540185 五、發明說明（1) " " 1 — --- _ 且吸有關一種紙質電池及其製造方法，其係-備 末、石墨、甘、、由、』甲拉、水性黏合劑、鋅細 = 漿…氣化鋅、氯化胺、水性黏合劑：！ 墨電裝，將正負電浆分別塗覆於：;斤：=水；；正極油 供應者。 飞电池而月匕作各式微電 。，：：ί!前市面有許多的產品都是微電源需求的物 口口，例如音樂贺卡，其音樂賀 > 而ν的物 器發出立坐款 ’、 主要疋讓小小的音樂获蓉 时毛出曰柒耷，而音樂發聲器的功弔^耷 ，也不大，目前都是使用水銀電池 ς j需的電 定的重量與體積，增加贺卡的重旦而、日>奋々电池有_ 整體的美觀；除此，許多需微4二^也會影響到賀卡 的問題’而有待解決。 电"、的物品也.都是遇到相同 有鑑於習用微電源需求之物〇 輕質量之電池配合應用，產及具小體積、 人乃積極努力研究，：潛觀等缺 確-、戶'用功效之本發明。 、'、於研發出 本發明之主要目的，在於接 池之方法；兑俜呈借1 t以^ 種可以製備紙片式+ ^ 你具備具吸水性紙片，太、备Μ 乃式私 胺、水性黏合劑、鋅細 虱化鋅、氯化 醇等所調製成呈捏菸咏末 甘油、丙酮、甲醇、， 化胺、水性黏合劑、 1 Jc、虱化鋅、540185 V. Description of the invention (1) " " 1 — --- _ And related to a paper battery and its manufacturing method, which are-Bimei, graphite, Gan, Yuyou, "Ala, water-based adhesives, Zinc fine = paste ... gasified zinc, amine chloride, water-based adhesives :! Electromechanical equipment, apply positive and negative plasma to :; catty: = water ;; positive oil supplier. Flying batteries and moon daggers for all kinds of microelectronics. ：： ί! Many products on the market are micro-power-required products, such as music greeting cards, whose music is congratulated> and ν's objects issued stand-up models, mainly to make small music successful When the hair comes out, the power of the music sounder is not large. At present, the weight and volume of the electricity set using a mercury battery are required to increase the weight of the greeting card.> The battery has an overall aesthetic appearance; in addition, many of the problems that require micro-seconds will also affect greeting cards' and remain to be solved. Electricity and quotations are also the same. They all meet the same requirements in view of the conventional micro power supply. Light weight batteries are used in conjunction with applications, and they have a small volume, and people are actively working on research. 'Use the efficacy of the invention. The main purpose of the invention was to develop a method for receiving the pool; we can borrow 1 t to make ^ kinds of paper sheets + ^ You have water-absorbent paper sheets, too, prepared M is a type of private amine, water-based adhesive Agent, zinc fine lice zinc, chlorinated alcohol, etc. are prepared into pinch tobacco glycerol, acetone, methanol, amine, water-based adhesive, 1 Jc, zinc lice,
第4頁 軋化锰$墨粉、硝酸银、甘油等 540185Page 4 Rolled Manganese $ Toner, Silver Nitrate, Glycerin, etc. 540185
所調製成水性之正極油 片正反面’再於正反面 池者。 墨電漿，將正負電漿分別塗覆於 封裝防水膠層，即製成一紙片式電 本發明之另一目的 各 ， 吸水性紙片正反面呈有正2 ”共一種紙質電池，其係於 負極油墨電衆係由；有墨電衆與負極油墨電I:該 細末、石，奚、甘油丙；ί薛鼠化胺：水性黏合劑、鋅 正極油墨電漿係由水、氣 ：：專所调製而成，而 正反面封裝-層防水膠，並於紙片 各式.微電源供應者、 、我片式電池，而能作 為使貴審查 及其目的’兹附以圖式詳細說明如后/月之-構特徵 "月參看第目所不，本發明之流程如下： (A )具備材料·· 1 ·具有適當密度及吸水性之紙片； Γ 2 J負極油墨電聚所需材料，有水（h20)、氯化辞（zN 12)、氣化胺UH4C1)為主的電解質（亦為媒染劑），水性 黏合劑，辞（ZN)細末、石墨、甘油，及丙酮、甲醇、乙醇 揮發性物質； 3 ·正極油墨電漿所需材料，有水、氯化鋅（Zn c丨2)、 氯化胺（N^Cl)、水性黏合劑、二氧化錳（Mn〇2)、石墨粉、 硝酸銀（N03Ag)、甘油； … （B ) _.調製正負極油墨電漿：The positive and negative sides of the prepared positive electrode oil sheet are then placed on the positive and negative sides. Ink plasma, the positive and negative plasmas are coated on the waterproof plastic layer of the encapsulation respectively, that is to make a paper sheet type of electricity. Another purpose of the present invention, the positive and negative sides of the water-absorptive paper sheet are positive 2 ", a kind of paper battery. Negative ink inks are made of ink; there are ink inks and negative inks I: The fine powder, stone, tincture, glycerol propyl; chelamine: water-based binder, zinc positive ink plasma: water, gas :: It is specially prepared, and the front and back sides are packaged with a layer of waterproof glue, and various types of paper. Micro power suppliers, and chip batteries can be used for your review and its purpose. As described later / month-structure characteristics " monthly reference, the process of the present invention is as follows: (A) with materials ·· 1 · paper sheet with appropriate density and water absorption; Γ 2 J negative electrode ink electropolymerization required Materials include electrolytes (also mordants) based on water (h20), chloride (zN 12), and gasified amine UH4C1), water-based binders, fines (ZN), graphite, glycerin, and acetone, Volatile substances of methanol and ethanol; 3 · Material required for cathode ink plasma, including water, zinc chloride (Z n c 丨 2), amine chloride (N ^ Cl), water-based binder, manganese dioxide (Mn〇2), graphite powder, silver nitrate (N03Ag), glycerin; ... (B) _. Modulation of positive and negative electrode ink plasma:
540185 、發明說明（3) 1 ·先將水、氣化鋅、氣化胺與水性黏合劑調製成電 水’冉加入辞細末、石墨、甘油而調製成濃油墨，再與丙 明、甲醇、乙醇調製成具有揮發性之負極油墨電漿； 將 2 ·先將水、氣化鋅、氣化胺、水性黏合劑調製成電 水’再加入二氧化錳、石墨粉、硝酸銀、甘油調製成水性 之正極油墨電漿； (C )塗覆電漿： 1 ·將負極油墨電漿塗覆於紙片反面； 2 ·將正極油墨電漿塗覆於紙片正面； (D )塗覆防水膠： ^ 在已塗覆有負極油墨電漿的紙片反面加覆一層防水 膠’並在已塗覆有正極油墨電漿的紙片正面加覆一層防水 膠’即製成紙質電池。 ^其中’本發明實施時，其所採用的水性黏合劑可為明 膠、糊精與澱粉所組成。 其中，請配合參看第二圖所示，本發明實施時，可將 片已在正反面塗覆有正負極油墨電漿之紙片疊合 )成串聯或並聯形態藉以增加電壓，再於最: 防水膠層。 Γ層、、、氏片封裝 凊參看第三圖所示，本發明之紙質電池，、 、 水、性魏合540185, Description of the invention (3) 1 · First, water, gasified zinc, gasified amine, and water-based binders are prepared into electro-water. Ran is added into the fine powder, graphite, and glycerin to prepare a thick ink, and then mixed with propylene and methanol. 2. Ethanol is used to prepare volatile anode ink plasma. 2. Make water, zinc gas, amine, and water-based binder into electric water first, and then add manganese dioxide, graphite powder, silver nitrate, and glycerin to prepare. Water-based positive electrode ink plasma; (C) Coating plasma: 1 · Apply negative electrode ink plasma to the reverse side of the paper sheet; 2 · Apply positive electrode ink plasma to the front side of the paper sheet; (D) Apply waterproof glue: ^ A paper battery is made by coating a layer of waterproof glue on the reverse side of the paper sheet coated with the negative electrode ink plasma and a layer of waterproof glue on the front surface of the paper sheet coated with the positive electrode ink plasma. ^ Among them, when the present invention is implemented, the water-based adhesive used therein may be composed of gelatin, dextrin and starch. Among them, please refer to the second figure. When the present invention is implemented, the sheets can be laminated with positive and negative ink plasma plasma coated on the front and back sides) in series or parallel to increase the voltage, and then: Glue layer. Γ-layer, ,, and hermetic package 凊 Refer to the third figure, the paper battery of the present invention,
第6頁 (1 0 )為介質，於紙片d 〇 )反面覆設有一層由水糸，紙片 氯化胺與水性黏合劑、鋅細末、石墨、甘油、氯化鋅、 醇、己醇組成之負極油墨電漿層（1 i )與一防 1獅、甲 而紙片正面覆設有一層由水、氯化辞、氯化膠層（1 3 )， 540185 五、發明說明（4) 劑、二氧化錳 漿層（1 2 )與一 其中，請 可依據所需電 漿層（12)(11) 層（13)(14)。 本發明紙 屬，正極的二 為電解質及媒 形成電解質隔 通過紙片隔離 等氧化劑更強 子而與負極鋅 時，係如第五 正負極，即可 因此，藉 下列之優點： 1 ·本發 效益高’具產 2 ·本發 源的物品（如 3 ·本發 彎折，可輕便 水壺等）上。 質電池之 氧化猛與 染劑，當 離膜，並 膜而與鋅 力分解， 結合放電 圖所示， 使用。 由上述結 主要動作 銷酸銀為 紙片由正 與負極相 結合放電 結果使正 ，而完成 將導線接 、石墨粉、硝酸銀、甘油組成之正極油墨電 防水膠層（1 4 )，以防止該電漿失水乾燥。 配合參看第四圖所示，本發明之紙質電池， 谷畺，由數片正反面已塗覆有正負極油墨電 之紙片（1 0 )疊合，並於最外層封裝一防水膠 原理’係以鋅為極放電金 氧化劑，氯化辞、氯化胺 極水性油墨吸水後，紙片 通放電形成起始，氯離子 ’促使二氧化猛、確酸銀 極多生成氧離子、硝酸離 電池循環；本發明使用 端（15)(16)連接負載（2〇) 構之設計，可歸納本發明確實具有 =流程’可快速大量製成紙質電池，經濟 業利用價值。 明所製成之紙質電池，可疼 ^ ^ ^ J廣泛應用於需微電 音樂卡片等）。 :戶:製成之紙質電⑻，不佔空間，可以任意 文裝於具有不_表面之物品（如飲料罐、Page 6 (1 0) is the medium. On the reverse side of the paper sheet d), a layer of water leash, paper sheet amine chloride and water-based adhesive, zinc fines, graphite, glycerin, zinc chloride, alcohol, hexanol is formed. The negative electrode ink plasma layer (1 i) and one anti-lion, armor, and paper are covered with a layer of water, chlorination, and chlorinated rubber (1 3) on the front side. 540185 V. Description of the invention (4) Agent, The manganese dioxide slurry layer (1 2) and one of them can be based on the required plasma layer (12) (11) layer (13) (14). In the paper of the present invention, when the second electrode of the positive electrode is an electrolyte and the medium forms an electrolyte and is separated by a oxidant such as a paper sheet to separate it from the negative electrode zinc, such as the fifth positive electrode, the following advantages can be used: 1 Gao'gu 2 · This item is from the source (such as 3 · This hair is bent, can be a portable kettle, etc.). The oxidation and dye of the mass battery are separated from the film, and the film is decomposed with zinc. Combined with the discharge diagram, it is used. The main action of the above junction is to sell the acid silver as a paper sheet, which is combined with the positive electrode and the negative electrode to make the positive electrode, and the positive electrode ink waterproof adhesive layer (1 4) composed of lead wires, graphite powder, silver nitrate, and glycerin is completed to prevent the electric current. The pulp is dehydrated and dried. With reference to the fourth figure, the paper battery of the present invention, Gusong, is composed of several sheets of paper (1 0) on which the front and back sides have been coated with positive and negative ink, and the outermost layer is encapsulated with a waterproof glue principle. Zinc is used as a gold-discharge oxidant. After chlorination and amine chloride extremely water-based inks absorb water, the discharge of the paper sheet begins to form. Chloride ions promote the oxidation of fierce dioxide, silver acid, and oxygen ions. The design of the end-use (15) (16) connected load (20) structure of the present invention can be concluded that the present invention does have a process flow, which can be quickly and mass-produced into a paper battery, which is economically useful. The paper battery made by Ming Dynasty can hurt ^ ^ ^ J is widely used in micro-electric music cards, etc.). : House: Paper-made electric cards made of paper that do not take up space and can be freely mounted on articles with non-surfaces (such as beverage cans,
第7頁 540185 五、發明說明（5) 綜上所述，本發明具有製成紙質電池，易於大量製 造，經濟效益高，可廣泛應用微電源物品等功效，其整體 技術特徵未見同類物品，為電池帶來革新，且具有產業充 分利用的價值，實已符合發明專利之要件，爰依法提出申 請，僅請貴局依法早日准予專利，讓本發明得以早曰嘉 惠廣大之社會大眾。Page 7 540185 V. Description of the invention (5) In summary, the present invention has the advantages of making paper batteries, easy to mass-produce, high economic benefits, and can be widely used in micro power supply items. Its overall technical characteristics are not seen in similar items. Bringing innovation to the battery, and having the value of full industrial utilization, have indeed met the requirements of invention patents, and applied in accordance with the law. We only ask your office to grant patents as soon as possible, so that the invention can benefit the general public as soon as possible.
540185 圖式簡單說明 (一） ·圖式部份： 第一圖：係本發明之流程示意圖。 第二圖：係本發明之另一實施流程示意圖。 第三圖··係本發明電池之剖示圖。 第四圖：係本發明紙片疊合之剖示圖。 第五圖：係本發明之使用示意圖。 (二） ·圖號部份： (A )具備材料 （B )調製正負極油墨電漿 (C )塗覆電漿 （C 1 )紙片疊合 (D )塗覆防水膠 (1 0 )紙片 （11 )負極油墨電漿 (1 2 )正極油墨電漿（1 3 ) ( 1 4 )防水膠 (15)(16)導線接端（20)負載540185 Schematic description (1) Schematic part: The first diagram: a schematic diagram of the process of the present invention. The second figure is a schematic diagram of another implementation process of the present invention. The third figure is a sectional view of the battery of the present invention. The fourth figure is a cross-sectional view showing the stacking of paper sheets according to the present invention. Fifth figure: It is a schematic diagram of the use of the present invention. (II) Drawing number part: (A) Material (B) Preparation of positive and negative electrode ink plasma (C) Coated plasma (C1) Paper stack (D) Coated with waterproof glue (1 0) Paper ( 11) Negative ink plasma (1 2) Positive ink plasma (1 3) (1 4) Waterproof glue (15) (16) Wire terminal (20) Load