TW200922808A - Provision of frames or borders around pigment flakes for covert security applications - Google Patents

Provision of frames or borders around pigment flakes for covert security applications Download PDF

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Publication number
TW200922808A
TW200922808A TW96144152A TW96144152A TW200922808A TW 200922808 A TW200922808 A TW 200922808A TW 96144152 A TW96144152 A TW 96144152A TW 96144152 A TW96144152 A TW 96144152A TW 200922808 A TW200922808 A TW 200922808A
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TW
Taiwan
Prior art keywords
sheet
flakes
sheets
pigment
coating
Prior art date
Application number
TW96144152A
Other languages
Chinese (zh)
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TWI511887B (en
Inventor
Alberto Argoitia
Cornelis Jan Delst
Stacey A Yamanaka
Wilfred C Kittler Jr
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Jds Uniphase Corp
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Priority claimed from US11/931,816 external-priority patent/US9164575B2/en
Application filed by Jds Uniphase Corp filed Critical Jds Uniphase Corp
Publication of TW200922808A publication Critical patent/TW200922808A/en
Application granted granted Critical
Publication of TWI511887B publication Critical patent/TWI511887B/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14Security printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0021Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/10Interference pigments characterized by the core material
    • C09C2200/1037Interference pigments characterized by the core material the core consisting of an inorganic suboxide or a mixture thereof, e.g. SiOx or TiOx
    • C09C2200/1041Interference pigments characterized by the core material the core consisting of an inorganic suboxide or a mixture thereof, e.g. SiOx or TiOx comprising at least one metal layer adjacent to core material, e.g. core-M or M-core-M
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/301Thickness of the core
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/303Thickness of a layer with low refractive material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/308Total thickness of the pigment particle
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2210/00Special effects or uses of interference pigments
    • C09C2210/40Embossed layers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2220/00Methods of preparing the interference pigments
    • C09C2220/20PVD, CVD methods or coating in a gas-phase using a fluidized bed

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Laminated Bodies (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

Opaque flakes, such as pigment or bright flakes used in paints and inks, have a selected shape and/or other indicia to provide a covert security feature to an object. Shaped opaque covert flakes are not readily detectable by causal observation, but in some embodiments are easily seen at 50X magnification. In manufacturing the flakes a sheet of embossed frames are provided having embossed symbols or indicia within. Upon removing a coating from the embossed sheet the coating material tends to break along frame lines or grooves and the resulting flakes are substantially uniform in size. In order to have the flakes break along frame lines or grooves more readily than along the embossing or grooves defining indicia within a frame, the frames are provided with a deeper groove than indicia grooves. As well a groove having a different shaped profile conducive to breakage can be used for the frame grooves whereas a groove having a profile less conducive to breakage can be used to form the indicia grooves. We have found that the flakes can be further protected from breakage by coating them in a protective coating. This coating may have other features which makes the logo more visible.

Description

200922808 九、發明說明: 【發明所屬之技術領域】 本發明一般而言係關於薄顏 ' ,且更特定言之,传 關於在用於塗料組合物中之標記镇 邱 、^ 溥片周圍提供邊界或邊框 以及在薄片之加邊框區域内提供由 代丨/、田或多個凹槽農中+ 4* 誌;且更特定言之,本發明提件 ^ 誌、,其中與凹槽式標誌相比,該 標 ^槽式邊框較不穩固且更 【先前技術】 已發展特用顏料以用於諸如印製於崎、高價值物品勺 裝、容器密封件上之防偽圖案的 匕 文王愿用中,且其5亩 應用於商業物品。舉例而言,美直接 /γτ e + 丁夷70聯邦儲備券 (U.S. twenty-dollar Federal Reserve Note) § .,s oie)目刖使用可光變 油墨。印於該紙幣正面右下角之 执的顏色隨勸家备 度之改變而改變。此為外現 巴1讀备角 q |兄丨万瑪圖案。該變色作 普通彩色影印機複寫,且接收紙 色安全特徵以確定該紙帶之真實性。一是否具有變 首::高價值文件及目標物使用類似措施。舉例而言,在 二接應庫用於諸如股票、護照、原始產品Μ或應用於密封 件(其應用於物品)的油漆 益社1 茶及油墨中使用虹彩顏料或繞射性 顏科。由於偽造者之技術曰臻成熟二 安全特徵。 ^欠難以偽造的 種防偽方法係在多層變 ★亥等符轳兹一 支巳顔枓4片上使用微觀符號。 及寺付就猎由諸如反射率 射羊之先學性質的局部變化形成於該 126980.doc 200922808 二變色顏料薄片之層的至少一者上。多層變色顏料薄片 般包括法布裏伯羅(Fabry Perot)型結構,甘 ns a r- 有藉由分 ^層。反射層分離之吸收層。反射層通f為金屬層, 得顏料薄片大體上不透明。若大部分此等類型顏二薄片、盘 其他顏料混合,則所得顏色可顯著不同於該顏料200922808 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates generally to thin-faces and, more particularly, to providing boundaries around marked towns and slabs used in coating compositions. Or the border and the border area of the sheet are provided by the 丨/, 田 or a plurality of grooves in the field; and more specifically, the present invention is in the form of a grooved sign In contrast, the standard grooved frame is less stable and more [Prior Art] Specially used pigments have been developed for use in anti-counterfeiting patterns such as printed on Saki, high-value items, and container seals. And its 5 acres are used for commercial items. For example, the U.S. twenty-dollar Federal Reserve Note §., s oie) witnessed the use of photo-changeable inks. The color printed on the lower right corner of the front of the banknote changes with the change of the persuasion. This is the appearance of the outside of the Pakistani 1 reading corner q | brothers Wanma pattern. The color change is overwritten by a conventional color photocopier and receives a paper security feature to determine the authenticity of the tape. Whether it has a change:: High-value documents and targets use similar measures. For example, iridescent pigments or diffractive Yankees are used in paints such as stocks, passports, original products, or in paints used in seals (which are used in articles). Due to the technology of the counterfeiter, the second security feature. ^ The anti-counterfeiting method that is difficult to forge is based on the multi-layered change. ★Hai et al. And the temple pays for hunting by a local variation such as the reflectivity of the sheep, which is formed on at least one of the layers of the 126980.doc 200922808 dichromatic pigment flake. The multilayer color-changing pigment flakes generally include a Fabry Perot-type structure, and the ns a r- has a layer. The absorption layer separated by the reflective layer. The reflective layer pass f is a metal layer, and the pigment flakes are substantially opaque. If most of these types of pigmented flakes and other pigments are mixed, the resulting color can be significantly different from the pigment.

少此等薄片與其他顏料混合,則其難以發現。 I 另—種技術使用經環氧樹脂封裝成形的聚對笨 二醋ΓΡΕΤ,’)薄片。將一反射層沈積於一卷ρΕτ上,且^ 將該PET切成小片。該等薄片經環氡樹脂塗佈或封裝以2 良該反射層之耐久性。此等薄片可以諸如方形、㈣… 邊形及’,單引號(apQstr〇phe),,之各種形狀獲得,且可選: #銀錫釓合金、金及銅之反射性金屬色澤。然而,該環 ⑽脂層及相對厚的PET基板(其用於真空沈積製程中' 1、厚度通常為約13微米(〇.5密耳))產生相對厚的薄片,通 二於U微米。不幸的是,若厚度遠大於基質顏料,則如 此厚的薄片對隱蔽應用 I个σ意。類似地,該厚薄片 = 墨中流動並非良好’且在油漆中產生結 :面之厚薄片時,通常在_表面上施加: 對厚的透明外塗層。 需要以能克服以上討执姑休_认& 標記目標物。 的揭限性之隱蔽防偽圖案來 本發明係關於提供且古炫< Μ 仏具有經精由機械方式在其中壓印或壓 :=或藉由雷射方式形成的標記或隱蔽符號之薄片, /、中該等隱蔽符號在顯微鏡下可見。為保留該等符號之完 I26980.doc 200922808 整f·生,在所有或部分隱蔽符號周圍提供邊樞 個別薄片自其所沈積之支撐結構移除時,大部= 提供的邊框線斷裂,而非以缺乏控制的不可 (其中斷裂線另外以較大 式斷裂 周圍屮㈤、*、 4錢Μ該等符號 ) 為進—步嘗試確保产邊推绩$ 裂,該等邊框凹槽可且有線或凹槽發生斷 八有,、界疋隱蔽符號之凹槽不同的剖 面’其令該等邊框凹槽細 斤 或破裂。在一”例/ 蔽付说凹槽更容易斷裂 =:::本!明之-較佳實施例中,薄 或夕個符被在該等—或多個符號周圍之四個以 上或四個以下之邊^卜目士 邊上,、有加邊框凹槽式邊界,以使得薄片 = 均一的方形或矩形斷裂。當然亦可以此方式藉 =襯底:除該等薄片前在三個邊上預加邊框符號來提 、m㈣片°提供習知釋放層以使得該等薄片 二易二其襯底或支撐層移除,且使得該等薄片在移除時 線斷裂。使用雷射、餘刻或壓印處於基板上之膜, 邊框可以製作符號之類似方式製作;在一較佳實施例中, 該等邊框乃連同符號之形成而以相同方法提供。 下文所用之術語1花薄片”描述藉由以壓花工具對薄片 施加壓力或對藉由塗佈於壓花基板上而形細花基板上 的採取基板形式之薄片施加麼力而虔花的薄片。 因此,本發明之-目標為提供其上具有符號之薄片,且 其中該等符號具有或曾具有經壓花、钱刻或雷射至薄片或 自經壓花臨時支撐物模製之薄片的邊框或邊界,以供在自 126980.doc 200922808 之過程期間保護該等符號,且其 内界定標誌或符號之凹槽深及/ 其臨時支撐襯底分離薄片 中該等邊框凹槽比在邊框 或更易於斷裂。 凹槽不同之橫截剖面 6又叶為比標諸凹槽更 本發月之一目標為提供具有與標言志 的邊框凹槽,且其中該等邊框凹槽經 容易斷裂或破裂。When these sheets are mixed with other pigments, they are difficult to find. I Another technique uses a poly-peptidic diacetate, which is formed by epoxy resin encapsulation, and a) sheet. A reflective layer is deposited on a roll of ρΕτ and the PET is cut into small pieces. The sheets are coated or encapsulated with a ring-turn resin to improve the durability of the reflective layer. Such flakes may be obtained in various shapes such as square, (four)...triangle and ', single quotation marks (apQstr〇phe), and optionally: #银锡釓合金, gold and copper reflective metallic color. However, the ring (10) lipid layer and the relatively thick PET substrate (which is used in the vacuum deposition process, typically having a thickness of about 13 microns (0.5 mils)) produces relatively thick flakes that pass through U microns. Unfortunately, if the thickness is much larger than the matrix pigment, then such a thick sheet applies a sigma to the concealment. Similarly, when the thick sheet = the flow in the ink is not good and the knot is thick in the paint: a thick sheet of the surface is usually applied: a thick transparent outer coating. Need to be able to overcome the above-mentioned swearing-recognition & mark target. The invention relates to a concealed anti-counterfeiting pattern. The present invention relates to a sheet which has a mark or concealed symbol which is mechanically embossed or pressed by a mechanical means: or by laser, /, these hidden symbols are visible under the microscope. In order to preserve the completion of these symbols, when all or part of the hidden symbols are provided around the individual support of the deposited support structure, most of the provided border lines are broken, instead of In the absence of control (in which the fault line is additionally broken with a larger break (5), *, 4 money, etc.), try to ensure that the production edge is cracked, and the border groove can be wired or The groove is broken, and the groove of the hidden symbol of the concealed symbol has a different profile, which causes the groove of the frame to be fined or broken. In a case/covering, the groove is more susceptible to breakage =::: Ben! In the preferred embodiment, the thin or the eve is four or more or less than the one or more symbols. On the side of the eyebrows, there is a grooved border with a border to make the sheet = uniform square or rectangular break. Of course, it can also be borrowed in this way: in addition to the three sides before the sheet By adding a border symbol, the m (four) piece provides a conventional release layer to remove the substrate or support layer, and causes the sheets to break when removed. Using a laser, a residual or The film is imprinted on the substrate, and the bezel can be made in a similar manner to the symbol; in a preferred embodiment, the bezel is provided in the same manner along with the formation of the symbol. The term "flower sheet" as used hereinafter is described by Applying pressure to the sheet by an embossing tool or applying a force to the sheet in the form of a substrate on the thin flower substrate by being applied to the embossed substrate. Accordingly, it is an object of the present invention to provide a sheet having symbols thereon, and wherein the symbols have or have been embossed, embossed or laser-to-sheet or a frame of a sheet molded from an embossed temporary support. Or a boundary for protecting the symbols during the process from 126980.doc 200922808, and wherein the grooves or grooves defining the marks or symbols are deeper and/or the temporary support substrate is separated from the sheets in the frame grooves than the frames or Easy to break. The cross-section of the groove is different. 6 The blade is more than the groove. One of the goals of this month is to provide a frame groove with a mark, and the frame groove is easily broken or broken.

在本發明之另-態樣中,在向基板添加釋放層之 基板預金屬化。在薄片自釋放層㈣彳4^ & 切=射性薄片而非再用以提供另一批經塗佈之薄= 預屬化之基板可經切割成長條以製成_新賴安全 (亦即’細絲)’該安全裝置含有與絲板製造 相 之匹配設計。 々祁丨j 除且經 以改良 在本發明之另一態樣中’,,分級”薄片在自基板移 適當後加工以產生成形,具有符號之薄片後經密封 薄片之耐久性以防在印刷或塗漆應用期間斷裂。 【發明内容】 根據本發明,提供複數個顏料標記薄片,各薄 位於由壁界定之續κ 3 4片周圍之邊框及-位於該邊框内之區 =中該等邊框壁中之至少-者的高度為至少高度Fh, ”中該邊框内之區域具有藉由其中所形成之—或多個深 度小於Id之凹槽界定的標誌,其中Fh>Id。 才“ 月之另―態樣’提供—薄層標記區域以供形成 才示δ己薄片,其包含: -經硬數個用以界定邊框之具有深度匕之邊框凹槽壓花的 I26980.doc •10· 200922808 基板及複數個在各邊框内形成標諸之標諸凹槽,其中 標誌、凹槽之深度小於工 、 , 、 且八中Fh>Id,使得當薄層或薄層 之、層分離為標記薄片時’與沿標誌凹槽相比,更可能 沿邊框凹槽發生斷裂。 b 人根據本發明之另一態樣,提供一種塗料組合物,其包 ,劑’·及分散於該載劑中之複數個單層無機介電隱蔽 =記薄片,其中該等薄片由邊框包圍,且其中可㈣之符 ::成於該邊框内部之區域中,且其中邊框壁比界定該可 辨別付號之凹槽壁深。 ,據本發明之另—態樣,提供—種製造其上具有標諸之 /的方法’該方法包含以下步驟:提供一經釋放層塗佈 之奸板,在該釋放層上提供一或多層光學塗料;以一或多 rn之形式在該光學塗料之複數個區域中記錄標認,其 忒絰3己錄之標誌係呈一或多個在該光學塗料内形成之凹 槽心式,在各區中之標諸周圍記錄凹槽式邊框,其中該凹 槽式邊框比形成該標諸之一或多個凹槽深;自該釋放層移 除光學塗料使得該塗料沿凹槽式邊框斷裂為以加邊框之標 誌形式之薄片。 在2明之又一態樣中,提供其上具有至少一符號之薄 中該等薄片藉由沿在其自支擇薄層移除前姓刻、雷 至該支樓薄層中之凹槽式邊框或邊界分離而自相 / ”離,且其中界定薄片周圍之該等邊框或邊界比其 上之至少—符號更容易斷裂。 根據另-態樣,本發明提供複數個經麗花顏料隱蔽標記 126980.doc 200922808 薄片’該等薄片經透光性非相容塗料塗佈,以減少薄片内 之凹槽深度。 【實施方式】 I. 介紹 用於隱敝安全應用_;μ 應用之用㈣片4常不可藉由一般觀察而 看見。使用諸如顯微鏡下檢查之一些類型的檢查技術或諸 如元素分析之分析技術。在一實施例中,含有諸如特定形 狀之標諸的不透明薄片大體上與其所混合的本體顏料或其 他物質之視覺特徵相匹配。在一特定實施例中,具有所選 擇形狀的單層無機不透明薄片與以虹彩雲母為基礎的薄片 或其他基質顏料相混合。出於此討論目的,無機材料之”單 層"包括相同無機材料彼此疊合之多層。 在熱、溶劑、陽光或其他因素可降解有機薄片之應用中 尤其需要無機隱蔽薄片。舉例而言,用於炸藥中之無機隱 蔽薄片甚至在暴露於高溫及/或壓力後仍可偵測且在環境 中具有抗性。根據本發明之實施例之薄片亦大體上比習知 成形的薄片更薄,通常小於約1〇微米,使得其能用於油墨 中且其在油漆中在不必需使用透明外塗層之狀況下產生光 滑表面修飾面層。根據本發明之實施例之薄、無機薄片亦 具有更接近使用類似技術製作之基質顏料薄片密度之密 度。併入有機基板之厚薄片通常具有與薄臈基質顏料薄片 不同的密度且當載劑為流體時可在應用前或期間分體。由 於薄片分體可導致隱蔽及基質薄片在組合物中之比率不一 致,因此薄片分體係不合意的,且若分體導致不當高濃度 126980.doc •12- 200922808 之隱蔽薄片’則其可使隱蔽薄片之隱蔽性質降級。 II.例示性不透明薄片 圖1為根據本發明之實施例具有安全特徵i 2的文件丨〇之 一部分的平面圖。安全特徵12之至少一部分14以包括具有 標誌的不透明薄片(下文稱為"隱蔽薄片”)之油墨或油漆印 刷,該等不透明薄片與諸如本體顏料薄片之本體顏料相混 合。在一實施例中,該等隱蔽薄片具有特定形狀,例如成In another aspect of the invention, the substrate to which the release layer is added to the substrate is pre-metallized. In the sheet self-release layer (4) 彳 4 ^ & cut = ejector sheet instead of being used to provide another batch of coated thin = pre-organized substrate can be cut into strips to make _ Xin Lai security (also That is, 'filaments'' the safety device contains a matching design with the silk plate manufacturing. In addition to the modification, in another aspect of the invention, the "graded" sheet is processed after being suitably moved from the substrate to produce a shaped, post-sliced sheet having the durability of the sealed sheet to prevent printing. Or rupture during application of the lacquer. [Invention] According to the present invention, a plurality of pigment-labeled sheets are provided, each of which is located at a border around a contiguous sheet of WL 3 defined by the wall and - in the area within the frame = the border At least the height of the wall is at least the height Fh, "where the area within the border has a mark defined by the groove formed therein - or a plurality of grooves having a depth less than Id, where Fh > Id. Only the "Month of the Month" provides a thin-layered marking area for the formation of the δ-sheet, which contains: - I26980.doc with a hard number of border groove embossings with a deep 匕 to define the border •10· 200922808 The substrate and a plurality of markings are formed in each of the frames, wherein the depth of the marks and grooves is smaller than the work, , and eight Fh>Id, so that when the thin layer or the thin layer When separated into a marking sheet, it is more likely to break along the border groove than the marking groove. According to another aspect of the present invention, there is provided a coating composition, which comprises a package, and is dispersed therein. a plurality of single-layer inorganic dielectric concealment in the carrier = a sheet, wherein the sheets are surrounded by a frame, and wherein the (4) symbol: is formed in an area inside the frame, and wherein the frame wall is more distinguishable than the frame The groove has a deep wall. According to another aspect of the invention, there is provided a method of manufacturing a standard having the same as described above. The method comprises the steps of: providing a release layer coated blade, Providing one or more layers of optical coating on the release layer; Or multiple rn forms are recorded in a plurality of areas of the optical coating, and the marks recorded by the rn3 are one or more grooved heart patterns formed in the optical paint, and the marks in each zone A grooved frame is recorded around the groove, wherein the grooved frame is deeper than the one or more grooves forming the mark; removing the optical paint from the release layer causes the paint to break along the grooved frame to be framed a sheet in the form of a mark. In another aspect of the invention, there is provided a thin sheet having at least one symbol thereon, the thin sheet being removed from the thin layer of the self-selecting thin layer The grooved border or boundary is separated from the phase/", and the border or boundary defining the periphery of the sheet is more susceptible to breakage than at least the sign thereon. According to another aspect, the present invention provides a plurality of lacquer pigment concealed indicia 126980.doc 200922808 sheets's such sheets are coated with a light transmissive non-compatible coating to reduce the depth of the grooves in the sheet. [Implementation] I. Introduction Used to conceal safety applications _; μ Application (4) Sheet 4 is often not visible by general observation. Some types of inspection techniques such as examination under the microscope or analytical techniques such as elemental analysis are used. In one embodiment, the opaque sheet containing the label, such as a particular shape, is substantially matched to the visual characteristics of the bulk pigment or other material to which it is blended. In a particular embodiment, a single layer of inorganic opaque sheet having a selected shape is mixed with an iridescent mica based sheet or other matrix pigment. For the purposes of this discussion, a "single layer" of inorganic material includes multiple layers of the same inorganic material superposed on each other. In particular, inorganic concealed sheets are required for applications in which heat, solvents, sunlight, or other factors can degrade organic sheets. Inorganic concealed sheets for use in explosives are detectable and resistant to environmental exposure even after exposure to elevated temperatures and/or pressures. Sheets in accordance with embodiments of the present invention are also substantially thinner than conventionally formed sheets, Typically less than about 1 micron, such that it can be used in inks and it produces a smooth surface finish in the paint without the need to use a clear outer coating. Thin, inorganic flakes according to embodiments of the invention also have Closer to the density of matrix pigment flake density made using similar techniques. Thick flakes incorporated into organic substrates typically have a different density than thin tantalum matrix pigment flakes and can be split before or during application when the carrier is a fluid. Separation can lead to concealment and the ratio of matrix flakes in the composition is inconsistent, so the flake system is undesired, and if the split causes improper The concealed sheet of concentration 126980.doc •12-200922808 can then degrade the concealing properties of the concealed sheet. II. Exemplary opaque sheet Figure 1 is a portion of a document having a security feature i 2 in accordance with an embodiment of the present invention. Plan view. At least a portion 14 of the security feature 12 is printed with an ink or paint comprising an opaque sheet having a logo (hereinafter referred to as "concealed sheet"), which are mixed with a bulk pigment such as a bulk pigment sheet. In an embodiment, the concealed sheets have a specific shape, such as

形為方形、矩形、梯形、”菱形"或圓形。在另—實施例 中,該等隱蔽薄片包括具有或不具有所選形狀之格柵圖 案。所選形狀較佳藉由壓花、蝕刻或使用雷射以產生邊框 或邊界來提供,當自其臨時支撐基板移除時薄片將沿該等 邊框或邊界斷裂。在一特定實施例中,該格柵圖案具有在 光譜可見光範圍内非光學活性之格柵間隔。亦即,此等格 柵圖案並不形成可見的繞射格柵。儘管並非所有標記薄片 必為隱蔽薄片,但有時隱蔽薄片亦稱為標記薄片。 -般而言’包括本體顏料薄片之本體顏料顆粒具有不規 則形狀。在-實施例中’隱蔽薄片可藉由其形狀與本體顏 料薄片區別。或者,本體顏料薄片具有第一選擇形狀,且 隱蔽薄片具有第二選擇形狀。成形顏料薄片之製造係藉由 各種技術完成的’諸如使用圖案化基板來將薄片材料:積 於該基板上,且接著自基板分離薄片以獲得諸如邊框或邊 界之圖案;或使用雷射或其他方式自—薄層薄片材料切判 圖案化薄片。該等隱蔽薄片之所選形狀可與(例如)製造; 施、製造日期或文㈣之其他方面或製㈣文件 126980.doc 13 200922808 油墨相關聯。 废塗機為一種類型的可用於製造根據本發明之實施例選 擇性成形或隨機成形之隱蔽薄片的裝置。使一卷聚合物基 板材料之溥層(亦稱為"網”)通過一或多個沈積區且經一或 夕個相層塗佈。可使該卷聚合物基板來回多次通過該一 〆 固'尤積區。接著自聚合物基板分離該(等)薄膜層且使 其加工為薄片。亦可使用其他裝置及技術。The shape is square, rectangular, trapezoidal, "diamond" or circular. In another embodiment, the concealed sheets comprise a grid pattern with or without a selected shape. The selected shape is preferably by embossing, Etching or using a laser to create a bezel or border, the lamella will break along the rim or boundary as it is removed from its temporary support substrate. In a particular embodiment, the grating pattern has a non-spectral visible range Optically active grid spacing. That is, such grid patterns do not form visible diffraction gratings. Although not all marking sheets are necessarily concealed sheets, sometimes concealed sheets are also referred to as marking sheets. 'The bulk pigment particles comprising the bulk pigment flakes have an irregular shape. In an embodiment the concealed flakes may be distinguished from the bulk pigment flakes by their shape. Alternatively, the bulk pigment flakes have a first selected shape and the concealed flakes have a second The shape is selected. The fabrication of the shaped pigment flakes is accomplished by various techniques, such as using a patterned substrate to: deposit the sheet material on the substrate, and then The substrate is separated from the sheet to obtain a pattern such as a border or a border; or the patterned sheet is cut from the thin sheet material using laser or other means. The selected shape of the concealed sheet can be, for example, manufactured; Or other aspects of (4) or (4) document 126980.doc 13 200922808 Ink associated. A waste coater is a type of device that can be used to make a concealed sheet that is selectively shaped or randomly shaped in accordance with embodiments of the present invention. The tantalum layer (also referred to as "web") of the polymeric substrate material is applied through one or more deposition zones and through one or one of the phase layers. The roll of the polymer substrate can be passed back and forth through the 〆 固 固 尤 尤 尤The (equal) film layer is then separated from the polymer substrate and processed into a sheet. Other devices and techniques can also be used.

♦通吊需將自一卷聚合物膜基板沈積(且因此自其移除)之 薄M層的總厚度限制為小於約職米。PET為-種類型的 用於滾塗機之聚合物膜基板,且PET膜基板通常至少為約 =米厚。較薄PET膜傾向於在真空沈積製程中熱變形。 «聚合物基板通過沈積區時,沈積區之熱及所沈積一或多 個薄膜層冷凝之熱均增加聚合物基板溫度。因此,自阳 膜切割且併人?_之薄片的最小厚度為㈣微米。 =外,具有所選擇形狀之薄片較佳藉由使邊框壓花至基 笼“來實現’ 4等薄片將沿該等邊框分離且斷裂開,隱蔽 厚片較佳在邊框内且經邊框界 逯界包括一或多個符號、 其他形式標誌及/或格栅圖案。 .u 杀在沈積或另外形成經加工 為涛片之薄膜層前將格柵圖宰壓 口系靨化於用於滾塗機的基板 上。在另一實施例中,當琴笼 i ^溥膜層自沈積基板剝離且加 工為薄片時,所選量(百 ^ /尤積基板表面積以格栅圖 案或形狀圖案壓花以獲得所選 盥A皙蒲μ目士 4 之隱敁溥片。此技術提供 。( 4膜層組合物及厚度)之障 蔽蟫片。舉例而言,以格撫閤安η , ; ^ 柵圖案及/或形狀圖案壓花】0%之 126980.doc -14· 200922808 :積=面積將產生具有約·隱蔽薄片之顏料混合 圖展不對於成形/具有符號之薄片及未成形/平挺薄 種不同光學設計的摻合物。可在相同真空製程中進 拍種不同光學設計,“此並非較佳。較佳地,以不同 百刀比經塵花表面積產生 旦 、生不π卷沈積基板以獲得具有不同 ㈣混合物’或以不同圖案麼花以獲得不同 形狀及/或格柵圖案。 為具有I花部分13及未經M花部分15之沈積基板η 、广之簡化圖。該_部分具有邊框,$出於說明 目、而經誇大’且另外或視情況具有(例如)格柵或符號, 且該未經壓花部分大體上為光滑的。或者,未嶋部分 以不同邊框、格柵或符號職。a花部分13與未經屬花部 二5的表面積之比產生所選量之具有與基質薄片(自未經 化部分產生)相同之薄膜結構的標記薄片(自壓花部分產 生)」儘管沈積基板U經由滾塗機内沈積區㈣示)自―卷 :丁進至3 4 19 ’但替代實施例使用不同類型基板及沈 積糸統。圖2B為具有壓花部分13,及未經壓花部分",之另 一沈積基板11,的一部分之簡化圖。 即使具有可識別標誌之顏料薄片易於觀察,其亦提供安 王特斂’然、而,右具有可識別標誌的顏料薄片不易觀察, 則偽造者甚至不會發覺隱藏薄片之存在。本發明之一實施 例使用具有與基質顏料㈣的光學特徵之隱蔽減薄片。 隱蔽顏料薄片由未經協助的人類視覺不可見,但在放大約 5〇X至1〇〇〇X下可見。具有大體上相同視覺特徵之隱蔽顏料 126980.doc -15- 200922808 薄片可與基質顏料以寬範圍比例相混合而不顯著影響組合 物之顏色。在一些實施例中,隱蔽顏料薄片在具有5_1〇重 量%之隱蔽顏料薄片及具有95-90重量%之具有類似外觀 (例如顏色及/或色程)的基質顏料薄片之組合物中易於識 別°通常’成形的不透明隱蔽薄片在使用手持顯微鏡(例 如"袖珍(shirt-pocket)"顯微鏡)之視野中易於識別且為識別 與具有符號之類似尺寸的薄片相比需更小的放大倍數。 f♦ The hoisting is required to limit the total thickness of the thin M layer deposited (and thus removed) from a roll of polymeric film substrate to less than about a meter. PET is a type of polymer film substrate for a roll coater, and the PET film substrate is usually at least about = m thick. Thinner PET films tend to be thermally deformed during the vacuum deposition process. When the polymer substrate passes through the deposition zone, the heat of the deposition zone and the heat of condensation of the deposited one or more film layers both increase the temperature of the polymer substrate. So, from the yang membrane cutting and merging? The minimum thickness of the sheet of _ is (four) microns. In addition, the sheet having the selected shape is preferably embossed to the base cage by the frame "to achieve" 4 sheets and the like will be separated and broken along the frame, and the hidden slab is preferably inside the frame and bordered by the frame. The boundary includes one or more symbols, other forms of marks, and/or a grid pattern. .u killing the grid to the roll for deposition before depositing or otherwise forming a film layer that is processed into a tile On another substrate, in a different embodiment, when the cage layer is peeled off from the deposition substrate and processed into a sheet, the selected amount (the surface area of the substrate is embossed in a grid pattern or a pattern of shapes) To obtain the concealer of the selected 盥A 皙 μ μ 目. 4. This technique provides a blunt smear of (4 film composition and thickness). For example, the lattice is adjusted to η, ; ^ Pattern and / or shape pattern embossing] 0% of 126980.doc -14· 200922808: product = area will produce a pigment mixture with about · concealed sheets, not showing the shape / symbol of the sheet and unformed / flat thin Blends of different optical designs. Different types of shots can be taken in the same vacuum process. Design, "This is not preferred. Preferably, the substrate is produced with a different surface area than the dust surface, and the substrate is deposited to obtain a mixture of different (four)' or different patterns to obtain different shapes and / Or a grid pattern. It is a simplified diagram of a deposition substrate η having a I flower portion 13 and an unmated portion 15. The _ portion has a frame, which is exaggerated for illustrative purposes and additionally or optionally (for example) a grid or symbol, and the unembossed portion is substantially smooth. Alternatively, the untwisted portion has a different border, grid or symbol. A flower portion 13 and a surface area without the flower portion 2 The ratio produces a selected amount of marking sheet (produced from the embossed portion) having the same film structure as the substrate sheet (produced from the unaltered portion)" although the deposition substrate U is shown in the roll deposition machine (4)) : Ding into 3 4 19 ' But alternative embodiments use different types of substrates and deposition systems. Fig. 2B is a simplified view of a portion of the deposition substrate 11 having the embossed portion 13 and the unembossed portion ". Even if the pigmented sheet with the identifiable mark is easy to observe, it also provides the Angkor's special, while the pigmented sheet with the identifiable mark on the right is difficult to observe, and the counterfeiter does not even notice the existence of the hidden sheet. One embodiment of the present invention uses a concealed relief sheet having optical characteristics with the matrix pigment (4). Concealed pigment flakes are not visible from unassisted human vision, but are visible at approximately 5〇X to 1〇〇〇X. A concealed pigment having substantially the same visual characteristics 126980.doc -15- 200922808 The flakes can be mixed with the matrix pigment in a wide range of proportions without significantly affecting the color of the composition. In some embodiments, the concealed pigment flakes are readily identifiable in a composition having 5 to 1% by weight of the concealed pigment flakes and having 95 to 90% by weight of a matrix pigment flake having a similar appearance (eg, color and/or color). Often 'formed opaque concealed sheets are readily identifiable in the field of view using hand-held microscopes (e.g., "shirt-pocket" microscopes) and require less magnification for identifying sheets of similar size with symbols. f

另一方法為使用顏色與基質薄片不同的、具有所選形狀 的不透明隱蔽薄片。在一實施例中,不透明隱蔽薄片為在 諸如M g F2之介電材料層之間具有鋁或其他反射物薄膜層之 亮金屬Γ銀”)薄片。亮薄片通常在寬範圍可見光波長下具 有高度反射性,且通常不具有特徵顏色。以金或銅製作的 ου薄片可表現出(例如)微黃色或微紅色。已發現可在顯色 基質顏料中添加介於約〇.25重量%至約5重量%之成形(例如 菱形形)党薄片而不引起可注意到的顏色改變,但在約 50X照明放大下(意即5〇倍放大)仍易於識別。在照明放大 下,該薄片之形狀及高亮度均使其區別於基質薄片。當使 用小於約0.25%之成形亮薄片時,該等隱蔽薄片變得難以 :測,因為基質薄片之稀釋導致較少在視野中成形的亮薄 當亮薄片之量超過約5重量%時,某些類型薄片(尤其深 色薄片)之顏色(例如色調)改變。在此等實例中,太多 片基本上”稀釋”基質顏料之多$ 貝颂枓之顏色。然而’在具有變色 之組合物中使用成形亮薄片係古 化碑巧你呵度合意的,因為將少量單 126980.doc -16 - 200922808 一類型成形亮薄片添加至許多不同類型(顏色及/或色程)之 顏料薄片中,且相對少量之成形亮薄片提供隱蔽安全特 徵。類似地,在含有顏料及亮薄片之組合物並不用於替換 或另外與含有1 00%顏料薄片之組合物區別的應用中,顏 色稀釋並非關鍵。 顏料通常於載劑中混合以形成油漆或油墨。載劑之實例 包括聚乙稀醇、聚乙酸乙稀酯、聚乙烯吼嘻咬酮、聚(乙 氧基乙烯)、聚(甲氧基乙烯)、聚(丙烯)酸、聚(丙烯醯 胺)、聚(氧化乙烯)、聚(順丁烯二酸酐)、羥乙基纖維素、 乙酸纖維素、諸如阿拉伯膠及果膠之聚(醣)、諸如聚乙烯 醇縮丁醛之聚(縮醛)、諸如聚乙烯氯及聚亞乙烯氯之聚(乙 烯鹵化物)、諸如聚丁二烯之聚(二烯)、諸如聚乙烯之聚 (烯烴)、諸如聚丙烯酸甲酯之聚(丙烯酸酯)、諸如聚甲基 丙烯酸曱酯之聚(甲基丙烯酸酯)、諸如聚(氧基羰基氧基伸 己烧)之聚(碳酸酯)、諸如聚對苯二曱酸乙二酯之聚(酯)、 聚(胺基甲酸酯)、聚(矽氧烷)、聚(硫)、聚(砜)、聚(乙烯 基腈)、聚(丙烯腈)、聚(苯乙烯)、諸如聚(2,5_二羥基_丨,4· 伸苯基乙烯)之聚(伸苯基)、聚(醯胺)、天然橡膠、曱醛樹 月曰、其他聚合物及聚合物及聚合物與溶劑之混合物。 圖3A為圖1中所示安全特徵14之一部分14A的簡化平面 圖。為看見該等薄片之形狀,安全特徵之部分14 A在放大 通常約2〇χ-30〇χ下觀察’其對徑(across)通常為約5_1〇〇微 采’更通常為對徑約20-40微米。該安全特徵使用包括基 質顏料顆粒1 6及具有所選形狀(在此狀況下為"菱形”形)的 126980.doc •17· 200922808 隱蔽顏料薄j4 I 8 >、、rk Μ ί 十溥片18之油墨印刷。選擇該隱蔽顏料 庳 ::::度以使得不擾“基質顏料顆粒製得的組合物: 該等基質顏料顆粒16經說明為不規則成形的薄片。或 ’基質顏料薄片具有所選(意即規則)形狀。類似地,隱 :顏料薄片18可具有格柵。添加格柵進—步增加偽造難 =在=實把例中,隱蔽顏料薄片18-般具有與基質 料顆粒相同的光學特徵。或者,隱蔽顏料薄片㈣有與基 質顏科顆粒不同的光學特徵,但所佔量充分少以使得不擾 亂以該等基質顏料顆粒製得的組合物之視覺外觀。 在一特定實施例中,該等”菱形”隱蔽薄片橫截面Css) 為約25微米乘以35微米之亮薄片。該等經成形薄片藉由將 菱形圖案壓花至-卷PET沈積基板材料中,且接著沈積亮 薄片(例如,介於各為約4〇〇 nm厚的峋匕層之間的約. 6〇nmA1)之標準薄膜設計而製得。此亮薄片之總厚度為約 9〇〇 nm’此為約i微米。經壓花圖案亦稱為"邊框與格柵 相反,其用於在薄片内或上產生圖案),且在一些實施例 中為正的(positive)且在其他實施例中為負的(negtive)。除 當與其他不規則形狀薄片成某些預定比分布時菱形薄片其 自身可提供一些隱蔽特徵之量測外,該等菱形薄片可以額 外隱蔽符號壓花’藉此提供兩種水平的可獲得的隱蔽特徵 以保護圖案。 金屬層與一或多個介電層之組合促進薄片自沈積基板之 移除。僅具有介電層之薄膜堆疊易碎且通常具有來自沈積 126980.doc 200922808 殘餘應力。該等薄膜堆疊更傾向於隨 =:薄片。全金屬堆疊或單層難以根據沈積基板:: 框加工為圖案化薄片1為金屬相對易延展 反:邊Another method is to use an opaque concealed sheet of a selected shape that is different in color from the substrate sheet. In one embodiment, the opaque concealed sheet is a bright metallic silver ("silver") sheet having a thin film of aluminum or other reflective material between layers of dielectric material such as MgF2. The bright flakes typically have a high range over a wide range of visible wavelengths. Reflective, and generally does not have a characteristic color. The ruthenium sheet made of gold or copper may exhibit, for example, a yellowish or reddish color. It has been found that it may be added in the chromogenic matrix pigment from about 〇25.5% by weight to about 5 wt% shaped (e.g., diamond shaped) party flakes do not cause noticeable color changes, but are still easily identifiable under about 50X illumination magnification (i.e., 5 fold magnification). The shape of the sheet is magnified by illumination. And high brightness distinguishes it from the matrix flakes. When less than about 0.25% of the formed brilliant flakes are used, the concealed flakes become difficult to measure: because the dilution of the matrix flakes results in less bright and thin light in the field of view. When the amount of flakes exceeds about 5% by weight, the color (eg, hue) of certain types of flakes (especially dark flakes) changes. In these examples, too many flakes are substantially "diluted" of the matrix pigment. $ Beggar's color. However, 'the use of shaped bright flakes in the composition with discoloration is a good idea, because you add a small amount of single 126980.doc -16 - 200922808 one type of shaped bright flakes to many Different types (color and/or color) of pigment flakes, and a relatively small number of formed flakes provide a hidden security feature. Similarly, compositions containing pigments and flakes are not used for replacement or otherwise contain 100% In applications where the composition of the pigment flakes differs, color dilution is not critical. Pigments are typically mixed in a carrier to form a paint or ink. Examples of carriers include polyethylene glycol, polyvinyl acetate, polyvinyl ketone , poly(ethoxyethylene), poly(methoxyethylene), poly(propylene) acid, poly(acrylamide), poly(ethylene oxide), poly(maleic anhydride), hydroxyethyl cellulose , cellulose acetate, poly (sugar) such as gum arabic and pectin, poly (acetal) such as polyvinyl butyral, poly (ethylene halide) such as polyvinyl chloride and polyethylene chloride, such as poly Poly(diene) of a diene, poly(olefin) such as polyethylene, poly(acrylate) such as polymethyl acrylate, poly(methacrylate) such as polymethyl methacrylate, such as poly(oxygen) a poly(carbonate) of a carbonyloxy group, a poly(ester) such as polyethylene terephthalate, a poly(urethane), a poly(oxane), a poly(sulfur) Poly(sulfone), poly(vinyl nitrile), poly(acrylonitrile), poly(styrene), poly(2,5-dihydroxy-indene, 4·phenylene vinyl) poly(phenylene) , poly(decylamine), natural rubber, furfural, and other polymers and polymers and mixtures of polymers and solvents. Figure 3A is a simplified plan view of a portion 14A of one of the security features 14 shown in Figure 1. Seeing the shape of the sheets, the portion 14 A of the security feature is observed at a magnification of typically about 2 〇χ 30 '. 'The cross is usually about 5 〇〇 micro plucking', more usually about 20 psi. 40 microns. This safety feature uses 126980.doc •17· 200922808 concealed pigment thin film j4 I 8 >, rk Μ ί 十溥 including matrix pigment particles 16 and having a selected shape (in this case a "diamond shape)) Ink printing of the sheet 18. The concealing pigment 庳::: is chosen such that the composition prepared from the matrix pigment particles is not disturbed: the matrix pigment particles 16 are illustrated as irregularly shaped sheets. Or the 'matrix pigment flakes have a selected (i.e., regular) shape. Similarly, the hidden: pigment flakes 18 can have a grid. Adding a grid further increases the difficulty of counterfeiting. = In the case of the actual case, the concealed pigment flakes 18 generally have the same optical characteristics as the matrix particles. Alternatively, the concealed pigment flakes (4) have optical characteristics different from those of the base gravitational particles, but are in an amount sufficiently small that they do not disturb the visual appearance of the compositions made with the matrix pigment particles. In a particular embodiment, the "diamond" concealed sheet cross-section Css) is a bright sheet of about 25 microns by 35 microns. The shaped sheets are embossed into a roll of PET deposited substrate material by a diamond pattern, and then a bright sheet is deposited (eg, between about 〇〇 约 各 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约The standard film design of nmA1) is made. The total thickness of the bright flakes is about 9 〇〇 nm' which is about i microns. The embossed pattern is also referred to as "the border is opposite the grid, which is used to create a pattern in or on the sheet, and in some embodiments is positive and negative in other embodiments (negtive ). In addition to the diamond sheet itself providing some measure of concealment characteristics when it is in some predetermined ratio distribution with other irregularly shaped sheets, the diamond sheets may additionally conceal the symbol embossing ' thereby providing two levels of available Concealed features to protect the pattern. The combination of the metal layer and one or more dielectric layers facilitates removal of the wafer from the deposition substrate. Only thin film stacks with dielectric layers are fragile and typically have residual stresses from the deposition 126980.doc 200922808. These thin film stacks are more prone to follow =: flakes. All metal stacking or single layer is difficult to deposit according to the substrate:: Frame processing into patterned sheet 1 is relatively easy to extend metal.

例中,總厚度介於約〇.5微米與約3微米H =金屬-介電薄片提供延展及易碎特徵之良=:電: 導致“基板移除且經加卫時薄片之良好圖案化。在一特 =例中,具有介於易碎介電層之間的、總厚度為約一In the example, the total thickness is between about 〇5 μm and about 3 μm. H = metal-dielectric flakes provide good ductility and fragile characteristics =: electricity: results in "good removal of the substrate when the substrate is removed and cured" In a special example, having a total thickness between the fragile dielectric layers of about one

屬層之成形亮薄片自壓花沈積基板產生約 使用習知技術將該等薄膜層自沈積基板剝離且經加工為 薄片。該經壓花菱形圖案提供線,沿該線薄膜層斷裂為具 有所選菱形形狀之薄片。在另—實施财,該菱形薄片為 約12微米乘以16微米’且在該等薄片之主要表面上包括格 栅。該格柵在標稱上為每毫米2_條線,且#用作標記時 在組合物中不產生明顯繞射作用。12x16微米薄片之形狀 於100X放大倍數下易見;然而’在此放大倍數下格柵不、 見。該格栅於400X放大倍數下容易明顯看到。在其他實施 例中’格拇較為粗糙,且在用於分辨標記薄月形狀之相同 放大倍數(例如50><至100><)下容易看見。因此,用於向標 記薄片提供安全特徵之格柵在光譜之可見光部分中不必為 光學活性的。 " 在一特定實施例中,基質顏料顆粒為以一層Ti02或其他 μ電材料塗佈之雲母薄片。該塗佈材料通常具有相對高的 折射率。雲母係相對便宜且容易加工為薄片基板之天然產 126980.doc -19- 200922808 〇 虽每母溥片基板以—岸所撰度 ^ 料塗佈時,與彳θ播上柘Μ # "、予又的鬲折射率材 換W“ 薄片。雲母薄片基板可以若干· 換材枓使用各種製程塗佈 干替 基礎"的顏斜 , 稱為”以雲母為 原件不同,因此需使用…L 影印件看來與 現安全特铁 云母為基礎的顏料薄片以提供外 广特敘。然而,使雲母薄片基板 板上提供符號為不實際的。根據本發明之=片基 薄片與以雲母為基礎之顏料相混人以使例之隱蔽 ..,^ 俏屁口以使仔隱蔽安全特徵能 7 一於經以雲母為基礎之顏料薄片印製的影像中。若在 了二光4波長下,該隱蔽顏料薄片之厚度為約五倍於四八 之一波長光學厚度(”QW0T”),則由諸如 = 無機介電材料製得的点形拓4 飞ns之早層 ㈣I传的成形顏料薄片具有類似於以 2之顏料的㈣。通常’用於與以雲母為基礎之㈣ 觀相匹配之如之單層隱蔽薄片的厚度為約6〇_至約_ ::。加工來自具有經慶花菱形圖案之沈積基板的 薄片傾向於具有比對應金屬介電薄片更低的產量。 圖3 B為根據本發明之—音·^点丨—^ + U之實&例之錢料薄片2()的簡化截 面。反射層22介於兩個介電薄膜層24、%之間。該等介電 薄膜層24、26向亮顏料薄片2〇提供硬度且促進該顏㈣片 自滚塗機基板之移除。需保持亮顏料薄片之厚度小於1〇微 米以提供乾燥或固化成光滑表面之組合物。在特定實施例 中’該薄片之厚度係介於約“毁米與約3微米之間。較薄薄 Μ其重量過小而傾向於更難以加工及處理’且較厚薄片 更堅固且因此更難以沿邊框圓案斷裂。 126980.doc •20· 200922808 反射層22通常為諸如鋁、鉑、金、銀或銅之高反射金 屬’或諸如鐵或鉻之適度反射金屬之薄膜層。反射層22充 分厚以在光譜可見光部分不透明(反射),但並不過厚以致 於干擾薄膜層自基板分離及隨後加工為薄片。換言之,過 厚金屬反射層將在介於相對易碎介電層24、26之間提供延 展性層’且其傾向於干擾該等沈積層加工為薄片。介電層 之適當材料尤其包括ZnS、MgF2、Si02、A1203、Ti02、 Nb2〇5及Ta2〇5。在一些實施例中,介電薄膜層24、26亦為 反射層22提供環境保護。 亮薄片20具有所選形狀且視情況或另外具有諸如表面 (格柵)圖案或元素指紋之其他標誌。將充分低濃度之亮薄 片20添加至顯色顏料及顯色組合物(例如油墨及油漆)中。 成形亮薄片可作為隱蔽安全特徵添加至基質(意即隨機成 形或另外成形的)亮薄片中。 圖3C為具有元素指示劑層28之亮薄片2〇|的簡化截面。 亮薄片20’具有位於介電層24,、26,之間的反射層22,、 22 ’’且層28提供元素指示劑。元素指示劑層28為未在基 質顏料中發現的材料之層,該基質顏料將與亮薄片共同使 用且使用諸如二次離子質譜("SIMS")分析、能量色散X—射 線(EDX )分析及奥格(Auger analysis)分析之元素分析技 術易於偵測。此外,元素指示劑存在於隱蔽薄片中但不存 在於基質薄片中,且微SIMS、微EDX或微奧格分析可易於 積測此差另。4堇向該豸料混合物、添加指#元素(例如將少 量含有指示元素之化合物添加至載劑)不可克服此安全特 126980.doc -21- 200922808 徵。The formed bright flakes of the genus layer are produced from the embossed deposition substrate. The film layers are peeled off from the deposition substrate and processed into a sheet using conventional techniques. The embossed diamond pattern provides a line along which the film layer is broken into sheets having a selected diamond shape. In another implementation, the diamond flakes are about 12 microns by 16 microns' and include grids on the major surfaces of the sheets. The grid is nominally 2 lines per mm and # does not produce significant diffraction in the composition when used as a marker. The shape of the 12x16 micron sheet is easy to see at 100X magnification; however, the grid is not visible at this magnification. The grid is easily visible at 400X magnification. In other embodiments, the thumb is relatively rough and is readily visible under the same magnification (e.g., 50 < to 100><>) for distinguishing the shape of the thin moon. Therefore, the grid used to provide security features to the marking sheets need not be optically active in the visible portion of the spectrum. " In a particular embodiment, the matrix pigment particles are mica flakes coated with a layer of TiO 2 or other μ electrical material. The coating material typically has a relatively high refractive index. Mica is relatively inexpensive and easy to process into a natural product of a thin substrate. 126980.doc -19- 200922808 〇When each mother substrate is coated with a coating, it is 彳 播 柘Μ # # The yttrium refractive index material is replaced by W". The mica thin-film substrate can be replaced by a variety of processes, and various processes are used to dry the foundation." It is called "mica is the original, so it is necessary to use ... L photocopying It appears that the pigment flakes based on the current safety special iron mica provide a wide range of special features. However, it is not practical to provide symbols on the mica sheet substrate. According to the present invention, the base sheet is mixed with the mica-based pigment to make the case concealed.., ^ The mouth is so that the child can hide the security feature. 7. The mica-based pigment sheet is printed. In the image. If the thickness of the concealed pigment flake is about five times that of the one-eighth wavelength optical thickness ("QW0T") at the two-light wavelength, the dot-shaped extension 4 such as = inorganic dielectric material is used. The formed pigment flakes of the early layer (4) I have a pigment similar to that of the pigment of 2. Typically, the thickness of a single layer of concealed sheets used to match the mica-based (four) view is from about 6 〇 to about _:. Sheets processed from deposited substrates having a diamond-like pattern tend to have lower yields than corresponding metal dielectric sheets. Fig. 3B is a simplified cross-sectional view of the sheet 2() of the actual & The reflective layer 22 is interposed between the two dielectric film layers 24,%. The dielectric film layers 24, 26 provide hardness to the bright pigment flakes 2's and promote removal of the face(s) from the roll coater substrate. The thickness of the bright pigment flakes is maintained to be less than 1 micron to provide a composition that dries or cures to a smooth surface. In a particular embodiment, the thickness of the sheet is between about "destroyed rice and about 3 microns. The thinner sheet is too small to be more difficult to process and handle" and the thicker sheet is stronger and therefore more difficult. The circular shape is broken along the border. 126980.doc •20· 200922808 The reflective layer 22 is typically a highly reflective metal such as aluminum, platinum, gold, silver or copper or a thin reflective layer of moderately reflective metal such as iron or chromium. Thick to be opaque (reflective) in the visible portion of the spectrum, but not so thick as to interfere with the separation of the film layer from the substrate and subsequent processing into a sheet. In other words, the overly thick metal reflective layer will be between the relatively fragile dielectric layers 24, 26. A ductile layer is provided therebetween and it tends to interfere with the processing of the deposited layers into flakes. Suitable materials for the dielectric layer include, inter alia, ZnS, MgF2, SiO 2 , A 120 3 , TiO 2 , Nb 2 〇 5 and Ta 2 〇 5. In some embodiments The dielectric film layers 24, 26 also provide environmental protection for the reflective layer 22. The bright flakes 20 have a selected shape and optionally have other indicia such as a surface (grid) pattern or elemental fingerprint. The bright flakes 20 are added to the chromogenic pigments and chromogenic compositions (e.g., inks and paints). The formed glitter flakes can be added as a hidden security feature to the substrate (i.e., randomly formed or otherwise formed) bright flakes. It is a simplified cross-section of a bright sheet 2〇 with an elemental indicator layer 28. The bright sheet 20' has a reflective layer 22, 22'' between the dielectric layers 24, 26, and the layer 28 provides an elemental indicator. The element indicator layer 28 is a layer of material not found in the matrix pigment that will be used in conjunction with the bright flakes and using, for example, secondary ion mass spectrometry ("SIMS") analysis, energy dispersive X-ray (EDX) analysis. And the elemental analysis technique of Auger analysis is easy to detect. In addition, the element indicator is present in the concealed sheet but not in the matrix sheet, and micro SIM, micro EDX or micro-ag analysis can easily detect this The difference is that the addition of the finger # element (for example, adding a small amount of a compound containing the indicator element to the carrier) cannot overcome this safety feature 126980.doc -21- 200922808.

元素指示劑層28不具光學活性,因為其介於兩個不透明 反射層22,、22,,之間。選擇反射層22,、22,,為用於基質薄 片的相同材料,例如鋁。元素指示劑之適當材料尤其包括 鉑、銥、鐵、釩、鈷及鎢。熟習此項技術者將瞭解所 兀常私不劑材料視其將一起使用的基質顏料而定。在一替 代實施例巾,亮顏料之反射層為元素指示劑材料(參見圖 ,參考數字22)。舉例而言,將使用鉑作為反射層之隱 蔽亮或顯色顏料薄片與使用鋁作為反射層之基質亮&片^ 顯色顏料薄片混合。在另—實施例中,具有併人顏料混合 物或組合物的元素指示劑之薄片的量經選擇以在顏料混合 物中提供所選元素比(例如鋁與鉑)。在替代或另一實施例 中,介電薄臈層24,、26,之材料(圖3Β,參考數字24、 經選擇以提供元素指示劑。 圖3D為根據本發明之另—實施例之變色顏料薄片%的簡 化截面。變色顏㈣片30通常稱為對稱5層法布裏·伯羅干 擾薄片。薄膜堆疊32包括反射金屬層34、兩個分隔層 36Α、3把及兩個吸收層38Α、38Β “及收層通常為極料 透明鉻、碳或其他材料層。反射層、分隔層及吸收層均為 光學活性的’'亦即其對變色顏料薄片之光學效能有;獻。 薄片之各邊向入射光提供類似法布裏-伯羅干擾結構,且 因此該薄片為光學對稱的。或者,該變色顏料薄片為全介 電顏料薄片或3層薄片,諸如吸收層/介電層/吸收層。 如光I顏料技術中所熟知的,冑色顏料薄片之顏色及色 126980.doc • 22- 200922808 程藉由溥片之光學設計、即在薄膜堆疊3 2中該等層之材料 及厚度來確定。變色顏料薄片3〇之光學設計通常經選擇以 與其將混合的基質顏料薄片之光學性質相匹配。使變色顏 料薄片30成形(參見圖3A,參考數字18),且視情況或另外 包括諸如表面格柵圖案及/或元素指示劑之其他標誌。The element indicator layer 28 is not optically active because it is interposed between the two opaque reflective layers 22, 22, . The reflective layers 22, 22 are selected to be the same material used for the substrate sheet, such as aluminum. Suitable materials for the element indicator include, inter alia, platinum, rhodium, iron, vanadium, cobalt and tungsten. Those skilled in the art will appreciate that the materials that are often used will depend on the matrix pigments they will be used with. In an alternative embodiment, the reflective layer of bright pigment is the elemental indicator material (see figure, reference numeral 22). For example, a concealed bright or chromogenic pigment flake using platinum as a reflective layer is mixed with a substrate bright & chromogenic pigment flake using aluminum as the reflective layer. In another embodiment, the amount of flakes of the elemental indicator having a blend or blend of pigments is selected to provide a selected elemental ratio (e.g., aluminum and platinum) in the pigment mixture. In an alternative or alternative embodiment, the material of the dielectric thin layer 24, 26 (Fig. 3A, reference numeral 24, selected to provide an elemental indicator. Fig. 3D is a color change according to another embodiment of the present invention). A simplified cross-section of the pigment flakes. The color-changing (four) sheet 30 is commonly referred to as a symmetric 5-layer Fabry-Perot interference sheet. The film stack 32 includes a reflective metal layer 34, two separation layers 36, 3, and two absorption layers 38. , 38 Β "and the layer is usually a transparent transparent chrome, carbon or other material layer. The reflective layer, the separation layer and the absorbing layer are all optically active '', that is, their optical performance for the color-changing pigment flakes; Each side provides a similar Fabry-Perot interference structure to the incident light, and thus the sheet is optically symmetric. Alternatively, the color changing pigment sheet is a full dielectric pigment sheet or a 3-layer sheet, such as an absorber layer/dielectric layer/ Absorbing layer. As is well known in the art of light pigmenting, the color and color of the pigmented flakes are 126980.doc • 22-200922808 by the optical design of the bracts, ie the materials of the layers in the film stack 32 Thickness to determine. Color change pigment thin The optical design of the sheet is typically selected to match the optical properties of the matrix pigment flakes to which it is blended. The color changing pigment sheet 30 is formed (see Figure 3A, reference numeral 18), and optionally includes, for example, a surface grid pattern And/or other indications of the element indicator.

舉例而言,反射層包括元素指示劑,其為不同於基質顏 料薄片之反射性金屬或包括一或多個額外元素指示劑層, 其可為或可不為光學活性的(參見圖3C,參考數字28)。或 者或另外,分隔層36A、36B及/或吸收層38A、38B包括元 素指示劑。舉例而言,若基質顏料薄片使用MgF2、Si〇2或 Ah〇3作為分隔層材料,則隱蔽顏料薄片3〇使用諸如丁丨〇2 或ZnS之不同分隔層材料。分隔及/或吸收指示劑材料包括 使用元素分析可容易偵測到的元素。 在—些實施你J中M吏用不同分隔材才斗及/或反射材料產 生具有與基質薄片不同的光學性質之隱蔽顏料薄片30。舉 =言,即使該等隱蔽及基質薄片在正常入射時具有類似 ;,色程可為不同。-般而言,低折射率分隔材料(諸 如他及以〇2)提供比高折射率分隔材料(諸如ZnS及Ti02) 二:色程("快變"顏料)。然而,可將該等隱蔽薄片以相 辰度添加至基質顏料薄片中’即使其色程與基質薄片 之巴程並不精確匹配, 本發明之一眚,” 觀察者不能偵測根據 異。 一實鉍例之混合物與100%基質薄片之間的差 圖4為根據本發明 之一實施例具有分散於載劑44中的隱 126980.doc -23 - 200922808 蔽為片C之清漆4〇的截面。 0 ^ ^ 边载劑為透明的或經調色的, 且隱喊薄片42以一定濃度,坊.曲* ^ 該’辰度經選擇以避免一般視螯 谓樹到。可選顏色塗層 於生、电Λ θ戈儿(例如鍍鉻”)塗料46已經塗覆 於0漆40下之目標物48上。 復 全44 Men分 /月漆40向该目標物提供隱蔽安 厚“或 觀在—特定實施例尹,可選顏色塗 s 6為以珠光或變色顏^ ^ ^ 安全特徵。該目向目標物提供外現 杜 物為(例如)文件、產品、包裝或密封 件。清漆40使得能夠向 ^次在封 瞎〜 名U、蔽女全特徵之目標物提供 隱蔽女全特徵而不顯著 ’、 面 是°亥目私物之外觀。舉例而言, 右月又示已印製有外現安全牲 全特m I 隨後需向股票提供隱蔽安 即含有…ΰ符…漆4 0或類似油墨組合物(意 一4有隱蔽薄片之大體上透明的油墨組合物)加印 實施例中’向已具有一或多個隱蔽安全特徵之目標物提 仏額外隱蔽安全特徵。在一特定眘 禮h在特疋實%例中,該等隱蔽薄片 構成不超過該清漆之2%。 圖5為根據本發明之另一實施例包括分散於黏合 =中之基質顏料薄片16及成形隱蔽薄片_組合物 即油墨或油漆)之截面。隱蔽薄片18具有所選形狀或 诸如凡素指示劑或表面格柵圖案之其他標誌。组合- :覆於諸如標戴、產品包裝、紙幣或消費物品之目標物Μ 向已存在油墨或油漆組合物添加隱蔽薄片,此向由、、由黑 或油漆製作的影像提供隱蔽安全特徵。舉例而言’具有= 色顏料之油墨用於在紙幣或其他目標 奶上钗供變色影像作 126980.doc -24- 200922808 為外現*全特徵。將根據本發明之—實施例之隱蔽薄片添 加至油墨中且將所得混合物用於印製影像,該等影像似乎 大體上類似於以原始油墨印製的彼等影像…匕,添加隱 蔽安全特徵後’紙幣之-般觀察者不會注意到外現安全: 铽U、即變色影像)之外觀的變化。_蔽薄片之標誌指示(例 如)裏4日期、印製地點及/或油墨的來源(製造商)。 III·實驗結果 製造且量測使用100%紫、红 '綠色光變凹紋("〇νι”)顏料薄 片之測試標準。亮及光變標記樣品均具有每毫米2_條線 之格柵圖f ’其使得該等標記薄片更容易地區別於基質顏 料溥片(思即疋位)且更難以偽造。格柵圖案於約彻X下清 晰可見且並不誘發以該等測試組合物印製的影像產生可見 光繞射性質。認為標記薄片之低部分與未向觀察者良好定 向避免發生繞射作用。在—替代實施例中,較細格柵圖案 包括於成形標記薄片上。該等形狀於顯微鏡第一放大倍數 下可識別’但格柵圖案在此第一放大倍數下不容易看見。 格栅圖案於較高放大倍數下可見。認為使具有所選形狀或 符號之標記薄片包括該格栅圖案進一步加強該標記薄片之 隱蔽性質,因為偽造者可能在顯微鏡檢查下看見形狀或符 號’但看不見格柵圖案且因此在偽造物品中不包括格柵圖 案。 第-測試樣品(”樣品r)含有與1〇%(以重量計)具有格柵 的紫紅至綠色⑽顏料薄片(”標記薄片”)混合之9〇%(以重 里。十)之S知(基質紅至綠色顏料薄片。該等標記薄片藉 126980.doc •25- 200922808 由常規顯微鏡檢驗易於偵測,且該混合物之 〜 試標準相同,因為樟$ " ^ ^ 匹配。相近顏色匹配斗n /貝巴十刀 椤9 Μ Η夕—.^謹慎監控標記薄片之·製造且用於 % ^的新穎光學設計通常將用於匹λ Μ 薄片之每一顏色。 匕配基貝 另一種方法為使用w α 用了與許多不同顏色基質薄片一起使用 之不準心.己薄片設計。亦評估使用紹反射層(其給予 片”銀白色,|外觀)之亮標記薄片。製造亮薄片相對簡單且· 與顯色基質顏料薄Η .曰Λ + ^ 一 4片此合時此等薄片於5%濃度下極易偵 測。免標記薄片與啤炙紐Α ' 顏色之基質顏料一起使用以提供障 蔽安全特徵。組合物中Α 曰. 甲凴私§己薄片之量視所要結果而定。 “列而吕’含有與紫紅至綠色〇νι基質混合之亮標記薄 片之凹紋推合物的顏色效能在並行比較中區別於100%紫 至 '亲色Ο VI薄片之組合物。大體上不能區別於剛%紫紅 至”彔色OVI薄片之組合物使用少於5%的亮薄片,諸如在紫 、彔色0VI薄片中売標記薄片之濃度介於約0·25重量% 與3重量%之間的組合物。認為可將濃度大於”紅亮薄片 添加至顏料薄片中,從而在不顯著改變組合物之外觀的條 :下提供較淺或不深顏色。亮標記薄片甚至在低於1%之 /辰度下在適當放大倍數下易於偵測,因為該組合具有所選 幵ν狀及不同顏色(例如"銀白色”而非紫紅色)。 IV.例示性方法 圖6為根據本發明之-實施例製作顏料薄片之方法600的 Ό王圖提供一卷基板,其具有以該卷基板之所選沈積表 126980.doc -26- 200922808 面面積之比的未經虔花(”光滑”)部分及經壓花部分(步驟 602)。在一實施例中,該經壓 / · 斗目女π 丨刀係以邊框壓花用於產 有仏形狀之薄片。在-替代實施例中 分係以格拇圖案或符號厂堅花。在 使用諸如雷射切除之除壓花外的 ^ J乃沄圖案化。將至少一 膜層沈積於該卷基板上(;步驟604), ' ^立所沈積一或多個薄膜 層經加工為薄片(步驟606)以產生具有 、 % Η AU ^ 選里之標記薄片之 :片昆合物。標記薄片之產量視諸如所加工薄膜層類型、 邊框性質、格柵圖案或符號及加工參數之因素而定。 舉例而言,參看圖2A及2B,若該卷基板1〇%之表面經格 柵或符號壓花’則預期產量為約1〇%之具有格柵圖宰或符 就的標記薄片。若該卷基板之抓表面以菱形邊框屬花, 則對於介電-金屬-介電薄片而言預期約9%的產量,因為將 薄膜堆疊之圖案化部分加工為成形薄片時存在1〇%產量損 失。類似地,對於成形全介雷續μ 取心生;1電溥片而言預期約5%產量, 因為將薄膜堆疊之圖案化部分加工為成形薄片時存在观 產量損失。 、、儘管上文已關於各種特定實施例描述本發明,但現將描 述提供顯著優勢之本發明之一態樣。 舉例而言’提供顯著優勢之本發明之—實施例為在基板 材料上(其用於在其上形成塗層)使用框住符號之邊框或邊 界或經此等邊界加邊框之標誌的態樣。 現轉向圖7,展不具有複數個歐元符號之薄層的照片, 其中薄層上各€符號具有包圍其之經壓花邊界。此通常藉 126980.doc •27- 200922808For example, the reflective layer includes an elemental indicator that is a reflective metal different from the matrix pigment flakes or that includes one or more additional element indicator layers that may or may not be optically active (see Figure 3C, reference numerals) 28). Alternatively or additionally, the separator layers 36A, 36B and/or the absorbent layers 38A, 38B comprise an element indicator. For example, if the matrix pigment flakes use MgF2, Si〇2 or Ah〇3 as the separator material, the concealed pigment flakes 3 〇 use different separator materials such as Dings 2 or ZnS. Separating and/or absorbing indicator materials include elements that are readily detectable using elemental analysis. In some implementations, the use of different separators and/or reflective materials produces a concealed pigment flake 30 having optical properties different from those of the substrate flakes. That is, even if the concealed and matrix sheets are similar at normal incidence; the color path can be different. In general, low refractive index spacer materials (such as he and 〇2) provide a higher specific refractive index separation material (such as ZnS and TiO2): color range ("fast change" pigment). However, the concealed flakes can be added to the matrix pigment flakes in a phase-integration 'even if the color distance does not exactly match the brace of the matrix flakes, one of the present inventions," the observer cannot detect the difference. The difference between the mixture of the examples and the 100% matrix sheet is shown in Fig. 4 as a cross section of the varnish 4 蔽 126980.doc -23 - 200922808 which is dispersed in the carrier 44 according to an embodiment of the present invention. 0 ^ ^ The side carrier is transparent or toned, and the sheet 42 is smothered at a certain concentration, and the 'end' is selected to avoid the general view of the tree. Optional color coating The coating 46, which has been applied to the target 48 under the lacquer 40, has been applied to the swarf (e.g., chrome-plated) coating 46. Reconstruction 44 Men points / month paint 40 to provide hidden security to the target "or view - specific embodiment Yin, optional color coating s 6 for pearlescent or color changing ^ ^ ^ security features. The target Providing external artifacts such as documents, products, packaging or seals. Varnish 40 enables the provision of hidden female features to the target of the full-featured, U-, and female features without significant ', no It is the appearance of the private object of the sea. For example, the right moon shows that it has been printed out and the safety is full. Then I need to provide hidden stock to the stock, which contains ... 漆 ... lacquer 40 or similar ink composition ( The substantially transparent ink composition having a concealed sheet) in the printing embodiment 'provides an additional concealed security feature to a target that has one or more concealed security features. In a particular caution h In a practical example, the concealed sheets constitute no more than 2% of the varnish. Figure 5 is a view of another embodiment of the invention comprising a matrix pigment flake 16 dispersed in a bond = and a shaped concealed flake _ composition, i.e., ink or Cross section of the paint) Shape or other mark such as a grain indicator or a surface grille pattern. Combination - : Overlying objects such as wearing, product packaging, banknotes or consumer goods 添加 Adding a cover sheet to an existing ink or paint composition, this direction Images made from black or paint provide concealed security features. For example, 'ink with = color pigments is used to make color-changing images on banknotes or other target milk. 126980.doc -24- 200922808 Full feature. The concealed sheet according to the embodiment of the present invention is added to the ink and the resulting mixture is used to print an image that appears to be substantially similar to the image printed with the original ink...匕, adding concealment After the security feature, the 'the observer of the banknote will not notice the appearance of the security: 铽U, that is, the color change image. The appearance of the change. _The cover of the foil indicates (for example) 4 dates, printing location and / or ink Source (manufacturer) III. Experimental Results Manufacture and measure the test standard using 100% violet and red 'green light-recessed ("〇νι) pigment flakes. Both bright and photo-labeled samples have a grid pattern f' of 2' lines per mm which makes the marking sheets more easily distinguishable from the matrix pigment sheets (thinking of the jaws) and more difficult to counterfeit. The grid pattern was clearly visible under Jochen X and did not induce visible light diffraction properties in the images printed with the test compositions. It is believed that the lower portion of the marking sheet is not well oriented to the observer to avoid diffraction. In an alternative embodiment, the finer grid pattern is included on the shaped marking sheet. These shapes are identifiable at the first magnification of the microscope 'but the grid pattern is not easily visible at this first magnification. The grid pattern is visible at higher magnifications. It is believed that including a marking sheet having a selected shape or symbol to include the grating pattern further enhances the concealing nature of the marking sheet because the counterfeiter may see the shape or symbol under the microscopic examination but may not see the grating pattern and thus in the counterfeit article Does not include the grille pattern. The first test sample ("sample r") contains 9% (by weight) of the mixture of 1% by weight (by weight) of the magenta to green (10) pigment flakes ("marked flakes") having a grid (see) Matrix red to green pigment flakes. These marking flakes are easily detected by conventional microscopy using 126980.doc •25-200922808, and the test is the same as the test standard, because 樟$ " ^ ^ matches. Similar color matching bucket n / Beba 10 椤 Μ — — . 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 谨慎 新颖 新颖The use of wα uses a misaligned design with many different color matrix sheets. It also evaluates the use of a reflective layer (which imparts a silvery white, | appearance) bright marking sheet. Making a bright sheet is relatively simple and · Thinner with chromogenic matrix pigments. 曰Λ + ^ One of these four sheets is extremely easy to detect at 5% concentration. Label-free sheets are used together with the base pigment of the beer color to provide a barrier Safety features. Composition Α 曰. A The amount of private slabs depends on the desired result. The color efficiency of the "grass" containing the embossed embossing of the brightly labeled flakes mixed with the magenta to green 〇νι matrix is distinguished from the 100% purple to the parallel comparison. A composition of a color Ο VI flake. A composition that is substantially indistinguishable from a mixture of just % purplish red to "green OVI flakes" uses less than 5% of bright flakes, such as the concentration of bismuth-labeled flakes in purple, ochre 0VI flakes. Between about 0.25% by weight and 3% by weight of the composition. It is believed that a concentration greater than "red bright flakes can be added to the pigment flakes to provide a lighter or lesser under the strip that does not significantly alter the appearance of the composition: Dark color. Brightly labeled flakes are easy to detect at appropriate magnifications even below 1%/min, as the combination has selected 幵ν and different colors (eg "silver white) instead of fuchsia) IV. Illustrative Method FIG. 6 is a diagram of a method 600 for fabricating a pigment flake according to an embodiment of the present invention. A roll of substrate having a selected deposition table 126980.doc -26-200922808 of the roll substrate is provided. Area ratio of unscented flowers (" a smooth ") portion and an embossed portion (step 602). In one embodiment, the pressure/mesh female π knives are embossed with a frame for a sheet having a serpentine shape. In an alternative embodiment The middle part is patterned by a thumb pattern or a symbol factory. It is patterned using a ruthenium other than embossing, such as laser cutting. At least one film layer is deposited on the roll substrate (step 604), ' The deposited one or more film layers are processed into a sheet (step 606) to produce a sheet of the label having a % Η AU ^ selection: the sheet yield is determined by, for example, the type of film layer being processed, Depending on the nature of the border, the pattern of the grid or the symbols and the parameters of the processing parameters. For example, referring to Figures 2A and 2B, if 1% of the surface of the roll substrate is embossed by a grid or symbol ', then a yield of about 1% of the marked sheet having a grid pattern or symbol is expected. If the scratched surface of the roll substrate is a diamond-shaped frame, a yield of about 9% is expected for a dielectric-metal-dielectric sheet because there is a yield of 1% when processing the patterned portion of the film stack into a formed sheet. loss. Similarly, about 5% yield is expected for forming full-scale singulation; 1 electro-thin film is expected because of the loss of yield when processing the patterned portion of the film stack into shaped sheets. Although the invention has been described above with respect to various specific embodiments, it will now be described that one aspect of the invention that provides a significant advantage. For example, the present invention, which provides a significant advantage, is an embodiment in which a frame or border of a symbol or a border with such a border is used on a substrate material for forming a coating thereon. . Turning now to Figure 7, a photograph of a thin layer of a plurality of euro symbols is shown, wherein each of the symbols on the thin layer has an embossed border surrounding it. This usually borrows 126980.doc •27- 200922808

由以加邊框€符號來壓花諸如pet基板之有機基板,且隨後 以可移除塗料塗佈該基板來完成。圖8為該等薄片自其概 底或基板分離後之照片。此照片清楚地展示多數符號為^ 整的,其中似乎很少裂紋進入或穿過該等符號。藉由使= 本發明,圖中極少部分薄片以使€符號模糊的方式斷裂。 然而所顯示的為在薄片自其所沈積的基板斷裂開後邊框未 沿薄片所有邊存在。-些薄片不具有邊界且其他薄片可具 有一且高達四個邊界。然而,此為可理解的。由於邊框邊 界使薄片自其最近的薄片分離’目此當薄片分離時,邊界 通常保持連接於一薄片且非在該邊框邊界的另一側之其相 鄰薄片。然而存在此邊框邊界導致多數薄片在邊框線了在 邊框一側或另一侧斷裂,提供具有相對直邊緣之相對均句 薄片。通常1帶符號之各薄片在自其所沈積之網或基板 分離後將具有至少—連接至其之邊界或邊框部分。較佳 地,邊框比薄片之其他部分易於切開。 圖9為複數個攜帶μ符號之Mg_Gn薄片之照片,其中由於 缺乏邊框而應力破裂且導致明顯的隨機斷裂線,因此薄片 隨機斷裂保留-些符號且破壞其他符號。圖9說明遍及該 等:片之應力裂紋,由於此等裂紋之作用,因此其引起薄 離&外,裂紋在薄片中持續出現藉此使符號模糊。 二據本發明提供邊框並不會完全防止應力裂紋,然而提供 ,、中可在更大程度上控制此等裂紋以沿邊框線 4或優先沿邊框線路經斷裂。與圖9相反,與圖7及卜 起展示之本發明之實施例提供—種方式,纟”片可沿預 126980.doc -28- 200922808 定邊界分離,藉此在薄片上更高程度地保留該等符號之形 狀及完整性且一般不使薄片中之隱蔽符號模糊。 在未經加邊框的符號中出現的裂紋在更易碎的、玻璃樣 介電材料中出現且擴展,但沿圖7所示經加邊框之符號的 薄層中所提供邊框線停止且改變路徑以繼續其擴展。提供 邊框產生薄片沿邊框線優先破裂。在圖8之薄片中所觀察 到的多數裂紋不會完全穿過薄片之總厚度,而停止於薄片 之彈性更大的金屬核心(Al/Ni/Al)水平上,產生對原始經 壓花符號之清晰性有害的遮蔽作用。 圖8及9中之薄片為約1300 nm或ι·3微米厚且具有以下層 結構:10 nm Cr/480 nm MgF2/80 nm AI/50 nm Ni/80 nm A1 480 nm MgFVlO nm Cr。存在川以提供外現特徵之磁性 層。 現轉向圖10,其為大量缺少任何隱蔽符號或邊框之薄片 中複數個經加邊框之符號的照片,其中經加邊框之符號與 其他薄片之比為1:1 〇。存在此實施例之兩個引人關注之態 樣。在第一偵測水平上,裝備有1〇〇><手持顯微鏡者可偵測 具有歐元符號之隱蔽薄片的存在,且此外,其亦可快速估 计出隱蔽與非隱蔽符號之比為約丨:丨〇。此外,其可比較方 形符號與隨機成形薄片之比以提供鑑定之一些量測。因 此,在加邊框形狀内該等符號之形狀、分布及識別可用於 在某確信範圍内判定該塗層是否可信。 雖然具有經邊界或邊框框住之符號的薄片通常沿邊框線 或凹槽斷裂為所需形狀,如圖1〇中加邊框之歐元所指示、', 126980.doc •29- 200922808 c存在薄片不合需要地沿形成符號之壓花線斷裂開的情 況。 見 > 看圖11 a ’展示界定僅一部分陣列之基板u 〇之切開 ^面’更特定言之,可看見一整個薄片及與其相鄰之部分 區域(〃中形成其他薄片)的基板。在此例示性實施例中’ 因為需要攜帶字符”JDSU’,及隨附標識之加邊界或加邊框薄 片沿邊框邊界U1斷裂開使得薄片形狀為方形,所以形成 邊界或邊框1 1 1之凹槽丨丨丨的深度大體上比形成標識丨i 2或 文子113之凹槽更深。較佳地,邊框深度與標識或文字深 度之比為至少10:8且較佳更大以確保薄片沿邊框邊界亦 即在邊框凹槽内斷裂及切斷。圖llb為指示基板上壓花之 相對深度的剖面分析。卩定邊框之凹槽為U形的且比界定 標識及文字之V形及較窄凹槽寬。較佳地,塗佈基板且形 成薄片之塗佈材料填充文字及標識之凹槽比填充邊框凹槽 多。此增加邊框的可斷裂性且減少沿界定文字或標識之凹 槽的可斷裂性。圖llc對應於圖Ua及Ub且為基板之法線 視圖。 與圖11a相反,圖lld為呈鏡像凹凸之基板,其中邊框由 壁界定且其中文字及標識自基板底部突出。圖以展示此 等壁之相對高度且圖Uf為該基板之法線視圖。當該薄片 薄層自基板移除時’標識及邊框仍由壁界定。 圖12a為先前技術之加邊框薄片的截面視圖,其中界定 呈字母或標識形式之標誌的凹槽與界定邊框的凹槽具有相 同深度。雖然展示完整雙壁u形邊框來說明圖i2a與圖1沘 126980.doc -30- 200922808 之間的差異,但在薄片自1 壁u形邊框,此係因為::》離後’通常將不具有雙 υ印口馬4片應沿邊 來指示當薄片自基板分離時 =展示虛線 而,因為圖12a中之凹槽:片將切斷之位置。然 同,所以很可能一肚薄 曰及付唬而,均相 12b時可見’界定符號 _如觀測圖 ^ ^ 凹槽的咼度或深度約為界定邊框 之凹槽之高度或深度的—车。 m 半亦即,邊框比符號深。tf_盈 保大部分薄片將沿邊框 寸琥/衣此確 ^ 凹槽切斷而非沿符號凹槽切斷… …,邊框凹槽與符號凹槽 為4:2或更大。 勹主八2且較佳 展示圖12a及12b中之薄片具 邱月也丨辟1 μ 「 均勾塗層,其中頂部、底 4及侧壁上薄片之厚度大體相同。 使用塗佈之物理氣相、,士接 /積(VD)技術(亦即,將撞擊 之材料以法線或接近法線之轨^搫基板 茛之軌線蒸發或濺射至基板)導致 在頂部、底部及側壁上之嗦镥场目士上 工 < 沈積層具有相同厚度。然而, 際上’ PVD沈積產生以傾斜角度入射至基板上之原子,如 圖m所示’且此等傾斜執線產生異常現象,導致厚度變 化。對於極端傾斜軌線而言,較深凹槽中凹槽之開口將具 有與底部相比較薄之塗層’此在目標在於使薄片沿凹槽斷 裂之情況中係合意的。 縱橫比愈高,該等特徵在底部、頂部及側壁之間的差異 將愈大。此現象在具有高縱橫比特徵之半導體裝置的製造 中係熟知的。 薄片斷裂可經由不同機制而發生。 126980.doc 31 - 200922808 磨損為藉由施加與薄片表面 割為藉由對薄片施加剪切力而產千:的之二:〜生的斷裂。切 藉由對薄片表面施加垂直力而產:的斷衣。屡縮或撞擊為 因於此等機制之組合。此…h㈣通吊斷w可歸 =ΓΤ生。舉例而言,材料研磨可…油墨: Α…所必需的液相混合操作期間發生。 機械誘發之磨損及藉由 應用期間發生,此時;切割通常在某些印刷 在凸版m 皮、通過師子。此情況之實例為 在凸版(flexo)印刷或凹 期間在塗刷器強制Ml ΰ應用’獨或在旋轉絲網應用 紋―系:==過篩子時油墨中之薄片與網 在稱為”刀磨法”之研磨:互作用。此相互作用類似於 由―刀=用之方法。在此方法中,藉 < 顆粒之旋轉總成來獲得研磨作用。 :擊式研磨可藉由與其他薄片或與用於後 设備:高速機械性相互作用而發生。 及塗佈之 ^如此’表面不規則性將集中施加於 生非均勾負載分布之情況。 員载產 勻負載分布展示於圖14a中。所施加之 二”破裂點(區域)位置而定而存在局部差異 而4 5 ’右認為因磨;fg ; l 底部出現之=二斷裂’則在區域1所指示之深層特徵 底部上的剪… 圖14b之區域2中所示之陰影特徵 底部之微社播 此外,如上文所解釋’預期深層特徵 -之破、、、α構比陰影特徵之微結構更易碎。 雖然本發明提供—種促使薄片沿邊框線而非沿標諸線或 126980.doc -32· 200922808 凹槽斷衣的方式,但下文所述之實施例在薄片自基板分離 後保濩薄片以防止不必要之進一步斷裂。圖^ 5展示已封裝 於一防護塗層中之薄片。 在此實粑例申’薄片可經高介電指數材料(諸如ZnS、This is accomplished by embossing an organic substrate such as a pet substrate with a border symbol, and then coating the substrate with a removable coating. Figure 8 is a photograph of the sheets separated from their base or substrate. This photo clearly shows that most symbols are integers, where few cracks appear to enter or pass through the symbols. By making = the invention, a very small portion of the sheet is broken in such a way that the symbol of the symbol is blurred. However, it is shown that the border does not exist along all sides of the sheet after the sheet has broken from the substrate on which it is deposited. - Some sheets have no boundaries and other sheets may have one and up to four boundaries. However, this is understandable. Since the border border separates the sheet from its nearest sheet, the boundary typically remains attached to a sheet and its adjacent sheet on the other side of the border of the border, when the sheet is separated. However, the presence of this border boundary causes most of the sheets to break at one side or the other side of the border line, providing a relatively uniform sheet with relatively straight edges. Typically, each of the signed 1-sheets will have at least a boundary or frame portion attached thereto after being separated from the web or substrate on which it is deposited. Preferably, the frame is easier to cut than other portions of the sheet. Figure 9 is a photograph of a plurality of Mg_Gn flakes carrying μ symbols in which stress cracks due to lack of a bezel and results in a distinct random break line, so that the flakes randomly break some symbols and destroy other symbols. Figure 9 illustrates the stress cracks throughout the sheet: due to the effect of such cracks, which cause thinning & the crack continues to appear in the sheet thereby blurring the sign. According to the present invention, the provision of the bezel does not completely prevent stress cracking, however, it is provided that the cracks can be controlled to a greater extent to be broken along the bezel line 4 or preferentially along the bezel line. In contrast to Fig. 9, an embodiment of the invention, shown in conjunction with Fig. 7 and showing, can be separated in a manner along the pre-126980.doc -28-200922808 boundary, thereby retaining a higher degree on the sheet. The shape and integrity of the symbols and generally do not obscure the hidden symbols in the sheet. Cracks that appear in unframed symbols appear and expand in more fragile, glass-like dielectric materials, but along Figure 7 The border line provided in the thin layer showing the symbol of the border is stopped and the path is changed to continue its expansion. The bezel is provided to cause the sheet to preferentially rupture along the border line. Most of the cracks observed in the sheet of Fig. 8 do not completely pass through. The total thickness of the sheet, which stops at the more elastic metal core (Al/Ni/Al) level of the sheet, creates a masking effect that is detrimental to the clarity of the original embossed symbol. The sheets in Figures 8 and 9 are approximately 1300 nm or ι·3 μm thick and has the following layer structure: 10 nm Cr/480 nm MgF2/80 nm AI/50 nm Ni/80 nm A1 480 nm MgFVlO nm Cr. There is a magnetic layer that provides the appearance characteristics. Turning now to Figure 10, it is missing a lot A photograph of a plurality of bordered symbols in a hidden symbol or a frame of a border, wherein the ratio of the symbol of the bordered frame to the other sheets is 1:1. There are two interesting aspects of this embodiment. At the detection level, it is equipped with 1 〇〇><Handheld Microscope can detect the presence of a hidden sheet with a Euro symbol, and in addition, it can quickly estimate the ratio of hidden and non-concealed symbols to approximately: In addition, it compares the ratio of square symbols to randomly shaped sheets to provide some measure of the identification. Thus, the shape, distribution, and identification of the symbols within the shape of the border can be used to determine the coating within a certain range of confidence. Whether the layer is believable. Although the sheet with the symbol enclosed by the border or border is usually broken into the desired shape along the border line or groove, as indicated by the euro with the border in Figure 1 , ', 126980.doc •29- 200922808 c There is a case where the sheet is undesirably broken along the embossed line forming the symbol. See > See Figure 11 a 'Showing the cut surface of the substrate u 仅 which is only a part of the array' More specifically, one can be seen a substrate of the entire sheet and a portion thereof adjacent thereto (other sheets are formed in the crucible). In this exemplary embodiment, 'because the character needs to be carried, JDSU', and the border or border frame of the attached label along the border U1 The breakage is such that the shape of the sheet is square, so the depth of the groove 形成 forming the boundary or the frame 1 1 1 is substantially deeper than the groove forming the mark 丨i 2 or the text 113. Preferably, the ratio of the depth of the bezel to the depth of the logo or text is at least 10:8 and preferably greater to ensure that the web is broken and severed along the border of the bezel, i.e., within the bezel of the bezel. Figure 11b is a cross-sectional analysis indicating the relative depth of embossing on the substrate. The groove of the frame is U-shaped and wider than the V-shaped and narrow groove defining the mark and the letter. Preferably, the coating material which coats the substrate and forms the sheet fills the grooves of the characters and logos more than the grooves of the filling frame. This increases the rupture of the bezel and reduces the rupturability of the grooves along the defined text or logo. Figure 11c corresponds to Figures Ua and Ub and is a normal view of the substrate. In contrast to Figure 11a, Figure 11d is a substrate having a mirrored relief wherein the bezel is defined by a wall and wherein the text and logo protrude from the bottom of the substrate. The figure shows the relative height of the walls and Figure Uf is the normal view of the substrate. The logo and bezel are still defined by the wall when the thin layer of the sheet is removed from the substrate. Figure 12a is a cross-sectional view of a prior art framed sheet wherein the grooves defining the indicia in the form of letters or logos have the same depth as the grooves defining the frame. Although the full double-walled u-shaped frame is shown to illustrate the difference between Figure i2a and Figure 1沘126980.doc -30- 200922808, but in the slice from the 1-wall u-frame, this is because:: "From the back 'usually will not Four sheets with double-twisted mouth horses should be indicated along the edge when the sheet is separated from the substrate = the dotted line is shown because of the groove in Figure 12a: the position at which the sheet will be severed. However, it is very likely that you will be thin and sloppy, and you can see the 'definite symbol _ as observed in the uniform phase 12b ^ ^ The width or depth of the groove is about the height or depth of the groove defining the frame. . m half, that is, the border is darker than the symbol. Most of the tf_ surplus sheets will be cut along the border. The groove is cut rather than cut along the symbol groove... The border groove and symbol groove are 4:2 or larger.勹主八2 and better display the sheets in Figures 12a and 12b with Qiu Yue also open 1 μ "all hook coating, in which the thickness of the top, bottom 4 and side panels are substantially the same. Use coated physical gas Phase, VJ technology (ie, evaporating or sputtering the material of the impinging material on the normal or near normal line) onto the top, bottom and side walls The 目 目 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上 上This results in a change in thickness. For an extremely inclined trajectory, the opening of the groove in the deeper groove will have a coating that is thinner than the bottom. This is desirable in the case where the sheet is broken along the groove. The higher the ratio, the greater the difference between the features at the bottom, top and sidewalls. This phenomenon is well known in the fabrication of semiconductor devices having high aspect ratio features. Flake fracture can occur via different mechanisms. Doc 31 - 200922808 The damage is produced by applying a shearing force to the surface of the sheet by the application of shearing force to the sheet: the second: the fracture of the raw. The cut is produced by applying a vertical force to the surface of the sheet: The impact is due to a combination of these mechanisms. This ... h (four) pass hang w can be returned to the health. For example, material grinding can be ... ink: Α ... necessary liquid phase mixing operation occurs. Mechanically induced wear and tear By the time of application, at this time; the cut is usually printed on the letterpress m, passing through the division. An example of this is to force the Ml ΰ application in the squeegee during flexo printing or concave. Rotating screen application pattern: == When the sieve is used, the sheet and the web in the ink are called “knife grinding method”: interaction. This interaction is similar to the method used by “knife=.” The grinding effect is obtained by the rotation assembly of the particles. The impact grinding can be performed by interacting with other sheets or with the rear equipment: high-speed mechanical interaction. Sex will be concentrated on the non-homogeneous load distribution The load distribution of the load is shown in Figure 14a. There is a local difference depending on the position of the two "rupture points (regions) applied and 4 5 'right is considered to be grinding; fg; l appears at the bottom = two fractures' Then the cut on the bottom of the deep feature indicated by area 1... The micro-cosm of the bottom of the shadow feature shown in area 2 of Figure 14b, in addition, as explained above, the 'expected deep feature' - the break, the alpha-conformity shadow The microstructure of the features is more fragile. Although the present invention provides a means for causing the sheet to break along the border line rather than along the line or 126980.doc -32.200922808, the embodiments described below protect the sheet from separation after separation of the sheet from the substrate to prevent It is not necessary to break further. Figure ^5 shows a sheet that has been encapsulated in a protective coating. In this example, a thin sheet can be passed through a high dielectric index material (such as ZnS,

Ti02、SiOx、Al2〇3等)塗佈或介電/金屬多層薄片可經增強 符號觀測性之半透明材料(諸如溶膠_凝膠(si〇x))塗佈。若 薄片用η<1.65之低折射率材料製成,則用高折射率材料(亦 即η大於或等於U5)封裝薄片可產生具有二向色性之微結 構化薄片此實鈿例基本上為形成具有隱蔽功能以及類似 於:光顏料之視覺光學效應的成形/具有符號之薄片的交 替尚/低/咼所有介質層之堆疊。 有利地’封裝製程將不僅改良薄片之耐久性,且亦可向 微結構化薄片提供額外功能。熟知與真空氣相沈積技術 (PVD或CVD)相&,藉由溶膠_凝膠或其他濕式化學方法封 裝為非表面相容的。舉例而t,此係用於眼科光學塗料中 以遮蔽在模製眼鏡製程期間之刮痕或其他表面缺陷。 在濕式化學方法中藉由非4日六& 戸相谷性塗料封裝將傾向於填充 壓花薄片中所存在之諸如凹槽的空隙,減少已處於薄片易 碎區域上之非均勻負載’從而改良斷裂性質。才目比之下, 相容性塗層為在不同於該(等)層所沈積之基板微結構的各 處將具有大體相同厚度之塗層。非相容性塗層(例如濕式 化學塗層)將具有填充微結構中之間隙的傾向且因此使薄 片”平坦化"。此極為有利’因為其提供將薄片壓花使得可 看見視覺效應之益處’且其中薄片接著以保存或增強視覺 126980.doc -33 - 200922808 效應之方式平坦化。The coated or dielectric/metal multilayer sheets of Ti02, SiOx, Al2〇3, etc. can be coated with a semi-transparent material (such as a sol-gel (si〇x)) that enhances the symbolic observation. If the sheet is made of a low refractive index material of η <1.65, then encapsulating the sheet with a high refractive index material (i.e., η greater than or equal to U5) can produce a microstructured sheet having dichroism. A stack of alternating/low/咼 all dielectric layers of a shaped/signed wafer having a concealing function and similar to the visual optical effect of the light pigment is formed. Advantageously, the packaging process will not only improve the durability of the sheet, but also provide additional functionality to the microstructured sheet. It is well known to be compatible with vacuum vapor deposition (PVD or CVD) and is non-surface compatible by sol-gel or other wet chemical methods. By way of example, this is used in ophthalmic optical coatings to mask scratches or other surface imperfections during the molding process. In a wet chemical process, a non-four-day six & phase-grain coating will tend to fill the voids such as grooves present in the embossed sheet, reducing the non-uniform load that is already on the fragile area of the sheet. Thereby improving the fracture properties. In some cases, the compatible coating will have a coating of substantially the same thickness at various locations different from the substrate microstructure deposited by the (etc.) layer. An incompatible coating (such as a wet chemical coating) will have a tendency to fill the gaps in the microstructure and thus "flatten the sheet". This is extremely advantageous 'because it provides embossing of the flakes for visible visual effects The benefit of 'and where the flakes are then planarized in a manner that preserves or enhances the effect of the 126980.doc -33 - 200922808 effect.

itC ^ 不/入Ρ品工業之”可 食用薄片’’具有特定適用性。許多經FDA批准用於消費 用於"可食用薄片"的材料包括介電材料,諸如&〇'ItC ^ does not enter the "edible flakes" of the pharmaceutical industry's specific applicability. Many FDA approved materials for consumption "edible flakes" include dielectric materials such as &

TiOx、A10x、Fe0〆然而,此等材料比金屬或聚合材料更 易碎且已發現根據本發明内之教示,如更通常已知之製造 ’’可食用小飾物(charm)"或"可食用薄片,,,其中邊框比薄片 内之標誌更易斷裂,且用溶膠-凝膠或其他防護塗層塗佈 此等更易碎薄片極為有利於預防一些在後加工期間另外可 能發生之斷裂。 亦在藉由封裝方法用半透明延展性材料塗佈之薄片中看 到對於斷裂性之改良。在此情況下,藉由在真空下沈積柔 軟半透明聚合材料之薄層來塗佈薄片。—種適當沈積法為 所明之電桌聚合。熟知此方法用於塗佈、丁丨〇、%或 COxHy(其為Si〇2、Ti〇2及金剛石狀碳之電漿增強化學氣相 沈積(CVD)之變化形式)。此外,一些聚合物可經物理氣相 沈積蒸發或甚至濺射以產生微結構化隱蔽標記之功能或改 良其耐久性。 【圖式簡單說明】 圖1為具有安全特徵之文件之一部分的平面圖。 圖2A為具有壓花部分及未經壓花部分之沈積基板的一部 分之簡化圖。 圖2B為具有壓花部分13,及未經壓花部分丨5之另一沈積 基板11’的—部分之簡化圖。 126980.doc -34- 200922808 圖3A為圖1中所示安全特徵14之一部分14A的簡化平面 圖。 圖3B為亮顏料薄片之簡化截面。 圖3C為提供元素指紋之亮薄片20,的簡化截面。 圖3D為根據本發明之另一實施例之變色顏料薄片30的簡 化截面。 圖4為根據本發明之一實施例具有分散於載劑中的不透 明隱蔽薄片之清漆的截面。 *圖5為根據本發明之另一實施例分散於黏合劑中之基質 薄片及不透明隱蔽薄片的截面。 土 圖6為根據本發明之一實施例製作顏料薄片之方法的流 程圖。 圖7為㈣複數個各藉由壓花至基板之方形邊框或邊界 加邊框的歐元符號之薄層的照片。 、2 8為複數個各具有歐元符號且大部分具有包圍該符號 的70整或部分邊框之Mg-Gn變色薄片的照片。 圖9為薄片上複數個Mg_Gn μ符號之照片,其中由於缺乏 邊框該等薄片因斷裂線而隨機斷裂,保留一些符號且破壞 其他符號。 圖10為較大量缺少任何隱蔽符號或邊框的薄片中複數個 加邊框的符號之照Μ 中加邊框符號與其他薄片之 1:10 〇 '、·、 圖1 la為說明基板内之邊框凹槽深度的切去之經壓花基 板的等角視圖。 土 126980.doc -35- 200922808 圖lib為圖lla中所示基板之截面分析。 圖H c為圖11 a之基板之法線視圖。 圖lid為說明自基板突出之邊框壁及標識壁之高度的切 去之經壓花基板的等角視圖。 圖lie為圖lid中所示基板之截面分析。 圖Ilf為圖lid之基板之法線視圖。 圖12a為關於具有均勻塗層之先前技術薄片之截面的說 明。TiOx, A10x, Fe0 However, such materials are more brittle than metals or polymeric materials and have been found to be made according to the teachings of the present invention, as is more generally known to produce ''meal'" or " edible Sheets, where the borders are more susceptible to breakage than marks in the sheets, and coating such more fragile sheets with a sol-gel or other protective coating is highly advantageous in preventing some otherwise breakage that may occur during post processing. Improvements in fracture properties are also seen in sheets coated with a translucent ductile material by a packaging method. In this case, the sheet is coated by depositing a thin layer of soft translucent polymeric material under vacuum. An appropriate deposition method is the electricity table polymerization described. This method is well known for coating, butan, % or COxHy, which is a variation of plasma enhanced chemical vapor deposition (CVD) of Si〇2, Ti〇2 and diamond-like carbon. In addition, some polymers may be vaporized by physical vapor deposition or even sputtered to create a function of microstructured concealed indicia or to improve their durability. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a plan view of a portion of a document having security features. Figure 2A is a simplified diagram of a portion of a deposition substrate having an embossed portion and an unembossed portion. Fig. 2B is a simplified view of a portion having the embossed portion 13 and the other deposited substrate 11' of the unembossed portion 丨5. 126980.doc -34- 200922808 Figure 3A is a simplified plan view of a portion 14A of one of the security features 14 shown in Figure 1. Figure 3B is a simplified cross section of a bright pigment flake. Figure 3C is a simplified cross section of a bright sheet 20 providing an elemental fingerprint. Figure 3D is a simplified cross section of a color changing pigment sheet 30 in accordance with another embodiment of the present invention. Figure 4 is a cross section of a varnish having an opaque concealed sheet dispersed in a carrier in accordance with one embodiment of the present invention. * Figure 5 is a cross section of a substrate sheet and an opaque concealing sheet dispersed in a binder according to another embodiment of the present invention. Figure 6 is a flow diagram of a method of making a pigment flake in accordance with an embodiment of the present invention. Figure 7 is a photograph of (iv) a plurality of thin layers of euro symbols each embossed to the square border or border of the substrate. And 28 are photographs of a plurality of Mg-Gn color-changing sheets each having an euro symbol and most having a 70-part or partial border surrounding the symbol. Figure 9 is a photograph of a plurality of Mg_Gn μ symbols on a sheet in which the sheets are randomly broken due to the broken line due to the lack of a frame, retaining some symbols and destroying other symbols. Figure 10 is a photograph of a plurality of bordered symbols in a sheet lacking any hidden symbols or borders. The border symbol and other sheets are 1:10 〇', ·, and Figure 1 la is a frame groove in the substrate. An isometric view of the embossed substrate with a deep cut. Soil 126980.doc -35- 200922808 Figure lib is a cross-sectional analysis of the substrate shown in Figure 11a. Figure Hc is a normal view of the substrate of Figure 11a. Figure lidd is an isometric view of the cut embossed substrate illustrating the height of the bezel wall and the identification wall from the substrate. Figure lie is a cross-sectional analysis of the substrate shown in Figure lid. Figure Ilf is a normal view of the substrate of the lid. Figure 12a is an illustration of a cross-section of a prior art sheet having a uniform coating.

其中邊 圖1沘為關於根據本發明之薄片之截面的說明 框深度約為符號深度的兩倍。 其中壁 圖13a為關於根據本發明之薄片之截面的說明 上之塗層比底部之塗層薄。 圖13b為關於根據本發明之薄片之戴面的說明。 圖14a為關於薄片凹槽之截面 m田的說明,其中頂壁之塗層 比凹槽槽底之塗層厚,有利於幫 寬助溥片沿凹槽斷裂。 圖14b為關於展示均勻塗層厚 & 用以界定薄片符號之 凹槽的說明。 其中薄片封裝於 圖15為關於根據本發明之薄片的說明 一透光性防護塗層中。 【主要元件符號說明】 10 文件 11 沈積基板 11, 沈積基板 12 安全特徵 126980.doc -36 - 200922808 13 壓花部分 13' 壓花部分 14 安全特徵12之至少一部分 14A 安全特徵14之至少一部分 15 未經壓花部分 16 基質顏料顆粒 17 一卷 18 隱蔽顏料薄片/成形隱蔽薄片 19 另一卷 20 亮顏料薄片 20' 亮薄片 22 反射層 22' 反射層 22" 反射層 24 介電薄膜層 24' 介電薄膜層 26 介電薄膜層 26' 介電薄膜層 28 元素指示劑層 30 變色顏料薄片/隱蔽顏料薄片 32 薄膜堆疊 34 反射金屬層 36A 分隔層 36B 分隔層 126980.doc -37- 200922808 38A 吸收層 38B 40 42 44 46 48 50 52 110 111 吸收層 清漆 隱蔽薄片 載劑 可選顏色塗層/亮塗料 目標物 組合物 黏合劑/載劑 基板 邊框邊界/邊界/邊框/凹槽 112 標識 113 文字1A is an illustration of a section of a sheet according to the present invention. The depth of the frame is about twice the depth of the symbol. Wherein the wall Figure 13a is a coating on the section of the sheet according to the invention which is thinner than the coating on the bottom. Figure 13b is an illustration of a wearing surface of a sheet according to the present invention. Fig. 14a is an illustration of a section of a sheet groove in which the coating of the top wall is thicker than the coating of the bottom of the groove, which facilitates the rupture of the gusset along the groove. Figure 14b is an illustration of a groove showing the uniform coating thickness & The sheet is packaged in Fig. 15 for a description of the sheet according to the invention in a light transmissive protective coating. [Major component symbol description] 10 Document 11 Deposition substrate 11, Deposition substrate 12 Security features 126980.doc -36 - 200922808 13 Embossed portion 13' Embossed portion 14 At least a portion of security feature 12 14A At least a portion of security feature 14 15 Embossed portion 16 matrix pigment particles 17 roll 18 concealed pigment flakes/formed concealed flakes 19 another roll 20 bright pigment flakes 20' bright flakes 22 reflective layer 22' reflective layer 22" reflective layer 24 dielectric film layer 24' Electro-film layer 26 Dielectric film layer 26' Dielectric film layer 28 Element indicator layer 30 Color-changing pigment sheet/concealed pigment sheet 32 Film stack 34 Reflective metal layer 36A Separation layer 36B Separation layer 126980.doc -37- 200922808 38A Absorbing layer 38B 40 42 44 46 48 50 52 110 111 Absorbent layer varnish concealed sheet carrier optional color coating / bright coating target composition adhesive / carrier substrate border border / border / border / groove 112 logo 113 text

126980.doc -38-126980.doc -38-

Claims (1)

200922808 十、申請專利範圍: 1 種複數個顏料標記薄片,各薄片包含一位於由壁界定 之薄片周圍之邊框及一位於該邊框内之區域,其中該等 邊框壁中之至少一者的高度為至少高度Fh,且其中該邊 框内之區域具有藉由其中所形成之一或多個深度小於工d 之凹槽所界定之標誌,其中Fh>Id。 2. 如請求項1之複數個顏料薄片,其中各薄片具有大體上 平坦之上表面,其中該等壁自該平坦表面向下延伸且其 中該一或多個凹槽向下延伸。 3. 如請求項1之複數個顏料薄片,其中該標誌為符號或標 識。 4. 如請求項1之複數個顏料薄片,其中該等薄片之每一者 具有相同之符5虎或標識。 5. 如請求項1之複數個顏料薄片,其中該Fh/Id為至少15。 6. 如請求項1之複數個顏料薄片,其中各薄片係封裝於一 塗料中。 7·如請求項6之複數個顏料薄片,其中該塗料係選自金 屬、金屬化合物 '氧化物、硝酸鹽、聚合物及金屬陶瓷 之群。 8. 如請求項1之複數個顏料薄片,其中該一或多個凹槽為V 形凹槽。 9. 如請求項8之複數個顏料薄片,其中該一或多個凹槽為U 形凹槽。 1 0.如請求項1之複數個顏料薄片,其中該標誌僅可在放大 126980.doc 200922808 倍數下看見。 11. 如請求項2之複數個顏料薄片,其中該每—薄片係由多 層塗料組成以提供一可見光學效應。 12. 種用於形成標記薄片之標記區域薄層,其包含: a) —經具有一深度Fh之邊框凹槽壓花之基板及複數個 位於各邊框内之標誌凹槽,其中該等標誌凹槽之深度係 =於1:,且其中Fh>Id,使得當該薄層上之一塗層分離為200922808 X. Patent Application Range: A plurality of pigment marking sheets, each sheet comprising a frame located around a sheet defined by the wall and an area located within the frame, wherein the height of at least one of the frame walls is At least a height Fh, and wherein the region within the bezel has a mark defined by a groove in which one or more depths are formed less than the work d, where Fh > Id. 2. The plurality of pigment flakes of claim 1, wherein each of the flakes has a substantially flat upper surface, wherein the walls extend downwardly from the flat surface and wherein the one or more grooves extend downwardly. 3. A plurality of pigment flakes as claimed in item 1, wherein the sign is a symbol or a logo. 4. A plurality of pigment flakes as claimed in claim 1, wherein each of the flakes has the same symbol 5 tiger or logo. 5. The plurality of pigment flakes of claim 1, wherein the Fh/Id is at least 15. 6. The plurality of pigment flakes of claim 1, wherein each of the flakes is encapsulated in a coating. 7. The plurality of pigment flakes of claim 6, wherein the coating is selected from the group consisting of metals, metal compounds 'oxides, nitrates, polymers, and cermets. 8. The plurality of pigment flakes of claim 1, wherein the one or more grooves are V-shaped grooves. 9. The plurality of pigment flakes of claim 8, wherein the one or more grooves are U-shaped grooves. 1 0. A plurality of pigment flakes as claimed in claim 1, wherein the logo is only visible at a magnification of 126980.doc 200922808. 11. The plurality of pigment flakes of claim 2, wherein each of the flakes is comprised of a plurality of layers of paint to provide a visible optical effect. 12. A thin layer of marking regions for forming a marking sheet, comprising: a) a substrate embossed through a frame groove having a depth Fh and a plurality of marking grooves located in each of the frames, wherein the markings are concave The depth of the groove is =1, and wherein Fh>Id, such that when one of the coatings on the thin layer is separated 心Λ溥片a寸’與沿該等標誌凹槽相&,更可能沿邊框凹 槽發生斷裂;或 b) 一級具# —高度Fh之邊框壁壓花之基板及複數個位 I於各邊框内之標誌壁,其中該等標誌壁之高度係小於 '、中Fh>Id,使得當該薄層上之一塗層分離為標記 '片時’與沿該等標諸壁相比,更可能沿該等邊框壁發 13.::求項12之標記區域薄層,其中該等邊框凹槽之截面 具有一與該等士 邊框壁之截面不同的剖面’或其中該等 14•士… 有一與該等標誌壁之截面不同的剖面。 叫〆項13之標記區域薄 凹槽中之—本、 导層其中5亥邊框凹槽及該標誌 之另—土 為錐形且其中該邊框凹槽及該標誌凹槽中 者具有平行側壁。 15.::求項12之標記區域薄層 塗佈之網,且1中…》 經塗枓 16•一種 八中該荨己薄片係由該塗料形成。 之至少兩:顏料標記薄片,各薄片包含-位於由壁界定 〜固薄片側面周圍之邊框及一位於該邊框内之區 126980.doc 200922808 域,其中該等邊框壁中之至少一者的高度為至少高度 Fh,且其中該邊框内之區域具有藉由其中所形成之一或 多個深度小於id之凹槽界定的標誌,其中Fh>^。 1 7 · —種複數個壓花顏料隱蔽標記薄片, u碍乃,其係經透光性非相 容性塗料塗佈’從而減少該薄片内之凹槽的深度。 18·如請求項17之複數個壓花薄片,#中該非相容:塗料有 效使該等薄片平坦化。The heart-shaped piece a inch' is more likely to be broken along the groove of the frame along the groove of the mark; or b) the base plate of the frame wall embossed with the #-height Fh and a plurality of bits I a flag wall within the frame, wherein the height of the flag walls is less than ', Fh> Id, such that when one of the coatings on the layer is separated into a mark 'sheet', as compared to the walls along the standard May be along the walls of the bezel 13.:: a thin layer of the marked area of claim 12, wherein the cross-section of the bezel has a profile that is different from the cross-section of the bezel wall or where the 14... There is a section that is different from the cross section of the flag walls. In the thin area of the marking area of the item 13, the inner layer of the guiding layer and the other side of the marking are tapered, and wherein the frame groove and the marking groove have parallel side walls. 15.:: Thin layer of the marked area of the item 12 coated web, and 1 ..." 经 枓 16 • A type of 中 荨 薄片 薄片 薄片 薄片 薄片 薄片 薄片 薄片 薄片 薄片 薄片 薄片 薄片 薄片 薄片At least two: pigment marking sheets, each sheet comprising - a border defined by the wall defining a periphery of the solid sheet and a region within the border 126980.doc 200922808, wherein the height of at least one of the border walls is At least a height Fh, and wherein the region within the border has a mark defined by a groove in which one or more depths are formed less than id, where Fh > 1 7 - a plurality of embossed pigment concealed marking sheets, which are coated with a light transmissive non-compatible coating to reduce the depth of the grooves in the sheet. 18. If the plurality of embossed sheets of claim 17 are incompatible, the coating is effective to planarize the sheets. 19·如請求項17之複數個壓花薄片,其中該非相容性塗料為 溶膠-凝膠塗料。 20.如請求項【之複數個顏料標記薄片,其中該等薄片經非 相容性塗料塗佈,該非相容性塗料減少該等凹槽之深 度’且其中該標誌未因該塗料而模糊。 .如請求項20之複數個顏料標記薄片,其中該非相容性塗 料增強該標諸與背景之間的對比使得該標誌變得更可 見。 22·如請求項20之複數個顏料標記薄片,其中該等顏料標記 薄片為可食用薄片。 23·如請求項17之複數個顏料標記薄片,其中該等顏料標記 薄片為可食用薄片。 24. —種箔,其包含一基板,該基板具有可釋放地沈積於其 上以用於在自該基板移除後即形成薄片之一或多個薄膜 層,該一或多個薄膜層具有複數個形成於其中之形成凹 槽或脊之加邊框的符號,其中該等符號周圍之該等邊框 為該等薄片提供線以在自該基板移除該一或多個薄膜層 126980.doc 200922808 時該等薄片沿該等線分離,且其中該等邊框具有比該等 符號深的凹槽。 C19. The plurality of embossed sheets of claim 17, wherein the incompatible coating is a sol-gel coating. 20. The claim [a plurality of pigmented indicia sheets, wherein the sheets are coated with an incompatible coating, the incompatible coating reduces the depth of the grooves] and wherein the indicia is not obscured by the coating. A plurality of pigment-labeled sheets of claim 20, wherein the incompatible coating enhances the contrast between the label and the background such that the indicia becomes more visible. 22. The plurality of pigment-labeled sheets of claim 20, wherein the pigment-labeled sheets are edible sheets. 23. The plurality of pigment-labeled sheets of claim 17, wherein the pigment-labeled sheets are edible sheets. 24. A foil comprising a substrate having releasably deposited thereon for forming one or more thin film layers after removal from the substrate, the one or more thin film layers having a plurality of symbols formed in the frame forming grooves or ridges, wherein the borders around the symbols provide lines for the sheets to remove the one or more film layers from the substrate 126980.doc 200922808 The sheets are separated along the lines, and wherein the borders have grooves deeper than the symbols. C 126980.doc126980.doc
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