soluble substance, so after high temperature and high pressure water treatment will be completely removed into the embryo, Moreover, as chitin is easy to obtain, unique and unique, and can be used as a functional fiber, the application of fast and effective anti-counterfeiting methods and mechanisms for textiles is also greatly limited. The second type of microcapsule coating technology will set the characteristic sugar and acid into microcapsules and blend into the fiber to achieve the anti-counterfeiting function. Because it is contained in the fiber, it is not easy to lose, and it has excellent performance. It has heat resistance and acid and alkali resistance. It can maintain its original state after being heated for 25 minutes, and most importantly, it has better privacy and independence. Therefore, it should be more suitable. Fast and effective anti-counterfeiting methods and mechanisms. However, how to uniformly and efficiently transfer DNA to fibers and increase the degree of cattle, and then produce textiles with DNA anti-counterfeiting technology will be a challenge. The structure of the microcapsules is composed of two parts: the core and the capsule. The wall material can be various natural or synthetic high-molecular materials, and the size is generally about 10~200 micrometers in diameter. The shape is mostly spherical or polyhedral. The phase separation method and the interfacial polymerization method can be used, but other special methods can also be used for manufacture; the microcapsule technology first appeared in the first half of the 1990s, and the printing ink originally applied to non-carbon carbon paper has been successfully applied in printing in recent years. , medicine, biochemistry, and liquid crystal 4 fields. With the rise of environmental awareness, it has also achieved considerable results in the prevention and control of public waste water. Especially in the textile dyeing and finishing industry, it can be coated with microcapsules for dispersing, acid, cationic, reducing, active and oil-soluble dyes. In order to facilitate the treatment of subsequent wastewater, it is better to use this technology to attach certain specific functional composites to the fabric by microcapsules to achieve the production of functional spinning 1310414 fabric. Therefore, in recent years, microcapsule technology is quite large in this field. Development 'currently used mainly in dyeing and printing, functional field absorption, chemistry (four), bleaching and age. The preparation and external line method is that the polymer is chemically treated to become a soluble salty solid, which is spun into filaments, which are then reduced to non-dissolved by the coagulation tank, and then need to be stretched. The viscosity of the spinning solution should be adjusted to be too small, and it is easy to break into droplets when drawing, and the viscosity is =r. _ Easy =: Stable: The spun yarn is then subjected to post-extension processing to stabilize the masonry 5 and is large and complex. Inch eight plus two two = ribonucleotide anti-counterfeiting fiber with a special method must be adjusted to achieve fibrillation, while the conventional spinneret and spinning raft and equipment is simple. This 'how to improve the above (four) means; The effect required. Motivation. Missing is the main concern for the development of this case. == and:=: The lack of seven techniques of use, according to the content of the invention 1310414 The first concept of the case is: propose a nozzle for the manufacture of synthetic fibers, including a polymer solution The inlet channel and the pair of water supply inlet channels, and the intermediate polymer solution inlet channel merges with the pair of water supply inlet channels on both sides into a __mixed flow channel, and a synthetic iron dimension is produced at the mixed channel outlet. In this way, the post-extension processing equipment of the conventional spinning can be omitted, and the effect of reducing the manufacturing cost can be achieved. The second concept of the present invention is to propose a method for manufacturing an anti-counterfeit fiber for deoxyribonucleic acid. First, a plurality of deoxyribonucleic acid microcapsules are combined into a raw material solution to form a polymer solution; The polymerization solution forms a confluence interface with the flowing two acid hydrolyzed water; then, a deoxyribonucleic acid anti-counterfeiting fiber is produced. By controlling the confluence conditions of the two acid hydrolysis waters, different quality DNA anti-counterfeiting fibers are produced. The second concept of the present invention is to propose a DNA anti-counterfeit fiber which is manufactured by the manufacturing method of the second concept. According to a preferred embodiment set forth in the first concept, a nozzle for manufacturing synthetic fibers includes a polymer solution inlet channel and a pair of water supply inlets, wherein the polymer solution inlet channel is used for supply manufacturing. - synthetic fiber • polymer solution, the pair of water supply channels, located on the side of the polymer solution inlet 2 'to supply two acid hydrolysis water; and the polymer solution into the flow channel and the person, water into the flow channel Confluence is a mixed flow path and produces & fiber at the outlet of the mixed flow channel. Preferably, the synthetic fiber is a DNA anti-counterfeiting fiber comprising a plurality of deoxyribonucleic acid microcapsules. The polymer solution described in the tannic acid is first dissolved in - nylon 6 one by one. 『转_一氧氧_核核微杂制。 1310414 Preferably, the above two water-soluble water for acid hydrolysis, the temperature is 60 degrees Celsius. Only the deionized ion is better, the upper shop for money The kerchief is called the two flow passages of the polymer melted Wei flow _ flow channel, % channel, and the reading 妓 9G degree. I and the water supply flow is better, the above-mentioned spinner for manufacturing synthetic fibers, Pot = s: r two acid hydrolysis water on both sides to smother the poly: solution diterpene to produce acid hydrolysis. m according to the preferred embodiment proposed in the second concept, the method of nuclear nucleic acid anti-counterfeiting fiber, The method comprises the steps of: k removing the lactate to access the 'preparation-polymer solution' polymer solution comprising a plurality of denuclear ribozyme nucleic acid microcapsules; then, driving the acidolysis L to take the L liquid and driving the two substances, t Both sides of the liquid; weaving, converging the polymerization of the two anti-feeding materials to prevent the flow of water, the production of - deoxyribonucleic acid better - the above method for the manufacture of deoxyribonucleic acid anti-counterfeiting fibers including the following pre-treatment Step: pre-purifying the water quality of the two water-transfer waters - deionized water; and heating the two acid solutions The water is at a temperature of 60 degrees Celsius. Preferably, the above step of preparing a polymer solution is to dissolve a formic acid 'produced-nylon 6 formic acid solution, and mix the complexes, the liquid nucleus of the liquid _ woven sac into the nylon 6 曱 acid solution, preferably to produce a polymer, the above-mentioned step of converging the flowing polymer solution with the two streams of acid hydrolysis of the flow further comprises the following steps: 1310414 by the two streams of acid hydrolysis The solution of the solution produces an acidolysis; and the diameter of the DNA anti-counterfeit fiber formed by the polymerization flow rate is controlled by the method of "the embodiment" for the purpose of describing the oxygen-containing core proposed in the present invention. And the method, the following is a description of the preferred embodiment. Please refer to the first embodiment, which is the first embodiment of the present invention. The dosing nozzle 80 for manufacturing synthetic fibers includes a polymer solution lining 31 and a water supply inlet passage A%; wherein the 'polymer inspection flow passage 31 is for supplying a polymer-synthesized fiber to dissolve the polymer Inflow of water 32. % is located on both sides of the polymer solution inlet passage 31 for supplying two acid hydrolysis water, 43; and the polymer solution inlet passage 31 and the pair of water supply inlet passages 32, 33 are merged into a mixed flow. The synthetic fiber is produced at the outlet of the mixed flow passage 34. In the spinneret 80 for producing synthetic fibers, the polymer solution inlet passage 31 is located in the middle, and flows through the polymer solution 41 of the synthetic fiber to be produced. And the synthetic fiber to be manufactured is a DNA anti-counterfeit fiber in this embodiment, but can also be applied to the manufacture of other types of synthetic fiber. When the synthetic fiber to be manufactured is a DNA anti-counterfeiting fiber The polymer solution 41 comprises a plurality of deoxyribonucleic acid microcapsules. The polymer solution 41 of the present embodiment is prepared by first dissolving a nylon 6 in a monocarboxylic acid' and then mixing the plurality of deoxyribonucleic acid microcapsules. However, Brigade is not limited to nylon 6 fiber materials and tannic acid solvents. 1310414 In the two 32, 33 of the polymer solution inlet channel 31, the pair of water supply inlet channels 32, 3: ten water supply channel polymer solution inlet channel 31 in the flow channel line symmetry to 133 of the two channel center The line cool angle is small:; ==^ at 180 degrees. In this embodiment ^. ° Please enter the water supply into the flow passages 32, 33. The angle between the centerlines of the two flow passages is 90. The pair of water supply divergence 32, 33 _____ _, the acid hydrolysis water 42, 43 water
水42、43為埶水時，1對綮人铷、々去離子水。虽酸解用 / 士 h 溶液41的酸解效果較佳。 在本實施财，酸制水42、43的溫度是攝氏6〇度。 由於該等兩股酸解用水42、43是以具傾斜角的 近混成流道34，故當聚合物溶液 弋接 4將2在43流人混成—之後，該等兩及=；=4解2用: 將在兩丨歧擊棘合餘液4卜以產线解作用。 接著介紹製造去氧核醣核酸防偽 明採用本實施方法的理由。纖義以，首先說 “ j 由&於去氧_核酸微膠囊不耐 二雜：溫的持久性較不佳。若要製造去氧核醣核酸防 ，在抽絲純·計上_完全捨錢⑽絲的傳 改採為化學溶液濕式紡絲法。如此，在產品的生 產上就可以完全不考量熱的效應， 釀核酸微膠囊對於化學溶液的比例即可以; 與失敗機率，並方便產品的製作。 一 以下說明製備聚合物溶液41的配方，聚合物溶 t括複數個絲核醣鍵微膠囊1合物溶液Μ的配方 12 1310414 (甲酸+尼龍6)—(加熱)—（混合去氧核醣核酸微膠囊 (PS薄膜))—冷卻。 而聚合物溶液41的濕式紡絲配方如下： (曱酸+尼龍6+去氧核醣核酸微膠囊乂〜驅動該聚合物 /容液進入喷絲嘴―與去離子水混合—酸解控制PH值—(尼 月I 6+去氧核核酸微膠囊)s—熱風烘乾_^纖絲。其中，下 標L表示液態，下標s表示固態。 上述濕式紡絲的步驟包括：驅動聚合物溶液41，並驅 動兩股酸解用水42、43接近聚合物溶液41兩侧；及匯合 該流動的聚合物溶液41與該等流動的兩股酸解用水42、 43，產生一去氧核醣核酸防偽纖維。 請繼續參閱第二圖，其為本案所提出之製造去氧核醣 核酸防偽纖維的方法之一較佳實施例中，聚合物溶液在喷 絲嘴中細絲化並酸解的攝影圖。在第二圖中，當尼龍6的 聚合物溶液41受到上下兩股酸解用水42、43的熱水流夾 擊時，會產生斷面尺寸逐漸縮小化的情況，在此同時亦發 生酸解作用，釋出酸性溶液而凝固成形，變成内含去氧核 醣核酸微膠囊的尼龍6纖維絲。如圖所示，去氧核醣核酸 微膠囊及尼龍6所混成的酸性溶液由中心的主流道加入， 在噴絲嘴80出口紡絲速度的限制下，聚合物溶液41與該 等兩股酸解用水42、43的流率大小將會決定纖絲成型的尺 寸，而上下兩側的兩股酸解用水42、43(熱水，溫度為攝 氏60度)則提供紡絲過程的酸解作用，其加入量越大酸解 效果越佳而纖絲尺寸也將會因總出口流率固定的影響而下 降，加入置越少纖絲尺寸將會加大，但卻會因酸解度不足 13 1310414 ==^。基於上㈣，可知，以較大流率熱水 内含的去^秋似乎較佳；但實際上，由於過細的纖絲所 的认人、亥醣核酸微膠囊的數量不足，而無法滿足後續 佳^寸=故以樣品的有效檢測濃度所推算得的纖絲最 著，為了有效特徵化微尺度下的喷絲嘴流體特性， 率比其中為聚合 的質^流率的質讀率，m_r為兩股酸解用水42、43加總 1繼續參閱第三圖⑻、第三圖⑻與第三_，第三圖 攻，弟—圖之製造去氧核醣核酸防偽纖維的方法中，質量 =率比Φ=1.0時，去氧核醣核酸防偽纖維的成形攝影圖； ^圖^為第二圖之製造去氧核醣核酸防偽纖維的方法 史質1流率比φ=2.0時，去氧核醣核酸防偽纖維的成形 攝影圖；第三圖⑷為第二圖之製造去氧核酶核酸防偽纖維 方法中’質量流率比〇>=G.5時’去氧核醣核酸防偽纖維的 成形攝影圖。在第三圖⑻、第三圖(b)與第三圖⑷中，在穩 定的出口勤與總流率的情況下，藉著調整上下兩側的兩 股酸解用水42、43的流率，將可控制成型纖絲的寬度。亦 即調整質量流率比φ從Φ=2.0至㈣.5，則成形出的纖絲 尺寸直徑將對應為從ΙΟΟμιη到25μηι。 接著說明在混成流道34内流場的速度分佈。請參閱第 四圖（a)、第四圖作)與第四圖（c) ’第四圖（a)為質量流率比 時，以微粒子測速儀系統測量得之去氧核醣核酸防 偽纖維混成流道内流場的雷諾數Re變化圖；第四圖(的為 14 1310414 貝里流率比φ=2.0時，以微粒子測速儀系統測量得之去氧 ，醣核酸防偽纖維混成流道内流場的雷諾數Re變化圖； 第二圖(e)為質量流率比φ=().5時，以微粒子測速儀系統測 量仵之去氧核醣核酸防偽纖維混成流道内流場的雷諾數 Re變化圖。在第四圖（a)、第四圖(b)與第四圖（c)中，喷絲 嘴8〇混成流道34區域的酸解用水42、43與聚合物溶液 41同時加入反應，酸解用水42、43佔據了大部分區域， =且由於酸解用水的夾擊，迫使聚合物溶液41的流動範圍 縮小而高速流動，因此聚合物溶液41的内部流與兩股酸解 用水42 43的外部流在接近介面的部分將會產生極大的速 度差異，但是在很短的流動距離後，内外流場的流動速度 差異將會迅速耦合而形成單一典型的拋物線完全擴展流。 在第四圖（a)、第四圖(b)與第四圖（c)的每個圖中都有三 條曲線，分別代表在内外流體發生接觸後算起，往流動方 向Υ-75μιη，γ=13〇μιη，及γ=25〇μιη處流道橫斷面的流場 速度为佈曲線，其中，χ是流場位置至噴絲嘴80混成流道 34壁的距離’無因次速度的雷諾數Re大小為Re=pVL/v， P為流體密度，v為動黏度，L是内流場中心至喷絲嘴8〇 混成流道34壁的距離。由圖中可發現，内外流體的質量流 率差異越大時，外部流體將迫使内部流體以更高速度流 動，如此成型纖維尺寸也將越細小，但因成型速度過快， 將致使去氧核醣核酸微膠囊的數量在有限長度内變越少。 所以由速度測量結果可知，在φ=1〇時，完全擴展流的最 大無因次速度Re約為3.5左右，換算為平均流動速度為 25(^m/sec ;而纖絲直徑約50μιη，若以一英寸長尼龍6體 15 1310414 積約0.02C.C.，纖絲在去氧核醣核酸微膠囊的濃度為 1000ppm(g/C.C.)之情況下’將有0.02mg的含量；在此情 況下’若可取樣得100根纖絲’則對於後續的聚合晦分析 而言，就可以足夠。 本案之特點為：一種製造合成纖維的噴絲嘴，包括： 一聚合物溶液進流道用以供應製造一合成纖維的一聚合物 溶液；一對供水進流道，位於聚合物溶液進流道兩侧，用 以供應兩股酸解用水；而聚合物溶液進流道與該對供水進When the waters 42 and 43 are drowning, one pair of cockroaches and cockroaches deionized water. Although the acid hydrolysis effect of the /acid solution 41 is better. In this implementation, the temperature of the acid waters 42, 43 is 6 degrees Celsius. Since the two solubilized waters 42 and 43 are near-mixed flow paths 34 having an inclined angle, when the polymer solution is spliced 4 and 2 is mixed with 43 people, the two are ===4 solutions 2 use: will be in the two 丨 丨 棘 棘 合 合 4 4 4 4 4 以 解 解 解 解 解Next, the reason for using this embodiment of the method for manufacturing DNA anti-counterfeiting will be described. Fibrous meaning, first of all, "j by & deoxygenation_nucleic acid microcapsules are not resistant to two miscellaneous: the durability of temperature is less. If you want to make DNA prevention, on the pure silk meter (10) The transfer of silk is adopted as the chemical solution wet spinning method. Thus, the effect of heat can be completely ignored in the production of the product, and the ratio of the nucleic acid microcapsules to the chemical solution can be obtained; the probability of failure and the convenience product The following is a description of the preparation of the polymer solution 41, the polymer solution includes a plurality of silk ribose sugar microcapsules 1 solution solution Μ 12 1210414 (formic acid + nylon 6) - (heating) - (mixed deoxygenation) Ribonucleic acid microcapsules (PS film)) - cooling. The wet spinning formulation of polymer solution 41 is as follows: (Citrate + Nylon 6 + Deoxyribonucleic acid microcapsules ~ drive the polymer / liquid into the spinner Mouth - mixed with deionized water - acid solution control PH value - (Ni Yue I 6 + deoxyribonucleic acid microcapsules) s - hot air drying _ ^ fibrils. Among them, subscript L means liquid, subscript s means solid The above wet spinning step comprises: driving the polymer solution 41 and driving The two acid-dissolving waters 42, 43 are adjacent to both sides of the polymer solution 41; and the flow of the polymer solution 41 and the two streams of acid-dissolving water 42, 43, generate a DNA anti-counterfeiting fiber. With continued reference to the second figure, which is a photograph of a preferred embodiment of the method for producing an anti-counterfeit fiber for the preparation of DNA, the filament solution of the polymer solution in the spinneret and acidolysis. In the figure, when the polymer solution 41 of the nylon 6 is pinched by the hot water flow of the upper and lower two acid hydrolysis waters 42, 43, the cross-sectional size is gradually reduced, and at the same time, acid hydrolysis occurs, and acidity is released. The solution is solidified and formed into a nylon 6 fiber filament containing the microcapsules of the deoxyribonucleic acid. As shown in the figure, the acidic solution mixed with the deoxyribonucleic acid microcapsule and the nylon 6 is added from the center of the main channel, in the spinneret. Under the limitation of the 80 outlet spinning speed, the flow rate of the polymer solution 41 and the two acid hydrolysis waters 42 and 43 will determine the size of the filament formation, and the two acid hydrolysis waters on the upper and lower sides 42 and 43 (hot water, temperature is 6 ° Celsius 0 degree) provides the acid hydrolysis of the spinning process, the greater the amount of addition, the better the acid hydrolysis effect and the size of the filament will also decrease due to the fixed total outlet flow rate, and the smaller the filament size will be added. Increased, but it will be less than 13 1310414 ==^ due to acid hydrolysis. Based on the above (four), it can be seen that the hot water contained in the hot water flow seems to be better; but in fact, due to the fine filament The number of identifiable and hexameric microcapsules is insufficient, and cannot satisfy the subsequent sufficiency. Therefore, the fibrils estimated by the effective detection concentration of the sample are the most important, in order to effectively characterize the characteristics of the nozzle at the micro-scale. , the ratio is the mass reading rate of the mass flow rate of the polymerization, m_r is the two acid hydrolysis water 42, 43 plus the total 1 continue to refer to the third figure (8), the third figure (8) and the third _, the third picture attack, In the method of manufacturing DNA anti-counterfeiting fiber, when the mass=rate ratio Φ=1.0, the photographic image of the anti-counterfeit fiber of the DNA; ^Fig. 2 is the manufacturing of the DNA anti-counterfeiting fiber of the second figure The method of historical quality 1 flow rate ratio φ=2.0, the formation photography of DNA anti-counterfeiting fiber ; ⑷ FIG manufacturing method of the third of the second FIG. Deoxy ribozyme nucleic security fibers in the 'square mass flow ratio > = G.5 when' deoxyribonucleic acid security fibers forming photographic FIG. In the third figure (8), the third figure (b) and the third figure (4), by adjusting the flow rate of the two acid hydrolysis waters 42, 43 on the upper and lower sides in the case of stable outlet and total flow rate , will control the width of the forming filaments. That is, the adjusted mass flow rate ratio φ is from Φ = 2.0 to (4). 5, and the formed filament size diameter will correspond to from ΙΟΟμιη to 25μηι. Next, the velocity distribution of the flow field in the mixing flow path 34 will be described. Please refer to the fourth figure (a), the fourth figure) and the fourth figure (c). The fourth figure (a) is the mass flow rate ratio, and the DNA anti-counterfeiting fiber is measured by the microparticle speedometer system. The Reynolds number Re change diagram of the flow field in the flow channel; the fourth figure (14 1310414 Berry flow rate ratio φ=2.0, the deoxygenation measured by the microparticle speedometer system, the sugar nucleic acid anti-counterfeiting fiber mixed into the flow field in the flow channel The Reynolds number Re change diagram; The second figure (e) shows the Reynolds number Re of the flow field in the mixed flow of the anti-counterfeit DNA of the sputum by the microparticle velocity measuring system when the mass flow rate ratio is φ=(). In the fourth figure (a), the fourth figure (b) and the fourth figure (c), the acid solution water 42 and 43 in the region of the flow path 34 of the spinneret 8 are simultaneously added to the reaction with the polymer solution 41. The acid hydrolysis water 42 and 43 occupy most of the area, and because of the pinching of the acid hydrolysis water, the flow range of the polymer solution 41 is forced to decrease and flow at a high speed, so the internal flow of the polymer solution 41 and the two acid hydrolysis water 42 43 The external stream will have a great speed difference in the part close to the interface, but in a very short time After the flow distance, the difference in flow velocity between the inner and outer flow fields will be rapidly coupled to form a single typical parabolic full expansion flow. In each of the fourth (a), fourth (b) and fourth (c) There are three curves in the middle, which represent the flow field velocity of the cross section of the flow channel in the flow direction Υ-75μιη, γ=13〇μιη, and γ=25〇μιη after the contact between the internal and external fluids. Wherein, χ is the distance from the flow field position to the wall of the spinneret 80 mixed into the flow channel 34. The Reynolds number Re of the dimensionless velocity is Re=pVL/v, P is the fluid density, v is the dynamic viscosity, and L is the inflow. The distance from the center of the field to the spinneret 8 is mixed into the wall of the flow channel 34. It can be seen from the figure that the greater the difference in mass flow rate between the inner and outer fluids, the external fluid will force the internal fluid to flow at a higher speed, so that the fiber size is also shaped. The smaller the size, but the faster the molding speed will cause the number of DNA microcapsules to become less in a finite length. Therefore, from the speed measurement results, the maximum non-integration of the fully expanded flow is obtained at φ=1〇. The secondary speed Re is about 3.5, which is converted into the average flow speed. The degree is 25 (^m / sec; and the filament diameter is about 50 μιη, if the one-inch long nylon 6 body 15 1310414 product is about 0.02 cc, the concentration of the filament in the deoxyribonucleic acid microcapsule is 1000 ppm (g / CC) In the case, 'there will be a content of 0.02 mg; in this case, '100 filaments can be sampled', which is sufficient for subsequent polymerization analysis. The characteristic of this case is: a spinning spline for making synthetic fibers. The nozzle comprises: a polymer solution inlet passage for supplying a polymer solution for manufacturing a synthetic fiber; and a pair of water supply inlet passages on both sides of the polymer solution inlet passage for supplying two acid hydrolysis water; The polymer solution inlet channel and the pair of water supply
流道匯合為一混成流道，並在混成流道出口產生合成纖 維。使用上述的噴絲嘴以製造去氧核醣核酸防偽纖維的方 法如下：首先，製備一聚合物溶液，聚合物溶液包括複數 個去氧核難酸微膠囊；接著，驅動聚合物紐，並驅動 兩股酸_水騎聚合物雜_;絲，匯合該流動的 聚合物溶液與該等義的兩麟解用水，產生—去氧核畴 核酸防偽纖維。 ‘上所述’本案之去氧嫌㈣防偽纖維與其製造用 、、、絲嘴及方法確實能制發明構想所設定的功效。唯， =所=者僅為本案讀佳實施例，舉凡熟悉本案技藝之 於:下作之等效修飾齡 ，俾得更深入之瞭 •本案得藉由下列圖式之詳細說明 解： 【圖式簡單說明】 16 1310414 =了圖：本案所提出之製造合成纖維的喷絲嘴的流道示意 H)， 第二圖：本案所提出之製造去氧核醣核酸防偽纖維的方法 之-較佳實施例巾，聚合齡液在噴絲嘴巾細絲化並酸解 的攝影圖； 第二圖（a):其為第二圖之製造去氧核醣核 方法中，質量流率ttw.〇時，钱核賴酸的 成形攝影圖； 第一圖(b).其為第二圖之製造去氧核醣核酸防偽纖維的 方法中，質1流率比Φ=2·〇時，去氣核醣核酸防偽纖維的 成形攝影圖； 第二圖(c):其為第二圖之製造去氧核醣核酸防偽纖維方 法中’質量流率比φ=〇 5時’去氧核醣核酸防偽纖維的成 形攝影圖； 第四圖(a):其為質量流率比φΗ.Ο時’以微粒子測速儀系 統測量得之去氧核醣核酸防偽纖維混成流道内流場的雷諾 數Re變化圖； 第四圖(b):其為質量流率比φ^2.〇時’以微粒子測速儀系 統測量得之去氧核酶核酸防偽孅維混成流道内流場的雷諾 數Re變化圖；及 第四圖(c):其為質量流率比φ<0.5時’以微粒子測速儀系 統測量得之去氧核黯核酸防偽殲維混成流道内流場的雷諸 數Re變化圖。 【主要元件符號說明】 17 1310414 80 :噴絲嘴 31 :聚合物溶液進流道 32、33 :供水進流道 34 :混成流道 41 :聚合物溶液 42、43 :酸解用水The flow channels merge into a mixed flow path and produce synthetic fibers at the mixed flow path exit. The method of using the above-mentioned spinneret to manufacture a DNA anti-counterfeit fiber is as follows: First, a polymer solution is prepared, the polymer solution includes a plurality of deoxyribonucleolytic acid microcapsules; then, the polymer is driven, and the two are driven The acid-water riding polymer _; silk, converging the flowing polymer solution and the equivalent of two lining water, producing - deoxyribonucleic acid anti-counterfeiting fibers. The above-mentioned deoxygenation (4) anti-counterfeiting fiber and its manufacturing, wire-mouth and method can indeed produce the effects set by the invention. Only, ========================================================================================================== Brief description of the formula] 16 1310414 = Fig.: The flow path of the spinneret for manufacturing synthetic fibers proposed in the present invention is H), and the second figure: the method for producing DNA anti-counterfeiting fibers proposed in the present invention - preferred implementation A photograph of a film of a polymerized age in a spinneret filamentized and acid-decomposed; Figure 2 (a): in the method of producing a deoxyribose core in the second figure, when the mass flow rate is ttw. The photogram of the nucleoside acid; the first figure (b). In the method of manufacturing the DNA anti-counterfeiting fiber of the second figure, when the mass 1 flow rate ratio Φ=2·〇, the degassing RNA anti-counterfeiting Forming photograph of the fiber; Fig. 2(c): FIG. 2 is a photographing diagram of the DNA anti-counterfeiting fiber of the 'mass flow rate ratio φ=〇5' in the method for producing the DNA anti-counterfeit fiber of the second figure; Figure 4 (a): It is measured by the particle velocity meter system when the mass flow rate ratio is φΗ.Ο The Reynolds number Re of the flow field in the mixed flow of the anti-counterfeiting fiber of the ribonucleic acid; the fourth figure (b): the mass flow rate ratio φ^2.〇's the deoxyribozyme nucleic acid measured by the microparticle speedometer system The Reynolds number Re change diagram of the flow field in the anti-counterfeiting and entangled flow channel; and the fourth figure (c): the mass flow rate ratio φ <0.5 when the DNA deceleration system is used to measure the deoxyribonucleic acid anti-counterfeiting The number of Re changes in the flow field in the mixed flow channel. [Explanation of main component symbols] 17 1310414 80 : Spinneret 31 : Polymer solution inlet 32 , 33 : Water supply inlet 34 : Mixed flow path 41 : Polymer solution 42 , 43 : Water for acid hydrolysis
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