TW200305589A - Composition containing a polymer or copolymer of a 3, 4-dialkoxythiophene and non-aqueous solvent - Google Patents

Abstract

A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3, 4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3, 4- dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: (i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3, 4- dialkoxythiophene) and the polyanion; and (ii) evaporating water from the mixture prepared in step (i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above- described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste.

Description

200305589 A7 B7 V. Description of the invention (1) Field of the invention The present invention relates to a method for preparing a composition containing a polymer or copolymer of 3,4-dialkoxythiophene and a non-aqueous solvent. 5 Background of the invention US 5,494,609 discloses a conductive coating composition comprising: a dispersion liquid containing dispersed particles of an essentially conductive polymer; and a hydrophobic thin film-forming thermoplastic polymer contained in an organic solvent; And the anhydride anhydride surfactant solution; wherein the thermoplastic polymer is soluble in the solvent at least 1 weight percent; and wherein the dispersion system comprises the essentially conductive polymer from about 1 to about 50 weight percent. EP-A 440 957 discloses a dispersion of polysigmaphene composed of structural units of the general formula (I):

s〆 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economics, where R1 and R2 individually represent nitrogen or C1-C4-alkyl or together form a 20-substituted Cm-alkylene group, which contains a polymeric anion. EP-A-686 662 discloses a mixture of the following compounds: A) Neutral polythiophene with a recurring structural unit of the general formula (I), -3- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297) «) 200305589 A7 B7 V. Description of the invention (2)

Among them, R1 and R2 respectively represent hydrogen or C1-C4-alkyl, or together represent optionally substituted Cl, alkylene, optionally substituted methylene, C ^ 2-alkyl or 1,2-Ethyl or 1,2-cyclohexyl substituted by phenyl is preferred, and B) Organics containing di- or more light groups- and / or retarders or amidines or 10 internal amido groups Compounds; and conductive coatings made by them, which are adjusted to increase electrical resistance, preferably up to &lt; 300 ohms / square. WO 99/34371 discloses a screen printing paste having a viscosity of 1 to 200 dPa · s (102 to 2xl04 mPa · s), containing a conductive polymer paste and a solution or dispersion, a selective binder, a thickener, and filler. WO 15 99/34371 also discloses a method for preparing screen paste, in which (3,4-ethylenedioxythiophene) [PEDOT] / poly (styrene sulfonic acid) is printed by the Shelley Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Ester) [PSS] A solution or dispersion with a content of <2% by weight is concentrated to a solids content of> 2% by weight by removing the solvent, where a binder and / or a filler are added as appropriate. Example 1 discloses a method of evaporating water to obtain a 3 weight percent solid dispersion in a rotary evaporation apparatus at 45 ° C and 20 hPa (mbar) from a 1.3 weight percent solid dispersion of PEDOT / PSS in water. EP-A 1 081 549 discloses a coating composition comprising a solution of a substituted or unsubstituted thiophene-containing conductive polymer, a film-forming adhesive, and an organic solvent medium; the medium has a weight percentage of less than 37 -4- This paper size is subject to Chinese National Standard (CNS) A4; (210 X 297 male *) 200305589 A7 B7 V. Water content of invention description (3). Contains 1.0 weight percent PEDOT / PSS—that is, 0.0294 weight percent PEDOT, because BAYTRON® P contains a weighted PEDOT to PSS ratio of 1: 2.4 and a coating dispersion system containing water between 8 and 25 weight percent Disclosed in the examples of the present invention, a 1.22 weight percent dispersion of 5 BAYTRON® P-PEDOT / PSS in water is used as the starting material. EP-A 1 081 546 discloses a coating composition comprising a conductive polymer and an organic solvent medium, wherein the solvent is selected from the group consisting of alcohols, alcohols, naphthenes, aromatic hydrocarbons, esters, glycol ethers, and mixtures thereof. Group; the medium has a water content of less than 12 weight percent. PEDOT / PSS concentration between 0,02 and 0.1 weight percent-PEDOT between 0.00588 and 0.0294 weight percent, because BAYTRON⑧P contains 1 ·· 2 · 4 of PEDOT to PSS weight ratio and water content between A coating dispersion system between 2 and 8 weight percent is disclosed in the examples of the present invention, using 15 BAYTRON® P-PEDOT / PSS 1.22 weight percent dispersion 1 as a starting material. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, EP-Α 1 081 548, discloses a coating composition comprising a substituted or unsubstituted thiophene-containing conductive polymer and an organic solvent medium; the water content of the medium is lower than 12 weight percent. PEDOT / PSS concentration between 20 0.02 and 0.1 weight percent-PEDOT between 0.00588 and 0.0294 weight percent, because BAYTRON® P contains a PEDOT to PSS weight ratio of 1: 2,4 and a water content between The coating dispersion system between 2 and 8 weight percent is disclosed in the examples of the present invention, using 1.22 weight percent of BAYTRON⑧P-PEDOT / PSS in water. -5- This paper size applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm) 200305589 A7 B7

Diffusion—as starting material. WO 02 / G42352 discloses a method for manufacturing a water-dispersible powder. The powder is basically composed of polymer particles τ having heavy phen units and at least one other polymeric anionic polymer ρ, which is characterized by containing The dispersion or solution of the polymer T is mixed with a compound-forming an azeotrope with water-and the water is removed by a masonic steaming hall, and the obtained polymer is isolated and dried. 10 15 Shelley Consumer Goods Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs 20 WO 02/067273 Uncovered-A method for exchanging solvents in a mixture containing water and optionally substituted polyphene, the method includes: a) in a container Heating at least one solvent under conditions suitable for evaporation of water; b) contacting the heated solvent with a mixture containing water and optionally substituted polythiophene, the contact being sufficient to remove at least from the mixture in the form of steam A portion of the water; and c) using the solvent to exchange water removed from the mixture. WO 02/072660 discloses a method for preparing a dispersion or solution, which contains optionally substituted polythiophene in an organic solvent, which is characterized by a) a water-miscible organic solvent or a water-miscible organic solvent The mixture is added to a dispersed or aqueous solution containing optionally substituted polythiophene, and b) at least a portion of the water is removed from the formed mixture. WO 02 / 072Ή4 discloses a solution and / or dispersion of an organic semiconductor in a solvent mixture of at least two organic solvents, which is characterized by (the solvent itself has a boiling point below 200 ° C and points at or below 15t, B) at least one solvent has a melting point between i40 ° C and 20 (TC), (C) the solvent used does not contain benzyl CHr · or CH- groups, ①) the solvent used for Buddha is not derived from benzene It contains tertiary butyl substituents or more than two = -6- 200305589 A7 B7 V. Description of the invention (5) 5 10 15 The 20 methyl substituents are printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Medium == In terms of 'the coating of the conductive polymer dispersion is expected to be non-aqueous to help the surface wetting' and to reduce the drying time, the second is to avoid excessive dilution of the conductive polymer, and high conductivity The degree of polymer should be as much as possible. This can be done by using an organic solvent to dilute the conductive polymer to overly dilute it to two hundred knives. For example, the same as ΕΡ-Α 1 081 546, ΕΡ-Α 1 081 548 and EP-Α 1 081 549. Therefore, according to the aspect of the invention, The aspect of the invention provides a method for preparing an aggregate. The composition is a conductive polymer having a concentration of at least 0 08 weight percent in most non-aqueous media or an aqueous medium having a solvent concentration of at least 30 weight percent. Another aspect of the present invention is to provide a coating composition, which is a conductive polymer containing a concentration of at least 0.08% by weight in most non-aqueous media or an aqueous medium having a solvent concentration of at least 30% by weight. One aspect is to provide a coating method for coating a composition which is conductive in a non-aqueous medium or an aqueous medium having a solvent concentration of at least 30% by weight and having a roll of at least 008% by weight. Another aspect of the present invention is to provide a printing ink or paste, which is based on most non-aqueous media or solvents with an aqueous concentration of at least 30% by weight.

This paper size applies to Chinese painting standard (CNS) A4 size X 297 public policy T 200305589 A7 _ B7 V. Description of the invention (6) The medium contains a conductive polymer with a concentration of at least 0.08% by weight. Another aspect of the present invention is to provide a printing method for printing a printing ink or paste. The ink or paste contains at least 0% in most non-aqueous media or aqueous media having a concentration of at least 30% by weight at a concentration of 5 degrees. Conductive polymer at a concentration of 8 weight percent. Other aspects and advantages of the invention will be apparent from the following description. SUMMARY OF THE INVENTION 1 2% by weight of 10 W0 99/34371 Example 1 evaporated in water at 60 ° C and 50 hPa (mbar) pedoT / PSS Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Because the viscosity of the dispersion increases, only 60% of the water can be removed. When the extremely viscous PEDOT / PSS material formed—containing 96% by weight of water and 4% by weight of pEDOT / PSS—diluted with 15 times the non-aqueous solvent, the formed slurry still contained 50 to 55% by weight of water. When the PEDOT / PSS substance is further diluted to a non-aqueous solvent of 70 to 85 weight percent, a non-uniform dispersion with a lower viscosity is produced. It was unexpectedly found that adding 1.2% by weight of a non-aqueous solvent to PEDOT / PSS in water before evaporating the water can remove more than 60% of the water, and can prevent the colloidal instability of PEDOT / PSS-latex Remove more than 99% of the water. The aspect of the present invention is achieved by a method for preparing a composition, which is a polymer or copolymer containing 3,4 · dialkoxythiophene between 0.08 and 3.0 weight percent. The two alkoxy groups may be the same or similar. 8- This paper is scaled according to the National Standard (CNS) A4 specification (21〇χ 297 公 f 200305589 A7 B7 V. Description of the invention (7) XOR together means that it may be replaced as appropriate. An oxy-alkylene-oxy bridge, a polymeric anion, and at least one non-aqueous solvent selected from a polymer or copolymer of (3,4-dialkoxythiophene) and a dispersion of a polymeric anion in water, which It is prepared in the absence of substantially oxygen, and the method comprises the following steps and 5 steps in sequence: 〇 Disperse an aqueous solution of at least one non-aqueous solvent and a polymer or copolymer of (3,4-dialkoxythiophene) Mixing with the polymeric anion; and ii) evaporating water from the mixture prepared in step 0 until the water content therein is reduced by at least 65 weight percent. The aspect of the present invention can also be achieved by a coating composition, which can be generated from a layer having improved conductivity at a specific transparency of 10, which is prepared according to the aforementioned method. The aspect of the present invention can also be achieved by a coating method, which includes the following steps: providing the aforementioned coating composition; and coating the coating composition on a carrier, dielectric layer, calender layer, or transparent conductive layer that has been rubbed as appropriate. In order to produce 15 layers with improved conductivity at a specific transparency. The aspect of the present invention is also achieved by a printing ink or paste, which can be generated from a layer having an improved conductivity at a specific transparency, and is prepared according to the aforementioned method. The printing of the present invention by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is also achieved by a printing method, which includes the following steps: 20 providing the aforementioned printing ink; printing the printing ink on a frictional carrier and dielectric layer as appropriate , Calendered layer or transparent conductive layer to produce a material layer with improved conductivity under specific transparency. Preferred specific examples are disclosed in the scope of the attached patent application. -9- The paper standard is CKiS A4 specification (21G X 297 male 1) 200305589 Α7 Β7 V. Description of the invention (ο Detailed description of the invention defines oxo ^ The meaning of the word ^ means the meaning of each All possible changes in the number of carbon atoms' that is, for three carbon atoms ... n-propyl and isopropyl; for five or four carbon atoms: n-butyl, isobutyl and third butyl; For five carbon atoms: n-pentyl, 1,1-dimethyl-propyl, 2,2-dimethylpropyl, 2-methyl-butyl, etc. Refers to two oxygen atoms bonded by an alkylene group. A substituted or unsubstituted alkylene group, such as-(CH2) n_ * 10 group, where η is an integer between 1 and 5, which Can pass alkoxy, aryloxy, alkyl, aryl, alkaryl, alkyloxyalkyl, alkyloxyalkaryl, alkyloxyaryl, hydroxyl, carboxyl, carboxyalkyl, carboxyamine , Sulfo or alkylsulfo. Derivatives used with a particular polymer mean that they are alkyl, 15alkoxy, alkyloxyalkyl, carboxyl, alkylsulfonate and carboxyl Substituted by an ester group Variation. The term "non-aqueous solvent" is the opposite of the term "a non-aqueous solvent" which means a single non-aqueous solvent, which means one or more non-aqueous solvents. The Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs prints "multiple The term hydroxyl non-aqueous solvent means a non-aqueous solvent having at least two hydroxyl groups. The term azeotrope or azeotrope used in the present invention means a solution of two or more liquids, the composition of which is It will not change during distillation. The term used to reveal the solution of the present invention means a mixture of at least one solid in at least one solvent, which is a liquid and wherein the solid is a molecular solvent. (CNS) A4 regulation (210 X 297 mm f 200305589 A7 __ B7 V. Explanation of the invention (9) Solution, that is, most of the solid molecules are actually dissolved without aggregates or nano or micron particle forms. Reveal The term dispersion as used in the present invention means a mixture of at least one solid in at least one solvent, which is a liquid and in which the solid is non-fractionally soluble, that is, most of the solid The polymer is not dissolved, but in the form of aggregates or nano particles or micron particles. It is used in the preparation of (3,4-dialkoxythiophene) polymers or copolymers and polymer anions in water dispersions. There is no oxygen on it, the word is that from the time the initiator is added to the completion of the polymerization, the reaction medium is essentially free of 10 oxygen, and the polymerization reaction is performed under an inert gas atmosphere. PEDOT / PSS dispersed aqueous solution The term improvement is used to refer to the pEDOT / pss dispersion aqueous solution prepared according to the polymerization method disclosed in EP-A 0440 957. The difference is that the polymerization method is performed in the absence of substantial oxygen. 15 "于Improved conductivity coefficient under specific transparency. The term means the printing of polymers or copolymers and polymeric anions used in (3,4-dialkoxythiophene) and polymeric anions in water from the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The conductivity of a coating derived from a dispersion-derived composition in the absence of substantially oxygen is higher than that of a coating made from a composition containing the same ingredients at the same concentration and with the same transparency, and In the case where there is a difference in the oxygen concentration of the substance 20 from (3,4-dialkoxythiophene) and the polymerization of the anionic polymer or copolymer in the dispersion of water were derived. The term transparent used to disclose the present invention means the property of allowing at least 70% of incident light to pass through without diffusing. The term translucent used to disclose the present invention means to allow light to pass through, and diffuse-11 · Chinese paper standard (CNS) A4 is applicable to the standard of non-paper _H_10 X 297 mm &quot; 200305589 A7 B7 V. Description of the invention (10 ) Shooting makes it impossible to see the objects below clearly. The term "flexibility" used to disclose the present invention means that the curvature of a curved object such as, for example, a drum can be followed without damage. The PEDOT used in the present disclosure refers to poly (3,4-ethylenedioxythiophene). The PSS used in this disclosure refers to poly (styrenesulfonic acid) or poly (styrenesulfonate). The PET used in this disclosure refers to poly (ethylene terephthalate). 10 The term screen printing used in this disclosure includes all types of printing, where printing is performed via screen printing, such as screen printing. The term used to mean a dispersed aqueous solution of PEDOT / PSS means a dispersed aqueous solution of PEDOT / PSS prepared according to the polymerization method disclosed in EP-A 0 440 957. 15 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, the Intellectual Property Bureau, and the Consumer Cooperatives with a composition containing (3,4_ 二 院 Oxyphene) and a non-aqueous solvent. Printed according to the present invention. · Oxygen bridges, methods for polymerizing anions, and at least -oxygen-compositions, which are polymers or copolymers of polymers or copolymers which are not present in the solvent (3,4- Dispersion liquid begins to be prepared, which includes the following steps in water in order:

The paper size is subject to the Chinese National Standard (CNS) A4 regulations; f |: 200305589 A7 B7 V. Description of the invention (11) The polymer or copolymer of the aqueous solvent and the (3,4-dialkoxythiophene) and the polymer anion The aqueous dispersion is mixed; and, water is evaporated from the mixture prepared in step 丨) until the water content therein is reduced by at least 65% by weight. It has been found that the polymer or copolymer of 3,4-dialkoxythiophene-in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkynyloxy group Aggregation of bridge one and polymeric anion is minimized to minimize evaporation by at least 65% by weight of water for regular homogenization on-line in a continuous process or off-line in a discontinuous process. In this way, it is possible to reach a polymer or copolymer of 3,4-dioxooxythiophene, one of which is the two alkoxy group, without increasing the viscosity obstructively because of the aggregation of the polymer / polymeric anion 10. It may be the same or different or together to indicate the high concentration of optionally substituted fluorenyl-alkylene-oxy bridges and polymeric anions. Or it can be found on the dispersion that is evaporating that the formation of high viscosity, skin, and obvious aggregation 'significantly reduces the evaporation rate of water. This can be considered as phase separation, except that the water 15 and the organic liquid are preferably miscible in the absence of the polymer or copolymer / polymeric anion. It is believed that the phase separation may occur during the evaporation to become a dehydrated phase ~ in which the polymeric anionic chain system exists in a helical form leading to aggregation ~ and a phase rich in ^ phase-in which the polymeric anionic chain is extended by one. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs According to a first specific example of the method of the present invention, the method further includes a step of homogenizing the dispersion prepared in step 至少 at least once during step (ii). According to a second specific example of the method of the present invention, the method further includes a step of homogenizing the dispersion prepared in step (ii) at least twice during step (ii). -13- The paper size is generally in accordance with Chinese national elephant t ^ (cns &gt; A4 specification (21G χ 297 200305589 A7 B7) V. Description of the invention (12) According to the third specific example of the method of the present invention, (3,4-dialkoxy A dispersion of a polymer or copolymer of thiophene) and a polymeric anion in water is prepared under an inert gas such as nitrogen, helium or argon. According to a fourth specific example of the method of the present invention, step i) further comprises mixing the non- Aqueous solvents and polymers or copolymers of (3,4-dialkoxythiophene) and aqueous dispersions of polymeric anions and an organic liquid which form an azeotrope with water. This can more quickly evaporate water, and It is advantageously added when the water content is substantially reduced to accelerate the reduction of residual water content. Ethanol, isopropanol, n-propanol, n-butanol, second butanol, methyl isobutyl ketone, ethyl acetate All examples of organic liquids that form a binary azeotrope with water. For example, n-butanol can easily reduce the water content to less than 5 weight percent. According to a fifth specific example of the method of the present invention, (3,4- Polymer or copolymer phase of dialkoxythiophene) The weight ratio of anionic polymerization system is between 1: 6.0 in the range of 15 according to a sixth specific example of the method of the present invention, the mixture from step i) the reduction of at least 70 weight percent aqueous: 2.0 to 1. According to a seventh specific example of the method of the invention, the water system in the mixture from step i) is reduced by at least 80% by weight. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs According to the eighth specific example of the method of the present invention, the water system in the mixture 20 from step i) is reduced by at least 90% by weight. According to a ninth specific example of the method of the present invention, the water system in the mixture from step i) is reduced by at least 95 weight percent. According to a tenth specific example of the method of the present invention, the water system in the mixture from step i) is reduced by at least 99% by weight. -14- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (u) According to the eleventh specific example of the method of the present invention, at least 30 weight of the composition Percentages are non-aqueous melting! . According to a twelfth specific example of the method of the present invention, at least 65% by weight of the composition is a non-aqueous solvent. According to a thirteenth specific example of the method of the present invention, at least 80% by weight of the composition is a non-aqueous solvent. According to a fourteenth specific example of the method of the present invention, the composition is a polymer or copolymer containing 3,4-dialkoxyphene between 0.15 and 2.5% by weight. According to the fifteenth specific example of the method of the present invention, the composition is a polymer or copolymer containing 3,4-dialkoxythiophene between 0.2 and 1.6 weight percent. According to a sixteenth specific example of the method of the present invention, the composition is a poly 15 compound or copolymer containing 3,4-dialkoxythiophene between 0.2 and 0.8% by weight. According to a seventeenth specific example of the method of the present invention, the composition is a polymer or copolymer containing 3,4-dialkoxythiophene between 0.2 and 0.4% by weight. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 20 Poly (3, 'ethylenedioxythiophene) [PEDOT] / poly (styrene sulfonate) [pss] dispersion prepared according to the method of EP 440 957 generally has PH of about 1.9. The pH of the dispersion can be changed between L2 and 3.2 without adversely affecting the properties of the composition prepared by the present invention. The degree to which water can be removed by the method of the present invention generally depends on the ability of the water to diffuse to the surface through the dispersion, which depends on the PEDOT / PSS-dispersion solution being steamed. ) A4 gauge (210 X 297 Gongchu) 200305589 A7 _ B7 V. Description of the invention (Viscosity under the conditions of development. However, the viscosity of the PEDOT / PSS-dispersion is closely related to the PEDOT / PSS- content of the final dispersion Relationship. Using a dispersion containing 0.8 weight percent PKDOT / PSS and a weight ratio of PEDOT to PSS of 1: 2'4 can easily reach a water content of 1 to 5 weight percent, but increase the content of PEDOT / PSS- The weight ratio relative to pSS is 1: 2.4, which has a great effect on the viscosity of the dispersion, making it easy to achieve a water content of 10 to 15% by weight. 10 The temperature at which distillation is performed is preferably 80 ° C or lower, Especially 70 ac or lower. It has been found that steaming cranes at a temperature of 88 to 89 ° C produces PEDOT / PSS dispersions which, when processed into screen printing pastes, produce printed materials with a significantly increased surface resistance. Ordering should be noted for use PEDOT / PSS dispersion obtained by the method of the present invention The viscoelastic properties are stable when stored under ambient conditions. 15 A polymer or copolymer of 3,4-dioxooxyphene According to the eighteenth specific example of the method of the present invention, 3,4-dialkoxy Noisy polymers or copolymers are printed by the Intellectual Property Bureau of the Ministry of Economic Affairs.

.0——RT Among them, R and R2 respectively represent hydrogen or a fluorinated group or together represent a substituted Ci-5 fluorinated or fluorinated group. -16- The standard T-reading mark of this paper; ^ (CNS) A4 «; ¥ (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (is) The nineteenth specific example of the method according to the present invention, (3 , 4_Dialkyloxyphene) polymer or copolymer is (3,4 · dialkoxy) in which the two oxygen groups together represent optionally substituted oxy-alkylene-oxy bridges Thiophene) polymer or copolymer. 5 According to the twentieth specific example of the method of the present invention, the polymer or copolymer of (3,4-dialkoxythiophene) is an oxy-alkane in which two alkoxy groups together represent a substituted case, as appropriate. (3,4-dialkoxythiophene) polymers or copolymers based on aryl-oxy bridges, selected from the group consisting of poly (3,4-dimethoxythiophene), poly (3, 4-methyldioxythiophene) derivative, poly (3,4-ethylenedioxydithiophene), poly (3,4 · ethylenedioxythiophene) derivative, poly (3,4-ethylenedioxythiophene) derivative Propylenedioxythiophene), poly (3,4-propylenedioxythiophene) derivatives, poly (3,4-butylenedioxythiophene), and poly (3,4-butylenedioxythiophene) Derivatives and their copolymers. According to the twenty-first specific example of the method of the present invention, the polymer or copolymer of (3 4-dialkoxy 15 thiophene), and the substituents of the oxy-alkylene-oxy bridge are alkyl and alkane Oxygen, alkoxyalkyl, carboxyl, alkylsulfonate complex, alkoxyalkylsulfonate complex and carboxylate. The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the 22nd specific example of the method according to the present invention. In the poly (3, 'dialkoxyphene), the two alkoxy groups together represent the substituted oxygen as appropriate. -20 alkylene-oxy bridge, which is 1,2-ethylenyl, methylene substituted by alkyl, as appropriate, C! -I2-alkyl- or phenyl- Substituted 1,2-ethylidene, 1,3-propylidene or 1,2-cyclohexyl. The polymer is disclosed in the Handbook of Revised by D. Fichou

Oligo- and Polythiophenes, Wiley-VCH, Weinheim (1999); -17- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 Description of the invention (16) 5 10 15 20 L. Groenendaal et al., Advances Materials, Vol. 2, pp. 481 to 494 (2000); L. J. Kloeppner, et al., Polymer preprints, Vol. 40 (2), Vol. 792 (1999); P. Schottland et al., Synthetic Metals, Vol. 101, pp. 7-8 (1999); and D. M. Welsh et al., Polymer Preprints, Vol. 38 (2), p. 320 (1997). According to the twenty-third specific example of the method of the present invention, the dispersion of the polymer or copolymer of (3,4-dithiooxythiophene) and the polymeric anion in water is based on the use of an initiator in the reaction medium in the presence of the polymeric anion. It is prepared under inert atmosphere under oxidizing or reducing conditions, so that when the initiator is added, the reaction medium contains less than 3 mg of oxygen in the mother liter reaction medium. According to the twenty-fourth specific example of the method of the present invention, the dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polymeric anion in water is based on the use of an initiator in the reaction medium in the presence of the polymeric anion. It is prepared under oxidizing or reducing conditions under an inert atmosphere, so that when the initiator is added, the reaction medium contains less than 15 mg of oxygen per liter of reaction medium. According to the twenty-fifth specific example of the method of the present invention, the dispersion of the polymer or copolymer of (3, 'dialkoxythiophene) and the polymeric anion in water is based on the use of an initiator in the reaction medium in the presence of the polymeric anion. It is prepared in an inert atmosphere under oxidizing or reducing conditions, so that when the initiator is added, the reaction medium contains less than 0.5 mg of oxygen per liter of the reaction medium. The oxygen concentration in the reaction medium can be adjusted by any means, such as freeze-thaw technology, passing bubbles of inert gas such as argon, nitrogen or helium through the reaction medium for a long time, and consuming oxygen in the sacrificial reaction under the blanket of inert gas. The polymerization reaction can be performed at room temperature, i.e., about 25 ° C, under atmospheric pressure. 18- The size of this paper is applicable to the national standard of the dry country (CNS) A4 (2) 〇χ 297 蹵 y Order printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumer cooperatives 200305589 Λ7 B7 V. Description of the invention (Polymeric anion according to the method of the present invention In the twenty-sixth specific example, the polymeric anion system includes a polymeric anion of a polymeric carboxylic acid such as polyacrylic acid, polymethacrylic acid, or polymaleic acid, and a polysulfonic acid such as poly (styrenesulfonic acid). Polycarboxylic acids and polysulfonic acids can also be copolymers of vinyl carboxylic acids and vinyl sulfonic acids with other polymerizable monomers such as acrylates, methacrylates, and styrene. The twenty-seventh specific example of the method according to the present invention The polymer anion is a polymer anion of poly (styrene sulfonic acid) or a copolymer of poly (styrene sulfonic acid) and styrene 10 ene. According to the twenty-eighth specific example of the method of the present invention, 3,4_ Polymers or copolymers of alkoxythiophenes-where the two alkanoyl groups may be the same or different or together represent optionally substituted oxy-alkylene-oxy bridges-the molar ratio relative to the polymeric anion Is between 1: 0 In the range of .95 to 1: 6.5. 15 According to the twenty-ninth specific example of the method of the present invention, a polymer or copolymer of 3,4-dialkoxybiphene-wherein the two alkoxy groups may be the same or different or Together, it indicates that the molar ratio of the substituted oxy-alkylene-oxy bridges relative to the polymeric anion, as appropriate, is in the range of 1: 0.95 to 1: 3.0. 20 Non-aqueous solvents Ten specific examples, the non-aqueous solvent cannot form a co-product with water. According to the thirty-first specific example of the method of the present invention, the non-aqueous solvent is selected from the group consisting of alcohols, ketones, aromatics, esters, ethers, and Its mixed-19-

This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 public policy) 200305589 A7 V. Description of invention (18) B7 10 15 Group of 20 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The thirty-second specific example of the method according to the present invention is a glycol ether or _, such as tetrahydrosqueak. The thirty-third specific example of the method according to the present invention is a water miscible agent. The thirty-fourth specific example of the method according to the present invention is added in a further processing step. Thirty-fifth specific example of the method according to the present invention ⑽: is a di- or polyhydroxy- and / or organic compound containing a carboxyl group or a stilbene or stilbene group, such as a sugar alcohol such as sorbitol, mannitol, sugar And fructose, bis (ethylene glycol), 1'2-propanediol, propylene glycol N • methyl roline, and the conductive coating made by them 'adjusted as shown in Ep_A Gamma to increase its resistance' to Side ohms / square is preferred, and the manner in which the case is mentioned is incorporated herein. The suitability of a particular non-aqueous solvent can be evaluated by mixing 8 grams of a 12 weight percent PEDOT / PSS aqueous dispersion with 12 grams of solvent. This non-aqueous solvent is considered suitable if mutual miscibility without gel formation is observed. Tetrahydrofuran is miscible, but the dispersion is extremely viscous. The applicability of the aforementioned miscibility test does not exclude phase separation when the PEDOT / PSS dispersion is further diluted with the same solvent, as found when using tetrahydrofuran. Those skilled in the art know that PEDOT / PSS-dispersions do not have the possibility of phase separation without limiting dilution. Ethyl lactate is not suitable because it induces gel formation. Benzyl alcohol, furfuryl alcohol, and cyclohexane are not suitable because they cause phase separation. Wherein the non-aqueous solvent is among them, the non-aqueous solvent is among them, the non-aqueous solvent is among them, the non-aqueous solvent is -20- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 200305589 Α7 V. Description of the invention (19) 5 10 A thirty-sixth specific example of the method of the present invention, which comprises: Zhanshan 100 (one x ^ water-soluble alcohol), Qin methyl n ratio agent is selected from the group consisting of 1,2-propanediol, propylene glycol, bis (acetrolidone) , N, N-dimethylformamide, N • methylethylmethylacetamide, glycerol, hexanediol, and carbitol acetate, and are grouped. Binders According to the method of the present invention In the thirty-seventh specific example, a binder is added in the step. This binder adheres the composition of the present invention to a processing step or a conductive layer, so that the non-planar structure on the carrier is statically coated. This This kind of adhesive can also increase the group's degree of strength produced by the method of the present invention. Easy ordering According to the thirty-eighth specific example of the method of the present invention, a binder is added in a further processing step, wherein the binder is a polyester amine group. Formate copolymers, such as BAYER DI SPERCOLL U VP ΚΑ 8481. 15 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 20 According to the thirty-ninth specific example of the method of the present invention, a binder is added in the further processing step, wherein the binder is selected from the group consisting of polyacrylate, carboxylate A group consisting of methyl cellulose, polyvinylpyrrolidone, hydroxypropyl cellulose, sulfonate-containing copolymers containing acid groups, modified acrylic copolymers and poly (vinyl alcohol). The applicability is by adding 0.1 weight percent of particulate adhesive to the dispersion medium generally used in the PEDOT / PSS-containing composition of the present invention, such as 87 weight percent of 1,2-propylene glycol, 9 weight percent of bis (ethylene glycol), 3% by weight of deionized water, 0.5% by weight of ZONYL® FSO, and 0.5% by weight of silicone defoamer-21 · This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (20) X50860A. The binder dissolved in the dispersion medium to the extent of 0.1% by weight is considered to be suitable for the composition of the present invention. The adhesive has an adhesive applied · 01 = CARBOPOL® ETD_2623, using 5 polyalkenyl polyether cross-linked acrylic acid homopolymers and the copolymers, available from B. F.

Goodrich; Binder 02 = CARBOPOL® Aqua 30, a latex of a copolymer of acrylic acid and ethyl acrylate, from B. F. Goodrich; Binder 03 = AMBERGUM® 3021, carboxymethyl cellulose, from 10 Hercules Inc. ; Binder 04 = LUVISKOL® K30, polyvinylpyrrolidone from BASF; Binder 05 = hydroxyalkyl cellulose methylpropyl ether from Shin-Etsu Chemical Company; 15 Binder 06 = KLUCEL® L, Hydroxypropyl cellulose from Hercules

Inc .; Binder 07 = NEOCRYL® BT24, an acrylic latex-based aqueous latex obtained from Zenica; Binder Printed by the Consumer Cooperative of the Intellectual Property Bureau, Ministry of Economic Affairs 08 = AQUACER⑧503, obtained from BYC Cera and propylene 20 Main water-based latex; Binder 09 = P0LYPH0BE® TR117, obtained from Union Carbide and acrylate-based water-based latex; Binder 10 = AMOREX® CR2900, obtained from Westvaco

Aqueous latex mainly based on acrylic acid vinegar; -22- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (21) Binder 11 = CRX_8057 -45, Acrylate-based water-based latex obtained from Westvaco Corporation; Binder 12 = PRIMALtm EP-5380, 54% by weight of water-based latex based on acrylic acid, obtained from Rohm and 5 Haas; Binder 13 = JAGOTEX ® KEM1020, 58% by weight aqueous latex based on acrylic acid S, obtained from Ernst Jager Chem. Rostoffe GmbH; Adhesive 14 2 PERMUTEX® PS-34 = 320, 54% by weight based on 10 acrylic acid based water Latex from Stahl

Holland BV; Binder 15 = JAGOTEX® KEM4009, 55 wt.% Acrylic latex copolymer latex from Ernst Jager Chem. Rostoffe GmbH; 15 Binder 16 = GOOD RITE® K797, 50 wt.% Acrylic · AMPS copolymer aqueous latex Available from BF Goodrich; Adhesive printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 17 = GOOD RITE® K7058, 50% by weight water-soluble acrylic polymer, obtained from BF Goodrich; 20 Adhesive 18 = NARLEX® DX2020, Acrylic / styrene copolymer latex from Alco Chemical; Binder 19 = ALCOPERSE® 725, acrylic / styrene copolymer latex from Alco Chemical; Binder 20 = CARBOPOL® EP2, 18.1 weight percent uncrosslinked-23 -This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (22) Methacrylic acid / ethyl acrylate copolymer latex from BF Goodrich; Adhesive 21 = 97.5 to 99.5 percent hydrolyzed poly (vinyl alcohol) from WACKER CHEMIE; 5 Binder 22 = DISPERCOLL® U VP KA 8481, Polyvinylamine Carbamate copolymer dispersion from BAYER. Binders 1, 2 and 20 have a significant effect on the viscosity of the dispersion, regardless of the PEDOT / PSS- content. 10 Pigments and Dyes According to the fortieth embodiment of the method of the present invention, pigments or dyes are added in further processing steps to provide colored or non-transparent compositions. Transparent colored compositions can be achieved by incorporating colored dyes or pigments such as diazo-based and phthalocyanine pigments. 15 Non-transparent compositions can also be obtained by incorporating black pigments in an amount sufficient to produce opacity at the applied layer thickness, such as LEVANYL® from BAYER, LEVANYL® NLF from BAYER, and carbon black from Degussa Dispersions, and MHI Black from the Intellectual Property Bureau of the Ministry of Economic Affairs, Employees' Cooperative, printed 8102M carbon black dispersions or titanium dioxide pigments from Mikuni. 2〇 Suitable pigments are ... -24- This paper size is applicable to the national standard 1P (CNS) A4 specifications_ (210 X 297 public # 7 200305589 A7 B7 V. Description of the invention (23)

Pigment nr.

Pigment

Manufact urer PIG01

PLEXONYL® Blue B2G

CLARIANT

Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper size applies to the Chinese national standard iCNS) A4 specification (210 X 297 gong) 200305589 A7B7 V. Description of the invention (24)

LEVANYL9 Yellow HR-LF

BAYER

PIG03 NOVOPERM® Yellow HJR02

CLARIANT

PIG04

LEVANYL® Blue G-LP

BAYER

PIG05

CLARIANT

H0STAPERM9 Blue B2G

This paper size applies to China National Standard (CNS) A4 specifications (210 x 297 male «) 200305589 A7 B7 V. Description of invention (25) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Cooperative PIG06 HOSTAPERM® Blue 62G ** L CLARIANT o 04¾ O PIG07 LEVANYL® N-LP BAYER Carbon black pigment dispersed in water PIG08 LEVANYL® A-SP BAYER Black pigment dispersed in water PIG09 MHI 8102M DBGUSSA Black pigment dispersed in water PIG10 OA Black 1 Mikuni Color Ltd dispersed in Black Pigment in Water PIG11 Bonjet Black CW-2 Orient Chemicals Industries PIG12 Bonjet Black CW-1 Orient Chemicals Industries PIG13 FX-GBI-015 Nagase Nippon Shokubai Dispersed in Water Black-breaking pigment in 2-butanone (50-80 ×) + T-isobutyl ketone (8-20 ×) PIG14 LEVANYL® B-LF BAYER Black-breaking material dispersed in water PIG15 TPX100 CABOT CORP 20X Dispersion in Water PIG16 TPX100 CABOT CORP 15X Dispersion 27 in Black T Water- This paper is sized for China National Standard (CNS) A4 (210 X 297) Θ 200305589 V. Description of the invention (26) A7 B7 5 Cross-linking agent According to the forty-first specific example of the method of the present invention, the cross-linking agent is based on a further cross-linking epoxy (such as glycidyloxypropyldimethoxystone). Xiyao), crushed-fired hydrolysates (such as the hydrolyzate of tetraethylanhydrite or tetrafoxy'f) disclosed in EP 564 911-mentioned by reference and incorporated herein-as appropriate Protected form of di · or oligomeric isoisocyanate. 10 Antifoaming agent According to the forty-second specific example of the method of the present invention, a suitable antifoaming agent is a polysilicone antifoaming agent X50860A. 15 Agent The surfactant is added according to the forty-third specific example of the method of the present invention, and the surfactant is added according to the forty-fourth specific example of the method of the present invention. An anionic surfactant is added. Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 20 According to the present invention Forty-fifth specific example of the method, non-ionic surfactants are added, such as ethoxylated / fluoroalkyl surfactants, polyethylated polysilicon surfactants, polysiloxane / polyether interface activity Agent, ammonium fluoroalkyl carboxylic acid , Polyethoxylated surfactant and an active agent containing the. Appropriate non-ionic surfactants include: -28- This paper size is applicable to National Standard T of China (CNS) A4 4 (210 X 297 public i-Γ 200305589 A7 B7 V. Description of the invention (27) Surfactant number 01 = ZONYL® FSN, F (CF2CF2) i. 40% by weight solution of 9CH2CH20 (CH2CH20) xH in 50% by weight isopropanol aqueous solution, where x = 0 to about 25, purchased from DuPont; Surfactant No. 02 = ZONYL® FSN-100 ·· FfFzCF; ^-9CH2CH20 (CH2CH20) xH, where x = 0 to about 25, purchased from DuPont; Surfactant No. 03 = ZONYL® FSN300, 40 weight of fluorinated interfacial activity 10 Percent aqueous solution, purchased from

DuPont; Surfactant No. 04 = ZONYL® FSO, ethoxylated non-ionic

50% by weight solution of a mixture of a fluorinated surfactant with the general formula F (CF2CF2V 15 7CH2CH20 (CH2CH20) yH—where y = 0 to about 15—in a 50% by weight ethylene glycol aqueous solution, from DuPont; Ministry of Economic Affairs Intellectual Property Bureau employee consumer cooperative printed surfactant number 05 = ZONYL® FSO-100, an ethoxylated non-ionic surfactant with a general formula 7CH2CH20 (CH2CH20) yH—where y = 〇 to about 15—mixture, purchased from DuPont; Surfactant No. 06 = Tegoglide® 410, polyoxygenated_Polymer-29- This paper size applies Chinese national standard iCNS) A4 specification (210 X 297 mm) 200305589 B7 V. Description of the invention (28) Copolymer surfactant, purchased from S. Goldschmidt; Surfactant No. 07 = Tegowet®, PCS-polyester copolymer surfactant, purchased from Goldschmidt; 5 Surfactant No. 08 = FLUORAD®FC431: CF3 (CF2) 7S02 (C2H5) N-CH2C0- (OCH2CH2) nOH, purchased from 3M; Surfactant No. 09 = FLUORAD®FC126, a mixture of ammonium salts of perfluorocarboxylic acid, purchased from 3M ; 10 Surfactant No. 10 = Polyepoxy Alkane-10 lauryl ether surfactant No. 11 = FLUORAD (R) FC430, 98.5% active fluorine-containing aliphatic ester, purchased from 3M; Suitable anionic surfactants include: Surfactant No. 12 = ZONYL® 7950, fluorinated Surfactant, 15 purchased from DuPont; Surfactant No. 13 = ZONYL® FSA, F (CF2CF2) i. 25CH solution of 9CH2CH2SH2CH2COOLi printed in 50wt% isopropanol solution by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs , Purchased from DuPont; 20 Surfactant No. 14 = ZONYL® FSE, [F (CF2CF2) 1. 7CH2CH20] xP (0) (0NH4) y where x = 1 or 2; y = 2 or 1; and x + y = 3, 14% by weight solution in 70% by weight ethylene glycol aqueous solution, purchased from DuPont; -30- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 200305589 B7 V. Description of the invention (29) Surfactant number 15 = ZONYL® FSJ, [F (CF2CF2) i. 7CH2CH20] xP (0) (0NH4) y where x = 1 or 2; y = 2 or 1; and x + y = 3, Blend with a hydrocarbon surfactant in a 25% by weight 40% by weight solution in an aqueous solution of isopropyl alcohol, purchased From DuPont; Surfactant Number 16 = ZONYL® FSP, [F (CF2CF2) !. 7CH2CH20] xP (0) (0NH4) y where x = 1 or 2; y = 2 or 1; and x + y = 3, 35 wt% solution in 69.2 10 wt% isopropanol aqueous solution, purchased from DuPont; Surfactant No. 17 = ZONYL® UR: [FCCFiCFi) !. 7CH2CH20] xP (0) (0H) y where x = 1 Or 2; y = 2 or 1; and x + y = 3, speaking from 15 DuPont; Surfactant number 18 = Z0NYL® TBS 'F (CF2CF2) 3. Printed by 8CH2CH2S03H at the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs at 4.5 33% by weight solution in acetic acid aqueous solution, purchased from DuPont; 20 surfactant number 19 = ammonium salt of perfluorooctanoic acid; printing ink or paste According to the first specific example of printing ink or paste according to the present invention, the The printing ink or paste is lithographic printing ink, gravure printing ink, rubber-31- The paper size is generally Chinese National Standard (CNS) A4 specification (21 × 297 mm) 200305589 A7 B7 V. Description of the invention ( 30) 5 10 15 Employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Ink jet printing ink or offset printing ink. The applicability of the composition prepared by the method of the present invention to a particular printing method is essentially determined by the viscosity of the composition. Lithographic printing inks have a viscosity depending on the ink formulation, drying mechanism, printing press, and printing speed under printing conditions from about 15 Pa.s to 35 Pa.s. The gravure and rubber web printing inks vary greatly depending on whether the viscosity of the ink in the tank or the diluted ink on the printing machine is considered. In addition, dye-based inks tend to have lower viscosities than pigmented inks because pigments have the problem of sedimentation in cans and on printing presses. Generally, the viscosity of the embossed ink is about 15 mPa.s during printing. Screen printing inks depend on the type of ink, mesh and printing speed. The typical viscosity of the diluted ink during rapid processing (shear rate of about 100 si) from screen printing is between 0.5 and 5 Pa.s, and at slow speed (shear rate == about 1 s1) is 8 to 40 Pa.s, other times the cutting rate = about H ^ s-1) is 50 to 800 Pa.s. Inkjet inks have a viscosity depending on the type of inkjet method, nozzle structure, printing speed, ink drying mechanism, and desired print quality under printing conditions of about 2 mPa.s to 20 mPa.s. 20 Printing method The aspect of the present invention is achieved by a printing method including the following steps: providing the printing ink or paste of the present invention; printing the printing ink or paste on a carrier, dielectric, which is selectively coated with a substrate; Layer, calendered layer, or transparent conductive layer • 32- This paper is in accordance with the national standard (CNS) A41 ^ (21〇χ 297 γιπ 200305589 A7 B7) V. The description of the invention (3i), in order to obtain a specific transparency Thin layer with increased conductivity. The paste layer has excellent adhesion to calender layers, polyacrylate coatings, polycarbonates and polyesters such as polyethylene terephthalate, and is transparent to visible light. &gt; The surface resistance at 75% S 1000 ohms / square, and 5 can get ^ 85%. m Order printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 20 Printed electroluminescent phosphors that can be applied with printing ink or paste 1Ι-νι semiconductors such as ZnS or a combination of Group II elements and oxidizing anions, the most common are silicates, borates, vanadates, tungstates and oxysulfates. Typical doping agents are metals And all rare earth elements Cu, Ag, 10 Mn, Eu, Sm, Tb, and Ce. The electroluminescence photoluminescence can use a transparent barrier layer against moisture such as Al203 and A1N encapsulation. The photoluminescence is described by Sylvania, Shinetsu polymer KK, Durel, Acheson and Toshiba. Examples of coatings containing this phosphor include the 72X purchased from Sylvatiia / GTE and the coating disclosed in US 4,855,189. Suitable electroluminescent phosphors are doped with manganese, copper or Tritium ZnS, Tritium-doped CaGa〗 S4, and electroluminescence photoluminescence pastes provided by DuPont, for example: Luxprint® 7138, white phosphorescent; LuxpΓint® 7151, blue-green phosphorescent; and Luxprint® 7174 , Yellow-green scale light quality; and Electrodag® EL-035A provided by Acheson. A particularly good electroluminescence photoluminescence is a zinc sulfide phosphor light doped with manganese and encapsulated in A1N. Any dielectric material can be used, such as yttrium oxide Barium titanate is preferred, such as Luxprint® 7153 high-K dielectric insulator provided by DuPont and Electrodag® EL- -33- Titanate lock slurry provided by Acheson (CNS) A4 Regulations & l t; 210 X 297 male dragon) 200305589 A7 B7 V. Description of the invention (32) 040 〇 According to the first specific example of the printing method of the present invention, the printing method is a method for manufacturing an electroluminescent device and includes the following steps: ⑴ Printing the printing ink or paste of the present invention on a transparent or translucent carrier to make 5 to obtain a transparent or translucent first conductive layer; (11) printing on the first conductive layer including electroluminescent calendering (111) a dielectric layer is printed on the thin layer containing electroluminescent phosphors as appropriate; and (iV) is a layer containing electroluminescent phosphors (if present) or a layer containing electroluminescent phosphors ( If the dielectric layer is not present, a solution, a dispersion or a paste containing a polymer or copolymer of (3,4-dialkoxyphene) is printed on the second conductive layer. The (3,4-dialkoxythiophene) polymer or copolymer in the solution, dispersion, or paste used may be the same as (3,4) in the solution, dispersion, or paste used in step (iv). -Dialkoxythiophene) polymers or copolymers are the same or different. The second specific example of the printing method according to the present invention is printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The printing method 15 is a method for manufacturing an electroluminescent device, which includes the following steps. Ink or paste to make a second conductive layer; (ii) printing a dielectric layer on the second conductive layer as appropriate; (out) on the dielectric layer (if present) or the second conductive layer (if The dielectric layer is absent) and a layer containing electroluminescence phosphorescence is printed; and (iv) a polymer or copolymer containing (3,4-dialkoxythiophene) is printed on the electroluminescence phosphorescence layer. (3, 'dialkoxythiophene) in the solution, dispersion or paste used in step (i) to obtain a transparent or translucent first conductive layer. ) The polymer or copolymer can be the same or similar to the (3,4-dialkoxythiophene) polymer or copolymer in the transparent solution, dispersion or paste used in step (iv). Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 200305589 A7 B7 V. Invention Ming (33) isocyanurate. Coating method The aspect of the present invention is achieved by a coating method including the following steps: 5 The coating composition is configured according to the aforementioned method; the coating composition is coated on a carrier, dielectric, which is coated with an underlying layer as appropriate. Layer, phosphorescent layer or transparent conductive layer to make a thin layer with an increased conductivity at a specific transparency. Transparent or translucent carrier 10 According to the first embodiment of the coating method and the third embodiment of the printing method of the present invention, the carrier is paper, polymer film, glass or ceramic. According to the second embodiment of the coating method or the fourth embodiment of the printing method of the present invention, the carrier is a transparent or translucent polymer film. The transparent or translucent carrier suitable for the electroluminescent device of the present invention can be printed by members of the Intellectual Property Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives. 15 Rigid or flexible, and it is made of glass, glass-polymer laminate, polymer laminate. Polymers, thermoplastic polymers or rigid plastic polymers. Examples of flexible thin carriers are those made from cellulose esters, cellulose triacetates, polypropylene, polycarbonates or polyesters, with poly (ethylene terephthalate) or poly (naphthalene) · Ethylene 1,4-dicarboxylate) is particularly preferred. 20 Industrial applications The coating composition of the present invention can be used, for example, to apply an antistatic or conductive coating on a substrate, a dielectric layer, a phosphorescent layer, or a transparent conductive layer which is optionally coated with an underlayer. -35- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (34) The printing ink or paste pad of the present invention can be used, for example, to apply antistatic or conductive patterns On the carrier, dielectric layer, phosphor layer, or transparent conductive layer, which is coated on the bottom layer as appropriate. This can be, for example, a step in manufacturing an electroluminescent device that can be used in lamps, displays, backlights such as 5 LCDs, automotive dashboards and key switch backlights, emergency lighting, and cellular phones. , Personal digital assistants, home electronics, indicator lights, and other applications that require light. Hereinafter, the present invention will be described by comparison examples and embodiments of the present invention. The percentages and ratios shown in the examples are by weight unless stated otherwise. 10 Comparative examples and examples of the present invention use the following carriers: • AUTOSTAT® = 175 micron thick thermally stabilized poly (ethylene terephthalate) [PET] coated on both sides with a primer layer, by AUTOTYPE INTERNATIONAL LTD Provided; • 100 micron thick thermally stabilized 15 PET coated with a base coat number 01; • 100 micron thick thermally stabilized PET coated with a base coat number 02; • 100 micron thick without a base coat Thermally stabilized PET; printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs • MAKROFOL® DE 1-1 SC = 125 micron polycarbonate film, purchased from BAYER AG; • BAYFOL® CR polycarbonate and poly (for stupid A 115 micron thick extruded film of a blend of butanediol diformate) from BAYERAG. The base coat number 01 has the following composition: -36- This paper size is applicable to Chinese National Standard (CNS) A4 broadcast: _ (210 X 297 public «) 200305589 A7 B7 V. Description of the invention (35)

88% vinylidene oxide, 10% methyl acrylate and copolymers

Kieselsol® 10F, colloidal silica of BAYER Mersolat⑧Η, surfactant of BAYER

Ultravon® W, CIBA-GEIGY's interfacial active primer coating number 02 has the following composition: 50 mole percent ethylene glycol, 26.5 mole percent formic acid, 20 mole percent isophthalic acid, 3.45 mole percent sulfoisobenzene Copolymer of dicarboxylic acid and 0.05% mole, 77.2% / 0% 0 〇 〇 copolymer of 20% ethyl acrylate and 80% methacrylic acid copolymer 5.8% Hordamer® PE02, polyethylene aqueous dispersion, From HOECHST 2.4% PAREZ RESIN® 707, melamine-formaldehyde resin, purchased from AMERICAN CYANAMID 14.6% The following layers are used in the comparative example and the embodiment of the present invention. • • LUXPRINT ™ 7153E layer (high-K dielectric insulator), P55 Screen printing by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs for screen printing; • LUXPRINT ™ 7138J layer (white calender), screen printing via P55 screen. 10 Comparative examples and the composition of the examples of the present invention use the following ingredients not mentioned above: -37- This paper size applies the Chinese National Standard (CNS) A4 Regulation (210 X 297 mm) 200305589 Α7 Β7 V. Invention Explanation (36) • Non-aqueous solvents: CA = carbitol acetate [bis (ethylene glycol) ethyl ether acetate] DEG = bis (ethylene glycol) NMP = N-methylpyrrolidone 5 PD = 1 , 2-propanediol (propylene glycol)

BuOH = n-butanol • X50860A = Polysilicone antifoaming agent χ5086〇A, obtained from the n_msu 10 PED〇T / PSS dispersion used to prepare the pedott paste described in the examples and comparative examples of the present invention Inventive Examples 1 to 79 and Comparative Examples used a 1.2% by weight aqueous dispersion containing conventional PEDOT / PSS to the pss weight ratio of 1: 2 · 4 in the pastes described in Examples 1 to 79 of the present invention, as in Ερ_Α 44〇15 957—incorporated herein by reference—disclosed the preparation of peDOT to the customary ι · 2 weight percent of the PSS printed by the Intellectual Property Bureau of the Ministry of Economic Affairs's consumer co-operative at a weight ratio of 1: 2.4 pEDOT / pSS Aqueous knife dispersions using AR1000 plate cone rheometer (diameter 4 cm; cone angle 2 °). The general viscosity measured at 20 ° C is 5 and the shear rate is 38 mPa.s at 35 s · 1. The shear rate decreases to 33 5 mpa s, while the general pH is 1.9. Modified 1.2 weight percent PEDOT / PSS aqueous dispersion used in Examples 80 to 95 of the present invention with a PEDOT to PSS weight ratio of 1: 2.4: In the pastes described in Examples 80 to 95 of the present invention, the 1.2 weight percent of PEDOT to PSS weight ratio of 1: 2.4 -38- This paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 male ghost) 200305589 Α7

The PEDOT / PSS aqueous dispersion was printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs in the absence of substantial oxygen, resulting in printed matter with the same optical transparency, but the conductivity was substantially higher than the "conventional method" mentioned above. This improved method is carried out as follows: · At room temperature, 1,649 grams of poly (benzyl ethylene sulfonic acid) [PSS] (Mw = 290,000) aqueous solution and 39.351 kg of deionized water are used in the device. Mix in a stirrer (18 rpm) and a 60 liter Bttchi reactor with a nitrogen inlet. After 30 minutes of nitrogen gas bubbled through the mixture, 213 g (1.5 mol) of EDOT was added to the solution. The reaction mixture was heated To 30 ° C. The concentration of oxygen in this solution was 0.08 mg / liter using InPro 6000 Series 02 and Knick Process Unit 73 02 measuring system. After that, 3.75 g of Fe2 (S04) 3 9H20 and 428.2 g of Na &amp; O8 were added. The polymerization reaction was initiated. The reaction mixture was stirred at 300c for 7 hours. After that, an additional 71.6 grams of Na2S208 was added. After another 16 hours of reaction, the reaction mixture was cooled to room temperature and the N2 bubbles were stopped. Ion exchanger (5000 ml of LewatitTM S100MB + 8320 ml of LewatitTM M600MB) was treated twice. The resulting mixture was heat-treated at 95 ° C for 2 hours. The resulting viscous mixture (50730 g, 1.03 weight percent) was first diluted with 14585 g of deionized water , And then use high shear [micro fluidizer, 40 MPa (400 Bar)] processing. This method produces 20.65 kg of PEDOT / PSS blue dispersion of 65.315 kg, the weight ratio of PEDOT to PSS The ratio is 1: 2.46. 5 10 Examples 1 to 15 of the present invention The compositions of Examples 1 to 13 of the present invention are bound by the list shown in the table. -39- This paper size is applicable to Chinese national standard iCNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (30% of the solvents listed in Table 1 and the amounts listed in Table i are customary 12% by weight, and the weight ratio of PEDOT to PSS is 1 ·· 2 · 4. The PEDOT / PSS dispersion 'was evaporated from the formed mixture under stirring by evaporation under vacuum at 50 hPa (mbar) at 45 C, yielding the composition also listed in Table 1. 5 In these compositions The PEDOT content obtained by dividing the content of PEDOT / PSS by 3.4 Changes in weight percent between 5.27 and 1.57 billion in the viscosity of the system at 20 ° C and a shear rate of 1 s · 1 AR1〇〇〇 using cone plate rheometer (diameter 4 cm; cone angle 2. ) Measurements are also listed in Table 1. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. -4 Moderate rule paper fc] Biaojia secretary 97 200305589 A7 B7 V. Description of the invention (39) Table 1: Example number of the present invention before dehydration (final) Composition Non-aqueous solvent 1.2 wt% PEDO T / PSS Dispersion in water PEDO T / PS [wt%] Non-aqueous solvent water [wt%] Viscosity at Is-1 shear rate Pa.s Type dosage [g] Type Dosage [wt%] 1 DEG 400 400 1.006 DEG 84 15 10 2 PD 400 400 1.03 PD 84.97 14.0 15 3 PD 400 400 1.09 PD 89.91 9.0-4 PD + DEG 400+ 61.35 400 0.92 PD + DEG 74.98 + 11.5 12.6 16 5 PD + DEG 400+ 54.32 400 0.98 PD + DEG 81.0 + 11 7.02-6 DEG 300 300 1.09 DEG 87.91 11-7 DEG 200 400 1.62 DEG 65.38 33 50 8 DEG 200 400 1.66 DEG 68.84 29.5 70 9 NMP 70 700 3.28 NMP 23.72 73 100-300 10 NMP 70 700 3.64 NMP 28.91 67.45 200 11 CA 70 700 3.23 CA 23.77 73 100 12 CA 70 700 5.35 CA 42.59 52.06 4000 13 DEG 200 400 1.65 DEG 67.35 31 150 In the composition of Example 3 of the present invention Grain of PEDOT / PSS latex particles Department Use Chemical Process Specialists CPS DCP24000 Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed

Disc Centrifuge measurement, in which the particle size distribution is determined using differential centrifugal sedimentation 5. According to Stoke's law, particles in a fluid settle under a centrifugal field. The sedimentation speed increases with the square of the particle size, so particles with only a few percent difference in size settle at very different rates. Under Differential Settlement -41- This paper size uses Chinese National Standard (CNS) A4 specifications (210 X 297 each) 200305589 A7 B7 V. Description of the invention (40) All particles in the sample begin to settle to A 1 〇 Become a thin strip. The particle sample was prepared by diluting 1 10 ml of deionized water with 4 ml of 1,2-propanediol. The composition was then diluted with liter of deionized water and then diluted with 3 ml of ethanol to prepare Got. Then, at the beginning of the analysis, at the beginning of the analysis, 0.1 ml of the dispersed liquid was added to the top of the 95 ml clear liquid composed of 8% return water, and the particles settled under the centrifugal field. The detector first reads the maximum intensity y. When the particles reach the detector beam, the letter rhyme is low. Decrease in intensity 10 15 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. When using a monochromatic light source, theoretic light scattering can be mixed with intensity data to calculate spine degrees. When all particles pass the detector, the signal returns to its original value. The plot of particle concentration against the calculated particle diameter provides a differential distribution. It has also been found that the composition of Example 3 of the present invention has an average latex particle size of 223 nm, dlO of 223 nm, and d90 of 461 nm. The composition of the examples of the present invention 〖to〗 〇 is screen-printed on a pET film having a primer coating also shown in Table 2 through a screen shown in Table 2. The printed matter is dried at 120 ° C for 240 seconds . The optical density of the printed matter was measured using a transmission MacBeth TR924 densitometer with blue, green, and red optical filters. The results are listed in Table 2. The surface resistance of the printed matter is measured by the printed layer and the parallel steel electrodes-each 35 mm long and separated by 35 mm and forming a line-to-contact contact. The electrodes are separated by a TEFLON® insulator. This can directly measure the desired surface resistance. The results are also shown in Table 2. -42- Non-paper scale ii # Standard for Chinese Pages Bacteria Standard (CNS) A4 (210 X 297) ^ [7 200305589 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (41) Table 2: Example of the present invention No. Screen layer coating No. D Blue D Green D Red D Visible light surface resistance [ohm / square] 1A P77 1 0.05 0.07 0.10 0.08 500 1B P77 2 0.05 0.06 0.10 0.07 570 2 P77 1 0.05 0.07 0.09 0.07 560 3 P77 2 0.05 0.08 0.11 0.08 580 4 P77 1 0.04 0.06 0.09 0.07 710 5 P77 2 0.05 0.06 0.08 0.06 940 6 P59 1 0.06 0.08 0.11 0.09 460 7 P59 1 0.08 0.09 0.12 0.10 1150 9 P59 1 0.19 0.23 0.28 0.25 210 11 P59 1 0.13 0.16 0.21 0.17 460 13 P77 1 0.06 0.08 0.11 0.09 1340 5 With the addition of other ingredients to the composition of Examples 8 and 11 of the present invention, the screen pastes of Examples 14 and 15 of the present invention are individually prepared Table 3: Example of the present invention No. Dispersion added non-aqueous solvent (final) composition PEDO T / PSS [wt%] Non-aqueous solvent water [wt%] Type dosage [$] Type dosage [wt%] 14 60 g this invention Example 8 DEG 30 2.52 NMP + DEG 18.1 + 23.38 56 15 60 g Example 11 of the present invention DEG 30 2.15 CA + DEG 15.84+ 33.3 48.6 -43- Moderate rule on paper quasi-standard house standard M s) Μ Male 97 200305589 A7 B7 V. Description of the invention (42) 5 ο * 1 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5 T1 The PEDOT content obtained by dividing the content of PEDOT / PSS in Examples 14 and 15 of the present invention by 3.4 is the individual system It is 0.74 and 0.63 weight percent. The compositions of Examples 14 and 15 of the present invention were screen-printed on a ρΕτ film having an undercoat layer also shown in Table 4 through a screen shown in Table 4, and the printed matter was dried at 120 ° C for 240 seconds. The characteristics of these prints are described in Examples 1 to 13 of the present invention, and the results obtained are shown in Table 4. Table 4: Example of the present invention No. Screen mesh coating No. D 编号 D Green D Red D Visible light resistance [ohm / square] 14 P59 1 0.12 0.14 0.18 〇Λ6 1 'J 380 15 P59 1 0.09 0.11 0.13 〇ai 940 Examples 16 and 17 of the present invention The compositions of Examples 16 and 17 of the present invention are prepared by adding 400 g of bis (ethylene glycol) (DEG) to 400 g of a conventional PEDOT / PSS weight ratio of 1: 2.4. A 1.2 weight percent dispersion of PSS in water followed by evaporation at 60 ° C and a vacuum of 50 hPa (mbar) in a rotary evaporator to produce a mixture that produces the composition in Table 5 and wounds. Table 5 · Example 16 of the present invention Example 17 wt% PEDOT 0.315-wt% PEDOT / PSS 1.07 1.04S wt%. DEG 87.93 '83 QSS wt% deionized water 11.00 sj ^ .00 -44- 本Paper size is applicable to National Standard T (CNS) A4 (210 x 297 male «) 200305589 A7 B7 V. Description of the invention (43) Composition of Example 13 of the present invention and 1.2 weight percent dispersion of PEDOT / PSS in water The viscosity at 20 ° C is measured using increasing shear rate. The results are shown in Table 6 for the specific shear rate. Table 6 Two viscosity Pa.s] Shear rate [s · 1] 1.2 wt% dispersion of PEDOT / PSS in water Composition of Example 17 of the present invention 0.10 0.142 49.20 0.50 0.066 14.74 1.00 0.076 8.962 5.01 0.079 3.251 10.00 0.073 ___ 2.227 50.12 0.060 1.032 100.00 0.053 0.761 500.00 0.037 ____ 〇 ^ 376 5 This composition can be used directly for coating, or different ingredients can be added to make printing inks containing non-aqueous solvents for different printing technologies and Syrup. Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the composition of Example 17 of the present invention without additional ingredients is screen-printed on uncoated PET through different screens, and dried at 1200c 120 seconds. The characteristics of these prints are described in Examples 1 to 10 of the present invention, and the results obtained are shown in Table 7. The printed matter using the composition of Example 16 of the present invention produced the same results as those listed in Table 7 using the composition of Example Π of the present invention. -45- 200305589

V. Description of the invention (44) Table 7

Examples 18 to 22 of the present invention The compositions of Examples 18 to 22 of the present invention are prepared by adding 400 g of 5 1,2-propanediol, optionally 49 g of bis (ethylene glycol), and 400 g of conventional PEDOT. A 1.2 weight percent dispersion of PEDOT / PSS in water with a PSS weight ratio of 1: 2.4. The mixture formed by evaporation at 60 ° C and 50 hPa (mbar) vacuum in a rotary evaporator produces the composition, and then CARBOPOL⑧ETD is added. 2623 or 3-glycidylpropyltrimethoxysilazane, produced to produce the composition listed in Table 8. Table 8: Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

The composition of the embodiment of the present invention [3 1% ingredients Nr 18 nr 19 nr 21 nr 22 1 -----_ ^ PEDOT 0.300 0 · 279— 0.279 0300 PEDOT / PSS 1.02 0.95 0.95 1 ^ 02 ^ ----- -DEG 11.0-11.0 ----- PD 84.08 78.25 89.42 78.25 84 ^ 08 ^ 3-glycidyloxypropyltrimethoxysilane--continued ----------- CARBOPOL® ETD 2623-0.40 0.40 to Ionized water 14.90 9.80 9.10 9.40 H -46- This paper size applies Chinese National Standard (CNS) A4 (21〇Xπ / 200305589 Α7 Β7) V. Description of the invention (45) Viscosity rating 1:

Adhesive rating 2: Adhesive WWWtf ^^ T Adhesive rating 5: Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, removing the area larger than the area of the tape, screen printing. The screen printing machine was printed on an AUTOSTAT ™ CT7 carrier with a P120 screen screen and dried at 1205 ° C for 120 seconds. Qualitativeness of the printed layer The optical density and surface resistance of the printed matter penetrating the visible light filter prepared using the composition of Examples 18 to 22 of the present invention were evaluated as described in Examples 1 to 13 of the present invention, and the results are shown in Table 9. . The adhesion of the printed layer is measured by the tape test .... Use the remaining knife to cross the area of about 4x10 cm2 of the layer and mark it. Apply a 10 × 24 cm 2 TESAPACK⑧ 4122 brown tape, rub it with a hard object, and finally press it. The tape is removed upwards from one end in a single direction. The adhesiveness of the printed layer is determined visually on a scale of 0 to 5 according to the following standards, and 0 corresponds to the layer that has not been removed by tape: tape removal-tape removal equals 25% of the area of the tape The area of 50% of the tape area is equal to 75% of the area of the tape area, the area of double tape removal is equal to the area of the area of the tape area, and the middle ping level such as (VI, 1/2, 2/3, and 3 / 4. Use this invention's real -47- this paper size Gu Hat ® Μ y,

200305589 A7 B7 V. Description of the invention (46) The adhesion evaluation results of the printed matter obtained from the composition of Examples 18 to 22 are also shown in Table 9. Table 9: Evaluation of the examples of the present invention nr 18 nr 19 nr 20 nr 21 nr 22 Adhesive quality 0 0 0 0 5 Optical degree 2060 The results in Table 9 show that except for the printed matter using the composition containing 3-glycidoxypropyl-trimethoxysilane in Example 22 of the present invention, all the printed matter has excellent adhesion quality and surface. Low resistance. Examples 23 to 34 of the present invention The composition of Example 23 of the present invention was prepared as described in Examples 16 and 10 of the present invention and was composed of the following materials: 0.75 weight percent PEDOT / PSS, 93 weight percent 1 , 2-propanediol, 5.9% by weight of water and 0.5% by weight of 3-glycidyloxypropyltrimethoxystone. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the composition of Examples 24 to 34 of the present invention by adding different surfactants with different concentrations listed in Table 10 to Group 15 of Example 23 of the present invention. . The compositions of Examples 23 to 34 of the present invention were screen-printed on an AUTOSTATtm CT7 carrier, a LUXPRINT ™ Ή53E standard layer, and a LUXPRINT ™ 7138J standard layer through a P120 screen, and dried at 120 ° C for 120 seconds. 20 -48- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7

5 10 Evaluation of printed matter The optical density and surface resistance of printed matter on AUTOSTAT⑧CT7 are as described in Examples 1 to 13 of the present invention. The results obtained by evaluating the printed matter prepared from the compositions of Examples 23 to 34 of the present invention are shown. In Table 10. The adhesion of the printed matter on the AUTOSTAT ™ CT7 carrier, the LOXPRINT ™ 715 3E standard layer, and the LUXPIUNT ™ 7] 3 8 j standard layer was evaluated as described in Examples 18 to 22 of the present invention. The results obtained from the printed matter prepared by the compositions of Examples 23 to 34 of the present invention are also shown in Table 10. The mottledness of the printed layer on the AUTOSTATTM carrier and the standard layers of LOXPRINT ™ 7153E and LUXPRINTtm 7138J is evaluated visually according to the following standard scales 0 to 5, which corresponds to a good non-mottled layer: Mottled rating 0 Not visually observed Mottled mottled rating 1 was found to be mottled between 1 and 100 / of the print. Mottled rating between 2 Mottled between 11 and 20% of printed matter Mottled rating 3 Mottled between 21 and 40% of printed matter Mottled rating 4 Mottled between 41 and 60% of printed matter Mottled Rating 5 Mottled higher than 60% of the printed matter. The mottledness of the printed matter obtained by using the compositions of Examples 23 to 34 of the present invention is 15 printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The results are also shown in Table 10. -49- • Chinese papers (CNS) A4 specifications (210 X 297) ") for paper-free ift 200305589 A7 B7 V. Description of the invention (48) Table 10: The AUTOSTAT CT in the composition is located on the following Evaluation of the layer resistivity of the surface active agent of the spot. The surface D of the hair is visible with a sticky number, wt%, resistive light, AUT LUXP LUXP. Example (ohm OSTA RINT RINT number / flat T 7138J 7153E square) CT7 23--2380 0.02 0 1 4 4 24 03 0.125 2280 0.02-1 3 4 25 02 0.125 2640 0.02-1 2 2 26 04 0.125 2260 0.03 0 1 1-2 4 27 0.25 0.03 0 1 2 2 28 0.50 0.03 0 1 2 2 29 05 0.125 2090 0.03 0 1 1-2 3 30 19 1.0 2090 0.03 0 1 4 5 31 06 0.125 4000 0. 03 1 1 3 4 32 0.25 0. 03 1 1 3 4 33 0.50 0. 03 0-1 1 1-2 3 34 1.0 0. 03 2 2 1 1-2 The results in Table 10 show that the incorporation of different non-ionic surfactants will reduce mottledness and improve the adhesion of the printed matter of the composition of the present invention. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5 Examples 35 to 41 of the present invention The starting materials of the compositions of Examples 35 to 41 of the present invention are added by adding 34.68 kg of 2-propanediol and 3.84 kg of double (ethylene glycol) Alcohol) 25.6 kg of conventional 1.2 weight percent PEDOT / PSS dispersion in a reactor with a weight ratio of PEDOT to PSS of 1: 2 · 4 at 62 ° C with stirring between 10 31 and 55 hPa (mbar) Use an oil bath to heat for 234 minutes under vacuum. -50-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (49) 15 liters of water will be distilled off, which will form The mixture was cooled to 2000c and then again at 60.5. (: Prepared by stirring under a vacuum between 24 and 26 hPa (mbar) using an oil bath for 287 minutes to further distill off 4.85 liters of water. The water content in the resulting 38.1 kilograms of paste was borrowed by Karl Fischer method 5 is measured at 3.9% by weight. The compositions of Examples 35 to 41 of the present invention are then added by adding deionized water in the amounts listed in Table ^, ZONYL® FSO-100, silicone defoamer X5086A, and CARBOPOL® AQUA 30 is prepared by stirring for 30 minutes. 10 Table 11: Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Industrial Cooperatives for the preparation of ingredients of the present invention 瞀 GT-· Nr35 nr 36 nr 37 nr 38 Nr 39 nr 40 nr 41 Starting material 4,950 8,372.5 3,726 92.83 92.09 93.09 87.65 2-glycidyloxypropylmethoxysilane 25 42.5 0.5 0.5 CARBOPOL ® AQUA 30 隹-7.5 2.0 2.0 2.0-CARBOPOL ® EP2-----2.0 Deionization Water 9,4 31.9 30.5 4.80 4.661 4.72 9.1 ZONYL® FSO-lOO * 6.25 21.25 9.5 0.25 0.25 0.125 0.25 X50860A 6.25 21.25 9.5 0.12 0.5 0.5 DEG 3 10.6 5--0.063 Total 5,000 8,500 3,788 100 100 100 100 * ZONYL® FSO Department is ZONYL® FSO-100 is 50% by weight dissolved in a mixture of 50% by weight water and 50% by weight ethylene glycol • 51- Moderate rule paper on paper Standard writer 7 9 2 X 10 2 C Standard 200305589 A7 B7 Economic Printed by the Ministry of Intellectual Property Bureau and Consumer Goods Cooperatives. V. Description of the invention (50) The final composition of the liquid 0 is shown in Table 12. Table 12: Composition Composition of the Example of the Invention [weight percentage] nr35 nr 36 Nr 37 nr 38 Nr 39 nr 40 Nr 41 PEDOT 0.224 0.224 0.224 0.209 0.208 0.210 0.197 PEDOT / PSS 0.760 0.760 0.760 0.712 0.706 0.715 0.672 EDG 9.000 9.000 9.000 8.417 8.350 8.460 7.947 PD 85.040 84.540 84.540 79.094 78.463 79.467 74.681 3-glycidyloxypropyltrimethoxy Silane 0.500 0.500 &quot; '0.500' 0.500 CARBOPOL ® AQUA--0.2000 2.000 2.000 2.000-CARBOPOL ® EP2 2.000 ZONYL® FS0100 0.125 0.250 0.250 0.250 0.250 0.125 0.250 X50860A 0.120 0.240 0.240 0.120 0.500-0.500 Ethylene glycol 0.063 0.125 0.125-- 0.063-DI water 4.262 4.375 4.885 9.407 9.231 9.17 13.450 The 5 particle size of the PEDOT / PSS latex in the compositions of Invention Examples 35 to 37 was determined as described in the composition of Invention Example 3 above. The average particle size distribution of the PEDOT / PSS latex in these compositions was determined. The latex particle size, dlO value and d90 value are shown in Table 13. -52- This paper size is in accordance with Chinese National Standard (CNS) A4 (210x297 mm) 200305589 A7 B7 V. Description of the invention (51) Table 13: The average PEDOT / PSS latex particle size [nanometer] PEDOT / PSS latex dlO [nanometer] PEDOT / PSS latex d90 [nanometer] 35 184 46 344 36 187 44 342 37 182 53 327 Viscosity measurement The screen pastes of Examples 35 and 36 of the present invention are at 20 ° C Viscosity 5 was measured using an AR1000 plate cone rheometer (diameter 4 cm; cone angle 2 °) at a specific shear rate at an increasing shear rate, and is shown in Table 14. Table 14: • Packing • Ordering • Printed viscosity [Pa.s] Shear rate [s'1] 1.2wt.% PEDOT / PS S dispersion in water Example 35 Composition of the present invention Example 3 6 Composition of the present invention Example 37 Composition of the present invention Example 39 Composition 0.10 0.142 17.59 18.66 37.55 111.1 0.50 0.066 7.843 8.262 14.08 0.63 28.8 1.00 0.076 5.540 5.864 9.103 21.25 5.01 0.079 2.506 2.658 3.380 6.31 6.899 10.00 0.073 1.793 1.903 2.258 5.345 50.12 0.060 0.851 0.908 0.956 63.10 2.109 100.00 0.053 0.634 0.674 0.686 1.684 -53- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (52) Shear rate [S-1] 2% CARBOPOL⑧ in a solvent mixture consisting of 87% PG, 9% DEG, 3% water, 0.25% ZONYL® FS0100 and 0.5% polycrystone defoamer X50860A AQUA 30 viscosity [pa, s] 0.10 2.479 0.63 0.820 1.00 0.633 6.31 0.475 10.00 0.443 63.10 〇3〇8 1 100.00 0.280 __ 631.00 0.197 CARBOPOL EP2 also found that the composition of Example 50 of the present invention is 500.00 0.037 0.325 0.348 0.343 631 · 〇〇0.6579 The viscosity increase when CARBOPOL® AQUA 30 is added is partly due to the non-Newtonian properties of CARBOPOL® AQUA 30 solution, as shown in Table 15 as 2 The dependence of the viscosity of CARBOPOL® AQUA 30 solution in the same medium on the shear rate is shown. 5 415 ·· The dependence of the viscosity of the printed product on the consumer co-operatives of the Intellectual Property Bureau of the Ministry of Economic Affairs on the shear rate dependence is shown in Table I6. The solution of CARBOLOL® EP2 in the same medium is shown in Table I6. 10 -54- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (53) Table 16: Shear rate [S-1] Viscosity [Pa, s] The composition of Example 41 of the present invention is a 2% CARBOPOL® EP2 solution in a solvent mixture consisting of 87% PG, 9% DEG, 3% water, 0.25% ZONYL® FS0100 and 0.5% silicone defoamer X50860A. 188.6 2.962 0.63 53.960 2.014 1.00 40.210 1.829 6.31 12.670 1.250 10.00 9.517 1.127 63.10 3.213 0.706 100.00 2.494 0.630 631.00 0.939 0.360 Screen printing 5 The composition of Examples 35 to 38 and 40 of the present invention is screen-printed with a P120 screen. The printing plate is printed on the AUTOSTATtm CT7 carrier, the LUXPRINT ™ 7153E standard layer and the LUXPRINT ™ 7138 standard layer and dried at 20 ° C for 120 seconds. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives. 10 Qualification of the printed layer. For the coatings on the AUTOSTAT® CT7 of the compositions of Examples 35 to 38 and 40 of the present invention, as described in Examples 1 to 13 of the present invention. The optical density of the visible light filter is generally evaluated. The turbidity is specifically measured according to ASTM D1003-61, and the quality of the printed matter is visually evaluated. -55- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of Invention (54) Estimate. The results printed through the P120 screen are shown in Table π. The turbidity value reflects the amount of light scattering in the printed layer, and it increases with the number of visually visible mottles, that is, the number of scattered light spots in the print. The 5 degree of turbidity found in printed matter prepared using the compositions of Examples 37, 38, and 40 of the present invention is lower and less or less mottled than the printed matter of Examples 35 and 36 of the present invention. Table 17: Compositions of Example of the Present Invention Printed on AUTOSTAT1M CT7 Nr 35 Nr 36 Nr 37 Nr 38 Nr 39 Print quality mottled mottled with a few mottled non-mottled non-mottled turbidity 5.99 5.66-3.57 2.57 D visible light 0.03 0.03 0.03 0.03 0.03 Inventive Examples 35 to 38 and 40. For the coatings on AUTOSTAT (R) CT7, MAKROFOL DE 1-1 SCI, PET with a bottom coating of 10 and LUXPRINT® 7138J and LUXPRINTtm 7153E, as in Examples 23 to 34 of the present invention The patchiness of the printed matter was evaluated as described above. The results printed through the P120 screen are shown in Table 18. Consumption cooperation by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, Du found that all components printed on all thin sheets and 15 on the LUXPRINT® 7138J were extremely mottled. Only the printed matter on the LUXPRINT® 7153E found a noticeable change in mottledness, because the coating composition of the compositions of Examples 35 and 36 of the present invention was far inferior to the compositions of Examples 37, 38, and 40 of the present invention. -56- This paper size is applicable to Chinese National Standards (CNS) A4 Regulation 4 (210 X 297 public love) 200305589 A7 B7 V. Description of the invention (55) Table 18: Use of the composition of the embodiment of the present invention 1 Mottle test nr 3 5 nr 36 nr 37 nr 38 nr 40 AUTOST AT ™ CT7 1 1 1 1 1 MAKRO FOL DE 1-1 SCI 1 1 1 1 PET with undercoat No. 1 1 1 1 1 LUXPRI NT 7138J 2 2 0-1 0-1 LUXPRI NT 7153E 4 3 1 1 1-2 ------ The composition of Examples 35 to 38 and 40 of the present invention was in the Intellectual Property Bureau of the Ministry of Economic Affairs, the Shellfish Consumer Cooperative, AUTOSTAT® CT7 For MAKROFOL DE 1-1 SCI, PET with a bottom 5 coating, and coatings on LUXPRINT® 7138J and LUXPRINT ™ 7153E, the adhesion quality is evaluated as described in Examples 18 to 22 of the present invention. The results printed on the P120 screen are shown in Table 19. 〇 57- The paper size is applicable to the Chinese standard (cns) A4 (21G X 297) Chu 0505589 A7 B7 V. Description of the invention (56) Table 19: Adhesive quality of eP brush using the composition of the embodiment of the present invention nr 35 nr 36 nr 37 nr 38 nr 40 AUTOST AT ™ CT7 0 0 0 0 0 MAKRO FOL DE 1-1 SCI 3 3 3 ' PET 0 0 0 0 LUXPRI NT 7138J 1 0 0 0 0 LUXPRI NT 7153E 0 0 0 0 1 0 Except for MAKROFOL ™ DE 1-1 SCI, superior adhesion was found. Printed by the Shelley Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs on the composition of Examples 35 to 38 and 40 of the present invention on 5 AUTOSTAT® CT7, MAKROFOL DE 1-1 SCI, PET with undercoat and LUXPRINT® 7138J and LUXPRINT ™ 7153E In terms of the coatings, the surface resistance of the printed matter was evaluated as described in Examples 1 to 13 of the present invention. The results printed through the P120 screen are shown in Table 20. -58- General Chinese National Standard (CJNS &A4; Y210 X 297) for paper-free dimensions 200305589 A7 _ B7 V. Description of the invention (57) Table 20: Surface resistance of printed matter using the composition of the embodiment of the present invention [ohm / Sq.) Nr 35 nr 36 nr 37 nr 38 nr 40 AUTOST AT ™ CT7 1423 1390 2200 1723 1523 MAKRO FOL DE 1-1 SCI 1393 1343 Mine 1546 1503 PET with undercoat No. 1 1296 1256 1583 1566 LUXPRI NT 7138J 3150 2360 5700 4050 2200 LUXPRI NT 7153E 5200 1800 2390 1725 1850 The surface resistance of printed materials produced using the compositions of Examples 35 and 36 of the present invention on a film is much lower than those of the compositions of Examples 37, 38, and 40 of the present invention. The change in surface resistance found on the LUXPR1NT® 7138J and LUXPRINT® 7153E layers is a change in layer thickness due to different wetting properties of different compositions. Printed by Shelley Consumer Co-operation, Intellectual Property Bureau of the Ministry of Economic Affairs, printed on different layers of AUTOSTAT CT7 and uncoated PET. The results are shown in Table 21. Surface resistance increases significantly with increasing layer thickness, and optical density decreases significantly. -59-

^ The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 male sTJ 200305589 A7B7 V. Description of the invention (58) Table 21: Example 15 of the present invention. Screen printing type on AUTOSTST CT7 PET Example 35 of the invention Surface resistance [ohm / square] of the present invention D Adhesive surface resistance [Ohm / square] D Adhesive surface resistance [Ohm 丨 square] D visible light P43---423 0.09-463 0.09 P59雠-562 0.08-586 0.07 P79--0 700 0.05-796 0.05 P120 1200 0.03 0 1423 0.03 0 1390 0.03 Examples 42 to 45 of the present invention The compositions of Examples 42 to 45 of the present invention are from Example 5 35 of the present invention Preparation of the starting materials to 41, which is adding 30 minutes of deionized water, ZONYL FSO, 3-glycidyloxypropyltrimethoxysilane, and silicone defoamer in the amount listed in Table 22 with stirring for 30 minutes. X50860A and optional Flexonyl® Blue B2G 〇 Printed by Shelley Consumer Cooperative, Intellectual Property Bureau, Ministry of Economic Affairs • 60- This paper size is applicable to China National Standard iCNS) A4 size (210 X 297 mm 200 305 589

V. Description of the invention (59 Table 22: 2-Glycidyloxypropyltrimethoxysilane)

Starting material ZONYL®

FSO

X50860A Printed by Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 5 The final composition is shown in Table 23. The ingredients of the invention are shown in Table 23; nr 42 nr 43 Nr 44 nr 45 PEDOT 0.224 0.223 0.211 0.211 PEDOT / PSS 0.762 0.759 0.719 0.716 DEG 9.032 1 8.986 1 8.52ΐΠ 8.477 PD 85 · 344— 84.913 80.513 80.107 3 _glycidyloxypropyltrimethoxysilane 0.500 0.500 0.472 0.472 ZONYL® FSOIOO 1 0.125 I 0.250 I 0.118 1 0.118 X50860A 0.250 0.500 0.236 0.472 ethylene glycol 0.063 0.125 0.059 0.118 Deionized water 3.924 3.967 3.702 3.742 PIG01 vertical-5.660 5.660 * ZONYL® FSO is a 50% by weight solution of ZONYL® FSO-100 in a mixture of 50% by weight water and 50% by weight ethylene glycol. 61 China National Standard (CNS) A4 specification (210 X 297 male «) 200305589 A7 B7 V. Description of the invention (60) The compositions of Examples 42 to 45 of the present invention were printed on a AUTOSTAT CT7 carrier using a manual press and P120 screen screen on. Surface resistance and optical density were measured as described in Examples 1 to 15 of the present invention. The results are listed in Table 24. 5 Table 24: Screen No. D blue D edge color D red D visible light surface resistance [ohm / square] in the embodiment of the present invention 42 P120 0.02 0.02 0.04 0.03 1663 43 P120 0.02 0.03 0.04 0.03 1917 44 P120 0.08 0.18 0.83 0.38 2843 45 P120 0.09 0.18 0.74 0.37 3583 The optical density of the printed matter printed using the compositions of Examples 44 and 45 of the present invention showed that it was transparent and blue. Examples 46 to 51 10 The compositions of Examples 46 to 51 of the present invention were prepared from the starting materials used in Examples 35 to 41 of the present invention, and were added with the amounts listed in Table 25 under stirring for 30 minutes. Ionized water, different nonionic and anionic fluorine-containing surfactants listed in Table 25, 3-glycidyloxypropyltrimethylammonium, intellectual property bureau, shellfish consumer cooperation, duoxysilane and silicone defoamer X50860A . 15 • 62- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (6i) Table 25: Ingredients Composition of the embodiment of the present invention 46 47 48 49 50 51 from Starting material 98.75 98.5 98.0 97.22 98.29 98.75 3-Glycidyloxypropyltrimethoxysilane 0.5 0,5 0,5 0,5 0,5 0,5 Zonyl® FS0100 0.25 雠----Zonyl® FSO Lai 0.5- ---Zonyl® FSA ONE-1---Zonyl® FSE-ONE-1.78-ONE Zonyl® FSP Section---0.71-Ammonium perfluorooctanoate-_-_ 0.25 X50860A 0.5 0.5 0.5 0.5 0.5 0.5 The final composition is shown in the table 26 in. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs X Consumer Cooperatives Table 26: Composition 46 47 48 49 50 51 PEDOT / PSS 0.762 0.760 0.756 0.750 0.758 0.762 DEG 9.023 9.000 8.954 8.883 8.981 9.023 PD 84.754 84.540 84.110 83.441 84.359 84.754 3-Glycidyloxypropyltrimethoxysilane 0.500 0.500 0.500 0.500 0.500 0.500 Zonyl® FSO100 (active) 0.250-----Zonyl® FSO (active)-0.250-----63- This paper size is applicable to China Standard (CNS) A4 specification (210 X 297 mm) 200305589 A7 B7 V. Description of invention (62)

Zonyl ⑧ FSA (active)

Zonyl® FSE (active)

Zonyl® FSP (active) ammonium perfluorooctanoate

Polysiloxane defoamer X50860A 0.240 0.240 0.250 0.250 0.249 0.012 0.240 0.240 0.240 0.240 Ethylene glycol 0.125 1.071 Isopropyl alcohol deionized water 4.471 4.586 0.325 4.815 4.865 0.319 4.594 4.711 Composition 5 Examples 46 to 5 of the present invention Using a manual press and P120 screen screen printing on the AUTOSTAT CT7 carrier and standard Luxprint® 7138J and Luxprint® 7153E layers, as described in Examples 35 to 38 and 40 of the present invention. Surface resistance and optical density were measured as described in Examples 1 to 15 of the present invention. Mottled properties and adhesion qualities were measured as described in Examples 23 to 34 of the present invention and Examples 18 to 22 of the present invention. The results are shown in Table 27. The mottled properties of the composition layers of Examples 46 to 51 of the present invention are good or excellent, and the mottled properties found on thin layers containing nonionic and anionic surfactants are extremely low. Compositions containing non-ionic surfactants (Examples 46 and 47 of the present invention) and compositions containing anionic surfactants (Examples 48 and 51 of the present invention) are both standard Luxprim® 7138J and Luxprint® 7153E The layer has superior adhesion. However, the compositions containing phosphate anionic surfactants in Examples 49 and 50 of the present invention gave poor adhesion on one or both of the 15 layers. In the case of Autostat® -64- This paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 G *). Ordered by the Intellectual Property Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperation, Du printed 10 200305589 A7 B7 V. Description of the invention (63) CT7 'All compositions have superior or excellent adhesion, regardless of whether the composition contains nonionic or anionic surfactants. Table 27: _Composition Example No. 46 _ 47 48 49 50 51 D Visible light 0.06 0.05 0.05 0.06 0.05 0.04 Spot-linked test Autostat ⑧ CT7 1 1 1-2 1 1-2 1 Adhesion quality Autostat ⑧ CT7 0 -1 0 0 0-1 0-1 0 Luxprint® 7138J 0 0 0 0-1 4 0 Luxprint® 7153E 0 0 0 4 4 0 Surface resistance, ohms / square Autostat® CT7 695 773 833 763 786 850 Luxprint® 7138J 3090 2900 2350 1475 1400 3600 Luxprint® 7153E 710 740 705 875 775 795 Printed on 5 layers of Luxprint® 7153E printed on Autostat® CT7 and standard Luxprint® 7138J and • tired Surface resistivity varies depending on the choice of surfactant. Contains ZONYL® FSE and ZONYL® FSP—both are anionic phosphate surfactants (see Examples 49 and 50 of the present invention). The surface resistance produced on the standard Luxprint® 7138J is significantly lower, but In the case of Example 50 of the present invention, the adhesive-65- this paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 200305589 A7 B7 5. Description of the invention (64)-The performance is also poor. These results clearly show that nonionic and anionic surfactants can be used in the composition of the present invention. 5 Examples 52 to 58 of the present invention The compositions of Examples 52 to 58 of the present invention are based on the weight ratio of PEDOT to PSS by mixing the solvent listed in Table 28 in Table 28 and the amount listed in Table 28. 1: 2.4 PEDOT / PSS in water in a conventional 1.2 weight percent dispersion in water, distilled at 60 ° C and 50 hPa (mbar) under vacuum 10 to evaporate from the resulting mixture with stirring, the production is also listed in the table Prepared from the composition of 28. The PEDOT content in these compositions, obtained by dividing the PEDOT / PSS content by 3.4, is between 0.53 and 1.03 weight percent. Table 28: Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the number of water removed from the mixture before dehydration of the Example No. of the present invention. Wt% (final) composition non-aqueous solvent 1.2 wt% PED OT / P SS dispersion in water PED OT / P SS [wt%] Non-aqueous solvent water [wt%] Surfactant type dosage [g] Type dosage [wt%] nr. Wt% 52 PD 50 150 68.2 1.8 PD 50 47.2 05 1 53 PD 75 150 85.0 1.8 PD 75 22.2 05 1 54 PD 20 267 71.3 3.2 PD 20 75.8 11 1 55 DEG 20 291.7 74.5 3.5 DEG 20 73.6 11 2.9 6- Moderate paper on paper

200305589 A7 B7 V. Description of the invention (65) 56 DEG 20 241.7 68.7 2.9 DEG 20 74.7 11 2.4 57 PD + 17 200 68.0 2.4 PD + 17+ 63.26 * 0.34 DEG 17 DEG 17 58 DEG 17 241.7 66.9 2.9 DEG 17 79.1 05 1 * 2 wt% dispersion of Ti02 in PD17. The compositions of Examples 52 to 58 of the present invention were printed on AUTOSTAT® CT7 via a screen screen as listed in Table 29, and dried at 120 ° C for 5 240 seconds. Surface resistance and optical density were measured as described in Examples 1 to 15 of the present invention. The results are shown in Table 29. The results in Table 29 show that the surface resistance decreases significantly as the PEDOT / PSS concentration in the coated composition increases. 10 Table 29: • Packing, ordering • Printed composition of the employee ’s cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, Example No. P48 Screen, P77 Screen, Thin Layer Quality D, JL Light Surface Resistance [ohm / square] Thin Layer Quality D can JL light surface resistance [ohm / square] 52 superior 0.16 150 superior 0.10 250 53--many tiny bubbles 0.07 430 54 superior surface 0.15 175 55 few bubbles 0.25 85 • • • 56 few bubbles 0.21 100 many bubbles 0.18 115 57 barely Adhesive 0.40 140 • One-58 Fully Adhesive 0.21 85-• • -67- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (66) Examples of the invention 59 to 69 The composition used to prepare the composition of Examples 59 to 69 of the present invention is obtained by first adding 18 kg of 1,2-propanediol and 2 kg of bis (ethylene glycol) to 20 kg of PEDOT to PSS weight ratio of 1 : The conventional 1.2 weight percent dispersion of PEDOT / PSS in 2.4: 5, stirred at 60 ° C and 50 hPa (mbar) under evaporating water, until 15.05 kg of liquid (mainly water) is removed, and finally stirred The ingredients listed in Table 30 was added to 297 g of the substance, and prepared to give a starting composition listed therein. Table 30: Amount [g] of the composition used to prepare Examples 59 to 69 of the present invention [gram] Starting material 297 2-Glycidyloxypropyltrisylsilane 1.5 ZONYL® FSO 0.75 X50860A 0.75 • Order · 10 Subsequently, PIG01 to PIG07 are added to the compositions listed in Table 30, and the amount is the amount required to obtain the compositions of Examples 59 to 69 of the present invention listed in Table 31 below. Table 31 Consumption Cooperative Printed Group ^ Payment Weight Percent tt) 59 60 61 62 63 64 65 66 67 68 69 FEDOT 0306 0312 0306 0312 0294 0306 0312 0312 0312 0312 012 0306 PEDOT / PSS m 1.05 1.04 1.06 1.00 1.04 1.05 1.06 1.06 1.06 1.06 m DEG 7.79 7.92 7.79 7.92 733 7.79 7.92 7.92 7.92 7.92 7.92 FD 69.87 71.04 69.87 im 67 * 53 69.87 71.04 71.04 71.04 im 69.87 -68- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (67) &gt; Glycidyloxypropyltrimethoxywei 05 0.5 05 05 0.5 05 0.5 0.5 05 0.5 05 CARBO ΚΆΜ AQUA 30 2.0 2.0 10 20 2.0 10 2.0 2.0 2.0 Z0 20 7〇tm, ® FS0100 025 025 025 025 025 0 25 025 025 025 025 025 X5086A 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.024 0.024 HQ01 0.6 03 _ HQ02 • • 1 · 0 05 HQQ3 • Pain • Sag 12 0.6 HOM surface • surface • _ 0.6 Steal one • HQ05 _ 15 • • FIG05 • 15 Mold Ore «007 • 057 1.14 Deionized Water 17.92 16.90 1752 16.70 19.97 17.92 16.60 15.70 15.70 15.70 15.70 1738 The pastes of Examples 59 to 69 of the present invention were printed by the Industrial and Commercial Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs through a P43 screen Screen printing on a AUTOSTAT® CT7 carrier and LUXPRINT® 7138J and LUXPRINT ™ 7153E using a manual screen printing press. AUTOSTAT® CT7 was dried at 120 ° C for 2 minutes, while 5 LUXPRINT® 7138J and LUXPRINTtm 7153E were printed at 130 ° C. Dry for 5 minutes. Printing quality, adhesion, surface resistance, and optical density were evaluated as described in Examples 1 to 15 of the present invention. Table 32 shows the results of the print on the AUTOSTAT® CT7. -69- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 X 297 male "" 5. Description of the invention (60 Table 32 5 61 65 i by P43 _______ [covered in iWTOSTAT® ctTX ^^ i- Properties / Adhesiveness using Tesapack 4122 0 0 Surface resistance [ohm / square] Blue 0.25 Green 0.48 0.34 0.22 Visible light 2.12 1.34 0.17 0.80 0.59 0.20 The printed matter of Examples 59 to 69 of the present invention &lt; all paste All pastes are about 400 ohms. The properties of the printed matter are obviously not affected by the choice of pigments. The results of the printed matter on the 7U8J: Ca_Ding ™ 7153E layer are shown in Table 7: 2 ”. Table 33: Ϊ 于 7153 Layer of this invention 1 Example No. __coating — surface resistance [European single layer 60 330 170 -70- This paper size applies to Chinese National Standard (CNS) A4 specification (210x297 ^ *) 200305589 A7 B7 V. Description of the invention (69 ) 61 1 __390 Π 200 410 220 62 L 340 II) 180 340 180 63 200 460, 214 64 __400 230 430 220 65 __350 190 37 ^ ~ J 200 66 __31〇170 390 J 165 67 __340 160 Γ 400 160 68 l_320 170 330 160 69 ^ _380 185 490 190 Implemented using the present invention The single-layer printed matter obtained from the 59-69 paste still has a surface resistance of about 40.0 ohms / square, and when the second-layer printed matter is printed on top of the first-layer printed matter, it is reduced to about 200 ohm / square. These results show that the present invention The colored composition can be used to produce a printed matter with 5 important optical densities and a surface resistance of about 400 ohms / square, regardless of the choice of pigment. Examples 70 to 72 of the present invention Printed by the Industrial Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The starting compositions used to prepare the compositions of Examples 70 and 71 of the present invention and Examples 72 of the present invention were individually added individually by first adding 594 g of 1,2-propanetriol and 6 g of N-methyl-benzene. Slightly burned ketone and 540 g of ι, 2-propanediol and 60 g of N-methyl-π billow __ 400 grams of PEDOT / PSS weight ratio of 1: 2 · 4 conventional PEDOT / PSS in water dispersed 1.2% by weight And then distilled under vacuum at 60. (: and 98kPa (0.98bar) under vacuum, and stirred under 15 to evaporate the water, until 391 g and 398 g of liquid (mainly water) were individually removed after 70 and 90 minutes. While prepared. The resulting composition series are shown in Table 34. -7 Pu Wood paper standard General Lao National Standard (CNS) Ai specifications 1 21〇 297 Gongchu 200305589 A7 B7 V. Description of invention (7〇 Table 34

-L ___ M8_ ^ — These compositions are then individually used as the starting composition of the composition of 71 and Example 72 of the present invention, which are added with appropriate amounts of the ingredients listed in Table 35 to prepare the compositions listed therein. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Industrial Cooperatives. 5 Table 35: Composition of ingredients without examples, hvt%) nr 70 nr 71 nr 72 PEDOT 0.215 0.203 0.215 PEDOT / PSS 0.73 0.69 0.73 PD 89.4 85.2 81.4 DEG-0.95 NMP 0.93 0.88 9.04 3-glycidyloxypropyldimethoxysilane 0.50 0.48 0.49 CARBOPOL⑧ AQUA 30 6.66 6.35 6.58 ZONYL® FS0100 0.25 0.24 0.25 X50860A 0.05 0.05 0.05 DISPERCOLL® U VP KA 8481-3.81-deionized water 1.39 1.32 1.37 This invention is implemented The uncolored pastes of Examples 70 to 72 were printed on a BAYFOL⑧CR1-4 and AUTOSTAT® CT7 carrier and a LUXPRINT® 7138J and • 72 by using a manual screen printing press through a P79 screen screen. This paper applies the Chinese national standard iCNS) A4. Specifications (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (71) On LUXPRINTtm 7153E, BAYFOL® CR1-4 is dried at 80 ° C for 10 minutes, AUTSTAT® CT7 is dried at 120 ° C for 2 minutes, and LUXPRINT ® 7138J and LUXPRINT ™ 7153E are based on 130. (: Drying for 5 minutes. Then, as described in Examples 1 to 15 of the present invention, 5 print quality, adhesion, surface resistance, and optical density were evaluated. The print quality series are shown in Table 36, and the surface resistance results are shown in Table 37. In Table 38, the optical density measurements are shown in Table 38, and the adhesion results are shown in Table 39. Tables are printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Shelley Consumer Cooperative, and printed on the examples of the present invention. Surface resistance [ohm / square 1 in BAYFOL® CR1-4 P79 layer on AUTOSTAT® CT7 P79 layer on AUTOSTAT® 7138J P79 layer on LUXPRINT® 7138J layer 70 2800 2800 3200 71 3200 3100 3300 72 2000 2350 3440 10 Table 36: Examples of the present invention are numbered on BAYFOL® CR1-4 Mottled pinhole turbidity of printed matter 70 2 0-71 0 0 1 72 1 3 2 This paper size is applicable to China National Standard (CNS) A4 (210x297) ^ 200305589 A7 B7 V. Description of the invention (5 袅 39: This Invention Example No. Adhesion according to TESAPACK® 4122 test P79 layer on BAYFOL® CR1-4 on P79 layer on AUTOSTA T® CR7 on LUXPRINT ⑧7138J P79 layer on LUXPRINT® 7153E P79 layer 70 4 0 4 4 71 0 0 0 0 72 4 〇H 0 0 The results in Table 39 clearly show that printed matter made using a paste containing DISPERCOLL® U VP KA 8481 according to Example 71 of the present invention has a higher print quality than the present invention. Examples 70 and 72 do not contain DISPERCOLL® U VP KA 8481. The adhesive is high: the printed product has a high adhesive. This proves that 袅 38 ·· The P79 layer on the AUTOSTST® CR7 according to the embodiment of the present invention is d μ color d The color recording d it color d can be seen first 70 0.02 0.03 0.03 0.02 71 0.02 0.02 0.03 0.03 72 0.02 0.02 0.03 0.01 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 11 DISPERCOLL® U VP KA 8481 For the paste of this invention in BAYER® The adhesion on CR 1-4 has an effect. Examples 73 to 76 of the present invention The composition of Example 73 of the present invention was prepared by first adding 54 kg of it glycerol and 6 kg of bis (ethylene glycol) to 40%. Kg pED〇T to pss ruled paper -74- 200305589 A7 B7 V. Description of the invention (73) Conventional 1.2 weight percent knife dispersion of PEDOT / PSS in water with a weight ratio of 1: 2.4 followed by 60C (Heating element temperature) and 83 hPa (mbar) vacuum distillation for 11 hours At this time, the water was stirred to evaporate. At this time, 39 75 kg of liquid was removed, and the residual water concentration was 27 weight percent. Subsequently, the ingredients of Example 73 of the present invention listed in Table 40 were added under 5 agitation to obtain the compositions listed therein. The composition of Example 73 of the present invention is then used as a starting composition for the preparation of the compositions of Examples 74 to 76 of the present invention. The appropriate amount of DISPERCOLL® U VP KA 8481 is added to produce the composition economy listed in Table 40. The Intellectual Property Bureau of the Ministry of Intellectual Property Bureau printed 10 articles. Table 40: Composition of the examples of the present invention [weight percentage] nr 73 nr 74 nr 75 r.221 nr 76 0.209 PEDOT 0.229 0.224— PEDOT / PSS 0.78 0.76 Γθ.75 0.71 PD 80.9 79.3 77.7 73.4 DEG 9.35 9.17 8.99 8.50 3-Glycidyloxypropyltrimethylfluorenylsilane 0.51 0.50 0.49 0.46 CARBOPOL® AQUA 30 6.74 6.60 6.47 6.12 ZONYL FS0100 0.25 0 · 25 — 0.24 0.23 X50860A 0.05 0.05 j 0.05 0,05 DISPERCOLL® U VP KA 8481 1.98 3.89 9.18 to Ionic water 1.40 1.38 1.35 1.27 The pastes of Examples 73 to 76 of the present invention were printed on BAYFOL® CR 1-4 and AUTOSTAT® -75- using a manual screen printing press via a P79 screen screen. The standard is applicable to Chinese national standards (CNS ) A4 Regulations (2ιox x 297) 200305589 A7 B7 V. Description of the Invention (74)

On the CT7 carrier and LUXPRINT® 7138J and LUXPRINTtm 7153E, BAYFOL® CR1_4 was dried at 80 ° C for 10 minutes, AUTSTAT⑧CT7 was dried at 120 ° C for 2 minutes, and LUXPRINT⑧ 7138J and LUXPRINT ™ 7153E were dried at 130 ° C for 5 minutes. 5 Then, the print quality, adhesion, surface resistance and optical density were evaluated as described in Examples 1 to 15 of the present invention. The print quality series on BAYFOL® CR 1_4 are shown in Table 41. The surface resistance results on all media are shown in Table 42. The optical density measurements on BAYFOL® CR 1-4 and AUTOSTAT® CT7 are based on 10 measurements. In Table 43. The surface resistance [ohm / square] of the present invention is printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Industrial Cooperatives on BAYFOL® CR 1-4 on AUTOST AT® CR7 on the LUXPRI NT® 7138J layer and on the LUXPRI NT® 7153E layer Example No. 100% stretched at 120 ° C before stretching 73 740 10700 1050 1050 840 74 990 10800 840 840 • 75 1430 23000 1000 1000 • 76 1240 20100 960 960-Table 41: Examples of this invention are numbered in BAYFOL® Printed on CR 1-4. Mottled pinhole turbidity of the paper 73 0 0 1 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7 The Industrial Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed Description of Invention (75) A 431 Example of the present invention No. P79 layer on BAYFOL® CR 1-4 P79 layer on AUTOSTST® CR7 Stretched before visible light 100% stretched at 120 ° C d visible light d blue d green d red d visible light 73 '0.05 0.08 0.02 0.03 0.04 0.02 74 0.04 0.08 0.03 0.04 0.05 0.03 75 0.03 0.07 0.02 0.03 0.04 0.03 76 0.03 0.11 0.02 0.03 0.05 0.02 on all media The series of adhesion measurement values are shown in Table 44. A 44: Adhesion of Example No. according to TESAPACK® 4122 test on P79 to BAYFOL⑧ CR Ια on AUTOS TAT® CT7 on LUXPR INT® 7138J layer before stretching on LUXPR INT® 7153E layer at 120 ° C After stretching down to 100%, 73 4 5 1 0 0 74 0 0 0 0 0 75 0 0 0 0 0 76 0 0 0 0 0 0 All the pastes evaluated are on the AUTOSTAT® CT7 and LUXPRINT⑧ 7138J and LUXPRINT® 7153E layers. The printed materials have excellent adhesion measurements, with or without DISPERCOLL® U VP KA 8481. However, compared with the printed material made from the paste of Example 73 of the present invention without DISPERCOLL® U VP KA 8481, the use of -77- this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (76) In the case of BAYFOL® CR 1-4, the adhesiveness of printed matter obtained by using the pastes of Examples 74 to 76 of the present invention containing DISPERCOLL® U VP KA 8481 is greatly improved. In addition, when using the printed matter prepared by the paste containing DISPERCOLL® U VP KA 8481 according to the present invention, the printed carrier is stretched at 100% at 5 120 ° C, and this kind of superior adhesion to BAYFOL® CR Ι Α is maintained. Sex. This stretching is accompanied by an increase in optical density from 0.02 to 0.03 to 0.07 to 0.11, and a surface resistance increase of 10 to 16 times. The increase in resistance during such stretching is much lower on printed matter made by using the paste of Example 74 of the present invention than on printed matter made by using the paste of Examples 75 and 76 of the present invention, indicating that it exceeds the good adhesion. The required amount of DISPERCOLL® U VP ΚΑ 8481 results in an increase in the surface resistance of the printed matter formed, which increases significantly when stretched. Example 77 of the present invention 15 The composition of Example 77 of the present invention was prepared by adding 239 g of printed alcohol '631 g of 1,2 · propylene glycol and 69 g of diethylene glycol (1,2-propanediol) of n-butanol, Intellectual Property Bureau, Ministry of Economic Affairs, Shellfish Consumer Cooperatives. ) In a conventional 1'2 weight percent dispersion of PEDOT / PSS in water at 1,635 grams of PEDOT to PSS weight ratio of 1: 2 · 4, followed by stirring at 6 (rc (heat source temperature) and 30 hPa (mbar) Distilled under vacuum for 16 hours, with part of pure water and 20 parts of azeotropic mixture with n-butanol (42.8% by weight of water and 57.2% by weight of n-butanol. The boiling point at atmospheric pressure is 927 ° C , Compare the water evaporation form of 100 ° C and n-butanol at 117 ° C. At this time, 1793 grams of liquid are removed, and the final PEDOT / PSS concentration is 2.5% by weight. The residual water content measured by Karl Fisher method is 3.9% by weight. Hundreds-78- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 200305589 Printed by Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of invention (77). Examples 78 and 79 For preparing the compositions of Examples 78 and 79 of the present invention The starting composition 5 used was prepared as follows. Firstly, 34.56 kg of double (ethylene glycol) 230.4 kg of pedOT in a 400 liter container was added to the PSS / PSS weight ratio of 1: 2.4. 2 2 In the weight percent dispersion, the oil bath (Example 78 of the present invention) at 55 ° C and the water bath of 60 ° C (Example of the present invention are used at a temperature of 88 to 89 ° C under stirring). 79) Distill 10 times to evaporate water, both under 20 hPa (mbar) vacuum, at the same time, add 31,104 kilograms of 12-propanediol at a rate of 31 kilograms per hour, until 242.9 kilograms of liquid mainly water is evaporated The water concentration was individually reduced to 1.1% by weight and 8.4% by weight. The composition obtained is shown in Table 45. 15 Table 45 · Example 78 of the present invention since Example 78 of the present invention [wt% ] Starting composition [wt%] PEDOT / PS S 0.82 0.73 PD 88.28 81.77 DEG 9.8 9.1 Deionized water 1, 1 8.4 These compositions are then individually used as starting materials for preparing the compositions of Examples 78 and 79 of the present invention. Starting composition, add the appropriate amount of ingredients shown in Table 46 to prepare 200 g of the listed composition -79- This paper size is applicable to National Standards of China (CNS) A4 grid (21 × χ297 mm) 200305589 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of Inventions (78) Table 46 : Ingredients Example composition of the present invention 丨 wt% l nr 78 nr 79 PEDOT 0.238 _ 0.211 PEDOT / PSS 0.808 0.719 PD 86.956 80.543 DEG 9.653 8.964 3-glycidoxypropyltrimethoxysilane 0.5 0.5 ZONYL® FS0100 0.5 0 · 5 X50860A 0.5 1 0.5 Deionized water 1.084 8.274 The paste of Examples 78 and 79 of the present invention is screen-printed on an AUTOSTAT® CT7 carrier and LUXPRINT® 7138J and LUXPRINT ™ 7153E using a manual screen printing press using a P120 screen. 5 AUTOSTAT® CT7 at 120. (: Dry for 2 minutes, and UJXPRTNT® 7138J and LUXPRINT ™ 7153E for 5 minutes at 130 ° C. Printing quality, adhesion, surface resistance, and optical density are evaluated as described in Examples 1 to 15 of the present invention. The printing quality results, optical density measurements, and surface resistance results of Examples 78 and 79 of the present invention are individually shown in Tables 47 and 48. -80- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 male «) 200305589 A7 B7 V. Description of the invention (79) Table 47: Print quality D blue D green D red D visible light surface resistance [ohm / square] Adhesive Autostat CT7 Matte 0.02 0.02 0.03 0.02 13800 1 Luxprint 7138 J ----50000 0 Luxprint 7153E---34000 0 Table 48: Print Quality D Blue D Green D Red D Visible Surface Resistance [ohm / square] Adhesive Autostat CT7 Mild Mottled 0.02 0.02 0.03 0.03 2170 0-1 Luxprint 7138 J-----5100 0-1 Luxprint 7153E-----5300 0 The results in Tables 47 and 48 clearly show the use of the paste of Example 47 of the present invention-prepared by evaporation at 88 to 89 ° C Preparation of the starting composition-a prepared 5 printed material having a starting composition prepared by printing at 55 ° C compared with the paste of Example 48 of the present invention-which has the same composition and printed by the Shelley Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The prepared coatings have poor coating quality and surface resistance. Examples 80 to 83 of the present invention 10 The starting compositions of Examples 80 to 83 of the present invention are also listed by the amounts listed in Table 49. The solvents in Table 49 are mixed in the amounts listed in Table 49 -81- This paper size applies to the Chinese national standard iCNS) A4 size (210 X 297 mm) 200305589 A7 B7 V. Description of the invention (80) 0.82 weight percent improvement PEDOT / PSS Aqueous Dispersion—The weight ratio of pss to PEDOT is 2. 4: 1, with a water bath with the temperatures listed in Table 49 under agitation, and distillation under a vacuum of 50 hPa (mbar) under stirring, and steaming from the resulting mixture The resulting composition is also listed in Table 49. 5 Table 49: The temperature of the water bath of the mixture before dehydration in the example of the present invention [° C] (finished) Composition of non-aqueous solvent 0.82% PEDO T / PSS PEDO T / PSS non-aqueous solvent water [wt%] Type dosage [ G] Dispersion in water [wt%] Type dosage [g] 80 BuOH PD DEG 2335 900 98 2333 60 2.74 PD + DEG 93.06 4.2 81 BuOH PD DEG 2335 900 98 2333 70 3.10 PD + DEG 94.70 2.2 82 PD DEG 900 98 2333 60 2.88 PD + DEG 91.02 6.1 83 PD DEG 900 98 2333 70 3.00 PD + DEG 94.50 2.5 The PEDOT content in these compositions-obtained by dividing the content of PEDOT / PSS by 3.4, which is between 0.8 and 0.8. Between 6 and 0. 912% by weight 0 The initial composition of Examples 80 to 83 of the present invention printed by the Bureau of Intellectual Property of the Ministry of Economic Affairs, Cooperative Co., Ltd. itself was passed through the sieve listed in Table 10 50 using a manually operated pressure Machine screen printing on autostattm ct〇7, the printed matter formed is dried at 130t 2 -82 · This paper size is common Chinese National Standard (CNS) A4 specification (210 X 297 public love 200305589 A7 B7 V. Description of the invention (81) minutes. This is as in Example 1 and The surface resistance and optical density were evaluated as described in 15. The quality of the printed matter was evaluated as mottled as described in Examples 23 to 34 of the present invention, and the comet (printing defect, in which the point-like defect 5 has a tail like comet behind) ) Grades 0 through 5, according to the following criteria, 0 corresponds to a thin layer without good comet: comet rating 0 head & no comet was found during review ~ a comet rating 1 on printed matter between 0 and 1% Finding comet Comet rating 2 Finding comet on printed matter between 1.1 and 5% | Comet rating 3 Found stratified comet rating 4 on prints between 5.1 and 10% Between ιο · ι and 15% Printing ^ Comet Rating 5 Issue 1 ^ ~ ^ ~ on more than 15% of the printed matter. Table 50: The starting composition of the example number of the present invention 80 81 82 83 Screen used P34 P34 P34 P34 ~ Dm 0.29 0.32 0.29 0.29 D green 0.36 0.39 0.36 0.37 D red 0.47 0.52 0.48—0.49 D visible light 0.30 0.34 0.31 0.31 mottle test 3 3 3 —--- 3 comet test 1 1 1 1 surface resistance [ohm / square] 101 90 96 95 Printed by Shelley Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs, used on 60 There is no significant difference in printing properties between prints produced by water bath azeotropic evaporation at ° C and those produced by water bath azeotropic evaporation at 70 ° C. Adding alcohols such as isopropanol or n-butanol improves print quality by reducing mottle and presence of comet. -83-This paper size is in accordance with Chinese National Standard &lt; CNS &gt; A4 Specification (21 × 297297200305589 A7 B7 V. Description of the Invention (82) These starting compositions are then used to prepare the examples of the present invention to 83. An opaque composition is prepared by adding an appropriate amount of the ingredients listed in Table 51, including the black pigment PIG07, to prepare 100 grams of the ingredients listed therein. Table 51: Ingredients 1 Composition of the present invention Γ wt% l nr 80 nr 81 nr 82 nr 83 PEDOT 0.733 0.830 0.771 0.803 PEDOT / PSS 2.494 2.822 2.622 2.731 PD + DEG + BuOH 88.546 88.218 88.418 88.309 3-Glycidoxypropyltrimethoxysilane 0.5 0.5 0.5 0.5 ZONYUD FS0100] 0.25 0.25 0.25 0.25 X50860A 0.05 0.05 0 · 0.05 0.05 Adhesive 02 6.66 6.66 6.66 6.66 PIG07 1.50 1.50 1.50 1.50 The opaque compositions of Examples 80 to 83 of the present invention were printed on the screens of Table 51 using a manually-operated screen press. On AUTOSTAT® CT7 carrier and LXJXPRINT® 7138J and LUXPRINT ™ 7153E layers, AUTOSTAT® CT7 is dried at 120 ° C for 2 minutes, while LUXPRINT⑧ 7138J and LUXPRINT ™ 10 7153E are dried at 130 ° c. 5 minutes. The surface resistance and optical density and the printing quality of the Intellectual Property Bureau of the Ministry of Printing and Economics of the Industrial and Commercial Cooperatives were evaluated as described in this article. 15 The printing quality results and optical density measurements of printed materials on AUTOSTAT® CT7 are shown in In Table 52, the surface resistance results of printed materials on AUTOSTAT® CT7, LUXPRINT® 7138J, and LUXPRINTtm 7153E are also shown in Table 52. -84- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (%) 200305589 A7 B7 V. Description of the invention (83) Table 52: The opaque component of the invention; Object 1 80 81 82 The screen used by P34, P34, P34 OD on Autostat® CT7 --- IT Du 1.57 1.52 1.42 τ \ ^ Λ 1.54 1.4? ^ green 1.35 ΤΛ Α gold 1.52 ——- ~ 1.45 red 1.25 1 37 D visible light 1.54 1.46 1.26 1 30 mottle test 1 1 2 9 comet test 1 1 7 9 surface resistance Ohm / square 'square'-L · Autostat® CT7 205 211 209 〇η Λ Luxprint® 7138J 176 177 Αβτ \ / 7 _J61 Δ t H 226 Luxprint® 7153E 269 ———-— 262 _21 ^ 1 300 in all Three types of printed properties on the evaluated surface. Examples 84 to 95 of the present invention. Printed by Shelley Consumer Cooperatives, Bureau of Intellectual Property, Ministry of Economic Affairs. 10 The starting compositions of Examples 84 to 95 of the present invention were prepared using the amounts listed in Table 53. The solvent also listed in Table 53 is an improved version of the mixed amount of 0.82 weighted PEDOT / PSS aqueous dispersion-the weight ratio of PSS to PEDOT is 2.4: 1—in a 60 ° C water bath under stirring And 50 hPa (50 mbar) vacuum evaporation to evaporate from the formed mixture 'to produce the composition also shown in Table 53. -85- This paper size applies the national standard (CNS) A4 specifications &lt; 210 X 297 male 1 公 200305589 A7 B7 V. Description of the invention (M) Table 53 Mixture before dehydration (most-non-aqueous solvent 0.82% PEDOT / Dispersion of PSS in water M_ PEDOT / PSS [wt%] Non-F- [wt%] Type dosage [g] Type for [wt%] PD DEG 9.765 1.085 44.310 3.0 PD + DEG 91.5 5.5 Ming composition 'It is added Appropriate amounts of the ingredients listed in Table 54 include various black pigments to prepare 100 grams of the listed compositions. Table 54: __ κ Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the composition of the embodiment number of the present invention [wt%] 84 85 86 87 88 89 90 91 92 93 94 95 PEDOT 0.76 0.74 0.74 0.76 0.77 0.78 0.77 0.77 0.77 0.75 0.74 0.73 PEDOT / PSS 2.66 2.60 2.60 2.66 2.69 2.69 2.69 2.69 2.69 2.63 2.60 2.55 PD + DEG 81.01 79.46 79.46 81.20 81.92 83.30 81.92 81.92 81.92 81.92 81.92 80.1ϋ 79.46 77.72 GOPTM S * 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 ZONYL ® FSOIOO 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 X50860A 0.05 0.05 0.05 0.05 0.05 0.05 0 .05 0.05 0.05 0.05 0.05 0.05 Adhesive 02 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 6.66 Adhesive 22---------2.0---86- &amp; Zhang scale applies to Chinese National Standard (CNS ) A4 (21〇χ297297M) 200305589 A7 B7 V. Description of the invention (85) PIG07 •-• 1.5 3.0 3.0 3.0 3.0 plane PIG10 4.0--• plane _-PIG11 plane 5.7--• • •-• _ PIG12 • 5.7-• Flap • •-Turn to PIG13 •-3.8 _ _ Righteous •-• • PIG14 Fen---3.0 雠 •-• Bay PIG15 Female •-• Noodle • _ • _ 5.7 PIG16 Suspect •--_ Secret • Fine 7.6 deionized water 4.87 4.78 4.78 4.88 4.93 5.01 4.93 4.93 4.93 4.81 4.78 4.67 Glycidoxypropyltrimethoxysilane 3-Glycidoxypropyltrimethoxysilane (GOPTMS), ZONYL® FS0100 and X50860A before stirring Add it to the starting composition, and then add pigment and binder 23 under mixing, except for Examples 89 and 90 of the present invention. If it is the paste of Example 93 of the present invention, the adhesive 22 is the final component added under stirring. Printed by the Cooperative Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The opaque compositions of Examples 84 to 95 of the present invention are slightly viscous, except for Example 88 of the present invention, which is slightly viscous. These opaque compositions should be left at least overnight before being printed on the AUTOSTAT® CT7 carrier and the LUXPRINT® 7138J and LUXPRINTtm 7153E layers using a screen printing machine screen printing 10 using a manually operated screen press through the screen listed in Table 55. AUTOSTAT® CT7 Dry at 130 ° C for 2 minutes, while LUXPRINT® 7138J and LUXPRINT ™ 7153E dry at 130 ° C for 5 minutes. Surface resistance, optical density, and print quality were evaluated as described here. Print quality results of printed materials on AUTOSTAT® CT7 and -87- This paper size is in accordance with Chinese National Standard (CNS) A4 (210x297 mm) 200305589 A7 B7 V. Description of the invention (86) The optical density measurement values are shown in the table Table 55 shows the surface resistance results of printed materials on AUTOSTAT® CT7, LUXPRINT® 7138J, and LUXPRINT ™ 7153E. Table 55: The opaque composition numbered in the examples of the present invention 84 85 86 87 88 89 90 91 92 93 94 95 Screen used P34 P34 P34 P34 P34 P34 P34 P34 P34 P34 P34 P34 P34 on the Autostat® CT7 D 0.70 1.71 2.03 0.36 2.84 0.98 1.65 1.87 2.22 2.20 2.85 0.94 Ό mt 0.75 1.66 1.97 0.43 2.71 0.99 1.62 1.85 2.16 2.04 2.64 0.94 D Red 0.83 1.64 1.88 0.52 2.62 1.05 1.62 1.87 2.16 2.01 2.57 0.98 D visible 0.71 1.67 1.97 0.38 2.77 0.97 1.62 1.85 2.18 2.07 1.ΊΊ 0.93 Mottled test 3 3-4 3 3 0 3 2 1 1 3 0 4 Comet test 2 1-2 2-3 0-1 1 1 2-3 1 1 4 0-1 1-2 Surface Resistance, ohm / square Autostat ⑧ CT7 98 106 115 100 91 94 94 94 84 113 114 121 Luxprint® 7138J-104 99-89 88 83 86 77 94 104-Luxprint® 7153E-114 124-92 95 104 98 89 108 113- Printed by the Intellectual Property Bureau Employee Consumer Cooperatives, Ministry of Economic Affairs5 The print properties were satisfactory on all three surfaces evaluated. Comparative Example 1 -88- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 200305589 A7 B7

V. Description of the invention (87) Example 1 of WO 02/042352 was repeated, and EDOT was polymerized in the presence of PSS as disclosed in EP-a, 0440957. 150 grams of the dispersion and 600 grams (690 Ml) toluene was mixed to form an oil-in-water emulsion, and 260 ml of water / toluene azeotrope was distilled off at 90 ° C for 5 hours using an oil bath at a temperature not exceeding 135 ° C. The PEDOT / PSS layer settled overnight, and a deposit was found on the thermometer. The azeotrope is at 92 ° C. (: Under distillation for another 200 minutes, a total of 825 ml (723 · 8 g) of azeotrope was distilled off. The distillate was separated into an aqueous phase (130 ml) and an oil phase. Washed with ethanol, filtered and dried to recover 17.8 g A dark blue residue containing 1 8 10 grams of PEDOT / PSS latex and 16 grams of water has been found to have a rubbery degree. After 5 minutes in an ultrasonic bath, the residue is easily redistributable &amp; in water. Comparative Example 2 15 Screen printing ink was prepared using powders prepared by freeze-drying an aqueous PEDOT / PSS dispersion as disclosed in samples XVII to XXIII of WO 02/00759. WO 02/00759 / 00759 samples XVII to XXIII are prepared by using different solvents in a selective and simultaneous use of CARBOPOL ™ ETD2623-added to 20-powder 'The powder was obtained by CHRIST BETA-16 under a vacuum of 0 ° (7 hPa (mbar)). Freeze-dried PEDOT: PSS weight ratio of 1: 2.46 in a rack freeze dryer. PEDOT / PSS aqueous dispersion is prepared until all water is evaporated (ie, until the rack temperature is equal to room temperature). Use ULTRA-TURRAX ™ to pre-score The paper size applies the Chinese national standard #_ (CNS) A4 specification (210: -89- 200305589 A7 B7 V. Description of the invention (88)), and then long-time ball milling [Time refer to Table 56 (= w〇〇2 / 〇〇 Table 8 of 759)] Knowing that the sample having the composition of Table 56 to XXIII (= Table 8 of WO 02/00759) 〇 Ball milling time [hour] PEDO T / PSS A [wt%] Water [wt% ] Carrier medium CAR ΒΟΡΟ L ETD 2623 [wt%]: ---- 一 · [wt%] XVII 24 1.19 〇JT bis (ethylene glycol) / carbitol-fluorene acetate 4/1 98.5 noodles XVIII 48 1.58 (0.42 m ^ m) 96.0 2 XIX 48 ^ 1.58 0.42 ^ N-methyl-pyrrole 96.0 2 ~ XX 48 1.58 XXII 96 1.98 0.52 ^ alcohol ill butyl _ jr ^ 96.0 2 XXIII 24 1.24 0.31 alcohol 97.5-this kind of high energy dispersion Technology is inferior to, — alcohol) 98.45-^ 々 忒, different water for organic negative 'without consuming such high energy for a long time. Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The characteristic series of samples χνπ to χχ obtained by redispersing the freeze-dried powder is shown in Table 57 (= Table 9 of WO 〇2 / 00759). -90- 200305589 A7 B7 V. Description of the invention (89) Equipment — Table 57PWO 02/00759 Table 9): Sample dispersion characteristics XVII Viscous and flocculating XVIII Extremely viscous dispersion XIX Extremely viscous dispersion XX Extremely viscous Dispersion XXII Highly flocculated XXIII Uniformly flowing dispersion sample XIII The composite viscosity was measured using an AR cone-plate rheometer at 25 ° c and frequencies of 10, 1 and 0.1 Hz. Individual systems were 1000 Pa.s, 5000 Pa. s and 40,000 Pa.s 〇5. Sample XXIII was screen-printed on a substrate-coated polyethylene terephthalate carrier with a P59 screen. The method for measuring the surface resistance of the formed printed matter is to cut a strip with a length of 27.5 cm and a width of 35 mm, and apply the electrode of the conductive polymer ECCOCOAT CC-2 at a width distance of 10 cm, and apply a fixed potential between the electrodes. A 10 picoammeter KEITHLEY 485 was used to measure the current flowing through the circuit, and the surface resistivity, ohm / square, was calculated from the potential and current, and the geometry of the area between the electrodes was taken into consideration. The optical density of this print was measured using a MACBETH ™ T924 densitometer through a visible light filter. The results are listed in Table 58 (= Table 10 of WO 02/00759). 15 Table 58 and Table 10 of WO 02/00759): The surface resistivity of the screen used for screen printing [ohm / square] Optical density [visible light filter] XXIII P59 370 0.11 -91- This paper size is applicable to China Standard (CNS) A4 Specification (210 X 297) «Ordered · Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 200305589 A7 B7 V. Description of the Invention (90) Example 96 of the present invention Preparation of the composition of Example 96 of the present invention Adding 57 grams of ethylene glycol to 430 grams of conventional 1.2% by weight PEDOT / PSS dispersion in water-the weight ratio of PEDOT to PSS is 1: 2.46—in, then at 60 ° C and 50 hPa (mbar) under vacuum The resulting mixture was evaporated in a rotary evaporator to produce the composition in Table 59. Table 59: Example 96 of the present invention Wt% PEDOT 0.29 wt% PEDOT / PSS, determined by drying at 150 ° C for 4 hours and measuring 1.00 wt% 2TET ^ &quot; ~ 95.6 wt% deionized water, by Karl-Fischer method Determining 3.4 Complex soil ^ Particle size [nanometer] 183 * Viscosity at 25C and Is · 1 12.56 Pa.s "Viscosity at 1.399 Pa.s Pei Ding ·" Eight T 1 · 〇mu, Xiao Cong 厶 Η / · / No 4, 10 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 15 The particle size of the PEDOT / PSS latex in the solvent-exchanged dispersion was measured as described in Examples 1 to 15 of the present invention, and the results are listed in Table 59. Viscosity measurement was performed using an AR100 plate cone rheometer at 25 ° C using a 2. angled cone and a 4 cm diameter plate at a shear rate increased from 0.1 to 1000 s-1, Table 59 lists the viscosity at ls "and 25s-i shear rate. The 25s-1 shear rate approximately corresponds to the shear rate of a Brookfield viscometer using a # 2 mandrel. The composition of Example 96 of the present invention is too viscous to be filtered. The paper size is -92-. This paper size is suitable for Chinese low-grade TCNS) A4 size (210 X 297 mm). 200305589 A7 B7. 5. Description of the invention (91 5 2000 rpm Spin for 1 second to spin-coat on a glass plate, spin-coat at 4,000 rpm for 50 seconds, then dry at 2rc for 30 minutes, and then at 85 C for 5 minutes. Apply the same method to the spin coating Cover the other layers. The characteristics of the thin layer obtained by spin coating 1, 2, and 3 are described in Examples 1 to 10 of the present invention, and the results are shown in Table 60. The frequency of the aggregate is borrowed from the center of the pan. 0.1 g of the solvent-dispersed dispersion was placed on A5 size AUTOSTAT ™ CT7 tablets, and A5 size AUTOSTATtm CT7 tablets were placed on top of it. The dispersion was visually inspected and classified into 1 to 3 ratings according to the following criteria: Aggregate rating 0 not found Aggregate; Aggregate rating 1 1 to 2 aggregates; Aggregate rating 2 3 to 5 aggregates; Aggregate rating 3 1 to 5 aggregates. ~~ 10 Spin coating number layer thickness [nano] Aggregation Material Rating Surface Resistance [ohm / square] Coefficient [S / cm] Optical density ~~~ D blue D green D red D visible light 1 66.7 0 2347 64 0.01 0.02 0.02 0.02 ^ 03 2 105.7 0 953 99 0.02 0.03 0.04 3 149.3 0-1 566 118 0.03 0.05 0.06 0.05 Printing of Comparative Examples 3 to 5 by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The starting materials used in the pastes of Comparative Examples 3 to 5 were prepared according to the method disclosed in WO 02/067273. 500 ml 3-neck flasks 15 100 ml of ethylene glycol, heated to 120 ° C on an oil bath, stirred at 2000 i * pm with ULTRA-TURRAX: stir. Use perfusion fruit -93-

200305589 A7 B7 V. Description of the invention (92) Add 76 ml of conventional 1.2 weight percent PEDOT / PSS dispersion in water at a rate of 1 ml / min-the weight ratio of PEDOT to pss is 1. · 2 · 46. The system is continuously flushed with nitrogen. Many water systems evaporate through the shaft of the ULTRA-TURRAX blender. After 3 hours, the mixture was cooled to room temperature. In Comparative Example 3, a Dean-Stark trap was used. In Comparative Examples 4 and 5, the Dean Stark trap was replaced by a conventional distillation apparatus using a condenser to improve the distillation rate. The conventional PEDOT / PSS dispersions used in Comparative Examples 3 and 4 were from the same batch as the composition of Example 96 of the present invention. BAYTRON ™ P from BAYER was used to prepare the composition of Comparative Example 5. The resulting dispersions were all thixotropic and were filtered through an 8 micron Millipore filter, leaving very little residue. The formation and concentration series of the dispersions are shown in Table 61. All dispersions were significantly flocculated. The particle size of the PEDOT / PSS latex in the solvent-exchanged dispersion was measured as described in Examples 1 to 15 of the present invention, and the results are shown in Table 61. Viscosity measurement is using AR100 plate cone rheometer at 25 ° C and 2 ° at 25 ° C. Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives printed a cone with a cone and a plate with a diameter of 4 cm. The shear rate was carried out. Table 61 lists the viscosity at Is · 1 and 25s-1 shear rate. The 25s-1 shear rate corresponds approximately to the shear rate of a Brookfield viscometer using a # 2 mandrel. -94- This paper size is in accordance with Chinese National Standard (CNS) A4 (210x297 mm) 200305589 A7 B7 V. Description of Invention (93) Table 61: Comparative Example No. PEDO T / PSS * [wt%] By Karl-Fische Γ Water content measured by method [wt%] Ethylene glycol [wt%] Viscosity of particle size distribution at 25 ° C # [Pa.s] Mean value of weight average, Nano half-width [Nano] Is1 25 s ] 3 0.81 15.3 83.89 77.7 55.6 0.515 0.192 4 0.8 13.6 85.6 78.5 76.4 0.559 0.205 5 1.0 10.05 88.95 96.1 59.5 0.660 0.223 * Measured by drying at 150 ° C for 4 hours # Use a plate with 2 ° cone and 6 cm diameter The weight average particle size measured by a cone-plate viscometer 5 increases with decreasing water content and increasing viscosity. The composition of Comparative Examples 3 to 5 printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs was followed by rotation at 800 rpm for 6 seconds and rotation at 1500 rpm for 50 seconds, followed by drying at 25 ° C for 30 minutes, and then at 85 ° C. Spin coating at 5 ° C for 5 minutes. Apply the other layers to this spin coat using the same method. The characteristics of the thin layer obtained by spin coating 1, 2, and 3 are as described in Examples 1 to 10 of the present invention, and the results are shown in Table 62. -95- This paper size applies to China National Standard (CNS) A4 (210 X 297 male «) Α7

table

Use the comparative example '——_ 10.03l〇.05l〇 ^ 07 | Q ^ Use the same liquid η ~ The degree of aggregation in the layer of Shixuan coating is much higher. Printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 10 15 Liquid Zhao and the hair; The layer of spin-coated layer of the aggregation process in the layer of :::, and the preparation of Example 96 of the invention which has not been transitioned before has nothing to do with. The higher degree of PEDOT / PSS polymer in the composition of Example 96 in the spin-coating compositions of Comparative Examples 3 to 5 is reflected in the quality of the layer it is made of, which is much lower than that of the 96 groups of inhabitants of the present invention. The fact is that the layer prepared by 3 spin coatings cannot measure the surface electrical Pi. In addition, the electrical conductivity of the thin layer prepared by using the same PEDOT / PSS aqueous dispersion as the composition of Example 96 of the present invention to prepare the composition of Guanguan 3 and * 2 spin coating is much lower than that of the present invention. The composition prepared in Example 96. These results show the superiority of the solvent replacement method of the present invention compared to the flash residue method disclosed in WO 02/06727. • 96- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (21〇χ 297 公 «) 200305589 A7 B7 Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The features or combinations of features disclosed herein or any of its general principles are the same whether or not they relate to the claimed invention. As far as the foregoing description is concerned, those skilled in the art can easily know various modifications within the scope of the present invention. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

Claims (1)

200305589 VI. Method of applying for a patent A8 B8 C8 D8 L composition method, the composition system contains a poly butterfly that is intermediate, polymer anion =: 3,4-dioxo-dioxolane can be the same or similar tit-type Non-aqueous solvents' wherein the two oxy-oxy bridges, where: c shows that the polymer or copolymer of optionally substituted oxyalkylene- and polymeric anion MΦ, ·-oxy alkoxide 存在) has oxygen. Preparation of dispersion liquid: The dispersion liquid is not substantially at least 4 = ΐ, and the method includes the following steps: 〇10 polymer or copolymer and the α4 · di-yl ° phene) polymerization step. The aqueous dispersion is mixed; and ") Since at least 65 times Jinbai; 3 substances evaporate water 'until the water content therein has been reduced by Wang / 0 3 weight percent. The method of applying for the first item in the scope of the patent of * * month, where The water in the mixture obtained from step i) is reduced by at least 80% by weight. The method of item 1 in the scope of patent No. 15 H7 of claim 7 wherein the water in the mixture obtained from step D is reduced by at least 90%. % By weight. The method of item 1 of the patent scope of Suo Qi, which can be obtained from the step i) The water in the mixture has been reduced by at least 95% by weight. The employee of the Intellectual Property Bureau of the Ministry of Economic Affairs has cooperated with Du Duan to make the method of item 1 in which the dye or pigment is added in a progressive processing step. 20 = application The method of the first item of the patent scope 'wherein the polymer or copolymer of (3,4 ·% dioxo%) is selected from the group consisting of the following polymers: · poly (3,' methyldioxythiophene), poly (3,4-methyldioxythiophene) derivative, poly (3'4-ethylenedifluorenylthiophene), poly (3,4-ethylenedioxythiophene) derivative, poly (3, "propylene Dioxythiophene), poly (3,4_propanedioxythiophene) derivative 98-This paper size applies to China National Standard (cns) A4 specification (210x297 public Υ Υ 200305589) 6. Scope of patent application Intellectual Property Bureau of the Ministry of Economic Affairs Employee Consumer Cooperative Printed Oxygen Dioxin ~ 8 is selected from the method such as Erlifan: Item \, which is _ glycerol, bis (ethylene glycol), N-methylpyrrolidone, and carbitol acetic acid The group consisting of esters. 疋 1. Money is coated with M products, which can produce a thin layer with improved conductivity at μ 敎 transparency. The composition is prepared by the tenth method. Τ qiao 10, a coating method 'includes the following steps: the configuration of the coating grade product as described in item 9 of the patent scope; and coating the coating grade product as the case may be The bottom-coated carrier, dielectric layer, phosphor layer, or transparent conductive layer to produce a thin layer with improved conductivity at a specific transparency. The coating method as described in claim 10 of the patent scope, wherein the carrier It is paper, polymer film, glass or ceramic. 12. A printing ink or paste, which can produce a thin layer with an improved conductivity coefficient under a specific transparency, is prepared by the method of the first patent application. 13. The printing ink of item 12 in the scope of Shenqing Patent, wherein the printing ink is lithographic printing ink, gravure printing ink, rubber plate rotary printing ink, screen printing ink, inkjet printing ink Liquid or offset printing ink. 14. A printing method comprising the following steps: configuring the printing ink such as the item 12 of the scope of patent application; printing the printing ink on the bottom of the case as appropriate 5 15 20 -99-This paper size applies Chinese national standards ( CNS) A4 specification (210x297 mm) Order 200305589 A8 B8 C8 D8 VI. Patent application layer coating on the carrier, dielectric layer, calender layer or transparent conductive layer to obtain an improved conductivity coefficient under specific transparency Thin layer. 15. The printing method according to item 14 of the application, wherein the carrier is paper, polymer film, glass or ceramic. Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -100 The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210x297 mm) 200305589 ㈠, this case refers to ^^ _ side: Canton: Figure (None) (II), this A brief description of the component representative symbols of the diagram: None If there is a chemical formula in this case, 1 »Reveal_The chemical formula that best shows the invention of Tewei: None Page 2-2