TW201202409A - Detergent composition for dishwashing by hand - Google Patents

Abstract

Disclosed is a detergent composition for dishwashing by hand which comprises (a) a sulfosuccinic acid di- or monoalkyl ester represented by general formula (1) or (1') or a salt of the ester, (b) 1-50 mass% anionic surfactant (excluding (a)) comprising a C8-21 hydrocarbon group and either a sulfuric ester base or a sulfonic acid base, and (c) an ingredient which is (c1) a C10-18 fatty acid or a salt thereof and/or (c2) an alkyl glyceryl ether in which the alkyl group has 6-18 carbon atoms, wherein the (c)/(a) mass ratio is 0.001-11, and when the ingredient (c) is a C10-18 fatty acid or a salt thereof, then the (b)/[(a)+(c)] mass ratio is 0.01-10.

Description

201202409 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a hand-washing food detergent composition. [Prior Art] The hand-washing device detergent requires a sufficient amount of foaming and continuation of the foam during washing. This foaming/bubble persistence is a non-important physical property relating to the continuation of the rinsing property, and has been developed mainly for the development of a detergent having excellent foaming property. In Japanese Patent Laid-Open Publication No. SHO 62-215699, a technique of a detergent containing a sulfo-succinic acid-divalent surfactant and having a high foaming property and excellent detergency is suitable for use in detergent cleaning. The technique of a food detergent composition containing a sulfosuccinate diacetin surfactant and another anionic surfactant is disclosed in Japanese Patent Laid-Open No. Hei 8-50761, which is described in the detailed description. Contains fatty acids as an adjuvant. A foaming inhibitor which can use a fatty acid as a liquid lotion composition which can use an alcohol ester of a (iv)ylsuccinyl salt as an anionic surfactant can be described in Japanese Patent Laid-Open No. Hei-3-207799. Further, a liquid detergent composition containing an anionic surfactant, an amine oxide type surfactant, and a 2-ethylhexyl monoglyceride slit is described in Japanese Patent Laid-Open Publication No. Hei. Further, Japanese Patent Laid-Open Publication No. 69 discloses a liquid detergent composition containing an anionic surfactant, a sedative salt, and a higher fatty acid or a salt thereof. SUMMARY OF THE INVENTION 155204.doc 201202409 The present invention relates to a hand-washing food detergent composition, which is contained. (4) by the following general formula (1) or (cutting table to succinct (four) two / monofilament vinegar or its salt [ Hereinafter, it is referred to as (4) component]; (b) an anionic surfactant having a carbon number of 8 to 21, a sulfuric acid-based salt or a sulfate-based acid group [wherein (4) is = outside] [hereinafter referred to as (b) Component] U0 mass α and (4) a fatty acid having 1 to 18 carbon atoms or a salt thereof, or a calcined glycerin scale having a carbon number of 6 to 18 (hereinafter referred to as component (4)); In the case of 10 to 18 fatty acids or strontium salts, '(8)/[(4) valence f ratio is QQ, and the mass ratio of (4)/(4) is 0.001 to 11. [Chemical 1] R ~ (OA) X-〇COCH2CHCO〇 — (a2〇) —r2 so3m (1)

R^OCOCHaCHCOO-RZ S03M (1') [wherein, Ri and R2 are each an alkyl group having a carbon number of 5 to 18 or a hydrogen atom, and at least one of R1 and R2 is a hospital having a carbon number of 5 to 18; . v and 八2 are respectively independent carbonization bases of 2 to 4, x and y are the average addition mole numbers and are independently 06 and X y is not 0 at the same time. μ is an inorganic or organic cation. Further, the present invention relates to a method for cleaning a foodstuff by washing the food by hand using the washing liquid of the hand-washing detergent composition of the present invention described above, and then rinsing with water. The present invention comprises a hand-washing detergent composition comprising: (4) di/monoalkyl sulfosuccinate or a salt thereof (carbon number of one alkyl group is 5 to 18); 155204.doc 201202409 (b An anionic surfactant having a hydrocarbon group having a carbon number of 8 to 2 Å, a sulfate group or a sulfonate group (excluding (a) 1 to 50% by mass; and (c) a carbon number of 10 to 18) The fatty acid or a salt thereof; the mass ratio of (8) / [(4) + (c)] is 0·01 10 10 ' and the mass ratio of (cV (a) is 0.001 to 11. The present invention includes a hand washing detergent combination And comprising: (a) a di/monoalkyl sulfosuccinate or a salt thereof (the carbon number of one alkyl group is 5 to 18); (b) a hydrocarbon group having a carbon number of 8 to 21, and a sulfate a salt- or sulfonate-based anionic surfactant [excluding (a)]; and (c) a pyridyl glycerin having a carbon number of 6 to 18. [Embodiment] In recent years, the environment has been lightened. For the purpose of load and effective use of water resources, it is preferable to reduce the amount of water used in hand washing and washing, and it is desirable to minimize the flushing water after washing with the detergent. However, in general, A detergent having excellent foaming property/bubble persistence requires a large amount of water to complete the rinsing. Therefore, it is strongly required to exhibit rich foaming and foam persistence during washing, but the bubble disappears instantaneously during rinsing. A hand-washing detergent for rinsing with a small amount of water. In this respect, the defoaming during rinsing is disclosed in Japanese Patent Laid-Open No. 215-699, Japanese Patent Laid-Open No. Hei. No. Hei. In addition, as a "foaming inhibitor", the fatty acid as an antifoaming agent is used as a "foaming inhibitor" in this patent, and the purpose is to achieve low foaming property during washing, and There is no suggestion that the technique of continuously forming a very rich bubble during washing is associated with the technique of instantaneous defoaming during rinsing. / Again, it is generally believed that the completion of the rinsing is defoaming and the point slip of the food is eliminated 155204. Doc 201202409 is lost. However, the detergent with excellent foaming/bubble persistence is poor in defoaming property and the food is always sticky. Therefore, a large amount of water is required to complete the flushing. Therefore, it is strongly sought to be displayed during washing. Bubble and bubble A hand-washing detergent that is continually viscous, but which is viscous and rinsed with a small amount of water during rinsing. In this respect, 'Japanese Patent Laid-Open No. 62_215699 and Japanese Patent Special Table 20〇8_5() In 7611, there is no consideration for the improvement of the viscous sensation during rinsing. Japanese Patent Unexamined 3_99 is a technique for improving the viscous and rinsing properties. However, in recent years, the purpose of reducing environmental load and utilizing water resources effectively has been achieved. 'Requires i to use a small amount of water to inhibit stick-slip.' The technique of rinsing is completed. From this point of view, further improvement is desired. Therefore, the present invention provides a blistering of foaming and washing during display. Sexually, but when washed, the bubble disappears in an instant and the hand-washing detergent is rinsed with a small amount of water, and/or provides a kind of blistering when washing, but the viscous slip disappears in an instant when flushing Wash the hand-washing detergent with a small amount of water. According to the present invention, it is possible to provide a hand-washing detergent which exhibits the persistence of foaming at the time of washing and which is rich in foaming and washing, but which is instantaneously disappeared at the time of washing and is rinsed with a small amount of water. <(a) Component> The component (a) of the present invention is a compound of the following formula (1) or oxime,). [Chemical 2] 155204.doc (1) 201202409 R1-(OA1) x-〇COCH2CHCO〇- (a2〇) -Rj I y so3m R1—〇C〇CH2CHCO〇一R2 (1,)

I

so3M

[wherein, R1 and R2 are each a calcining group or a hydrogen atom having a carbon number of 5 to 18, preferably 5 to 15, more preferably 5 to 13 3, and at least one of Ri and R2 has a carbon number of 5~1 8 burnt base. A1 and A2 are each independently a carbon number of 2 to 4, preferably 2 to 3, and X and y are the average addition molar number and are independently 〇~6 ^, and X and y are different at the same time. Hey. Μ is an inorganic or organic cation. When the component (a) is a dialkyl sulfosuccinate or a salt thereof, R1 and R2 in the formula (1) or (Γ) may be the same or different, and the carbon number is An alkyl group of 5 to 18, preferably 5 to 15, more preferably 5 to 13. When the component (4) is a dialkyl sulfosuccinate represented by the formula (1) or a salt thereof, Ai and a2 are each independently an alkylene group having 2 to 4 carbon atoms, preferably 2 to 3 carbon atoms, x. , y is the average addition of the number of moles and is not 〇 at the same time, and is 〇~6, preferably 〇 or 〇丨~2. Further, Χ+Υ is more preferably 0.1 to 12' and more preferably 0.2 to 4. Further, when the component (4) is a monoalkyl sulfosuccinate or a salt thereof, one of R1 and r2 in the formula (1) or (1) has a carbon number of 5 to 18, preferably 5 to 15, more preferably an alkyl group of 5 to 13, and the other is a hydrogen atom. When the component (4) is a sulfosuccinyl (tetra) monoalkyl ester represented by the formula (1) or a salt thereof, A丨 and A2 are each independently an alkylene group having 2 to 4 carbon atoms, preferably 2 to 3 carbon atoms. x and y are the average addition moles and are not 〇'. Preferably, ~6'. Or (M is small, x + y is preferably 〇 1 to 12, more preferably 0.2 to 4. Preferably, Ri and R 2 are each a carbon number of 5 to 18, preferably Μ, more preferably 5 〜 The succinct group of '13' is the continuation radical 155204.doc 201202409 dialkyl group or its salt. Further, the component (4) is preferably a (4) di/monoalkyl ester represented by the formula (7). Or a salt thereof. In the formula (1) or (Γ), R1 and R2 are each preferably a hexyl group, an octyl group, a decyl group, a decyl group, a dodecanyl group, a tridecyl group, a 2-ethylhexyl group, or an n-octyl group. , a second octyl group, an isopentyl group, an isodecyl group, an isodecyl group, and a cyclohexyl group, and more preferably selected from the group consisting of n-octyl, second octyl, decyl, isodecyl, and 2-ethylhexyl M is an inorganic cation selected from the group consisting of hydrogen ions, nano ions, recorded ions, potassium ions, and cation ions, and an organic cation selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, and hydrazine acid salt, preferably a cation selected from the group consisting of a nano ion, a money ion, a potassium ion, and a magnesium ion. 1 When the component (4) is a carboxylic acid dialkyl vinegar or a salt thereof, the preparation method of the same compound as RW is not particularly For example, it can be produced by the method described in the above-mentioned Patent No. 2,028,091, and the asymmetric compound having different R and R can be produced, for example, by referring to Japanese Patent Laid-Open No. Sho 58-24555. In the case of using a commercially available compound, In the case of Pelex 〇T_p (R, r2, both of which are 2_ethylhexyl), Pdex TR (R1, R> is a LUensit A_B manufactured by the compound company of the thirteenth alkyl group. (Rl, r2 are compounds of 2 ethylhexyl), 1 can be obtained from Mitsui Cytec Co., Ltd. (10). (10) (R1, R2 are compounds of pentyl), and Aer〇s〇1 ai96 (r丨, r2 are all cyclohexyl compounds), etc. It can also be used as a raw material of component (a) by adding a siloxane to a specific carbon number. <(b)Component> I55204.doc 201202409 The component (b) of the present invention is an anionic surfactant having a hydrocarbon group having a carbon number of 8 to 21 and a sulfate group or a sulfonic acid group [excluding the component (a)]. Such an anionic surfactant is known to be foamed. Very excellent, more specifically, an anionic surfactant selected from the following a decyl phthalate salt having a carbon number of 8 to 8 , preferably a carbon number of 8 to 15; an alkyl group having a carbon number of 8 to 18, preferably 8 to 15 carbon atoms and having an alkyl group a polyoxyalkylene ether alkyl sulfate having a carbon number of 2 and/or 3 and an average alkyl group of an alkylene group having a molar number of 0"^ having a carbon number of 8 to 15 An alkyl alkylbenzenesulfonate; and an alkanesulfonate having a carbon number of 8 to 15. The salt is preferably an inorganic salt selected from the group consisting of sodium salt, ammonium salt, potassium salt, and magnesium salt, and An organic amine salt derived from monoethanolamine salt, monoethanolamine salt, diethanolamine salt, and morpholinium salt. The component (b) is preferably a compound of the following formula (2) in terms of foaming property or bubble persistence at the time of washing and defoaming property at the time of washing. R3-0-(R40)n-S03M (2) wherein R3 is an alkyl group having a carbon number of 8 to 18, preferably 8 to 15, and R4 is an ethyl group and/or a stretching group, and η is The average addition molar number is 6 above 6 and the number ' is preferably 0 or more and 2 or less. Μ is an inorganic or organic cation]. When η is in the case where R4 is an ethyl group, it is preferably 15 or less, more preferably 0.3 or more. Further, when nW is a propyl group, it is preferably a number under (10) and further less than U. Further, it is preferably 〇" or more". In the case of "extension" and "extension", η may be selected from the range of the above. In the case of the general formula (2), in the case of the case, the car is preferably a hospital base having a branched structure. The compound of the compound, the compound of the general formula (7) I55204.doc •10·201202409 The object is preferably as follows: • oct 蟪 蟪 〜 〜 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿 儿The ratio of the number of ears is preferably ~1 〇〇 mol%, more preferably 40 〜1 〇〇 mol%, and particularly preferably 7 〇~(10) mol % 〇 is selected from the formula (2) An inorganic cation of a nano ion, a recording ion, an unloading ion, and a town ion, or an organic cation selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, and a salt of a salt, preferably a sodium ion, a money ion, a potassium ion, And a method of preparing the compound of the formula (7), and is not particularly limited. For example, after adding a specific amount of epoxy bromide and/or epoxy propylene to a fatty alcohol represented by R3-0H, Using a gas selected from the group consisting of sulfur trioxide (liquid or gas), sulfur trioxide containing gas, fuming sulfuric acid, and chlorosulfonic acid The acidifying agent is sulfated and produced by neutralization with a specific alkali agent. The addition reaction of the epoxy ethene (hereinafter referred to as Ε0) and/or propylene propylene (hereinafter referred to as ρ〇) requires a catalyst. In addition, it is possible to use (4) a salt test, a bribe, etc., and a catalyst having an oxidation lock as a main component as described in Japanese Patent Laid-Open No. Hei. Polyoxyethylene thinning test, the latter can obtain a compound having a relatively narrow additive molar distribution. Further, it can be oxidized by using a combination of a catalytic catalyst and a metal as disclosed in Japanese Patent Laid-Open No. 58384. Controlling the addition of the molar distribution by the catalyst. The field is obtained by the formula (2) f η is 〇 when it contains the preferred rule 3 and has a branched structure The alcohol to be represented is an alcohol obtained by waking up a hydrogen group with a carbon number of 8 to 14 (containing an alkyl group having an alkyl group at the β-position relative to the OH group). 15~7〇莫耳%); After the condensation of the aldehyde having a carbon number of 4~8, the reduction is obtained. a Guerbet type alcohol (100 mol% of a structure having an alkyl group having a carbon number of 3 to 6 branched at the p-position with respect to the hydrazine H group); hydrogenation of the isobutylene dimer 3,5,5-dimercaptohexanol obtained; multi-branched triterpene alcohol obtained by hydroquinonement of a terpolymer of isobutylene (branche rate of 1 〇〇 mol%); a synthetic alcohol having a coal content as a raw material (a branching ratio of about 2 〇 to 1 〇〇 mol% of a burnt group). In the present invention, as the component (b), a compound represented by the formula (2) is preferably used. Further, R4 is a compound in which propyl group is 伸2 to 丨〇, and further 〇4 to 〇8. <(C) component> The component (C) of the present invention (c) has a carbon number of 1 The fatty acid of 〇18 or its salt or the alkyl glyceryl ether of the (C2) alkyl group having a carbon number of 6 to 18. In the case where the quinone component is the component (cl), specific examples thereof include citric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, linoleic acid, and linoleic acid. As the salt U', a mixed fatty acid such as a coconut fatty acid may be used. Examples of the salt of the fatty acid include inorganic salts selected from the group consisting of sodium salts, ammonium salts, potassium salts, and magnesium salts, and are selected from monoethanolamine salts and diethanolamine salts. An organic amine salt such as a triethanolamine salt or a minophenate salt, preferably a sodium salt, an ammonium salt, a potassium salt, and a magnesium salt, more preferably a sodium salt, an ammonium salt, or a potassium salt. More preferably as the component (4). It is lauric acid, myristic acid, palmitic acid or the like, and particularly preferably lauric acid, myristic acid or the like, preferably myristic acid or a salt thereof. Therefore, foaming power and defoaming From the viewpoint of sex, it is preferred that the component (c) 155204.doc •12·201202409 contains myristic acid or a salt thereof, and the component (4) is preferably 30 to 100% by mass of the nutrient acid or a salt thereof. More preferably, it is 5 〇 1 〇〇 1 〇〇 〇 /., especially preferably 80 〜 100 mass. / (4) component of the present invention The carbon number of the base is 6 to 18', and the alkyl glyceryl ether is preferably a compound of the following formula (3). R5-〇-(Gly)rH (3) Wherein R5 represents an alkyl group having a carbon number of 6 to 18, and Gly represents a residue from which two hydrogen atoms are removed from glycerin, and 1> is an average addition molar number indicating a number of 丨~々.]" In 3), R5 is an alkyl group having a carbon number of 6 to 18, preferably 7 to 12, more preferably 8 to 10, and a straight chain such as a hexyl group, a heptyl group, an octyl group, a decyl group or a fluorenyl group may be used. In the present invention, in view of reducing the stick-slip feeling at the time of rinsing, a compound having a branched structure is preferable, and a specific alkyl group having a branched structure of R5 is more preferably selected from 2_. The group of the ethylhexyl 'second octyl group, the isodecyl group and the isodecyl group is further preferably a 2-ethylhexyl group or an isodecyl group, and particularly preferably a 2-ethylhexyl group. In the formula (3), Preferably, it is a compound of 1 to 2', which is preferably a compound of the formula R, 2-ethylhexyl, and r=l. The structure represented by Gly is derived from glycerin. -CH2CH(〇H)cH2 bonded to the hydroxyl group of the 3 position - the structure represented by - or the structure represented by the glycerol bond with the 2-position of the base group - (: Η ((: Η 2〇Η) (: Η 2 ·), and varies depending on the catalyst and reaction conditions In order to obtain the compound of the formula (3), for example, an alkanol represented by r5-oh may be used as the alcohol having 6 to 10 carbon atoms, and an acid catalyst such as BF3 or an aluminum catalyst may be used. It is produced by reacting with an epoxy compound 155204.doc -13-201202409 such as an alcohol or a glycidol. For example, in the case of using 2-ethylhexanol, the obtained 2-ethylhexyl monoglyceryl ether is as A mixture of a plurality of products may be included as described in the JP-A-2002-49291. <Hand Washing Detergent Composition> The hand-washing detergent composition of the present invention is obtained by using (b) component, (4) component and (with) foaming/bubble persistence under specific conditions. The component (cl) of the 0 component, and the washing water having a relatively high concentration of the detergent exhibits a very high foaming property and bubble persistence, but can be made by adding the rinse water after the washing is finished. It disappears, and the reason for rinsing with a small amount of water is not necessarily clear. It is considered that the calcium in the tap water forms a I with no (c) component, and the fat is released by dilution of the fatty acid released from the microcell. This eliminates bubbles in an instant. Fatty acids are widely known as defoamers. By using a detergent composition of the present invention having 13⁄4 fatty acids, it is possible to obtain a blistering during washing, and in addition, it can be obtained during rinsing. The effect of rapid defoaming, this situation (4) can not be expected as an unexpected effect of the effect of defoaming (tetra) acid. Regarding the hand-washing detergent composition of the present invention, by using foaming/bubble persistence (8) component, However, the detergent m mesh shows a very high foaming property in the higher detergent, but the concentration of the detergent is higher, and it is difficult to remove the viscous slip by the rinsing. The component (4) having a fluffy structure and the (e2) component as the component (4) can disturb the depositability of the surfactant layer adsorbed on the surface of the food container, and (9) reduce the stickiness during rinsing. 155204.doc -14· 201202409 When the component (cl) is used as the component (C) in the hand-washing detergent composition of the present invention, it is preferable to contain the component (a) from the viewpoints of foaming power, defoaming property and economy. 1 to 30% by mass, more preferably 丨~ plus mass °/〇' is particularly preferably contained in an amount of 2 to 15% by mass. Further, the component (b) is contained in an amount of from 1 to 50% by mass, preferably from 4 to 40% by mass. More preferably, it is contained in an amount of 1 〇 to 3 〇 by mass. Further, in the present invention, the amount of the component (b) for determining the mass 〇/〇 or the mass ratio is used as the amount of the acid type compound. Preferably, it contains (c) component 〇1~2〇 mass ° /., more preferably contains 0.5 to 10 mass ❶ / 〇, especially preferably contains mass When the (c 1) is used as the component (c) in the hand-washing detergent composition of the present invention, (b) component / [(a) The mass ratio of the component + (c) component is 〇〇1 or more, preferably 〇" or more, more preferably 0.3 or more, particularly preferably 〇45 or more, and particularly preferably 〇.6 or more. From the viewpoint of defoaming property, the mass ratio is 1 Torr or less, preferably 6 or less, more preferably 3 or less, particularly preferably 2 or less, and particularly preferably 16 or less. Further, the hand washing device of the present invention is washed. When the component (cl) is used as the component (c) in the detergent composition, the mass ratio of the component (c) to the component (a) is 〇.〇〇1 from the viewpoint of foaming power and defoaming property. The above is preferably 〇〇1 or more, more preferably 0.05 or more, particularly preferably 0_07 or more, and particularly preferably 〇〇9 or more. On the other hand, the mass ratio of shai is 11 or less, preferably 5 or less, more preferably 3 or less, and still more preferably 1.7 or less. Further, when the component (c1) is used as the component (c) in the hand-washing detergent composition of the present invention, the mass of the component (a)/(b) is preferably 0.1 to 10, more preferably It is 0.3~5, especially preferably 0.5~3. 155204.doc •15- 201202409 When using the component (c) as the component (4) in the month of this issue, the foaming force and/or the bubble are all relative to the interface activity in the composition. The total mass of the component (a) component, (b) component, and (4) component is preferably 5〇100% by mass%, more preferably 7〇100100% by mass, and particularly preferably 80~100 mass%/ Further, in the case of using (c2) a knife as the component (c) in the hand-washing detergent composition of the present invention, the viewpoint of the vanacle resistance and the stickiness of the rinsing during rinsing are eliminated. In particular, it is preferable to contain (a) a component of 3% by mass, more preferably 2 to 25% by mass, particularly preferably 6 to 2% by mass. Further, preferably, it contains (b) a component 1~ 50% by mass, more preferably 5 to 4% by mass, and particularly preferably 10 to 30% by mass. Further, in the present invention, the amount of the component (b) for determining the mass % or the mass ratio, etc. The amount of the acid-type compound is in the form of an acid-soluble compound in the hand-washing detergent composition of the present invention. Preferably, the component (c) contains 〜5 to 2% by mass. More preferably, it contains 1 to 10% by mass. More preferably, it contains 1 5 to 5 masses of 0/〇. In the present invention, the component (c2) is used. In the case of the component (c), the total mass of the component in the composition and the component (c) is relative to the component (a) and the component (b) from the viewpoint of ease of foaming and stickiness. And the total mass of the component (c) (mass ratio of [(a) component + (c) component] / [(a) component + (b) component + (c) component), preferably 0.1 to 0.9, more Preferably, it is 0.2 to 0.7, and particularly preferably 0.4 to 0.6. Further, when the component (C2) is used as the component (c) in the hand-washing detergent composition of the present invention. In terms of foaming power and anti-sticking feeling, the quality of (b) component / [(a) component + (c) component] is better than 〇. 〇1 or more, 155204.doc •16· 201202409 Preferably, it is 0.1 or more, and particularly preferably 0.5 or more, and more preferably 1 or more. Further, the mass is preferably 20 or less, more preferably 15 or less, particularly preferably 10 or less, and particularly preferably 5 or less. Hand washing food detergent composition When the component (c2) is used as the component (c), the mass ratio of the component (c) component/(a) is 0.01 or more, preferably 〇丨 or more, from the viewpoint of the foaming power and the anti-sticking property. More preferably, it is 0.15 or more. Further, the mass ratio is 1 Torr or less, preferably 4 or less, more preferably 1.5 or less, and particularly preferably 0.7 or less. Further, in the hand-washing detergent composition of the present invention When the component (c2) is used as the component (c), the mass of the component (a)/(b) is preferably 〇〇1 to 2, more preferably from the viewpoint of foaming power and defoaming property. 0.034 5, especially preferably 0.1 to 1, especially preferably 0.3 to 〇.7. In the case where the component (C2) is used as the component (c) in the present invention, the content of all the surfactants in the composition is from the viewpoints of foaming power, defoaming property and anti-sticking property. The total mass of the component a, the component (b) and the component (c) is preferably 20 to 1% by mass, more preferably 4 to 1% by mass, still more preferably 60 to 100% by mass. The hand-washing detergent composition of the present invention preferably contains a component (cl) and a component (c2) as a (c) component in that the viscous slip is instantaneously disappeared during rinsing and can be washed with a small amount of water. )ingredient. In the hand-washing detergent composition of the present invention, as the component (d), it is preferred to contain a porphyrin-containing compound and/or a carbon number for the purpose of improving the emulsifying power of the oil stain and enhancing the detergency. The alkyl diamine of the alkylene group of 2 to 6 is preferably a magnesium-containing inorganic compound. These compounds have the effect of the present invention 155204.doc •17·201202409: that is, as required for the component (4), (8), at least two of the other anionic surfactants: A compound that interacts to form a complex compound and enhances the activity of the emulsifying surface, and has a common effect/action mechanism. Examples of the inorganic compound containing a hydrocarbon include gasification locks and the like, sulfuric acid, magnesium, etc. (4) 'hydrogen peroxide, and oxidative lock, etc., more preferably selected from gasification towns and magnesium sulfate compounds, particularly preferably Gasification town. Further, as the alkylene diamine compound, ethylenediamine, propylenediamine, hexamethylenediamine, cyclohexanediamine, and a diamine represented by the following formula (4), more preferably cyclohexanediamine, are preferred. , 1,3-bis(amine fluorenyl)cyclohexane, especially preferably bis(amine fluorenyl) cyclohexane. [Chemical 3]

[wherein, R6 to R17 are each an alkyl group having a carbon number of 丨~3, an alkyl group having a carbon number of 〜3, or a hydrogen atom, and two of R6~ are an alkyl group having a carbon number of ^] . The content of the component (d) is preferably from 5% by mass, more preferably from 1.5 to 15% by mass, even more preferably from 1 to 5% by mass. Further, the component (d) is in the form of water containing crystals, and the content expressed herein is the mass of the water to be removed. In the hand-washing detergent composition of the present invention, an inorganic compound other than the component (d) may be used in combination as the auxiliary component (d). As the inorganic compound, 155204.doc 201202409 may, for example, be sodium chloride, potassium hydride, her/or sodium, potassium iodide, sodium sulfate, potassium sulfate, or alum. The behavior of the bubbles during the washing and rinsing of the present invention is very important. In the general study of the hand-washing detergent composition, in consideration of the foaming/bubble persistence during washing and using a surfactant having a foaming effect, the surfactant having the above-mentioned foaming effect in the present invention It will have a great influence on the defoaming property during rinsing, so care must be taken when using it. In the present invention, in particular, as the component (4), care must be taken in the operation of an interfacial activator selected from the group consisting of a 4 amine-type surfactant, a certain betaine-type surfactant, and an alkanoamine surfactant. The amine oxide type surfactant may, for example, be N-decylaminopropyl-N,N-dimethylamine oxide (as a mercapto group, a lauryl or myristyl group), and an N-alkyl group. -N,N-didecylamine oxide (as an alkyl group, a lauryl or myristyl group). Further, examples of the carbonyl betaine type surfactant include N-decylaminopropyl-N,N-dimercapto-indole-carboxymethylammonium betaine and N-decylaminopropyl-N. N-dimethyl-N-(2-hydroxysulfonyl)ammonium betaine, ice-alkyl-N,N-dimethyl-N-carboxymethylammonium betaine' and N-alkyl·Ν,Ν _Dimethyl-indole-(2-sulfosylpropyl) ammonium betaine. Further, examples of the alkanolamine type surfactant include an alkanolamine such as monoethanolamine, diethanolamine or methylmonoethanolamine, and a fatty acid amidine compound such as lauric acid or myristic acid. In the present invention, the behavior of the bubbles is very important, and care must be taken when using the (e) component which imparts a foaming effect to the composition, especially with respect to the content of the (e) component of all the surfactants in the composition. It is preferably 5% by mass or less, more preferably 3% by mass or less, still more preferably 2% by mass or less, and particularly preferably 1 155204.doc • 19-201202409 vol. In the following, it is preferably 5% by mass or less, and most preferably no (e) component 0. In the present invention, a sulfobetaine type surfactant (hereinafter referred to as (f) forming a knife) may be used as an increase. Surfactant for foaming effect. The base-based sugar beet test 5 interface / tongue f active agent to improve the foaming / bubble persistence during washing, but does not damage the defoaming properties of the moment of α washing. As the sulfobetaine type surfactant, it is preferred that the alkyl group has a carbon number of 10 to 18, and the alkyl group is 烷基-alkyl-Ν, Ν-dimethyl- Ν- 丙基 丙基 县 县 县 县 县 县 县 县 县 县· ν, ν, dimethyl good (2·stone-based yellow propyl) material base sweet green 'county carbon number (four) ~ Ν Ν 醢 醢 胺 胺 丙 曱, 曱 Ν Ν 磺 sulfopropyl ammonium sulfobetaine Ν 醯 醯 胺 胺 _ _ Ν Ν Ν 甲基 甲基 甲基 甲基 甲基 甲基 甲基 ( ( 。 。 。 。 。 。 。 。 。 。 。 。 。 The content of the (f) forming knives in the composition is preferably 〇 5 to 3% by mass, more preferably 1 15% by mass or less, particularly preferably 2 to 1% by mass. Further, (1) component, [(4) component () into a knife], the negative t匕, preferably 〇〇1 to 〇2, more preferably 〇, the foaming/bubble persistence during washing and the rinsing time It is preferred in terms of defoaming properties. The hand-washing detergent composition of the present invention has the purpose of improving storage stability. The 5 ' car is preferably a dissolution aid (hereinafter referred to as component (4)). As the dissolution aid #], it is good to be sodium, potassium or magnesium salt of toluene acid, xylene, cumene or I or 4, especially good for toluene acid or its (g) into / knife The content is preferably 〇m by mass in the composition. /. More preferably, it is 1 to 10% by mass, and particularly preferably a solvent of the present invention (hereinafter referred to as (h) component) for the purpose of 丨5 to 5 mass%. The preparation for improving the storage stability or the viscosity of the hand-washing detergent composition may contain 155204.doc -20-201202409 as a specific example of the agent, preferably selected from the group consisting of ethanol, isopropanol, and ethylene glycol. Alcohol monoethylene glycol, dipropylene glycol, glycerin, isoprene glycol, propylene glycol monoterpene ether, propanol monoethyl ether, 3-methyl-3-methoxybutanol, phenoxyethanol phenethyl alcohol, stupidoxy Isopropanol, diethylene glycol butyl ether (diethylene glycol ° ° ^) monoethyl alcohol monobutyl ether, and water-soluble organic solvent of benzyl alcohol. Wherein ' is preferably a water-soluble organic solvent selected from the group consisting of diethylene glycol butyl ether, ethanol, & propylene glycol, and more preferably one or more water-based organic solvents selected from the group consisting of ethanol and propylene glycol. Here, the water-soluble organic solvent is a mixture of the octanol/water partition coefficient and the amount of the solvent of the solvent, and the amount of the solvent is preferably 3% by mass or less. Good for 5~% by mass, especially good for 10~15 quality 〇/〇. In the hand-washing detergent composition of the present invention, in terms of viscosity adjustment and stability, it is preferred to formulate a polymer for anti-gelation [hereinafter referred to as (1) component. An anti-gelling polymer, especially a polyalkylene glycol, as described in Japanese Patent Laid-Open No. Hei 11-513067. Specific examples of the polyalkylene glycol used for the gelation of the polymer for gelation include a weight average molecular weight determined by gel permeation chromatography (gel_permeatiation chromatography). 2 〇〇 to 3 聚 of polypropylene glycol, and polyethylene glycol having a weight average molecular weight of 200 to 3,000. Further, an alkylene oxide adduct of glycerin may be used as the component (1). The glycerol % oxygen calcination & substance is effective for suppressing the formation of a film which can form a surfactant at the gas-liquid interface of the detergent composition, and it is particularly preferable to use an average of 5 to 120 for the addition of glycerin. It is preferably 10 to 50 moles of ethylene oxide, especially an ethylene oxide adduct of glycerol having a weight average molecular weight of 500 to 4,000. 155204.doc -21 - 201202409 (i) The content of the knives is preferably 〇5 to 丨〇% by mass, more preferably 0.1 to 5% by mass, even more preferably 0.5 to 3% by mass. The hand-washing detergent composition of the present invention is preferably in the form of a liquid composition obtained by dissolving/dispersing/emulsified the above components in water, more preferably an aqueous solution. The water system to be used may be a sub-gas acid sterilizing water or the like which is obtained by removing ion-exchanged water or distilled water which removes a small amount of dissolved metal components, or by dissolving a sub-gas acid of about 0.5 to 1 jaw. The hand-washing detergent composition of the present invention is at 2$. The pH value in the case of hydrazine is preferably from 4 to 9, more preferably from 5 to 8, and the pH is adjusted to be carried out using the following substances: a mineral acid selected from the group consisting of sulfuric acid, hydrochloric acid, and phosphoric acid, selected from the group consisting of citric acid, An organic alkali agent such as malic acid, maleic acid, fumaric acid, and succinic acid, and an argon oxide, sodium hydroxide, magnesium hydroxide, sodium carbonate, and potassium carbonate. In the present invention, in terms of foaming property/bubble persistence, it is preferred to impart a buffering ability to the composition, and it is preferred to use the above organic acid, preferably citric acid and an inorganic alkali agent in combination. The organic acid may also be formulated in the composition in the form of a sodium salt or a potassium salt. Further, among the compounds for pH adjustment, magnesium hydroxide or the like is equivalent to a component and can be treated as a (£1) component. The hand-washing detergent composition of the present invention preferably has a viscosity of from 5 to 500 mPa.s at a temperature of from 2 to 3 mPa.s. The viscosity can be obtained by (g) component. , (h) component, (1) component, etc. are adjusted. The hand-washing detergent composition of the present invention may contain ingredients such as perfumes, dyes, and pigments. <Hand wash and wash method> 155204.doc •22· 201202409 Net copy: The ΠΓ ΠΓ 洗 detergent composition is used for hand washing of the food. The washing liquid used in the hand washing is obtained by using the hand washing detergent composition of the present invention, and a stock solution of the composition or an aqueous liquid 7 is used. As a specific hand washing method, for example, a water-containing sponge is used for flexibility. (4) The composition of the present invention is cut and mixed with a washing liquid, and is rubbed while rubbing it several times by hand. The total concentration of the component (4), the component (b), and the component (4) in the cleaning liquid held by the flexible material is preferably 1,000 to 30,000 ppm, more preferably 1 to 2 inches, and _ claw It is preferably 2'000 to 1 〇, _ ppm, which is preferable in terms of higher foaming property and bubble sustainability. After the completion of the washing, water is added for rinsing, for example, with respect to 1 part by mass of the composition used in the present invention, and sufficient defoaming is carried out with 3.3 to 丨 33 parts by mass of the rinsing water, thereby rapidly completing the rinsing. The amount of the rinse water is about 2/3 to 1/1 Torr when the prior hand wash detergent composition is used. EXAMPLES The following examples of κ will be described for the practice of the present invention. The examples are intended to be illustrative of the invention and are not intended to limit the invention. The hand-washing detergent compositions of Tables 1 to 7 were prepared using the following formulation ingredients, and the following evaluations were carried out. The results are shown in Tables 1 to 7. Further, the mass % of the compounding ingredients in Tables ^ to 7 is based on the value of the active ingredient. <Mixing component>, sodium di-2-ethylhexyl sulfosuccinate (1): Reagent [Kanto Chemical Co., Ltd.] • Sodium di-2-ethylhexyl sulfosuccinate (2): Pelex OT-P [Kao (share)] • Sodium dipentyl sulfosuccinate: Aerosol AY-100 [Active ingredient is 97 quality 155204.doc •23· 201202409 % or more, obtained from Mitsui Cytec (share) • Sodium dicyclohexyl sulfosuccinate: Aeros〇i A_196 [93-95% by weight of active ingredient, obtained from Mitsui Cytec (share)] • Sodium succinate (tridecyl ester) sodium: PelexTR[花王(股)] base ό ό 癸 癸 癸 . . . . . . 试剂 试剂 试剂 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和 和It is obtained by an esterification reaction with a polyoxyethylene-2-ethylhexyl hydrazine. Polyoxyethylene-2-ethylhexyl fluorene is obtained by adding j mole of ethylene oxide to 1 mol of 2-ethylhexanol. •% gibberic acid dialkyl ketone (1): a branched alcohol having a branching ratio of 94% by mass by using isaichemi23 (the alkyl group having a carbon number of 12 and an alkyl group having 13 carbon atoms) a compound obtained by a mixture of 2-ethylhexanol in a mass ratio of 80/20 and an esterification reaction with sulfosuccinic acid. (Average molecular weight: 553) • Sodium dialkyl sulfosuccinate (2): a mixture obtained by mixing triterpene alcohol with 2·ethylhexanol in a mass ratio of 80/20, and A compound obtained by esterification of a shaft acid. (Average molecular weight: 559) • b-Ι: After the addition of 〇·6 mol p〇 to the natural alcohol 1 C of the alkyl chain, it is sulphated by sulfur dioxide and neutralized with sodium oxynitride ( It is the result of neutralization until the pH value of 10% diluted with water is 11). • b-2: sodium lauryl sulfate [trade name Emal 0, Kao (share)] • b-3: sodium sulfhydryl sulfate [Kanto Chemical Co., Ltd.] and sodium lauryl sulfate [trade name Emal] 0, Kao (share)] is a mixture of mass ratio of 90/10. 155204.doc -24 · 201202409 'b-4 : The ratio of 90% sodium lauryl sulfate [trade name Emal 〇, Kao (share)] and sodium tetradecyl sulfate [Wuzhi Pure Chemical Industry Co., Ltd.] by mass ratio 90 The ratio of /10 is mixed. • b-5: A mixture of n-octyl sulfate and lauryl sulfate (trade name: Emai 〇, Kao (share)) at a mass ratio of 10/90. • b-6: in the natural chain of the C12 natural alcohol 1 molar addition 〇. 4 moles p〇 'sulfurization by sulfur trioxide' neutralization with sodium hydroxide (neutralization to water The pH value of the diluted 10% is 11). • b-7: after the addition of 天然8mol p〇 in the natural alcohol 1 C of the alkyl chain, 'sulfurization with sulfur trioxide, neutralization with sodium hydroxide (neutralization to dilution with water) 10% of the pH value is 11). • b-8: after adding 1 〇 mol p〇 to the natural alcohol 1 mol of the alkyl chain, it is sulfated by sulfur trioxide and neutralized with sodium hydroxide (neutralized to diluted with water) 10% of the pH value is 11). B-9. The base chain is CIO. Cll : C12 : C13 = l〇: 35 : 35 : 20 (mass ratio) of alkylbenzenesulfonic acid (the number after C refers to the carbon number) • b-ΙΟ: alkane (Carbon number 14 to 17 second alkyl mixed) sodium sulfonate (trade name: HOSTAPURSAS60 'Manufactured by Clariant Co., Ltd.) • b-11. In the case of an alkyl alcohol chain C12, a natural alcohol 1 molar addition 〇·6 mol p After hydrazine, it is sulphated by sulfur dioxide, and neutralized with ammonia water (neutralization until the pH of 10% of water is diluted to U). B-12. The base chain of the institute is C12/C10/C8=90/5/5 (mass ratio) of natural alcohol, j moles, addition of 0.6 moles, and sulfation by sulfur trioxide, using hydrogen Sodium oxide is neutralized (the pH of the neutralization to 1% by weight is called 155204.doc -25-201202409). • GE-EH: 2-ethylhexyl monoglyceryl ether (monoglyceryl ether 99% by mass) • Nonionic 1: The composition of the alkyl group is a mixed alkyl group of C12/C14 = 60/40 (mass ratio) and the average glucoside Alkyl glucoside with a degree of condensation of 1.5 • Nonionic 2 : Softanol 70H (manufactured by Nippon Shokubai Co., Ltd.) • Nonionic 3 : Softanol 33 (manufactured by Nippon Shokubai Co., Ltd.) _e-l : N-Lauryl- N,N-dimercapto-indole-(2-hydroxysulfopropyl)ammonium sulfone beet test (Kao (manufactured by Kao): Amphitol 20HD) • e_2: lauryl dimethyl amine oxide (Kao (share), Amphitol 2 〇N) •e_3 .Amine oxide: N-fluorenyl-N,N-didecylamine oxide/N-myristyl-N,N-dimethylamine oxide=2/3 (mass ratio) 'glycerin EO Adduct: glycerol with a weight average molecular weight of woo; 〇 adduct • polypropylene glycol: weight average molecular weight of 1, propylene glycol • PTS 'HzO: sodium phthalate monohydrate • MgCl2- 6H20: Magnesium hexahydrate hexahydrate <foaming power (scrub evaluation)> Cylindrical glass with a diameter of 5 cm and a height of 13 cm with 20 plastic beads of about 9 mm in diameter Container, adding 4〇 mi 35〇〇η diluted with hard water of 0.5 mass% (2〇〇 fold) of the composition. Further, 〇〇4 g of butter was added, and the temperature was adjusted to 2 Torr 15 minutes after sealing. Hey. The temperature-controlled glass container was placed in a washing tester (Suga Test Instruments Co., Ltd.) and mixed for 15 minutes at 20 ° C. The placed glass container measures the height (mm) of the bubble in the container. The evaluation was performed twice for one composition, and the average value of 155204.doc -26 - 201202409 was set as the foaming power (washing evaluation) of the composition. <Foaming power (initial foaming amount) and defoaming property> The composition was diluted 3 times with 3.5 °DH hard water, and was pumped by a pump foamer (200 mesh per tablet) at 5 〇〇mi 3 in the measuring cylinder, the volume is recorded according to the scale of the measuring cylinder. 'Set the foaming force (initial bubble 8 amount ^ / & then, (10) mk3.5 〇 DH hard water is added to the bubble through the watering can from t, determination 30 The amount of foam after the second. When the bubble does not disappear, the hard water of 3_5°DH of 丨(9) nd is further added to the bubble (total 2〇〇(6)), and the amount of foam after 3 seconds is measured in the same manner. The defoaming property is determined by the rate of change of the amount of foam represented by the following formula, and is determined to be utilized as long as it is 30% or less before being added to 200 ml. Dilution (flushing) can achieve rapid defoaming. Bubble rate change rate (%) = (adding hard water 1〇〇m丨 or 2〇〇m丨 after the amount of foam / initial amount of foam) χ 100 and 'made spray The pot is removed from the bottom of a 250 ml polypropylene jar (AS ONE: Ι-Boy jar) by about one-third of the opening in the state where the lid is opened. Manufactured by uniformly mounting a thin plastic perforated plate with 13 holes of approximately 2 mm in diameter. 155204.doc 27- 201202409 155204.doc

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Is OOCN·^哿 and 挎 -34- 201202409 Detergent combination Table 8 The hand-washing utensils and the precursors of Table 8 were prepared using the following formulation ingredients. The results are shown in Table 8. Furthermore, the mass % of the ingredients is based on the value of the active ingredient. <Foaming power> 'Dilution of the composition by 3 liters in a cylinder of 5 〇〇ml by means of a pumping device (each gram of bubbles, 3.5° 根据 according to the cylinder) Η hard water Make a 3 degree reading bubble volume (ml) and set it as a foaming force. <Evaluation of ease of elimination of stickiness>> The composition 1 g and the temperature were adjusted to 25. 〇 自 自 〇 〇 今 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Two sides of the dish. At this time, each surface is subjected to 5 times of scrubbing and 5 scrubbing, and immediately at 4 L/min of water (the temperature is adjusted to the temperature. The crucible is rubbed by hand at a speed of solidification, and washed to one dish at a time. The viscous sensation of the lotion disappears. The time (seconds) until all the stickiness on the five discs disappears is used as an indicator of the ease of stickiness. 155204.doc 35. 201202409 〇〇155204. Doc

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Claims (1)

201202409 VII. Patent Application Range: 1 . A hand-washing food detergent composition comprising: (a) a di/monoalkyl sulfosuccinate represented by the following formula (1) or (Γ) Or a salt thereof; (5) an anionic surfactant having a hydrocarbon group having a carbon number of 8 to 21 and a sulfate group or a sulfonate group (excluding (a) 1 to 50% by mass; and (c) a component (cl) having a carbon number of 1 to 18 or a salt thereof, and/or (C2) an alkyl glyceryl ether having an alkyl group having 6 to 18 carbon atoms, and (c) a component (cl) In the case of a fatty acid having a carbon number of 10 to 18 or a salt thereof, the mass ratio is 0.001 to 11 ' and the mass ratio of (b) / [(4) + ((〇) is 〇01 to 1 (), [Chemical 1] R - (OA1) x-ococh2chcoo- (a2〇) -r^ (1) (Γ I y so3m R'-OCOCH^HCOO-R2 I SOM [, medium 2' R, R2 are carbon numbers 5~1 8 respectively An alkyl group or a hydrogen atom, and at least one of R1 and R2 is an alkyl group having a carbon number of 5 to 18; Al and A2 are independently an alkylene group having a carbon number of 2 to 4, and x and y are average additions. Moore number:: Separately 〇~6; further, x, y not (four) is 〇; M is machine cation 2. The hand-washing detergent composition according to claim 1, wherein the mass ratio is 〇 〇 。 9. zhong 3. If the H2 hand-washing detergent composition is requested, (b)/[(a The mass ratio of +(c)] is 〇.〇1~2〇. t 155204.doc 201202409 The hand-washing detergent composition of claim 1 or 2, wherein the quality of (c)/(a) The ratio is 〇.〇1~1(). 5. The hand-washing detergent composition of the item 1 or 2, wherein (c) is formed into a knife ir, (cl) has a carbon number of 1 〇 18 In the case of a fatty acid or a salt thereof, the mass ratio of the component (b) is 0.1 to 10; and when the component (c) is an alkyl glyceryl ether having a carbon number of 6 to 18 in the alkyl group (c2) The mass ratio of the component (a) to the component (b) is 0.01 to 2. 6. The handwash detergent composition according to the item or the 2, further comprising (d) 3 inorganic compounds and/or Or a dialkyl diamine having an alkylene group having a carbon number of 2 to 6. A hand-washing detergent composition of claim 1 or 2, wherein (b) an alkylsulfate salt having an alkyl group having 8 to 18 alkyl groups and an alkyl group having a carbon number of 18 a polyoxyalkylene alkyl ether sulfate having a carbon number of 2 and/or 3 and an alkyl group having an average molar addition of a polyoxyalkylene group having a molar number of from 1 to 6 An anionic surfactant having an alkylbenzenesulfonate having an alkyl group having a carbon number of 8 to 15 and an alkanesulfonate having a carbon number of 10 to 15. Hand-washing detergent composition of month 1 or 2, with respect to composition φ # & ' < content of all surfactants, (a) total of ingredients, components, and (C) The mass is 50 to 1% by mass. A method of washing a masher by washing the hopper with a washing liquid of any of the hand-washing detergent compositions of claims 1 to 8 and thereafter rinsing with water. / 155204.doc 201202409 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the characteristics that can best show the invention. Chemical formula: (none) 155204.doc