TW201421167A - Microlithographic projection exposure apparatus and method for varying an optical wavefront in a catoptric lens of such an apparatus - Google Patents

Microlithographic projection exposure apparatus and method for varying an optical wavefront in a catoptric lens of such an apparatus Download PDF

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TW201421167A
TW201421167A TW102124555A TW102124555A TW201421167A TW 201421167 A TW201421167 A TW 201421167A TW 102124555 A TW102124555 A TW 102124555A TW 102124555 A TW102124555 A TW 102124555A TW 201421167 A TW201421167 A TW 201421167A
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lens
mirror
mirrors
processing head
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TWI610141B (en
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Boris Bittner
Norbert Wabra
Martin Von Hodenberg
Ricarda Schneider
Sonja Schneider
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Zeiss Carl Smt Gmbh
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/08Mirrors
    • G02B5/0816Multilayer mirrors, i.e. having two or more reflecting layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70216Mask projection systems
    • G03F7/70233Optical aspects of catoptric systems, i.e. comprising only reflective elements, e.g. extreme ultraviolet [EUV] projection systems
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70483Information management; Active and passive control; Testing; Wafer monitoring, e.g. pattern monitoring
    • G03F7/70591Testing optical components
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70483Information management; Active and passive control; Testing; Wafer monitoring, e.g. pattern monitoring
    • G03F7/70591Testing optical components
    • G03F7/706Aberration measurement
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/708Construction of apparatus, e.g. environment aspects, hygiene aspects or materials
    • G03F7/7095Materials, e.g. materials for housing, stage or other support having particular properties, e.g. weight, strength, conductivity, thermal expansion coefficient
    • G03F7/70958Optical materials or coatings, e.g. with particular transmittance, reflectance or anti-reflection properties
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21KTECHNIQUES FOR HANDLING PARTICLES OR IONISING RADIATION NOT OTHERWISE PROVIDED FOR; IRRADIATION DEVICES; GAMMA RAY OR X-RAY MICROSCOPES
    • G21K1/00Arrangements for handling particles or ionising radiation, e.g. focusing or moderating
    • G21K1/06Arrangements for handling particles or ionising radiation, e.g. focusing or moderating using diffraction, refraction or reflection, e.g. monochromators
    • G21K1/062Devices having a multilayer structure
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B26/00Optical devices or arrangements for the control of light using movable or deformable optical elements
    • G02B26/06Optical devices or arrangements for the control of light using movable or deformable optical elements for controlling the phase of light

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Chemical & Material Sciences (AREA)
  • Optics & Photonics (AREA)
  • Public Health (AREA)
  • Theoretical Computer Science (AREA)
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  • Crystallography & Structural Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Engineering & Computer Science (AREA)
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  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Lenses (AREA)

Abstract

A microlithographic projection exposure apparatus (10) for projecting a reflective mask (14) onto a light-sensitive layer (16) contains a catoptric lens (26) comprising a plurality of mutually adjusted mirrors (M1 to M6) configured to reflect projection light having a center wavelength of between 5 nm and 30 nm. The lens (26) is configured to direct projection light reflected from the mask (14) onto the light-sensitive layer (16). At least one of the plurality of mirrors (M2, M3) is a correction mirror for correcting wavefront deformations, which changes its form permanently when it is processed by a processing beam (65). Furthermore, a processing device (42) is provided, having a processing head (44), from which the processing beam (65) emerges during operation of the processing head. The processing head is arranged or can be arranged within the lens (26) such that the processing beam (65) impinges on none of the other plurality of mirrors before it processes the correction mirror (M2, M3).

Description

微影投射曝光裝置及改變此類裝置之反射透鏡中光波前的方法 Micro-image projection exposure apparatus and method for changing optical wavefront in a reflective lens of such a device

本發明有關一種微影EUV投射曝光裝置,及有關一種改變此類裝置之反射透鏡中光波前的方法。 The present invention relates to a lithographic EUV projection exposure apparatus and to a method of modifying the optical wavefront in a reflective lens of such apparatus.

使用微影投射曝光裝置將遮罩中含有的或遮罩上形成的結構轉印至光阻或某個其他感光層。投射曝光裝置之最重要的光學組件是:光源;照射系統,其調節由光源產生的投射光及將該投射光引到遮罩上;及透鏡,其將遮罩為照射系統所照射的區段成像於感光層上。 The structure contained in the mask or formed on the mask is transferred to the photoresist or some other photosensitive layer using a lithographic projection exposure apparatus. The most important optical components of the projection exposure apparatus are: a light source; an illumination system that adjusts the projected light generated by the light source and directs the projected light onto the mask; and a lens that masks the section illuminated by the illumination system Imaged on the photosensitive layer.

投射光的波長越短,可借助投射曝光裝置定義於感光層上的結構越小。最新一代的投射曝光裝置使用極紫外線光譜範圍(EUV)中的投射光,其中心波長為13.5nm。通常將此類裝置稱為「EUV投射曝光裝置」。 The shorter the wavelength of the projected light, the smaller the structure defined by the projection exposure device on the photosensitive layer. The latest generation of projection exposure devices use projected light in the extreme ultraviolet spectral range (EUV) with a center wavelength of 13.5 nm. Such devices are often referred to as "EUV projection exposure devices."

然而,對於如此短的波長,並沒有任何光學材料具有足夠高的透射率。因此,在EUV投射曝光裝置中,以反射鏡取代慣常在較長波長下使用的透鏡元件及其他折射光學元件,且遮罩亦含有反射結構的圖案。專門含有反射鏡作為成像光學元件的透鏡被命名為「反射透鏡」。 However, for such a short wavelength, no optical material has a sufficiently high transmittance. Therefore, in the EUV projection exposure apparatus, the lens element and other refractive optical elements conventionally used at longer wavelengths are replaced by mirrors, and the mask also contains a pattern of the reflective structure. A lens specifically containing a mirror as an imaging optical element is named "reflective lens".

為確保遮罩中所含結構在感光層上的最佳成像,對透鏡中反射鏡的尺寸精確性訂定極為嚴格的要求。然而,由於製造及安裝容限,永遠無法確實達到透鏡設計所決定的最小成像像差。通常將透鏡的成像像差描述為一般量測之真實光波前與理想光波前的偏差。此類偏差又稱為「波前變形」,其可分解成如作為級數展開式的個別部分。在此情況中,特定而言,因為分解的個別項可直接指派給特定的Seidel成像像差,諸如像散或彗形像差,已證明根據Zernike係數的分解是適當的。 In order to ensure optimal imaging of the structure contained in the mask on the photosensitive layer, extremely stringent requirements are placed on the dimensional accuracy of the mirror in the lens. However, due to manufacturing and mounting tolerances, the minimum imaging aberration determined by the lens design can never be achieved. The imaging aberration of a lens is generally described as the deviation of the true optical wavefront from the ideal optical wavefront measured in general. Such deviations are also referred to as "wavefront distortions", which can be broken down into individual parts as a series expansion. In this case, in particular, since the decomposed individual items can be directly assigned to specific Seidel imaging aberrations, such as astigmatism or coma, it has been proved that decomposition according to Zernike coefficients is appropriate.

為校正成像像差,透鏡中含有的反射鏡可借助操縱器進行極精細的調整,其涵蓋反射鏡的位移及撓曲二者。但是,以此做法僅可減少波前變形的較長波部分。 To correct for imaging aberrations, the mirrors contained in the lens can be finely adjusted by means of a manipulator, which covers both the displacement and deflection of the mirror. However, this method can only reduce the longer wave portion of the wavefront deformation.

在投射曝光裝置啟動之後,還需要進行校正。這是因為已經確定例如在反射鏡基板在相對較長時間上經受特別高光強度的位置處,高能EUV投射光導致緊密作用,這與反射鏡表面形狀的局部限定變更相關聯。因此,有時也需要在投射曝光裝置啟動之後能夠改良透鏡的成像性質。 Correction is also required after the projection exposure device is activated. This is because it has been determined that, for example, where the mirror substrate is subjected to a particularly high light intensity over a relatively long period of time, the high energy EUV projection light causes a tight effect, which is associated with a locally defined change in the shape of the mirror surface. Therefore, it is sometimes necessary to improve the imaging properties of the lens after the projection exposure apparatus is activated.

一個校正短波波前變形的辦法在於局部移除適當反射鏡的表面,以變更反射鏡的形狀及藉此減少或影響波前變形,致使可利用先前提到的操縱器比較容易地校正此波前變形。 One approach to correcting short-wavefront distortion is to locally remove the surface of the appropriate mirror to alter the shape of the mirror and thereby reduce or affect the wavefront distortion, such that the wavefront can be corrected relatively easily using the previously mentioned manipulator. Deformation.

但是,此藉由材料移除的後處理,諸如在透鏡元件中所成功採用的後處理,在EUV透鏡中因為許多原因是有問題的。首先,儘管材料移除變更有關反射鏡的形狀,但同時也損害敏感的反射塗層,因而導致反射係數的局部減少。一個解決此問題的辦法在於對反射鏡基板(而非塗層本身)進行局部後處理,如見於US 2005/0134980 A1。 However, this post-processing by material removal, such as the post-processing successfully employed in lens elements, is problematic in EUV lenses for a number of reasons. First, although material removal changes the shape of the mirror, it also damages the sensitive reflective coating, resulting in a local reduction in the reflection coefficient. One solution to this problem consists in partial post-treatment of the mirror substrate (rather than the coating itself) as seen in US 2005/0134980 A1.

另一辦法不在於從反射鏡表面移除材料,而是使在反射塗層下方的反射鏡基板局部變得緊密,如說明於DE 10 2011 084 117 A1。為此目的,將處理射束(如,電子束或高能光束)引到要處理的反射鏡上。處理射束在與反射塗層沒有明顯交互作用的情況下穿透反射塗層,並導致反射鏡基板下伏區中的緊密作用。相關聯的基板局部收縮最終引起所要的反射鏡變形。 Another approach is not to remove the material from the surface of the mirror, but to make the mirror substrate under the reflective coating partially compact, as described in DE 10 2011 084 117 A1. For this purpose, a processing beam (eg, an electron beam or a high energy beam) is directed onto the mirror to be processed. The processing beam penetrates the reflective coating without significant interaction with the reflective coating and causes a tight effect in the underlying region of the mirror substrate. The associated local shrinkage of the substrate ultimately causes the desired mirror deformation.

但是,在這兩個辦法中,基本問題仍然存在:為了決定校正的需求及所需的後處理,任何類型的後處理一開始都需要將反射鏡併入透鏡中。如果接著將有關反射鏡從透鏡卸下、進行後處理及稍後再合併,則在確定校正需求時所存在的條件可能不復全部重現。反射鏡本身的卸下及稍後合併因此可以說是額外又不需要且無法控制的後處理類型。此外,不對確定校正需求時所使用的反射鏡進行後處理,而是對該反射鏡完全相同的複製品進行後處理(如已經提到的US 2005/0134980 A1所提出),並無法避免此問題。 However, in both approaches, the basic problem remains: in order to determine the need for calibration and the required post-processing, any type of post-processing needs to incorporate the mirror into the lens at the outset. If the mirrors are then removed from the lens, post-processed, and later merged, the conditions that exist when determining the calibration requirements may not fully reproduce. The removal and later merging of the mirror itself can be said to be an additional type of post-processing that is not required and cannot be controlled. In addition, the mirrors used to determine the calibration requirements are not post-processed, but the identical replicas of the mirrors are post-processed (as proposed in US 2005/0134980 A1) and cannot be avoided. .

對於設計用於具有明顯較長中心波長之投射光及因此主要含有透鏡元件作為光學元件的投射曝光裝置,DE 10 2004 046 542 A1提出從透鏡的光入射側或光出射側,將處理輻射耦合至透鏡中。在此情況中,將透鏡元件的光學性質納入考慮,致使針對局部材料收縮及/或增加折射率所需的這些輻射強度僅發生在所要的校正透鏡元件上。結果,處理輻射不處理輻射所略過的其他透鏡元件。 DE 10 2004 046 542 A1 proposes to couple processing radiation from the light incident side or the light exit side of the lens to a projection exposure device designed for a projection light having a significantly longer central wavelength and thus mainly comprising a lens element as an optical element. In the lens. In this case, the optical properties of the lens elements are taken into account such that the intensity of the radiation required to shrink and/or increase the refractive index for the local material occurs only on the desired corrective lens element. As a result, the processing radiation does not process other lens elements that are skipped by the radiation.

但是,因為反射鏡的塗層雖然可反射EUV投射光,但卻無法反射處理輻射,所以無法在EUV透鏡中採用此一方法。結果,無法以此方式處理內部反射鏡。 However, because the coating of the mirror can reflect EUV projection light, but can not reflect the processing radiation, this method cannot be used in the EUV lens. As a result, the internal mirror cannot be processed in this way.

本發明之目的在於提供一種微影投射曝光裝置,其可用以有效減少甚至短波波前變形。此外,本發明之目的在於提供一種可高效地改變此類裝置之反射透鏡中光波前的方法。 It is an object of the present invention to provide a lithographic projection exposure apparatus that can be used to effectively reduce even short wavefront distortion. Furthermore, it is an object of the present invention to provide a method for efficiently changing the optical wavefront in a reflective lens of such a device.

此目的可利用將反射遮罩投射至感光層上的微影投射曝光裝置來達成,此裝置包含一反射透鏡,該反射透鏡包含複數個互相調整的反射鏡。反射鏡較佳經組態以反射中心波長在5nm及30nm之間的投射光。透鏡經組態以將從遮罩反射的投射光引到感光層上。該複數個反射鏡中的至少一個是用於校正波前變形的校正反射鏡,其在用處理射束處理時,永久地變更其形狀。投射曝光裝置另外包含處理器件,其包含處理頭,處理射束在處理頭操作期間從處理頭出現。處理頭係配置在或可配置在透鏡內,致使處理射束在處理校正反射鏡之前,不會撞擊在該其他複數個反射鏡的任一者上。 This object is achieved by a lithographic projection exposure apparatus that projects a reflective mask onto a photosensitive layer, the apparatus comprising a reflective lens comprising a plurality of mutually adjusted mirrors. The mirror is preferably configured to reflect projected light having a center wavelength between 5 nm and 30 nm. The lens is configured to direct the projected light reflected from the mask onto the photosensitive layer. At least one of the plurality of mirrors is a correcting mirror for correcting wavefront distortion that permanently changes its shape when processed by the processing beam. The projection exposure apparatus additionally includes a processing device that includes a processing head that appears from the processing head during operation of the processing head. The processing head is disposed or configurable within the lens such that the processing beam does not impinge on any of the other plurality of mirrors prior to processing the correcting mirror.

本發明基於以下考量:唯有在決定校正需求之後將要處理的校正反射鏡保留在透鏡中,才進行波前變形的有效校正。另一方面,由於適於處理的處理射束不為反射鏡所反射,所以為了處理內部反射鏡,處理射束必須從配置在透鏡中的處理頭出現。在此情況中,處理頭可永久地配置在透鏡中或僅在實際處理期間位在透鏡內。在此情況中,處理頭以一方式引入透鏡中,致使不必拆卸透鏡。結果,不會發生在卸下且稍後重新併入反射鏡的情況中一般所無法避免的成像性質減損。 The invention is based on the consideration that an effective correction of the wavefront deformation is only carried out after the correction mirror to be processed remains in the lens after determining the correction requirement. On the other hand, since the processing beam suitable for processing is not reflected by the mirror, in order to process the internal mirror, the processing beam must appear from the processing head disposed in the lens. In this case, the processing head can be permanently disposed in the lens or only within the lens during actual processing. In this case, the processing head is introduced into the lens in a manner such that it is not necessary to disassemble the lens. As a result, imaging property impairments that are generally unavoidable in the case of unloading and later reintegration into the mirror will not occur.

結果,即使是內部反射鏡(即,在透鏡的光束路徑中,既非第一也非最後反射鏡的反射鏡),本發明亦可針對校正目的使其進行後處理,而不必從透鏡卸下該反射鏡以進行後處理。 As a result, even if it is an internal mirror (i.e., a mirror that is neither the first nor the last mirror in the beam path of the lens), the present invention can be post-processed for correction purposes without having to be detached from the lens. The mirror is post-processed.

處理射束較佳具有僅使反射鏡基板而非反射塗層緊密(如果其撞擊在反射塗層上)的性質。特定而言,具有充分高能的電子束或光束適合作為處理射束。 The processing beam preferably has the property of only making the mirror substrate, rather than the reflective coating, compact (if it impinges on the reflective coating). In particular, an electron beam or beam of sufficient energy is suitable as the processing beam.

如果處理射束是高能光束,則可以有目標的方式在校正反射鏡之要處理的區域上,借助可傾斜反射鏡或其類似物以類似掃描器的方式引導高能光束。但是,特別在處理射束是電子束時,可為便利的是,借助移動器件移動處理頭橫越校正反射鏡的區域。可以此方式毫無問題地實現在使用電子束處理的情況中較為便利的相對較短處理距離,以使電子束直徑保持較小。 If the processing beam is a high energy beam, the high energy beam can be guided in a scanner-like manner by means of a tiltable mirror or the like in a targeted manner on the area to be processed by the correction mirror. However, particularly where the processing beam is an electron beam, it may be convenient to move the processing head across the area of the correction mirror by means of the moving device. A relatively short processing distance which is convenient in the case of using electron beam processing can be realized in this way without any problem, so that the electron beam diameter is kept small.

特定而言,移動器件可經組態以移動處理頭橫越校正反射鏡的區域,致使在以處理射束處理校正反射鏡期間,在處理頭及該區域之間的距離不超過最大處理距離10mm(較佳5mm、及更佳1mm)。以此方式,可借助處理射束,在基板材料中產生甚至局部極狹窄限定的緊密作用。 In particular, the mobile device can be configured to move the processing head across the area of the correcting mirror such that during processing of the correcting mirror with the processing beam, the distance between the processing head and the region does not exceed a maximum processing distance of 10 mm (preferably 5 mm, and more preferably 1 mm). In this way, even the local extreme narrow definition of compaction can be produced in the substrate material by means of the treatment beam.

如果儘管射束直徑較小,但要連續處理相對較大的區域,則處理器件可經組態以沿著移動路徑移動處理頭橫越該區域,致使在走完移動路徑之後,處理射束已漸進地處理該區域上接近二維區的量。 If, although the beam diameter is small, a relatively large area is to be processed continuously, the processing device can be configured to move the processing head across the area along the moving path such that after the moving path is finished, the processing beam has The amount of the area close to the two-dimensional area is progressively processed.

一般而言,以處理射束處理的區域將是由反射鏡基板承載之反射塗層的表面。此確保反射鏡基板的緊密作用發生在直接接近反射塗層處,及可因此對光波前發揮其最大效應。 In general, the area treated with the processing beam will be the surface of the reflective coating carried by the mirror substrate. This ensures that the tight action of the mirror substrate occurs directly adjacent to the reflective coating and can therefore exert its maximum effect on the optical wavefront.

但是,處理射束原則上亦可撞擊在反射塗層未覆蓋之校正元件的區域上。該區域例如可以是背對反射塗層之反射鏡基板後側上的區域。關於在透鏡中配置處理頭所需的結構空間,此類處理區域在某些情況下是有利的。 However, the processing beam can in principle also impinge on the area of the correction element which is not covered by the reflective coating. This region may for example be the area on the back side of the mirror substrate facing away from the reflective coating. Such processing regions are advantageous in certain circumstances with regard to the structural space required to configure the processing head in the lens.

如果處理頭並非永久地配置在透鏡中,則透鏡可具有支撐複數個反射鏡的支撐結構,在該支撐結構中形成存取通道。接著可在借助處理射束處理校正反射鏡時,透過存取通道將處理頭引入透鏡中。因此,借助於一直存在的存取通道,不需要為了能夠執行處理而對透鏡進行任何結構更改。此確保甚至在處理之後,所有反射鏡仍確切位在決定校正需求時其所位在的位置處。存取通道可為提供用於使投射光通過的光通道。但是,甚至更便利的是除了此光通道之外,還提供存取通道。 If the processing head is not permanently disposed in the lens, the lens can have a support structure that supports a plurality of mirrors in which access channels are formed. The processing head can then be introduced into the lens through the access channel while the mirror is being corrected by the processing beam processing. Thus, with the aid of an always existing access channel, there is no need to make any structural changes to the lens in order to be able to perform the processing. This ensures that even after processing, all mirrors are exactly where they are located when determining the correction requirements. The access channel can be a light channel for passing the projected light. However, it is even more convenient to provide an access channel in addition to this optical channel.

僅在實際處理時間期間將處理頭引入透鏡之所以實用的原因很多。首先,處理頭可接著在處理期間配置在實際設計用於使投射光通過及較佳不同於存取通道的光通道中。相反地,在處理頭永久地配置在透鏡中的情況中,必須確保至少在投射操作期間,處理頭處於不會妨礙投射光通過的靜止定位中。從結構空間取決於透鏡設計的觀點來看,這可能有其困難。處理頭僅視需要配置在透鏡中的另一優點是,在只有一個處理頭的情況下,亦可處理不同的校正反射鏡。 There are many reasons why the processing head is introduced into the lens only during the actual processing time. First, the processing head can then be configured during processing to be in an optical channel that is actually designed to pass the projected light and preferably different from the access channel. Conversely, in the case where the processing head is permanently disposed in the lens, it must be ensured that the processing head is in a stationary position that does not interfere with the passage of the projected light, at least during the projection operation. This may be difficult from the point of view of the structural space depending on the lens design. Another advantage of the processing head being disposed in the lens as desired is that different correction mirrors can be processed with only one processing head.

關於方法,利用改變微影投射曝光裝置之反射透鏡中光波前的方法達成序言中提到的目的,其中該方法包含以下步驟:a)從複數個反射鏡組裝反射透鏡,該等反射透鏡較佳經設計以反射中心波長在5nm及30nm之間的投射光,及其中該複數個反射鏡中的至少一個係一用於校正波前變形的校正反射鏡;b)調整該等反射鏡;c)用一處理射束處理該校正反射鏡的一區域,藉此該校正反射鏡的形狀永久地變更,及其中該處理射束在處理該 校正反射鏡之前未撞擊在該其他複數個反射鏡的任一者上;其中在步驟b)及c)之間未從該透鏡移除任何反射鏡。 With regard to the method, the object mentioned in the preamble is achieved by a method of changing the optical wavefront in the reflective lens of the lithographic projection exposure apparatus, wherein the method comprises the steps of: a) assembling a reflective lens from a plurality of mirrors, preferably the reflective lenses. Projected to reflect a projected light having a center wavelength between 5 nm and 30 nm, and wherein at least one of the plurality of mirrors is a correcting mirror for correcting wavefront distortion; b) adjusting the mirrors; c) Processing a region of the correcting mirror with a processing beam whereby the shape of the correcting mirror is permanently altered, and wherein the processing beam is processing The correcting mirror has not impinged on any of the other plurality of mirrors; wherein no mirrors have been removed from the lens between steps b) and c).

對上述優點及較佳具體實施例做出參考。 Reference is made to the above advantages and preferred embodiments.

特定而言,可在步驟c)期間使發射處理射束的處理頭移動橫越校正反射鏡的區域,致使在用處理射束處理校正反射鏡期間,在處理頭及該區域之間的距離不超過最佳處理距離10mm、較佳5mm、更佳1mm。 In particular, the processing head that emits the processed beam may be moved across the area of the correcting mirror during step c) such that during processing of the correcting mirror with the processing beam, the distance between the processing head and the area is not More than the optimum treatment distance of 10 mm, preferably 5 mm, more preferably 1 mm.

在步驟c)期間,可在該區域上方引導處理射束,致使在走完移動路徑之後,處理射束已漸進地處理該區域上的二維區。 During step c), the processing beam can be directed over the area such that after the moving path is completed, the processing beam has progressively processed the two-dimensional area on the area.

如果處理頭僅在處理期間位在透鏡中,則該處理頭可在處理之前透過存取通道引入透鏡中,該存取通道提供於經組態以支撐反射鏡的支撐結構中,且該存取通道不同於設計用於使投射光通過透鏡的光通道。 If the processing head is only in the lens during processing, the processing head can be introduced into the lens through the access channel prior to processing, the access channel being provided in a support structure configured to support the mirror, and the access The channel is different from the light channel designed to pass the projected light through the lens.

本發明另外有關一種透鏡,其包含:一反射鏡;一處理頭,其經組態以發射處理射束;及包含一移動器件,其經組態以將處理頭配置在反射鏡的區域上的不同位置處,致使處理射束引起反射鏡之形狀的永久變更。 The invention further relates to a lens comprising: a mirror; a processing head configured to emit a processing beam; and a mobile device configured to configure the processing head on a region of the mirror At different locations, the processing beam causes a permanent change in the shape of the mirror.

在一具體實施例中,在處理頭及反射鏡的區域之間的距離在此情況中不超過最大處理距離10mm。 In a specific embodiment, the distance between the processing head and the area of the mirror does not exceed a maximum processing distance of 10 mm in this case.

本發明另外有關一種改變透鏡中光波前的方法,包含以下步驟:a)從複數個反射鏡組裝一反射透鏡;b)調整該等反射鏡;c)將一處理射束引到一反射鏡的一區域上,藉此該反射鏡 的形狀永久地變更,其中該反射鏡在該透鏡的光束路徑中既非該透鏡的第一也非最後反射鏡。 The invention further relates to a method of changing the optical wavefront in a lens, comprising the steps of: a) assembling a reflective lens from a plurality of mirrors; b) adjusting the mirrors; c) directing a processing beam to a mirror On one area, the mirror is taken The shape is permanently altered, wherein the mirror is neither the first nor the last mirror of the lens in the beam path of the lens.

10‧‧‧投射曝光裝置 10‧‧‧Projection exposure device

12‧‧‧反射結構 12‧‧‧Reflective structure

14‧‧‧遮罩 14‧‧‧ mask

16‧‧‧感光層 16‧‧‧Photosensitive layer

18‧‧‧晶圓 18‧‧‧ Wafer

20‧‧‧照射系統 20‧‧‧ illumination system

22‧‧‧EUV光 22‧‧‧EUV light

24‧‧‧照射場 24‧‧‧ illuminating field

24'‧‧‧縮小影像 24'‧‧‧Reduced image

26‧‧‧透鏡 26‧‧‧ lens

28‧‧‧光束 28‧‧‧ Beam

30‧‧‧物體平面 30‧‧‧ object plane

32‧‧‧影像平面 32‧‧‧Image plane

34‧‧‧第一光瞳表面 34‧‧‧First optical surface

36‧‧‧主光線 36‧‧‧Main light

38‧‧‧第二光瞳表面 38‧‧‧Second optical surface

40‧‧‧屏蔽光閥 40‧‧‧Shielding light valve

42‧‧‧處理器件 42‧‧‧Processing device

44‧‧‧處理頭 44‧‧‧Processing head

46‧‧‧移動器件 46‧‧‧Mobile devices

47‧‧‧支撐結構 47‧‧‧Support structure

48‧‧‧伸縮臂 48‧‧‧ telescopic arm

50‧‧‧樞轉器件 50‧‧‧ pivoting device

52‧‧‧馬達操作的XY移動平台 52‧‧‧Motor operated XY mobile platform

54‧‧‧反射鏡基板 54‧‧‧Mirror substrate

56‧‧‧光學區域 56‧‧‧Optical area

58‧‧‧反射塗層 58‧‧‧Reflective coating

60‧‧‧薄層 60‧‧‧ thin layer

62‧‧‧周圍區域 62‧‧‧ surrounding area

64‧‧‧背面區域 64‧‧‧Back area

65‧‧‧電子束 65‧‧‧Electron beam

66‧‧‧變形 66‧‧‧ deformation

68‧‧‧光通道 68‧‧‧Light channel

70‧‧‧存取通道 70‧‧‧Access channel

71‧‧‧外部空間 71‧‧‧External space

72‧‧‧樞轉擋板 72‧‧‧ pivoting baffle

74‧‧‧封閉外蓋 74‧‧‧Closed cover

78‧‧‧底座 78‧‧‧Base

80‧‧‧引導元件 80‧‧‧Guide elements

82‧‧‧引導孔 82‧‧‧ Guide hole

85‧‧‧定位偵測器件 85‧‧‧ Position Detection Device

86‧‧‧光發射器件 86‧‧‧Light emitting device

88a、88b、88c‧‧‧光接收單元 88a, 88b, 88c‧‧‧ light receiving unit

d‧‧‧處理距離 d‧‧‧Processing distance

M1-M6‧‧‧反射鏡 M1-M6‧‧‧Mirror

OA‧‧‧光軸 OA‧‧‧ optical axis

從以下參考圖式之具體實施例的說明,將明白本發明的更多特徵及優點,其中:圖1顯示根據本發明之EUV投射曝光裝置的示意透視圖;圖2根據第一具體實施例顯示圖1所示投射曝光裝置之透鏡的縱剖面,處理頭處於非啟用定位中;圖3顯示圖2的縱剖面,處理頭處於啟用定位中;圖4a至4c顯示透鏡中含有之校正反射鏡在用處理射束處理之前、期間及之後的剖面;圖5根據第二具體實施例顯示圖1所示投射曝光裝置之透鏡之一部分的縱剖面,處理頭位在透鏡外;圖6顯示圖5的縱剖面,處理頭位在透鏡內;圖7顯示列出根據本發明之方法之重要步驟的流程圖。 Further features and advantages of the present invention will become apparent from the following description of the embodiments of the invention, wherein: FIG. 1 shows a schematic perspective view of an EUV projection exposure apparatus according to the present invention; FIG. 2 shows according to the first embodiment. Figure 1 shows a longitudinal section of the lens of the projection exposure apparatus, the processing head is in a non-enabled positioning; Figure 3 shows the longitudinal section of Figure 2, the processing head is in the activated position; Figures 4a to 4c show the correction mirror contained in the lens FIG. 5 shows a longitudinal section of a portion of the lens of the projection exposure apparatus of FIG. 1 according to the second embodiment, the processing head position is outside the lens; FIG. 6 shows the position of the processing head in FIG. In the longitudinal section, the processing head position is within the lens; Figure 7 shows a flow chart listing the important steps of the method according to the invention.

1.投射曝光裝置的基本構造 1. The basic structure of the projection exposure device

圖1以未按比例的高度示意透視圖顯示根據本發明之微影投射曝光裝置的基本構造,該裝置整體指定為10。投射曝光裝置10用以將配置在遮罩14在圖1中面向下之一側上的反射結構12投射至感光層16。感光層16(特定而言,可為光阻,又叫做抗蝕劑)由晶圓18或某個其他基板承載。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 shows a basic configuration of a lithographic projection exposure apparatus according to the present invention, which is designated as 10 in a highly schematic perspective view, not to scale. The projection exposure apparatus 10 is for projecting the reflective structure 12 disposed on the side of the mask 14 on the lower side in FIG. 1 to the photosensitive layer 16. Photosensitive layer 16 (specifically, a photoresist, also known as a resist) is carried by wafer 18 or some other substrate.

投射曝光裝置10包含照射系統20,其以EUV光22照射遮罩14設有結構12的那一側。特定而言,在5nm及30nm之間的範圍適合作為EUV光22的波長;在所圖解的本具體實施例中,EUV光22的中心波長約13.5nm。EUV光22照射遮罩14之面向下側上的照射場24,該照射場在所圖解的具體實施例中具有環形段的幾何形狀。 The projection exposure apparatus 10 includes an illumination system 20 that illuminates the side of the mask 14 with the structure 12 with EUV light 22. In particular, a range between 5 nm and 30 nm is suitable as the wavelength of the EUV light 22; in the illustrated embodiment, the EUV light 22 has a center wavelength of about 13.5 nm. The EUV light 22 illuminates the illumination field 24 on the downward facing side of the mask 14, which in the illustrated embodiment has the geometry of the annular segment.

投射曝光裝置10另外包含透鏡26,其在感光層16上產生結構12位在照射場24之區中的縮小影像24’。透鏡26具有光軸OA,其與環形段形狀的照射場24的對稱軸重合且因此位在照射場24之外。 The projection exposure apparatus 10 additionally includes a lens 26 that produces a reduced image 24' of the structure 12 in the region of the illumination field 24 on the photosensitive layer 16. The lens 26 has an optical axis OA which coincides with the axis of symmetry of the illumination field 24 of the annular segment shape and is therefore located outside the illumination field 24.

透鏡26係設計用於掃描操作,其中在感光層16的曝光期間,遮罩14與晶圓18同步移動。圖1中以箭頭A1、A2指示遮罩14及晶圓18的此等行進移動。因此,在感光層16曝光期間,照射場24以類似掃描器的方式在遮罩14上掃過,因而可將相對較大的連續結構區投射於感光層16上。遮罩14及晶圓18移動的速度比在此情況中等於透鏡26的成像比例β。在所圖解的具體實施例中,由透鏡26產生的影像24’縮小(|β|<1)且為正像(β>0),為此之故,晶圓18移動得比遮罩14慢,但是方向相同。 Lens 26 is designed for scanning operations in which mask 14 moves synchronously with wafer 18 during exposure of photosensitive layer 16. These movements of the mask 14 and the wafer 18 are indicated by arrows A1, A2 in FIG. Thus, during exposure of the photosensitive layer 16, the illumination field 24 is swept across the mask 14 in a scanner-like manner so that a relatively large continuous structural region can be projected onto the photosensitive layer 16. The speed at which the mask 14 and the wafer 18 move is greater than the imaging ratio β of the lens 26 in this case. In the illustrated embodiment, the image 24' produced by the lens 26 is reduced (|β|<1) and is a positive image (β>0), for which reason the wafer 18 moves slower than the mask 14. , but in the same direction.

光束從照射場24(位在透鏡26的物體平面中)中的各點發出,該等光束進入透鏡26。透鏡26具有以下效應:進入光束在各場點處會聚在透鏡26的影像平面中。光束從物體平面中發出的場點、及該等光束在影像平面中再次會聚的場點彼此在此情況中處於指定為光學共軛的關係。 The beams are emitted from points in the illumination field 24 (located in the object plane of the lens 26) that enter the lens 26. Lens 26 has the effect that the incoming beam converges in the image plane of lens 26 at each field point. The field points emitted by the beam from the plane of the object, and the field points at which the beams converge again in the image plane, in this case are in a relationship designated as optically conjugate.

對於在照射場24中心的個別點,以28示意性指示及標示此光束。在此情況中,光束28進入透鏡26時的孔徑角是透 鏡之數值孔徑NA的度量單位。由於成像縮小之故,透鏡26的影像側數值孔徑NA按成像比例β的倒數放大。 For individual points at the center of the illumination field 24, the beam is schematically indicated and labeled at 28. In this case, the aperture angle of the beam 28 when entering the lens 26 is The unit of measure of the numerical aperture NA of the mirror. Due to the reduction in imaging, the image side numerical aperture NA of the lens 26 is magnified by the reciprocal of the imaging ratio β.

圖2同樣以示意性且未按比例的縱剖面顯示透鏡26的重要組件。在30所示的物體平面及32所示的影像平面之間,沿著光軸OA配置總共6個反射鏡M1至M6。從物體平面30中的一點發出的光束28首先撞擊在凹面第一反射鏡M1上,向後反射到凸面第二反射鏡M2上,撞擊在凹面第三反射鏡M3上,向後反射到凹面第四反射鏡M4上及接著撞擊在凸面第五反射鏡M5上,凸面第五反射鏡M5將EUV光向後引到凹面第六反射鏡M6上。凹面第六反射鏡M6最後將光束28聚焦至影像平面32中的共軛影像點中。 Figure 2 also shows important components of the lens 26 in a schematic and not to scale longitudinal section. A total of six mirrors M1 to M6 are arranged along the optical axis OA between the object plane shown at 30 and the image plane shown at 32. The light beam 28 emitted from a point in the object plane 30 first impinges on the concave first mirror M1, is reflected back onto the convex second mirror M2, impinges on the concave third mirror M3, and reflects backward to the concave fourth reflection. The mirror M4 and then the impact on the convex fifth mirror M5, the convex fifth mirror M5 leads the EUV light back to the concave sixth mirror M6. The concave sixth mirror M6 finally focuses the beam 28 into the conjugate image points in the image plane 32.

如果以圖2中的虛線所示部分增補反射鏡M1至M6,則因此增補之反射鏡的反射表面將相對於透鏡26的光軸OA為旋轉對稱。但是,如可輕易看出,由於反射鏡將部分阻擋光路徑,故無法以此完全旋轉對稱的反射鏡實現上述光束路徑。因此,反射鏡M1至M6具有實線所示的形狀。 If the mirrors M1 to M6 are partially supplemented as indicated by the broken line in Fig. 2, the reflecting surface of the supplemental mirror will therefore be rotationally symmetric with respect to the optical axis OA of the lens 26. However, as can be readily seen, since the mirror will partially block the light path, the beam path cannot be achieved with this fully rotationally symmetric mirror. Therefore, the mirrors M1 to M6 have a shape indicated by a solid line.

透鏡26具有第一光瞳表面34,其位在第二反射鏡M2的表面中或與其直接接近。藉由以下事實辨認光瞳表面:從物體平面30中的點發出之光束的主光線與光軸OA相交。這在圖2中針對光束28的主光線36顯示,該主光線以虛線形式指示。 The lens 26 has a first pupil surface 34 that is located in or directly adjacent to the surface of the second mirror M2. The pupil surface is identified by the fact that the chief ray of the light beam emitted from the point in the object plane 30 intersects the optical axis OA. This is shown in Figure 2 for the chief ray 36 of the beam 28, which is indicated in dashed lines.

第二光瞳表面38位在第五反射鏡M5及第六反射鏡M6之間的光束路徑中,其中從第二光瞳表面38到這兩個反射鏡M5、M6的距離相對較大。屏蔽光閥40配置在第二光瞳表面38的水平面處。 The second pupil surface 38 is located in the beam path between the fifth mirror M5 and the sixth mirror M6, wherein the distance from the second pupil surface 38 to the two mirrors M5, M6 is relatively large. The shielded light valve 40 is disposed at a level of the second diaphragm surface 38.

2.處理器件 2. Processing device

處理器件42配置在透鏡26中,該處理器件包含處理 頭44及用於移動處理頭44的移動器件46。在所圖解的具體實施例中,處理器件42永久地固定於透鏡26的支撐結構47。除了別的之外,支撐結構47還承載反射鏡M1至M6及冷卻器件及調整操縱器,在圖2中僅以其外輪廓示意性指示該支撐結構。 Processing device 42 is disposed in lens 26, which includes processing Head 44 and mobile device 46 for moving processing head 44. In the illustrated embodiment, the processing device 42 is permanently affixed to the support structure 47 of the lens 26. The support structure 47 carries, among other things, mirrors M1 to M6 and cooling means and adjustment manipulators, which are schematically indicated in Fig. 2 only by their outer contours.

移動器件46使處理頭44可相對於支撐結構47移動,且因此使其相對於固定於該支撐結構的反射鏡M1至M6移動。在所圖解的具體實施例中,移動器件46包含在其自由端支撐樞轉器件50的伸縮臂48。借助樞轉器件50,處理頭44可以馬達操作的方式繞著兩個正交軸樞轉。在伸縮臂48與處理頭44相對的末端處,伸縮臂48固定於馬達操作的XY移動平台52,伸縮臂48與固定在末端的處理頭44可借助移動平台52沿著兩個正交方向平移移動。移動器件46能夠以此方式引導處理頭44靠近反射鏡M2及M3之反射表面的不同位置,如圖3中關於第二反射鏡M2以實線顯示及關於第三反射鏡M3以虛線顯示。 The moving device 46 allows the processing head 44 to move relative to the support structure 47 and thus move relative to the mirrors Ml through M6 secured to the support structure. In the illustrated embodiment, the moving device 46 includes a telescoping arm 48 that supports the pivoting device 50 at its free end. With the pivoting device 50, the processing head 44 can be pivoted about two orthogonal axes in a motor operated manner. At the end of the telescoping arm 48 opposite the processing head 44, the telescoping arm 48 is secured to a motor operated XY moving platform 52, and the telescoping arm 48 and the fixed end processing head 44 are translatable in two orthogonal directions by means of the moving platform 52. mobile. The moving device 46 can guide the processing head 44 to different positions of the reflecting surfaces of the mirrors M2 and M3 in this manner, as shown in FIG. 3 with respect to the second mirror M2 in solid lines and with respect to the third mirror M3 in broken lines.

為了結構空間的理由,便利的是不在圖2及3所示透鏡26的縱向面而是在與其垂直的矢狀面中配置處理器件42。此外,完全不同的設計亦適合用於移動器件,只要這些設計適於將處理頭遞送到透鏡26之反射鏡M1至M6中的至少一個。 For reasons of structural space, it is convenient not to arrange the processing device 42 in the longitudinal plane of the lens 26 shown in Figures 2 and 3 but in the sagittal plane perpendicular thereto. Moreover, completely different designs are also suitable for use in mobile devices, as long as these designs are suitable for delivering the processing head to at least one of the mirrors Ml through M6 of the lens 26.

在所圖解的具體實施例中,處理頭44含有本身即為習用的電子槍,諸如用在例如X射線源中的電子槍。此類電子槍通常包含:電子源,如,白熾陰極;Wehnelt圓柱;及加速陽極,以加速由白熾陰極釋出的電子。由處理頭44發射之電子的能量較佳在5keV及80keV之間、及尤其在40keV及50keV之間的範圍中。除了別的之外,所發射的電子理想上應具有的能量還取決於組成反射鏡M2、M3之基板的材料。 In the illustrated embodiment, the processing head 44 contains an electron gun that is a conventional one, such as an electron gun used in, for example, an X-ray source. Such electron guns typically include an electron source such as an incandescent cathode, a Wehnelt cylinder, and an accelerating anode to accelerate electrons released by the incandescent cathode. The energy of the electrons emitted by the processing head 44 is preferably between 5 keV and 80 keV, and especially between 40 keV and 50 keV. The energy that the emitted electrons should ideally have, among other things, also depend on the materials of the substrates that make up the mirrors M2, M3.

作為電子槍的替代,處理頭44亦可含有較佳以脈衝 方式操作的雷射,或來自此雷射的光所耦合之光纖的光出射窗。雷射應產生中心波長在0.3μm及3μm之間及脈衝能量在0.01μJ及10μJ之間的光;重複率應在1Hz及100MHz之間。 As an alternative to the electron gun, the processing head 44 may also preferably contain pulses A laser that operates in a manner, or a light exit window of an optical fiber to which the light from the laser is coupled. The laser should produce light with a center wavelength between 0.3 μm and 3 μm and a pulse energy between 0.01 μJ and 10 μJ; the repetition rate should be between 1 Hz and 100 MHz.

3.功能 3. Function

以下參考圖3及4解說透鏡26及處理器件42的功能。 The function of the lens 26 and the processing device 42 will be explained below with reference to Figs.

首先,組裝及調整透鏡26。在調整的背景下,一般反覆量測透鏡26的成像性質。舉例而言,這可以其本身即為已知的方式來完成:以干涉儀決定透鏡26之影像平面32中的光波前。在調整期間,改變反射鏡M1至M6的定位致使最小化成像像差。另外,亦可使用操縱器(如果存在),其以有目標的方式使反射鏡M1至M6的一或多個變形,以按此方式減少波前變形。 First, the lens 26 is assembled and adjusted. In the context of adjustment, the imaging properties of lens 26 are typically measured over. For example, this can be done in a manner known per se: the interferometer determines the optical wavefront in the image plane 32 of the lens 26. During the adjustment, changing the positioning of the mirrors M1 to M6 results in minimizing the imaging aberration. Alternatively, a manipulator (if present) can be used which deforms one or more of the mirrors M1 to M6 in a targeted manner to reduce wavefront distortion in this manner.

但是,即使在此相對較複雜調整程序之後,殘餘成像像差有時還是存在,這在對透鏡26的成像性質要求極為嚴格的情況中是無法接受的。該殘餘成像像差通常是短波波前變形,其根據Zernike係數以波前變形的分解中的較高項說明。可以配置在第一光瞳平面34中之第二反射鏡M2的目標後處理減少殘餘成像像差中與場定位無關的作用。後處理的目的是使第二反射鏡M2變形,致使剩餘的殘餘成像像差減少或轉換成長波成像像差,在上述調整程序中可借助其他操縱器校正長波成像像差。 However, even after this relatively complicated adjustment procedure, residual imaging aberrations sometimes exist, which is unacceptable in the case where the imaging properties of the lens 26 are extremely strict. This residual imaging aberration is typically a short wave wavefront deformation, which is illustrated by the higher term in the decomposition of the wavefront deformation according to the Zernike coefficient. The target post-processing of the second mirror M2, which may be configured in the first pupil plane 34, reduces the effect of field positioning independent of residual imaging aberrations. The purpose of the post-processing is to deform the second mirror M2 such that the remaining residual imaging aberration is reduced or converted into a growing wave imaging aberration in which long-wave imaging aberrations can be corrected by means of other manipulators.

圖4a以縱剖面顯示第二反射鏡M2的放大圖。反射鏡M2包含反射鏡基板54,其在所圖解的具體實施例中由特殊玻璃組成,諸如ULE®或Zerodur®。此類玻璃在反射鏡M2的操作溫度下具有較低或等於零的熱膨脹係數,因此其在相對較小溫度變更下不會變形。反射鏡基板54具有準確處理的光學區域 56,其形狀是決定第二反射鏡M2之光學性質的關鍵。光學區域56承載反射塗層58(未按比例圖解),反射塗層58包含多個具有交替折射率的個別薄層60。反射塗層58經設計以反射短波EUV投射光。反射鏡基板54另外具有周圍區域62及背面區域64,這兩個區域不具光學作用但是對第二反射鏡M2的散熱很重要。 Fig. 4a shows an enlarged view of the second mirror M2 in a longitudinal section. Mirror M2 comprises a mirror substrate 54, which in the illustrated embodiment is composed of special glass, such as ULE® or Zerodur®. Such glasses have a coefficient of thermal expansion that is lower or equal to zero at the operating temperature of mirror M2, so that it does not deform under relatively small temperature changes. The mirror substrate 54 has an optical region that is accurately processed 56, the shape of which is the key to determining the optical properties of the second mirror M2. The optical region 56 carries a reflective coating 58 (not to scale) and the reflective coating 58 comprises a plurality of individual thin layers 60 having alternating refractive indices. Reflective coating 58 is designed to reflect short wave EUV projection light. The mirror substrate 54 additionally has a peripheral region 62 and a back region 64 which are not optically active but are important for heat dissipation of the second mirror M2.

圖4b顯示在借助處理器件42的處理操作期間的第二反射鏡M2。在所圖解的處理定位中,處理頭44位在與反射塗層58的處理距離d處,其小於10mm。需要如此短處理距離以使發散電子束65在第二反射鏡M2上產生足夠小的射束點。高能電子在與薄的反射塗層58沒有明顯交互作用的情況下穿透該反射塗層。相反地,在反射鏡基板54中,高能電子被吸收及在此引起反射鏡基板54的局部緊密作用。此緊密作用繼而與光學區域56及所承載之反射塗層58的變形66相關聯,如圖4c所示。此局部變形66產生所要的波前校正及因而改良透鏡26的成像性質。 Figure 4b shows the second mirror M2 during processing operations by means of the processing device 42. In the illustrated process positioning, the processing head 44 is at a processing distance d from the reflective coating 58, which is less than 10 mm. Such a short processing distance is required to cause the diverging electron beam 65 to produce a sufficiently small beam spot on the second mirror M2. The high energy electrons penetrate the reflective coating without significant interaction with the thin reflective coating 58. Conversely, in the mirror substrate 54, high-energy electrons are absorbed and locally cause a close interaction of the mirror substrate 54. This compaction is in turn associated with the optical region 56 and the deformation 66 of the supported reflective coating 58 as shown in Figure 4c. This local deformation 66 produces the desired wavefront correction and thus the imaging properties of the lens 26.

如果要在第二反射鏡M2的複數個位置產生變形66,則借助移動器件46將處理頭44漸進地移動至對應位置。如果處理頭44以一方式(以蜿蜒的方式)沿著移動路徑移動橫越光學區域56,致使在走完移動路徑之後,處理射束65已漸進地處理光學區域56上的二維區,則亦可出現反射鏡基板54之相對較大區的緊密作用。 If a deformation 66 is to be produced at a plurality of positions of the second mirror M2, the processing head 44 is progressively moved to the corresponding position by means of the moving means 46. If the processing head 44 moves across the optical region 56 along the path of movement in a manner (in a meandering manner), the processing beam 65 has progressively processed the two-dimensional region on the optical region 56 after the moving path has been completed, A close effect of the relatively large area of the mirror substrate 54 may also occur.

如果也要校正場相依波前變形,則必須借助處理頭44以上述方式處理近場配置的反射鏡。由於第三反射鏡M3至少配置在光瞳平面34之外,其中可校正的場相依性較小,如圖3中以虛線所示。更適於此做法的是第四反射鏡M4,其配置較 接近中間影像。 If the field dependent wavefront deformation is also corrected, the near field configured mirror must be processed by the processing head 44 in the manner described above. Since the third mirror M3 is disposed at least outside the pupil plane 34, the correctable field dependence is small, as shown by the dashed line in FIG. More suitable for this is the fourth mirror M4, which is more configured. Close to the middle image.

由於處理器件42整合於透鏡26中,因此亦可在投射曝光裝置10啟動之後,毫無問題地針對校正目的實施處理。會有此校正需求的原因是,例如,如果超過特定光強度達相對較長的時間週期,則高能EUV投射光將部分穿透反射鏡M1至M6的反射塗層48及同樣可導致反射鏡基板54的緊密作用。光學區域56與緊密作用相關聯的變形可借助處理器件42利用合適設計的後處理加以補償或至少加以修改,致使可以其他操縱器比較容易地校正剩餘的殘餘成像像差。 Since the processing device 42 is integrated in the lens 26, it is also possible to carry out the processing for the purpose of correction without problems after the projection exposure device 10 is activated. The reason for this correction requirement is that, for example, if a particular light intensity is exceeded for a relatively long period of time, the high energy EUV projection light will partially penetrate the reflective coating 48 of the mirrors M1 to M6 and may also result in a mirror substrate. The close function of 54. The deformation associated with the compaction of the optical region 56 can be compensated or at least modified by the processing device 42 with a post-processing of a suitable design, such that other manipulators can more easily correct the remaining residual imaging aberrations.

4.第二具體實施例 4. Second embodiment

處理器件42在透鏡26中的永久配置可因為各種原因而變得有其困難。首先,由於EUV透鏡26中的光束路徑很複雜,可用結構空間通常有限,致使無法容納額外的裝配件。還有,從成本的觀點來看,處理器件42僅視需要而非永久地配置在透鏡26中會比較有利。 The permanent configuration of the processing device 42 in the lens 26 can become difficult for a variety of reasons. First, because the beam path in the EUV lens 26 is complex, the available construction space is often limited, making it impossible to accommodate additional assemblies. Also, from a cost point of view, it may be advantageous for the processing device 42 to be disposed in the lens 26 only as needed, rather than permanently.

參考圖5及6,以下說明根據本發明之處理器件42的第二具體實施例,其中處理頭44僅視需要而引入透鏡26中。圖5在上方顯示透鏡26的片段,在其支撐反射鏡M1至M6的支撐結構47中形成光通道68,其提供用於使EUV投射光通過。除了光通道68之外,在支撐結構47中形成存取通道70,該存取通道連接光通道68與圍繞透鏡26的外部空間71。在正常投射操作期間,可以樞轉擋板72分開光通道68與存取通道70;此外,提供封閉外蓋74,其隔離存取通道70與外部空間71。 Referring to Figures 5 and 6, a second embodiment of a processing device 42 in accordance with the present invention is illustrated below in which the processing head 44 is incorporated into the lens 26 only as needed. Figure 5 shows a section of the lens 26 on top, forming a light channel 68 in its support structure 47 supporting the mirrors Ml to M6, which is provided for the passage of EUV projection light. In addition to the light tunnel 68, an access channel 70 is formed in the support structure 47 that connects the light tunnel 68 with the outer space 71 surrounding the lens 26. During normal projection operation, the pivoting shutter 72 can be separated from the optical channel 68 and the access channel 70; in addition, a closed outer cover 74 is provided that isolates the access channel 70 from the exterior space 71.

在此具體實施例中,處理器件42(或更明確地說,其移動器件46)係固定於包含引導元件80的底座78。引導元件80對應於在透鏡26之支撐結構47中形成的引導孔82。 In this particular embodiment, the processing device 42 (or more specifically, its moving device 46) is secured to the base 78 that includes the guiding member 80. The guiding element 80 corresponds to a guiding hole 82 formed in the support structure 47 of the lens 26.

如果在初始調整之後或在投射曝光裝置10啟動之後的時間點出現需要第二反射鏡M2之後處理的校正需求,則取下封閉外蓋74及向上轉開樞轉擋板72。存取通道70接著提供在外部空間71及光通道68之間的連續連接。之後,將處理器件42的底座78從外側固定於支撐結構47,使引導元件80嚙合至引導孔82中,如圖6中所示。 If the correction requirement for processing after the second mirror M2 is required after the initial adjustment or at the time point after the projection exposure apparatus 10 is activated, the closing outer cover 74 is removed and the pivoting shutter 72 is turned upward. Access channel 70 then provides a continuous connection between external space 71 and optical channel 68. Thereafter, the base 78 of the processing device 42 is secured to the support structure 47 from the outside, causing the guiding member 80 to engage into the guide hole 82, as shown in FIG.

在下一個步驟,借助移動器件46將處理頭44帶到相對於第二反射鏡M2的所要定位處,及借助處理射束65執行處理。 In the next step, the processing head 44 is brought to the desired position relative to the second mirror M2 by means of the moving device 46, and the processing is performed by means of the processing beam 65.

為了能夠將處理頭準確地定位在第二反射鏡M2的光學區域56上方,在此具體實施例中,處理器件42具有額外的定位偵測器件85,可用定位偵測器件85以高精確性量測處理頭44相對於支撐結構47及因此相對於第二反射鏡M2的定位(即,空間及角座標)。為此目的,定位偵測器件85係設計為包含光發射器件86的μGPS系統,光發射器件86配置在處理頭44上,及從外部光源將光饋送到光發射器件86,及至少三個光接收單元88a、88b、88c在不同位置處固定於支撐結構47。藉由疊加在光接收單元88a、88b、88c接收的光與外部光源所產生的參考光,可以高精確性決定光接收單元88a、88b、88c及光發射器件86之間的距離。以此方式,可以幾微米的精確性量測處理頭44相對於第二反射鏡M2的定位。有關適當μGPS系統的更多細節請見DE 10 2008 003 282 A1。但是,其他量測系統,如,採用三角測量的習用量測系統,亦適合用於定位偵測。 In order to be able to accurately position the processing head above the optical region 56 of the second mirror M2, in this embodiment, the processing device 42 has an additional position detecting device 85 that can be used with a high accuracy The positioning of the processing head 44 relative to the support structure 47 and thus with respect to the second mirror M2 (ie, space and angular coordinates). For this purpose, the position detecting device 85 is designed as a μGPS system including a light emitting device 86 disposed on the processing head 44, and feeding light from the external light source to the light emitting device 86, and at least three lights The receiving units 88a, 88b, 88c are fixed to the support structure 47 at different locations. By superimposing the light received by the light receiving units 88a, 88b, 88c and the reference light generated by the external light source, the distance between the light receiving units 88a, 88b, 88c and the light emitting device 86 can be determined with high accuracy. In this way, the positioning of the processing head 44 relative to the second mirror M2 can be measured with an accuracy of a few microns. More details on the appropriate μGPS system can be found in DE 10 2008 003 282 A1. However, other measurement systems, such as the use of triangulation, are also suitable for position detection.

5.重要的方法步驟 5. Important method steps

在圖7所示流程圖中概述根據本發明之方法的重要步驟。 The important steps of the method according to the invention are outlined in the flow chart shown in FIG.

在第一步驟,從複數個反射鏡M1至M6組裝透鏡26,其中複數個反射鏡中的至少一個是用於校正波前變形的校正反射鏡。 In a first step, the lens 26 is assembled from a plurality of mirrors M1 to M6, wherein at least one of the plurality of mirrors is a correcting mirror for correcting wavefront distortion.

之後,在步驟S2,調整該等反射鏡。 Thereafter, in step S2, the mirrors are adjusted.

在後續步驟S3,用處理射束處理校正反射鏡的區域,藉此校正反射鏡的形狀永久地變更。在此情況中,處理射束在處理校正反射鏡之前未撞擊在其他複數個反射鏡的任一者上。此外,在步驟S2之後,未從透鏡移除任何反射鏡。 At a subsequent step S3, the area of the correction mirror is corrected by the processing beam, whereby the shape of the correction mirror is permanently changed. In this case, the processing beam does not impinge on any of the other plurality of mirrors before processing the correcting mirror. Furthermore, after step S2, no mirrors are removed from the lens.

26‧‧‧透鏡 26‧‧‧ lens

44‧‧‧處理頭 44‧‧‧Processing head

47‧‧‧支撐結構 47‧‧‧Support structure

48‧‧‧伸縮臂 48‧‧‧ telescopic arm

50‧‧‧樞轉器件 50‧‧‧ pivoting device

68‧‧‧光通道 68‧‧‧Light channel

70‧‧‧存取通道 70‧‧‧Access channel

71‧‧‧外部空間 71‧‧‧External space

72‧‧‧樞轉擋板 72‧‧‧ pivoting baffle

78‧‧‧底座 78‧‧‧Base

82‧‧‧引導孔 82‧‧‧ Guide hole

85‧‧‧定位偵測器件 85‧‧‧ Position Detection Device

86‧‧‧光發射器件 86‧‧‧Light emitting device

88a、88b、88c‧‧‧光接收單元 88a, 88b, 88c‧‧‧ light receiving unit

M1-M4‧‧‧反射鏡 M1-M4‧‧‧Mirror

Claims (15)

一種用於將一反射遮罩(14)投射於一感光層(16)上的微影投射曝光裝置(10),包含a)一反射透鏡(26),包含組態用於反射一中心波長在5nm及30nm之間的投射光的複數個互相調整的反射鏡(M1至M6),其中該透鏡(26)經組態以將反射自該遮罩(14)的投射光引到該感光層(16)上,及其中該複數個反射鏡中的至少一個(M2、M3)係一用於校正波前變形的校正反射鏡,該校正反射鏡在用一處理射束(65)處理時永久地變更其形狀;b)一處理器件(42),包含一處理頭(44),該處理射束(65)在該處理頭操作期間從該處理頭出現,其中該處理頭係配置在或可配置在該透鏡(26)內,致使該處理射束(65)在處理該校正反射鏡(M2、M3)之前未撞擊在該其他複數個反射鏡的任一者上。 A lithographic projection exposure apparatus (10) for projecting a reflective mask (14) onto a photosensitive layer (16), comprising a) a reflective lens (26) comprising a configuration for reflecting a center wavelength a plurality of mutually adjusted mirrors (M1 to M6) of projected light between 5 nm and 30 nm, wherein the lens (26) is configured to direct projected light reflected from the mask (14) to the photosensitive layer ( 16) above, and at least one of the plurality of mirrors (M2, M3) is a correcting mirror for correcting wavefront distortion, the correcting mirror being permanently processed by a processing beam (65) Changing its shape; b) a processing device (42) comprising a processing head (44) from which the processing beam (65) appears during operation of the processing head, wherein the processing head is configured or configurable Within the lens (26), the processing beam (65) is caused not to impinge on any of the other plurality of mirrors prior to processing the correction mirrors (M2, M3). 如申請專利範圍第1項所述之微影投射曝光裝置,其中該校正反射鏡(M2、M3)在該透鏡(26)的光束路徑中既非第一也非最後反射鏡。 The lithographic projection exposure apparatus of claim 1, wherein the correction mirrors (M2, M3) are neither the first nor the last mirror in the beam path of the lens (26). 如申請專利範圍第1或2項所述之微影投射曝光裝置,其中該處理器件包含一移動器件(46),其經組態以移動該透鏡(26)中的該處理頭(44)橫越該校正反射鏡(M2、M3)的一區域。 The lithographic projection exposure apparatus of claim 1 or 2, wherein the processing device comprises a moving device (46) configured to move the processing head (44) in the lens (26) An area of the correction mirror (M2, M3) is corrected. 如申請專利範圍第3項所述之微影投射曝光裝置,其中該移動器件(46)經組態以移動該處理頭(44)橫越該校正反射鏡(M2、M3)的該區域,致使在用該處理射束處理該校正反射鏡 期間,在該處理頭(44)及該區域之間的距離(d)不超過一最大處理距離10mm。 The lithographic projection exposure apparatus of claim 3, wherein the moving device (46) is configured to move the processing head (44) across the area of the correction mirror (M2, M3), such that Processing the correction mirror with the processing beam During this period, the distance (d) between the processing head (44) and the region does not exceed a maximum processing distance of 10 mm. 如申請專利範圍前述任一項所述之微影投射曝光裝置,其中該處理頭(44)永久地配置在該透鏡(26)中。 A lithographic projection exposure apparatus according to any of the preceding claims, wherein the processing head (44) is permanently disposed in the lens (26). 如申請專利範圍第1至4項中任一項所述之微影投射曝光裝置,其中該透鏡(26)具有用於支撐該複數個反射鏡(M1至M6)的一支撐結構(47),一存取通道(70)形成在該支撐結構中,及其中該處理頭(44)可透過該存取通道(70)引入該透鏡(26)中。 The lithographic projection exposure apparatus according to any one of claims 1 to 4, wherein the lens (26) has a support structure (47) for supporting the plurality of mirrors (M1 to M6), An access channel (70) is formed in the support structure, and wherein the processing head (44) is introduced into the lens (26) through the access channel (70). 如申請專利範圍第3或4項及第6項所述之微影投射曝光裝置,其中該處理頭(44)在引入該透鏡(26)中時由該移動器件(46)固持,及其中該移動器件(46)的至少一部分延伸通過該存取通道(70)。 The lithographic projection exposure apparatus of claim 3, wherein the processing head (44) is held by the moving device (46) when introduced into the lens (26), and wherein At least a portion of the mobile device (46) extends through the access channel (70). 如申請專利範圍第6或7項所述之微影投射曝光裝置,其中用於使該投射光通過的一光通道(68)另外形成於該支撐結構(47)中,該光通道與該存取通道(70)不同。 The lithographic projection exposure apparatus of claim 6 or 7, wherein an optical channel (68) for passing the projection light is additionally formed in the support structure (47), the optical channel and the memory Take the channel (70) differently. 如申請專利範圍前述任一項所述之微影投射曝光裝置,其中該處理射束(65)係一電子束或一光束。 The lithographic projection exposure apparatus of any of the preceding claims, wherein the processing beam (65) is an electron beam or a light beam. 如申請專利範圍前述任一項所述之微影投射曝光裝置,包含一定位偵測器件(85),其經組態以偵測該處理頭(44)在處理期間相對於該校正反射鏡(M2、M3)的定位。 The lithographic projection exposure apparatus of any of the preceding claims, comprising a position detecting device (85) configured to detect the processing head (44) relative to the correcting mirror during processing ( Positioning of M2, M3). 一種用於改變一微影投射曝光裝置(10)之一反射透鏡(26)中光波前的方法,其中該方法包含以下步驟: a)從複數個反射鏡(M1至M6)組裝該反射透鏡(26),其中該複數個反射鏡中的至少一個係一用於校正波前變形的校正反射鏡(M2、M3);b)調整該等反射鏡(M1至M6);c)用一處理射束(65)處理該校正反射鏡的一區域,藉此該校正反射鏡(M2、M3)的形狀永久地變更,及其中該處理射束(65)在處理該校正反射鏡之前未撞擊在該其他複數個反射鏡的任一者上;其中在步驟b)及c)之間未從該透鏡移除任何反射鏡。 A method for changing a light wavefront in a reflective lens (26) of a lithographic projection exposure apparatus (10), wherein the method comprises the steps of: a) assembling the reflective lens (26) from a plurality of mirrors (M1 to M6), wherein at least one of the plurality of mirrors is a correcting mirror (M2, M3) for correcting wavefront distortion; b) Adjusting the mirrors (M1 to M6); c) processing a region of the correcting mirror with a processing beam (65), whereby the shape of the correcting mirror (M2, M3) is permanently changed, and The processing beam (65) does not impinge on any of the other plurality of mirrors prior to processing the correction mirror; wherein no mirrors are removed from the lens between steps b) and c). 如申請專利範圍第11項所述之方法,其中一發射該處理射束的處理頭(44)在步驟c)期間移動橫越該校正反射鏡(M2、M3)的該區域,致使在用該處理射束處理該校正反射鏡期間,在該處理頭及該區域之間的距離(d)不超過一最大處理距離10mm。 The method of claim 11, wherein a processing head (44) that emits the processing beam moves across the area of the correcting mirror (M2, M3) during step c), thereby causing the During processing of the correction beam, the distance (d) between the processing head and the region does not exceed a maximum processing distance of 10 mm. 如申請專利範圍第11或12項所述之方法,其中該處理頭(44)僅在一處理期間位在該透鏡(26)中。 The method of claim 11 or 12, wherein the processing head (44) is located in the lens (26) only during a process. 如申請專利範圍第11或12項所述之方法,其中該處理頭(44)在處理之前透過一存取通道(70)引入該透鏡中,該存取通道提供於經組態以支撐該等反射鏡(M1至M6)的一支撐結構(47)中。 The method of claim 11 or 12, wherein the processing head (44) is introduced into the lens through an access channel (70) prior to processing, the access channel being provided to be configured to support the A support structure (47) of the mirrors (M1 to M6). 如申請專利範圍第12至14項中任一項所述之方法,其中偵測該處理頭(44)在處理期間相對於該校正反射鏡(M2、M3)的定位。 The method of any of claims 12-14, wherein the positioning of the processing head (44) relative to the correction mirror (M2, M3) during processing is detected.
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