TWI222990B - Dye set and ink composition with high water-fastness and ink-jet printing method thereof - Google Patents
Dye set and ink composition with high water-fastness and ink-jet printing method thereof Download PDFInfo
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- TWI222990B TWI222990B TW090117200A TW90117200A TWI222990B TW I222990 B TWI222990 B TW I222990B TW 090117200 A TW090117200 A TW 090117200A TW 90117200 A TW90117200 A TW 90117200A TW I222990 B TWI222990 B TW I222990B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/40—Ink-sets specially adapted for multi-colour inkjet printing
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- Wood Science & Technology (AREA)
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- Inks, Pencil-Leads, Or Crayons (AREA)
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Abstract
Description
1222990 五、發明說明（l) 【發明領域】 本發明係有關於一種具高度防水性的多色染料組合、 含有此組合色料之墨水組成物，以及其在喷墨列印之應 用。 【發明背景】 一般來說，對於彩色喷墨列印的要求，必需具有寬廣 的色彩範圍和理想的混合配色，像是藍色或紅色。洋藍^ 墨水（cyan ink)，洋紅色墨水（magenta ink)，黃色墨水 (yellow ink)和黑色墨水（black ink)，這樣的組合稱為 第一級染料組合色料（primary dye-set)。第二級染料系且 合（secondary dye - set)是指不包含第一級染料組合色 料，卻經由第一級染料組合色料的混合配色而成的其他顏 色。 夕 事實上，對於彩色喷墨列印而言，一個成功的墨水組 合需付合下面幾點要求：耐磨（good crusting resistance)，穩定（good stability)，獨特的黏度 (proper viscosity)，獨特的表面張力（pr〇per surface tension)，高色彩飽和度（high color saturation)，低 暈開性（little color-to-color bleed)，短的乾燥時間 (rapid dry time)等。而且當使用在喷墨列表機時'，^0會 造成凝聚（kogation)，及喷墨於載體時，像是在一般紙^ (plain paper)上時，可如同在其他喷墨特殊用紙一&樣，、 成功地喷墨。 ’ 色彩的表示方法依實際色物體的蒐集與否分為兩大表 0535-6474TWF;A90057;esmond.ptd 第6頁 1222990 五、發明說明（2) appearance system):主要 色糸統’一為顯色系統（c 〇 1 0 r 是依據實際色物體的蒐集給予有系統的排列及描述而得之 系統，例如Ostwald表色系統，Munsel 1表色系統，德國 D I N表色糸統專。另一為混色系統（c 〇 1 〇 r m i X i n g system) ··不是基於實際色物體所歸納的系統，而是基於三 原色光能混合出許多色彩所歸納的系統，到目前為止最重‘ 要的混色系統是以儀器測量色彩的C丨E系統。舉例來說， Munsel 1表色系統是由美國晝家Munsei 1所創製，是利用三 屬性--色相（hue)，明度（vaiue)，彩度（chr〇roa)—來描寫 色彩之最有名之系統。CIE系統的色刺激（為X，γ，z三刺 激質）與色彩的感覺是由光源，物體，觀測者三要素合併 所造成的，其色域是利用L*，a*，b*此三值來定義，L*表 示色彩的焭度（1丨2111；11633 of a color)，a*和b*則代表色 彩的色相（hue)和彩度（chroma )。a*的範圍從表示綠色的 -a到表示紅色的+ a，b*的範圍則是從表示藍色的—b到表示 黃色的+ b。CIE系統並且於1 976年的推薦中加入了色相<角7^ 度和彩度（hue angle，hO ; chroma，C*)(方程式1 與2 )。在CIELAB的色域中，色差（△£)是指在兩個色樣之間 的顏色差別度（方程式3 )。ΛΕ差越多，表示兩色樣間^ 色差異度越大。而0D(0ptical density)代表光學密度， 照射某物後穿透之強度為I 度（方程式4)。 也可稱為吸光度（absorbancy)其定義為一強度為丨 則l〇g( 1。/1)之值稱為光學密 方程式1 h° = tan-1 ( b* / a*) 12229901222990 V. Description of the Invention (l) [Field of the Invention] The present invention relates to a highly waterproof multi-color dye combination, an ink composition containing the combination colorant, and its application in inkjet printing. [Background of the Invention] Generally, for the requirements of color inkjet printing, it is necessary to have a wide color range and an ideal mixed color, such as blue or red. The combination of cyan ink, magenta ink, yellow ink and black ink is called the primary dye-set. Secondary dye-set refers to other colors that do not contain the first-stage dye combination color, but are mixed and matched by the first-stage dye combination color. In fact, for color inkjet printing, a successful ink combination must meet the following requirements: good crusting resistance, good stability, unique viscosity, unique Surface tension (prOper surface tension), high color saturation (high color saturation), low halo openness (little color-to-color bleed), short dry time (rapid dry time), etc. In addition, when used in an inkjet printer, ^ 0 will cause kogation, and when inkjet on a carrier, such as on plain paper, it can be used as other inkjet special papers. ; Like, successfully inkjet. '' The color representation method is divided into two tables based on the collection of actual colored objects: 0535-6474TWF; A90057; esmond.ptd Page 6 1222990 V. Description of the invention (2) Appearance system): The main color system is displayed. The color system (c 0 1 0 r is a system based on the actual arrangement and description of the collection of color objects, such as the Ostwald color system, the Munsel 1 color system, and the German DIN color system. The other is Color mixing system (c 〇 〇 rmi X ing system) ·· It is not a system based on the actual color objects, but a system based on the three primary colors of light energy to mix many colors. The most important color mixing system so far is The C 丨 E system for measuring color with an instrument. For example, the Munsel 1 color system was created by the American day house Munsei 1. It uses three attributes-hue, lightness, and chroma (chr〇). roa) —the most famous system to describe color. The color stimulus (X, γ, and z stimuli) of CIE system and the feeling of color are caused by the combination of light source, object and observer. Is using L *, a *, b * is defined by these three values, L * represents the degree of color (1 丨 2111; 11633 of a color), a * and b * represent the hue and chroma of the color. The range of a * The range from -a for green to + a for red, and b * ranges from -b for blue to + b for yellow. The CIE system added Hue < Angle 7 in the 1976 recommendation ^ Degree and chroma (hue angle, hO; chroma, C *) (equations 1 and 2). In the color gamut of CIELAB, the color difference (△ £) refers to the degree of color difference between two color samples (the equation 3). The greater the ΔΕ difference, the greater the difference in color between the two color samples. 0D (0ptical density) represents the optical density, and the intensity of penetration after irradiating something is 1 degree (equation 4). It can also be called Absorbance is defined as an intensity with a value of 10 g (1.1 / 1) called the optical density equation 1 h ° = tan-1 (b * / a *) 1222990
C* = ( a*2 + b*2 )1/2 ΔΕ = (AL*2 + Aa*2 + Ah,2 v/2 式2 nn , 十 ΔΙ)*2 )1/2 方程式 3 0D = i〇g(i0/i) 方。 而在本發明；=::料和高 古π 4 Q ^ 口丨王巳枓其防水性的實驗，主要是以 個^ L ΔΕ值的大小來判定其防水性的優越與否，一 =^好的墨水組合，在經由防水性否 水性質越佳。 Ρ顏色退色的程度越少’也表示防 【先前技藝】 才於喷墨列印而言，一般所知，乡墨水中僅使用單一 色，，常易造成噴墨口的阻塞（plugging)，所以通常會添 加夕種保濕劑，但卻容易造成乾燥速度緩慢，且抗水性 差。例如 1 986 年，U.S· Pat· No· 4,631，085，1 987 年， 1^.?^^4,713，113，1 988 年，1].3.?&1：.1^〇· 4，7 3 7，1 9 0 ’其墨水都是單一色料必須在添加保溼劑以防 止凝集。1999 年 ’U.S· Pat· No· 5, 925, 177 中，一種特 別的墨水組成物’包括酸性黃色染料23 (acidic yeU〇w 23)，尿素（urea)，水。添加尿素可以防止黃色染料發生 結晶而阻塞喷墨頭的問題。 對於彩色喷墨列印機而言，通常包括了洋紅色墨水 (magenta ink) ’洋藍色墨水（cyan ink)，黃色墨水 (yellow ink)和黑色墨水（black ink)，共四色墨水，其C * = (a * 2 + b * 2) 1/2 ΔΕ = (AL * 2 + Aa * 2 + Ah, 2 v / 2 formula 2 nn, ten ΔΙ) * 2) 1/2 equation 3 0D = i 〇g (i0 / i) square. In the present invention; = :: material and high ancient π 4 Q ^ 口 Wang Wang's water resistance test, mainly based on the size of the value of ^ L ΔΕ to determine whether the water resistance is superior or not, one = ^ good The ink combination has better water resistance and water resistance. The less the degree of fading of the P color, it also means that [previous technique] is only for inkjet printing. It is generally known that only a single color is used in rural ink, which often causes plugging of the inkjet port. Evening humectants are usually added, but it is easy to cause slow drying and poor water resistance. For example, 1986, US Pat No 4,631,085, 1987, 1 ^.? ^^ 4,713,113, 1988, 1] .3.? &Amp; 1: .1 ^ 〇 · 4, 7 3 7, 19 0 'The ink is a single colorant and a moisturizer must be added to prevent aggregation. In 1999, 'U.S. Pat. No. 5, 925, 177, a special ink composition' includes acidic yellow dye 23 (acidic yeUow 23), urea, and water. Adding urea can prevent the yellow dye from crystallizing and blocking the inkjet head. For color inkjet printers, it usually includes magenta ink, magenta ink, cyan ink, yellow ink, and black ink.
0535-6474TWF;A90057;esmond.p t d 第 8 頁 1222990 五、發明說明（4) 中大多使用水溶性的色料（water —base dye)為主。最近幾 年則有洋紅色墨水（magenta ink)，洋藍色墨水（Cyan ink)，黃色墨水（yel low ink)，黑色墨水（black ink)， 淺洋紅墨水（light magenta ink)和淺洋藍墨水（nght cyan ink)，共六色墨水，或再加上淺黃色墨水 yell〇W ink) ’形成共七色墨水。這些墨水，其組成包括 二種=上之水溶性的染料，水，有機溶劑，及其他添加 性及：L生溶性的染料…在列印後影像的防水 墨水所Ξ包量開發防水性及抗光性佳之顏料 添加物。㈣顏料為色^顏：，水’有機溶劑’及其他 抗光性上，比水溶性的毕：：墨’在影像的防水性及 的防水性及抗光性，作，枓墨水優異。顏料雖然擁有較佳 (dispersant)與附著劑，卩$須配合適當的分散劑 (particle size)，故尹 加上顏料具有較大的顆粒尺寸 頭，降低列印品質。易發生沉澱與凝集，而阻塞喷墨 【發明概述】 本發明的目的之— 色料（dye set)，盆呈亡疋提供一種水溶性多色染料組合 本發明的目的、之、二有:曰度的防水性。 合色料的墨水組成物。〃疋提供一種含有上述多色染料組 就是提供一種使用上述墨水組成物 本發明的目的之 之噴墨列印方法。0535-6474TWF; A90057; esmond.p t d page 8 1222990 V. Description of the invention (4) Most of the water-base dyes are used. In recent years, there are magenta ink, Cyan ink, yellow ink, black ink, light magenta ink and light magenta ink. (Nght cyan ink), a total of six colors of ink, or light yellow ink (yell〇W ink) 'to form a total of seven colors of ink. The composition of these inks includes two kinds of water-soluble dyes, water, organic solvents, and other additives and: L-soluble dyes ... Developed water resistance and resistance against the amount of waterproof ink in printed images Glossy pigment additive. The pigment is color, pigment, water, organic solvent, and other light resistance, which is more water-soluble than that of water-soluble: ink, which is excellent in water resistance, water resistance, and light resistance of the image. Although the pigment has a better dispersant and adhesion agent, it must be matched with an appropriate dispersant (particle size), so Yin plus the pigment has a larger particle size head, which reduces the print quality. Precipitation and agglutination are easy to occur, and inkjet is blocked. [Summary of the Invention] The purpose of the present invention is a dye set. A water-soluble multi-color dye combination is provided. The object of the present invention is as follows: Degree of water resistance. A color ink composition. (Ii) To provide an inkjet printing method containing the above-mentioned multicolor dye set is to provide the above-mentioned ink composition, which is an object of the present invention.
1222990 五、發明說明（5) 本發明的目的之四就是提供一種新穎的水溶性洋紅色 染料組合色料，以及含有此組合色料之墨水組成物。 本發明的目的之五就是提供一種新穎的水溶性黃色染 料組合色料，以及含有此組合色料之墨水組成物。 為達上述目的’本發明提供一種具高度防水性之水溶 性多色染料組合色料（d y e s e t)，包括： (a) 水溶性洋藍色染料組合色料，包含··直接性藍色 染料199 (directive blue 199)，酸性藍色染料9 (acidic blue 9)； (b) 水溶性洋紅色染料組合色料，包含：反應性紅色 染料 180 (reactive red 180)，酸性紅色染料52 (acidic red 52) ’直接性紅色染料75 (directive red 75);以及 (c) 水溶性黃色染料組合色料，包含：直接性黃色染 料 132 (directive yellow 132)，酸性黃色染料5 (acidic yellow 5) 0 在上述成分中，成分（a)所使用之直接性藍色染料199 (directive blue 199)與酸性藍色染料 9 (acidic blue 9)，為習知技術中常用來作為藍色染料之組合色料。而成 分（b)與成分（c)所使用之洋紅色與黃色組合色料則為本發 明首創。 本發明成分之（a )洋藍色染料組合色料中，使用德國 科萊恩公司所出品之直接性藍色染料199 (directive blue 199)及酸性藍色染料9 (acidic blue 9)。 在本發明成分（b)洋紅色染料組合色料中，使用德國1222990 V. Description of the invention (5) The fourth object of the present invention is to provide a novel water-soluble magenta dye combination colorant and an ink composition containing the combination colorant. A fifth object of the present invention is to provide a novel water-soluble yellow dye combination colorant and an ink composition containing the combination colorant. In order to achieve the above objective, the present invention provides a highly water-resistant, water-soluble, multi-color dye combination colorant (dyeset), including: (a) a water-soluble magenta dye combination colorant, including a direct blue dye 199 (directive blue 199), acidic blue dye 9 (acidic blue 9); (b) water-soluble magenta dye combination colorant, including: reactive red dye 180 (reactive red 180), acid red dye 52 (acidic red 52 ) 'Directive red dye 75 (directive red 75); and (c) water-soluble yellow dye combination colorants, including: direct yellow dye 132 (directive yellow 132), acid yellow dye 5 (acidic yellow 5) 0 above Among the components, the direct blue dye 199 (direct blue 199) and the acidic blue dye 9 used in the component (a) are commonly used in the conventional technology as a combination of blue dyes. The magenta and yellow colorants used in component (b) and component (c) are the first of this invention. In the (a) magenta dye combination colorant of the present invention, the direct blue dye 199 (acid blue 199) and the acidic blue dye 9 (acidic blue 9) produced by Clariant, Germany are used. In the component (b) magenta dye combination colorant of the present invention, Germany is used
0535-6474TWF;A90057;esmond.ptd 第10頁 ί2^299〇 五、發明說明（6) #耳公司所出品之之反應性紅色染料180 (reactive red U 〇 )及直接性紅色染料7 5 ( d i r e c t i v e r e d 7 5 )。酸性紅 色染料52 (acidic red 52)為德國科萊恩公司所出品。 I發明之範圍尚包括含有此洋紅色染料組合色料之墨水組 成物。 在本發明成分（c)黃色染料組合色料中，所使用之直 接性黃色染料132 (directive yellow 132)為德國拜耳 A司所出品。酸性黃色染料5 ( a c i d i c y e 1 1 〇 w 5 )來自德 國BASF公司。本發明之範圍尚包括含有此黃色染料組合色 料之墨水組成物。 本發明之墨水組成物係包含上述之多色染料組合色料 與一水溶液媒介物。本發明之噴墨列印方法，包括提供本 發明之墨水於一噴墨列印裝置；以及噴出此墨水於一記 戴體上。 本案所提供墨水組成物，使用在熱汽泡式喷墨列印 機，不但改善了熱穩定性，儲存性，且有獨特的黏度和表 、張力，更疋具有高度防水性，此尚品質的色彩影像，對 於在各種色系，皆表現適宜，可大大提升列印品質。 在本發明的墨水組成物中，上述各個染料的添加量均 %、為0 · 1 1 〇重i % (以墨水總重量為基準），較佳為2〜5重量 本發明的墨水組成物中包含一水溶液媒介物。此水、、六 性=介物除了水之外，尚可包含一水溶性或與水互溶之= 機溶劑，例如環己烷（cycl〇heXane)，甲醇Uethan〇i)，0535-6474TWF; A90057; esmond.ptd Page 10 ί 2 ^ 299〇 V. Description of the invention (6) #Reactive red dye 180 (reactive red U 〇) and direct red dye 7 5 (directivered 7 5). Acid red 52 is produced by Clariant, Germany. The scope of the invention also includes an ink composition containing the magenta dye combination colorant. In the yellow dye combination colorant of the component (c) of the present invention, the direct yellow dye 132 (direct yellow 132) used is produced by Bayer A, Germany. The acid yellow dye 5 (acid, dcy, y e 1 1 0 w 5) is from BASF, Germany. The scope of the present invention also includes an ink composition containing the yellow dye combination colorant. The ink composition of the present invention comprises the above-mentioned multi-color dye combination colorant and an aqueous vehicle. The inkjet printing method of the present invention includes providing the ink of the present invention on an inkjet printing device; and ejecting the ink on a recording body. The ink composition provided in this case is used in a thermal bubble inkjet printer, which not only improves thermal stability and storage properties, but also has unique viscosity, surface and tension, and is highly waterproof. Color images are suitable for various color systems and can greatly improve print quality. In the ink composition of the present invention, each of the above-mentioned dyes is added in an amount of 0.1% by weight (based on the total weight of the ink) of 0.1% by weight, and preferably 2 to 5 weight of the ink composition of the present invention. Contains an aqueous vehicle. In addition to water, the water, hexahydrate = mediator may also contain a water-soluble or water-miscible = organic solvent, such as cyclohexane (cycloheXane, methanol Uethan〇i),
0535.6474TW;A90057;esmond.ptd 1222990 五、發明說明（7) 乙醇（e t h a η ο 1 ) ’ 乙二醇（e t h y 1 e n e g 1 y c ο 1)，二乙二醇 (diethylene glycol)，三乙二醇（triethylene glycol) ’ 聚乙二醇（p〇iyethyiene glycol)，丙二醇 (propylene glycol)，丁二醇（butylenes glycol)，戊二 醇（pentylene glycol)或己二醇（hexylene glycol)或多 元醇等等。 本發明的墨水組成物可更包含一界面活性劑。界面活 性劑的主要功能在於降低溶液之墨水表面張力，進而可以 提升墨水保濕的功能，使供墨及喷墨順利，同時也兼具分 散劑的功能，一般實用上，如分散性染料本身容易造成色 料的結晶或凝集的現象，而阻塞墨水匣喷嘴，所以需要加 強分散劑之濕潤作用，來提高添加物在墨水中的分散能 力，通常在一般墨水配方中會添加一種以上的界面活性 劑，包含陰離子型式、陽離子型式、非離子型式，或兩性 之界面活性劑。其總添加量範圍在2 〇 · 〇重量％以下。其所 添加的界面活性劑’例如是聚乙二醇（p 〇 1 y e t h a n d i ο 1 )， 聚丙二醇（p〇lypropandiol)，環氧乙烷/環氧丙烷共聚合 物（Ε0/Ρ0 copolymer)，二辛基硫基琥珀酯化鈉（sodiunl dioctyl sulfosuccinate) ’ 聚丁基樹脂（p〇iybutyl resin) ’ 纖維素衍生物（cellulose derivative)，苯乙烯 / 丙烯之共聚合樹脂（styrene/acrylic copolymer resin) ’順丁稀/本乙稀之共聚合物（maieic acid/ styrene copolymer)或一種同時含有親水性官能基 (hydrophilic segment)與親油性官能基（hydr〇ph〇bic0535.6474TW; A90057; esmond.ptd 1222990 V. Description of the invention (7) Ethanol (etha η ο 1) 'Ethylene glycol (ethy 1 eneg 1 yc ο 1), diethylene glycol, triethylene glycol (Triethylene glycol) 'polyethylene glycol (propylene), propylene glycol, butylenes glycol, pentylene glycol or hexylene glycol or polyols, etc. . The ink composition of the present invention may further include a surfactant. The main function of the surfactant is to reduce the ink surface tension of the solution, which can improve the moisturizing function of the ink, make the ink supply and inkjet smooth, and also have the function of a dispersant. In general, such as the disperse dye itself is easy to cause The phenomenon of crystallization or agglutination of the pigment, and blocking the ink cartridge nozzle, so we need to strengthen the wetting effect of the dispersant to improve the dispersion ability of the additive in the ink. Generally, more than one surfactant is added to the general ink formula. Contains anionic, cationic, non-ionic, or amphoteric surfactants. The total amount of addition is in the range of 2% by weight or less. The surfactants added thereto are, for example, polyethylene glycol (p 〇1 yethandi ο 1), polypropylene glycol (polipropandiol), ethylene oxide / propylene oxide copolymer (E0 / PO copolymer), two Sodiunl dioctyl sulfosuccinate '' polybutyl resin '' cellulose derivative, styrene / acrylic copolymer resin (styrene / acrylic copolymer resin) '' A cis-butadiene / ethylene copolymer (maieic acid / styrene copolymer) or a type containing both a hydrophilic functional group (hydrophilic segment) and a lipophilic functional group (hydrophophic)
0535-6474TWF;A90057;e smond.p t d 第12頁 1222990 五、發明說明（9) acetate) ’ 二乙三胺醋酸鈉（diethylenetriamino pentasodium acetate)和尿咪醋酸鈉（uramil di sodiura acetate) ° 此外’在本發明之墨水配方中，可更加入抗紫外線試 劑（UV-blocker)，以阻擋叮光之吸收進而增進色料的抗光 性；添加殺菌劑（b i 〇c i de )、防腐劑等，以抑制細菌在墨 水中滋長；添加分散劑（Dispersant)，增加添加物在黑水 中的分散能力。 & 為讓本發明之上述和其他目的、特徵、和優點能更明 顯易懂’下文特舉出較佳實施例，並配合所附圖式，作詳 細說明如下： ° 【圖式之簡單說明】 圖一 ’係為本案所提供實施例之三色墨水之染料組合 色料’將其噴墨於一般噴墨列印紙之色域圖。 圖二’係為本案所提供比較例之三色墨水之染料組合 色料’將其喷墨於一般喷墨列印紙之色域圖。 ，圖三’係為本案所提供之實施例的三色墨水染料組合 ^料，將其噴墨於一般紙張，經置入水中3 0分鐘後之色域 、、圖四，係為本案所提供之比較例的三色墨水染料組人 色料，將其喷墨於一般紙張，經置入水中3 0分鐘後之色域 圖。 & 、圖五，係為本案所提供實施例與比較例之三色黑太仇 料組合色料的防水性測試後之色域比對圖（外圍曲線代表^0535-6474TWF; A90057; e smond.ptd Page 12 1222990 V. Description of the invention (9) acetate) 'Diethylenetriamino pentasodium acetate and uramil di sodiura acetate ° Also' in In the ink formulation of the present invention, a UV-blocker can be further added to block the absorption of sting light and thereby improve the light resistance of the colorant; a biocide and a preservative can be added to suppress Bacteria grow in the ink; Dispersant is added to increase the dispersion ability of the additive in black water. & In order to make the above and other objects, features, and advantages of the present invention more comprehensible, hereinafter, the preferred embodiments are described in detail with the accompanying drawings as follows: ° [Simplified description of the drawings FIG. 1 is a color gamut diagram of inkjet printing on a general inkjet printing paper of a dye combination colorant of a three-color ink according to the embodiment provided by the present application. Fig. 2 'is a color gamut diagram of the dye combination of the three-color ink of the comparative example provided by the present application, which is ink-jetted onto a general ink-jet printing paper. Figure 3 'is the three-color ink dye combination material of the embodiment provided in the present case. The color gamut after ink-jetting it into general paper after 30 minutes in water, Figure 4 is provided by the case. The color gamut diagram of the comparative example of the three-color ink dye group human colorant, which was ink-jetted onto ordinary paper and placed in water for 30 minutes. & Figure 5 is the color gamut comparison chart of the three-color black phoenix material combination colorants in the examples and comparative examples provided by the present case after the water resistance test (the outer curve represents ^
1222990 五、發明說明（10) 置於水中3 0分鐘後實施例之墨水組成物，内部曲線代表置 於水中3 0分鐘後比較例之墨水組成物）。 【實施例】 本案所提供之組合色料之三色墨水組成物，包含了 (a) 3重量％直接性藍色染料199 (directive blue 199) 2重量％酸性藍色染料9 (acidic blue 9) 4·0 重量％的卩丑6 700(p〇lyethylene glycol 700)(來自 U· C· C·) 4· 0 重量％ 的2 -咯烷酮（2-pyrrol idone)(來自 DOW) 4· 0重量％的2-乙基-2-（羥甲基）-1，3_丙二醇 (EHMPD ，來自Lancast er) 2· 0重量％的界面活性劑13-S-5(來自中日合成） 2· 0重量％的界面活性劑13-S-7(來自中曰合成） 3· 0重量％的界面活性劑〇τ-75(來自KY0WA) 〇· 5重量％的界面活性劑465(來自air producet) 2·5 重量％ 的1， 4- 丁二醇（來自Lancaster) 〇· 5重量％的殺菌劑SL-70 0 (來自KY0WA) 去離子水 (b) 2重量％反應性紅色染料18〇 (reactive red 180) (來自拜耳）， 15重量％酸性紅色染料52(acidic red 52)(來 自科萊恩），1222990 V. Description of the invention (10) The ink composition of the example after 30 minutes in water, the internal curve represents the ink composition of the comparative example after 30 minutes in water). [Example] The three-color ink composition of the combined colorant provided in this case contains (a) 3% by weight of direct blue dye 199 (directive blue 199) 2% by weight of acidic blue dye 9 (acidic blue 9) 4.0% by weight 6700 (polyol glycol 700) (from U.C.C.) 4.0% by weight 2-pyrrolidone (from DOW) 4.0 Wt% 2-ethyl-2- (hydroxymethyl) -1,3-propanediol (EHMPD, from Lancaster) 2.0 wt% surfactant 13-S-5 (from Sino-Japanese Synthetic) 2 · 0% by weight of surfactant 13-S-7 (from Zhongyue Synthesis) 3.0% by weight of surfactant ττ-75 (from KY0WA) 5% by weight of surfactant 465 (from air producet) 2.5% by weight of 1,4-butanediol (from Lancaster) 0.5% by weight of fungicide SL-70 0 (from KY0WA) deionized water (b) 2% by weight reactive red dye 18〇 (reactive red 180) (from Bayer), 15% by weight acidic red 52 (from Clariant),
0535-6474TW;A90057；esm〇nd.ptd 1222990 五、發明說明（11) 1重量％直接性紅色染料75 (directive red 75) (來自拜耳） 4·0 重量％的？£6 700(polyethylene glycol 700) (來自 υ· c. c·) 4· 0 重量％ 的2 - 口各烧 _(2-pyrrolidone)(來自 DOW) 4.0重量％的2-乙基-2-（羥甲基）-1，3_丙二醇 (EHMPD ;來自Lancaster) 2· 0重量％的界面活性劑13-S-5(來自中日合成） 2· 0重量％的界面活性劑13-S-7(來自中曰合成） 3· 0重量％的界面活性劑〇T-75(來自KY0WA) 〇· 5重量％的界面活性劑465(來自air producet) 2·5 重量％ 的1，4 -丁二醇（來自Lancaster) 0· 5重量％的殺菌劑SL-700 (來自KY0WA) 去離子水 (c) 2· 5重量％直接性黃色染料132 (directive yellow 132)(來自拜耳）， 1重量％酸性黃色染料5 (acidic yellow 5)(來 自 BASF) 4·0 % 的PEG 700(polyethylene glycol 700)(來 自 U. C. C·) 4·0 % 的2~ 略烧酮（2-pyrrolidone)(來自 DOW) 4.0 %的2-乙基-2-（羥曱基）-1，3-丙二醇 (EHMPD ;來自Lancaster)0535-6474TW; A90057; esm〇nd.ptd 1222990 V. Description of the invention (11) 1% by weight direct red 75 (from Bayer) 4.0% by weight? £ 6 700 (polyethylene glycol 700) (from υ · c. C ·) 4 · 0% by weight of 2-mouth each burning _ (2-pyrrolidone) (from DOW) 4.0% by weight of 2-ethyl-2- ( Hydroxymethyl) -1,3-propanediol (EHMPD; from Lancaster) 2.0% by weight surfactant 13-S-5 (from Sino-Japanese synthesis) 2.0% by weight surfactant 13-S-7 (From Synthetic Synthesis) 3.0% by weight of surfactant 〇T-75 (from KY0WA) 0.5% by weight of surfactant 465 (from air producet) 2.5% by weight of 1,4-butane Alcohol (from Lancaster) 0.5% by weight of fungicide SL-700 (from KY0WA) Deionized water (c) 2.5% by weight Direct yellow 132 (from Bayer), 1% by weight acidic Acid yellow 5 (from BASF) 4.0% PEG 700 (polyethylene glycol 700) (from UC C ·) 4.0% 2 ~ 2-pyrrolidone (from DOW) 4.0 % 2-ethyl-2- (hydroxyfluorenyl) -1,3-propanediol (EHMPD; from Lancaster)
0535-6474TWF;A90057;esmond.ptd 第16頁 1222990 、發明說明（12) 五 0 %的界面活性劑1 3 - S - 5 (來自中曰合成） 0%的界面活性劑13-S-7(來自中日合成） 0 %的界面活性劑〇T-75(來自KY0WA) 5%的界面活性劑465(來自air producet) 5% 的1，4- 丁二醇（來自 Lancaster) 5%的殺菌劑SL-700(來自KY0WA) 去離子水 本案所使用之紙張為市售一般紙張（p丨a i n0535-6474TWF; A90057; esmond.ptd page 16 1222990, description of the invention (12) 50% surfactant 1 3-S-5 (from Chinese synthesis) 0% surfactant 13-S-7 ( Synthetic from China and Japan) 0% surfactant OT-75 (from KY0WA) 5% surfactant 465 (from air producet) 5% 1,4-butanediol (from Lancaster) 5% fungicide SL-700 (from KY0WA) Deionized water The paper used in this case is commercially available general paper (p 丨 ain
Paper) 〇 本案所使用之喷墨列印機為市售專用噴墨列印機。 本案所提供之三色墨水組合物，此染料組合喷墨列印 於一般紙張之色域顯示於圖一。測試防水性 Λ ^ 墨列印完成之全彩圖樣，測量其各個顏色之色：m 後，置入去離子水3〇分鐘，取出，於室溫下自：=負 :測量各個顏色之其色彩光學性質，&染料、组合色料之色 域顯示於圖二。 【比較例】 本案所提供對照實驗之組合色料之三色墨水組成物， 來自於市售愛普生（Epson)193彩色墨水£之黑水。 本案的對照實驗所使用之紙張為市售一^紙張ain paper) ° 本案的對照實驗所使用之噴墨列印機為一般市售喷墨 列印機。 'Paper) 〇 The inkjet printer used in this case is a commercially available inkjet printer. The color gamut of the three-color ink composition provided by this case for inkjet printing on general paper is shown in Figure 1. Test the water resistance Λ ^ Ink-printed full-color pattern, measure the color of each color: m, put in deionized water for 30 minutes, take it out, and at room temperature from: = negative: measure the color of each color Optical properties, & color gamuts of & dyes and combination colorants are shown in Figure 2. [Comparative example] The three-color ink composition of the combination coloring material provided in the control experiment in this case is from the black water of the commercially available Epson 193 color ink. The paper used in the control experiment in this case is a commercial paper (ain paper) ° The inkjet printer used in the control experiment in this case is a general commercially available inkjet printer. '
0535-6474TW;A90057;esmond.ptd 第17頁 1222990 五、發明說明（13) 本案所提供之三色墨水組合物，此染料組合 於一般紙張之色域顯示於圖三。測試防水性方法， 墨列印完成之全彩圖樣，測量复久^ #洛 ' ' 後，置入去離子水30分鐘，取出， =^九于往負 … 於至溫下自麸齡碌饴， 再測量其各個顏色之色彩光學性質，丸二 。 P舶-μ m 丨負，此乐枓組合色料之色 域顯不於圖四。 本案所提供之實施例與比較例 域比對圖顯示於圖五。 本案所提供之實施例與比較例 經防水性測試後之色 經防水性測試後之洋 色Uagenta)與黃色（yel low)之ΔΕ值比對顯示於表 △ Ε 註一：◎表示ΛΕ值界於3〇以下 〇表示ΔΕ值界於3〇 —5〇之間 △表示ΔΕ值界於50 -70之間 ^ X表示ΔΕ值界於7〇以上 吞主二：△ Ε值的大小可爽剌中甘 -個具防水性良好的墨水組合必J能優越與否’ 即顏色褪色的程度越少，其防水性質攻小的^ ’ 0535-6474TW; Α90057; esmond. ptd 第18頁 1222990 五、發明說明（14) 【發明之效果】 根據本發明案所提供之三色墨水組合色料，包括了 (1)直接性藍色染料199 (directive blue 199)，酸性藍 色染料9 (acidic blue 9)。（2)反應性紅色染料I80 (reactive red 180)，酸性紅色染料52 (acidic red 52)，直接性紅色染料75 (directive red 75)。（3)直接 性黃色染料132 (directive yellow 132)，酸性黃色染料 5 ( ac i d i c y e 1 1 〇w 5 )。將此染料組合色料應用在熱汽泡 式喷墨列印機，不但改善了熱穩定性，儲存性，且有獨特 的黏度和表面張力，更是具有高度防水性 (water-fastness)，尤其在洋紅色與黃色的抗水性表現 亡，效果更為明顯。此高品質的色彩影像，對於在各種色 系’皆表現適宜，可大大提升列印品質。 雖然本發明已以較佳實 限定本發明，任何熟習此技 和範圍内，當可作些許之更 範圍當視後附之申請專利範0535-6474TW; A90057; esmond.ptd Page 17 1222990 V. Description of the invention (13) The three-color ink composition provided in this case. The color gamut of this dye combination in general paper is shown in Figure 3. Test the water resistance method. After printing the full-color pattern printed with ink, measure the renewal ^ # 洛 '', put in deionized water for 30 minutes, and take it out. Then, measure the color optical properties of each color, Maru II. P-bo-μm 丨 negative, the color gamut of this Leo combination colorant is not as shown in Figure 4. A comparison chart of the examples and comparative examples provided in this case is shown in Figure 5. The colors of the examples and comparative examples provided in this case after the water resistance test are compared with the ΔΕ value of the orange color Uagenta) and yellow (yel low) after the water resistance test. Below 30, 〇 means that the ΔE value boundary is between 30 and 50, △ means that the ΔE value boundary is between 50 and 70, and X means that the ΔE value boundary is more than 70. Swallowing the main two: △ The value of E can be cool Zhong Gan-a combination of inks with good water resistance must be superior or not, that is, the less the color fades, the smaller the water resistance. ^ 0535-6474TW; Α90057; esmond. Ptd Page 18 1222990 V. Invention Explanation (14) [Effect of the invention] The three-color ink combination colorant provided according to the present invention includes (1) direct blue 199 and acidic blue 9 . (2) Reactive red dye I80 (reactive red 180), acidic red dye 52 (acidic red 52), and direct red dye 75 (directive red 75). (3) Direct yellow dye 132 (direct yellow 132), acid yellow dye 5 (ac i d i c y e 1 1 0w 5). This dye combination colorant is applied to thermal bubble inkjet printer, which not only improves the thermal stability and storage, but also has unique viscosity and surface tension. It is also highly water-fastness, especially In the magenta and yellow water resistance performance, the effect is more obvious. This high-quality color image is suitable for performance in various color systems, and can greatly improve print quality. Although the present invention has defined the invention with better practice, anyone familiar with this technology and scope can make a little more scope.
施例揭露如上，然其並非用以 藝者’在不脫離本發明之精神 動與潤飾，因此本發明 圍所界定者為準。 ” WThe embodiments are disclosed as above, but they are not intended to be used by artists' without departing from the spirit of the present invention. Therefore, those defined in the present invention shall prevail. "W
公告本· 申請曰 類別： ， ___ /Bulletin · Application Category:, ___ /
中文 發明專利說明書 具高度防水性的染料組合色料、其墨水組成物及 法 ^22990- 發明名稱 發明人 申請人 英文 姓名 (中文） 姓名(英文） 國籍 住、居所 姓名 (名稱） (中文） 姓名 (名稱）(英文） 國籍 住、居所 (事務所) 代表人 姓名 (中文） 代表人 姓名 (英文）Chinese invention patent specification Highly waterproof dye combination colorant, ink composition and method thereof ^ 22990- Name of invention Inventor applicant English name (Chinese) Name (English) Nationality residence, residence name (Name) (Chinese) Name (Name) (English) Nationality Residence, Residence (Office) Name of Representative (Chinese) Name of Representative (English)
喆 S?Sition with high water_fastness and ink-jet 呂椬境 佘怡璇 錢#欣 沈昱璋? S? Sition with high water_fastness and ink-jet 吕 椬 境 佘怡璇 钱 # 欣 沈 昱 璋
Yi-Jing Leu In-Shan Sir Chia-Hsin Chien Yu-Chang Shen 1 華民國2·中華民國3.中華民國4.中華民國 哲过市花園街56號9-6 $雄市三民區本和街153號4樓之2 ，園縣龍潭鄉佳安村忠孝路27-2號 安和路一段78巷2號6樓 明基電通股份有限公司 1·中華民國 桃園縣龜山鄉山鶯路157號 1·李焜耀Yi-Jing Leu In-Shan Sir Chia-Hsin Chien Yu-Chang Shen 1 Republic of China 2. Republic of China 3. Republic of China 4. 56 Garden Street, Zhe Guoshi, Republic of China 9-6 $ 153, Benhe Street, Sanmin District, Xiongshi No. 2 on the 4th floor, 6th Floor, No. 2, Lane 78, Section 1, Anhe Road, No. 27-2, Zhongxiao Road, Jia'an Village, Longtan Township, Yuanxian County1.
0535-6474TWF2;A90057;PATRICI.ptc 第1頁0535-6474TWF2; A90057; PATRICI.ptc Page 1
alkali metals)，像是氫氧化鐘（lithium hydroxide)， 氫氧化鈉（sodium hydroxide)和氫氧化鉀（potassium hydroxide)。銨類氫氧化物（ammonium hydroxide)，驗金 屬類碳酸化合物（carbonates of alkali metals)，碳酸 链（lithium carbonate)，碳酸納（sodium carbonate)和 石炭酸鉀（potassium carbonate) 〇alkali metals), such as lithium hydroxide, sodium hydroxide, and potassium hydroxide. Ammonium hydroxide, carbonates of alkali metals, lithium carbonate, sodium carbonate, and potassium carbonate
本發明的墨水組成物可更包含一螯合劑。螯合劑 (Chelation agent)的添加可以防止結晶鹽類的產生，避 免凝集顆粒而阻塞墨水匣之喷頭。適當的螯合劑包括有乙 二胺醋酸納（sodium ethylenediaminetetraacetate)，氰 三醋酸納（trisodium nitrilotriacetate)，經乙基乙二 胺醋酸納（hydroxyethyl ethy lened iamine trisodiumThe ink composition of the present invention may further include a chelating agent. The addition of a chelation agent can prevent the generation of crystalline salts and prevent the agglomerated particles from blocking the nozzles of the ink cartridge. Suitable chelating agents include sodium ethylenediaminetetraacetate, trisodium nitrilotriacetate, and hydroxyethyl ethy lened iamine trisodium
05 3 5-6474TWF3;A90057;PATRICIA.p t c 第13頁05 3 5-6474TWF3; A90057; PATRICIA.p t c page 13
Claims (1)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW090117200A TWI222990B (en) | 2001-07-13 | 2001-07-13 | Dye set and ink composition with high water-fastness and ink-jet printing method thereof |
| US10/177,457 US6669766B2 (en) | 2001-07-13 | 2002-06-20 | Dye set and ink composition with high water-fastness |
| DE10230358A DE10230358A1 (en) | 2001-07-13 | 2002-07-05 | Multicolor water-soluble dye composition giving ink jet printing with improved water-resistance contains blue component together with novel red and yellow components |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW090117200A TWI222990B (en) | 2001-07-13 | 2001-07-13 | Dye set and ink composition with high water-fastness and ink-jet printing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI222990B true TWI222990B (en) | 2004-11-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW090117200A TWI222990B (en) | 2001-07-13 | 2001-07-13 | Dye set and ink composition with high water-fastness and ink-jet printing method thereof |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US6669766B2 (en) |
| DE (1) | DE10230358A1 (en) |
| TW (1) | TWI222990B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006061333A2 (en) * | 2004-12-06 | 2006-06-15 | Ciba Specialty Chemicals Holding Inc. | Aqueous formulations of dye mixtures |
| US7387665B2 (en) * | 2006-04-12 | 2008-06-17 | E.I. Du Pont De Nemours And Company | Inkjet ink and ink set |
| KR20080088161A (en) * | 2007-03-29 | 2008-10-02 | 삼성전자주식회사 | Ink combination |
| JP6111774B2 (en) * | 2013-03-22 | 2017-04-12 | セイコーエプソン株式会社 | Ink jet ink, recording apparatus and recorded matter |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61101568A (en) | 1984-10-23 | 1986-05-20 | Ricoh Co Ltd | Water based ink |
| JPS61101572A (en) | 1984-10-23 | 1986-05-20 | Ricoh Co Ltd | Water based ink |
| JPS61101574A (en) | 1984-10-23 | 1986-05-20 | Ricoh Co Ltd | Water based ink |
| US5534051A (en) * | 1995-07-11 | 1996-07-09 | Hewlett-Packard Company | Specific dye set for thermal ink-jet printing |
| US5536306A (en) * | 1995-07-11 | 1996-07-16 | Hewlett-Packard Company | Thermal ink-jet inks having reduced black to color and color to color bleed |
| US5785743A (en) * | 1995-12-06 | 1998-07-28 | Hewlett-Packard Company | Bleed alleviation in ink-jet inks using organic acids |
| US5688311A (en) * | 1997-01-30 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Ink jet inks containing long chain alcohols |
| US6247808B1 (en) * | 1998-04-22 | 2001-06-19 | Hewlett-Packard Company | Ink-jet printing system for improved print quality |
| US5925177A (en) | 1998-05-01 | 1999-07-20 | Xerox Corporation | Yellow ink for ink jet printing |
| EP1160291B1 (en) * | 2000-05-30 | 2002-02-27 | ILFORD Imaging Switzerland GmbH | Azo dyes, their preparation and use thereof |
| JP2002294111A (en) * | 2001-03-29 | 2002-10-09 | Brother Ind Ltd | Water-base ink set for ink jet recording |
| US6511169B1 (en) * | 2001-08-01 | 2003-01-28 | Eastman Kodak Company | Ink jet printing method |
| US6685768B2 (en) * | 2001-08-01 | 2004-02-03 | Eastman Kodak Company | Ink jet ink set |
| US6511170B1 (en) * | 2001-08-01 | 2003-01-28 | Eastman Kodak Company | Ink jet printing method |
-
2001
- 2001-07-13 TW TW090117200A patent/TWI222990B/en not_active IP Right Cessation
-
2002
- 2002-06-20 US US10/177,457 patent/US6669766B2/en not_active Expired - Fee Related
- 2002-07-05 DE DE10230358A patent/DE10230358A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
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| DE10230358A1 (en) | 2003-01-23 |
| US20030019393A1 (en) | 2003-01-30 |
| US6669766B2 (en) | 2003-12-30 |
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